Search Results (2,168)

The Jiaduoling area is located in the northern segment of the Southwest Sanjiang Metallogenic Belt, a region characterized by complex geological structures and abundant mineral resources. This study systematically identifies the spatial correlation between subsurface magnetic bodies and tectonic structures by utilizing 1:50,000 high-precision aeromagnetic data. Advanced processing techniques—including upward continuation, vertical derivatives, total gradient modulus, and Euler deconvolution—were integrated to refine the structural framework and clarify the mechanisms of fault-controlled mineralization. The results indicate that the aeromagnetic anomaly pattern is predominantly governed by NW-trending faults. Specifically, the deep-seated major fault F₁ (with a calculated depth exceeding 3 km) served as the primary migration channel for ore-forming fluids, while secondary faults created localized ore-hosting spaces. Physical property analysis reveals a significant magnetic contrast, where Mesozoic intermediate-acid magmatic rocks act as the essential source for mineralization, providing both material and thermal energy for the formation of porphyrite-type iron deposits. Based on these findings, a three-dimensional “aeromagnetic anomaly-structural framework-mineralization” correlation model was established. Finally, two high-potential metallogenic prospective zones (P1 and P2) were delineated, providing precise geophysical evidence and strategic guidance for regional mineral exploration and the targeting of concealed ore bodies. Full article

The rapid expansion of high-protein dairy-based powders (HPDPs), including milk protein concentrates and isolates (MPC/MPI), whey protein concentrates and isolates (WPC/WPI), and micellar casein concentrates and isolates (MCC/MCI), has intensified the need to understand instability phenomena that emerge during processing and storage. These products are governed by protein-rich amorphous matrices, in which molecular mobility, interfacial composition, and mineral interactions dictate both physical stability and functional performance. Importantly, these physical instabilities are directly coupled with functional deterioration, particularly in terms of impaired wetting, dispersion, and dissolution during rehydration. This review presents an integrated mechanistic framework linking these instability phenomena across processing, storage, and reconstitution, thereby consolidating concepts that remain fragmented across the current literature on high-protein dairy matrices. Key controlling factors include glass transition temperature (Tg), water activity-induced plasticization, protein–protein and protein–mineral interactions, and surface compositional heterogeneity established during spray drying. These factors govern the progression from surface stickiness through uncontrolled agglomeration to caking, forming a consolidation continuum. In contrast to lactose-driven matrices, caking and agglomeration in HPDPs arise primarily from protein-mediated restructuring and inter-particle bonding, with lactose crystallization acting only as a secondary mechanism in mixed-composition grades. The review further distinguishes engineered agglomeration from storage-induced consolidation and evaluates advances in molecular mobility characterization and Tg-based stability mapping. Significant gaps remain in linking localized surface evolution, mineral redistribution, and inter-particle bridge chemistry under realistic environmental conditions. The review concludes by proposing a mobility-centered “stability-by-design” framework that integrates composition, processing, particle architecture, and storage conditions to guide the development of future HPDPs with improved physical stability and functional recovery. Full article

This study evaluated the effects of dietary supplementation with dried Haematococcus pluvialis biomass on egg quality in laying hens using a multilevel analytical approach. A total of 100 ISA Brown hens were divided into two groups: a control group (CTRL) fed a basal diet and an experimental group (HP) receiving the same diet supplemented with 0.075% H. pluvialis. Supplementation did not significantly affect most physical egg parameters, although yolk index and yolk height were improved in the HP group. A marked increase in yolk pigmentation was observed, with values reaching 15 on the DSM color fan compared to 8.4 in CTRL (p < 0.0001). Significant enhancements in yolk nutritional quality were detected, including increased total carotenoids and the presence of astaxanthin exclusively in the HP group. Mineral composition was also markedly affected, with significant increases in essential elements such as Fe, Mg, Zn, I, and P in both albumen and yolk. The fatty acid profile was favorably modulated, showing a reduction in saturated fatty acids and an increase in monounsaturated fatty acids, along with improved nutritional indices (AI, TI, HH). Instrumental sensory analysis revealed clear discrimination between groups based on color (E-eye), while differences in volatile profiles (E-nose) were less pronounced. However, a reduction in oviposition rate and egg mass was observed in the supplemented group. Overall, the inclusion of H. pluvialis biomass represents an effective strategy for the natural biofortification of eggs, improving their nutritional and functional value. Full article

Naranjilla (Solanum quitoense Lam.) is an Andean fruit crop of high economic and nutraceutical value, appreciated for its acidic-aromatic flavour and its contents of carotenoids, vitamin C and phenolic compounds. However, naranjilla production is constrained by susceptibility to pests and diseases, which has promoted the use of wild relatives from section Lasiocarpa in breeding programmes. The objective of this study was to characterise the physical, chemical, mineral and antioxidant attributes of 21 naranjilla materials developed in Ecuador and to identify elite segregants using multivariate approaches. Significant differences were observed among segregants for all evaluated variables. Antioxidant capacity, together with polyphenols and flavonoids, explained the largest proportion of total variation, whereas soluble solids and acidity were associated with organoleptic quality. Segregant P40 stood out due to its high antioxidant activity, soluble solids content and fruit weight; hence, it was identified as the most outstanding elite material. These results confirm the potential of naranjilla breeding in improving both yield and fruit quality. Full article

Hyperspectral imaging (HSI) provides rich spatial and spectral information for remote sensing, mineral exploration, and biomedical analysis, but its limited spatial resolution and sensor imperfections lead to blurred, noisy, and mixed-pixel observations. Addressing these degradations jointly—rather than sequentially—has been shown to improve physical interpretability, yet existing joint deblurring–unmixing methods rely primarily on hand-crafted regularizers that do not fully exploit spatial–spectral structure. Meanwhile, recent plug-and-play (PnP) approaches applied to HSI leverage deep priors but focus solely on either deconvolution or unmixing in isolation. To bridge this gap, we formulate the joint inverse problem of hyperspectral deblurring and spectral unmixing and propose, to our knowledge, the first plug-and-play framework tailored for this coupled task using the Alternating Direction Method of Multipliers (ADMM) and a pretrained deep denoiser (DnCNN) as an implicit PnP prior. Our method uses the natural splitting properties of ADMM to separate a physics-driven subproblem that enforces fidelity to the hyperspectral forward model, which includes linear mixing and blur under a linear, space-invariant convolution approximation, from the data-driven prior step. This synergy of model-based fidelity and learned spatial prior enables more accurate abundance estimates than those obtained with approaches relying solely on analytical regularizers. Experimental results on real hyperspectral datasets demonstrate that the proposed Plug-and-Play Joint Deconvolution and Unmixing (PnP-JDU) method outperforms conventional unmixing baselines, stand-alone PnP unmixing methods, and the Deblurring and Sparse Unmixing via the Alternating Direction Method with Total Variation (DSUnADM-TV) baseline in reconstruction and abundance accuracy metrics. Across the tested datasets and imaging conditions, PnP-JDU achieves lower RMSE, higher PSNR, lower reconstruction and abundance errors, and lower SAD values, while preserving fine spatial details and producing physically meaningful abundance maps. Full article

This study investigated the impact of recreational use on trails in the Atlantic Forest (Ubatuba Municipality, São Paulo State, Brazil) using physical, chemical and geochemical indicators. Five trails with different morphological characteristics were selected, and paired samples were collected from the trail surface (TR) and trail-side slope (TA). The statistical approach combined local analyses for each trail with global clustering (n = 19) using Student’s t-test, along with multivariate modeling through Principal Component Analysis (PCA) and Pearson correlation. The analysis included physical attributes (bulk density, particle size and porosity), chemical attributes (pH, organic matter and macronutrients) and geochemical compositions (major oxides and trace elements determined by XRF). The overall results reveal systematic compaction in the trail surface (TR), with bulk density increasing from 1.32 g/cm³ (TA) to 1.37 g/cm³ (TR) (p = 0.038), and total porosity decreasing from 47.26% to 45.34% (p = 0.016). In contrast, the geochemical oxide composition (SiO₂, Al₂O₃, Fe₂O₃) remained stable (p > 0.05), indicating the resilience of the mineral matrix. However, significant local dynamics (p < 0.05) in K₂O and MgO were observed in more preserved trails, associated with surface compaction and fragmentation of the litter layer, and phosphorus showed strong dependence on organic matter (r = 0.85). Multivariate analysis indicates that degradation is predominantly physical and micromorphological at the local scale, with bulk density and porosity being the most sensitive indicators for environmental monitoring. Full article

The steel industry is currently grappling with the dual environmental challenges of massive steel slag accumulation and carbon emissions. To address the limitations of traditional carbonation processes—namely slow reaction kinetics and insufficient mechanical properties—this study proposes a novel rapid carbonation enhancement method coupling microwave thermal field intensification, silicon carbide (SiC) physical absorption, and potassium silicate chemical activation. The effects of microwave heating parameters on the performance of carbonated steel slag blocks were systematically investigated. The results indicate a significant synergistic effect between the microwave thermal effect and the alkali-activated system. Under the conditions of a 0.14 liquid-to-solid ratio and microwave heating at 90 °C for 45 min, the compressive strength reached a peak of 48.82 MPa (a 44.7% increase over the conventional treatment group). Microstructural characterization revealed the reinforcement mechanism: the introduction of SiC and potassium silicate solution (K₂SiO₃) under microwave heating promotes a denser distribution of carbonation products. Synchronized with alkali activation, this effect promotes the in-situ growth of dense calcite crystals within a gel network, thereby significantly optimizing the pore structure (e.g., reducing the average pore size to 43 nm), and enhancing strength through synergistic effects. This research is subject to further energy and life-cycle assessments, and this approach holds potential for CO₂ mineralization and the recycling of steel slag. Full article

With the development of deep Earth engineering, the stability of surrounding rocks subjected to high temperatures from fire hazards has become an increasingly prominent issue. Therefore, studying the physical and mechanical properties of rocks under different thermal treatment modes is of great significance for the design of underground engineering. Taking red sandstone as the research object, this paper conducts physical parameter tests, uniaxial compression tests, and X-ray diffraction (XRD) on specimens under real-time high temperatures and natural cooling in the range of 600–1000 °C, to analyze the variations in specimen composition, the correlation between physical and mechanical properties and temperature, and to explore the underlying mechanisms. The results show that under both real-time high temperatures and natural cooling, the volume of sandstone increases while the mass decreases with rising temperature. At 1000 °C, the volume expansion rates are 3.30% and 3.80%, and the mass loss rates are 6.30% and 5.60%, respectively. Mechanical parameters, including peak strength, elastic modulus, and peak strain under the two treatments, all deteriorate significantly compared with those at room temperature. At 1000 °C, peak strength decreases by 54.83% and 36.26%, elastic modulus decreases by 74.55% and 67.96%, and peak strain increases by 65.63% and 43.75%, respectively. High-temperature-induced changes in the internal mineral structure and composition of sandstone are the main causes of rock mechanical property deterioration. During the cooling process, thermal shrinkage and recrystallization of mineral particles densify the rock structure; therefore, the compressive strength of naturally cooled sandstone is higher than that under real-time high temperatures. This study can provide theoretical guidance for the repair and reinforcement of rock engineering after high-temperature action. Full article

Mineral scaling on carbon electrodes remains a critical limitation to the long-term performance of capacitive deionization (CDI) systems treating hard and alkaline waters. In this study, alternating polarization (AP) is investigated as an in situ electrochemical regeneration strategy to reverse cathodic scaling in flow-through CDI treating a feed containing 5 mM NaCl, 5 mM NaHCO₃, and 2.5 mM CaCl₂ under three modes: conventional cycling (control), delayed AP introduced after fouling developed, and immediate AP implemented from the first cycle. Under conventional operation, cathodic scaling reduced the salt adsorption capacity (SAC) to 5.9 ± 0.2 mg/g, increased cathode mass from 0.208 ± 0.004 g (pristine) to 0.353 ± 0.054 g, and decreased specific capacitance to 28 ± 2 F/g, accompanied by extensive pore blockage and carbonate deposition observed by SEM and BET measurements. Application of delayed AP restored electrode functionality, increasing SAC to 8.9 ± 0.6 mg/g and specific capacitance to 56 ± 2 F/g while reducing the cathode mass to 0.212 ± 0.007 g and removing surface precipitates. The immediate AP operation reduced the extent of scale formation from cycle 1, maintaining SAC at 8.4 ± 0.2 mg/g throughout operation, with stable physical and electrochemical properties. These improvements are attributed to periodic polarity reversal, which induces alternating alkaline and acidic microenvironments at the electrode surface and promotes the electrochemical dissolution of carbonate phases during anodic polarization. Overall, this work establishes AP as a simple, chemical-free operational strategy for both preventing and reversing cathodic mineral scaling, thereby enabling sustained CDI performance and mitigating capacity loss over the tested operational periods in complex water matrices. Full article

Saimaluu-Tash I, located in a high-altitude glacial valley in Kyrgyzstan, preserves one of Central Asia’s largest and most culturally significant concentrations of rock engravings. Despite extensive archaeological research, the physical, mechanical, and chromatic properties of the sandstone substrates relevant for conservation assessment remain poorly characterized. This study integrates petrographic microscopy, scanning electron microscopy, colorimetry, and Vickers hardness testing with the digital documentation of twelve engraved blocks to evaluate weathering processes, engraving practices, and long-term preservation. The engravings are carved into arkosic sandstone with carbonate cement, characterized by a weathered surface enriched in clay minerals and covered by a dark surface coating (patina). Weathered surfaces exhibit significantly lower hardness (0.6 ± 0.2 GPa) than unweathered stone (2.8 ± 0.6 GPa), which facilitated the engraving of the petroglyphs by allowing tools to penetrate more deeply into the stone. Colorimetric analyses reveal a strong chromatic contrast between the surface patina and the lighter sandstone exposed by engraving (ΔE ≈ 22.7). This contrast would have enhanced the original visibility of the petroglyphs and highlights potential conservation issues associated with the progressive reformation of this surface layer. Iconographic analysis identifies recurrent themes related to hunting, herding, mobility, animal management, and symbolic spatial practices within a nomadic high-mountain landscape. Overall, the results demonstrate how an integrated material and interpretative approach contributes to understanding rock art production processes. They support preventive and sustainable conservation strategies for vulnerable engraving landscapes shaped by long-term interactions between geological processes and human activity. Full article

Background/Objectives: Linear growth in children reflects cumulative influences of nutrition, health, and skeletal development. Vitamin K₂, particularly menaquinone-7 (MK-7), plays an important role in bone mineralization, yet evidence regarding its potential relationship with height growth in children remains limited. This study evaluated the association between continuous MK-7 supplementation and longitudinal height growth in children. Methods: A longitudinal observational study was conducted among 1150 apparently healthy children aged 6–14 years in Hanoi, Vietnam (2022–2025), including 613 controls and 537 children receiving MK-7 supplementation. MK-7 was administered orally at 360 µg/day from baseline throughout follow-up. A total of 3491 repeated height measurements were collected. Analyses were stratified according to pubertal stage (no-puberty and pre-puberty). Height gain was summarized according to follow-up duration, and initial mixed-effects models were used to explore longitudinal growth trajectories. Because substantial follow-up imbalance was observed after the first follow-up assessment, the primary regression analyses were subsequently restricted to baseline and first follow-up observations. Multivariable linear regression models evaluated the interaction between MK-7 supplementation and follow-up duration after adjustment for age, sex, baseline body mass index-for-age Z-score, early sleep, and physical activity. Results: Height gain increased significantly with follow-up duration across all analyses (β range: 0.49–0.58 cm/month; all p < 0.001). MK-7 supplementation alone was not independently associated with height gain; however, positive interactions between MK-7 supplementation and follow-up duration were observed in several subgroup analyses. In the overall cohort, the interaction estimate was β = 0.05 cm/month (95% CI: 0.02–0.09). Positive interactions were observed in no-puberty children (β = 0.05; 95% CI: 0.01–0.09) and pre-puberty children (β = 0.06; 95% CI: 0.03–0.09). The largest interaction estimate was observed among pre-puberty boys (β = 0.10; 95% CI: 0.07–0.13), whereas no statistically significant interaction was observed among girls in the pre-puberty subgroup. Conclusions: The findings suggest that continuous MK-7 supplementation may be associated with progressively greater height gain over time rather than an immediate increase in height. The observed associations appeared more evident with longer follow-up duration, particularly among pre-pubertal boys. However, given the observational design and substantial follow-up imbalance between groups, the findings should be interpreted cautiously. Further prospective studies with balanced longitudinal follow-up are needed to clarify the potential relationship between MK-7 supplementation and pediatric linear growth. Full article

Backfilling the industrial solid waste coal gangue into deep coal mine goafs for CO₂ geological sequestration is a crucial pathway to achieve the synergistic effect of pollution reduction and carbon mitigation. However, in complex deep geological environments, the chemical evolution of multiple mineral phases of coal gangue under gas–water–rock coupling effects and the carbon-controlling mechanism of residual total organic carbon (TOC) remain unclear. In this study, coal gangue from the goaf of the Xiaobaodang Coal Mine was used as the research object. Relying on a customized high-temperature and high-pressure reaction system to simulate the deep in situ environment (45 °C, 10 MPa), and combined with X-ray diffraction (XRD), total organic carbon determination, and isothermal CO₂ adsorption experiments, the geochemical mechanism by which inorganic minerals and organic residual carbon synergistically control the ultimate CO₂ adsorption potential was systematically revealed. The results show that the modification of the CO₂ adsorption potential of coal gangue by gas–water–rock reactions exhibits strong mineral phase differentiation. Systems rich in active silicates generate a large amount of secondary clay minerals through intense carbonation alteration, achieving a significant increase in micro–nano pores and absolute adsorption capacity. Systems rich in carbonates steadily release deep primary adsorption potential by widening mass transfer channels through mineral dissolution. In contrast, systems rich in primary clay minerals face an irreversible attenuation of adsorption space due to physical clogging of pore throats caused by fluid migration. Furthermore, the initial organic carbon content exerts a significant non-linear regulatory effect on the development of the micropore network. The physical adsorption sites provided by the high relative content of layered clay minerals (>41%), coupled with the interfacial enhancement effect exerted by a moderate organic carbon content (0.12~0.16%), constitute an optimal physicochemical synergistic enhancement network, which is the core geological reason for stimulating the ultimate carbon sequestration capacity of coal gangue. The results of this study not only enrich the multiphase interfacial thermodynamic theory of complex heterogeneous geological bodies but also provide solid theoretical support for the precise optimization of target areas and the long-term evaluation of carbon sinks in goaf CO₂ sequestration engineering. Full article

Infectious prion adsorption on metal, minerals, wood, and plastic is well documented, raising the specter of food safety hazards for meat packing workers, sport hunters, and consumers. We previously demonstrated that sodium hypochlorite, and to a lesser extent, potassium peroxymonosulfate, and hypochlorous acid can decontaminate prion-contaminated nonporous surfaces. However, the extent to which chemical aging of surfaces affects subsequent recoverable prion seeding activity is unknown. In this study, we investigated the potential for four chemical decontaminants known for their anti-prion activity (sodium hypochlorite [bleach], hypochlorous acid [Briotech], potassium peroxymonosulfate [Virkon-S], and Wex-Cide-128) to alter the surfaces of steel knives and the subsequent prion decontamination efficacy of each. We found that hypochlorous acid, sodium hypochlorite, and potassium peroxymonosulfate corrode the surfaces of steel knives, resulting in significant physical alterations. Knives exposed to hypochlorous acid exhibited the most substantial corrosion (rust), which is consistent with its oxidizing effects. Oxidation of the knife surface was corroborated by complementary energy-dispersive X-ray spectroscopy data trends. Scanning electron microscopy data indicate corrosion is apparent after minimal exposure to oxidizing agents. Finally, we used the real-time quaking-induced conversion assay on swabs collected from chemically aged knife surfaces to evaluate recoverable surface-associated CWD-prion seeding activity detected by RT-QuIC after prion exposure and decontamination. Our results indicate decreased recoverable prion seeding activity from knife surfaces aged with 40% bleach. We also observed some recoverable seeding activity post-decontamination on knives chemically aged with 10% bleach and Wex-Cide-128, but largely similar efficacy to prior studies. This implies that existing chemical prion decontaminants are likely effective after repeated use on steel surfaces. Full article

In the Anthropocene, the environmental crisis necessitates a radical repositioning of the human-nature relationship. This paper examines the sijo poetry in Musan Cho Oh-hyun’s For Nirvana through an interdisciplinary framework bridging Zen philosophy with material ecocriticism. The study elucidates how Musan deconstructs anthropocentric exceptionalism by restoring agency to the non-human world. Textual analysis reveals three arguments. First, elemental forces like wind and waves are subjectified as primordial teachers through mujō-seppō (non-sentient beings preaching the Dharma), dismantling sovereign human scriptural authority. Second, visceral encounters with animals and insects critique logocentric domination, proposing “epistemological silence” and “radical humility” as alternative eco-politics. Finally, bodily decay and trans-corporeal porosity are reframed as generative pathways toward a radical “ecological Nirvana”—a physical matrix of cyclical renewal. By synthesizing Jane Bennett’s vital materialism with Dōgen’s Zen vision of “walking mountains”, this study deploys a Zen materialism lens that enriches Western theory with the Buddhist soteriology of compassion (karuna). Ultimately, Musan reconfigures Nirvana not as an escapist transcendence, but as a profound somatic descent into the material mesh, where ultimate spiritual realization lies in the ego’s total dissolution into the “walking, talking minerals” of a sacred, suffering ecosystem. Full article

In recent years, synergistic effects between inorganic clay minerals (e.g., montmorillonite, sepiolite, kaolinite) and bio-based flame retardants (e.g., chitosan-based, lignin-based, phytate-based) have achieved certain progress in the area of polymer flame retardancy. The effects of bio-based flame retardants are exerted through mechanisms such as catalytic char generation and vapour-phase hindrance. However, they have limitations when used alone, including insufficient thermal stability and the need for a high dosage. Inorganic clays form physical barriers through their layered or tubular structures. The high thermal stability of these structures suppresses heat and mass transfer, thereby offsetting the shortcomings of bio-based flame retardants. This synergistic combination greatly improves the flame retardancy of polymer composites, often strengthening their mechanical performance in the process. It therefore offers great potential for the design of multifunctional, eco-friendly flame-retardant polymer composites. Nevertheless, a systematic review of the synergistic mechanisms, fabrication approaches and application progress of different inorganic clay minerals when combined with various bio-based flame retardants is still lacking. Therefore, this article offers a comprehensive review of the current developments of synergistic systems that incorporate various primary clays, such as sepiolite and montmorillonite, with bio-based flame retardants for usage in polymers. Before this, the synergistic flame-retardant mechanism and the key preparation techniques of the composite system were explained in detail. Finally, this article puts forward solutions to the current challenges and sets out prospects for innovation in the designing of flame-retardant materials and the optimisation of processes. The aim is to promote the sustainable growth of efficient, eco-friendly flame-retardant materials. Full article