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Keywords = middle-high rank coal

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22 pages, 2768 KB  
Article
Elemental Geochemistry of Float-Sink Products from Late Paleozoic Coals with Different Ranks: Implications for Clean Utilization and Resource Potential
by Dongna Liu, Wenhui Yi, Fenghua Zhao and Bijiang Xue
Minerals 2026, 16(6), 591; https://doi.org/10.3390/min16060591 - 1 Jun 2026
Viewed by 389
Abstract
Coal rank exerts a fundamental control on the distribution of elements during density-based separation, yet this influence remains poorly understood. The primary objective of this study is to elucidate how coal rank governs the enrichment and partitioning of major, trace, and rare earth [...] Read more.
Coal rank exerts a fundamental control on the distribution of elements during density-based separation, yet this influence remains poorly understood. The primary objective of this study is to elucidate how coal rank governs the enrichment and partitioning of major, trace, and rare earth elements (REY) in float–sink products, and to assess the implications for clean coal utilization and critical metal recovery. To achieve this, three Late Paleozoic bituminous coals of different ranks from Shanxi Province, China, were subjected to density fractionation (1.3–1.8 g/cm3) combined with proximate and ultimate analyses, X-ray fluorescence (XRF), inductively coupled plasma mass spectrometry (ICP-MS), X-ray diffraction (XRD), and coal petrography. The results show that coal rank fundamentally governs element distribution and enrichment patterns. With increasing rank, the dominant inorganic minerals shift from clay minerals to carbonates, leading to pronounced differentiation in elemental affinities. In medium- to high-rank bituminous coals, chalcophile elements (e.g., As, Mo, Tl) associated with sulfides are significantly enriched in high-density fractions, whereas in high-rank bituminous coals, carbonate-related elements (e.g., Sr, Ca, Mg) show marked enrichment. Rare earth elements are primarily hosted in clay and phosphate minerals. Light rare earth elements dominate in medium- to high-rank coals, while middle rare earth elements increase in high-rank coals due to carbonate influence. Density-based separation effectively concentrates hazardous elements (e.g., As, Pb, Cd) in high-density tailings, demonstrating substantial potential for mitigating environmental risks. Meanwhile, critical metals such as lithium (Li), strontium (Sr), and REY are enriched in medium- to high-density products, with Li hosted in clay minerals and Sr strongly enriched in carbonate-rich high-rank coal (up to 1525 μg/g), indicating recoverable resources from coal processing wastes. Full article
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27 pages, 6231 KB  
Article
Geochemistry of Inertinite-Rich Coals from the Zhundong Coalfield, Xinjiang: Organic Compounds and Paleoenvironment Reconstruction
by Qingfeng Lu and Wenfeng Wang
Minerals 2026, 16(6), 574; https://doi.org/10.3390/min16060574 - 27 May 2026
Viewed by 411
Abstract
Organic compounds in fossil fuels (coal, petroleum), particularly polycyclic aromatic hydrocarbons (PAHs), serve as significant molecular fossils to reveal paleoenvironments, paleoclimates, and major geological events and have become the focus of multidisciplinary research. Inertinite-rich coals are widely distributed in the Jurassic coal of [...] Read more.
Organic compounds in fossil fuels (coal, petroleum), particularly polycyclic aromatic hydrocarbons (PAHs), serve as significant molecular fossils to reveal paleoenvironments, paleoclimates, and major geological events and have become the focus of multidisciplinary research. Inertinite-rich coals are widely distributed in the Jurassic coal of Xinjiang, yet the organic geochemical significance and their paleoenvironment implications remain underexplored. This study elucidates the indicative significance of organic compounds in inertinite-rich coals from the Yihua mine of the Zhundong Coalfield, Xinjiang, China, aiming to reveal the coal-forming mechanisms and paleoenvironmental implications of Jurassic low-rank coals in the Zhundong Coalfield. A comprehensive analysis was conducted on 36 coal-seam samples, including maceral identification, vitrinite reflectance measurement, Soxhlet extraction, and GC-MS analysis of saturated and aromatic hydrocarbons. The results show the coal is dominated by inertinite (69.6%), with vitrinite (23.7%) and trace liptinite (0.7%), and classified as low-rank bituminous coal (Ro = 0.42%). Extractable organic matter yield is low (0.20%), with aromatic hydrocarbons (35.19%) far exceeding saturated hydrocarbons (10.57%). PAHs are dominated by high-ring (4–6 ring) compounds, such as benzofluoranthene and retene. The molecular geochemical parameters suggest these PAHs are primarily derived from biomass combustion, recording significant wildfire activity during the Middle Jurassic. Terpenoid biomarkers (cadalene and dehydroabietane) confirm terrestrial higher plant inputs, while isoprenoid parameters suggest an oxidizing coal-forming environment. This research demonstrates that organic compounds, especially PAHs, serve as reliable tracers for paleowildfires and inertinite genesis, providing critical geochemical evidence for understanding coal-forming processes in arid-semiarid regions. Full article
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20 pages, 8520 KB  
Article
Geochemical Characteristics of Coal-Bearing Elements and Their Geological Significance at the Southern Margin of the Junggar Basin, Xinjiang—A Case Study of the Sulphur Gully Mining Area
by Weiwei Xia, Jiapeng Zhang, Bo Wei, Shuo Feng, Xin Li, Lu Wang and Yilixia Yimiti
Appl. Sci. 2026, 16(9), 4471; https://doi.org/10.3390/app16094471 - 2 May 2026
Viewed by 570
Abstract
With the growing demand for strategic metals and the gradual depletion of traditional metal ore deposits, coal and coal-bearing strata are regarded as potential sources of rare metals; consequently, research into the characteristics of associated elements in coal-bearing strata has become one of [...] Read more.
With the growing demand for strategic metals and the gradual depletion of traditional metal ore deposits, coal and coal-bearing strata are regarded as potential sources of rare metals; consequently, research into the characteristics of associated elements in coal-bearing strata has become one of the primary avenues of searching for new alternative resources. To investigate the sedimentary environmental characteristics and controlling factors of the coal-bearing strata along the southern margin of the Junggar Basin, coal seams 9–15 of the Xishanyao Formation in Sulphur Gully (Early Middle Jurassic) were selected as the subject of this study. This study employed analytical techniques including industrial analysis, total sulphur analysis, X-ray powder diffraction (XRD), X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to determine the mineralogical and elemental geochemical characteristics of coal samples from Seylangou mining area, specifically from coal seams 9–15 and their overlying and underlying strata. Based on analyses of elemental ratios such as Al2O3/TiO2, Sr/Ba, Rb/Sr, Ni/Co and V/(Ni + V), the source of material during the deposition of this deposit was identified, and the characteristics of the depositional environment, as indicated by palaeosalinity, palaeoclimate and redox conditions, were revealed. The results indicate that the macroscopic coal-rock types of coal seams 9–15 at the Sulphur Gully Coal Mine on the southern margin of the Junggar Basin are predominantly semi-dull to dull, with small amounts of filamentous coal and lustrous coal. The average proportion of the vitrinite group in the coal is 42.75%, the inertinite group is 51.40%, and the liptinite is 2.25%. The average content of inorganic matter in the coal is 3.60%, and the average maximum reflectance of the vitrinite group is 0.651%. The coal represents a transitional stage from low-rank to medium-rank coal, corresponding to a metamorphic stage of Grade I–II. The coal is classified as a bituminous coal with medium total moisture, very low ash, medium-volatile matter, medium-to-high fixed carbon and very low sulphur. The minerals in the coal seam are predominantly kaolinite, calcite and quartz. The major elements in the ceiling of the coal seam are dominated by SiO2, followed by Al2O3; the coal itself is dominated by CaO, SiO2 and Al2O3; and the base plate of the coal seam is dominated by Al2O3. The trace elements Cs and Bi are relatively enriched in the coal seam ceiling; Sr is relatively enriched in the coal; whilst Li, Cr and other elements are highly enriched in the coal seam base plate. The source rocks of the coal and the roof consist of deposits of felsic igneous rock (dacite), whilst the source rocks of the floor consist of deposits of intermediate igneous rock (andesite). The depositional environment ranges from marine brackish water at the base to transitional slightly brackish water and then to terrestrial freshwater at the top; the depositional climate was cold and arid, and the depositional environment was oxidising. This study provides valuable insights for further research into the elemental geochemical characteristics, sediment sources and depositional environments of the Xishanyao Formation coal seams in Liuhuangou, Xinjiang. Full article
(This article belongs to the Special Issue Research on Mineralogical and Geochemical Characterization)
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15 pages, 1727 KB  
Article
Mathematical Model Establishment for the Multi-Scale Permeability of Coal Reservoirs and Its Engineering Significance
by Zhigang Du, Feilong Xiong, Yingying Li, Guiyang Ren, Jianggen He, Yongyan Yan, Qi Liu and Hongyang Bai
Energies 2026, 19(8), 2006; https://doi.org/10.3390/en19082006 - 21 Apr 2026
Cited by 1 | Viewed by 386
Abstract
Permeability is a critical parameter governing the gas flow behavior of the coalbed methane (CBM) reservoir during the exploration and exploitation of CBM, as well as the geological storage of CO2 in the coalbeds. It is strongly associated with the multi-scale fractures [...] Read more.
Permeability is a critical parameter governing the gas flow behavior of the coalbed methane (CBM) reservoir during the exploration and exploitation of CBM, as well as the geological storage of CO2 in the coalbeds. It is strongly associated with the multi-scale fractures developed in coal. Based on the distribution characteristics of micro-fractures, a multi-scale permeability model for coal reservoirs was established by introducing the permeability tensor, which comprehensively considers adsorption-induced coal swelling, pore pressure, effective stress, and micro-fractures. Further, the dynamic evolution law and mechanism of multi-scale permeability of coal reservoirs under different adsorption pressures were discussed. The results indicate that the increase in effective stress on the coal caused by adsorption-induced swelling essentially leads to a decrease in the equivalent multi-scale permeability of coal. Two key indicators, namely equilibrium pressure and rebound pressure, were defined to quantitatively characterize the evolution law of the equivalent multi-scale permeability during gas adsorption or desorption processes. The effective stress generated by the CO2 adsorption-induced swelling effect in the low-rank coal is 1.47 times that in the middle-rank coal and 2.51 times that in the high-rank coal. Additionally, the effective stress generated by the CO2 adsorption-induced swelling effect in the low-rank coal is 5.15 times that generated by N2, while this level is 4.32 times higher than that in the middle-rank coal. Therefore, compared with the low- and middle-rank coal, the high-rank coal exhibits a smaller decrease in multi-scale permeability due to its weaker adsorption-induced swelling effect. During N2 adsorption, the pore pressure effect dominates over the adsorption-induced swelling effect, resulting in a decrease in the effective stress on the coal with increasing gas pressure. Consequently, the equivalent multi-scale permeability of coal will increase much more significantly with an increase in injected N2 pressure than with an increase in CO2 pressure. By accounting for the differences between the effects of adsorption-induced swelling and pore compression on the equivalent multi-scale permeability of coal reservoir, the injectivity of CO2 can be improved by mixing it with N2. Full article
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23 pages, 14673 KB  
Article
Sequence Stratigraphy, Sedimentary Evolution, and Coal-Accumulation Model of the Lower Xishanyao Formation in the Nileke Sag, Yili Basin
by XinFei Wang, Xin Li, RenDong Peng, ShuGuang Yang and Bin Zhang
Geosciences 2026, 16(1), 31; https://doi.org/10.3390/geosciences16010031 - 6 Jan 2026
Viewed by 1560
Abstract
The Lower-Middle Jurassic Xishanyao Formation in the Nileke Sag of the Yili Basin contains substantial reserves of coal and coalbed methane (CBM). Elucidating its depositional evolution and the controlling factors of coal accumulation within a sequence-stratigraphic framework is crucial for guiding future exploration. [...] Read more.
The Lower-Middle Jurassic Xishanyao Formation in the Nileke Sag of the Yili Basin contains substantial reserves of coal and coalbed methane (CBM). Elucidating its depositional evolution and the controlling factors of coal accumulation within a sequence-stratigraphic framework is crucial for guiding future exploration. This study integrates regional geological surveys, core observations, well-log analysis, and quantitative lithofacies statistics of the lower member to establish a sequence-stratigraphic framework and reconstruct the sedimentary paleogeography. Eleven minable coal seams are identified, exhibiting a depositionally controlled spatial thickness distribution. The coal is classified as low-rank bituminous (Rank I–II), characterized by high inertinite, low ash, medium-high volatile matter, and ultra-low sulfur content, indicating formation in a freshwater swamp influenced by seasonal droughts and floods. Three third-order sequences (SQ1–SQ3) are recognized. SQ2, deposited during peak transgression as a braided-river delta plain, provided the optimal environment for peat accumulation. In contrast, SQ3 is dominated by progradational deltas with coarser sediments, where coal accumulation weakened. The results demonstrate that coal accumulation was jointly controlled by tectonic subsidence (providing accommodation space), climate (causing peat oxidation and fine-clastic input), and sedimentation (with interdistributary bays on the delta plain being the most favorable sites). Coal accumulation in the Lower Xishanyao Member resulted from the coupling of tectonic, climatic, and sedimentary processes. This genetic model provides a theoretical basis for regional coal and CBM exploration. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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17 pages, 2031 KB  
Article
Geochemical Characteristics and Paleoenvironmental Significance of the Xishanyao Formation Coal from the Xiheishan Mining Area, Zhundong Coalfield, Xinjiang, China
by Yongjie Hou, Kaixuan Zhang, Xiangcheng Jin, Yongjia Xu, Xiaotao Xu and Xiaoyun Yan
Minerals 2025, 15(7), 686; https://doi.org/10.3390/min15070686 - 27 Jun 2025
Cited by 1 | Viewed by 1188
Abstract
The eastern Junggar Basin in Xinjiang, China is a key coal-bearing region dominated by the Middle Jurassic Xishanyao Formation. Despite its significance as a major coal resource base, detailed paleoenvironmental reconstructions of its coal seams remain limited. This study investigates the B1 [...] Read more.
The eastern Junggar Basin in Xinjiang, China is a key coal-bearing region dominated by the Middle Jurassic Xishanyao Formation. Despite its significance as a major coal resource base, detailed paleoenvironmental reconstructions of its coal seams remain limited. This study investigates the B1, B2, B3, and B5 coal seams of the Xishanyao Formation using X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to assess geochemical indicators of the depositional environment during coal formation. The results show that the coal samples are characterized by high inertinite content and low vitrinite reflectance, indicative of low-rank coal. Slight enrichment of strontium (Sr) was observed in the B1, B2, and B5 seams, while cobalt (Co) showed minor enrichment in B3. Redox-sensitive elemental ratios (Ni/Co, V/Cr, and Mo) suggest that the peat-forming environment ranged from oxidizing to dysoxic conditions, with relatively high oxygen availability and strong hydrodynamic activity. A vertical trend of increasing paleosalinity and a shift from warm–humid to dry–hot paleoclimatic conditions was identified from the lower (B1) to upper (B5) coal seams. Additionally, the estimated atmospheric oxygen concentration during the Middle Jurassic was approximately 28.4%, well above the threshold for wildfire combustion. These findings provide new insights into the paleoenvironmental evolution of the Xishanyao Formation and offer a valuable geochemical framework for coal exploration and the assessment of coal-associated mineral resources in the eastern Junggar Basin. Full article
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21 pages, 2249 KB  
Article
Multifractal Characterization of Full-Scale Pore Structure in Middle-High-Rank Coal Reservoirs: Implications for Permeability Modeling in Western Guizhou–Eastern Yunnan Basin
by Fangkai Quan, Yanhui Zhang, Wei Lu, Chongtao Wei, Xuguang Dai and Zhengyuan Qin
Processes 2025, 13(6), 1927; https://doi.org/10.3390/pr13061927 - 18 Jun 2025
Cited by 2 | Viewed by 1114
Abstract
This study presents a comprehensive multifractal characterization of full-scale pore structures in middle- to high-rank coal reservoirs from the Western Guizhou–Eastern Yunnan Basin and establishes a permeability prediction model integrating fractal heterogeneity and pore throat parameters. Eight coal samples were analyzed using mercury [...] Read more.
This study presents a comprehensive multifractal characterization of full-scale pore structures in middle- to high-rank coal reservoirs from the Western Guizhou–Eastern Yunnan Basin and establishes a permeability prediction model integrating fractal heterogeneity and pore throat parameters. Eight coal samples were analyzed using mercury intrusion porosimetry (MIP), low-pressure gas adsorption (N2/CO2), and multifractal theory to quantify multiscale pore heterogeneity and its implications for fluid transport. Results reveal weak correlations (R2 < 0.39) between conventional petrophysical parameters (ash yield, volatile matter, porosity) and permeability, underscoring the inadequacy of bulk properties in predicting flow behavior. Full-scale pore characterization identified distinct pore architecture regimes: Laochang block coals exhibit microporous dominance (0.45–0.55 nm) with CO2 adsorption capacities 78% higher than Tucheng samples, while Tucheng coals display enhanced seepage pore development (100–5000 nm), yielding 2.5× greater stage pore volumes. Multifractal analysis demonstrated significant heterogeneity (Δα = 0.98–1.82), with Laochang samples showing superior pore uniformity (D1 = 0.86 vs. 0.82) but inferior connectivity (D2 = 0.69 vs. 0.71). A novel permeability model was developed through multivariate regression, integrating the heterogeneity index (Δα) and effective pore throat diameter (D10), achieving exceptional predictive accuracy. The strong negative correlation between Δα and permeability (R = −0.93) highlights how pore complexity governs flow resistance, while D10’s positive influence (R = 0.72) emphasizes throat size control on fluid migration. This work provides a paradigm shift in coal reservoir evaluation, demonstrating that multiscale fractal heterogeneity, rather than conventional bulk properties, dictates permeability in anisotropic coal systems. The model offers critical insights for optimizing hydraulic fracturing and enhanced coalbed methane recovery in structurally heterogeneous basins. Full article
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17 pages, 3863 KB  
Article
Adsorption Pore Volume Distribution Heterogeneity of Middle and High Rank Coal Reservoirs and Determination of Its Influencing Factors
by Kai Wang, Fangkai Quan, Shizhao Zhang, Yubo Zhao, He Shi, Tingting Yin and Zhenyuan Qin
Processes 2025, 13(2), 429; https://doi.org/10.3390/pr13020429 - 6 Feb 2025
Cited by 3 | Viewed by 2776
Abstract
Heterogeneity of adsorption pore volume distribution affects desorption and diffusion processes of coal reservoirs. In this paper, N2 and CO2 adsorption and desorption experiment tests were used to study the pore structure of middle and high rank coal reservoirs in the [...] Read more.
Heterogeneity of adsorption pore volume distribution affects desorption and diffusion processes of coal reservoirs. In this paper, N2 and CO2 adsorption and desorption experiment tests were used to study the pore structure of middle and high rank coal reservoirs in the study area. The fractal theory of volume and surface area is used to achieve a full-scale fractal study of adsorption pores (pore diameter is less than 100 nm) in the study area. Firstly, adaptability and control factors of volume fractals and surface area fractals within the same aperture scale range are studied. Secondly, fractal characteristics of micro-pores and meso-pores are studied. Thirdly, fractal characteristics within different aperture scales and the influencing factors of fractal characteristics within different scale ranges are studied. The results are as follows. With the increase in coal rank, pore volume and specific surface area of pores less than 0.8 nm increase, and dominant pore size changes from 0.55~0.8 nm (middle coal rank) to 0.5~0.7 nm (high coal rank). As coal rank increases, TPV and average pore diameter (APD) decrease under the BJH model, while SSA changes are not significant under the BET model. Moreover, as the pore diameter decreases, the correlation between the integral dimension of pore volume and degree of coal metamorphism decreases. This result can provide a theoretical basis for the precise characterization of the target coal seam pore and fracture structure and support the optimization of favorable areas for coalbed methane. Full article
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21 pages, 3623 KB  
Article
Characteristics of the Microfracture and Pore Structure of Middle- and High-Rank Coal and Their Implications for CBM Exploration and Development in Northern Guizhou
by Haiying Ren, Zhijun Guo, Honggao Xie, Sijie Han, Xiaozhi Zhou, Lingyun Zhao, Yuanlong Wei and Wenci Qiu
Energies 2025, 18(1), 5; https://doi.org/10.3390/en18010005 - 24 Dec 2024
Cited by 2 | Viewed by 1323
Abstract
The microfracture and pore structure characteristics of coal reservoirs are crucial for coalbed methane (CBM) development. This study examines the evolution of pore and fracture structures at the microscopic level and their fractal characteristics, elucidating their impact on CBM development in the northern [...] Read more.
The microfracture and pore structure characteristics of coal reservoirs are crucial for coalbed methane (CBM) development. This study examines the evolution of pore and fracture structures at the microscopic level and their fractal characteristics, elucidating their impact on CBM development in the northern Guizhou coal reservoirs. The results indicate that the pores and fractures in the coal reservoirs are relatively well-developed, which facilitates the adsorption of CBM. The density of primary fractures ranges from 5.8 to 14.4 pcs/cm, while the density of secondary fractures ranges from 3.6 to 11.8 pcs/cm. As the metamorphic degree of coal increases, the density of primary fractures initially increases and then decreases, whereas the density of secondary fractures decreases with increasing metamorphic degree. With increasing vitrinite reflectance, the specific surface area and pore volume of the coal samples first decrease and then increase. The fractal dimension ranges from 2.3761 to 2.8361; as the vitrinite reflectance of the coal samples increases, the fractal dimension D1 decreases initially and then increases, while D2 decreases. In the northern Guizhou region, CBM is characterized by an enrichment model of “anticline dominance + fault-hydrogeological dual sealing” along with geological controlling factors of” burial depth controlling gas content and permeability + local fault controlling accumulation”. The research findings provide a theoretical basis for the occurrence and extraction of CBM in northern Guizhou. Full article
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18 pages, 4562 KB  
Article
Analysis and Characterization of Micro–Nano Pores in Coal Reservoirs of Different Coal Ranks
by Jinxing Song, Yulu Yue and Yufang Liu
Appl. Sci. 2024, 14(12), 5198; https://doi.org/10.3390/app14125198 - 14 Jun 2024
Cited by 8 | Viewed by 1861
Abstract
Coalbed methane represents a promising source of clean and efficient unconventional energy. The intricate network of micro–nano pores within coal serves as the primary adsorption space for gas, contributing to the complexity of gas migration channels. In this study, based on the box-counting [...] Read more.
Coalbed methane represents a promising source of clean and efficient unconventional energy. The intricate network of micro–nano pores within coal serves as the primary adsorption space for gas, contributing to the complexity of gas migration channels. In this study, based on the box-counting method, three coal samples representing low, medium, and high ranks were subjected to high-precision micro-CT scanning and nano-CT scanning to generate three-dimensional (3D) pore network models using Avizo visualization software. This facilitated the accurate and quantitative characterization of the micro–nano pore structures within coal reservoirs. The results indicated that the face rate distribution range of each sample was large, indicating relatively strong heterogeneity in each sample. The volume fractal dimension of each sample, determined through micro–nano-CT scanning, was around 2.5, while the surface fractal dimension exhibited oscillatory characteristics with moderate uniformity. The pore equivalent radius and throat equivalent radius distributions were unimodal across all the samples, with the micro-CT scanning revealing a concentration primarily within the range of 100–400 μm for the pore equivalent radius and within 200 μm for the throat equivalent radius. Conversely, the nano-CT scanning exhibited concentrations primarily within the range of 500–2500 nm for the pore equivalent radius and within 2000 nm for the throat equivalent radius. The analysis of the 3D reconstruction structures indicated that the middle-rank coal exhibited more developed large–medium pores compared with the low-rank and high-rank coal, while the low-rank and high-rank coal exhibited relatively more micro–small pores. Furthermore, the low-rank coal exhibited the fewest number of pores but the largest average pore equivalent radius and throat radius. Additionally, the middle–high-rank coal exhibited a relatively larger number of pores. Despite the complex topological structures observed in each sample, a significant proportion indicated a coordination number of 0–20, indicating excellent connectivity within the coal samples. This study is conducive to the optimization of coalbed methane surface development blocks and the formulation of reasonable development plans. Full article
(This article belongs to the Special Issue Advances in Unconventional Natural Gas: Exploration and Development)
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14 pages, 4470 KB  
Article
The Occurrence and Distribution of Nitrogen in Coal of Different Ranks and Densities
by Dongna Liu, Qi Zhang, Fenghua Zhao, Xile Liu and Shangqing Zhang
Minerals 2024, 14(6), 549; https://doi.org/10.3390/min14060549 - 26 May 2024
Cited by 11 | Viewed by 3705
Abstract
Nitrogen is one of the significant pollutants emitted from coal combustion, and the study of its distribution and occurrence is very important for the efficient and clean utilization of coal resources. Four kinds of coal with different metamorphic ranks from major coal-producing provinces [...] Read more.
Nitrogen is one of the significant pollutants emitted from coal combustion, and the study of its distribution and occurrence is very important for the efficient and clean utilization of coal resources. Four kinds of coal with different metamorphic ranks from major coal-producing provinces of China were studied. A gravity float-and-sink experiment was applied to obtain coal samples with different densities from Shanxi Province. The microscope optical method, Kjeldahl method, and X-ray photoelectron spectroscopy (XPS) were used to assess the occurrence, form, and distribution of nitrogen in the coal. The results show that the nitrogen content was about 0.47%–1.85%, and the maximum nitrogen content was positively correlated with the rank of coal, but the difference was not obvious. In the low-rank coal, the nitrogen content was mainly related to vitrinite and inertinite, while in the middle–high-rank coal, the nitrogen content was mainly related to inertinite and minerals. Pyrrolic (N-5) and pyridinic (N-6) were the main forms of nitrogen in the low-rank coal. The contents of N-6 and N-5 decreased with increases in the coal density, but the contents of quaternary N-Q1 and quaternary N-Q2 increased. N-Q2 mainly comes from fixed ammonia nitrogen in minerals, and vitrinite and liptinite contain more N-6 and less N-Q1 than inertinite. This research provides valuable evaluation guidance for the efficient utilization of coal. Full article
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18 pages, 9180 KB  
Article
Magmatic Intrusion during the Yanshanian Period and Multi-Mineral Enrichment Mechanisms in the Eastern Margin of the North China Craton
by Lusheng Yin, Huaihong Wang, Dongdong Wang, Yinan Liu, Haiyan Liu, Yuzhen Zhu, Lijun Shen and Zengxue Li
Minerals 2024, 14(4), 332; https://doi.org/10.3390/min14040332 - 24 Mar 2024
Cited by 6 | Viewed by 2285
Abstract
The mineralization within the North China Craton (NCC) is intricately linked to Mesozoic large-scale extension in eastern China and is a consequence of a unified geodynamic tectonic background. Despite previous attempts to elucidate the relationship between large-scale mineralization and magmatic activity in the [...] Read more.
The mineralization within the North China Craton (NCC) is intricately linked to Mesozoic large-scale extension in eastern China and is a consequence of a unified geodynamic tectonic background. Despite previous attempts to elucidate the relationship between large-scale mineralization and magmatic activity in the NCC, a lack of systematic research has hindered the identification of connections among deposits with inconsistent metallogenic ages. This study focuses on the coal measures of the Huanghebei Coalfield (HHBC) in western Shandong, presenting a regional magmatic–hydrothermal metallogenic system with a genetic connection. It delves into the intricate interplay between the multi-mineral enrichment mechanism, metallogenic regularity, and the NCC’s destruction. The findings reveal that: (1) Various stages of magmatic intrusion during the Yanshanian period significantly influenced the Late Paleozoic coal measures in the HHBC. The coal measures exhibit distinct ranks, ranging from medium-rank bituminous C to A and high-rank anthracite C, resulting in noticeable differences in gas generation among different coal ranks. The shale between the coal seams C5 and C7 emerges as excellent with a good hydrocarbon-generating capacity during the middle-maturity stage. (2) The “Intrusion along the rock layer type” proves most conducive to shale gas enrichment, while the “laccolith type” is more favorable for shale gas enrichment compared to “dike type” intrusions, which have a limited impact on shale gas enrichment. (3) The mineralization process of CBM, shale gas, and iron ore is influenced by Yanshanian-period magma. The enrichment degree of CBM and shale gas exhibits an inverse correlation with the distance from the magmatic intrusion. Iron deposits demonstrate a close association with the magmatic intrusion, with enhanced enrichment along the rock layer. The results indicate that the destruction of the NCC triggered intense metasomatism in the deep cratonic fluids, serving as the primary driving mechanism for large-scale mineralization during the Yanshanian period. Magmatic intrusions bring hydrothermal fluids conducive to mineralization, and the heat release from these intrusions promotes thermal evolution, hydrocarbon generation, and the enrichment of organic-rich strata. Full article
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14 pages, 3481 KB  
Article
Energy Variation Features during the Isothermal Adsorption of Coal under High-Temperature and High-Pressure Conditions
by Tongling Jing, Chuanqi Tao, Yanbin Wang, Huan Miao, Mingyu Xi, Xingchen Zhao and Haiyang Fu
Processes 2023, 11(9), 2524; https://doi.org/10.3390/pr11092524 - 23 Aug 2023
Cited by 6 | Viewed by 1890
Abstract
This paper aims to describe methane adsorption in coal under the conditions of high temperature and high pressure, as well as quantitatively decipher the change rule of energy in the isothermal adsorption process. The isothermal adsorption test was carried out with four groups [...] Read more.
This paper aims to describe methane adsorption in coal under the conditions of high temperature and high pressure, as well as quantitatively decipher the change rule of energy in the isothermal adsorption process. The isothermal adsorption test was carried out with four groups of middle-rank coals from the Linxing area with different degrees of metamorphism. The impacts of the degree of deterioration of coal, temperature, and pressure on adsorption were analyzed with regard to the adsorption amount, adsorption potential, and adsorption space. Additionally, the energy change during the adsorption of methane by the coal was considered. The results show that the coal adsorption capacity hinges on the degree of deterioration of the coal, as well as the pressure and temperature. Additionally, the impact of temperature upon coal methane adsorption under depth conditions is highlighted. Like the adsorption space, the adsorption potential is an important parameter used to quantitatively characterize the adsorption ease and adsorption capacity; furthermore, the adsorption potential of millipores exceeds that of mesopores, as they are capable of offering a larger specific surface area for adsorption. The total decrease in the surface free energy during adsorption increases as the pressure increases; simultaneously, the increase rate is fast and then slow. The total decrease in the above-described free energy diminishes as the temperature escalates. Under the same pressure, the total decrease in the aforementioned free energy increases as the reflectance of the specular body of the coal increases. The decrease in the aforementioned free energy at each point of pressure lessens as the pressure grows; notably, when the pressure is comparatively low, the reduction is very fast. As the pressure escalates continuously, the decrease speed is slow. Regarding the effect of pressure and temperature upon adsorption, the adsorption gas volume of coal exists in a conversion depth from 1200 m to 1500 m; at the same time, the impact of pressure upon adsorption is dominant up to this depth. Additionally, beyond this depth, temperature gradually comes to have the greatest impact on adsorption. Full article
(This article belongs to the Section Chemical Processes and Systems)
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17 pages, 5023 KB  
Article
Pore Structure Multifractal Characteristics of Coal Reservoirs in the Central and Eastern Qinshui Basin and Influencing Factors
by Chaochao Duan, Xuehai Fu, Ze Deng, Junqiang Kang, Baoxin Zhang, Jielin Lu, Xing Hong, Ruirui Dai and Xiaogang Li
Processes 2023, 11(1), 286; https://doi.org/10.3390/pr11010286 - 16 Jan 2023
Cited by 9 | Viewed by 2632
Abstract
The heterogeneity of the pore structure of coal reservoirs affects the desorption and diffusion characteristics of coalbed methane, and determining its distribution law is conducive to improving the theory of coalbed methane development. The central and eastern parts of the Qinshui Basin are [...] Read more.
The heterogeneity of the pore structure of coal reservoirs affects the desorption and diffusion characteristics of coalbed methane, and determining its distribution law is conducive to improving the theory of coalbed methane development. The central and eastern parts of the Qinshui Basin are rich in coalbed methane resources, but the heterogeneity characteristics of the pore structure of coal reservoirs are not clear. NMR has the advantages of being fast, non-destructive and full-scale, and multifractal can describe the self-similarity of NMR T2 curve at different scales so as to analyze the complexity of pore distribution. Based on this, 15 samples with different coal ranks were collected from the central and eastern Qinshui Basin (Ro,max between 1.54 and 2.78%), and quantitative pore characterization experiments such as low-field nuclear magnetic resonance (LF-NMR) and low-temperature liquid nitrogen adsorption (LTN2A) were conducted. Based on multifractal theory, the heterogeneity law of pore structure was quantitatively evaluated, and its influencing factors were elucidated. The results showed that the BJH pore volume of coal samples in the study area ranged from 0.0005–0.0028 cm3/g, with an average of 0.0014 cm3/g, and the BET specific surface area was 0.07–2.52 m2/g, with an average of 0.41 m2/g. The NMR T2 spectrum peaked at 0.1–1, 10–100 and 100–1000 ms, and the spectrum was mostly bimodal or trimodal, indicating that pores of different pore sizes were developed. There were great differences in the pore structure of different coal ranks; high-rank coal was dominated by micropores, and the proportion of mesopores and macropores of medium-rank coal was higher. The pore structure of coal samples showed obvious multifractal characteristics, and the fractal characteristics of the sparse region (low-value information) were more significant; they dominated the pore distribution and had a stronger influence on the distribution of pore space. Pore structure heterogeneity is closely related to the degree of coalification, and with the increase in coalification, it is closely related to coal lithotype and quality, and high mineral and inertinite contents lead to the enhancement of pore structure heterogeneity in coal reservoirs, while Ro,max, Mad and vitrinite group contents have opposite effects. The research results provide theoretical guidance for the subsequent exploration and development of coalbed methane in the region. Full article
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Article
Characteristics and Origins of the Difference between the Middle and High Rank Coal in Guizhou and Their Implication for the CBM Exploration and Development Strategy: A Case Study from Dahebian and Dafang Block
by Fuping Zhao, Shuxun Sang, Sijie Han, Zhangli Wu, Jinchao Zhang, Wenxin Xiang and Ang Xu
Energies 2022, 15(9), 3181; https://doi.org/10.3390/en15093181 - 27 Apr 2022
Cited by 13 | Viewed by 2804
Abstract
The coalbed methane (CBM) geology in Guizhou is characterized by a high gas content, pressure and resource abundance, indicating superior CBM resource potential. However, there are also many unfavorable factors, such as complex structure geology, significant regional differences in CBM geology, the widespread [...] Read more.
The coalbed methane (CBM) geology in Guizhou is characterized by a high gas content, pressure and resource abundance, indicating superior CBM resource potential. However, there are also many unfavorable factors, such as complex structure geology, significant regional differences in CBM geology, the widespread development of tectonically deformed coal, and the unclear understanding of the configuration of geological factors for CBM enrichment and high yield, which restrict the increase in CBM production and a large-scale development. Taking the Dahebian Block in Liupanshui coal field and the Dafang Block in Qianbei coal field as examples, this study presented the CBM geological differences between middle- and high-rank coals; their origins were analyzed and the effect of depth on gas content and permeability was discussed. A CBM enrichment and high-yield model was illustrated, and the geologic fitness-related exploration and development methods for Guizhou CBM were finally proposed. The results show that (1) significant differences between the middle- and high-rank coals occur in coal occurrence and distribution, coal qualities, and coal reservoir properties. Compared to Dahebian coal, Dafang coal has a higher coal rank, vitrinite content, and gas content, but a lower number of coal layers and permeability. (2) The sedimentary–tectonic evolution of the Longtan coal-bearing sequence is the fundamental reason for CBM geological differences between the Dadebian Block and Dafang Block, consisting of coal occurrence, qualities, maceral, rank, structure, and their associated reservoir properties. (3) The coordinated variation of gas content and permeability contributes to a greater depth for CBM enrichment and a high yield of the middle-rank coal. It is suggested that the best depths for CBM enrichment and high yield in Guizhou are 600–800 m for the middle-rank coal and 500 m for the high-rank coal, respectively. (4) Considering the bottleneck of inefficient CBM development in Guizhou, we proposed three CBM assessment and development technologies, including the CBM optimization of the classification–hierarchical optimization–analytical hierarchy, multiple coal seams commingling production with the pressure relief of tectonically deformed coal, and surface–underground CBM three-dimensional drainage development. The aim of this study was to provide new insights into the efficient exploration and development of CBM in Guizhou. Full article
(This article belongs to the Special Issue Advances in Unconventional Oil and Gas)
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