Search Results (477)

This study investigates the impact of Time-of-Use (TOU) scheduling and battery energy storage systems (BESS) on voltage stability in a typical Malaysian medium-voltage distribution network with high photovoltaic (PV) system penetration. The analyzed network comprises 110 nodes connected via eight feeders to a pair of 132/11 kV, 15 MVA transformers, supplying a total load of 20.006 MVA. Each node is integrated with a 100 kW PV system, enabling up to 100% PV penetration scenarios. A hybrid mitigation strategy combining TOU-based load shifting and BESS was implemented to address voltage violations occurring, particularly during low-load night hours. Dynamic simulations using DIgSILENT PowerFactory were conducted under worst-case (no load and peak load) conditions. The novelty of this research is the use of real rural network data to validate a hybrid BESS–TOU strategy, supported by detailed sensitivity analysis across PV penetration levels. This provides practical voltage stabilization insights not shown in earlier studies. Results show that at 100% PV penetration, TOU or BESS alone are insufficient to fully mitigate voltage drops. However, a hybrid application of 0.4 MWh BESS with 20% TOU load shifting eliminates voltage violations across all nodes, raising the minimum voltage from 0.924 p.u. to 0.951 p.u. while reducing active power losses and grid dependency. A sensitivity analysis further reveals that a 60% PV penetration can be supported reliably using only 0.4 MWh of BESS and 10% TOU. Beyond this, hybrid mitigation becomes essential to maintain stability. The proposed solution demonstrates a scalable approach to enable large-scale PV integration in dense rural grids and addresses the specific operational characteristics of Malaysian networks, which differ from commonly studied IEEE test systems. This work fills a critical research gap by using real local data to propose and validate practical voltage mitigation strategies. Full article

This research addresses urban inequality by focusing on the rehabilitation of communal rooftops in Ciutat Vella, Barcelona, the city’s historic district, where residential vulnerability is concentrated in a particularly dense heritage urban environment with a shortage of outdoor spaces. Using participatory methodologies, this research develops low-cost, removable, and recyclable prototypes aimed at improving social interaction, technical performance, and environmental conditions. The focus is on vulnerable populations, particularly the elderly. The approach integrates a bottom–up process and scalable solutions presented as a Toolkit of micro-projects. These micro-projects are designed to improve issues related to health, safety, durability, accessibility, energy savings, and acoustics. In addition, several possible material solutions for micro-projects are examined in terms of sustainability and cost. These plug-in interventions are designed for adaptability and replication throughout similar urban contexts and can significantly improve the quality of life for people, especially the elderly, in dense historic environments. Full article

The formation and evolution of haze layers in planetary atmospheres play a critical role in shaping their chemical composition, radiative balance, and optical properties. In the outer solar system, the atmospheres of Titan and the giant planets exhibit a wide range of compositional and seasonal variability, creating environments favorable for the production of complex organic molecules under low-temperature conditions. Among them, Uranus—the smallest of the ice giants—has, since Voyager 2, emerged as a compelling target for future exploration due to unanswered questions regarding the composition and structure of its atmosphere, as well as its ring system and diverse icy moon population (which includes four possible ocean worlds). Titan, as the only moon to harbor a dense atmosphere, presents some of the most complex and unique organics found in the solar system. Central to the production of these organics are chemical processes driven by low-energy photons and electrons (<50 eV), which initiate reaction pathways leading to the formation of organic species and gas phase precursors to high-molecular-weight compounds, including aerosols. These aerosols, in turn, remain susceptible to further processing by low-energy UV radiation as they are transported from the upper atmosphere to the lower stratosphere and troposphere where condensation occurs. In this review, I aim to summarize the current understanding of low-energy (<50 eV) photon- and electron-induced chemistry, drawing on decades of insights from studies of Titan, with the objective of evaluating the relevance and extent of these processes on Uranus in anticipation of future observational and in situ exploration. Full article

Zinc (Zn)-based batteries have attracted significant interest for applications ranging from electric bikes to grid storage because of its advantageous properties like high abundance, non-toxicity and low-cost. Zn offers a high theoretical capacity of two electrons per atom, resulting in 820 mAh/g, making it a promising anode material for the development of highly energy dense batteries. However, the advancement of Zn-based battery systems is hindered by the limited availability of cathode materials that simultaneously offer high theoretical capacity, long-term cycling stability, and affordability. In this work, we present a new mixed material cathode system, comprising of a mixture of manganese dioxide (MnO₂) and copper oxide (Cu₂O) as active materials, that delivers a high theoretical capacity of ~280 mAh/g (MnO₂ + Cu₂O active material) (based on the combined mass of MnO₂ and Cu₂O) and supports stable cycling for >200 cycles at 1C. We further demonstrate the scalability of this novel cathode system by increasing the electrode size and capacity, highlighting its potential for practical and commercial applications. Full article

For meeting the growing demand for lightweight impact-resistant materials, this study designed and fabricated a carbon hollow microsphere (CHM)-reinforced polydimethylsiloxane (PDMS) composite and systematically investigated the influence of CHM packing structure on its energy absorption performance. Through optimizing the controllable preparation processes of the CHMs, CHMs with low breaking rates and novel structural stability were successfully prepared. A vacuum-assisted mixing–casting method was employed to synthesize the CHM/PDMS composites with varying CHM contents (0~10 wt.%). The results demonstrated that the incorporation of CHMs significantly enhanced the compressive strength, compressive modulus, and energy absorption efficiency of the PDMS matrix. Under quasi-static loading, the composite with 4 wt.% CHM exhibited optimal comprehensive performance, achieving a 124.68% increase in compressive strength compared to pure PDMS. In dynamic impact tests, the compressive strength and energy absorption at a strain rate of 4500 s⁻¹ increased by 1245.09% and 1218.32%, respectively. The improvement of mechanical properties can be mainly attributed to the introduction of CHMs with an appropriate percentage, which can form a dense stacking structure so that the interaction force between the CHMs and PDMS matrix can be improved through the dense stacking effect, and the external force can be effectively dissipated through interface interaction, in addition to the energy dissipated by the deformation of the matrix deformation and crush of the CHMs. Additionally, the introduction of CHMs elevated the onset thermal decomposition temperature of the materials, leading to an enhanced thermal stability of the CHM/PDMS composite compared to that of the pure PDMS. Overall, this study provides theoretical and experimental foundations for designing lightweight impact-resistant materials and demonstrates the potential of CHM/PDMS composites for multifunctional safety protection. Full article

Alkaline electrolytic water hydrogen generation, a key driver in the growth of hydrogen energy, heavily relies on high-efficiency and high-purity ion exchange membranes. In this study, three-dimensional (3D) wrinkled reduced graphene oxide (WG) nanosheets obtained through a simple thermal reduction process and two-dimensional (2D) graphene oxide act as building blocks, with ethylenediamine as a crosslinking stabilizer, to construct a unique 3D/2D 2 nm-tunneling structure between the GO and WG sheets through via an amide connection at a WG/GO ratio of 1:1. Here, the wrinkled graphene (WG) undergoes a transition from two-dimensional (2D) graphene oxide (GO) into three-dimensional (3D) through the adjustment of surface energy. By increasing the interlayer spacing and the number of ion fluid channels within the membranes, the E-W/G membrane has achieved the rapid passage of hydroxide ions (OH⁻) and simultaneous isolation of produced gas molecules. Moreover, the dense 2 nm nano-tunneling structure in the electrolytic water process enables the E-W/G membrane to attain current densities >99.9% and an extremely low gas crossover rate of hydrogen and oxygen. This result suggests that the as-prepared membrane effectively restricts the unwanted crossover of gases between the anode and cathode compartments, leading to improved efficiency and reduced gas leakage during electrolysis. By enhancing the purity of the hydrogen production industry and facilitating the energy transition, our strategy holds great potential for realizing the widespread utilization of hydrogen energy. Full article

Background: Western dietary patterns worldwide are increasingly dominated by energy-dense, nutrient-deficient industrial foods, often identified as ultra-processed foods (UPFs). Such products may have detrimental health implications, particularly if nutritionally inadequate. This study aimed to examine the intake of unhealthy UPFs among children and adolescents from five Mediterranean countries (Italy, Spain, Portugal, Egypt, and Lebanon) involved in the DELICIOUS project and to assess the association with dietary quality indicators. Methods: A survey was conducted with a sample of 2011 parents of children and adolescents aged 6 to 17 years to evaluate their dietary habits. Diet quality was assessed using the Youth Healthy Eating Index (Y-HEI), the KIDMED index to determine adherence to the Mediterranean diet, and compliance with national dietary guidelines. Results: Increased UPF consumption was not inherently associated with healthy or unhealthy specific food groups, although children and adolescents who consumed UPF daily were less likely to exhibit high overall diet quality and adherence to the Mediterranean diet. In all five countries, greater UPF intake was associated with poorer compliance with dietary recommendations concerning fats, sweets, meat, and legumes. Conclusions: Increased UPF consumption among Mediterranean children and adolescents is associated with an unhealthy dietary pattern, possibly marked by a high intake of fats, sweets, and meat, and a low consumption of legumes. Full article

This paper presents an attack detection, response, and recommendation framework designed to protect the integrity and operational continuity of IoT-based critical infrastructure, specifically focusing on an energy use case. With the growing deployment of IoT-enabled smart meters in energy systems, ensuring data integrity is essential. The proposed framework monitors smart meter data in real time, identifying deviations that may indicate data tampering or device malfunctions. The system comprises two main components: an attack detection and prediction module based on machine learning (ML) models and a response and adaptation module that recommends countermeasures. The detection module employs a forecasting model using a long short-term memory (LSTM) architecture, followed by a dense layer to predict future readings. It also integrates a statistical thresholding technique based on Tukey’s fences to detect abnormal deviations. The system was evaluated on real smart meter data in a testbed environment. It achieved accurate forecasting (MAPE < 2% in most cases) and successfully flagged injected anomalies with a low false positive rate, an effective result given the lightweight, unsupervised, and real-time nature of the approach. These findings confirm the framework’s applicability in resource-constrained energy systems requiring real-time cyberattack detection and mitigation. Full article

Circulating fluidized bed fly ash (CFBFA) stockpiles release alkaline dust, high-pH leachate, and secondary CO₂/SO₂—an environmental burden that exceeds 240 Mt yr⁻¹ in China alone. Yet, barely 25% is recycled, because the high f-CaO/SO₃ contents destabilize conventional cementitious products. Here, we presents a pressurized flue gas heat curing (FHC) route to bridge this scientific deficit, converting up to 85 wt% CFBFA into structural lightweight gravel. The gypsum dosage was optimized, and a 1:16 (gypsum/CFBFA) ratio delivered the best compromise between early ettringite nucleation and CO₂-uptake capacity, yielding the highest overall quality. The optimal mix reaches 9.13 MPa 28-day crushing strength, 4.27% in situ CO₂ uptake, 1.75 g cm⁻³ bulk density, and 3.59% water absorption. Multi-technique analyses (SEM, XRD, FTIR, TG-DTG, and MIP) show that FHC rapidly consumes expansive phases, suppresses undesirable granular-ettringite formation, and produces a dense calcite/needle-AFt skeleton. The FHC-treated CFBFA composite gravel demonstrates 30.43% higher crushing strength than JTG/TF20-2015 standards, accompanied by a water absorption rate 28.2% lower than recent studies. Its superior strength and durability highlight its potential as a low-carbon lightweight aggregate for structural engineering. A life-cycle inventory gives a cradle-to-gate energy demand of 1128 MJ t⁻¹ and a process GWP of 226 kg CO₂-eq t⁻¹. Consequently, higher point-source emissions paired with immediate mineral sequestration translate into a low overall climate footprint and eliminate the need for CFBFA landfilling. Full article

Planar heaters are designed to deliver uniform heat across broad surfaces and serve as critical components in applications requiring energy efficiency, safety, and mechanical flexibility, such as wearable electronics and smart textiles. However, conventional metal-based heaters are limited by poor adaptability to curved or complex surfaces, low mechanical compliance, and susceptibility to oxidation-induced degradation. To overcome these challenges, we applied a protein-assisted electroless copper (Cu) plating strategy to electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofiber substrates to fabricate flexible, conductive planar heating membranes. For interfacial functionalization, a protein-based engineering approach using bovine serum albumin (BSA) was employed to facilitate palladium ion coordination and seed formation. The resulting membrane exhibited a dense, continuous Cu coating, low sheet resistance, excellent durability under mechanical deformation, and stable heating performance at low voltages. These results demonstrate that the BSA-assisted strategy can be effectively extended to complex three-dimensional fibrous membranes, supporting its scalability and practical potential for next-generation conformal and wearable planar heaters. Full article

This paper investigates the application of non-calcined metal tartrate as a novel alternative pore former to prepare functional ceramic composites to fabricate solid oxide fuel cells (SOFCs). Compared to carbonaceous pore formers, non-calcined pore formers offer high compatibility with various ceramic composites, providing better control over porosity and pore size distribution, which allows for enhanced gas diffusion, reactant transport and gaseous product release within the fuel cells’ functional layers. In this work, nanocrystalline gadolinium-doped ceria (GDC) and Ni-Gd-Ce-tartrate anode powders were prepared using a single-step co-precipitation synthesis method, based on the carboxylate route, utilising ammonium tartrate as a low-cost, environmentally friendly precipitant. The non-calcined Ni-Gd-Ce-tartrate was used to fabricate dense GDC electrolyte pellets (5–20 μm thick) integrated with a thin film of Ni-GDC anode with controlled porosity at 1300 °C. The dilatometry analysis showed the shrinkage anisotropy factor for the anode substrates prepared using 20 wt. The percentages of Ni-Gd-Ce-tartrate were 30 wt.% and 40 wt.%, with values of 0.98 and 1.01, respectively, showing a significant improvement in microstructural properties and pore size compared to those fabricated using a carbonaceous pore former. The results showed that the non-calcined pore formers can also lower the sintering temperature for GDC to below 1300 °C, saving energy and reducing thermal stresses on the materials. They can also help maintain optimal material properties during sintering, minimising the risk of unwanted chemical reactions or contamination. This flexibility enables the versatile designing and manufacturing of ceramic fuel cells with tailored compositions at a lower cost for large-scale applications. Full article

Solid-state electrolytes (SSEs) have emerged as a promising solution for next-generation lithium-ion batteries due to their excellent safety and high energy density. However, their practical application is still hindered by critical challenges such as their low ionic conductivity and high interfacial resistance at room temperature. The innovative application of 3D printing in the field of electrochemistry, particularly in solid-state electrolytes, endows energy storage devices with attractive characteristics. In this study, ceramic-in-gel polymer electrolytes (GPEs) based on PVDF-HFP/PAN@LLZTO were fabricated using a direct ink writing (DIW) 3D printing technique. Under the optimal printing conditions (printing speed of 40 mm/s and fill density of 70%), the printed electrolyte exhibited a uniform and dense sponge-like porous structure, achieving a high ionic conductivity of 5.77 × 10⁻⁴ S·cm⁻¹, which effectively facilitated lithium-ion transport. A structural analysis indicated that the LLZTO fillers were uniformly dispersed within the polymer matrix, significantly enhancing the electrochemical stability of the electrolyte. When applied in a LiFePO₄|GPEs|Li cell configuration, the electrolyte delivered excellent electrochemical performance, with high initial discharge capacities of 168 mAh·g⁻¹ at 0.1 C and 166 mAh·g⁻¹ at 0.2 C, and retained 92.8% of its capacity after 100 cycles at 0.2 C. This work demonstrates the great potential of 3D printing technology in fabricating high-performance GPEs. It provides a novel strategy for the structural design and industrial scalability of lithium-ion batteries. Full article

As global climate change intensifies and energy crises deepen, photovoltaic (PV) applications in cities are increasingly garnering attention worldwide. In this context, retrofitting existing high-density residential areas with PV applications is becoming a focus of urban low-carbon development. As the most densely populated city in Western China, Chengdu is characterized by rapid development and high energy consumption. The widespread application of photovoltaic (PV) systems could significantly alleviate its energy consumption issues. This research investigated the PV application potentials of 27 non-residential areas in high-density residential areas in Chengdu, Sichuan Province from a design perspective and proposed design recommendations for PV applications in these spaces. In addition, this study analyzed urban morphological factors affecting the PV generation potential in non-residential areas through a Pearson correlation. The key factors influencing the PV application potential in these areas were building density (BD), non-residential area perimeter-to-area ratio (NBPAR), and maximum building height (H_max). This research aims to provide new strategies and methods for the low-carbon transformation of future urban high-density residential areas. Full article

Low-permittivity microwave dielectric ceramics are essential for high-frequency communication and radar systems, as they minimize signal delay and interference, thereby enabling compact and high-performance devices. In this study, LiAl_5−xNi_xO_8−0.5x (x = 0.1–0.5) ceramics were synthesized via a solid-state reaction method to investigate the effects of Ni²⁺ substitution on crystal structure, microstructure, and dielectric properties. X-ray diffraction and Rietveld refinement reveal a phase transition from the P4₃32 to the Fd$\stackrel{-}{3}$m spinel structure at x ≈ 0.3, accompanied by a systematic increase in the lattice parameter (7.909–7.975 Å), attributed to the larger ionic radius of Ni²⁺ compared to Al³⁺. SEM analysis confirms dense microstructures with relative densities exceeding 95% and grain size increases from less than 1 μm at x = 0.1 to approximately 2 μm at x = 0.5. Dielectric measurements show a decrease in permittivity (ε_r) from 8.24 to 7.77 and in quality factor (Q × f) from 34,605 GHz to 20,529 GHz with increasing Ni content, while the temperature coefficient of the resonant frequency (τ_f) shifts negatively from −44.8 to −69.1 ppm/°C. Impedance spectroscopy indicates increased conduction losses and reduced activation energy with higher Ni²⁺ concentrations. Full article

This paper presents a comprehensive review of handover management and load balancing optimization (LBO) in ultra-dense 5G and emerging 6G cellular networks. With the increasing deployment of small cells and the rapid growth of data traffic, these networks face significant challenges in ensuring seamless mobility and efficient resource allocation. Traditional handover and load balancing techniques, primarily designed for 4G systems, are no longer sufficient to address the complexity of heterogeneous network environments that incorporate millimeter-wave communication, Internet of Things (IoT) devices, and unmanned aerial vehicles (UAVs). The review focuses on how recent advances in artificial intelligence (AI), particularly machine learning (ML) and deep learning (DL), are being applied to improve predictive handover decisions and enable real-time, adaptive load distribution. AI-driven solutions can significantly reduce handover failures, latency, and network congestion, while improving overall user experience and quality of service (QoS). This paper surveys state-of-the-art research on these techniques, categorizing them according to their application domains and evaluating their performance benefits and limitations. Furthermore, the paper discusses the integration of intelligent handover and load balancing methods in smart city scenarios, where ultra-dense networks must support diverse services with high reliability and low latency. Key research gaps are also identified, including the need for standardized datasets, energy-efficient AI models, and context-aware mobility strategies. Overall, this review aims to guide future research and development in designing robust, AI-assisted mobility and resource management frameworks for next-generation wireless systems. Full article