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Search Results (2,341)

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16 pages, 647 KiB  
Article
Geographic Scale Matters in Analyzing the Effects of the Built Environment on Choice of Travel Modes: A Case Study of Grocery Shopping Trips in Salt Lake County, USA
by Ensheng Dong, Felix Haifeng Liao and Hejun Kang
Urban Sci. 2025, 9(8), 307; https://doi.org/10.3390/urbansci9080307 - 5 Aug 2025
Abstract
Compared to commuting, grocery shopping trips, despite their profound implications for mixed land use and transportation planning, have received limited attention in travel behavior research. Drawing upon a travel diary survey conducted in a fast-growing metropolitan region of the United States, i.e., Salt [...] Read more.
Compared to commuting, grocery shopping trips, despite their profound implications for mixed land use and transportation planning, have received limited attention in travel behavior research. Drawing upon a travel diary survey conducted in a fast-growing metropolitan region of the United States, i.e., Salt Lake County, UT, this research investigated a variety of influential factors affecting mode choices associated with grocery shopping. We analyze how built environment (BE) characteristics, measured at seven spatial scales or different ways of aggregating spatial data—including straight-line buffers, network buffers, and census units—affect travel mode decisions. Key predictors of choosing walking, biking, or transit over driving include age, household size, vehicle ownership, income, land use mix, street density, and distance to the central business district (CBD). Notably, the influence of BE factors on mode choice is sensitive to different spatial aggregation methods and locations of origins and destinations. The straight-line buffer was a good indicator for the influence of store sales amount on mode choices; the network buffer was more suitable for the household built environment factors, whereas the measurement at the census block and block group levels was more effective for store-area characteristics. These findings underscore the importance of considering both the spatial analysis method and the location (home vs. store) when modeling non-work travel. A multi-scalar approach can enhance the accuracy of travel demand models and inform more effective land use and transportation planning strategies. Full article
17 pages, 5314 KiB  
Article
The Settlement Ratio and Settled Area: Novel Indicators for Analyzing Land Use in Relation to Road Network Functions and Performance
by Giulia Del Serrone, Giuseppe Cantisani and Paolo Peluso
Eng 2025, 6(8), 188; https://doi.org/10.3390/eng6080188 - 5 Aug 2025
Abstract
Land use significantly influences mobility dynamics, affecting both travel behavior and mode choice. Traditional indicators such as the Floor Area Ratio, Land-Use Mix Index, and Built-up Area Ratio are widely used to describe settlement patterns; yet, they often fail to capture their functional [...] Read more.
Land use significantly influences mobility dynamics, affecting both travel behavior and mode choice. Traditional indicators such as the Floor Area Ratio, Land-Use Mix Index, and Built-up Area Ratio are widely used to describe settlement patterns; yet, they often fail to capture their functional impacts on road networks. This study introduces two complementary indicators—Settlement Ratio (SR) and Settled Area (SA)—developed through a spatial analysis framework integrating GIS data and MATLAB processing. SR offers a continuous typological profile of built-up functions along the road axis, while SA measures the percentage of anthropized land within fixed analysis windows. Applied to two Italian state roads, SS14 and SS309, in the Veneto Region, the dual-indicator approach reveals how the intensity (SR) and extent (SA) of settlement vary across different territorial contexts. In suburban segments, SR values exceeding 15–20, together with SA levels between 10% and 15%, highlight the significant spatial impact of isolated development clusters—often not evident from macro-scale observations. These findings demonstrate that the SR–SA framework provides a robust tool for analyzing land use in relation to road function. Although the study focuses on spatial structure and indicator design, future developments will explore correlations with traffic flow, speed, and crash data to support road safety analyses. Full article
(This article belongs to the Special Issue Interdisciplinary Insights in Engineering Research)
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26 pages, 4116 KiB  
Article
Robust Optimal Operation of Smart Microgrid Considering Source–Load Uncertainty
by Zejian Qiu, Zhuowen Zhu, Lili Yu, Zhanyuan Han, Weitao Shao, Kuan Zhang and Yinfeng Ma
Processes 2025, 13(8), 2458; https://doi.org/10.3390/pr13082458 - 4 Aug 2025
Abstract
The uncertainties arising from high renewable energy penetration on both the generation and demand sides pose significant challenges to distribution network security. Smart microgrids are considered an effective way to solve this problem. Existing studies exhibit limitations in prediction accuracy, Alternating Current (AC) [...] Read more.
The uncertainties arising from high renewable energy penetration on both the generation and demand sides pose significant challenges to distribution network security. Smart microgrids are considered an effective way to solve this problem. Existing studies exhibit limitations in prediction accuracy, Alternating Current (AC) power flow modeling, and integration with optimization frameworks. This paper proposes a closed-loop technical framework combining high-confidence interval prediction, second-order cone convex relaxation, and robust optimization to facilitate renewable energy integration in distribution networks via smart microgrid technology. First, a hybrid prediction model integrating Variational Mode Decomposition (VMD), Long Short-Term Memory (LSTM), and Quantile Regression (QR) is designed to extract multi-frequency characteristics of time-series data, generating adaptive prediction intervals that accommodate individualized decision-making preferences. Second, a second-order cone relaxation method transforms the AC power flow optimization problem into a mixed-integer second-order cone programming (MISOCP) model. Finally, a robust optimization method considering source–load uncertainties is developed. Case studies demonstrate that the proposed approach reduces prediction errors by 21.15%, decreases node voltage fluctuations by 16.71%, and reduces voltage deviation at maximum offset nodes by 17.36%. This framework significantly mitigates voltage violation risks in distribution networks with large-scale grid-connected photovoltaic systems. Full article
(This article belongs to the Special Issue Applications of Smart Microgrids in Renewable Energy Development)
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23 pages, 6611 KiB  
Article
Study on Flow and Heat Transfer Characteristics of Reheating Furnaces Under Oxygen-Enriched Conditions
by Maolong Zhao, Xuanxuan Li and Xianzhong Hu
Processes 2025, 13(8), 2454; https://doi.org/10.3390/pr13082454 - 3 Aug 2025
Viewed by 67
Abstract
A computational fluid dynamics (CFD) numerical simulation methodology was implemented to model transient heating processes in steel industry reheating furnaces, targeting combustion efficiency optimization and carbon emission reduction. The effects of oxygen concentration (O2%) and different fuel types on the flow [...] Read more.
A computational fluid dynamics (CFD) numerical simulation methodology was implemented to model transient heating processes in steel industry reheating furnaces, targeting combustion efficiency optimization and carbon emission reduction. The effects of oxygen concentration (O2%) and different fuel types on the flow and heat transfer characteristics were investigated under both oxygen-enriched combustion and MILD oxy-fuel combustion. The results indicate that MILD oxy-fuel combustion promotes flue gas entrainment via high-velocity oxygen jets, leading to a substantial improvement in the uniformity of the furnace temperature field. The effect is most obvious at O2% = 31%. MILD oxy-fuel combustion significantly reduces NOx emissions, achieving levels that are one to two orders of magnitude lower than those under oxygen-enriched combustion. Under MILD conditions, the oxygen mass fraction in flue gas remains below 0.001 when O2% ≤ 81%, indicating effective dilution. In contrast, oxygen-enriched combustion leads to a sharp rise in flame temperature with an increasing oxygen concentration, resulting in a significant increase in NOx emissions. Elevating the oxygen concentration enhances both thermal efficiency and the energy-saving rate for both combustion modes; however, the rate of improvement diminishes when O2% exceeds 51%. Based on these findings, MILD oxy-fuel combustion using mixed gas or natural gas is recommended for reheating furnaces operating at O2% = 51–71%, while coke oven gas is not. Full article
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16 pages, 428 KiB  
Article
Biodiversity Patterns and Community Construction in Subtropical Forests Driven by Species Phylogenetic Environments
by Pengcheng Liu, Jiejie Jiao, Chuping Wu, Weizhong Shao, Xuesong Liu and Liangjin Yao
Plants 2025, 14(15), 2397; https://doi.org/10.3390/plants14152397 - 2 Aug 2025
Viewed by 142
Abstract
To explore the characteristics of species diversity and phylogenetic diversity, as well as the dominant processes of community construction, in different forest types (deciduous broad-leaved forest, mixed coniferous and broad-leaved forest, and Chinese fir plantation) in subtropical regions, analyze the specific driving patterns [...] Read more.
To explore the characteristics of species diversity and phylogenetic diversity, as well as the dominant processes of community construction, in different forest types (deciduous broad-leaved forest, mixed coniferous and broad-leaved forest, and Chinese fir plantation) in subtropical regions, analyze the specific driving patterns of soil nutrients and other environmental factors on the formation of forest diversity in different forest types, and clarify the differences in response to environmental heterogeneity between natural forests and plantation forests. Based on 48 fixed monitoring plots of 50 m × 50 m in Shouchang Forest Farm, Jiande City, Zhejiang Province, woody plants with a diameter at breast height ≥5 cm were investigated. Species diversity indices (Margalef index, Shannon–Wiener index, Simpson index, and Pielou index), phylogenetic structure index (PD), and environmental factors were used to analyze the relationship between diversity characteristics and environmental factors through variance analysis, correlation analysis, and generalized linear models. Phylogenetic structural indices (NRI and NTI) were used, combined with a random zero model, to explore the mechanisms of community construction in different forest types. Research has found that (1) the deciduous broad-leaved forest had the highest species diversity (Margalef index of 4.121 ± 1.425) and phylogenetic diversity (PD index of 21.265 ± 7.796), significantly higher than the mixed coniferous and broad-leaved forest and the Chinese fir plantation (p < 0.05); (2) there is a significant positive correlation between species richness and phylogenetic diversity, with the best fit being AIC = 70.5636 and R2 = 0.9419 in broad-leaved forests; however, the contribution of evenness is limited; (3) the specific effects of soil factors on different forest types: available phosphorus (AP) is negatively correlated with the diversity of deciduous broad-leaved forests (p < 0.05), total phosphorus (TP) promotes the diversity of coniferous and broad-leaved mixed forests, while the diversity of Chinese fir plantations is significantly negatively correlated with total nitrogen (TN); (4) the phylogenetic structure of three different forest types shows a divergent pattern in deciduous broad-leaved forests, indicating that competition and exclusion dominate the construction of deciduous broad-leaved forests; the aggregation mode of Chinese fir plantation indicates that environmental filtering dominates the construction of Chinese fir plantation; the mixed coniferous and broad-leaved forest is a transitional model, indicating that the mixed coniferous and broad-leaved forest is influenced by both stochastic processes and ecological niche processes. In different forest types in subtropical regions, the species and phylogenetic diversity of broad-leaved forests is significantly higher than in other forest types. The impact of soil nutrients on the diversity of different forest types varies, and the characteristics of community construction in different forest types are also different. This indicates the importance of protecting the original vegetation and provides a scientific basis for improving the ecological function of artificial forest ecosystems through structural adjustment. The research results have important practical guidance value for sustainable forest management and biodiversity conservation in the region. Full article
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20 pages, 12851 KiB  
Article
Evaluation of a Vision-Guided Shared-Control Robotic Arm System with Power Wheelchair Users
by Breelyn Kane Styler, Wei Deng, Cheng-Shiu Chung and Dan Ding
Sensors 2025, 25(15), 4768; https://doi.org/10.3390/s25154768 - 2 Aug 2025
Viewed by 165
Abstract
Wheelchair-mounted assistive robotic manipulators can provide reach and grasp functions for power wheelchair users. This in-lab study evaluated a vision-guided shared control (VGS) system with twelve users completing two multi-step kitchen tasks: a drinking task and a popcorn making task. Using a mixed [...] Read more.
Wheelchair-mounted assistive robotic manipulators can provide reach and grasp functions for power wheelchair users. This in-lab study evaluated a vision-guided shared control (VGS) system with twelve users completing two multi-step kitchen tasks: a drinking task and a popcorn making task. Using a mixed methods approach participants compared VGS and manual joystick control, providing performance metrics, qualitative insights, and lessons learned. Data collection included demographic questionnaires, the System Usability Scale (SUS), NASA Task Load Index (NASA-TLX), and exit interviews. No significant SUS differences were found between control modes, but NASA-TLX scores revealed VGS control significantly reduced workload during the drinking task and the popcorn task. VGS control reduced operation time and improved task success but was not universally preferred. Six participants preferred VGS, five preferred manual, and one had no preference. In addition, participants expressed interest in robotic arms for daily tasks and described two main operation challenges: distinguishing wrist orientation from rotation modes and managing depth perception. They also shared perspectives on how a personal robotic arm could complement caregiver support in their home. Full article
(This article belongs to the Special Issue Intelligent Sensors and Robots for Ambient Assisted Living)
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14 pages, 2138 KiB  
Article
Comparison Between Bond Strengths of a Resin Cement on Traditional Prosthetic Substrates and a 3D-Printed Resin for Permanent Restorations
by Alessandro Vichi, Hanan Al-Johani, Dario Balestra and Chris Louca
Coatings 2025, 15(8), 896; https://doi.org/10.3390/coatings15080896 (registering DOI) - 1 Aug 2025
Viewed by 230
Abstract
Recently, 3D-printed resins have been introduced as materials for definitive indirect restorations. Herein, a comparative assessment of the bond strengths of 3D-printed resins to a resin cement was performed. Methods: four definitive restorative materials were selected, i.e., a Feldspar ceramic (VITA Mark II, [...] Read more.
Recently, 3D-printed resins have been introduced as materials for definitive indirect restorations. Herein, a comparative assessment of the bond strengths of 3D-printed resins to a resin cement was performed. Methods: four definitive restorative materials were selected, i.e., a Feldspar ceramic (VITA Mark II, VM), a polymer-infiltrated ceramic network (VITA Enamic, VE), a nanohybrid resin composite (Grandio Bloc, GB), and one 3D-printed resin (Crown Permanent, CP). VM and VE were etched and silanized, GB was sandblasted, and CP was glass bead blasted; for one further experimental group, this was followed by sandblasting (CPs). A resin cement (RelyX Unicem) was then used for bonding, and then a notched shear bond strength test (nSBS) was performed. Failure modes were observed and classified as adhesive, cohesive, or mixed, and SEM representative images were taken. Data were statistically analyzed with one-way ANOVA, Tukey, and Chi-square tests. Significant differences were detected in nSBS among materials (p < 0.001). The highest nSBS was found in VM (30.3 ± 1.8 MPa) a, followed by CPb, GBbc, CPbc, and VEc. Failure modes were significantly different (p < 0.001), and with different prevalent failure modes. The bond strength for 3D-printed permanent resin materials was shown to be lower than that of the felspathic ceramic but comparable to that of the resin block and PICN substrates. Full article
(This article belongs to the Special Issue Advanced Polymer Coatings: Materials, Methods, and Applications)
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28 pages, 3834 KiB  
Article
An Exact 3D Shell Model for Free Vibration Analysis of Magneto-Electro-Elastic Composite Structures
by Salvatore Brischetto, Domenico Cesare and Tommaso Mondino
J. Compos. Sci. 2025, 9(8), 399; https://doi.org/10.3390/jcs9080399 - 1 Aug 2025
Viewed by 104
Abstract
The present paper proposes a three-dimensional (3D) spherical shell model for the magneto-electro-elastic (MEE) free vibration analysis of simply supported multilayered smart shells. A mixed curvilinear orthogonal reference system is used to write the unified 3D governing equations for cylinders, cylindrical panels and [...] Read more.
The present paper proposes a three-dimensional (3D) spherical shell model for the magneto-electro-elastic (MEE) free vibration analysis of simply supported multilayered smart shells. A mixed curvilinear orthogonal reference system is used to write the unified 3D governing equations for cylinders, cylindrical panels and spherical shells. The closed-form solution of the problem is performed considering Navier harmonic forms in the in-plane directions and the exponential matrix method in the thickness direction. A layerwise approach is possible, considering the interlaminar continuity conditions for displacements, electric and magnetic potentials, transverse shear/normal stresses, transverse normal magnetic induction and transverse normal electric displacement. Some preliminary cases are proposed to validate the present 3D MEE free vibration model for several curvatures, materials, thickness values and vibration modes. Then, new benchmarks are proposed in order to discuss possible effects in multilayered MEE curved smart structures. In the new benchmarks, first, three circular frequencies for several half-wave number couples and for different thickness ratios are proposed. Thickness vibration modes are shown in terms of displacements, stresses, electric displacement and magnetic induction along the thickness direction. These new benchmarks are useful to understand the free vibration behavior of MEE curved smart structures, and they can be used as reference for researchers interested in the development of of 2D/3D MEE models. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
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18 pages, 3738 KiB  
Article
Effect of Alternate Sprinkler Irrigation with Saline and Fresh Water on Soil Water–Salt Transport and Corn Growth
by Yue Jiang, Luya Wang, Yanfeng Li, Hao Li and Run Xue
Agronomy 2025, 15(8), 1854; https://doi.org/10.3390/agronomy15081854 - 31 Jul 2025
Viewed by 259
Abstract
To address freshwater scarcity and the underutilization of low-saline water in the North China Plain, a field study was conducted to evaluate the effects of alternating sprinkler irrigation using saline and fresh water on soil water–salt dynamics and corn growth. Two salinity levels [...] Read more.
To address freshwater scarcity and the underutilization of low-saline water in the North China Plain, a field study was conducted to evaluate the effects of alternating sprinkler irrigation using saline and fresh water on soil water–salt dynamics and corn growth. Two salinity levels (3 and 5 g·L−1, representing S1 and S2, respectively) and three irrigation strategies—saline–fresh–saline–fresh (F1), saline–fresh (F2), and mixed saline–fresh (F3)—were tested, resulting in six treatments: S1F1, S1F2, S1F3, S2F1, S2F2, and S2F3. S1F1 significantly improved soil water retention at a 30–50 cm depth and reduced surface electrical conductivity (EC) and Na+ concentration (p < 0.05). S1F1 also promoted more uniform Mg2+ distribution and limited Ca2+ loss. Under high salinity (5 g·L−1), surface salt accumulation and ion concentration (Na+, Mg2+, and Ca2+) increased, particularly in S2F3. Corn growth under alternating irrigation (F1/F2) outperformed the mixed mode (F3), with S1F1 achieving the highest plant height, leaf area, grain number, and 100-grain weight. The S1F1 yield surpassed others by 0.4–3.0% and maintained a better ion balance. These results suggest that alternating irrigation with low-salinity water (S1F1) effectively regulates root-zone salinity and improves crop productivity, offering a practical strategy for the sustainable use of low-saline water resources. Full article
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26 pages, 3459 KiB  
Article
Compressive Behaviour of Sustainable Concrete-Filled Steel Tubes Using Waste Glass and Rubber Glove Fibres
by Zobaer Saleheen, Tatheer Zahra, Renga Rao Krishnamoorthy and Sabrina Fawzia
Buildings 2025, 15(15), 2708; https://doi.org/10.3390/buildings15152708 - 31 Jul 2025
Viewed by 111
Abstract
To reduce the carbon footprint of the concrete industry and promote a circular economy, this study explores the reuse of waste materials such as glass powder (GP) and nitrile rubber (NR) fibres in concrete. However, the inclusion of these waste materials results in [...] Read more.
To reduce the carbon footprint of the concrete industry and promote a circular economy, this study explores the reuse of waste materials such as glass powder (GP) and nitrile rubber (NR) fibres in concrete. However, the inclusion of these waste materials results in lower compressive strength compared to conventional concrete, limiting their application to non-structural elements. To overcome this limitation, this study adopts the concept of confined concrete by developing concrete-filled steel tube (CFST) stub columns. In total, twelve concrete mix variations were developed, with and without steel tube confinement. GP was utilised at replacement levels of 10–30% by weight of cement, while NR fibres were introduced at 0.5% and 1% by volume of concrete. The findings demonstrate that the incorporation of GP and NR fibres leads to a reduction in compressive strength, with a compounded effect observed when both materials are combined. Steel confinement within CFST columns effectively mitigated the strength reductions, restoring up to 17% of the lost capacity and significantly improving ductility and energy absorption capacity. All CFST columns exhibited consistent local outward buckling failure mode, irrespective of the concrete mix variations. A comparison with predictions from existing design codes and empirical models revealed discrepancies, underscoring the need for refined design approaches for CFST columns incorporating sustainable concrete infill. This study contributes valuable insights into the development of eco-friendly, high-performance structural systems, highlighting the potential of CFST technology in facilitating the adoption of waste materials in the construction sector. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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26 pages, 4949 KiB  
Article
Sustainable Mobility in Barcelona: Trends, Challenges and Policies for Urban Decarbonization
by Carolina Sifuentes-Muñoz, Blanca Arellano and Josep Roca
Sustainability 2025, 17(15), 6964; https://doi.org/10.3390/su17156964 - 31 Jul 2025
Viewed by 168
Abstract
The Barcelona Metropolitan Area (AMB) has implemented various policies to reduce car use and promote more sustainable mobility. Initiatives such as superblocks, Low Emission Zones (LEZs), and the Bicivia network aim to transform the urban model in response to environmental and congestion challenges. [...] Read more.
The Barcelona Metropolitan Area (AMB) has implemented various policies to reduce car use and promote more sustainable mobility. Initiatives such as superblocks, Low Emission Zones (LEZs), and the Bicivia network aim to transform the urban model in response to environmental and congestion challenges. However, the high reliance on private vehicles for intermunicipal travel, uneven infrastructure, and social resistance to certain changes remain significant issues. This study examines the evolution of mobility patterns and assesses the effectiveness of the above policies in fostering real and sustainable change. A mixed-methods approach was adopted, which combined an exploratory factor analysis (EFA) of 2011–2024 data, trend linear regression, and a comparative international analysis. The EFA identified four key structural dimensions: traditional transport infrastructure, active mobility and bus lines, public bicycles and mixed use, and transport efficiency and punctuality. The findings reveal a clear reduction in private car use and an increase in sustainable modes of transport. This indicates that there are prospects for future transformation. Nonetheless, challenges persist in intermunicipal mobility and the public acceptance of the measures. This study provides empirical and comparative evidence and emphasizes the need for integrated metropolitan governance to achieve a resilient and sustainable urban model. Full article
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13 pages, 1009 KiB  
Article
A Statistical Optimization Method for Sound Speed Profiles Inversion in the South China Sea Based on Acoustic Stability Pre-Clustering
by Zixuan Zhang, Ke Qu and Zhanglong Li
Appl. Sci. 2025, 15(15), 8451; https://doi.org/10.3390/app15158451 - 30 Jul 2025
Viewed by 168
Abstract
Aiming at the problem of accuracy degradation caused by the mixing of spatiotemporal disturbance patterns in sound speed profile (SSP) inversion using the traditional geographic grid division method, this study proposes an acoustic stability pre-clustering framework that integrates principal component analysis and machine [...] Read more.
Aiming at the problem of accuracy degradation caused by the mixing of spatiotemporal disturbance patterns in sound speed profile (SSP) inversion using the traditional geographic grid division method, this study proposes an acoustic stability pre-clustering framework that integrates principal component analysis and machine learning clustering. Disturbance mode principal component analysis is first used to extract characteristic parameters, and then a machine learning clustering algorithm is adopted to pre-classify SSP samples according to acoustic stability. The SSP inversion experimental results show that: (1) the SSP samples of the South China Sea can be divided into three clusters of disturbance modes with statistically significant differences. (2) The regression inversion method based on cluster attribution reduces the average error of SSP inversion for data from 2018 to 1.24 m/s, which is more than 50% lower than what can be achieved with the traditional method without pre-clustering. (3) Transmission loss prediction verification shows that the proposed method can produce highly accurate sound field calculations in environmental assessment tasks. The acoustic stability pre-clustering technology proposed in this study provides an innovative solution for the statistical modeling of marine environment parameters by effectively decoupling the mixed effect of SSP spatiotemporal disturbance patterns. Its error control level (<1.5 m/s) is 37% higher than that of the single empirical orthogonal function regression method, showing important potential in underwater acoustic applications in complex marine dynamic environments. Full article
(This article belongs to the Section Acoustics and Vibrations)
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33 pages, 4686 KiB  
Article
Modeling of Dynamics of Nonideal Mixer at Oscillation and Aperiodic Damped Mode of Driving Member Motion
by Kuatbay Bissembayev, Zharilkassin Iskakov, Assylbek Jomartov and Akmaral Kalybayeva
Appl. Sci. 2025, 15(15), 8391; https://doi.org/10.3390/app15158391 - 29 Jul 2025
Viewed by 242
Abstract
The dynamics of the vibrational mode of motion of the driving member of a nonideal system, a mixing–whipping device based on a simple slide-crank mechanism, was studied. The highly nonlinear differential equations of motion were solved numerically by the Runge–Kutta method. The interaction [...] Read more.
The dynamics of the vibrational mode of motion of the driving member of a nonideal system, a mixing–whipping device based on a simple slide-crank mechanism, was studied. The highly nonlinear differential equations of motion were solved numerically by the Runge–Kutta method. The interaction of the mixing–whipping device with the nonideal excitation source causes the rotational speed of the engine shaft and the rotation angle of the driving member to fluctuate, accomplishing a damped process. The parameters of the device and the nonideal energy source have an effect on the kinematic, vibrational and energy characteristics of the system. An increase in the engine’s torque, crank length, number and radius of piston holes, and piston mass, as well as a decrease in the fluid’s density, leads to a reduction in the oscillation range of the crank angle, amplitude and period of angular velocity oscillations of the engine shaft and the mixing–whipping force power. The effects of a nonideal energy source may be used in designing a mixing–whipping device based on a slider-crank mechanism to select effective system parameters and an energy-saving motor in accordance with the requirements of technological processes and products. Full article
(This article belongs to the Special Issue Dynamics and Vibrations of Nonlinear Systems with Applications)
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17 pages, 1725 KiB  
Article
Ring Opening upon Valence Shell Excitation in β-Butyrolactone: Experimental and Theoretical Methods
by Pedro A. S. Randi, Márcio H. F. Bettega, Nykola C. Jones, Søren V. Hoffmann, Małgorzata A. Śmiałek and Paulo Limão-Vieira
Molecules 2025, 30(15), 3137; https://doi.org/10.3390/molecules30153137 - 26 Jul 2025
Viewed by 256
Abstract
The valence-shell electronic state spectroscopy of β-butyrolactone (CH3CHCH2CO2) is comprehensively investigated by employing experimental and theoretical methods. We report a novel vacuum ultraviolet (VUV) absorption spectrum in the photon wavelength range from 115 to 320 nm (3.9–10.8 [...] Read more.
The valence-shell electronic state spectroscopy of β-butyrolactone (CH3CHCH2CO2) is comprehensively investigated by employing experimental and theoretical methods. We report a novel vacuum ultraviolet (VUV) absorption spectrum in the photon wavelength range from 115 to 320 nm (3.9–10.8 eV), together with ab initio quantum chemical calculations at the time-dependent density functional (TD-DFT) level of theory. The dominant electronic excitations are assigned to mixed valence-Rydberg and Rydberg transitions. The fine structure in the CH3CHCH2CO2 photoabsorption spectrum has been assigned to C=O stretching, v7a, CH2 wagging, v14a, C–O stretching, v22a, and C=O bending, v26a modes. Photolysis lifetimes in the Earth’s atmosphere from 0 km up to 50 km altitude have been estimated, showing to be a non-relevant sink mechanism compared to reactions with the OH radical. The nuclear dynamics along the C=O and C–C–C coordinates have been investigated at the TD-DFT level of theory, where, upon electronic excitation, the potential energy curves show important carbonyl bond breaking and ring opening, respectively. Within such an intricate molecular landscape, the higher-lying excited electronic states may keep their original Rydberg character or may undergo Rydberg-to-valence conversion, with vibronic coupling as an important mechanism contributing to the spectrum. Full article
(This article belongs to the Special Issue Advances in Density Functional Theory (DFT) Calculation)
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20 pages, 3102 KiB  
Article
Ultrasonographic Evaluation of Labor Patterns: A Prospective Cohort Study in Greece
by Kyriaki Mitta, Ioannis Tsakiridis, Andriana Virgiliou, Apostolos Mamopoulos, Hristiana Capros, Apostolos Athanasiadis and Themistoklis Dagklis
J. Clin. Med. 2025, 14(15), 5283; https://doi.org/10.3390/jcm14155283 - 25 Jul 2025
Viewed by 299
Abstract
Background/Objectives: Recent changes in obstetric practices and population demographics have prompted a re-evaluation of labor patterns. This study aimed to characterize labor patterns in a Greek pregnant population using ultrasound and compare them with established labor curves. Methods: A prospective cohort study was [...] Read more.
Background/Objectives: Recent changes in obstetric practices and population demographics have prompted a re-evaluation of labor patterns. This study aimed to characterize labor patterns in a Greek pregnant population using ultrasound and compare them with established labor curves. Methods: A prospective cohort study was conducted at the Third Department of Obstetrics and Gynecology, School of Medicine, Faculty of Health Sciences, Aristotle University of Thessaloniki, Greece, over a two-year period (December 2022 to June 2024). Transabdominal ultrasound was used to determine the fetal head position and transperineal ultrasound was used to measure angle of progression (AoP) and head–perineum distance (HPD) during labor. Maternal and labor characteristics, including body mass index (BMI), parity, labor duration, and mode of delivery, were recorded. Statistical analysis included mixed linear models to assess the relationship between AoP, HPD, and cervical dilatation. Results: In total, 500 parturients were included in this study. Women entered the active phase of labor approximately 5 h before delivery, with AoP increasing sharply and HPD decreasing rapidly at this point. Cesarean section (CS) cases showed a slower increase in AoP compared to vaginal deliveries (VDs), with CS cases having a mean AoP of 117.9° (95% CI: 111.6–124.2°) at full dilation, compared to 133.4° (95% CI: 130.6–136.2°) in VD. HPD values declined more slowly in CS cases, with a mean HPD of 45.1 mm (95% CI: 40.6–49.6 mm) at full dilation, compared to 36.4 mm (95% CI: 34.3–38.5 mm) in VD. Epidural analgesia was associated with steeper increases in AoP and decreases in HPD in the final 2.5 h before delivery, while oxytocin administration accelerated these changes in the last 3–4 h. The mean time to delivery was 3.19 h (95% CI: 2.80–3.59 h) when AoP reached 125° and 3.92 h when HPD was 40 mm (95% CI: 3.53–4.30 h). BMI in women who gave birth via CS was significantly higher compared to VD (32.03 vs. 29.94 kg/m2, p-value: 0.008), and the total duration of labor was shorter in VD compared to CS and operative vaginal delivery (OVD) (8 h vs. 15 h, p-value < 0.001 and 8 h vs. 12 h, p-value < 0.001, respectively). Birthweight was also lower in VD compared to CS (3103.09 g vs. 3267.88 g, p-value: 0.05). Conclusions: This study provides the first ultrasonographic characterization of labor patterns in a Greek population, highlighting the utility of ultrasound in objectively assessing labor progression. Full article
(This article belongs to the Section Obstetrics & Gynecology)
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