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Keywords = natural zones

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2199 KiB  
Proceeding Paper
Analysis of Multi-Decadal Shoreline Changes at Topocalma Beach (O’Higgins Region, Chile) Using Satellite Imagery
by Waldo Pérez-Martínez, Idania Briceño de Urbaneja, Joaquín Valenzuela-Jara and Isidora Díaz-Quijada
Eng. Proc. 2025, 94(1), 16; https://doi.org/10.3390/engproc2025094016 - 6 Aug 2025
Abstract
This study presents a 39-year spatiotemporal analysis of shoreline variability at Topocalma Beach (Chile) using satellite-derived data collected between 1985 and 2024. A total of 350 satellite images were processed with CoastSat and DSAS v6.0 to quantify erosional and accretional trends across distinct [...] Read more.
This study presents a 39-year spatiotemporal analysis of shoreline variability at Topocalma Beach (Chile) using satellite-derived data collected between 1985 and 2024. A total of 350 satellite images were processed with CoastSat and DSAS v6.0 to quantify erosional and accretional trends across distinct beach sectors. The results show persistent erosion in the proximal zone near the Topocalma wetland and localized accretion in the distal (southern) segment. These changes are closely associated with the 2010 Maule earthquake and tsunami, strong ENSO phases, and an increase in storm surge activity since 2015. The spatiotemporal beach width model reveals distinct phases of retreat and short-term post-seismic stabilization, followed by a shift to sustained erosion. Overall, this study underscores the limited natural recovery capacity of the beach and highlights the utility of satellite-based monitoring tools for coastal resilience planning in data-limited regions. Full article
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19 pages, 3032 KiB  
Review
The Microstructure and Modification of the Interfacial Transition Zone in Lightweight Aggregate Concrete: A Review
by Jian Zhou, Yiding Dong, Tong Qiu, Jiaojiao Lv, Peng Guo and Xi Liu
Buildings 2025, 15(15), 2784; https://doi.org/10.3390/buildings15152784 - 6 Aug 2025
Abstract
The interfacial transition zone (ITZ) significantly influences the mechanical properties and durability of lightweight aggregate concrete (LWAC), yet existing research on the ITZ in LWAC remains fragmented due to varied characterization techniques, inconsistent definitions of ITZ thickness and porosity, and the absence of [...] Read more.
The interfacial transition zone (ITZ) significantly influences the mechanical properties and durability of lightweight aggregate concrete (LWAC), yet existing research on the ITZ in LWAC remains fragmented due to varied characterization techniques, inconsistent definitions of ITZ thickness and porosity, and the absence of standardized performance metrics. This review focuses primarily on structural LWAC produced with artificial and natural lightweight aggregates, with intended applications in high-performance civil engineering structures. This review systematically analyzes the microstructure, composition, and physical properties of the ITZ, including porosity, microhardness, and hydration product distribution. Quantitative data from recent studies are highlighted—for instance, incorporating 3% nano-silica increased ITZ bond strength by 134.12% at 3 days and 108.54% at 28 days, while using 10% metakaolin enhanced 28-day compressive strength by 24.6% and reduced chloride diffusion by 81.9%. The review categorizes current ITZ enhancement strategies such as mineral admixtures, nanomaterials, surface coatings, and aggregate pretreatment methods, evaluating their mechanisms, effectiveness, and limitations. By identifying key trends and research gaps—particularly the lack of predictive models and standardized characterization methods—this review aims to synthesize key findings and identify knowledge gaps to support future material design in LWAC. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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16 pages, 5546 KiB  
Article
Modification of Vegetation Structure and Composition to Reduce Wildfire Risk on a High Voltage Transmission Line
by Tom Lewis, Stephen Martin and Joel James
Fire 2025, 8(8), 309; https://doi.org/10.3390/fire8080309 - 5 Aug 2025
Abstract
The Mapleton Falls National Park transmission line corridor in Queensland, Australia, has received a number of vegetation management treatments over the last decade to maintain and protect the infrastructure and to ensure continuous electricity supply. Recent treatments have included ‘mega-mulching’ (mechanical mastication of [...] Read more.
The Mapleton Falls National Park transmission line corridor in Queensland, Australia, has received a number of vegetation management treatments over the last decade to maintain and protect the infrastructure and to ensure continuous electricity supply. Recent treatments have included ‘mega-mulching’ (mechanical mastication of vegetation to a mulch layer) in 2020 and targeted herbicide treatment of woody vegetation, with the aim of reducing vegetation height by encouraging a native herbaceous groundcover beneath the transmission lines. We measured vegetation structure (cover and height) and composition (species presence in 15 × 2 m plots), at 12 transects, 90 m in length on the transmission line corridor, to determine if management goals were being achieved and to determine how the vegetation and fire hazard (based on the overall fuel hazard assessment method) varied among the treated corridor, the forest edge environment, and the natural forest. The results showed that vegetation structure and composition in the treated zones had been modified to a state where herbaceous plant species were dominant; there was a significantly (p < 0.05) higher native grass cover and cover of herbs, sedges, and ferns in the treated zones, and a lower cover of trees and tall woody plants (>1 m in height) in these areas. For example, mean native grass cover and the cover of herbs and sedges in the treated areas was 10.2 and 2.8 times higher, respectively, than in the natural forest. The changes in the vegetation structure (particularly removal of tall woody vegetation) resulted in a lower overall fuel hazard in the treated zones, relative to the edge zones and natural forest. The overall fuel hazard was classified as ‘high’ in 83% of the transects in the treated areas, but it was classified as ‘extreme’ in 75% of the transects in the adjacent forest zone. Importantly, there were few introduced species recorded. The results suggest that fuel management has been successful in reducing wildfire risk in the transmission corridor. Temporal monitoring is recommended to determine the frequency of ongoing fuel management. Full article
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17 pages, 5565 KiB  
Article
Green Mild Acid Treatment of Recycled Concrete Aggregates: Concentration Thresholds for Mortar Removal While Avoiding Degradation of Original Limestone Aggregate and Concrete
by Shunquan Zhang and Yifan Zhang
Materials 2025, 18(15), 3673; https://doi.org/10.3390/ma18153673 - 5 Aug 2025
Viewed by 104
Abstract
While acetic acid has proven effective as a mild acidic treatment for removing adhered mortar from recycled concrete aggregate (RCA) surfaces, its potential for dissolving damage to the surface of the original natural coarse aggregate (NCA) within the RCA and its impact on [...] Read more.
While acetic acid has proven effective as a mild acidic treatment for removing adhered mortar from recycled concrete aggregate (RCA) surfaces, its potential for dissolving damage to the surface of the original natural coarse aggregate (NCA) within the RCA and its impact on the resultant concrete properties require careful consideration. This investigation systematically evaluates the effects of varying concentrations of dilute acetic acid solutions, commonly used in RCA treatment protocols, through a multi-methodological approach that includes comprehensive physical characterization, stylus and 3D optical profilometry, scanning electron microscopy (SEM), and nanoindentation analysis. The results show that even dilute acid solutions have an upper concentration limit, as excessive acid concentration, specifically 0.4 M, induces significant textural dislocations on NCA surfaces, creating millimeter-scale erosion pits that increase aggregate water absorption by 18.5%. These morphological changes significantly impair concrete workability and reduce compressive strength performance. Furthermore, microstructural analysis reveals a 45.24% expansion in interfacial transition zone (ITZ) thickness, accompanied by notable reductions in elastic modulus and microhardness characteristics. In practical RCA treatment applications, for RCA containing limestone-based NCA, it is recommended to use acetic acid concentrations between 0.1 and 0.3 M to avoid substantial physical and microstructural degradation of aggregates and concrete. Full article
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29 pages, 14336 KiB  
Article
Geospatial Mudflow Risk Modeling: Integration of MCDA and RAMMS
by Ainur Mussina, Assel Abdullayeva, Victor Blagovechshenskiy, Sandugash Ranova, Zhixiong Zeng, Aidana Kamalbekova and Ulzhan Aldabergen
Water 2025, 17(15), 2316; https://doi.org/10.3390/w17152316 - 4 Aug 2025
Viewed by 175
Abstract
This article presents a comprehensive assessment of mudflow risk in the Talgar River basin through the application of Multi-Criteria Decision Analysis (MCDA) methods and numerical modeling using the Rapid Mass Movement Simulation (RAMMS) environment. The first part of the study involves a spatial [...] Read more.
This article presents a comprehensive assessment of mudflow risk in the Talgar River basin through the application of Multi-Criteria Decision Analysis (MCDA) methods and numerical modeling using the Rapid Mass Movement Simulation (RAMMS) environment. The first part of the study involves a spatial assessment of mudflow hazard and susceptibility using GIS technologies and MCDA. The key condition for evaluating mudflow hazard is the identification of factors influencing the formation of mudflows. The susceptibility assessment was based on viewing the area as an object of spatial and functional analysis, enabling determination of its susceptibility to mudflow impacts across geomorphological zones: initiation, transformation, and accumulation. Relevant criteria were selected for analysis, each assigned weights based on expert judgment and the Analytic Hierarchy Process (AHP). The results include maps of potential mudflow hazard and susceptibility, showing areas of hazard occurrence and risk impact zones within the Talgar River basin. According to the mudflow hazard map, more than 50% of the basin area is classified as having a moderate hazard level, while 28.4% is subject to high hazard, and only 1.8% falls under the very high hazard category. The remaining areas are categorized as very low (4.1%) and low (14.7%) hazard zones. In terms of susceptibility to mudflows, 40.1% of the territory is exposed to a high level of susceptibility, 35.6% to a moderate level, and 5.5% to a very high level. The remaining areas are classified as very low (1.8%) and low (15.6%) susceptibility zones. The predictive performance was evaluated through Receiver Operating Characteristic (ROC) curves, and the Area Under the Curve (AUC) value of the mudflow hazard assessment is 0.86, which indicates good adaptability and relatively high accuracy, while the AUC value for assessing the susceptibility of the territory is 0.71, which means that the accuracy of assessing the susceptibility of territories to mudflows is within the acceptable level of model accuracy. To refine the spatial risk assessment, mudflow modeling was conducted under three scenarios of glacial-moraine lake outburst using the RAMMS model. For each scenario, key flow parameters—height and velocity—were identified, forming the basis for classification of zones by impact intensity. The integration of MCDA and RAMMS results produced a final mudflow risk map reflecting both the likelihood of occurrence and the extent of potential damage. The presented approach demonstrates the effectiveness of combining GIS analysis, MCDA, and physically-based modeling for comprehensive natural hazard assessment and can be applied to other mountainous regions with high mudflow activity. Full article
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17 pages, 6882 KiB  
Article
Development and Evaluation of a Solar Milk Pasteurizer for the Savanna Ecological Zones of West Africa
by Iddrisu Ibrahim, Paul Tengey, Kelci Mikayla Lawrence, Joseph Atia Ayariga, Fortune Akabanda, Grace Yawa Aduve, Junhuan Xu, Robertson K. Boakai, Olufemi S. Ajayi and James Owusu-Kwarteng
Solar 2025, 5(3), 38; https://doi.org/10.3390/solar5030038 - 4 Aug 2025
Viewed by 149
Abstract
In many developing African countries, milk safety is often managed through traditional methods such as fermentation or boiling over firewood. While these approaches reduce some microbial risks, they present critical limitations. Firewood dependency contributes to deforestation, depletion of agricultural residues, and loss of [...] Read more.
In many developing African countries, milk safety is often managed through traditional methods such as fermentation or boiling over firewood. While these approaches reduce some microbial risks, they present critical limitations. Firewood dependency contributes to deforestation, depletion of agricultural residues, and loss of soil fertility, which, in turn, compromise environmental health and food security. Solar pasteurization provides a reliable and sustainable method for thermally inactivating pathogenic microorganisms in milk and other perishable foods at sub-boiling temperatures, preserving its nutritional quality. This study aimed to evaluate the thermal and microbial performance of a low-cost solar milk pasteurization system, hypothesized to effectively reduce microbial contaminants and retain milk quality under natural sunlight. The system was constructed using locally available materials and tailored to the climatic conditions of the Savanna ecological zone in West Africa. A flat-plate glass solar collector was integrated with a 0.15 cm thick stainless steel cylindrical milk vat, featuring a 2.2 cm hot water jacket and 0.5 cm thick aluminum foil insulation. The system was tested in Navrongo, Ghana, under ambient temperatures ranging from 30 °C to 43 °C. The pasteurizer successfully processed up to 8 L of milk per batch, achieving a maximum milk temperature of 74 °C by 14:00 GMT. Microbial analysis revealed a significant reduction in bacterial load, from 6.6 × 106 CFU/mL to 1.0 × 102 CFU/mL, with complete elimination of coliforms. These results confirmed the device’s effectiveness in achieving safe pasteurization levels. The findings demonstrate that this locally built solar pasteurization system is a viable and cost-effective solution for improving milk safety in arid, electricity-limited regions. Its potential scalability also opens avenues for rural entrepreneurship in solar-powered food and water treatment technologies. Full article
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11 pages, 258 KiB  
Article
Occupational and Nonoccupational Chainsaw Injuries in the United States: 2018–2022
by Judd H. Michael and Serap Gorucu
Safety 2025, 11(3), 75; https://doi.org/10.3390/safety11030075 - 4 Aug 2025
Viewed by 53
Abstract
Chainsaws are widely used in various occupational settings, including forestry, landscaping, farming, and by homeowners for tasks like tree felling, brush clearing, and firewood cutting. However, the use of chainsaws poses significant risks to operators and bystanders. This research quantified and compared occupational [...] Read more.
Chainsaws are widely used in various occupational settings, including forestry, landscaping, farming, and by homeowners for tasks like tree felling, brush clearing, and firewood cutting. However, the use of chainsaws poses significant risks to operators and bystanders. This research quantified and compared occupational and nonoccupational injuries caused by contact with chainsaws and related objects during the period from 2018 to 2022. The emergency department and OSHA (Occupational Safety and Health Administration) data were used to characterize the cause and nature of the injuries. Results suggest that for this five-year period an estimated 127,944 people were treated in U.S. emergency departments for chainsaw-related injuries. More than 200 non-fatal and 57 fatal occupational chainsaw-involved injuries were found during the same period. Landscaping and forestry were the two industries where most of the occupational victims were employed. Upper and lower extremities were the most likely injured body parts, with open wounds from cuts being the most common injury type. The majority of fatal injuries were caused by falling objects such as trees and tree limbs while using a chainsaw. Our suggestions to reduce injuries include proper training and wearing personal protective equipment, as well as making sure any bystanders are kept in a safety zone away from trees being cut. Full article
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21 pages, 1435 KiB  
Article
Spatiotemporal Context for Daylight Saving Time-Safety Interactions in the Contiguous United States
by Edmund Zolnik and Patrick Baxter
Future Transp. 2025, 5(3), 102; https://doi.org/10.3390/futuretransp5030102 - 4 Aug 2025
Viewed by 81
Abstract
Motor vehicle crashes are a persistent cause of unintentional deaths in the United States. Scholarship on how manmade interventions and natural phenomena interact to effectuate such calamitous outcomes is longstanding. One manmade intervention of interest in the literature is daylight saving time (DST). [...] Read more.
Motor vehicle crashes are a persistent cause of unintentional deaths in the United States. Scholarship on how manmade interventions and natural phenomena interact to effectuate such calamitous outcomes is longstanding. One manmade intervention of interest in the literature is daylight saving time (DST). Unfortunately, results on how the natural phenomena attributable to DST interact with driver behavior are inconsistent. To advance knowledge on DST-safety interactions, this study adopts a multilevel model approach to fatal motor vehicle crash outcomes in the contiguous United States. Results from a national analysis contextualize results from zonal analyses to unmask within- and between-time zone differences in DST-safety interactions. In the national analysis, motor vehicle crash fatalities decrease somewhat during DST (−0.10%). In the zonal analyses, motor vehicle crash fatalities decrease more so in the Central and Eastern time zones (−2.00% and −2.00%, respectively), but increase somewhat in the Pacific and Mountain time zones (+0.30%) during DST. The spatiotemporal context of the national analysis highlights specific policy implications from the zonal analyses to decrease the lethality of motor vehicle crashes. Specifically, interdictions to target alcohol and/or drug involvement in the northern latitudes of the Pacific and Mountain time zones during DST, the Central time zone at dawn or dusk before or after DST, and the northern latitudes in the Eastern time zone before or after DST are important. Generally, national DST-safety benefits mask zonal DST-safety costs in the Pacific and Mountain time zones. Full article
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21 pages, 4289 KiB  
Article
H2 Transport in Sedimentary Basin
by Luisa Nicoletti, Juan Carlos Hidalgo, Dariusz Strąpoć and Isabelle Moretti
Geosciences 2025, 15(8), 298; https://doi.org/10.3390/geosciences15080298 - 3 Aug 2025
Viewed by 193
Abstract
Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing [...] Read more.
Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing H2 flows to spread out rather than be concentrated in fractures. In that case, three different H2 transport modes exist: advection (displacement of water carrying dissolved gas), diffusion, and free gas Darcy flow. Numerical models have been run to compare the efficiency of these different modes and the pathway they imply for the H2 in a sedimentary basin with active aquifers. The results show the key roles of these aquifers but also the competition between free gas flow and the dissolved gas displacement which can go in opposite directions. Even with a conservative hypothesis on the H2 charge, a gaseous phase exists at few kilometers deep as well as free gas accumulation. Gaseous phase displacement could be the faster and diffusion is neglectable. The modeling also allows us to predict where H2 is expected in the soil: in fault zones, eventually above accumulations, and, more likely, due to exsolution, above shallow aquifers. Full article
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27 pages, 2496 KiB  
Article
A Context-Aware Tourism Recommender System Using a Hybrid Method Combining Deep Learning and Ontology-Based Knowledge
by Marco Flórez, Eduardo Carrillo, Francisco Mendes and José Carreño
J. Theor. Appl. Electron. Commer. Res. 2025, 20(3), 194; https://doi.org/10.3390/jtaer20030194 - 2 Aug 2025
Viewed by 287
Abstract
The Santurbán paramo is a sensitive high-mountain ecosystem exposed to pressures from extractive and agricultural activities, as well as increasing tourism. In response, this study presents a context-aware recommendation system designed to support sustainable tourism through the integration of deep neural networks and [...] Read more.
The Santurbán paramo is a sensitive high-mountain ecosystem exposed to pressures from extractive and agricultural activities, as well as increasing tourism. In response, this study presents a context-aware recommendation system designed to support sustainable tourism through the integration of deep neural networks and ontology-based semantic modeling. The proposed system delivers personalized recommendations—such as activities, accommodations, and ecological routes—by processing user preferences, geolocation data, and contextual features, including cost and popularity. The architecture combines a trained TensorFlow Lite model with a domain ontology enriched with GeoSPARQL for geospatial reasoning. All inference operations are conducted locally on Android devices, supported by SQLite for offline data storage, which ensures functionality in connectivity-restricted environments and preserves user privacy. Additionally, the system employs geofencing to trigger real-time environmental notifications when users approach ecologically sensitive zones, promoting responsible behavior and biodiversity awareness. By incorporating structured semantic knowledge with adaptive machine learning, the system enables low-latency, personalized, and conservation-oriented recommendations. This approach contributes to the sustainable management of natural reserves by aligning individual tourism experiences with ecological protection objectives, particularly in remote areas like the Santurbán paramo. Full article
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19 pages, 993 KiB  
Article
Antibacterial Properties of Submerged Cultivated Fomitopsis pinicola, Targeting Gram-Negative Pathogens, Including Borrelia burgdorferi
by Olga Bragina, Maria Kuhtinskaja, Vladimir Elisashvili, Mikheil Asatiani and Maria Kulp
Sci 2025, 7(3), 104; https://doi.org/10.3390/sci7030104 - 2 Aug 2025
Viewed by 161
Abstract
The rise in multidrug-resistant bacterial strains and persistent infections such as Lyme disease caused by Borrelia burgdorferi highlights the need for novel antimicrobial agents. The present study explores the antioxidant, antibacterial, and cytotoxic properties of extracts from submerged mycelial biomass of Fomitopsis pinicola [...] Read more.
The rise in multidrug-resistant bacterial strains and persistent infections such as Lyme disease caused by Borrelia burgdorferi highlights the need for novel antimicrobial agents. The present study explores the antioxidant, antibacterial, and cytotoxic properties of extracts from submerged mycelial biomass of Fomitopsis pinicola, cultivated in synthetic and lignocellulosic media. Four extracts were obtained using hot water and 80% ethanol. The provided analysis of extracts confirmed the presence of various bioactive compounds, including flavonoids, alkaloids, and polyphenols. All extracts showed dose-dependent antioxidant activity (IC50: 1.9–6.7 mg/mL). Antibacterial tests revealed that Klebsiella pneumoniae was most sensitive, with the L2 extract producing the largest inhibition zone (15.33 ± 0.47 mm), while the strongest bactericidal effect was observed against Acinetobacter baumannii (MBC as low as 0.5 mg/mL for L1). Notably, all extracts significantly reduced the viability of stationary-phase B. burgdorferi cells, with L2 reducing viability to 42 ± 2% at 5 mg/mL, and decreased biofilm mass, especially with S2. Cytotoxicity assays showed minimal effects on NIH 3T3 cells, with slight toxicity in HEK 293 cells for S2 and L1. These results suggest that F. pinicola extracts, particularly ethanolic L2 and S2, may offer promising natural antimicrobial and antioxidant agents for managing resistant infections. Full article
(This article belongs to the Section Biology Research and Life Sciences)
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14 pages, 3081 KiB  
Article
Habitat Distribution Pattern of François’ Langur in a Human-Dominated Karst Landscape: Implications for Its Conservation
by Jialiang Han, Xing Fan, Ankang Wu, Bingnan Dong and Qixian Zou
Diversity 2025, 17(8), 547; https://doi.org/10.3390/d17080547 - 1 Aug 2025
Viewed by 152
Abstract
The Mayanghe National Nature Reserve, a key habitat for the endangered François’ langur (Trachypithecus francoisi), faces significant anthropogenic disturbances, including extensive distribution of croplands, roads, and settlements. These human-modified features are predominantly concentrated at elevations between 500 and 800 m and [...] Read more.
The Mayanghe National Nature Reserve, a key habitat for the endangered François’ langur (Trachypithecus francoisi), faces significant anthropogenic disturbances, including extensive distribution of croplands, roads, and settlements. These human-modified features are predominantly concentrated at elevations between 500 and 800 m and on slopes of 10–20°, which notably overlap with the core elevation range utilized by François’ langur. Spatial analysis revealed that langurs primarily occupy areas within the 500–800 m elevation band, which comprises only 33% of the reserve but hosts a high density of human infrastructure—including approximately 4468 residential buildings and the majority of cropland and road networks. Despite slopes >60° representing just 18.52% of the area, langur habitat utilization peaked in these steep regions (exceeding 85.71%), indicating a strong preference for rugged karst terrain, likely due to reduced human interference. Habitat type analysis showed a clear preference for evergreen broadleaf forests (covering 37.19% of utilized areas), followed by shrublands. Landscape pattern metrics revealed high habitat fragmentation, with 457 discrete habitat patches and broadleaf forests displaying the highest edge density and total edge length. Connectivity analyses indicated that distribution areas exhibit a more continuous and aggregated habitat configuration than control areas. These results underscore François’ langur’s reliance on steep, forested karst habitats and highlight the urgent need to mitigate human-induced fragmentation in key elevation and slope zones to ensure the species’ long-term survival. Full article
(This article belongs to the Topic Advances in Geodiversity Research)
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17 pages, 7820 KiB  
Article
Visible Light Activation of Anatase TiO2 Achieved by beta-Carotene Sensitization on Earth’s Surface
by Xiao Ge, Hongrui Ding, Tong Liu, Yifei Du and Anhuai Lu
Catalysts 2025, 15(8), 739; https://doi.org/10.3390/catal15080739 - 1 Aug 2025
Viewed by 216
Abstract
Photocatalytic redox processes significantly contribute to shaping Earth’s surface environment. Semiconductor minerals exhibiting favorable photocatalytic properties are ubiquitous on rock and soil surfaces. However, the sunlight-responsive characteristics and functions of TiO2, an excellent photocatalytic material, within natural systems remain incompletely understood, [...] Read more.
Photocatalytic redox processes significantly contribute to shaping Earth’s surface environment. Semiconductor minerals exhibiting favorable photocatalytic properties are ubiquitous on rock and soil surfaces. However, the sunlight-responsive characteristics and functions of TiO2, an excellent photocatalytic material, within natural systems remain incompletely understood, largely due to its wide bandgap limiting solar radiation absorption. This study analyzed surface coating samples, determining their elemental composition, distribution, and mineralogy. The analysis revealed enrichment of anatase TiO2 and β-carotene. Informed by these observations, laboratory simulations were designed to investigate the synergistic effect of β-carotene on the sunlight-responsive behavior of anatase. Results demonstrate that β-carotene-sensitized anatase exhibited a 64.4% to 66.1% increase in photocurrent compared to pure anatase. β-carotene sensitization significantly enhanced anatase’s electrochemical activity, promoting rapid electron transfer. Furthermore, it improved interfacial properties and acted as a photosensitizer, boosting photo-response characteristics. The sensitized anatase displayed a distinct absorption peak within the 425–550 nm range, with visible light absorption increasing by approximately 17.75%. This study elucidates the synergistic mechanism enhancing the sunlight response between anatase and β-carotene in natural systems and its broader environmental implications, providing new insights for research on photocatalytic redox processes within Earth’s critical zone. Full article
(This article belongs to the Special Issue Advancements in Photocatalysis for Environmental Applications)
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17 pages, 5265 KiB  
Article
Influence of Agricultural Practices on Soil Physicochemical Properties and Rhizosphere Microbial Communities in Apple Orchards in Xinjiang, China
by Guangxin Zhang, Zili Wang, Huanhuan Zhang, Xujiao Li, Kun Liu, Kun Yu, Zhong Zheng and Fengyun Zhao
Horticulturae 2025, 11(8), 891; https://doi.org/10.3390/horticulturae11080891 (registering DOI) - 1 Aug 2025
Viewed by 204
Abstract
In response to the challenges posed by soil degradation in the arid regions of Xinjiang, China, green and organic management practices have emerged as effective alternatives to conventional agricultural management methods, helping to mitigate soil degradation by promoting natural soil recovery and ecological [...] Read more.
In response to the challenges posed by soil degradation in the arid regions of Xinjiang, China, green and organic management practices have emerged as effective alternatives to conventional agricultural management methods, helping to mitigate soil degradation by promoting natural soil recovery and ecological balance. However, most of the existing studies focus on a single management practice or indicator and lack a systematic assessment of the effects of integrated orchard management in arid zones. This study aims to investigate how different agricultural management practices influence soil physicochemical properties and inter-root microbial communities in apple orchards in Xinjiang and to identify the main physicochemical factors affecting the composition of inter-root microbial communities. Inter-root soil samples were collected from apple orchards under green management (GM), organic management (OM), and conventional management (CM) in major apple-producing regions of Xinjiang. Microbial diversity and community composition of the samples were analyzed using high-throughput amplicon sequencing. The results revealed significant differences (p < 0.05) in soil physicochemical properties across different management practices. Specifically, GM significantly reduced soil pH and C:N compared with OM. Both OM and GM significantly decreased soil available nutrient content compared with CM. Moreover, GM and OM significantly increased bacterial diversity and changed the community composition of bacteria and fungi. Proteobacteria and Ascomycota were identified as the dominant bacteria and fungi, respectively, in all management practices. Linear discriminant analysis (LEfSe) showed that biomarkers were more abundant under OM, suggesting that OM may contribute to ecological functions through specific microbial taxa. Co-occurrence network analysis (building a network of microbial interactions) demonstrated that the topologies of bacteria and fungi varied across different management practices and that OM increased the complexity of microbial co-occurrence networks. Mantel test analysis (analyzing soil factors and microbial community correlations) showed that C:N and available potassium (AK) were significantly and positively correlated with the community composition of bacteria and fungi, and that C:N, soil organic carbon (SOC), and alkaline hydrolyzable nitrogen (AN) were significantly and positively correlated with the diversity of fungi. Redundancy analysis (RDA) further indicated that SOC, C:N, and AK were the primary soil physicochemical factors influencing the composition of microbial communities. This study provides theoretical guidance for the sustainable management of orchards in arid zones. Full article
(This article belongs to the Section Fruit Production Systems)
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22 pages, 6617 KiB  
Article
Natural Plant Oils as Anti-Algae Biocides for Sustainable Application in Cultural Heritage Protection
by Michał Komar, Nathnael Derese, Kamil Szymczak, Paulina Nowicka-Krawczyk and Beata Gutarowska
Sustainability 2025, 17(15), 6996; https://doi.org/10.3390/su17156996 - 1 Aug 2025
Viewed by 267
Abstract
The prevention of biofilm formation and algal biodeterioration on building materials, particularly on cultural heritage sites, is a growing concern. Due to regulatory restrictions on conventional algicidal biocides in Europe, natural alternatives such as essential oils are gaining interest for their potential use [...] Read more.
The prevention of biofilm formation and algal biodeterioration on building materials, particularly on cultural heritage sites, is a growing concern. Due to regulatory restrictions on conventional algicidal biocides in Europe, natural alternatives such as essential oils are gaining interest for their potential use in heritage conservation. This study evaluates the anti-algal activity of Salvia officinalis and Equisetum arvense (essential oils, hydrolates, and extracts) against a mixed culture of five green algae species (Bracteacoccus minor, Stichococcus bacillaris, Klebsormidium nitens, Chloroidium saccharophilum, and Diplosphaera chodatii). The plant materials were processed using hydrodistillation and solvent extraction, followed by chemical characterization through gas chromatography–mass spectrometry (GC-MS). Biological efficacy was assessed by measuring algal growth inhibition, changes in biomass colour, chlorophyll a concentration, and fluorescence. S. officinalis yielded higher extract quantities (extraction yield: 23%) than E. arvense and contained bioactive compounds such as thujone, camphor, and cineole, which correlated with its strong anti-algal effects. The essential oil of S. officinalis demonstrated the highest efficacy, significantly inhibiting biofilm formation (zones of inhibition: 15–94 mm) and photosynthetic activity at 0.5% concentration (reduction in chlorophyll a concentration 90–100%), without causing visible discolouration of treated surfaces (∆E < 2). These findings highlight the potential of S. officinalis essential oil as a natural, effective, and material-safe algicidal biocide for the sustainable protection of cultural heritage sites. Full article
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