Search Results (14)

We draw connections between eight different theories used to describe microscopic (atomic) and macroscopic (seismological) scales. In particular, we show that all these different theories belong to a particular case of a single partial differential equation, allowing us to gain new physical insights and draw connection among them. With this general understanding, we apply the micropolar theory to the description of shear-wave dispersion in marine sediments, showing how we can reproduce observations by only using two micropolar parameters in contrast to the seventeen parameters required by modifications of Biot’s theory. We next establish direct connections between the micro (laboratory) and macro (seismological) scales, allowing us to predict (and confirm) the presence of post-perovskite in the lowermost mantle based on laboratory experiments and to predict the characteristic length $L_c$ at which shear deformation becomes significant at seismological scales in the lowermost mantle. Full article

We collected approximately 500 ScS–S differential travel times passing beneath the Philippines with various azimuths to discuss whether there were azimuthal variations in the ScS–S time residuals. By correcting for mantle heterogeneity using a three-dimensional (3D) mantle velocity model, we found a large variance reduction in the ScS–S residuals. In addition, the strong negative correlation between the S and ScS–S time residuals was greatly reduced, while the positive correlation between the ScS and ScS–S time residuals moderately improved, indicating that the corrected ScS–S residuals are manifestations of the lower half of the lower mantle structure. Next, we corrected for the local-scale heterogeneity in the lower mantle by subtracting the bin-averaged ScS–S residuals, and we experimented with fitting the trigonometric functions in terms of the propagation azimuth θ to the ScS–S residuals, suggesting that a 2θ variation is significant. If we accept the hypothesis of azimuthal anisotropy in the lowermost mantle, the fastest direction of the S-wave velocity was east-southeast–west-northwest (N97.5° E– N82.5° W), and the amplitude of the azimuthal anisotropy was approximately 1.4% anisotropy if we assume a D″ thickness of 300 km. Full article

Granulites and associated dykes from the less well-studied southern Ivrea–Verbano Zone (around Ivrea town) are characterized by combining field, macro, micro and chemical (major and trace-element mineral composition) data to identify chemical and rheological variations in the lower crust that could be relevant for geodynamic implications. The Ivrea granulites are similar to those in the Lower Mafic Complex of the central Ivrea–Verbano Zone. The mafic lithologies experienced stealth metasomatism (pargasitic amphibole and An-rich plagioclase) that occurred, at suprasolidus conditions, by a pervasive reactive porous flow of mantle-derived orogenic (hydrous) basaltic melts infiltrated along, relatively few, deformation-assisted channels. The chemical composition of the metasomatic melts is similar to that of melts infiltrating the central and northern Ivrea–Verbano Zone. This widespread metasomatism, inducing a massive regional hydration of the lowermost Southalpine mafic crust, promoted a plastic behavior in the lowermost part of the crust during the Early Mesozoic and, ultimately, the Triassic extension of the Variscan crust and the beginning of the Alpine cycle. Full article

The Miocene Columbia River Basalt Group (CRBG) of the Pacific Northwest of the United States is the world’s youngest and smallest large igneous province. Its earliest formations are the Imnaha, Steens, and now the Picture Gorge Basalt (PGB), and they were sourced from three different dike swarms exposed from SE Washington to Nevada to northcentral Oregon. PGB is often viewed to be distinct from the other formations, as its magmas are sourced from a shallow, relatively depleted, and later subduction-induced metasomatized mantle, along with its young stratigraphic position. It has long been known that the lowermost American Bar flows (AB1&2) of the Imnaha Basalt are chemically similar to those of the PGB, yet the Imnaha Basalt is generally thought to carry the strongest plume source component. These opposing aspects motivated us to revisit the compositional relationships between AB1&2 and PGB. Our findings suggest that tapping a shallow, variably depleted, and metasomatized mantle reservoir to produce earliest CRBG lavas occurred across the province, now pinpointed to ~17 Ma. Moreover, compositional provinciality exists indicating regional differences in degree of depletion and subduction overprint that is preserved by regionally distributed lavas, which in turn implies relatively local lava emplacement at this stage. Full article

Qualitative and quantitative analysis of seismic waveforms sensitive to the core–mantle boundary (CMB) region reveal the presence of ultralow-velocity zones (ULVZs) that have a strong decrease in compressional (P) and shear (S) wave velocity, and an increase in density within thin structures. However, understanding their physical origin and relation to the other large-scale structures in the lowermost mantle are limited due to an incomplete mapping of ULVZs at the CMB. The SKS and SPdKS seismic waveforms is routinely used to infer ULVZ presence, but has thus far only been used in a limited epicentral distance range. As the SKS/SPdKS wavefield interacts with a ULVZ it generates additional seismic arrivals, thus increasing the complexity of the recorded wavefield. Here, we explore utilization of the multi-scale sample entropy method to search for ULVZ structures. We investigate the feasibility of this approach through analysis of synthetic seismograms computed for PREM, 1-, 2.5-, and 3-D ULVZs as well as heterogeneous structures with a strong increase in velocity in the lowermost mantle in 1- and 2.5-D. We find that the sample entropy technique may be useful across a wide range of epicentral distances from 100° to 130°. Such an analysis, when applied to real waveforms, could provide coverage of roughly 85% by surface area of the CMB. Full article

Continental rifts have a significant role in supercontinent breakup and the development of sedimentary basins. The Australian Adelaide Superbasin is one of the largest and best-preserved rift systems that initiated during the breakup of Rodinia, yet substantial challenges still hinder our understanding of its early evolution and place within the Rodinian supercontinent. In the past decade, our understanding of rift and passive margin development, mantle plumes and their role in tectonics, geodynamics of supercontinent breakup, and sequence stratigraphy in tectonic settings has advanced significantly. However, literature on the early evolution of the Adelaide Superbasin has not been updated to reflect these advancements. Using new detrital zircon age data for provenance, combined with existing literature, we examine the earliest tectonic evolution of the Adelaide Superbasin in the context of our modern understanding of rift system development. A new maximum depositional age of 893 ± 9 Ma from the lowermost stratigraphic unit provides a revised limit on the initiation of sedimentation and rifting within the basin. Our model suggests that the basin evolved through an initial pulse of extension exploiting pre-existing crustal weakness to form half-grabens. Tectonic quiescence and stable subsidence followed, with deposition of a sourceward-shifting facies tract. Emplacement and extrusion of the Willouran Large Igneous Province occurred at c. 830 Ma, initiating a new phase of rifting. This rift renewal led to widespread extension and subsidence with the deposition of the Curdimurka Subgroup, which constitutes the main cyclic rift sequence in the Adelaide Superbasin. Our model suggests that the Adelaide Superbasin formed through rift propagation to an apparent triple junction, rather than apical extension outward from this point. In addition, we provide evidence suggesting a late Mesoproterozoic zircon source to the east of the basin, and show that the lowermost stratigraphy of the Centralian Superbasin, which is thought to be deposited coevally, had different primary detrital sources. Full article

The vibrational and thermodynamic properties of minerals are key to understanding the phase stability and the thermal structure of the Earth’s mantle. In this study, we modeled hydrous iron-bearing bridgmanite (Brg) and post-perovskite (PPv) with different [Fe³⁺-H] defect configurations using first-principles calculations combined with quasi-harmonic approximations (QHA). Fe³⁺-H configurations can be vibrationally stable in Brg and PPv; the site occupancy of this defect will strongly affect its thermodynamic properties and particularly its response to pressure. The presence of Fe³⁺-H introduces distinctive high-frequency vibrations to the crystal. The frequency of these peaks is configuration dependence. Of the two defect configurations, [${\mathrm{Fe}}_{\mathrm{Si}}^{\prime }+{\mathrm{OH}}^{·}]$ makes large effects on the thermodynamic properties of Brg and PPv, whereas [${\mathrm{V}}_{\mathrm{Mg}}^{″}+{\mathrm{Fe}}_{\mathrm{Mg}}^{·}+{\mathrm{OH}}^{·}$] has negligible effects. With an expected lower mantle water concentrations of <1000 wt. ppm the effect of Fe³⁺-H clusters on properties such as heat capacity and thermal expansion is negligible, but the effect on the Grüneisen parameter γ can be significant (~1.2%). This may imply that even a small amount of water may affect the anharmonicity of Fe³⁺-bearing MgSiO₃ in lower mantle conditions and that when calculating the adiabaticity of the mantle, water concentrations need to be considered. Full article

Both seismic observations of dense low shear velocity regions and models of magma ocean crystallization and mantle dynamics support enrichment of iron in Earth’s lowermost mantle. Physical properties of iron-rich lower mantle heterogeneities in the modern Earth depend on distribution of iron between coexisting lower mantle phases (Mg,Fe)O magnesiowüstite, (Mg,Fe)SiO₃ bridgmanite, and (Mg,Fe)SiO₃ post-perovskite. The partitioning of iron between these phases was investigated in synthetic ferrous-iron-rich olivine compositions (Mg_0.55Fe_0.45)₂SiO₄ and (Mg_0.28Fe_0.72)₂SiO₄ at lower mantle conditions ranging from 33–128 GPa and 1900–3000 K in the laser-heated diamond anvil cell. The resulting phase assemblages were characterized by a combination of in situ X-ray diffraction and ex situ transmission electron microscopy. The exchange coefficient between bridgmanite and magnesiowüstite decreases with pressure and bulk Fe# and increases with temperature. Thermodynamic modeling determines that incorporation and partitioning of iron in bridgmanite are explained well by excess volume associated with Mg-Fe exchange. Partitioning results are used to model compositions and densities of mantle phase assemblages as a function of pressure, FeO-content and SiO₂-content. Unlike average mantle compositions, iron-rich compositions in the mantle exhibit negative dependence of density on SiO₂-content at all mantle depths, an important finding for interpretation of deep lower mantle structures. Full article

The Jijal ultramafic–mafic complex in Pakistan probably preserves the most complete fragments of the petrological Moho. However, a few studies argue for multiple origins (including petrogenetic speculations and tectonic reconstructions) for different lithologies. One of the main reasons for this dispute is the lack of direct age information of the ultramafic rocks. Zircon grains, despite generally being exotic in ultramafic rocks, can provide significant insights into the petrogenetic process of the host ultramafic rocks. This study reports the first zircon U–Pb age and Lu–Hf and trace element data for zircon grains separated from chromitite lenses within the peridotite, which is commonly considered the lowermost part of the Jijal complex. These zircon grains yield concordant ²⁰⁶Pb/²³⁸U ages of ~182 ± 3 Ma, which is much older than the late Early Cretaceous age (<120 Ma) of the Jijal complex, and lying above it, the other complexes of the Kohistan paleo-arc. Furthermore, these Jurassic zircon grains present radiogenic εHf(t) values (+9.7 to +6.0) which are obviously lower than the values for the Cretaceous zircon grains of the Kohistan arc. From integrated analysis of the zircon trace element signatures (e.g., high Th, U, Th/U, and U/Yb ratios) and regional geology, we speculate that these zircon grains came from a ‘missing’ Early Jurassic arc akin to the Gangdese belt to the east, and entered the mantle by oceanic subduction processes. Although these Jurassic zircon grains cannot actually constrain the formation age of the chromitite as well as the peridotite, it reminds us that some cryptic pre-Cretaceous complexes and geodynamic processes were incorporated in building the oceanic crust of the Jijal intra-oceanic arc, or the mantle section (at least part of it) should probably belong to the Indus ophiolite mélange. Further research, particularly chronological studies on mantle (or ultramafic) rocks, as well as detailed geological mapping, should be carried out in the future for solving this issue. Full article

It is widely accepted that the lower mantle consists of mainly three major minerals—ferropericlase, bridgmanite and calcium silicate perovskite. Ferropericlase ((Mg,Fe)O) is the second most abundant of the three, comprising approximately 16–20 wt% of the lower mantle. The stability of ferropericlase at conditions of the lowermost mantle has been highly investigated, with controversial results. Amongst other reasons, the experimental conditions during laser heating (such as duration and achieved temperature) have been suggested as a possible explanation for the discrepancy. In this study, we investigate the effect of pulsed laser heating on the stability of ferropericlase, with a geochemically relevant composition of Mg_0.76Fe_0.24O (Fp24) at pressure conditions corresponding to the upper part of the lower mantle and at a wide temperature range. We report on the decomposition of Fp24 with the formation of a high-pressure (Mg,Fe)₃O₄ phase with CaTi₂O₄-type structure, as well as the dissociation of Fp24 into Fe-rich and Mg-rich phases induced by pulsed laser heating. Our results provide further arguments that the chemical composition of the lower mantle is more complex than initially thought, and that the compositional inhomogeneity is not only a characteristic of the lowermost part, but includes depths as shallow as below the transition zone. Full article

$\delta$ -AlOOH has been shown to be stable at the pressure–temperature conditions of the lower mantle. However, its stability remains uncertain at the conditions expected for the lowermost mantle where temperature is expected to rise quickly with increasing depth. Our laser-heated diamond-anvil cell experiments show that $\delta$ -AlOOH undergoes dehydration at ∼2000 K above 90 GPa. This dehydration temperature is lower than geotherm temperatures expected at the bottom ∼700 km of the mantle and suggests that $\delta$ -AlOOH in warm slabs would dehydrate in this region. Our experiments also show that the released H ${}_2$ O from dehydration of $\delta$ -AlOOH can react with metallic iron, forming iron oxide, iron hydroxide, and possibly iron hydride. Our observations suggest that H ${}_2$ O from the dehydration of subducting slabs, if it occurs, could alter the chemical composition of the surrounding mantle and core regions. Full article

The thermoelastic properties of K_0.7Na_0.3AlSi₃O₈ hollandite and NaAlSi₂O₆ jadeite, synthesized from a (K, Na)-felspar (microcline), were investigated by a combination of in situ energy dispersive synchrotron X-ray radiation and multi-anvil techniques at high pressure (P) and temperature (T) up to 21 GPa and 1700 K. The second-order phase transformation was found to occur in hollandite at ~16 GPa from tetragonal I/4m (hollandite-I) to monoclinic I2/m (hollandite-II), which confirms the previous report that the incorporation of Na in the hollandite structure decreases the transformation pressure. Fitting the pressure–volume–temperature data to the Birch–Murnaghan equation of state yielded estimates of the thermoelastic parameters for jadeite as well as the K_0.7Na_0.3AlSi₃O₈ hollandite-I and -II phases, which indicate that the incorporation of Na is likely to decrease the bulk moduli of both hollandite phases. The obtained thermoelastic parameters were combined with those of other mantle minerals reported previously to estimate the density of continental materials along an average mantle geotherm. Based on our results, continental crust and sediment become, respectively, 11% and 15% denser than the pyrolitic mantle at pressure >10 GPa, suggesting that once pulled down to the critical depth of ~300 km, the continental portions of the slab can subduct further into the deep mantle, down to the lowermost part of the mantle transition region. Full article

Seismic anisotropy is observed above the core-mantle boundary in regions of slab subduction and near the margins of Large Low Shear Velocity Provinces (LLSVPs). Ferropericlase is believed to be the second most abundant phase in the lower mantle. As it is rheologically weak, it may be a dominant source for anisotropy in the lowermost mantle. Understanding deformation mechanisms in ferropericlase over a range of pressure and temperature conditions is crucial to interpret seismic anisotropy. The effect of temperature on deformation mechanisms of ferropericlase has been established, but the effects of pressure are still controversial. With the aim to clarify and quantify the effect of pressure on deformation mechanisms, we perform room temperature compression experiments on polycrystalline periclase to 50 GPa. Lattice strains and texture development are modeled using the Elasto-ViscoPlastic Self Consistent method (EVPSC). Based on modeling results, we find that $\left\{110\right\}⟨1\overline{1}0⟩$ slip is increasingly activated with higher pressure and is fully activated at ~50 GPa. Pressure and temperature have a competing effect on activities of dominant slip systems. An increasing $\left\{100\right\}⟨011⟩$ : $\left\{110\right\}⟨1\overline{1}0⟩$ ratio of slip activity is expected as material moves from cold subduction regions towards hot upwelling region adjacent to LLSVPs. This could explain observed seismic anisotropy in the circum-Pacific region that appears to weaken near margins of LLVSPs. Full article

In this study, we conduct numerical simulations of thermochemical mantle convection in a 2D spherical annulus with a highly viscous lid drifting along the top surface, in order to investigate the interrelation between the motion of the surface (super)continent and the behavior of chemical heterogeneities imposed in the lowermost mantle. Our calculations show that assembly and dispersal of supercontinents occur in a cyclic manner when a sufficient amount of chemically-distinct dense material resides in the base of the mantle against the convective mixing. The motion of surface continents is significantly driven by strong ascending plumes originating around the dense materials in the lowermost mantle. The hot dense materials horizontally move in response to the motion of continents at the top surface, which in turn horizontally move the ascending plumes leading to the breakup of newly-formed supercontinents. We also found that the motion of dense materials in the base of the mantle is driven toward the region beneath a newly-formed supercontinent largely by the horizontal flow induced by cold descending flows from the top surface occurring away from the (super)continent. Our findings imply that the dynamic behavior of cold descending plumes is the key to the understanding of the relationship between the supercontinent cycle on the Earth’s surface and the thermochemical structures in the lowermost mantle, through modulating not only the positions of chemically-dense materials, but also the occurrence of ascending plumes around them. Full article