Search Results (178)

This study investigates the thermal response and surface modification of low-carbon manganese-alloyed 20GL steel during electrolytic plasma hardening. The objective was to evaluate the feasibility of surface hardening 20GL steel—traditionally considered difficult to quench—by combining high-rate surface heating with rapid cooling in an electrolyte medium. To achieve this, a transient two-dimensional heat conduction model was developed to simulate temperature evolution in the steel sample under three voltage regimes. The model accounted for dynamic thermal properties and non-linear boundary conditions, focusing on temperature gradients across the thickness. Experimental temperature measurements were obtained using a K-type thermocouple embedded at a depth of 2 mm, with corrections for sensor inertia based on exponential response behavior. A comparison between simulation and experiment was conducted, focusing on peak temperatures, heating and cooling rates, and the effective thermal penetration depth. Microhardness profiling and metallographic examination confirmed surface strengthening and structural refinement, which intensified with increasing voltage. Importantly, the study identified a critical cooling rate threshold of approximately 50 °C/s required to initiate martensitic transformation in 20GL steel. These findings provide a foundation for future optimization of quenching strategies for low-carbon steels by offering insight into the interplay between thermal fluxes, surface kinetics, and process parameters. Full article

In this study, we have explored the thermomechanical processing on 0.1C3Mn steel to produce an ultrafine-grained (UFG) dual-phase (DP) microstructure. The composition was designed to allow a decrease in temperature for the warm deformation of austenite. It was found that the warm deformation of austenite induced a dramatic ferrite transformation, in contrast to the absence of the formation of ferrite in the well-annealed state. Compression by 60% at 650 °C resulted in the generation of a UFG-DP microstructure with a ferrite grain size of 1.4 μm and a ferrite volume fraction of 62%. The UFG-DP 0.1C3Mn steel presents a good combination of strength, ductility and fracture resistance, and the fracture strain of the UFG-DP is higher than the as-quenched low-carbon martensite. The high fracture strain of the UFG-DP could be attributed to delayed void nucleation and constrained void growth, as revealed by the quantitative X-ray tomography. Full article

This study systematically investigates the influence mechanism of the element Cr on the mechanical properties of the heat-affected zone in pipeline steels for supercritical CO₂ transportation. Microstructural evolution in the heat affected-zone was characterized through thermal simulation tests, Charpy impact testing (−10 °C), and microhardness measurements, complemented by multiscale microscopic analyses (optical microscopy, scanning electron microscopy, electron backscatter diffraction, and transmission electron microscopy). The results demonstrate that Cr addition enhances the base metal’s resistance to supercritical CO₂ corrosion but reduces its low-temperature impact toughness from 277 J to 235 J at −10 °C. Notably, the intercritical heat-affected zone exhibits severe embrittlement, with impact energy plummeting from 235 J (base metal) to 77 J. Microstructural analysis reveals that Cr interacts with carbon to form stable carbonitride particles, which reduce the free carbon concentration and diffusion coefficient in austenite, thereby inducing heterogeneous austenitization. Undissolved carbonitrides pin grain boundaries, creating carbon concentration gradients. During rapid cooling, these localized carbon-enriched microregions preferentially transform into core–shell-structured M-A constituent, characterized by a micro-twin containing retained austenite core encapsulated by high hardness lath martensite. The synergistic interaction between micro-twins and interfacial thermal mismatch stress induces localized stress concentration, triggering microcrack nucleation and subsequent toughness degradation. Full article

S1100QL and S1300QL steels are classified as fine-grained steels with a low-carbon martensitic structure. Tandem welding is a method of creating a joint by melting two electrode wires in a one-behind-the-other configuration. This article presents the effects of creating dissimilar joints, elements of varying thicknesses made from S1100QL and S1300QL steels. The analysis focused on temperature changes in the heat-affected zone (HAZ) during welding, as well as the macro and microstructure, and the properties of the joints created at welding speeds of 80, 90, and 100 cm/min. The shortest cooling time (t8/5) in the HAZ for S1300QL steel was 9.4 s, while the longest was 12.4 s. Thermal cycle simulations were performed for the analyzed materials, with a cooling time of 5 s. The test results demonstrated that TWIN welding was stable, and an optimum welding speed is 80 cm/min. The HAZ microstructure for the highest cooling speed (t8/5 = 5 s) of S1100QL steel contains, in addition to martensite, lower bainite, while S1300QL steel consists of martensite. Tempered martensite was also detected at slower cooling rates. For all speed variants, the impact energy is above 27 J at a test temperature of −40 °C. In turn, hardness tests showed that the base material for both steels has the highest hardness. However, the lowest hardness was found for the weld. Full article

To optimize heat treatment of gears for high-end equipment and enhance their fatigue resistance, this paper studied the effects of Al, Mn and Cr content on surface microstructure, i.e., martensite, retained austenite, grain size, hardened layer depth and residual stress under different carburizing temperatures and low tempering of 20MnCr5 steel FZG gear. With numerical simulation combined with experimental verification, this paper establishes a simulation model for the carburizing process of 20MnCr5 steel FZG gear, analyzing the microstructure and retained austenite volume of the gear surface, after carburizing and quenching, by a scanning electronic microscope (SEM) and X-ray diffraction (XRD). In addition, the paper reveals the influence of the optimized heat treatment on the residual stress of the gear regulated with Al, Mn and Cr content in the meshing wear range of 200~280 µm. This study provides a guiding model theory and experimental verification for regulating proportions of alloying elements and optimizing the heat treatment process of low-carbon-alloy steel. Full article

The isothermal bainitic transformation kinetics, microstructure, and mechanical properties of the quenched low-carbon high-strength steel have been investigated via dilatometric measurements, microstructural characterization, and mechanical tests. The results show that the pre-transformed isothermal bainite promotes martensitic transformation, increasing the martensitic transformation temperature, and enhancing the transformation rate. The microstructure of the 400 °C isothermal steel consists predominantly of lath bainite ferrite with dot/slender M-A constituents, whereas the steel treated at 450 °C contains a combination of martensite/lath bainite and granular bainite. The presence of massive M-A constituents contributes to brittle fracture as these constituents tend to promote crack initiation. Hence, the 450 °C treatment, which leads to the formation of massive M-A constituents, induces brittleness, while the finer M-A constituents formed at 400 °C exert minimal influence on the toughness and result in a more stable microstructure owing to their small size and the surrounding fine lath microstructure. The differences in microstructure and properties between the steels treated at 400 °C and 450 °C illustrate the importance of controlling the quenching cooling rate in the high-temperature bainitic transformation region during thick plate quenching processes. Full article

Thermomechanical processing by applying deformation-induced ferrite transformation (DIFT) is an effective method of producing ultrafine-grained (UFG) ferritic steels, which usually present high yield strength but low strain hardening. In this study, we explored the concept of DIFT in the processing of UFG dual-phase (DP) steel, in order to improve its strain hardening capability and thus its ductility. The processing temperature was reduced to enhance the dislocation storage in austenite. It was found that the warm deformation of austenite induced a dramatic occurrence of DIFT, resulting in the formation of UFG-DP microstructures along the whole thickness of the specimen. In the UFG-DP microstructure, the average ferrite grain size was 1.2 μm and the ferrite volume fraction was 44 vol.%. The observation of twinned martensite suggests the occurrence of carbon partitioning during the DIFT process. The UFG-DP microstructure exhibited a good combination of strength and ductility, which was enabled by the synergy of the ultrafine ferrite grains and the efficient composite effect. The outcome of this study provides a novel pathway to develop advanced hot-rolled steels with a UFG-DP microstructure and which are associated with the advantages of their readiness to be scaled up and low costs. Full article

Low-cost and low-alloy dual-phase (DP) steel with a tensile strength (TS) above 1000 MPa and high ductility is in great demand in the automobile industry. An approach to using a medium-carbon and fibrous DP structure for developing such new DP steel has been proposed. The microstructure and mechanical performance of fibrous DP steel obtained via partial reversion from martensite in Fe-C-Mn-Si low-alloy steel have been investigated. The TS of the as-quenched DP steel is above 1300 MPa, while the total elongation is less than 6%. The total elongation was increased to above 13%, with an acceptable loss in TS by performing additional tempering. The fibrous tempered-martensite/ferrite DP steel exhibits an excellent balance of strength and ductility, surpassing the current low-alloy DP steels with the same strength grade. Plate-like or quasi-spherical fine carbides were precipitated, and the relatively high-density dislocations were maintained due to the delay of lath recovery by the enrichment of Mn and C in martensite (austenite before quenching), contributing to the tempering softening resistance. In addition, nanotwins and a very small amount of retained austenite were present due to the martensite chemistry. High-density dislocations, fine carbide precipitation, and partially twinned structures strengthened the tempered martensite while maintaining relatively high ductility. Quantitative strengthening models and calculations were not included in the present work, which is an interesting topic and will be studied in the future. Full article

This paper focuses on the microstructural characteristics of non-alloy structural steels with carbon contents below 0.3% (further—Low-Carbon Steel—LCS), as well as the possible structural transformations and the resultant mechanical properties attainable through conventional heat treatment or alternative surface treatment methods. The principal microstructural constituents that govern the properties of these steels include both equilibrium and non-equilibrium phases, such as martensite, retained austenite, sorbite, and troostite. Conventional methodologies for enhancing rigidity involve the implementation of supplementary stiffening ribs, which augment rigidity while concomitantly contributing to an increase in overall weight or dimensions of the structure. In structures where supplementary stiffening ribs are incorporated within the thin-walled steel shell, this may reduce manufacturing efficiency and simplicity of design. Modern laser treatment technologies for thin-walled steel structures, however, involve modifying the internal microstructure and creating rigidity ribs within the structure itself, thus circumventing the need for additional elements. Full article

This investigation aimed at evaluating the weldability of a 2.1 GPa-grade hot stamping steel (HSS) containing 0.40 wt.% carbon using laser butt welding. It is shown that the subject HSS can be properly joined by laser welding without welding defects, such as voids and micro-cracks. The mechanical properties of joints before and after hot stamping were examined using cross-weld uniaxial tension and Vickers hardness, while microstructure was systematically characterized using optical microscopy and electron backscatter diffraction. The experimental results demonstrate that fresh martensite was formed in the weld nugget after welding, leading to a hardness much higher than that of the base metal. Nevertheless, such cross-weld microstructural heterogeneity was erased after hot stamping and low-temperature baking heat treatments, resulting in a uniform microstructure of lath martensite across the weld. As a result, the joint after hot stamping and baking exhibited an ultimate tensile strength of 2140 MPa and a total elongation of 12.03%, with the fracture occurring in the base metal. Such excellent mechanical properties of the joint demonstrate the great weldability of the present 2.1 GPa-grade HSS during laser welding. Full article

This study investigates the solution-aging treatment of precipitation-hardening SUS 630 stainless steel, alongside an analysis of the carbon emissions generated by the energy consumed during aging treatments. By employing atmospheric and liquid tin as aging media, the research comprehensively explores the effects of aging treatments on the characteristics of 630 stainless steel. The maximum hardness value for the 630 stainless steel was observed after atmospheric aging at 500 °C for 1 h. The given 630 stainless steel obtained its maximum hardness value after atmospheric aging at 500 °C for 1 h, indicating that the formation of secondary precipitates strengthens the steel’s performance. By leveraging the intrinsic characteristics of liquid tin, using it as an aging medium (Sn bath aging) significantly improves the efficiency of the aging process, achieving mechanical properties comparable to those of atmosphere-aged steel. The 630 stainless steel aged in a Sn bath exhibited a refined martensitic matrix with substantial precipitate formation, contributing to superior impact toughness and dynamic fatigue resistance. With an equivalent mass and performance, Sn bath aging notably reduced the duration of the treatment compared to atmospheric aging, leading to substantial energy savings and reduced carbon emissions. The Sn bath treatment, recognized in metallurgical science and heat treatment for its excellent thermal conductivity and recyclability, shows potential to enhance process efficiency and enable low carbon emissions in the heat treatment industry. By highlighting the differences between aging methods, this study provides solutions for optimizing heat treatment processes and thereby achieving industrial advancement and sustainability goals. Full article

The impact of prior austenite grain size (PAGS) on the kinetics of austenite formation with an initial martensite microstructure was investigated in a medium-carbon, low-alloy steel. Two distinct PAGS of 117 and 330 μm, representing the range of grain sizes encountered in industries, were considered. In this analysis, high-resolution dilatometry was used to study the formation of austenite during continuous heating experiments. The analysis of the dilatometry results revealed that grain refinement accelerated the rate of austenite formation without impacting its austenite formation temperature. Intermittent quenching tests were conducted to elucidate the nucleation and growth mechanisms of austenite formation using a combination of optical, scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The differences in austenite formation kinetics as a function of prior austenite grain size were quantified and modeled in the framework of diffusion-controlled nucleation and growth theories using the genetic algorithm optimization. Full article

The effect of austempering temperature on crystallographic features and mechanical properties is investigated in low-carbon bainitic steel, focusing on the relationship between microstructure and mechanical properties. After isothermal holding at, above, and below martensite start (M_S) temperatures and tempering, a mixed microstructure of martensite/bainite and martensite/austenite (M/A) constituents is obtained. The fraction of M/A constituents increases as the austempering temperature increases, while the density of block boundaries decreases. The instantaneous work hardening rate exhibits continuous decay without a notable transition because of the retained austenite in the M/A constituents. The toughness decreases with increasing austempering temperature, which is related not only to the fraction of M/A constituents but also to the density of block boundaries. Isothermal treatment below the M_S temperature enables the formation of structures with fewer M/A constituents and high-density block boundaries, through which excellent toughness can be achieved. Full article

This study aimed to develop an alternative surface hardening technique for low-carbon steel alloy type 20Ch using plasma electrolytic oxidation (PEO). The surface hardening of 20Ch alloy steel samples was achieved through PEO in a Na₂CO₃ electrolyte solution. Optimal processing parameters were determined experimentally by measuring voltage and applied current. Quenching was performed in the electrolyte stream, and plasma was ionised through excitation. A mathematical model based on thermal conductivity equations and regression analysis was developed to relate the key parameters of the hardening process. The results from both the experimental and mathematical models demonstrated that PEO significantly reduces hardening time compared to traditional methods. The microstructural images revealed the transformation of the coarse-grained pearlite–ferrite structure into quenched martensite. Vickers microhardness tests indicated a substantial increase in surface hardness after PEO treatment, compared to the untreated samples. The major advantages of PEO include lower energy consumption, high quenching rates, and the ability to perform localised surface treatments. These benefits contribute to overall cost reduction, making PEO a promising surface hardening method for various industrial applications. Full article

Surface engineering of stainless steels using thermochemical treatments at low temperatures has been the subject of intensive research for enhancing the surface hardness of these alloys without impairing their corrosion resistance. By using treatment media rich in nitrogen and/or carbon, it is possible to inhibit chromium compound formation and obtain supersaturated solid solutions, known as expanded phases, such as expanded austenite or S-phase in austenitic stainless steels, expanded ferrite in ferritic grades, and expanded martensite in martensitic grades. These low-temperature treatments produce a significant increase in surface hardness, which improves wear and fatigue resistance. However, the corrosion behavior of the modified surface layers remains of paramount importance. In the international literature, many studies on this topic are reported, but the results are not always univocal, and there are still open questions. In this review, the corrosion behavior of the expanded phases and the modified layers in which they are present is critically analyzed and discussed. The relationships between the phase composition and the microstructure of the modified layers and the corrosion resistance are highlighted while also considering the different test conditions. Furthermore, corrosion test methods are discussed, and suggestions are given for improving the measurements. Finally, perspectives on future directions for investigation are suggested for encouraging further research. Full article