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14 pages, 2057 KB  
Article
An Approach for Balanced Power and Maneuvering Assistance Using Rotor Sails
by Cem Güzelbulut and Serdar Kaveloğlu
J. Mar. Sci. Eng. 2026, 14(7), 628; https://doi.org/10.3390/jmse14070628 (registering DOI) - 29 Mar 2026
Abstract
Wind-assisted ship propulsion (WASP) systems are gaining importance due to their contribution to reducing greenhouse gases and saving fuel. Existing studies mostly focus on the aerodynamics of sailing systems, the integration of sails and ship dynamics, and the prediction of fuel savings. The [...] Read more.
Wind-assisted ship propulsion (WASP) systems are gaining importance due to their contribution to reducing greenhouse gases and saving fuel. Existing studies mostly focus on the aerodynamics of sailing systems, the integration of sails and ship dynamics, and the prediction of fuel savings. The present study extends the use case of sailing systems by proposing a new control logic that improves maneuvering performance. Determining the spin ratio of rotor sails not only with thrust but also with side forces and moments is also included as an objective function. Using numerous random weights for each term and environmental conditions, the turning performance of the target ship was evaluated. Then, an artificial neural network (ANN) model was trained to decide on the optimal weights, depending on the environmental conditions. Finally, the performance of the new control approach was evaluated based on turning and zigzag test simulations. It was found that the advance, transfer, and tactical diameters dropped by up to 5%, 7% and 7%, respectively, compared to those of a conventional ship. When it comes to the zigzag performance, it was revealed that the overshoot angles dropped even though there was no simulation data about zigzag tests in the trained ANN model. Thus, it was shown that sails improve the maneuverability of ships in addition to providing additional thrust if a proper control approach is adopted. Full article
(This article belongs to the Special Issue Machine Learning for Prediction of Ship Motion)
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28 pages, 7001 KB  
Article
Thermal Intelligence for Hydro-Generators: Data-Driven Prediction of Stator Winding Temperature Under Real Operating Conditions
by Zangpo, Munira Batool and Imtiaz Madni
Energies 2026, 19(7), 1671; https://doi.org/10.3390/en19071671 (registering DOI) - 28 Mar 2026
Abstract
Hydropower remains one of the primary sources of power generation. It can be operated as either a base-load or peak-load plant due to its rapid, easy start-up and stop-down capability. However, power plants, old or new, need to be operated and maintained optimally [...] Read more.
Hydropower remains one of the primary sources of power generation. It can be operated as either a base-load or peak-load plant due to its rapid, easy start-up and stop-down capability. However, power plants, old or new, need to be operated and maintained optimally to meet energy demand and maximise economic returns. While the older plants without digital controls such as the Supervisory Control and Data Acquisition (SCADA) system are unable to leverage the evolving technology including big data and Artificial Intelligence (AI), the newer plants or plants that already have some form of data acquisition system have the advantage of leveraging the newer platforms for efficient operation, monitoring and fault diagnosis. Thus, an Artificial Neural Network (ANN), a machine learning (ML) algorithm, was chosen for this case study to predict the generator’s operational stator temperature by selecting six parameters that could potentially affect it. Real data from the 336 MW Chhukha Hydropower Plant (CHP) in Bhutan were used to train the ANN. The prediction of temperature using an ANN in MATLAB® yielded an R2 (correlation coefficient) of 96.8%, which is impressive but can be further improved through various optimisation and tuning methods with increased data volume and complexity. The performance of ANN prediction was validated against other regression models, and the ANN was found to outperform them. This demonstrated its capability to predict and detect generator temperature faults before failures, thereby enhancing hydropower operation and maintenance (O&M) efficiency. The model’s interpretation was also done through Shapley Additive ExPlanations (SHAP). Full article
(This article belongs to the Section F: Electrical Engineering)
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19 pages, 736 KB  
Article
Modeling and Optimization for Reverse Osmosis Water Treatment Using Artificial Neural Network and Genetic Algorithm Approach: Economic and Operational Perspectives
by Hamdani Hamdani, Iwan Vanany and Heri Kuswanto
Water 2026, 18(7), 810; https://doi.org/10.3390/w18070810 (registering DOI) - 28 Mar 2026
Abstract
This study contributes to the modeling and optimization model for reverse osmosis water treatment (ROWT) due to a lack of economic and operational aspects. This study proposes a hybrid modeling and optimization framework using a hybrid artificial neural network (ANN) and genetic algorithm [...] Read more.
This study contributes to the modeling and optimization model for reverse osmosis water treatment (ROWT) due to a lack of economic and operational aspects. This study proposes a hybrid modeling and optimization framework using a hybrid artificial neural network (ANN) and genetic algorithm (GA) to enhance the accuracy of economic and operational predictions for ROWT. The ANN model is developed using seventeen key process parameters extracted from various ROWT plants, including flow rate, pH, conductivity, and turbidity. The GA is employed to optimize the network architecture and learning parameters based on the mean absolute percentage error (MAPE) as the fitness function. The findings of this study indicate that the GA-optimized model significantly outperforms the baseline model, reducing MAPE for the economic aspect (84.9% improvement) and the operational aspect (32.2% improvement). The findings from this study indicate that the hybrid ANN–GA approach is a management decision-making tool for reducing expenses without compromising water quality in ROWT management. The practical implications of this study are that predictions not only meet operational parameters but also predict expenses incurred, allowing managers to plan future budgets by optimizing ROWT resources and maintenance activities. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
18 pages, 1974 KB  
Article
Development of Machine Learning Model for Analysis of Total Manufacturing Cost in Medium Turning of C45E Steel
by Miloš Madić, Milan Trifunović, Dragan Rodić and Dragan Marinković
Metals 2026, 16(4), 373; https://doi.org/10.3390/met16040373 (registering DOI) - 28 Mar 2026
Abstract
The primary goal of manufacturing technologies in the metalworking industry is to provide products with specified quality characteristics, while maximizing time and cost efficiency. The total manufacturing cost in turning depends on a number of factors. The analysis of their effects and the [...] Read more.
The primary goal of manufacturing technologies in the metalworking industry is to provide products with specified quality characteristics, while maximizing time and cost efficiency. The total manufacturing cost in turning depends on a number of factors. The analysis of their effects and the estimation of the total manufacturing cost are of practical importance in process planning. Therefore, in the present study, the relationship between four inputs (depth of cut, feed rate, cutting speed and volume of material to be removed) and the total manufacturing cost in medium turning of C45E steel was modeled by using an artificial neural network (ANN). The developed ANN model was used for the analysis of the main and interaction effects of the aforementioned inputs on the total manufacturing cost. Verification of the observed effects was also carried out by applying the connection weight approach. The total manufacturing cost was mostly affected by depth of cut, while the effect of cutting speed was least pronounced. In addition, the results also revealed the presence of two-way interactions associated with cutting speed. For the given case study (with defined volume of material to be removed and specified machine tool), an optimized cutting regime was determined by developing and solving a single-objective turning optimization problem with three constraints related to chip slenderness, cutting power and depth of cut. Cutting force, needed for the estimation of cutting power, was estimated by using the dimensional analysis-based prediction model. Full article
(This article belongs to the Special Issue Application of Machine Learning in Metallic Materials)
29 pages, 2733 KB  
Article
Productivity Prediction in Tight Oil Reservoirs: A Stacking Ensemble Approach with Hybrid Feature Selection
by Zhengyang Kang, Yong Zheng, Tianyang Zhang, Haoyu Chen, Xiaoyan Zhou, Quanyu Cai and Yiran Sun
Processes 2026, 14(7), 1089; https://doi.org/10.3390/pr14071089 - 27 Mar 2026
Abstract
To address the challenges of low accuracy and complex influencing factors in predicting horizontal well fracturing productivity during the development of unconventional oil and gas resources such as tight oil, this paper proposes a productivity prediction framework based on an improved feature selection [...] Read more.
To address the challenges of low accuracy and complex influencing factors in predicting horizontal well fracturing productivity during the development of unconventional oil and gas resources such as tight oil, this paper proposes a productivity prediction framework based on an improved feature selection method and an ensemble learning model. This study employs a fusion analysis using the entropy weight method to combine Pearson correlation analysis and improved gray relational analysis (IGRA) for feature selection. Thirteen machine learning models were tested with six distinct parameter combinations to construct a Stacking-based ensemble learning model, with base models including Random Forest (RF), Ridge Regression (RR), and Artificial Neural Network (ANN). Particle Swarm Optimization (PSO) was employed to optimize hyperparameters, followed by interpretability analysis using SHapley Additive exPlanations (SHAP). The results indicate that the model with fused weights demonstrated optimal performance. The Stacking model achieved significantly improved accuracy after PSO optimization, with the coefficient of determination increasing by 4.9%, outperforming all comparison models. Engineering guidance is provided: Under current geological conditions, sand ratio and displacement fluid volume require fine-tuning to prevent over-treatment. Fracturing design should implement differentiated strategies based on the target sand body thickness. This study not only delivers a high-precision production prediction tool but also offers decision support for efficient unconventional oil and gas field development through its exceptional interpretability. Full article
(This article belongs to the Section Petroleum and Low-Carbon Energy Process Engineering)
22 pages, 5007 KB  
Article
Prediction of Forest Fire Occurrence Risk in Heilongjiang Province Under Future Climate Change
by Zechuan Wu, Houchen Li, Mingze Li, Xintai Ma, Yuan Zhou, Yuping Tian, Ying Quan and Jianyang Liu
Forests 2026, 17(4), 414; https://doi.org/10.3390/f17040414 - 26 Mar 2026
Viewed by 177
Abstract
Against the backdrop of climate change, forest fires increasingly undermine ecosystem stability and reshape species distributions in Heilongjiang Province. Therefore, quantifying the drivers of fire occurrence and conducting long-term fire risk forecasting holds critical value for regional ecological security. Centered on the forested [...] Read more.
Against the backdrop of climate change, forest fires increasingly undermine ecosystem stability and reshape species distributions in Heilongjiang Province. Therefore, quantifying the drivers of fire occurrence and conducting long-term fire risk forecasting holds critical value for regional ecological security. Centered on the forested regions of Heilongjiang Province, this study systematically assessed the relative contributions of multi-source factors—including topography, vegetation, and meteorological conditions—to fire occurrence and compared the predictive performance of three models: Deep Neural Network with Residual Connections (ResDNN), Artificial Neural Network (ANN), and Support Vector Machine (SVM). Modeling results based on historical fire records indicated that the ResDNN model achieved the highest accuracy (85.6%). Owing to its robust nonlinear mapping capability, it performed better in capturing complex feature interactions than ANN and SVM. These results demonstrate its strong applicability to forest fire prediction in Heilongjiang Province. Building on these findings, the study employed the best-performing ResDNN model in conjunction with CMIP6 multi-model climate projections to simulate and map the spatiotemporal probability of forest fire occurrence from 2030 to 2070. The results provide an intuitive representation of long-term fire-risk trajectories under future climate scenarios and offer scientific support for regional fire prevention, monitoring, early-warning systems, and forest management under climate change. Full article
(This article belongs to the Section Forest Meteorology and Climate Change)
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25 pages, 13557 KB  
Article
Integrated Chemometric and Neural Network Analysis for the Differentiation of Cucurbita maxima and Cucurbita moschata
by Milorad Miljić, Biljana Lončar, Biljana Kiprovski, Lato Pezo, Miloš Radosavljević, Milenko Košutić, Vesna Vasić, Dragana Lukić, Milena Rašeta and Sanja Krstić
Agriculture 2026, 16(7), 733; https://doi.org/10.3390/agriculture16070733 - 26 Mar 2026
Viewed by 128
Abstract
This study examines the compositional differentiation of two Cucurbita species, C. maxima Duchesne and C. moschata Duchesne, to identify chemical markers relevant for their nutritional and functional potential. Multivariate statistical analysis, including principal component analysis (PCA), was applied to chromatographic, chemical, and antioxidant [...] Read more.
This study examines the compositional differentiation of two Cucurbita species, C. maxima Duchesne and C. moschata Duchesne, to identify chemical markers relevant for their nutritional and functional potential. Multivariate statistical analysis, including principal component analysis (PCA), was applied to chromatographic, chemical, and antioxidant descriptors to visualize patterns of variability among samples. Classification artificial neural network (cANN) models were used to explore the potential of machine learning for sample differentiation, using integrated lipidomic, carotenoid, phenolic, and liquid chromatographic datasets, providing a multidimensional biochemical characterization of Cucurbita samples, achieving good classification within the analyzed dataset, reflecting the model’s capacity to describe the available data. The integration of chemometric and ANN approaches provides a framework for the compositional profiling and quality assessment of Cucurbita species, offering insights into their sustainable valorization as sources of bioactive compounds for food and nutraceutical applications while acknowledging the need for further validation on larger datasets. Full article
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34 pages, 6554 KB  
Article
Syncretic Grad-CAM Integrated ViT-CNN Hybrids with Inherent Explainability for Early Thyroid Cancer Diagnosis from Ultrasound
by Ahmed Y. Alhafdhi, Gibrael Abosamra and Abdulrhman M. Alshareef
Diagnostics 2026, 16(7), 999; https://doi.org/10.3390/diagnostics16070999 - 26 Mar 2026
Viewed by 116
Abstract
Background/Objectives: Accurate detection of thyroid cancer using ultrasound remains a challenge, as malignant nodules can be microscopic and heterogeneous, easily confused with point clusters and borderline-featured tissues. Current studies in deep learning demonstrate good performance with convolutional neural networks (CNNs) and clustering; however, [...] Read more.
Background/Objectives: Accurate detection of thyroid cancer using ultrasound remains a challenge, as malignant nodules can be microscopic and heterogeneous, easily confused with point clusters and borderline-featured tissues. Current studies in deep learning demonstrate good performance with convolutional neural networks (CNNs) and clustering; however, many approaches focus on local tissue and provide limited, non-quantitative interpretation, reducing clinical confidence. This study proposes an integrated framework combining enhanced convolutional feature encoders (DenseNet169 and VGG19) with an enhanced vision transformer (ViT-E) to integrate local feature and global relational context during learning, rather than delayed integration. Methods: The proposed framework integrates enhanced convolutional feature encoders (DenseNet169 and VGG19) with an enhanced vision transformer (ViT-E), enabling simultaneous learning of local feature representations and global relational context. This design allows feature fusion during the learning stage instead of delayed integration, aiming to improve diagnostic performance and interpretability in thyroid ultrasound image analysis. Results: The best-performing model, ViT-E–DenseNet169, achieved 98.5% accuracy, 98.9% sensitivity, 99.15% specificity, and 97.35% AUC, surpassing the robust basic hybrid model (CNN–XGBoost/ANN) and existing systems. A second contribution is improved interpretability, moving from mere illustration to validation. Gradient-weighted class activation mapping (Grad-CAM) maps demonstrated distinct and clinically understandable concentration patterns across various thyroid cancers: precise intralesional concentration for high-confidence malignancies (PTC = 0.968), edge/interface concentration for capsule risk patterns (PTC = 0.957), and broader-field activation consistent with infiltration concerns (PTC = 0.984), while benign scans showed low and diffuse activation (PTC = 0.002). Spatial audits reinforced this behavior (IoU/PAP: 0.72/91%, 0.65/78%, 0.58/62%). Conclusions: The integrated ViT-E–DenseNet169 framework provides highly accurate thyroid cancer detection while offering clinically meaningful interpretability through Grad-CAM-based spatial validation, supporting improved confidence in AI-assisted ultrasound diagnosis. Full article
(This article belongs to the Special Issue Deep Learning Techniques for Medical Image Analysis)
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20 pages, 9472 KB  
Article
Spatial Downscaling of Satellite-Based Precipitation Data over the Qaidam Basin, China
by Yuanzheng Wang, Changzhen Yan, Qimin Ma and Xiaopeng Jia
Remote Sens. 2026, 18(7), 995; https://doi.org/10.3390/rs18070995 - 26 Mar 2026
Viewed by 173
Abstract
High-spatiotemporal-resolution precipitation data are essential for studies on regional hydrology, meteorology, and ecological conservation. Because the Qaidam Basin is a data-scarce region with a few ground stations and coarse-resolution remote sensing products, its utility in regional research is constrained. Therefore, high-resolution precipitation data [...] Read more.
High-spatiotemporal-resolution precipitation data are essential for studies on regional hydrology, meteorology, and ecological conservation. Because the Qaidam Basin is a data-scarce region with a few ground stations and coarse-resolution remote sensing products, its utility in regional research is constrained. Therefore, high-resolution precipitation data are urgently needed. Here, longitude, latitude, the normalized difference vegetation index (NDVI), the digital elevation model (DEM), daytime and nighttime land surface temperature, slope, and aspect were selected as environmental variables. Four machine learning methods, Artificial Neural Network (ANN), Cubist, Random Forest (RF), and Support Vector Machine (SVM), were used to downscale Tropical Rainfall Measuring Mission (TRMM) precipitation data from 25 to 1 km in the Qaidam Basin and validated using ground observation stations. For annual downscaling, the accuracy ranked as Cubist > ANN > RF > SVM, and residual correction further improved performance. The Cubist model produced the best results, generating finer spatial patterns and reducing outliers in both annual and monthly products. Longitude, latitude, the DEM, and the NDVI were important contributors to the Cubist model. The resulting high-resolution dataset provides valuable support for hydrological and climate change research in the Qaidam Basin. Full article
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30 pages, 5479 KB  
Article
Hydro-Sedimentological Controls on Natural and Anthropogenic Radionuclide Distribution in the Western Black Sea Shelf
by Maria-Emanuela Mihailov, Alina-Daiana Spinu, Alexandru-Cristian Cindescu and Luminita Buga
Environments 2026, 13(4), 184; https://doi.org/10.3390/environments13040184 - 26 Mar 2026
Viewed by 243
Abstract
This study examines the hydro-sedimentological–radioecological controls governing the distribution of natural (K-40, Ra-226, Th-232) and anthropogenic (Cs-137) radionuclides in surface sediments of the western Black Sea shelf. Activity concentrations were determined by high-resolution gamma spectrometry, and radiological indices—including radium equivalent activity (Ra_eq), external [...] Read more.
This study examines the hydro-sedimentological–radioecological controls governing the distribution of natural (K-40, Ra-226, Th-232) and anthropogenic (Cs-137) radionuclides in surface sediments of the western Black Sea shelf. Activity concentrations were determined by high-resolution gamma spectrometry, and radiological indices—including radium equivalent activity (Ra_eq), external hazard index (Hex), and annual effective dose (AED)—were calculated to evaluate environmental safety. All indices remained well below internationally accepted thresholds, confirming the absence of radiological hazard in both coastal and offshore settings. Strong correlations between Ra-226 and Th-232 indicate dominant lithogenic control of natural radionuclides, whereas Cs-137 exhibits geochemical decoupling consistent with its behavior. A significant relationship between the fine-grained sediment fraction (<63 µm) and Cs-137 activity highlights the grain size effect, with offshore depositional zones acting as sediment-focusing areas where Cs-137 and excess Pb-210 co-accumulate under low-energy hydrodynamic conditions. Despite localized offshore enrichment, dose contribution analysis shows that natural radionuclides dominate the absorbed-dose budget, while Cs-137 contributes only marginally. Spatial predictive modeling using Artificial Neural Networks, validated under a Spatial Leave-One-Group-Out framework, yielded moderate generalization capacity (R2 = 0.61 for Ra-226; R2 = 0.41 for Cs-137), reflecting smoother spatial gradients of lithogenic radionuclides than heterogeneous radiocesium deposition. Furthermore, Machine Learning algorithms provided significant analytical value: a Random Forest (RF) model successfully classified environments (nearshore/shelf/depositional basin) based on distinct radionuclide signatures. At the same time, an optimized Artificial Neural Network (ANN-GA) enabled the nonlinear reconstruction of radiometric–granulometric patterns to identify local anomalies. The results show that radionuclide distributions are primarily structured by sediment provenance, grain size sorting, and hydrodynamic energy gradients rather than ongoing anthropogenic inputs. Full article
(This article belongs to the Special Issue Advanced Research in Environmental Radioactivity)
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23 pages, 3657 KB  
Article
Performance of the Intumescent Coatings in Structural Fire via ANN-Based Predictive Models
by Kin Ip Chu and Majid Aleyaasin
Fire 2026, 9(4), 142; https://doi.org/10.3390/fire9040142 - 25 Mar 2026
Viewed by 255
Abstract
In this paper, an Artificial Neural Network (ANN) is built to predict the performance of intumescent coatings subjected to the ISO 384 fire curve. The performance metric is called the Retention Loss Onset Time (RLOT) in the structural steel. The network receives the [...] Read more.
In this paper, an Artificial Neural Network (ANN) is built to predict the performance of intumescent coatings subjected to the ISO 384 fire curve. The performance metric is called the Retention Loss Onset Time (RLOT) in the structural steel. The network receives the steel and coating thicknesses as input and provides RLOT as the performance of any intumescent coating in a fire accident with substantial accuracy. The required data for obtaining the model is provided by revisiting the recent attempts in this field, which include hybrid numerical and experimental methods. It is found that the trapped gas fraction parameter and empirical expansion ratio substantially affect the accuracy of predictive modelling. Therefore, a new, comprehensive dynamic model that numerically simulates the bubble expansion process has been developed. This novel method directly determines the expansion ratio of the thermal conductivity model. The Eurocode is then used with multi-layer models to predict the steel temperature profile for a 1 h duration ISO fire. The accuracy is improved by modelling the temperatures and thermal resistances at the centre of each divided layer. The effects of different coatings and steel thicknesses are also investigated to provide the required data. The results are verified and validated by comparing them with the recent numerical and empirical results available in the literature. Full article
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28 pages, 5779 KB  
Article
Recovery of Petermann Glacier Velocity from SAR Imagery Using a Spatiotemporal Hybrid Neural Network
by Zongze Li, Haimei Mo, Lebao Yang and Jinsong Chong
Appl. Sci. 2026, 16(7), 3169; https://doi.org/10.3390/app16073169 - 25 Mar 2026
Viewed by 149
Abstract
Numerous studies have demonstrated the potential of Synthetic Aperture Radar (SAR) in monitoring glacier velocity. However, owing to the complex dynamics of glaciers and the variability of their surface features, velocity fields derived from even short-interval SAR image pairs often exhibit missing parts. [...] Read more.
Numerous studies have demonstrated the potential of Synthetic Aperture Radar (SAR) in monitoring glacier velocity. However, owing to the complex dynamics of glaciers and the variability of their surface features, velocity fields derived from even short-interval SAR image pairs often exhibit missing parts. This study proposes a missing glacier velocity recovery method based on a spatiotemporal hybrid neural network to solve the above problem. Considering the spatiotemporal characteristics of glacier velocity fields, a hybrid network combining an Artificial Neural Network (ANN) and a Denoising Autoencoder (DAE) is developed. The ANN is first employed to capture spatial correlations associated with missing values, after which it is integrated with the DAE to model temporal variations using a time-aware loss function. An iterative weighting strategy adaptively balances spatial and temporal features during training. The method is applied to SAR–derived velocity fields of Petermann Glacier. Experimental results show that the method significantly improves the performance of glacier velocity recovery compared to traditional methods. Additionally, the study compares and analyzes the velocity of Petermann Glacier in different seasons, and the findings indicate that the glacier exhibits more pronounced seasonal differences in the accumulation zone. Full article
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44 pages, 11575 KB  
Article
GeoAI-Driven Land Cover Change Prediction Using Copernicus Earth Observation and Geospatial Data for Law-Compliant Territorial Planning in the Aosta Valley (Italy)
by Tommaso Orusa, Duke Cammareri and Davide Freppaz
Land 2026, 15(4), 533; https://doi.org/10.3390/land15040533 - 25 Mar 2026
Viewed by 448
Abstract
Mapping land cover, monitoring its changes, and simulating future alterations are essential tasks for sustainable land management. These processes enable accurate assessment of environmental impacts, support informed policymaking, and assist in the planning needed to mitigate risks related to urban expansion, deforestation, and [...] Read more.
Mapping land cover, monitoring its changes, and simulating future alterations are essential tasks for sustainable land management. These processes enable accurate assessment of environmental impacts, support informed policymaking, and assist in the planning needed to mitigate risks related to urban expansion, deforestation, and climate change. This study proposes a GeoAI-based framework leveraging Multilayer Perceptron (MLP), a class of Artificial Neural Networks (ANNs), to predict land cover changes in the Aosta Valley region (NW Italy). The model uses Copernicus Earth Observation data, specifically Sentinel-1 and Sentinel-2 imagery, and is trained and validated on land cover maps derived from different time periods previously validated with ground truth data. The objective is to provide a predictive tool capable of simulating potential future landscape configurations, supporting proactive regional land use planning including regulatory constraints under the current land use plan. Model performance is evaluated using accuracy metrics. The land cover classification methodology follows established approaches in the scientific literature, adapted to the specific geomorphological characteristics of the Aosta Valley. To explore and visualize potential future land cover transitions, Sankey and chord diagrams are used in combination with zonal statistics and thematic plots. These provide detailed insights into the intensity, direction, and magnitude of landscape dynamics. Training data were stratified-sampled across the study area, covering a diverse set of land cover classes to ensure robustness and generalization of the MLP model. This GeoAI approach offers a scalable and replicable methodology for anticipating land cover dynamics, identifying vulnerable areas, and informing adaptive environmental management strategies at the regional scale, while simultaneously considering the latest urban planning regulations. Full article
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17 pages, 1141 KB  
Article
Rapid and Accurate ED-XRF Quantification of Trace Arsenic in Rice-Based Foods Employing ANNs to Resolve Lead Spectral Interference
by Murphy Carroll, Zili Gao and Lili He
Foods 2026, 15(7), 1130; https://doi.org/10.3390/foods15071130 (registering DOI) - 25 Mar 2026
Viewed by 179
Abstract
Trace quantifications of arsenic (As) in foods by energy-dispersive X-ray fluorescence (ED-XRF) spectrometry are hindered by spectral overlap from lead (Pb) at characteristic emission lines. This study employed artificial neural networks (ANN) to statistically model and correct for As/Pb spectral overlap, enabling accurate [...] Read more.
Trace quantifications of arsenic (As) in foods by energy-dispersive X-ray fluorescence (ED-XRF) spectrometry are hindered by spectral overlap from lead (Pb) at characteristic emission lines. This study employed artificial neural networks (ANN) to statistically model and correct for As/Pb spectral overlap, enabling accurate As quantifications in rice-based foods. Calibration standards were prepared by pelletizing milled rice spiked with As and Pb, and validation was performed using a certified reference material, commercial rice-based foods, and Pb-spiked commercial foods. As calibration metrics were great (R2 = 0.92, standard error in calibration = 41.20 µg kg−1). The validation assessment achieved acceptable error using the As reference material (−19.43% error) and in commercial rice-based foods containing low Pb content (6 of 11 As determinations in agreement with the reference method). Additionally, accurate predictions of As were found in the presence of significant Pb interference (absolute mean error = 14.11% in Pb-spiked commercial foods). Overall, ANN modeling for Pb exhibited poor performance during both calibration and validation. This work demonstrates the usability of an ANN to address the As/Pb overlapping issue while offering insights into the strengths and weaknesses of ANNs when coupled with ED-XRF for trace elemental quantifications in foods. Full article
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21 pages, 3054 KB  
Article
Natural Hydrophobic Deep Eutectic Solvent-Based Enhanced Extraction of Bioactive Compounds from Cannabis sativa L. Leaf for Pharmaceutical Applications
by Serwat Naz, Sumia Akram, Rabia Naeem, Haroon Iftikhar, Rizwan Ashraf, Noor Ul Ain Khalid, Muhammad Shahid, Imad A. Abu-Yousef, Amin F. Majdalawieh and Muhammad Mushtaq
Int. J. Mol. Sci. 2026, 27(7), 2933; https://doi.org/10.3390/ijms27072933 - 24 Mar 2026
Viewed by 255
Abstract
Cannabis sativa L. leaves (CSL) are a rich in bioactive compounds and known for their medicinal and recreational uses. In this study, a natural hydrophobic deep eutectic solvent (HDES) system composed of menthol and thymol (1:1) was employed for the efficient extraction of [...] Read more.
Cannabis sativa L. leaves (CSL) are a rich in bioactive compounds and known for their medicinal and recreational uses. In this study, a natural hydrophobic deep eutectic solvent (HDES) system composed of menthol and thymol (1:1) was employed for the efficient extraction of bioactive compounds from CSL. Extraction of bioactives was optimized at various conditions involving DES/ethanol ratio, temperature, and extraction time, as well as shaking speed through statistical models including response surface methodology (RSM) and artificial neural network (ANN). The maximum bioactive yield, equal to 70% (w/w) of powdered CSL, was achieved at optimized values of 5.5 mL DES, 4.5 mL ethanol, and 225 rpm shaking speed at 55 °C for 107.5 min. It was observed that slightly adjusting the shaking speed and temperatures customized the nature of bioactives with more antioxidant, antidiabetic, and antimicrobial properties. The extracts of CSL produced while applying natural HDES were found to be non-toxic during hemolytic assay. Overall, HDES when mixed with ethanol in 55:45 ratio produced CSL extracts with an ample level of phenolics (133.75 mg GAE/g) and flavonoids (120.05 mg QE/g). GC-MS analysis of CSL extracts produced by HDES revealed the presence of multiple bioactives like tetrahydrocannabivarin, cannabidiol, cannabinol, cannabidivarol, dl-menthol, levomenthol, and 4-hydroxy-3-methylacetophenone. Based on these findings, it can be concluded that HDES in combination with ethanol may work as an efficient extraction solvent to recover CSL bioactives without compromising their antioxidant features and safety for use in food and pharmaceutical applications. Full article
(This article belongs to the Section Bioactives and Nutraceuticals)
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