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Keywords = modulus of deformation

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21 pages, 4359 KiB  
Article
Continuously Formed Fiber-Reinforced Thermoplastic Composite Rebar for Concrete Reinforcement
by Jacob C. Clark, William G. Davids, Roberto A. Lopez-Anido, Andrew P. Schanck and Cody A. Sheltra
J. Compos. Sci. 2025, 9(7), 378; https://doi.org/10.3390/jcs9070378 - 18 Jul 2025
Abstract
Despite the strength and ductility of steel reinforcing bars, their susceptibility to corrosion can limit the long-term durability of reinforced concrete structures. Fiber-reinforced polymer (FRP) reinforcing bars made with a thermosetting matrix offer corrosion resistance but cannot be field-bent, which limits flexibility during [...] Read more.
Despite the strength and ductility of steel reinforcing bars, their susceptibility to corrosion can limit the long-term durability of reinforced concrete structures. Fiber-reinforced polymer (FRP) reinforcing bars made with a thermosetting matrix offer corrosion resistance but cannot be field-bent, which limits flexibility during construction. FRP reinforcing bars made with fiber-reinforced thermoplastic polymers (FRTP) address this limitation; however, their high processing viscosity presents manufacturing challenges. In this study, the Continuous Forming Machine, a novel pultrusion device that uses pre-consolidated fiber-reinforced thermoplastic tapes as feedstock, is described and used to fabricate 12.7 mm nominal diameter thermoplastic composite rebars. Simple bend tests on FRTP rebar that rely on basic equipment are performed to verify its ability to be field-formed. The manual bending technique demonstrated here is practical and straightforward, although it does result in some fiber misalignment. Subsequently, surface deformations are introduced to the rebar to promote mechanical bonding with concrete, and tensile tests of the bars are conducted to determine their mechanical properties. Finally, flexural tests of simply-supported, 6 meter long beams reinforced with FRTP rebar are performed to assess their strength and stiffness as well as the practicality of using FRTP rebar. The beam tests demonstrated the prototype FRTP rebar’s potential for reinforcing concrete beams, and the beam load–deformation response and capacity agree well with predictions developed using conventional structural analysis principles. Overall, the results of the research reported indicate that thermoplastic rebars manufactured via the Continuous Forming Machine are a promising alternative to both steel and conventional thermoset composite rebar. However, both the beam and tension test results indicate that improvements in material properties, especially elastic modulus, are necessary to meet the requirements of current FRP rebar specifications. Full article
(This article belongs to the Section Fiber Composites)
12 pages, 2262 KiB  
Article
Long-Term Creep Mechanical and Acoustic Emission Characteristics of Water-Immersed Coal Pillar Dam
by Ersheng Zha, Mingbo Chi, Zhiguo Cao, Baoyang Wu, Jianjun Hu and Yan Zhu
Appl. Sci. 2025, 15(14), 8012; https://doi.org/10.3390/app15148012 - 18 Jul 2025
Abstract
This study conducted uniaxial creep tests on coal samples under both natural and water-saturated conditions for durations of about 180 days per sample to study the stability of coal pillar dams of the Daliuta Coal Mine underground reservoir. Combined with synchronized acoustic emission [...] Read more.
This study conducted uniaxial creep tests on coal samples under both natural and water-saturated conditions for durations of about 180 days per sample to study the stability of coal pillar dams of the Daliuta Coal Mine underground reservoir. Combined with synchronized acoustic emission (AE) monitoring, the research systematically revealed the time-dependent deformation mechanisms and damage evolution laws of coal under prolonged water immersion and natural conditions. The results indicate that water-immersed coal exhibits a unique negative creep phenomenon at the initial stage, with the strain rate down to −0.00086%/d, attributed to non-uniform pore compaction and elastic rebound effects. During the steady-state creep phase, the creep rates under water-immersed and natural conditions were comparable. However, water immersion led to an 11.4% attenuation in elastic modulus, decreasing from 2300 MPa to 2037 MPa. Water immersion would also suppress AE activity, leading to the average daily AE events of 128, which is only 25% of that under natural conditions. In the accelerating creep stage, the AE event rate surged abruptly, validating its potential as an early warning indicator for coal pillar instability. Based on the identified long-term strength of the coal sample, it is recommended to maintain operational loads below the threshold of 9 MPa. This research provides crucial theoretical foundations and experimental data for optimizing the design and safety monitoring of coal pillar dams in CMURs. Full article
(This article belongs to the Section Civil Engineering)
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28 pages, 5072 KiB  
Article
Study on the Mechanical Properties of Optimal Water-Containing Basalt Fiber-Reinforced Concrete Under Triaxial Stress Conditions
by Kaide Liu, Songxin Zhao, Yaru Guo, Wenping Yue, Chaowei Sun, Yu Xia, Qiyu Wang and Xinping Wang
Materials 2025, 18(14), 3358; https://doi.org/10.3390/ma18143358 - 17 Jul 2025
Abstract
In response to the high-performance requirements of concrete materials under complex triaxial stress states and water-containing environments in marine engineering, this study focuses on water-containing basalt fiber-reinforced concrete (BFRC). Uniaxial compression and splitting tensile tests were conducted on specimens with different fiber contents [...] Read more.
In response to the high-performance requirements of concrete materials under complex triaxial stress states and water-containing environments in marine engineering, this study focuses on water-containing basalt fiber-reinforced concrete (BFRC). Uniaxial compression and splitting tensile tests were conducted on specimens with different fiber contents (0.0%, 0.05%, 0.10%, 0.15%, and 0.20%) to determine the optimal fiber content of 0.1%. The compressive strength of the concrete with this fiber content increased by 13.5% compared to the control group without fiber, reaching 36.90 MPa, while the tensile strength increased by 15.9%, reaching 2.33 MPa. Subsequently, NMR and SEM techniques were employed to analyze the internal pore structure and micro-morphology of BFRC. It was found that an appropriate amount of basalt fiber (content of 0.1%) can optimize the pore structure and form a reticular three-dimensional structure. The pore grading was also improved, with the total porosity decreasing from 7.48% to 7.43%, the proportion of harmless pores increasing from 4.03% to 4.87%, and the proportion of harmful pores decreasing from 1.67% to 1.42%, thereby significantly enhancing the strength of the concrete. Further triaxial compression tests were conducted to investigate the mechanical properties of BFRC under different confining pressures (0, 3, and 6 MPa) and water contents (0%, 1%, 2%, and 4.16%). The results showed that the stress–strain curves primarily underwent four stages: initial crack compaction, elastic deformation, yielding, and failure. In terms of mechanical properties, when the confining pressure increased from 0 MPa to 6 MPa, taking dry sandstone as an example, the peak stress increased by 54.0%, the elastic modulus increased by 15.7%, the peak strain increased by 37.0%, and the peak volumetric strain increased by 80.0%. In contrast, when the water content increased from 0% to 4.16%, taking a confining pressure of 0 MPa as an example, the peak stress decreased by 27.4%, the elastic modulus decreased by 43.2%, the peak strain decreased by 59.3%, and the peak volumetric strain decreased by 106.7%. Regarding failure characteristics, the failure mode shifted from longitudinal splitting under no confining pressure to diagonal shear under confining pressure. Moreover, as the confining pressure increased, the degree of failure became more severe, with more extensive cracks. However, when the water content increased, the failure degree was relatively mild, but it gradually worsened with further increases in water content. Based on the CDP model, a numerical model for simulating the triaxial compression behavior of BFRC was developed. The simulation results exhibited strong consistency with the experimental data, thereby validating the accuracy and applicability of the model. Full article
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17 pages, 3443 KiB  
Article
Influence of Dissipated Energy on the Bonding Strength of Cold-Sprayed Titanium Coatings on Selected Metallic Substrates
by Medard Makrenek
Materials 2025, 18(14), 3355; https://doi.org/10.3390/ma18143355 - 17 Jul 2025
Abstract
Modern nanoindentation equipment allows for highly precise measurements of mechanical properties such as hardness and elastic modulus, generating detailed load–unload curves using advanced techniques and specialised software. In this study, titanium coatings were deposited on various metallic substrates using cold gas spraying. Before [...] Read more.
Modern nanoindentation equipment allows for highly precise measurements of mechanical properties such as hardness and elastic modulus, generating detailed load–unload curves using advanced techniques and specialised software. In this study, titanium coatings were deposited on various metallic substrates using cold gas spraying. Before deposition, the spraying parameters (temperature, pressure, velocity, and distance) were statistically optimised using the Taguchi method, reducing the number of experiments required from 81 to 9. This approach allowed the identification of optimal spray conditions (T = 731.0 °C, p = 33.0 bar, V = 343.6 mm/s, d = 35.5 mm), which were then applied to substrates including brass, steel, titanium, Al7075, copper, magnesium, and Al2024. Mechanical characterisation included hardness (H), reduced modulus (E), coating adhesion, and dissipated energy, calculated from the area of the load–unload hysteresis loop. Each coating–substrate combination underwent 36 nanoindentation tests, and adhesion was evaluated by pull-off tests. The initial results showed a poor correlation between adhesion and conventional mechanical properties (χ2 of 17.1 for hardness and 16.2 for modulus, both with R2 < 0.24). In contrast, the dissipated energy showed an excellent correlation with adhesion (χ2 = 0.52, R2 = 0.92), suggesting that dynamic deformation mechanisms better describe bonding. This introduces a new perspective to predict and optimise cold-spray adhesion in industrial applications. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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17 pages, 7633 KiB  
Article
Mechanical Behavior Characteristics of Sandstone and Constitutive Models of Energy Damage Under Different Strain Rates
by Wuyan Xu and Cun Zhang
Appl. Sci. 2025, 15(14), 7954; https://doi.org/10.3390/app15147954 - 17 Jul 2025
Abstract
To explore the influence of mine roof on the damage and failure of sandstone surrounding rock under different pressure rates, mechanical experiments with different strain rates were carried out on sandstone rock samples. The strength, deformation, failure, energy and damage characteristics of rock [...] Read more.
To explore the influence of mine roof on the damage and failure of sandstone surrounding rock under different pressure rates, mechanical experiments with different strain rates were carried out on sandstone rock samples. The strength, deformation, failure, energy and damage characteristics of rock samples with different strain rates were also discussed. The research results show that with the increases in the strain rate, peak stress, and elastic modulus show a monotonically increasing trend, while the peak strain decreases in the reverse direction. At a low strain rate, the proportion of the mass fraction of complete rock blocks in the rock sample is relatively high, and the shape integrity is good, while rock samples with a high strain rate retain more small-sized fragmented rock blocks. This indicates that under high-rate loading, the bifurcation phenomenon of secondary cracks is obvious. The rock samples undergo a failure form dominated by small-sized fragments, with severe damage to the rock samples and significant fractal characteristics of the fragments. At the initial stage of loading, the primary fractures close, and the rock samples mainly dissipate energy in the forms of frictional slip and mineral fragmentation. In the middle stage of loading, the residual fractures are compacted, and the dissipative strain energy keeps increasing continuously. In the later stage of loading, secondary cracks accelerate their expansion, and elastic strain energy is released sharply, eventually leading to brittle failure of the rock sample. Under a low strain rate, secondary cracks slowly expand along the clay–quartz interface and cause intergranular failure of the rock sample. However, a high strain rate inhibits the stress relaxation of the clay, forces the energy to transfer to the quartz crystal, promotes the penetration of secondary cracks through the quartz crystal, and triggers transgranular failure. A constitutive model based on energy damage was further constructed, which can accurately characterize the nonlinear hardening characteristics and strength-deformation laws of rock samples with different strain rates. The evolution process of its energy damage can be divided into the unchanged stage, the slow growth stage, and the accelerated growth stage. The characteristics of this stage reveal the sudden change mechanism from the dissipation of elastic strain energy of rock samples to the unstable propagation of secondary cracks, clarify the cumulative influence of strain rate on damage, and provide a theoretical basis for the dynamic assessment of surrounding rock damage and disaster early warning when the mine roof comes under pressure. Full article
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15 pages, 3833 KiB  
Article
High-Temperature Tribological Behavior of Polyimide Composites with Dual-Phase MoS2/MXene Lubricants: A Synergistic Effect Analysis
by Xingtian Ji, Pengwei Ren, Hao Liu, Yanhua Shi, Yunfeng Yan and Jianzhang Wang
J. Compos. Sci. 2025, 9(7), 373; https://doi.org/10.3390/jcs9070373 - 17 Jul 2025
Abstract
Polyimide (PI), owing to its high heat resistance and low density, is often employed as a substitute for metallic materials in high-temperature environments, such as aircraft engines, bearings, and gears. However, the relatively high friction coefficient of pure PI limits its application under [...] Read more.
Polyimide (PI), owing to its high heat resistance and low density, is often employed as a substitute for metallic materials in high-temperature environments, such as aircraft engines, bearings, and gears. However, the relatively high friction coefficient of pure PI limits its application under harsh conditions. Therefore, this study synthesized a composite lubricant with binary fillers to improve this performance. This study employed the hydrothermal method to synthesize MoS2/MXene composite lubricating fillers and systematically investigated the high-temperature tribological properties of PI composites reinforced with these fillers. The results demonstrated that the optimal PI composite containing 5% MoS2/MXene exhibited a 14 °C increase in initial decomposition temperature compared to pure PI. Additionally, its thermal conductivity was enhanced by 36%, while the hardness (0.398 GPa) and elastic modulus (6.294 GPa) were elevated by 12.4% and 18.6%, respectively, relative to the pure PI. In terms of tribological behavior, all composite formulations displayed typical temperature-dependent friction characteristics. It is worth noting that MXene’s high hardness and thermal conductivity inhibited the occurrence of abrasive wear. At the same time, the substrate was strengthened, and thermal resistance was enhanced, thereby delaying the plastic deformation of the material at high temperatures. Full article
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22 pages, 3791 KiB  
Article
Voxel Interpolation of Geotechnical Properties and Soil Classification Based on Empirical Bayesian Kriging and Best-Fit Convergence Function
by Yelbek Utepov, Aliya Aldungarova, Assel Mukhamejanova, Talal Awwad, Sabit Karaulov and Indira Makasheva
Buildings 2025, 15(14), 2452; https://doi.org/10.3390/buildings15142452 - 12 Jul 2025
Viewed by 182
Abstract
To support bearing capacity estimates, this study develops and tests a geoprocessing workflow for predicting soil properties using Empirical Bayesian Kriging 3D and a classification function. The model covers a 183 m × 185 m × 24 m site in Astana (Kazakhstan), based [...] Read more.
To support bearing capacity estimates, this study develops and tests a geoprocessing workflow for predicting soil properties using Empirical Bayesian Kriging 3D and a classification function. The model covers a 183 m × 185 m × 24 m site in Astana (Kazakhstan), based on 16 boreholes (15–24 m deep) and 77 samples. Eight geotechnical properties were mapped in 3D voxel models (812,520 voxels at 1 m × 1 m × 1 m resolution): cohesion (c), friction angle (φ), deformation modulus (E), plasticity index (PI), liquidity index (LI), porosity (e), particle size (PS), and particle size distribution (PSD). Stratification patterns were revealed with ~35% variability. Maximum φ (34.9°), E (36.6 MPa), and PS (1.29 mm) occurred at 8–16 m; c (33.1 kPa) and PSD peaked below 16 m, while PI and e were elevated in the upper and lower strata. Strong correlations emerged in pairs φ-E-PS (0.91) and PI-e (0.95). Classification identified 10 soil types, including one absent in borehole data, indicating the workflow’s capacity to detect hidden lithologies. Predicted fractions of loams (51.99%), sandy loams (22.24%), and sands (25.77%) matched borehole data (52%, 26%, 22%). Adjacency analysis of 2,394,873 voxel pairs showed homogeneous zones in gravel–sandy soils (28%) and stiff loams (21.75%). The workflow accounts for lateral and vertical heterogeneity, reduces subjectivity, and is recommended for digital subsurface 3D mapping and construction design optimization. Full article
(This article belongs to the Section Building Structures)
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29 pages, 2673 KiB  
Article
Process Parameters Optimization and Mechanical Properties of Additively Manufactured Ankle–Foot Orthoses Based on Polypropylene
by Sahar Swesi, Mohamed Yousfi, Nicolas Tardif and Abder Banoune
Polymers 2025, 17(14), 1921; https://doi.org/10.3390/polym17141921 - 11 Jul 2025
Viewed by 293
Abstract
Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent [...] Read more.
Nowadays, Fused Filament Fabrication (FFF) 3D printing offers promising opportunities for the customized manufacturing of ankle–foot orthoses (AFOs) targeted towards rehabilitation purposes. Polypropylene (PP) represents an ideal candidate in orthotic applications due to its light weight and superior mechanical properties, offering an excellent balance between flexibility, chemical resistance, biocompatibility, and long-term durability. However, Additive Manufacturing (AM) of AFOs based on PP remains a major challenge due to its limited bed adhesion and high shrinkage, especially for making large parts such as AFOs. The primary innovation of the present study lies in the optimization of FFF 3D printing parameters for the fabrication of functional, patient-specific orthoses using PP, a material still underutilized in the AM of medical devices. Firstly, a thorough thermomechanical characterization was conducted, allowing the implementation of a (thermo-)elastic material model for the used PP filament. Thereafter, a Taguchi design of experiments (DOE) was established to study the influence of several printing parameters (extrusion temperature, printing speed, layer thickness, infill density, infill pattern, and part orientation) on the mechanical properties of 3D-printed specimens. Three-point bending tests were conducted to evaluate the strength and stiffness of the samples, while additional tensile tests were performed on the 3D-printed orthoses using a home-made innovative device to validate the optimal configurations. The results showed that the maximum flexural modulus of 3D-printed specimens was achieved when the printing speed was around 50 mm/s. The most significant parameter for mechanical performance and reduction in printing time was shown to be infill density, contributing 73.2% to maximum stress and 75.2% to Interlaminar Shear Strength (ILSS). Finally, the applicability of the finite element method (FEM) to simulate the FFF process-induced deflections, part distortion (warpage), and residual stresses in 3D-printed orthoses was investigated using a numerical simulation tool (Digimat-AM®). The combination of Taguchi DOE with Digimat-AM for polypropylene AFOs highlighted that the 90° orientation appeared to be the most suitable configuration, as it minimizes deformation and von Mises stress, ensuring improved quality and robustness of the printed orthoses. The findings from this study contribute by providing a reliable method for printing PP parts with improved mechanical performance, thereby opening new opportunities for its use in medical-grade additive manufacturing. Full article
(This article belongs to the Special Issue Latest Progress in the Additive Manufacturing of Polymeric Materials)
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32 pages, 11521 KiB  
Article
Ultimate Capacity of a GFRP-Reinforced Concrete Bridge Barrier–Deck Anchorage Subjected to Transverse Loading
by Gledis Dervishhasani, Khaled Sennah, Hamdy M. Afefy and Ahmed Diab
Appl. Sci. 2025, 15(14), 7771; https://doi.org/10.3390/app15147771 - 10 Jul 2025
Viewed by 272
Abstract
This paper outlines a structural qualification process to assess the use of newly developed high-modulus (HM) glass fiber-reinforced polymer (GFRP) bars with headed ends in the joint between concrete bridge barriers and decks. The main goals of the study are to evaluate the [...] Read more.
This paper outlines a structural qualification process to assess the use of newly developed high-modulus (HM) glass fiber-reinforced polymer (GFRP) bars with headed ends in the joint between concrete bridge barriers and decks. The main goals of the study are to evaluate the structural performance of GFRP-reinforced TL-5 barrier–deck systems under transverse loading and to determine the pullout capacity of GFRP anchorage systems for both new construction and retrofit applications. The research is divided into two phases. In the first phase, six full-scale Test-Level 5 (TL-5) barrier wall–deck specimens, divided into three systems, were constructed and tested up to failure. The first system used headed-end GFRP bars to connect the barrier wall to a non-deformable thick deck slab. The second system was similar to the first but had a deck slab overhang for improved anchorage. The third system utilized postinstalled GFRP bars in a non-deformable thick deck slab, bonded with a commercial epoxy adhesive as a solution for deteriorated barrier replacement. The second phase involves an experimental program to evaluate the pullout strength of the GFRP bar anchorage in normal-strength concrete. The experimental results from the tested specimens were then compared to the factored applied moments in existing literature based on traffic loads in the Canadian Highway Bridge Design Code. Experimental results confirmed that GFRP-reinforced TL-5 barrier–deck systems exceeded factored design moments, with capacity-to-demand ratios above 1.38 (above 1.17 with the inclusion of an environmental reduction factor of 0.85). A 195 mm embedment length proved sufficient for both pre- and postinstalled bars. Headed-end GFRP bars improved pullout strength compared to straight-end bars, especially when bonded. Failure modes occurred at high loads, demonstrating structural integrity. Postinstalled bars bonded with epoxy performed comparably to preinstalled bars. A design equation for the barrier resistance due to a diagonal concrete crack at the barrier–deck corner was developed and validated using experimental findings. This equation offers a conservative and safe design approach for evaluating barrier–deck anchorage. Full article
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23 pages, 3933 KiB  
Article
Evaluations on the Properties of Polymer and Nanomaterials Modified Bitumen Under Different Aging Conditions
by Shaban Ismael Albrka Ali, Khalifa Salem Gallouz, Ikenna D. Uwanuakwa, Mustafa Alas and Mohd Rosli Mohd Hasan
Nanomaterials 2025, 15(14), 1071; https://doi.org/10.3390/nano15141071 - 10 Jul 2025
Viewed by 203
Abstract
This research evaluates the rheological and mechanical properties of polymer- and nanomaterials-modified bitumen by incorporating nanosilica (NSA), nanoclay (NCY), and Acrylonitrile Styrene Acrylate (ASA) at 5% by weight of the bitumen. The samples were prepared at 165 °C for one hour to obtain [...] Read more.
This research evaluates the rheological and mechanical properties of polymer- and nanomaterials-modified bitumen by incorporating nanosilica (NSA), nanoclay (NCY), and Acrylonitrile Styrene Acrylate (ASA) at 5% by weight of the bitumen. The samples were prepared at 165 °C for one hour to obtain homogeneous blends. All samples were subjected to short- and long-term aging to simulate the effects of different operating conditions. The research conducted a series of tests, including consistency, frequency sweep, and multiple creep stress and recovery (MSCR) using the dynamic shear rheometer (DSR) and bending beam rheometer (BBR). The results showed that all modified bitumen outperformed the neat bitumen. The frequency sweep showed a higher complex modulus (G*) and lower phase angle (δ), indicating enhanced viscoelastic properties and, thus, higher resistance to permanent deformation. The BBR test revealed that the bitumen modified with NCY5% has a creep stiffness of 47.13 MPa, a 51.5% improvement compared to the neat bitumen, while the NSA5% has the highest m-value, a 28.5% enhancement compared with the neat bitumen. The MSCR showed that the modified blends have better recovery properties and, therefore, better resistance to permanent deformation under repeated loadings. The aging index demonstrated that the modified bitumen is less vulnerable to aging and maintains their good flexibility and resistance to permanent deformations. Finally, these results showed that adding 5% polymer and nanomaterials improved the bitumen’s’ performance before and after aging by reducing permanent deformation and enhancing crack resistance at low temperatures, thus extending the pavement service life and making them an effective alternative for improving pavement performance in various climatic conditions and under high traffic loads. Full article
(This article belongs to the Section Nanocomposite Materials)
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20 pages, 1816 KiB  
Review
Recent Achievements of Epicardial Patch Electronics Using Adhesive and Conductive Hydrogels
by Su Hyeon Lee, Jong Won Lee, Daehyeon Kim, Gi Doo Cha and Sung-Hyuk Sunwoo
Gels 2025, 11(7), 530; https://doi.org/10.3390/gels11070530 - 9 Jul 2025
Viewed by 278
Abstract
Implantable cardiac devices are critical in improving patients’ quality of life through precise and continuous interaction between the device and pathological cardiac tissue. Due to the inherently rigid nature of conventional devices, several complications arise when interacting with soft cardiac tissue, caused by [...] Read more.
Implantable cardiac devices are critical in improving patients’ quality of life through precise and continuous interaction between the device and pathological cardiac tissue. Due to the inherently rigid nature of conventional devices, several complications arise when interacting with soft cardiac tissue, caused by a mechanical mismatch between the device and myocardium. This leads to the excessive formation of fibrous tissue around the implanted device, ultimately compromising both device functionality and tissue health. To address these challenges, flexible electronics based on polymers and elastomers significantly softer than conventional rigid metals and silicon have been explored. The epicardial approach enables the device to conform to the curved myocardial surface and deform synchronously with cardiac motion, thereby improving mechanical compatibility. However, modulus mismatches between soft polymers and cardiac tissue can still lead to mechanical instability and non-uniform adhesion, potentially affecting long-term performance. This review comprehensively summarizes recent research advancements in epicardial patch electronics based on bioadhesive and conductive hydrogels. We emphasize current research directions, highlighting the potential of hydrogels in epicardial electronics applications. Critical discussion includes recent trends, ongoing challenges, and emerging strategies aimed at improving the properties of hydrogel-based epicardial patches. Future research directions to facilitate clinical translation are also outlined. Full article
(This article belongs to the Special Issue Novel Gels for Biomedical Applications)
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20 pages, 3181 KiB  
Article
Mechanical Properties Regulation of Invar36 Alloy Metastructures Manufactured by Laser Powder Bed Fusion
by Jianyu Feng, Jialei Yan, Xiaoqiang Peng, Gening He and Ke Huang
Metals 2025, 15(7), 773; https://doi.org/10.3390/met15070773 - 8 Jul 2025
Viewed by 223
Abstract
Invar36 alloy, renowned for its exceptionally low coefficient of thermal expansion and excellent mechanical properties, is widely used in precision instruments, high-accuracy molds, and related fields. Metastructures fabricated via laser powder bed fusion (LPBF) have significantly broadened the application scope of Invar36 alloy, [...] Read more.
Invar36 alloy, renowned for its exceptionally low coefficient of thermal expansion and excellent mechanical properties, is widely used in precision instruments, high-accuracy molds, and related fields. Metastructures fabricated via laser powder bed fusion (LPBF) have significantly broadened the application scope of Invar36 alloy, owing to their unique advantages such as lightweight design, high specific strength, and high specific stiffness. However, the structure–property coupling relationship in Invar-based metallic lattice structures remains insufficiently understood, which poses a major obstacle to their further engineering utilization. In this study, 36 lattice structures with varying design parameters were fabricated and experimentally evaluated. The design variables included lattice architecture (body-centered cubic (BCC), diamond (DIA), face-centered cubic (FCC), and octet (OCT)), strut diameter (0.6 mm, 0.8 mm, and 1.0 mm), and inclination angle (35°, 45°, and 55°). The influence of these structural parameters on the mechanical performance was systematically investigated. The results indicate that lattice architecture has a significant impact on mechanical properties, with the OCT structure, characterized by stretch-dominated behavior, exhibiting the best overall performance. Under the conditions of a 35° inclination angle and a strut diameter of 1.0 mm, the elastic modulus, compressive strength, plateau stress, and energy absorption of the OCT structure reaches 2525.92 MPa, 110.65 MPa, 162.26 MPa, and 78.22 mJ/mm3, respectively. Furthermore, increasing the strut diameter substantially improves mechanical performance, while variations in inclination angle primarily influence the dominant deformation mode. These findings demonstrate that the mechanical properties of Invar36 alloy lattice structures fabricated via LPBF can be effectively tuned over a broad range, offering both theoretical insights and practical guidance for customized performance optimization. Full article
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22 pages, 4455 KiB  
Article
Assessing Engineering Behavior of Fly Ash-Based Geopolymer Concrete: Empirical Modeling
by Ahmad B. Malkawi
Infrastructures 2025, 10(7), 168; https://doi.org/10.3390/infrastructures10070168 - 1 Jul 2025
Viewed by 335
Abstract
The present work investigates the characteristics of fly ash-based geopolymer concrete (GPC) in terms of compressive, splitting, and flexural strength, elasticity modulus, and stress–strain relationship. Datasets including 726 observations were collected from the sorted literature, and regression models were proposed. These models were [...] Read more.
The present work investigates the characteristics of fly ash-based geopolymer concrete (GPC) in terms of compressive, splitting, and flexural strength, elasticity modulus, and stress–strain relationship. Datasets including 726 observations were collected from the sorted literature, and regression models were proposed. These models were then validated using experimental results obtained from 12 different mixtures prepared and tested in this research. Finally, the models were compared with the current models of several codes for ordinary Portland cement (OPC) concrete. The proposed models provided good accuracy with a determination coefficient greater than 60% for all models; such a value is considered large enough for big datasets. The behavior of GPC is not well-represented by OPC concrete standards, and GPC also displays a lower elastic modulus at similar strength. A constitutive model is proposed to describe GPC’s full stress–strain response, with the resulting equations providing relatively accurate predictions of its mechanical behavior. Compared to OPC concrete, GPC shows notably greater deformation, characterized by a wider range and higher average for both strain at peak stress (mean 0.00296) and ultimate strain (mean 0.01002). This work’s results may prompt further detailed research on GPC’s mechanical and, importantly, structural behavior. Full article
(This article belongs to the Section Infrastructures Materials and Constructions)
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18 pages, 5009 KiB  
Article
Preparation of Glass Fiber Reinforced Polypropylene Bending Plate and Its Long-Term Performance Exposed in Alkaline Solution Environment
by Zhan Peng, Anji Wang, Chen Wang and Chenggao Li
Polymers 2025, 17(13), 1844; https://doi.org/10.3390/polym17131844 - 30 Jun 2025
Viewed by 244
Abstract
Glass fiber reinforced polypropylene composite plates have gradually attracted more attention because of their repeated molding, higher toughness, higher durability, and fatigue resistance compared to glass fiber reinforced thermosetting composites. In practical engineering applications, composite plates have to undergo bending effect at different [...] Read more.
Glass fiber reinforced polypropylene composite plates have gradually attracted more attention because of their repeated molding, higher toughness, higher durability, and fatigue resistance compared to glass fiber reinforced thermosetting composites. In practical engineering applications, composite plates have to undergo bending effect at different angles in corrosive environment of concrete, including bending bars from 0~90°, and stirrups of 90°, which may lead to long-term performance degradation. Therefore, it is important to evaluate the long-term performance of glass fiber reinforced polypropylene composite bending plates in an alkali environment. In the current paper, a new bending device is developed to prepare glass fiber reinforced polypropylene bending plates with the bending angles of 60° and 90°. It should be pointed out that the above two bending angles are simulated typical bending bars and stirrups, respectively. The plate is immersed in the alkali solution environment for up to 90 days for long-term exposure. Mechanical properties (tensile properties and shear properties), thermal properties (dynamic mechanical properties and thermogravimetric analysis) and micro-morphology analysis (surface morphology analysis) were systematically designed to evaluate the influence mechanism of bending angle and alkali solution immersion on the long-term mechanical properties. The results show the bending effect leads to the continuous failure of fibers, and the outer fibers break under tension, and the inner fibers buckle under compression, resulting in debonding of the fiber–matrix interface. Alkali solution (OH ions) corrode the surface of glass fiber to form soluble silicate, which is proved by the mass fraction of glass fiber decreased obviously from 79.9% to 73.65% from thermogravimetric analysis. This contributes to the highest degradation ratio of tensile strength was 71.6% (60° bending) and 65.6% (90° bending), respectively, compared to the plate with bending angles of 0°. A high curvature bending angle (such as 90°) leads to local buckling of fibers and plastic deformation of the matrix, forming microcracks and fiber–resin interface bonding at the bending area, which accelerates the chemical erosion and debonding process in the interface area, bringing about an additional maximum 10.56% degradation rate of the shear strength. In addition, the alkali immersion leads to the obvious degradation of storage modulus and thermal decomposition temperature of composite plate. Compared with the other works on the long-term mechanical properties of glass fiber reinforced polypropylene, it can be found that the long-term performance of glass fiber reinforced polypropylene composites is controlled by the corrosive media type, bending angle and immersion time. The research results will provide durability data for glass fiber reinforced polypropylene composites used in concrete as stirrups. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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27 pages, 3625 KiB  
Article
Effect of Synthetic Wax on the Rheological Properties of Polymer-Modified Bitumen
by Marek Iwański, Małgorzata Cholewińska and Grzegorz Mazurek
Materials 2025, 18(13), 3067; https://doi.org/10.3390/ma18133067 - 27 Jun 2025
Viewed by 297
Abstract
The goal of this study is to evaluate how the inclusion of synthetic wax, added in 0.5% increments from 1.5% to 3.5%, affects the characteristics of PMB 45/80-65 (polymer-modified bitumen) during both short-term (RTFOT) and long-term (PAV) aging processes. Tests were carried out [...] Read more.
The goal of this study is to evaluate how the inclusion of synthetic wax, added in 0.5% increments from 1.5% to 3.5%, affects the characteristics of PMB 45/80-65 (polymer-modified bitumen) during both short-term (RTFOT) and long-term (PAV) aging processes. Tests were carried out to assess the fundamental properties of the binder, leading to the determination of the penetration index (PI) and the plasticity range (PR). The binder’s properties were examined at below-freezing operating temperatures, with creep stiffness measured using a bent beam rheometer (BBR) at −10 °C, −16° C, −22 °C, and −28 °C. The rheological properties of the asphaltenes were evaluated based on both linear and nonlinear viscoelasticity. The experimental study explored temperature effects on the rheological properties of composite materials using a DSR dynamic shear rheometer at 40 °C, 60 °C, and 80 °C over a frequency range of 0.005 to 10 Hz. The main parameters of interest were composite viscosity (η*) and zero shear viscosity (η0). Viscoelastic parameters, including the dynamic modulus (G*) and phase shift angle (δ), were determined, and Black’s curves were used to illustrate the relationship between these parameters, where G*/sinδ was determined. The MSCR test was employed to investigate the impact of bitumen on the asphalt mixture’s resistance to permanent deformation and to assess the degree and efficacy of asphalt modification. The test measured two parameters, irreversible creep compliance (Jnr) and recovery (R), under stress levels of 0.1 kPa (LVE) and 3.2 kPa (N-LVE). The Christensen–Anderson–Marasteanu model was used to describe the bitumen behavior during binder aging, as reflected in the rheological study results. Ultimately, this study revealed that synthetic wax influences the rheological properties of PMB 45/80-65 polymer bitumen. Specifically, it mitigated the stiffness reduction in modified bitumen caused by polymer degradation during aging at an amount less than 2.5% of synthetic wax. Full article
(This article belongs to the Special Issue Advances in Asphalt Materials (Second Volume))
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