Search Results (45)

The establishment of carbon capture, utilization, and storage supply chains at the national level is crucial for meeting global decarbonization targets: they have been suggested as a solution to maintain the global temperature rise below 2 °C relative to preindustrial levels. Optimizing these systems requires a balance of economic viability with environmental impact, but this is a challenge due to diverse operational limitations. This paper introduces an optimization framework that integrates life cycle assessment with a source-sink model while combining the geographical storage and conversion pathways of carbon dioxide into high-value chemicals. This study explores the economic and environmental outcomes of national carbon capture, utilization, and storage networks, considering several constraints, such as carbon dioxide reduction goals, product market demand, and renewable hydrogen availability. The framework is utilized in Germany as a case study, presenting three case studies to maximize overall annual profit and life cycle greenhouse gas reduction. In all analyzed scenarios, the results indicate a clear trade-off between profitability and emission reductions: profit-driven strategies are characterized by increased emissions, while environmental strategies have higher costs despite the environmental benefit. In addition, cost-optimal cases prefer high-profit utilization routes (e.g., gasoline through methane reforming) and cost-effective capture technologies, leading to significant profitability. On the other hand, climate-optimal approaches require diversification, integrating carbon dioxide storage with conversion pathways that exhibit lower emissions (e.g., gasoline, acetic acid, methanol through carbon dioxide hydrogenation). The proposed method significantly contributes to developing and constructing more sustainable, large-scale carbon projects. Full article

This research work seeks to introduce eco-friendly, low-carbon, and high-octane biofuel gasoline production using a synergistic approach. Four types of high-octane gasoline, including SynergyFuel-92, SynergyFuel-95, SynergyFuel-98, and SynergyFuel-100, were generated, emphasizing the deliberate combination of petroleum-derived gasoline fractions using reformate, isomerate, and delayed coking (DC) naphtha with octane-boosting compounds—bio-methanol and bio-ethanol. A set of tests have been performed to examine the effects of antiknock properties, density, oxidation stability, distillation range characteristics, hydrocarbon composition, vapor pressure, and the volatility index on gasoline blends. The experimental results indicated that the gasoline blends made from biofuel (SynergyFuel-92, -95, -98, and 100) showed adherence to important fuel quality criteria in the USA, Europe, and China. These blends had good characteristics, such as low quantities of benzene and sulfur, regulated levels of olefins and aromatics, and good distillation qualities. By fulfilling these strict regulations, Synergy Fuel is positioned as a competitive and eco-friendly substitute for traditional gasoline. The results reported that SynergyFuel-100 demonstrated the strongest hot-fuel-handling qualities and resistance to vapor lock among all the mentioned Synergy Fuels. Finally, the emergence of eco-friendly, low-carbon, and high-octane biofuel gasoline production with synergistic benefits is a big step in the direction of sustainable transportation. Full article

The sustainability of the natural gas-to-methanol (NGTM) and methanol-to-gasoline (MTG) processes are assessed in this systematic review as a potential substitute in the global energy transition. Methanol offers itself as a versatile and less carbon-intensive substitute for conventional gasoline in light of growing environmental concerns and the demand for cleaner fuels. This review’s rationale is to assess MTG’s ability to lessen environmental impact while preserving compatibility with current fuel infrastructure. The goal is to examine methanol and gasoline’s effects on the environment, society, and economy throughout their life cycles. This review used a two-phase systematic literature review methodology, filtering and evaluating studies that were indexed by Scopus using bibliometric and thematic analysis. A total of 25 documents were reviewed, in which 22 documents analyzed part of this study, and 68% employed LCA or techno-economic analysis, with the U.S. contributing 35% of the overall publications. A comparative analysis of the reviewed literature indicates that methanol-based fuels offer significantly lower greenhouse gas (GHG) emissions and life cycle environmental impacts than gasoline, particularly when combined with carbon capture and renewable feedstocks. This review also highlights benefits, such as improved safety and energy security, while acknowledging challenges, including high production costs, infrastructure adaptation, and toxicity concerns. Several drawbacks are high manufacturing costs, the necessity to adjust infrastructure, and toxicity issues. The report suggests investing in renewable methanol production, AI-driven process optimization, and robust legislative frameworks for integrating green fuels. The life cycle sustainability assessment (LCSA) of NGTM and MTG systems should be investigated in future studies, particularly in light of different feedstock and regional circumstances. The findings emphasize NGTM and MTG’s strategic role in aligning with several UN Sustainable Development Goals (SDGs) and add to the worldwide conversation on sustainable fuels. A strong transition necessitates multi-stakeholder cooperation, innovation, and supporting policies to fully realize the sustainability promise of cleaner fuels like methanol. Full article

Porous nanocrystalline lanthanum perovskite La-Fe-O (LaFeO₃) powders were synthesized by the sol–gel self-combustion method, using polyvinyl alcohol as the colloidal medium. The perovskite structure of the material, without secondary phases, was obtained at a calcination temperature of 900 °C for 40 min. The obtained powder was tested for catalytic activity at moderate temperatures (50–550 °C) for ethanol, methanol, acetone, benzene, and Pb-free gasoline vapors. Catalytic combustion begins at quite low temperatures (60–200 °C), compared to normal combustion, and this can be attributed to the nanometric crystallites, the large specific surface area, and the presence of iron cations with different valences, Fe³⁺/Fe²⁺, resulting from the method we used to obtain the material. The degree of conversion reaches values of over 99% for acetone and ethanol vapors at a temperature of 270 °C and 310 °C, respectively, and over 97% for methanol vapors at a temperature of 330 °C. The degree of conversion for Pb-free gasoline and benzene reaches somewhat lower values, over 88% at much higher temperatures, 470 °C and 550 °C, respectively. The lanthanum perovskite catalyst, LaFeO₃, obtained by the presented preparation method, can be recommended for the combustion of acetone, ethanol, and methanol vapors. The performance of this catalyst is remarkable and can be compared to that of a catalyst containing noble metals in its composition. Full article

The dehydration of methanol to produce light olefins and gasoline, known as MTO (methanol-to-olefins) process requires acidic catalysts that maintain their acidity at reaction temperatures. Zeolites, such as SAPOs and ZSM-5, are commonly used for this purpose due to their acidic centers. The initial step in these experiments involves the activation or pretreatment of these solids to remove physically adsorbed water from their pores. Inadequate pretreatment can lead to the destruction of the existing Brönsted sites through the dihydroxylation of surface -OH groups. Therefore, it is crucial to pretreat the zeolites properly to preserve the Brönsted sites. One method is to subject the fresh catalyst to programmed dehydration, which involves desorption at a controlled temperature while monitoring the appearance of water that results from Brönsted site dihydroxylation. The temperature at which the dehydration peak appears determines the optimal reaction temperature. The results presented in this work will demonstrate the progressive deactivation of the catalysts when the reaction temperature exceeds 400 °C. Full article

Methanol is widely recognized as a promising alternative fuel for achieving carbon neutrality in internal combustion engines. Its use in direct injection spark-ignition (DISI) engines, either as pure methanol or blended fuels, has demonstrated improvements in thermal efficiency and reductions in certain gaseous pollutants. However, due to the complex influencing factors and the great harm to human health, its particulate emissions need to be further explored and controlled, which is also an inevitable requirement for the development of energy conservation and carbon reduction in internal combustion engines. This study explores the effects of two-stage injection strategies combined with fuel blending on the combustion characteristics, stability, and particulate emissions of DISI engines. By testing four methanol blending ratios and four injection ratios, the presented study identifies that M20 fuel with an 8:2 injection ratio achieves optimal combustion performance, stability, and increased indicated mean effective pressure. Furthermore, under low methanol blending ratios, the 8:2 injection ratio can reduce particulate number concentrations by approximately 20%. These findings suggest that a well-designed two-stage injection strategy combined with methanol–gasoline blends can effectively control particulate emissions while maintaining the power, efficiency, and combustion stability of DISI engines. Full article

Despite Iran’s considerable renewable energy (RE) potential and excellent wind capacity and high solar radiation levels, these sources contribute only a small fraction of the country’s total energy production. This paper addresses the techno-economic viability of gray hydrogen production by these renewables, with a particular focus on solar energy. Given the considerable potential of solar energy and the strategic location of Shahrekord, it would be an optimal site for a hydrogen generation plant integrated with a solar field. HOMER Pro 3.18.3 software was utilized to model and optimize the levelized cost of hydrogen (LCOH) of steam reforming using different hydrocarbons in various scenarios. The results of this study indicate that natural gas (NG) reforming represents the most cost-effective method of gray hydrogen production in this city, with an LCOH of −0.423 USD/kg. Other hydrocarbons such as diesel, gasoline, propane, methanol, and ethanol have a price per kilogram of produced hydrogen as follows: USD −0.4, USD −0.293, USD 1.17, USD 1.48, and USD 2.15. In addition, integrating RE sources into hydrogen production was found to be viable. Moreover, by implementing RE technologies, CO₂ emissions can be significantly reduced, and energy security can be achieved. Full article

Alcohol-blended gasoline is recognized as an effective strategy for reducing carbon emissions during combustion and enhancing fuel performance. However, the carbon footprint associated with its production process in refineries deserves equal attention. This study introduces a refinery modeling framework to evaluate the long-term economic and environmental performance of utilizing alcohols derived from fossil, biomass, and carbon capture sources in gasoline blending processes. The proposed framework integrates Extreme Learning Machine-based models for gasoline octane blending, linear programming for optimization, carbon footprint tracking, and future trends in feedstock costs and carbon taxes. The results indicate that gasoline blended with coal-based alcohol currently exhibits the best economic performance, though its carbon footprint ranges from 818.54 to 2072.89 kgCO₂/t. Gasoline blended with biomass-based alcohol leads to a slight reduction in benefits and an increase in the carbon footprint. Blending gasoline with CCUM (CO₂ capture and utilization to methanol) results in the lowest economic performance, with a gross margin of 8.91 CNY/t_oil at a 30% blending ratio, but achieves a significant 62.4% reduction in the carbon footprint. In long-term scenarios, the additional costs brought by increased carbon taxes result in negative economic performance for coal-based alcohol blending after 2040. However, cost reductions driven by technological maturity lead to biomass-based alcohol and CCUM blending gradually showing economic advantages. Furthermore, owing to the negative carbon emissions characteristic of CCUM, the blending route with CCUM achieves a gross margin of 440.60 CNY/t_oil and a gasoline carbon footprint of 282.28 kgCO₂/t at a 20% blending ratio by 2050, making it the best route in terms of economic and environmental performance. Full article

Methanol has significant potential as an alternative fuel for internal combustion engines. Using methanol–gasoline blends with lean-burn technology in traditional spark-ignition engines can enhance fuel economy and reduce emissions. This paper investigates the effects of lean burn on the combustion and emissions in a commercial direct-injection gasoline engine fueled with methanol–gasoline blends. The lean-burn mode is adjusted by controlling the injection strategy. The results show that homogeneous lean burn (HLB) has earlier combustion phase and better power performance when the excess air ratio (λ) is less than 1.3, while its combustion phase extends more than stratified lean burn (SLB) when λ exceeds 1.4. Both lean-burn modes achieve optimal fuel economy at λ = 1.2–1.3. Under stable conditions, BSFC decreases with higher methanol blending ratios, with SLB being more economical at low blending ratios and HLB at higher ratios. The lowest HC and particulate matter emissions for both modes are achieved around λ = 1.3. SLB has lower NO_X emissions when λ < 1.3, while HLB shows lower NO_X emissions when λ > 1.3. The particulate size distribution is bimodal for blending lean-burn conditions, with SLB having the highest nucleation mode peak and HLB the highest accumulation mode peak. M20 (20% volume of methanol) corresponds to the highest particle emissions under lean-burn conditions. This study can provide a deeper understanding of methanol–gasoline blending lean burn, and provide a reference for emission control of spark-ignition engines. Full article

E-fuels represent a crucial technology for transitioning to fossil-free energy systems, driven by the need to eliminate dependence on fossil fuels, which are major environmental pollutants. This study investigates the production of carbon-neutral synthetic fuels, focusing on e-hydrogen (e-H₂) generated from water electrolysis using renewable electricity and carbon dioxide (CO₂) captured from industrial sites or the air (CCUS, DAC). E-H₂ can be converted into various e-fuels (e-methane, e-methanol, e-DME/OME, e-diesel/kerosene/gasoline) or combined with nitrogen to produce e-ammonia. These e-fuels serve as efficient energy carriers that can be stored, transported, and utilized across different energy sectors, including transportation and industry. The first objective is to establish a clear framework encompassing the required feedstocks and production technologies, such as water electrolysis, carbon capture, and nitrogen production techniques, followed by an analysis of e-fuel synthesis technologies. The second objective is to evaluate these technologies’ technological maturity and sustainability, comparing energy conversion efficiency and greenhouse gas emissions with their electric counterparts. The sustainability of e-fuels hinges on using renewable electricity. Challenges and future prospects of an energy system based on e-fuels are discussed, aiming to inform the debate on e-fuels’ role in reducing fossil fuel dependency. Full article

IC Engines have played a vital role in past years and will in future years too. The only way that engines are made popular is the power they produce, which is useful in the transportation sector, with which humans’ daily lives become easier concerning time and effort. The only issues with these engines are the depletion of fossil fuels and harmful emissions. To regulate these threats, in the current study an SI engine is modified to duel fuel mode in such a way that the engine runs with hydrogen gas at different flow rates along with air. Engine speed is varied from 1800 to 3400 rpm under constant load by letting an ethanol, methanol, and gasoline mixture enter into the cylinder. Performance parameters like brake thermal efficiency, HC emissions, and vibrations produced from the engine are in agreement with the blended fuels used in this study. Full article

Currently, conventional spark–ignition engines face challenges in meeting the ever-growing demands of customers and increasingly stringent regulations regarding pollutant emissions. A combination of innovative strategies and carbon-neutral fuels is deemed necessary in order to further reduce fuel consumption and minimize engine emissions. The present work aims to assess the performance of combustion strategies using low-carbon-content fuel, such as methanol M100, ignited by a plasma-assisted igniter (PAI) under ultra-lean conditions. The experimental campaign is conducted on a single-cylinder research engine at 1000 rpm and low loads, moving up to the engine lean stable limits. The specific purpose of this work is to determine the benefits brought by the proposed strategy, referred to as M100–PAI, which compared market gasoline E5 ignited by the PAI system and conventional spark. The synergy between M100 (methanol) and Plasma-Assisted Ignition (PAI) in internal combustion engines yielded notable benefits. This combination significantly improved combustion stability if compared to the other combinations tested, by extending the lean stable limit to λ = 2.0, reducing cycle-to-cycle variability, and facilitating faster flame front acceleration, resulting in enhanced homogeneity. These enhancements, obtained with the combination M100–PAI, contributed to higher fuel efficiency, showing a 10% efficiency gain over the combination E5–gasoline spark ignition. The findings highlight the potential of innovative combustion strategies using low-carbon fuels and advanced ignition systems to meet stringent emissions regulations while improving engine performance. Full article

Methanol–gasoline blends have emerged as a promising and environmentally friendly bio-fuel option, garnering widespread attention and promotion globally. The methanol content within these blends significantly influences their quality and combustion performance. This study explores the qualitative and qualitative analysis of methanol–gasoline blends using Raman spectroscopy coupled with machine learning methods. Experimentally, methanol–gasoline blends with varying methanol concentrations were artificially configured, commencing with initial market samples. For qualitative analysis, the partial least squares discriminant analysis (PLS-DA) model was employed to classify the categories of blends, demonstrating high prediction performance with an accuracy of nearly 100% classification. For the quantitative analysis, a consensus model was proposed to accurately predict the methanol content. It integrates member models developed on clustered variables, using the unsupervised clustering method of the self-organizing mapping neural network (SOM) to accomplish the regression prediction. The performance of this consensus model was systemically compared to that of the PLS model and uninformative variable elimination (UVE)–PLS model. Results revealed that the unsupervised consensus model outperformed other models in predicting the methanol content across various types of methanol gasoline blends. The correlation coefficients for prediction sets consistently exceeded 0.98. Consequently, Raman spectroscopy emerges as a suitable choice for both qualitative and quantitative analysis of methanol–gasoline blend quality. This study anticipates an increasing role for Raman spectroscopy in analysis of fuel composition. Full article

This study explores the potentiality of low/zero carbon fuels such as methanol, methane and hydrogen for motor applications to pursue the goal of energy security and environmental sustainability. An experimental investigation was performed on a spark ignition engine equipped with both a port fuel and a direct injection system. Liquid fuels were injected into the intake manifold to benefit from a homogeneous charge formation. Gaseous fuels were injected in direct mode to enhance the efficiency and prevent abnormal combustion. Tests were realized at a fixed indicated mean effective pressure and at three different engine speeds. The experimental results highlighted the reduction of CO and CO₂ emissions for the alternative fuels to an extent depending on their properties. Methanol exhibited high THC and low NO_x emissions compared to gasoline. Methane and, even more so, hydrogen, allowed for a reduction in THC emissions. With regard to the impact of gaseous fuels on the NO_x emissions, this was strongly related to the operating conditions. A surprising result concerns the particle emissions that were affected not only by the fuel characteristics and the engine test point but also by the lubricating oil. The oil contribution was particularly evident for hydrogen fuel, which showed high particle emissions, although they did not contain carbon atoms. Full article

The exceptional properties of methanol, such as its high octane number and latent heat of evaporation, make it an advantageous fuel for efficient utilization in dual-fuel combustion techniques. The aim of this study is to investigate the effect of direct methanol injection timing on the combustion, performance and emission characteristics of a dual-fuel spark ignition engine at different injection pressures. We conducted four different direct injection pressure tests ranging from 360° ahead to 30° CA ahead at 30° CA intervals. The experimental results indicate that regardless of the injection pressure, altering the methanol injection timing from −360° to −30° CA ATDC leads to distinct combustion behavior and changes in the combustion phase. Initially, as the injection timing is delayed, the combustion process accelerates, which is followed by a slower combustion phase. Additionally, the combustion phase itself experiences a delay and then advances. Regarding performance characteristics, both the brake thermal efficiency (BTE) and exhaust gas temperature (EGT) exhibit a consistent pattern of first increasing and then decreasing as the injection timing is delayed. This suggests that there is an optimal injection timing window that can enhance both the engine’s efficiency and its ability to manage exhaust temperature. In terms of emissions, there are different trends in this process due to the different conditions under which the individual emissions are produced, with CO and HC showing a decreasing and then increasing trend, and NOx showing the opposite trend. In conclusion, regardless of the injection pressure employed, adopting a thoughtful and well-designed injection strategy can significantly improve the combustion performance and emission characteristics of the engine. The findings of this study shed light on the potential of methanol dual-fuel combustion and provide valuable insights for optimizing engine operation in terms of efficiency and emissions control. Full article