Search Results (13)

The crystallization of soluble salts is one of the most significant agents of deterioration affecting porous building materials in historical architecture. This process not only compromises the physical integrity of the materials but also results in considerable aesthetic, structural, and economic consequences. Soluble salts involved in these processes may originate from geogenic sources—including soil leachate, marine aerosols, and the natural weathering of parent rocks—or from anthropogenic factors such as air pollution, wastewater infiltration, and the use of incompatible restoration materials. This study examines the role of capillary rise as a primary mechanism responsible for the vertical migration of saline solutions from the soil profile into historic masonry structures, especially those constructed with calcareous stones. It describes how water retained or sustained within the soil matrix ascends via capillarity, carrying dissolved salts that eventually crystallize within the pore network of the stone. This phenomenon leads to a variety of damage types, ranging from superficial staining and efflorescence to more severe forms such as subflorescence, microfracturing, and progressive mass loss. By adopting a multidisciplinary approach that integrates concepts and methods from soil physics, hydrology, petrophysics, and conservation science, this paper examines the mechanisms that govern saline water movement, salt precipitation patterns, and their cumulative effects on stone durability. It highlights the influence of key variables such as soil texture and structure, matric potential, hydraulic conductivity, climatic conditions, and stone porosity on the severity and progression of deterioration. This paper also addresses regional considerations by focusing on the context of Spain, which holds one of the highest concentrations of World Heritage Sites globally and where many monuments are constructed from vulnerable calcareous materials such as fossiliferous calcarenites and marly limestones. Special attention is given to the types of salts most commonly encountered in Spanish soils—particularly chlorides and sulfates—and their thermodynamic behavior under fluctuating environmental conditions. Ultimately, this study underscores the pressing need for integrated, preventive conservation strategies. These include the implementation of drainage systems, capillary barriers, and the use of compatible materials in restoration, as well as the application of non-destructive diagnostic techniques such as electrical resistivity tomography and hyperspectral imaging. Understanding the interplay between soil moisture dynamics, salt crystallization, and material degradation is essential for safeguarding the cultural and structural value of historic buildings in the face of ongoing environmental challenges and climate variability. Full article

Around the world, a large number of stone artifacts have been exposed to air for long periods of time, showing multiple types of deterioration that have attracted widespread attention. Among them, there is an often overlooked deterioration of stone artifacts, i.e., black stains on the surface of the calcareous stone, which are tightly bonded to the substrate as a result of the long-term deposition of air pollution. However, due to the current lack of a clear understanding of the black stains, people often tend to use the wrong cleaning and conservation methods, which is not conducive to sustainable conservation. Therefore, there is an urgent need to comprehensively recognize the black stains in terms of material properties and environmental sustainability to guide scientific sustainable conservation methods. To this end, in this paper, we take the black stains observed on marble buildings in the Xianling Tomb, China, as an example, and for the first time, we aim to create a comprehensive understanding of black deposition from the aspects of material properties and environmental characteristics. Multi-analytical approaches, including polarized light microscopy, X-ray fluorescence (XRF), and scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDS), were employed to discern the differences between the substrate and black stains. The results revealed that the formation of black stains was attributed to prolonged exposure to various air pollutants (PM, SO₂, NO₂, CO, and O₃). Subsequently, observational data from 2015 to 2023 were utilized to investigate the temporal evolution of local air pollutants and their coupled resonances. Multi-scale variations (annual, seasonal, monthly, weekly, and daily) of pollutant concentration sequences were identified, which helps us to have a clearer perception and to proactively control air pollutants in the region from different cycles. In addition, wavelet coherence (WTC) demonstrated significant time-scale dependency in correlation with air pollutants, which provides effective data support for the coordinated control of air pollutants. This study reveals the mechanism of black stain deterioration on stone artifact surfaces, provides data support for the control and prediction of air pollutants oriented to the sustainable conservation of stone artifacts, and provides a novel and comprehensive approach to the scientific knowledge and sustainable conservation of stone artifacts. Full article

The Karnak Temples complex, a monumental site dating back to approximately 1970 BC, faces significant preservation challenges due to a confluence of mechanical, environmental, and anthropogenic factors impacting its stone blocks. This study provides a comprehensive evaluation of the deterioration affecting the northeast corner of the complex, revealing that the primary forms of damage include split cracking and fracturing. Seismic activities have induced out-of-plane displacements, fractures, and chipping, while flooding has worsened structural instability through uplift and prolonged water exposure. Soil liquefaction and fluctuating groundwater levels have exacerbated the misalignment and embedding of stone blocks. Thermal stress and wind erosion have caused microstructural decay and surface degradation and contaminated water sources have led to salt weathering and chemical alterations. Multi-temporal satellite imagery has revealed the influence of vegetation, particularly invasive plant species, on physical and biochemical damage to the stone. This study utilized in situ assessments to document damage patterns and employed satellite imagery to assess environmental impacts, providing a multi-proxy approach to understanding the current state of the stone blocks. This analysis highlights the urgent need for a multi-faceted conservation strategy. Recommendations include constructing elevated platforms from durable materials to reduce soil and water contact, implementing non-invasive cleaning and consolidation techniques, and developing effective water management and contamination prevention measures. Restoration should focus on repairing severely affected blocks with historically accurate materials and establishing an open museum setting will enhance public engagement. Long-term preservation will benefit from regular monitoring using 3D scanning and a preventive conservation schedule. Future research should explore non-destructive testing and interdisciplinary collaboration to refine conservation strategies and ensure the sustained protection of this invaluable historical heritage. Full article

Cultural heritage assets face significant threats from climate change and land subsidence, leading to extensive social, economic, and environmental losses, and damage to artistic and monumental heritage in Italian coastal cities. In particular, addressing these challenges in the Venetian context necessitates the development of an adaptation plan for the lagoon area and the identification of targeted intervention strategies to preserve cultural and territorial heritage. To address these objectives, a systematic study was conducted to investigate the deterioration patterns exhibited by the most representative lithologies used in Venetian buildings. Thirty samples of five carbonate stone varieties subjected to natural aging were monitored in six different areas of Venice’s historic center and on Torcello Island, selected based on altimetry relative to tidal zero and exposure to environmental forces. An integrated multi-analytical approach was employed to identify and map macro- and micro-morphologies of stone surfaces related to chemical weathering and physical decay. Stones underwent evaluation during nine monitoring periods using various tests (ultrasound P-wave velocity and colorimetric measures) and analyses (µX-Ray Fluorescence, X-ray powder diffraction, stereomicroscope observations, and recognition of biological patinas). Data processing aimed to elucidate how microclimate and intrinsic stone features influence the occurrence and progression of deterioration phenomena. From the experimental findings, a Stone Deterioration Index and Intervention Procedures (SDIi) were proposed to estimate deterioration rates and assess the need for targeted intervention through conservative actions. Full article

In Galicia (NW Spain), granite was the most used stone material in historical buildings. Despite the good properties of granite as a construction material, it overcomes several physical and chemical weathering processes that cause decay, resulting in a loss of value in building materials, architectural elements and details. This is caused by a range of processes, from aesthetic damage to stone erosion. The causes of such decay are well known from case studies of historical buildings, being correlated with atmospheric agents, air pollution and aggregate materials, among others. In this work, we studied 15 historical monuments built with granite blocks of the architectural Heritage of the Barbanza Peninsula (Galicia). Because of the geographic features of this area, there is a steep rainfall and sea spray gradient that allows us to study historical buildings exposed to different environmental conditions in a short distance from the shoreline to inland. We used geochemical, petrological and microscopic tools to assess the decay of the granites and compared the results with environmental factors to assess the role of humidity (rainfall) and sea spray on the decay. Both the observation of coatings and the assessment of weathering have shown that buildings close to the shoreline are more affected by sea salts, while buildings far from the coast are mostly affected by biological weathering. Surprisingly, chemical weathering is higher in a strip area some hundreds of meters away from the sea shore and at lower altitudes (between 10 and 30 m). Indeed, very good correlation is observed for weathering indices, such as CIA, MWPI, VR, Si-Ti index, Kr, CAN and AKN, with a distance to the shoreline from 0.5 km, with linear correlation values ranging from −0.91 to 0.80. Full article

Tidal exchange, capillary rise, water condensation-evaporation cycles, and crystallization of salts are the main causes of damage in historic brick buildings in Venice. The present study addressed these issues by proposing a study of twenty-three brick samples collected on the main façade of the Santa Maria dei Servi Church (14th century). The color, mineralogical composition, and texture of these samples were studied using standard methods such as spectrophotometry, X-ray powder diffraction (XRPD), optical microscopy (OM), and field emission scanning electron microscopy (FESEM). The presence of carbonates (calcite and dolomite) and newly formed silicate phases, such as gehlenite and diopside, provided indications of the temperatures reached during firing and suggested the absence of a good standardization in the production process. Meanwhile, XRPD and hyperspectral analysis (HA) detected sulfates (e.g., gypsum and mirabilite) as the main weathering products due to the salt decay process that affects monuments in the Venice lagoon environment. Moreover, secondary phases, such as Mg- and Ca-zeolites, occurred in bricks where the groundmass observed by OM was more vitrificated, and the XRPD patterns displayed the highest amorphous content. On-site mapping of sulfates and chlorophyll by HA was also performed on the main façade of the Church, highlighting the large presence of salts and biodeterioration. Full article

Soluble salts are compounds found inside ornamental rocks and building stones exposed to atmospheric agents in environments rich in alkaline metal ions, such as sodium and potassium. The damage induced by their crystallization in those materials, used to build monuments and architectural structures of great importance, is an unsolved problem. Sodium sulfate is one of the most common and harmful salt found in these constructions. In this work, we studied the resistance through time to the wet-drying cycles of some natural stones (calcarenites, marbles, and sandstones) that have been utilized in the historical architecture in Italy. Samples were freshly cut and thermally aged to simulate increasing decay. Induced porosity in the thermally degraded samples was high in calcarenites, medium in marbles, and low in sandstones. Specimens subjected to artificial thermal aging lost a major percentage of mass compared to the non-weathered ones, when affected by the crystallization of soluble salts. With this study, we have observed that samples subjected to different wetting and drying cycles degrade faster due to the action of soluble salts, compared to samples that are not subjected to these cycles. Full article

The preservation of the Athenian Acropolis monuments constitutes an ongoing top-priority national project of global significance and impact. The project concerning the analytical investigation of the polychromy of the Acropolis monuments presented in this paper was part of the Acropolis Restoration Service (YSMA) program (2011–2015), regarding the restoration of the two corners of the west entablature of the Parthenon, which exhibited severe static damage, and a parallel restoration program of the Propylaea. The scope of this research was to investigate the materials in the paint decoration remains on the monuments by applying, entirely in situ, numerous non-invasive techniques on selected architectural members of the Parthenon and the Propylaea. The research focused, mainly, on surfaces where traces of colour or decoration patterns were visible to the naked eye. Furthermore, surfaces that are referred to in the literature as decorated but that are currently covered with weathering crusts (of white or black colour) and/or layers of patina (of yellowish and orange-brown hue), were also examined. The techniques applied in situ on the Acropolis monuments were X-ray fluorescence, micro-Raman, and Fourier Transform InfraRed (FTIR) spectroscopic techniques, conducted with the use of handheld or portable instruments. The scientific data gathered in situ are discussed in this paper to enhance our knowledge of the architectural polychromy of the classical period. Further investigation by applying analytical techniques on a few selected micro-samples would be highly complementary to this present work. Full article

Identifying species involved in biodeterioration processes is helpful, however further effort is needed to assess their ecological requirements and actual activity. Black fungi (BF) represent one of the most underestimated threats to stone cultural heritage in the Mediterranean basin; they are difficult to kill or remove due to their ability to grow inside the rock and cope with several stresses. Despite this, little is known about BF and factors favoring their growth on stone surfaces. Eighteen BF species were here investigated for temperature and salt tolerance, and metabolic traits by plate assays. The relation between some highly damaged monuments and their BF settlers was assessed using X-ray diffraction analysis, mercury intrusion porosimetry, and SEM. The sensitiveness to four commonly used traditional biocides was also tested. All strains were able to grow within the range of 5–25 °C and in the presence of 3.5% NaCl. Instrumental analyses were fundamental in discovering the relation between halophilic strains and weathered marble sculptures. The acid, cellulase, esterase, and protease production recorded proved BF’s potential to produce a chemical action on carbonate stones and likely affect other materials/historical artefacts. Besides, the use of carboxymethylcellulose and Tween 20 should be evaluated in restoration practice to prevent tertiary bioreceptivity. Agar diffusion tests helped identify the most resistant species to biocides, opening the perspective of its use as reference organisms in material testing procedures. Full article

One of the greatest problems in the field of cultural heritage is the process of material destruction of monuments. In most cases, the cause is operational or random wear. Such processes can be slowed down or eliminated thanks to the maintenance process. The most dangerous processes of monument wear and tear are those in which historical objects are exposed to environmental impact. Cycles of weather changes have a particularly negative impact on objects of this type. These types of objects are significantly damaged and are the most difficult to scan. The research work included the scanning of such an object and attempts were made to digitise the point cloud. The monument selected for the model laser scanning was a rock petroglyph located on the slope of the Chatkal mountain near the town of Tashkent in Uzbekistan. The article describes the process of digitally recording a historic object with the use of the Artec Eva scanner. The process of data acquisition from points in space and the processes of highlighting petroglyphs are described. The highlighted model was obtained using proprietary software created for this purpose by the authors of the article. As a result, data were saved which would be difficult to save and read using the previously used 3D scanning techniques. The obtained data can be made available to recipients in the form of exhibits in virtual museums. Full article

Stony monuments must continuously be safeguarded from damage caused over time, in particular from the detrimental effects of weathering. One of the new environmentally-friendly (nano) materials for stone reinforcement, particularly suitable for marble and calcareous (limestone, sandstone) artifacts, is Ca₁₀(PO₄)₆(OH)₂ hydroxyapatite (HAp), which has a considerably lower dissolution rate and solubility compared to CaCO₃ calcite (the building block of marble materials): thus, HAp has been proposed for the protection of calcareous monuments against acidic rain corrosion. Promising results have been obtained, but further optimization is necessary as the treated layer is often incomplete, cracked and/or porous. Several parameters need to be optimized, in this way a homogeneous layer can be obtained, and consequently the formation of metastable can be avoided, soluble phases instead of HAp. These include: the pH of the starting solution; the effect of organic and inorganic additions in particular, that of ethanol, which is known to adsorb calcite, thus possibly favoring the growth of the HAp layer. The formation of HAp nanoparticles and their application on stony substrates has been investigated by means of a multi-methodological approach based on scanning electron microscopy, x-ray diffraction, small- and/or wide-angle x-ray scattering, Fourier-transform infrared spectroscopy, and finally, in situ measurements of laser-induced breakdown spectroscopy and acid attack preliminary tests on stony substrates. Full article

The aim of this paper is to analyze the construction materials (mortars) of an architectural monument (Deserted Tower (Lilly Tower) from Corvins’ Castle, Romania). The mortars were characterized following a multidisciplinary approach, combining macroscopic observation with petrographic microscopy, mineralogical analysis (X-ray diffraction) and elemental analysis (X-ray fluorescence), hydric properties, and color of representative samples of the monument. The results revealed the use of gypsum mortars (produced by lumps with higher Fe content), with minor concentrations of crystalline dolomites of the Southern Carpathians, calcite, and quartz. The materials’ effective porosity and their water absorption capacity were high. A possible solution to consolidate the damaged area with some consolidation products (hydroxyapatite carbonate and its derivatives with Ag and Sr) was investigated, too. The interactions between the mortar’s specimens and the effectiveness of the consolidation treatments were evaluated by physico-chemical analyses (molecular structure by X-ray powder diffraction (XRPD), wavelength dispersive X-ray fluorescence (WDXRF), dynamic light scattering (DLS)), morphological characterization by microscopic techniques as SEM-EDS, TEM, and physical and mechanical investigations (peeling test and compressive strength). Results were drawn based on historical, in situ observations, and analytical data, and put into evidence the composition, high weathering degree, and the possibility to surface consolidate with Sr-CHAp. Full article

The colonization of stone-built monuments by different organisms (algae, fungi, lichens, bacteria, and cyanobacteria) can lead to biodeterioration of the stone, negatively affecting the artistic value of the heritage. To address this issue, laser cleaning has been widely investigated in recent years, due to the advantages it offers over traditional mechanical and chemical methods: it is gradual, selective, contactless, and environmentally friendly. That said, the laser parameters should be optimized in order to avoid any by-effects on the surface as a result of overcleaning. However, as the adjustment of each parameter to clean polymineralic stones is a difficult task, it would be useful to know the effect of overcleaning on the different forming minerals depending on the wavelength used. In this paper, three different wavelengths (355 nm, 532 nm, and 1064 nm) of a Q-Switch neodymium-doped yttrium aluminum garnet (Nd:Y₃Al₅O₁₂) laser, commonly known as QS Nd:YAG laser were applied to extract a naturally developed sub-aerial biofilm from Vilachán granite, commonly used in monuments in the Northwest (NW)Iberian Peninsula. In addition to the removal rate of the biofilm, the by-effects induced for fluences higher than the damage threshold of the stone were evaluated using stereomicroscopy, color spectrophotometry, and scanning electron microscopy with energy-dispersive x-ray spectroscopy. The results showed that different removal rates were obtained depending on the wavelength used and 532 nm obtained the highest removal level. In terms of by-effects, biotite melting was registered on all surfaces regardless of the wavelength. In addition, 532 nm seemed to be the most aggressive laser system, inducing the greatest change in appearance as a result of extracting the kaolinite crackled coating and the segregations rich in Fe, which are a result of natural weathering. These changes were translated into colorimetric changes visible to the human eye. The surfaces treated with 355 nm and 1064 nm showed lower surface changes. Full article