Search Results (491)

Thorium carbide (${\mathrm{ThC}}_{2\pm x}$) nano-structured thin disc-like pellets were produced from thoria nanoparticles (${\mathrm{ThO}}_2$-NP) and multi-walled carbon nanotubes (MWCNT). These composites are to be studied as a target material candidate for radioactive ion beam (RIB) production via nuclear reactions upon impact with high-energy proton beams on a stack of solid pellets. The ${\mathrm{ThO}}_2$-NP precursor was produced via precipitation of thorium oxalate from a thorium nitrate solution with oxalic acid and subsequent hydrothermal oxidation of the oxalate, creating the thoria nanoparticles. The ${\mathrm{ThO}}_2$-NP were then mixed with MWCNT in isopropyl alcohol and sonicated by two different methods to create a nanoparticle dispersion. This dispersion was then heated under medium vacuum to evaporate the solvent; the resulting powder was pressed into pellets and taken to an inert-atmosphere oven, where it was heated to 1650 °C and carbothermally reduced to ${\mathrm{ThC}}_{2\pm x}$. The resulting pellets were characterized via XRD, SEM-EDS, and Raman spectroscopy. The resulting thorium pellets exhibited, at most, trace levels of the oxide precursor. Furthermore, the nanotube structures were still present in the final product and are expected to contribute positively towards faster radioisotope release times by lowering isotope diffusion times, which is required for the efficient extraction of the shortest-lived (<1 s half-life) radioisotopes. Full article

We examine how the Arctic Oscillation (AO) shapes winter sea-surface-temperature (SST) variability in the East/Japan Sea, with a focus on sub-seasonal SST memory (how long anomalies persist) and air–sea coupling (where SST and atmospheric anomalies co-vary). Using daily OISST v2.1 and ERA5 reanalysis for 1993–2022, we first analyze winter persistence of SST and key atmospheric drivers and identify East Korea Bay and the Subpolar Front as hotspots of long-lived SST anomalies. A rank-reduced multivariate maximum covariance analysis then extracts the leading coupled mode between SST and a set of atmospheric fields under positive and negative AO phases; in both phases the coupled mode is front-anchored, but its amplitude and spatial focus differ. Finally, to quantify the mixed-layer memory, we construct Ornstein–Uhlenbeck-like time-integrated responses of the atmospheric principal components. The effective integration timescales, determined by maximizing zero-lag correlations with the SST mode, cluster at approximately 2–3 weeks for wind-stress curl and near-surface variables and 4–7 weeks for sea-level pressure and meridional wind, with longer timescales during negative AO. The time-integrated atmospheric responses exhibit SST-like persistence, confirming the mixed layer’s role as a stochastic integrator. These AO-conditioned memory windows define practical lead times over which integrated atmospheric indices can act as predictors of winter marine heatwaves and cold-surge-impacted SST anomalies. Full article

Air pollution is an important environmental issue that affects social development and human life. Atmospheric fine particulate matter (PM_2.5) is the primary pollutant affecting the air quality of most cities in the authors’ country. It can cause severe haze, reduce air visibility and cleanliness, and affect people’s daily lives and health. Therefore, it has become a primary research object. Ground monitoring and satellite remote sensing are currently the main ways to obtain PM_2.5 data. Satellite remote sensing technology has the advantages of macro-scale, dynamic, and real-time functioning, which can make up for the limitations of the uneven distribution and high cost of ground monitoring stations. Therefore, it provides an effective means to establish a mathematical model—based on atmospheric aerosol optical thickness data obtained through satellite remote sensing and PM_2.5 concentration data measured by ground monitoring stations—in order to estimate the PM_2.5 concentration and temporal and spatial distribution. This study takes the Yangtze River Delta region as the research area. Based on the measured PM_2.5 concentration data obtained from 184 ground monitoring stations in 2023, the newly released sixth version of the MODIS aerosol optical depth product obtained via the US Terra and Aqua satellites is used as the main prediction factor. Dark-pixel AOD data with a 3 km resolution and dark-blue AOD data with a 10 km resolution are combined with the European Center for Medium-Range Weather Forecasts (ECMWF) reanalysis meteorological, land use, road network, and population density data and other auxiliary prediction factors, and XGBoost and LSTM models are used to achieve high-precision estimation of the spatiotemporal changes in PM_2.5 concentration in the Yangtze River Delta region. Full article

As an important component of the global fishery economy, the crab breeding and processing industry faces the dual challenges of sustainable development and technological upgrading. This paper first systematically analyzes the regional distribution and core biological characteristics of major global economic crab species, laying a foundation for the targeted design of processing technologies and equipment. Secondly, based on advances in crab processing technology, the industry is categorized into two systems: live crab processing and dead crab processing. Live crab processing has formed a full-chain technological system of “fishing–temporary rearing–depuration–grading–packaging”. Dead crab processing focuses on high-value utilization: high-pressure processing enhances the quality of crab meat; liquid nitrogen quick-freezing combined with modified atmosphere packaging extends shelf life; and biological fermentation and enzymatic hydrolysis facilitate the green extraction of chitin from crab shells. In terms of intelligent equipment application, sensor technology enables full coverage of aquaculture water quality monitoring, precise classification during processing, and vitality monitoring during transportation. Automation technology reduces labor costs, while fuzzy logic algorithms ensure the process stability of crab meat products. The integration of the Internet of Things (IoT) and big data analytics, combined with blockchain technology, enables full-link traceability of the “breeding–processing–transportation” chain. In the future, cross-domain technological integration and multi-equipment collaboration will be the key to promoting the sustainable development of the industry. Additionally, with the support of big data and artificial intelligence, precision management of breeding, processing, logistics, and other links will realize a more efficient and environmentally friendly crab industry model. Full article

This article emerges from a researcher-generated longitudinal photography project conducted between 2016 and 2025 situated on the redundant site of the former Middleton Tuberculosis Hospital in North Yorkshire. The research project explored the site’s transformation through an unmanaged rewilding in the context of surrounding dairy farms within the Nidderdale ‘area of outstanding natural beauty’. The hospital site is reimagined as a bucolic ‘island’ stranded in the ideological socio-cultural notions embedded in “Nature”, the countryside, and agricultural landscape under increasing pressure to value biodiversity and nature’s restoration. Employing a reflexive lyrical critical lens informed by ‘resonance theory’, social semiotics, and expressive visual sociological practice, the article contributes to the debates surrounding landscape valorization, the contestation of the ‘countryside’ as a working, and recreational landscape. Researcher-generated photographic practice captures the duration of iterative site visits, the seasonal atmosphere and potential experience of resonance of the site, providing vivid sources for reflections, meaning-making, while proselytizing the axiom of Kress, that: ‘without frame no meaning’. The key research questions are: (1) Why is researcher-generated photography, amid AI image production, an effective epistemological method for re-presenting and understanding the significance of unmanaged landscape rewilding? (2) How do photographic re-presentations and lyrical reflexivity convey the lived resonance of being in places like the Middleton Hospital site? The text rejects illustrative photographic use in academic discourse, favoring an expressive, allusive, and lyrical interpretation of rewilding’s socio-cultural value. Full article

Conventional energy resources have been constrained by their inefficient utilization and present a severe impact on the human living environment, and there is an urgent need to develop energy technologies with high efficiency, low carbon emissions, and environmental cleanliness. Solid oxide fuel cells (SOFCs) have been recognized as a highly efficient and clean energy conversion device that directly converts chemical energy in fuels into electricity, holding promising prospects for addressing the issues of low efficiency and environmental concerns associated with conventional energy resources. However, under practical operation conditions, the cathodes of SOFCs are often exposed to various contaminations including working environment-induced degradation, cathode poisoning, and corrosion. This review summarizes the severe performance degradation of SOFC cathodes caused by CO₂ poisoning, analyzes recent research findings on cathode durability under CO₂-containing atmospheres, and provides an overview of the reported strategies for enhancing CO₂ tolerance. Full article

Basic physiology and molecular mechanisms accounting for the maldistribution of fluid that is characteristic of the “third fluid space” (V_t2) have been known for several decades but have been poorly integrated into the clinical literature. Today, the maldistribution can be quantified and simulated in living humans by using volume kinetic mathematics, which introduces possibilities to validate interventions designed to mitigate the pathophysiology. Fluid accumulation in V_t2 occurs both in fluid overload and inflammation, and both are largely influenced by interstitial fluid pressure. This is normally slightly sub-atmospheric but increases during volume loading to eventually exceed the ambient air pressure, whereby the loss of vacuum allows pools of fluid to appear in the interstitial gel. Opening of V_t2 due to fluid overload can be delayed/minimized by lowering the infusion rate, hemorrhage, and the use of hyper-oncotic fluid. Accumulation of fluid in V_t2 during acute inflammation and tissue injury can be explained by disruption of the cell–matrix interactions that actively regulate the interstitial pressure. Inflammatory mediators, mostly tissue cytokines, cause release of tensile forces that disrupt integrin-dependent adhesion between interstitial fibroblasts and collagen fibers. This disruption causes the interstitial space to expand, which results in a deep negative (suction) pressure. These events can be modulated by α-trinositol and insulin. Full article

This article examines Dag Solstad’s War Trilogy (1977–81) as a key work of realism and cultural memory in postwar Norwegian literature. Long dismissed as doctrinaire Marxist fiction, the trilogy is, in fact, one of the most ambitious literary engagements with World War II in Scandinavia. Drawing on Georg Lukács’s theory of the historical novel and Fredric Jameson’s account of realism’s “antinomies,” this article argues that Solstad’s realism is defined by contradiction: it is both a didactic mapping of social conflict and an aesthetic registration of lived sensation. The trilogy insists on the persistence of class antagonisms across civilian and military spheres; however, it also dwells on affective residues—hygiene, beauty, emotions, atmosphere—that resist narrative closure. This duality is framed through the concept of dual historicity: Solstad’s novels remember the 1930s and 1940s from the vantage point of the 1970s, while today they reach us as artifacts of that political and aesthetic moment. In light of this, the War Trilogy operates not only as historical fiction but as a medium of cultural memory, dramatizing the contradictions of remembrance itself. Realism here becomes neither transparency nor nostalgia, but a “battle of the senses” in which ideology and perception vie over the conditions of historical experience. Full article

Generalized frosts have a significant impact on the Pampa Húmeda of Argentina, particularly those without persistence (0DP), defined as events that do not last more than one day, and are the most frequent generalized frosts. This study investigates the dynamical and physical mechanisms that sustain these events, emphasizing the nonlinear interactions represented by the Rossby Wave Source (RWS) equation. Composite analysis of pressure, temperature, wind and geopotential height fields were performed, showing that 0DP events are related to abrupt cold air intrusion linked to the enhancement of upper levels troughs over the eastern Pacific Ocean and transient surface anticyclones over South America. This linear analysis only showed a lack of persistent upper-level maintenance and did not explain the dynamics of the rapid weakening of the circulation. For this reason, a nonlinear analysis based on the decomposition of the RWS equation into its advective and divergent terms is performed. The advective term only acts as an initial trigger, deepening troughs and favoring meridional cold air advection, while the divergent term dominates the events, representing 63–67% of the affected area. This term reinforces ridges, promotes subsidence and favors clear sky conditions that enhance nocturnal radiative cooling and frost formation. Positive anomalies of the divergent RWS term strengthen the ridge and advect cold air over the Pampa Húmeda, whereas subsequent negative anomalies over the southwestern Atlantic act as sinks of wave activity, leading to the rapid dissipation of the synoptic configuration. Consequently, the same mechanism that generates favorable conditions for frost development also determines their lack of persistence. These findings demonstrate that the short-lived nature of 0DP frosts is not due to the absence of dynamical forcing, but rather to nonlinear processes that both enable and constrain frost occurrence. This highlights the importance of incorporating nonlinear diagnostics, such as the RWS, to improve the understanding of short-lived atmospheric extremes. Full article

This study explores the health status of veteran Zelkova serrata trees (average age 300 years) in the Pohang region in the context of long-term climatic trends and local environmental variability. Eleven nationally designated veteran trees were monitored using physiological indicators Soil Plant Analysis Development (SPAD) values and live crown ratio (LCR), internal structural assessment (sonic tomography-derived decay ratio), and environmental parameters including meteorological records and Landsat-derived Land Surface Temperature (LST) data from 2000 to 2025. While recent years showed localized heat-extreme events, most sites displayed spatially heterogeneous yet gradually increasing LST trends, with 2024 recording the highest values at more than half the locations. Tree vitality differences were more strongly associated with site specific microclimatic conditions than with uniform long-term climate shifts: trees in cooler or less urbanized zones showed higher SPAD values and lower decay levels, whereas those in warmer, edge-influenced sites exhibited signs of physiological stress. The results indicate that rising summer surface temperature—and their interaction with atmospheric drying—intensify water-stress impacts, but the actual tree responses are modulated by local land-cover and soil stability contexts. These findings underscore the need for integrated, multi-scale assessment of veteran tree health and suggest that conservation practices should incorporate microclimate-based intervention strategies. Full article

The production and extensive use of silver nanoparticles (AgNPs) in various fields necessitate thorough testing, not only in terms of their potential applications but also regarding the effects they induce on various organisms. In addition, nanoparticles generated from various anthropogenic activities, which reach or are formed in the atmosphere, have a significant impact on the health of humans and other living organisms. Recent research indicates that the effects produced by these nanoparticles are dependent on their size and applied dose. In this context, the present study aimed to evaluate the physiological, biochemical and cytogenotoxic effects induced by different doses of AgNPs compared to positive and negative controls in Triticum aestivum L. and Allium cepa L. A significant stimulatory effect of the treatment performed with the solution of AgNPs with a size of 20 nm, at the lowest concentration (0.02 µg mL⁻¹), in the two tested species, was obtained. The growth and weight of the seedling were significantly increased, and the mitotic index was also elevated. Additionally, this treatment variant showed the lowest percentage of chromosomal aberrations. No significant differences were observed in cell viability, total polyphenol content, proline levels, or assimilatory pigment concentrations compared to the control. Our findings show that AgNPs may exert stimulatory effects, whether significant or not, on certain physiological and biochemical parameters. However, they also interfere with cell cycle regulation and genomic stability, raising concerns regarding their environmental and biological safety. The Allium test proved to be an effective method for detecting nanoparticle-induced genotoxicity and can be recommended as a preliminary screening assay in nanoparticle safety evaluations. Full article

Organic peroxy (ROO•) and hydroperoxy (•QOOH) radicals are key reactive intermediates that are formed via the oxidation of volatile organic compounds during combustion or in the Earth’s atmosphere. Their primary fate is continued unimolecular decay or bimolecular chemistry, the relative branching for which is heavily structure- and temperature-dependent. This article outlines a combined single- and multi-reference quantum chemical study to characterize the near-UV accessible electronically excited states of the prototypical ROO• and •QOOH intermediates, tert-butyl peroxy and hydroperoxy-tert-butyl radicals—the ground-state chemistries of which have been well studied both experimentally and computationally. Additionally, we simulate the electronic absorption profiles of these ROO• and •QOOH intermediates with a variety of multi- and single-reference methods. The results show an interesting conformer dependence on the electronically excited-state character and electronic absorption maxima of •QOOH. The results show promise for electronic absorption spectroscopy to be used as a selected probe for determining •QOOH conformers. Additionally, electronic absorption may contribute to the daytime removal of long-lived •QOOH intermediates formed in the troposphere. We expect that our studies will motivate experiments on the electronic absorption spectra of experimentally achievable ROO• and •QOOH. Full article

Methane is a short-lived climate forcer (SLCF) that has a pivotal influence on the Earth’s climate. This work focuses on mean methane concentrations and their year-to-year variability for the period 2003–2014 between four CMIP6 (Coupled Model Intercomparison Project Phase 6) Earth System Model simulations and CAMS (Copernicus Atmosphere Monitoring Service) reanalysis fields. The selected CMIP6 models are CNRM-ESM2-1, GFDL-ESM4.1, UKESM1, and EC-Earth3-AerChem, while monthly averaged fields from the CAMS global greenhouse gas reanalysis (EGG4) were employed. It is shown that the EC-Earth3-AerChem model closely aligns with CAMS methane concentration pattern, whereas other models display notable differences. Full article

As the region with the earliest housing stock market and the most advanced development in China, the Pearl River Delta has experienced extensive housing demolition and construction, leading to buildings having short lifespans. The environmental pollution generated during this process has brought attention to the concept of green buildings. However, whether due to previous patterns of demolition and construction or the significant impacts of social and economic changes in the current and future housing stock contexts, the comprehensive adaptability of human-centered living spaces remains a crucial issue. This focus is strongly related to the residents’ psychological responses, such as sense of belonging, safety, and atmosphere, across different scales of physical environment. However, most housing evaluation systems regarding sustainable issues are green building evaluation systems. And their concept and practice are often accompanied by a neglect of the interrelationship between people and the built environment, as well as a lack of an appropriate methodological framework to integrate these elements in the temporal dimension. This paper primarily tries to provide new answers to old questions about housing durability by reconceptualizing evaluation systems beyond ecological metrics, while simultaneously challenging accepted answers that privilege material and energy indicators over sociocultural embeddedness. Moreover, an effective housing evaluation framework must transcend purely technical or ecological indicators to systematically integrate the temporal and sociocultural factors that sustain long-term residential quality, particularly in rapidly transforming urban contexts. Therefore, theories closely related to building longevity, such as open building and the “level” strategy, were introduced. Based on this combined methodological framework, selected cases of local traditional housing and green building evaluation systems were studied, aiming to identify valuable longevity factors and improved evaluation methods. Furthermore, two rounds of expert consultation and a data analysis were conducted. The first round helped determine the local indexes and preliminary evaluation methods, while the second round helped confirm the weighting value of each index through a questionnaire study and data analysis. This systematic study ultimately established a preliminary long-term housing evaluation system for the Pearl River Delta. Full article

Rapid urbanization and climate change have exacerbated urban heat stress, underscoring the importance of research on human thermal comfort for sustainable urban development. This study analyzes the spatiotemporal variation and driving factors of apparent temperature in the Chang–Zhu–Tan urban agglomeration, China. The Humidex index, representing apparent temperature, was derived from multi-source remote sensing data (Landsat 8, MODIS) and meteorological variables (ERA5-Land reanalysis), employing atmospheric correction, random forest modeling, and path analysis. The results indicate pronounced spatiotemporal heterogeneity: apparent temperature reached its maximum in urban centers during summer (mean 52.9 °C) and its minimum in winter (mean 5.99 °C), following a decreasing gradient from urban core to periphery. Land cover emerged as a key driver, with vegetation (NDVI, r = −0.938) showing a strong negative correlation and built-up areas (NDBI, r = +0.8) a positive correlation with apparent temperature. Uniquely, in the Chang–Zhu–Tan region’s persistently high humidity, water bodies (MNDWI, r = +0.616) exhibited a positive correlation with apparent temperature, likely due to humidity-enhanced thermal perception in summer and relatively warmer water temperature in winter. Path analysis revealed that air temperature exerts the strongest direct positive influence on apparent temperature, while relative humidity and NDVI primarily act through indirect pathways. These findings provide scientific evidence to guide climate-adaptive urban planning and enhance human living conditions in humid environments. Full article