Search Results (989)

This study focuses on optimizing backfill materials to enhance the heat transfer performance of ground heat exchangers (GHEs) in ground source heat pump (GSHP) systems. A series of composite phase change material/original sand soil (CPCM/OSS) backfill materials was prepared using capric acid–myristic acid/expanded graphite (CA-MA/EG) at mass ratios of 5%, 10%, 15%, and 20%. Thermal conductivity testing, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), laboratory heat transfer tests, and 3D numerical simulations under typical intermittent summer conditions were systematically conducted. The results show that thermal conductivity, specific heat capacity, and thermal storage coefficient all increase with rising moisture content and CPCM dosage. The newly developed CPCM/OSS backfill material significantly improves the heat transfer performance of GHEs. Comprehensive thermophysical characterization indicates that the 10 wt% CPCM sample is the optimal formulation. Laboratory tests demonstrate that, relative to pure OSS backfill, the 10 wt% CPCM-doped CPCM/OSS raises the average soil temperature by approximately 2.5–2.8 °C. Numerical simulations over three consecutive days show that, relative to pure OSS backfill, the 10 wt% CPCM-doped composite enhances the heat exchange capacity per linear meter of the GHEs by 8.8%. The newly developed CPCM/OSS backfill material significantly improves the heat transfer performance of GHEs. It provides a feasible material solution and technical reference for GSHP system design. Full article

In extremely cold environments, inhaling frigid, dry air can pose significant health risks, potentially leading to airway inflammation and respiratory injury. While previous studies have examined thermal exchange within lung airways under hot-air inhalation, the majority have focused on localized regions rather than the entire respiratory tract. This study expands the scope of inquiry by simulating airflow and heat transfer throughout a more complete computed tomography (CT)-based respiratory tract, from the nasal cavity to the larynx and trachea and extending down to the 13th generation of the bronchial tree, under two cold-air inhalation scenarios at −5 °C and −20 °C. Using computational fluid dynamics, this study integrates Large Eddy Simulation with the Smagorinsky–Lilly subgrid-scale model to capture the complex interaction of turbulent flow and thermal transport in the human respiratory system. By analyzing temperature distributions, heat flux, heat-transfer coefficients, Nusselt numbers, and mass flux across the airways, the research shows how varying degrees of cold inhalation influence respiratory thermodynamics and associated biomechanical responses. As such, this study establishes a rigorous scientific foundation for the development of more sophisticated and predictive respiratory-tract models in sub-zero environments in future work. Full article

Night ventilation coupled with thermal mass is an effective means of reducing overheating in passive buildings. Successful systems require a high airflow rate coupled with enhanced convective heat transfer to the thermal mass. This work presents results for enhanced convection when the primary thermal mass is in the ceiling. Such mass distribution occurs, for example, in multi-story apartments in developing economies. Experimental results are measured in a scale model of a typical room. The original contribution is the use of upward-directed ventilation at an angle of 30° to 40° from a window located at a typical distance below the ceiling. At scaled air change rates of 4.9 air changes per hour, the measured convective heat transfer coefficient at the ceiling was 7.7 W/m² K. In contrast, when air flowed horizontally from the window, the heat transfer coefficient was 3.5 W/m² K or less, indicating that substantial improvement was gained by directing airflow toward the ceiling. To link the experimental results to an application in a full-size building, an approximate model is presented to estimate the impact of directed night ventilation on the thermal mass (specifically the concrete slab ceiling) and room air temperatures. Coupling angled flow with nighttime ventilation, the ceiling slab and peak daytime air temperature can be reduced by 5 °C compared to horizontal ventilation from a window at conventional height. These results have enabled collaborators in Gujarat, India, to launch tests in a full-scale home serving a low-income community without access to air conditioning. Full article

Injecting CO₂ into gas reservoirs is a crucial approach for enhancing natural gas recovery and achieving CO₂ geological storage, where the gas–gas diffusion behavior between CO₂ and CH₄ directly influences gas mixing efficiency. Direct observation of the spatiotemporal evolution of concentration fields during diffusion remains insufficient. In this study, a gas–gas diffusion experimental system capable of multi-time and multi-space stratified sampling within a high-temperature high-pressure PVT cell was established based on real reservoir fluid compositions. Non-equilibrium diffusion experiments were conducted under different pressures, different initial CO₂ mole fractions, and different diffusion times. A diffusion model was developed according to Fick’s second law. The results suggest that the gas column can be divided into a natural gas zone, a transition zone, and a CO₂ zone by the dimensionless concentration gradient threshold. At 5 MPa, the transition zone width expands rapidly within the first 4 h (dimensionless width increases from 0 to 0.6902), after which growth slows. Increasing pressure significantly inhibits diffusion, reducing transition zone width and prolonging equilibration time. Rising initial CO₂ concentration also suppresses diffusion mixing, particularly in the later stage. Component profile analysis confirms that, under high pressures and high CO₂ concentrations, the diffusion flux across the interface is weakened. Compared to CH₄, the diffusion equilibration time of CO₂ is shorter and more sensitive to pressure changes. The obtained diffusion coefficients (CH₄: 2.92 × 10⁻⁸ to 4.79 × 10⁻⁸ m²/s; CO₂: 3.91 × 10⁻⁸ to 6.08 × 10⁻⁸ m²/s) are on the order of 10⁻⁸ m²/s, consistent with bulk-phase PVT literature data, validating the reliability of the experimental method and inversion model. This study lays an experimental foundation for predicting multi-component gas mass transfer under conditions of CO₂-enhanced gas recovery and CO₂ geological storage. Full article

Poly(β-L-malic acid) (PMLA) has attracted considerable industrial attention due to its promising applications in biomedicine, bioplastics, and environmental fields. However, its biosynthesis is highly dependent on elevated dissolved oxygen (DO) levels, while the simultaneous production of pullulan represents a major obstacle. This study introduces a novel strategy to enhance PMLA production in Aureobasidium melanogenum by selectively inhibiting pullulan biosynthesis. We demonstrate that excessive pullulan accumulation severely impairs fermentation performance by significantly reducing oxygen transfer efficiency—an uncharacterized bottleneck in PMLA production. To address this, an ARTP-induced mutant, designated No. H13, was generated, exhibiting an 82.1% reduction in pullulan synthesis. This metabolic shift led to an 86.93% increase in the oxygen mass transfer coefficient (K_La), ultimately enhancing PMLA yield by 72.1% to 45.0 g/L with a specific production of 1.09 g/g. Transcriptomic analysis suggested a potential redirection of carbon flux toward PMLA biosynthesis through coordinated up-regulation of glycolysis and TCA cycle genes, alongside down-regulation of gluconeogenesis and pullulan-exporting ABC transporters. This work presents an alternative to enzymatic approaches by employing a consolidated mutagenesis strategy to reconfigure metabolic networks, offering a strategy for PMLA overproduction. Full article

Coaxial electrospinning technology enables the fabrication of nanofibers with a core-shell structure, thereby facilitating the encapsulation of functional materials. Its efficacy lies in the precise regulation of mass transfer behavior at the sensing interface. However, achieving the controllable preparation of core-shell fiber structures in complex environments and quantitatively predicting their mass transfer kinetics remain challenging. This study aims to establish a predictive framework combining simulation and experiment. Firstly, finite element simulations using COMSOL clarified that increasing the shell thickness or decreasing its effective diffusion coefficient can significantly delay analyte transport. A model incorporating time-varying parameters further revealed the influence of polymer swelling on the initial release kinetics. Using the diffusion of an aqueous KCl solution as a model system, experiments confirmed that increasing the shell solution concentration is an effective processing strategy for enhancing the mass transfer barrier. Based on the Box-Behnken design and response surface methodology (RSM), a quantitative model linking key process parameters to release kinetic parameters was established. Model diagnostics indicated that the regression equation is significant and reliable. Validation experiments demonstrated that the model possesses good predictive capability for the key release kinetic parameters, with prediction errors within an acceptable range. The framework established in this study indicates that active design of the mass transfer behavior of core-shell fibers can be achieved through process control, providing a quantitative predictive tool and methodological reference for the preparation of controllable mass transfer interfaces for sensing applications. Full article

In this paper, a flexible steady-state model of a highly integrated, natural convection-driven condensing methanol reactor was developed. The flowsheet model includes 1D submodels of the different sections of the integrated reactor–condenser and includes a method to estimate the maximum possible natural convection-driven flow. Experimental data are used to create a shortcut description for the heat transfer coefficients in the model. The model results indicate that when heat losses can be mitigated, autothermal operation is possible. The major part of the heat integration takes place in the economizer section; however, a significant amount of heat transfer occurs at the catalyst bed also. The model predicts that the loop mass flow and single-pass conversion strongly depend on the catalyst bed inlet temperature. Experimentally measured catalyst preheater and condenser duties suggest, however, that the model-calculated mass flow is likely too low and that it is less dependent on the catalyst bed inlet temperature than the model predicts. A possible cause for this is the neglect of radial temperature gradients in the catalyst bed in the model, overestimating the conversion. Another possible cause is a measurement error in the bed inlet temperature, causing the actual temperature to be lower than the measured value. Natural convection calculations show that the maximum achievable flow strongly depends on the single-pass conversion and that given a single-pass conversion, a minimum temperature difference is required for flow in the right direction. Sensitivity analyses (neglecting heat losses to the environment) show that with the current heat transfer description, the feasible operating range for autothermal, natural convection-driven flow is sizeable. However, at lower recycle mass flows, heat transfer is too fast, leading to premature condensation in the economizer section. If the heat transfer coefficient is smaller than the currently predicted value, autothermal operation is possible in a wide range of conditions. If heat losses are mitigated, the maximum productivity of 2000 ${\mathrm{kg}}_{\mathrm{MeOH}}{\mathrm{m}}_{\mathrm{cat}.}^{-3}{\mathrm{h}}^{-1}$ is achievable at high pressure, a moderate catalyst bed inlet temperature and a low condenser temperature. Full article

This study presents an innovative approach for the selective extraction of Co(II) and its separation from Ni(II) using ethyl ester glycine–betaine derivatives, specifically tri(n-pentyl)[2-ethoxy-2-oxoethyl]ammonium dicyanamide, as extractants in combination with continuous-mode liquid–liquid contact. Semi-pilot-scale implementation requires non-equilibrium conditions, characterized by short contact times between effluent and extractant phases. To address this, we propose dissolving analog of glycine–betaine ionic liquid (AGB-IL) in low-viscosity MIBK solvents to enhance mass transfer while reducing dependence on fossil-based solvents. Liquid–liquid extraction and continuous-flow stripping experiments were designed based on prior batch results and conducted in a saline environment, employing a chaotropic electrolyte for extraction and a kosmotropic electrolyte for stripping. Both open and closed systems were tested to compare extractive performance with batch conditions and with scenarios representative of industrial operations. Results indicate that continuous-flow systems achieve performance comparable to batch systems in terms of extraction efficiency, Co/Ni separation coefficients, and recyclability. These findings provide proof of concept for the development of semi-pilot and pilot-scale processes for efficient cobalt recovery. Full article

Modern aircraft fuel tank explosion protection relies critically on inerting efficiency. This study presents and investigates a novel scrubbing deoxygenation strategy utilizing mixed inert gas (MIG) generated by oxygen-consuming inerting systems for high-vapor-pressure RP5 aviation fuel. A high-fidelity computational fluid dynamics (CFD) numerical framework was established using the Eulerian–Eulerian two-fluid model coupled with Higbie’s penetration theory, with experimental validation ensuring computational accuracy (maximum errors for ullage oxygen concentration and dissolved oxygen in fuel controlled within 4.11% and 5.23%, respectively). The research systematically elucidates the influence mechanisms of bubble diameter, MIG temperature, and superficial gas velocity on mass transfer characteristics (oxygen mass transfer coefficient and volumetric mass transfer coefficient). Key findings reveal that reducing bubble diameter achieves localized polarization of mass transfer intensity in the central plume region through an “area-velocity” synergistic effect, with the oxygen volumetric mass transfer coefficient at 1.0 mm diameter increasing by 51.3% compared to 2.5 mm. The performance enhancement from superficial gas velocity primarily stems from the “area multiplication effect” triggered by surging gas holdup. Notably, MIG temperature exhibits a unique three-stage reversal characteristic of “kinetically dominated early stage, thermodynamically controlled late stage” on deoxygenation performance. These results provide critical physical foundations for the forward design of next-generation multifunctional onboard inerting systems. Full article

High-load sliding components, including gun barrels, are susceptible to accelerated wear and damage due to coupled thermal-mechanical stresses and reciprocating frictional conditions. Therefore, enhancing their operational lifespan requires the application of wear-resistant coatings with high melting points for effective surface protection. In this study, Ta-10W alloy coatings were deposited on CrNi3MoVA steel substrates through electricspark deposition, focusing on deposition voltage as a critical parameter. Experimental results indicate that the Ta-10W coatings are primarily composed of α-Fe, α-Ta₂O₅, δ-Ta₂O₅, α-Ta(W), and Fe-W intermetallic phases. An increase in deposition voltage facilitates enhanced melting and mass transfer, thereby promoting solid solution and oxidation strengthening, which results in improved hardness. However, higher voltages also induce defects such as porosity and microcracks. Hardness measurements and friction-wear tests demonstrate that coatings deposited at 80 V exhibit optimal performance, attaining the highest hardness (~753 HV) and a friction coefficient similar to that at 60 V. Conversely, the friction coefficient increases at 100 V due to defects and coating spalling. The wear mechanism transitions from adhesive wear at 60 V to adhesive wear with minor plastic deformation at 80 V and ultimately to spalling wear at 100 V. Finite element thermomechanical simulations reveal that increasing voltage significantly elevates the equivalent interfacial stress (600–1150 MPa), thus correlating with the propensity for microcracks to propagate into longitudinal semi-penetrating cracks at elevated voltages. This study establishes a theoretical foundation for optimizing electricspark deposition process parameters and contributes to the reliability design of Ta-W alloy coatings. Full article

Solar water heating systems (SWHS) offer a sustainable solution for reducing reliance on conventional energy sources; however, their performance is often limited by insufficient heat transfer within the collector. This study presents a CFD-based numerical investigation on the optimization of finned thermal collectors in a solar water heating system using Al₂O₃/water hybrid nanofluid. The effects of nanoparticle volume fraction (1–3%), fin geometry (triangular and hexagonal), and mass flow rate (5–20 kg/h) on the thermal and heat transfer performance of the system were analyzed. Key performance indicators including absorber/PV temperature, outlet fluid temperature, convective heat transfer coefficient, thermal efficiency, and improved daily efficiency were evaluated under transient operating conditions. The results show that increasing Al₂O₃ concentration enhances heat transfer and thermal efficiency due to improved thermophysical properties of the working fluid. Fin geometry significantly influences thermal behavior, with hexagonal fins generally producing higher outlet temperatures and thermal efficiency of 65%, while triangular fins provide higher daily efficiency improvement under optimized conditions. The convective heat transfer coefficient increased with both nanoparticle concentration and flow rate, reaching peak values during mid-day hours corresponding to maximum solar input. The study confirms that combining optimized fin structures with Al₂O₃/water nanofluids provides an effective strategy for improving the thermal performance of solar water heating collectors, while CFD modelling offers a reliable approach for system design and performance prediction. Full article

To extend shelf life and enjoy the aroma and bioactive properties of wild nettle all year long, a drying operation is needed. This research aimed to compare conventional drying with modern drying technology using ultrasound to investigate intensification of the process together with the quality of sensitive leafy herbs. The kinetic, energy, and selected quality attributes typical for dry products of plant origin were analyzed: color, water activity, and polyphenol retention. Drying tests on wild nettle were carried out at two temperatures of 50 and 70 °C, with and without airborne ultrasound (100 and 200 W). The results showed that the application of ultrasound contributed to higher drying rates throughout the moisture content range compared to convective drying at the same air temperature. The higher the ultrasound power, the higher the increase in drying rate and shorter drying time, confirming intensification of moisture diffusion due to ultrasound assistance. The higher temperature and ultrasound level strongly influenced the final appearance and antioxidant properties of dry nettle, leading to color change (dE00 = 8.2) and polyphenol degradation (36%). However, all of the analyzed drying variants reduced the risk of microbial development (a_w = 0.444). In conclusion, ultrasound can be effectively applied to intensify the drying of nettle leaves by providing more favorable drying conditions, including a 53% reduction in drying time and a drying rate more than twice as fast as that of convective drying. Full article

Ammonia (NH₃) from pig houses contributes to air-quality degradation and odor, yet farm-level emissions are highly sensitive to housing design, slurry chemistry and management. This study developed and validated a minute-resolution dynamic model for indoor NH₃ concentration and house-level emission in a mechanically ventilated finishing pig house. Volatilization from the slurry surface was computed from total ammonia nitrogen (TAN), pH and temperature using established mass-transfer formulations, and coupled between two zones (pit headspace and room airspace) via advection and diffusion across the slatted-floor open area. Over one production cycle, key drivers and indoor NH₃ were monitored; discrete TAN observations were upsampled to minute resolution by linear interpolation. Model coefficients were optimized by a genetic algorithm with chronological 70/30 splits for calibration and validation in the grower and finisher phases, respectively. The calibrated model reproduced minute-scale dynamics (validation RMSE 1.53–1.76 ppm, R² 0.87–0.88; MAPE 9.95–10.87%). Sobol’s global sensitivity analysis identified ventilation rate as the dominant driver of indoor concentration, and TAN and slurry pH as the principal drivers of emissions. The model provides decision support for minute-scale monitoring and management, and can be integrated with factor-control methods and ICT-based supervisory systems. Full article

Spar-type floating offshore wind turbines (FOWTs) operating in deep-sea environments are subjected to coupled wind and wave excitations spanning a wide frequency range, rendering single-frequency passive damping solutions inadequate. A folded-beam nonlinear energy sink (FB-NES) is proposed for broadband vibration suppression of spar-type FOWTs. The device employs pre-buckled elastic beam arms integrated with constrained layer damping patches, and a closed-form analytical relationship between the beam geometric parameters and the nonlinear stiffness coefficients is derived, enabling direct parameter design without iterative calibration. The pre-buckled geometry introduces a negative-stiffness mechanism that substantially lowers the targeted energy transfer (TET) threshold, ensuring device engagement under all normal operational sea states. A 14-degree-of-freedom aero-hydro-elastic model of the NREL 5 MW OC3-Hywind FOWT with the FB-NES is established via the Euler–Lagrange formulation and validated against OpenFAST. Based on the numerical results under operational and extreme parked load cases, the FB-NES achieves substantial broadband vibration reductions that grow monotonically with wave severity, consistently and substantially surpassing both the optimally tuned mass damper (TMD) and a conventional cubic nonlinear energy sink of equal mass. Wavelet analysis confirms that targeted energy transfer, rather than direct viscous damping, is the dominant energy dissipation mechanism. The FB-NES also maintains effective control over a wide frequency detuning range, demonstrating superior robustness compared to the TMD. Full article

The reaction dynamics of weakly-bound nuclear systems at near-barrier energies is a compelling topic in nuclear physics. This review summarizes decades of experimental work by the Nuclear Reaction Group at the China Institute of Atomic Energy. Using transfer reactions with the distorted wave born approximation and asymptotic normalization coefficient analyses, we confirm the first excited neutron halo (¹³C) on the $\beta$-stability line and identified new halo states in ¹²B. Total reaction cross-section measurements revealed proton halo nuclei ${}^{27}\mathrm{P}$ and ${}^{29}\mathrm{S}$, with core enlargement observed in ${}^{27}\mathrm{P}$ and ${}^{28}\mathrm{P}$. We established conditions for halo formation and delineated the proton halo existence region. In two-proton emission studies, we observed ${}^2\mathrm{He}$ cluster emission from highly excited ${}^{17,18}\mathrm{Ne}$ and ${}^{28,29}\mathrm{S}$, with ${}^{29}\mathrm{S}$ being the second such case internationally. In $\beta$-delayed decay, we discovered $\beta$2p emission in ${}^{22}\mathrm{Si}$ and determined its mass, observing isospin-symmetry breaking in ${}^{20}\mathrm{Mg}$, ${}^{22}\mathrm{Si}$, and ${}^{27}\mathrm{S}$. Decay schemes for ${}^{27}\mathrm{S}$ and ${}^{26}\mathrm{P}$ addressed the ${}^{26}\mathrm{Al}$ abundance problem. For nuclear interactions, we investigated the ${}^6\mathrm{He}$ optical potential, finding the dispersion relation inapplicable for ${}^6\mathrm{He}$ + ${}^{209}\mathrm{Bi}$, and developed notch and Bayesian methods to constrain uncertainties. For unstable nuclei, the proton drip-line systems ⁸B and ¹⁷F have been intensively studied via complete kinematics measurements of the ⁸B + ¹²⁰Sn and ¹⁷F + ⁵⁸Ni reactions, respectively. The results show that elastic breakup dominates for proton-halo ${}^8\mathrm{B}$, while inelastic breakup prevails for ${}^{17}\mathrm{F}$, with proton-rich nuclei exhibiting lower breakup probabilities than neutron-halo nuclei due to Coulomb effects. Fusion studies revealed sub-barrier enhancement in ${}^{17}\mathrm{F}$ + ${}^{58}\mathrm{Ni}$ from continuum couplings. We propose direct fusion–evaporation measurements with deflection systems integrated with breakup detection to disentangle complete and incomplete fusion channels. Full article