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Keywords = laser-assisted bonding

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12 pages, 3026 KB  
Article
An In Vitro Study Comparing Debonding of Orthodontic Ceramic and Metal Brackets Using Er:YAG Laser and Conventional Pliers
by Aous Abdulmajeed, Tiannie Phan, Kinga Grzech-Leśniak and Janina Golob Deeb
Appl. Sci. 2025, 15(21), 11844; https://doi.org/10.3390/app152111844 - 6 Nov 2025
Viewed by 833
Abstract
Removing orthodontic brackets often presents clinical challenges, as it may cause patient discomfort, bracket fracture, or enamel damage resulting from strong adhesive bonds. Various techniques have been proposed to facilitate safer and more efficient debonding. Among them, laser-assisted methods have gained attention for [...] Read more.
Removing orthodontic brackets often presents clinical challenges, as it may cause patient discomfort, bracket fracture, or enamel damage resulting from strong adhesive bonds. Various techniques have been proposed to facilitate safer and more efficient debonding. Among them, laser-assisted methods have gained attention for their potential to minimize mechanical stress and improve patient comfort. The main objective of this study was to evaluate the effect of an erbium-doped yttrium–aluminum–garnet (Er:YAG) laser as an alternative to traditional mechanical methods for removing metal and ceramic orthodontic brackets. Materials and Methods: Thirty-six extracted premolars were prepared for bonding metal or ceramic brackets using a light-cure adhesive system. The control group consisted of six ceramic and six metal brackets removed with conventional orthodontic pliers. In the experimental groups, brackets were debonded using the Er:YAG laser (2940 nm, 0.6 mm spot size, 150 mJ; 15 Hz; (2.25 W) with an H14 handpiece. Irradiation time was recorded for each method, and teeth were rescanned to measure the surface area and volume of the crowns before and after bracket removal. Data were analyzed using one-way ANOVA and Tukey’s HSD test (p < 0.05). Scanning electron microscopy (SEM) was used for surface analysis. Results: A significant difference in debonding time (p = 0.001) was observed between the laser and traditional methods. The laser group took 52.5 s for metal and 56.25 s for ceramic brackets, compared to 1.05 s (metal) and 0.64 s (ceramic) in the traditional group. A significant difference in remaining cement volume was noted (p = 0.0002), but no differences were found between metal and ceramic brackets with laser removal. Conclusions: Er:YAG laser-assisted debonding is safe and minimally invasive but more time-consuming and costly than conventional methods, showing no improvement in clinical efficiency under current parameters. Full article
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16 pages, 1673 KB  
Article
Experimental Analysis of Steel–Concrete Bond Strength Under Varying Material and Geometric Parameters
by Gregor Trtnik, Jakob Šušteršič and Tomaž Hozjan
CivilEng 2025, 6(3), 48; https://doi.org/10.3390/civileng6030048 - 11 Sep 2025
Viewed by 1210
Abstract
This study presents the outcomes of a comprehensive experimental investigation focused on the bond behavior between reinforcing steel bars and tremie concrete, assessed through standardized pull-out tests. The objective was to evaluate the influence of some key parameters: reinforcement bar diameter, concrete age [...] Read more.
This study presents the outcomes of a comprehensive experimental investigation focused on the bond behavior between reinforcing steel bars and tremie concrete, assessed through standardized pull-out tests. The objective was to evaluate the influence of some key parameters: reinforcement bar diameter, concrete age (and associated compressive strength), steel fiber content, and a bentonite coating on rebar surfaces. Experiments were conducted under laboratory conditions according to relevant standards. Slip between the reinforcement and tremie concrete was measured using a sophisticated high-precision optical laser device, enabling accurate assessment of bond characteristics. A large, i.e., a statistically sufficient, number of specimens was tested, allowing the results to be analyzed using the ANOVA technique to determine the statistical significance of each parameter. The results show that, under most test conditions, the influence of the bentonite suspension coating on the bond strength was not statistically significant. Similarly, variations in the bar diameter and fiber content showed no statistically significant impact within the tested ranges. In contrast, concrete age (compressive strength) exhibited a statistically significant influence, confirming that concrete maturity is a dominant factor in bond development. The results contribute to a better understanding of the bond mechanisms in reinforced concrete and can assist in optimizing design strategies where bond performance is critical. Full article
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18 pages, 26273 KB  
Review
Recent Applications of Focused Ion Beam–Scanning Electron Microscopy in Advanced Packaging
by Huan Zhang, Mengmeng Ma, Yuhang Liu, Wenwu Zhang and Chonglei Zhang
J. Manuf. Mater. Process. 2025, 9(5), 158; https://doi.org/10.3390/jmmp9050158 - 13 May 2025
Cited by 2 | Viewed by 4820
Abstract
Advanced packaging represents a crucial technological evolution aimed at overcoming limitations posed by Moore’s Law, driving the semiconductor industry from two-dimensional toward three-dimensional integrated structures. The increasing complexity and miniaturization of electronic devices have significantly heightened the challenges associated with failure analysis during [...] Read more.
Advanced packaging represents a crucial technological evolution aimed at overcoming limitations posed by Moore’s Law, driving the semiconductor industry from two-dimensional toward three-dimensional integrated structures. The increasing complexity and miniaturization of electronic devices have significantly heightened the challenges associated with failure analysis during process development. The focused ion beam–scanning electron microscope (FIB-SEM), characterized by its high processing precision and exceptional imaging resolution, has emerged as a powerful solution for the fabrication, defect localization, and failure analysis of micro- and nano-scale devices. This paper systematically reviews the innovative applications of FIB-SEM in the research of core issues, such as through-silicon-via (TSV) defects, bond interfacial failures, and redistribution layer (RDL) electromigration. Additionally, the paper discusses multimodal integration strategies combining FIB-SEM with advanced analytical techniques, such as high-resolution three-dimensional X-ray microscopy (XRM), electron backscatter diffraction (EBSD), and spectroscopy. Finally, it provides a perspective on the emerging applications and potential of frontier technologies, such as femtosecond-laser-assisted FIB, in the field of advanced packaging analysis. Full article
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27 pages, 2715 KB  
Review
A Narrative Review and Clinical Study on Er:YAG Laser Debonding of Ceramic and Composite Veneers
by Jose Villalobos-Tinoco, Fabio Andretti, Clint Conner, Silvia Rojas-Rueda, Nicholas G. Fischer, Margiezel Pagan-Banchs and Carlos A. Jurado
Biomimetics 2025, 10(5), 295; https://doi.org/10.3390/biomimetics10050295 - 6 May 2025
Cited by 1 | Viewed by 3651
Abstract
Background: Composite resin veneers have gained popularity due to their affordability and minimally invasive application as biomimetic restorations. However, long-term clinical challenges, such as discoloration, wear, and reduced fracture resistance, necessitate their replacement over time. Ceramic veneers, particularly feldspathic and lithium disilicate, offer [...] Read more.
Background: Composite resin veneers have gained popularity due to their affordability and minimally invasive application as biomimetic restorations. However, long-term clinical challenges, such as discoloration, wear, and reduced fracture resistance, necessitate their replacement over time. Ceramic veneers, particularly feldspathic and lithium disilicate, offer superior esthetics and durability, as demonstrated by studies showing their high survival rates and enamel-preserving preparation designs. However, while ceramic veneers survive longer than composite resin veneers, ceramic veneers may need to be removed and replaced. Reports vary for using Er:YAG (erbium-doped yttrium aluminum garnet) lasers for the removal of existing veneers. Methods: A review was conducted to evaluate the effectiveness of removing restorative materials with an Er:YAG laser. A clinical study was included, highlighting the conservative removal of aged composite resin veneers using the Er:YAG laser. This method minimizes enamel damage and facilitates efficient debonding. Following laser application, minimally invasive tooth preparation was performed, and feldspathic porcelain veneers were bonded. Results: The review showed positive outcomes whenever the Er:YAG laser was used. In the case study, after a 3-year follow-up, the restorations exhibited optimal function and esthetics. Conclusions: Laser-assisted debonding provides a safe and predictable method for replacing failing composite veneers with ceramic alternatives, aligning with contemporary biomimetic principles. Full article
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14 pages, 10029 KB  
Article
Microstructural and Mechanical Characterization of Cu/SnAg Pillar Bumps with Ni-Less Surface Finish Utilizing Laser-Assisted Bonding (LAB)
by Sang-Eun Han, Dong-Gyu Choi, Seonghui Han, Tae-Young Lee, Deok-Gon Han, Hoo-Jeong Lee and Sehoon Yoo
Materials 2025, 18(8), 1834; https://doi.org/10.3390/ma18081834 - 16 Apr 2025
Viewed by 1111
Abstract
In this study, an interconnection was formed between a Cu/SnAg pillar bump and an Ni-less surface-treated Cu pad through laser-assisted bonding (LAB), and its bonding characteristics were evaluated. The LAB process influences the bond quality and mechanical strength based on the laser irradiation [...] Read more.
In this study, an interconnection was formed between a Cu/SnAg pillar bump and an Ni-less surface-treated Cu pad through laser-assisted bonding (LAB), and its bonding characteristics were evaluated. The LAB process influences the bond quality and mechanical strength based on the laser irradiation time and laser power density. The growth of the intermetallic compound (IMC) in the joint cross-section was observed via FE-SEM analysis. Under optimized LAB conditions, minimal IMC growth and high bonding strength were achieved compared to conventional thermo-compression bonding (TCB) and mass reflow (MR) processes. As the laser irradiation time and laser power density increased, solder splashing was observed at bump temperatures above 300 °C. This is hypothesized to be due to the rapid temperature rise causing the flux to vaporize explosively, resulting in simultaneous solder splashing. With increasing laser power density, the failure mode transitioned from the solder to the IMC. Full article
(This article belongs to the Section Electronic Materials)
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11 pages, 1432 KB  
Article
Thermal Dynamics of Laser-Irradiated Trilayer Bonded-Zirconia Structures
by Mitchell Tharp, Jaccare Jauregui-Ulloa, Grace Mendonça De Souza and Susana Salazar Marocho
J. Funct. Biomater. 2025, 16(4), 137; https://doi.org/10.3390/jfb16040137 - 11 Apr 2025
Viewed by 813
Abstract
This study aims to assess the thermal dynamics of supporting structures during laser-assisted debonding of bonded yttrium-stabilized zirconia (YSZ) ceramic. We tested the hypothesis that the heat transfer to dentin analog material and composite resin resembles that of dentin. Thirty sintered YSZ (ZirCAD, [...] Read more.
This study aims to assess the thermal dynamics of supporting structures during laser-assisted debonding of bonded yttrium-stabilized zirconia (YSZ) ceramic. We tested the hypothesis that the heat transfer to dentin analog material and composite resin resembles that of dentin. Thirty sintered YSZ (ZirCAD, Ivoclar, Schann, Liechtenstein) slabs (4 mm diameter, 1 mm thickness) were air particle abraded, followed by two coats of Monobond Plus (Ivoclar). The slabs were bonded to exposed occlusal dentin, NEMA G10 dentin analog, or composite resin cylinders using Multilink Automix (Ivoclar) dual-cured cement. The bonded YSZ specimens (n = 10/group) subjected to irradiation with an Er,Cr:YSGG laser (Waterlase MD, Biolase, Foothill Ranch, CA, USA) at 7.5 W, 25 Hz, with 50% water and air for 15 s. Heat transfer during laser irradiation was monitored with an infrared camera (Optris PI 640, Optris GmbH, Berlin, Germany) at 0.1-s intervals. Data were analyzed using one-way ANOVA, which showed no significant differences in mean temperature between zirconia and cement layers across the substrates (composite resin, G10, dentin) (p = 0.0794). These results suggest flexibility in substrate choice for future thermal dynamics studies under laser irradiation. Full article
(This article belongs to the Special Issue Property, Evaluation and Development of Dentin Materials)
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28 pages, 1104 KB  
Systematic Review
Orthodontic Ceramic Bracket Removal Using Lasers: A Systematic Review
by Mateusz Michalak, Sylwia Kiryk, Agnieszka Kotela, Kamila Wiśniewska, Jan Kiryk, Jacek Zbigniew Zborowski, Jacek Matys and Maciej Dobrzyński
J. Funct. Biomater. 2025, 16(4), 123; https://doi.org/10.3390/jfb16040123 - 1 Apr 2025
Cited by 2 | Viewed by 2415
Abstract
Objective: The aim of this systematic review was to evaluate the effectiveness and safety of various laser systems for debonding ceramic orthodontic brackets compared to conventional mechanical removal methods. The primary outcomes assessed included enamel damage, pulp temperature changes, adhesive remnant index (ARI), [...] Read more.
Objective: The aim of this systematic review was to evaluate the effectiveness and safety of various laser systems for debonding ceramic orthodontic brackets compared to conventional mechanical removal methods. The primary outcomes assessed included enamel damage, pulp temperature changes, adhesive remnant index (ARI), and shear bond strength (SBS). Materials and Methods: A systematic search was conducted in November 2024 across the PubMed, Scopus, and Web of Science (WoS) databases following PRISMA guidelines. The initial search yielded 453 records, of which 41 studies met the inclusion criteria for qualitative and quantitative analysis. The risk of bias was assessed using a standardized scoring system, and only studies with accessible full texts were included. Results: The review highlighted significant heterogeneity in laser parameters, measurement protocols, and study methodologies. Among the evaluated lasers, CO2 and Er:YAG were the most frequently studied and demonstrated high efficacy in debonding ceramic brackets while maintaining enamel integrity. Sixteen studies assessing SBS reported a reduction from baseline values of 13–23 MPa to clinically acceptable ranges of 7–12 MPa following laser application. ARI was analyzed in 25 studies, with laser-treated groups exhibiting higher scores (2–3), indicating safer debonding with more adhesive remaining on the tooth surface, thereby reducing enamel damage. Pulpal temperature increases were examined in 23 studies, revealing that most laser types, when used within optimal parameters, did not exceed the 5.5 °C threshold considered safe for pulpal health. However, diode and Tm:YAP lasers showed potential risks of overheating in some studies. Conclusions: Laser-assisted debonding of ceramic orthodontic brackets is an effective and safe technique when applied with appropriate laser parameters. CO2 and Er:YAG lasers were the most effective in reducing SBS while preserving enamel integrity. However, variations in laser settings, study methodologies, and the predominance of in vitro studies limit the ability to establish standardized clinical guidelines. Further randomized controlled trials (RCTs) are necessary to develop evidence-based protocols for safe and efficient laser-assisted bracket removal in orthodontic practice. Full article
(This article belongs to the Special Issue New Trends in Biomaterials and Implants for Dentistry (2nd Edition))
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10 pages, 7511 KB  
Article
A Study on Laser-Assisted Cylindrical Grinding of Superhard Diamond Composite (DSiC) Materials: Surface Integrity and Efficiency
by Masih Paknejad, Bahman Azarhoushang, Robert Bösinger and Esmaeil Ghadiri Zahrani
J. Manuf. Mater. Process. 2025, 9(2), 56; https://doi.org/10.3390/jmmp9020056 - 11 Feb 2025
Cited by 1 | Viewed by 4106
Abstract
A novel laser-assisted cylindrical grinding process has been developed to enhance the machining of silicon-carbide-bonded diamond composites (DSiCs), critical for improving the performance and durability of components in subsea pump applications. DSiCs, containing approximately 50% diamond by volume, exhibit excellent mechanical and thermal [...] Read more.
A novel laser-assisted cylindrical grinding process has been developed to enhance the machining of silicon-carbide-bonded diamond composites (DSiCs), critical for improving the performance and durability of components in subsea pump applications. DSiCs, containing approximately 50% diamond by volume, exhibit excellent mechanical and thermal properties. The conventional grinding of these superhard materials presents challenges such as high grinding forces, elevated temperatures, and significant tool wear. To overcome these difficulties, a laser-assisted cylindrical grinding process has been developed, utilizing ultra-short-pulse laser radiation to induce material ablation with controlled structural damages, thereby reducing grinding forces, temperatures, and tool wear. This research investigates the influence of grinding wheel specifications and grinding parameters on surface quality and tool life. The results indicate modest enhancements in surface integrity, achieving damage-free ground surfaces, and notable improvements in grinding ratio (G-ratio) by up to 247% and actual removal depth by up to 99% compared to conventional grinding. The laser-assisted cylindrical grinding process using vitrified-bonded diamond wheels holds significant promise for advancing subsea pump technology by enabling the use of DSiCs and achieving plateau ground surfaces. Full article
(This article belongs to the Special Issue Advances in Laser-Assisted Manufacturing Techniques)
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19 pages, 9363 KB  
Article
Investigating the Influence of Laser-Etched Straight and Wavy Textures on Grinding Efficiency and Tool Quality of WC–Co Carbide Cutting Tools
by Chao Li, Tielin Li, Xiaohong Zhang, Tianzhongsen He, Linzhi Su, Dongdong Wen, Sizhen Shao, Xiao Cai and Qingzheng Cao
Materials 2025, 18(3), 528; https://doi.org/10.3390/ma18030528 - 24 Jan 2025
Cited by 6 | Viewed by 1337
Abstract
WC–Co cemented carbide has been widely used as machining tool material due to its good mechanical properties. Grinding is an important process in the manufacture of cemented carbide tools. When grinding tools, there are problems such as excessive grinding force, small chip space, [...] Read more.
WC–Co cemented carbide has been widely used as machining tool material due to its good mechanical properties. Grinding is an important process in the manufacture of cemented carbide tools. When grinding tools, there are problems such as excessive grinding force, small chip space, and poor lubrication and cooling performance, which in turn contribute to surface defects such as burrs, burns, and even edge damage such as edge chipping. These problems constrain the use of carbide tools, so that the cutting force is unstable and the machining surface quality is poor when the tool is in service. In this paper, straight-line and wavy-texture patterns were designed and formed on the surface of WC–Co tools using a picosecond laser. Grinding experiments were conducted on the ablated tool using a resin-bonded diamond wheel, and surface morphology, roughness, grinding force, and cutting edge quality were evaluated. Finally, turning experiments were conducted to compare the cutting performance of the tools after conventional and laser-assisted grinding. The experimental results showed that the tools with wavy texture showed superior surface and cutting edge quality, with 53.7% and 51.2% reduction in normal and tangential grinding forces, respectively, and 66.6% maximum reduction in edge chipping for the wavy textured tools. Therefore, this study not only reveals the advantages of laser-assisted grinding in machining WC–Co cutting tools, but also provides a valuable theoretical basis for realizing high-efficiency and low-loss tool machining. Full article
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14 pages, 3064 KB  
Article
Ring Beam Modulation-Assisted Laser Welding on Dissimilar Materials for Automotive Battery
by Se-Hoon Choi, Jong-Hyun Kim and Hae-Woon Choi
J. Manuf. Mater. Process. 2025, 9(2), 28; https://doi.org/10.3390/jmmp9020028 - 21 Jan 2025
Cited by 3 | Viewed by 2343
Abstract
This paper investigates Ring Beam Modulation-assisted Laser (RBML) welding as a novel approach for joining dissimilar materials, specifically aluminum and copper, which are essential in high-performance applications such as electric vehicle batteries and aerospace components. The study aims to address challenges such as [...] Read more.
This paper investigates Ring Beam Modulation-assisted Laser (RBML) welding as a novel approach for joining dissimilar materials, specifically aluminum and copper, which are essential in high-performance applications such as electric vehicle batteries and aerospace components. The study aims to address challenges such as thermal mismatches, brittle intermetallic compounds, and structural defects that hinder traditional welding methods. The research combines experimental and computational analyses to evaluate the impact of heat input distributions and laser modulation parameters on weld quality and strength. Three welding cases are compared: fixed center beam with variable ring beam outputs, variable center beam with fixed ring outputs, and a wobble-mode beam to enhance interfacial bonding. Computational modeling supports the optimization process by simulating heat flows and material responses, exploring various shape factors, and guiding parameter selection. Key findings include a nonlinear relationship between heat input and welding strength across the cases. Case 1 demonstrates improved weld strength with higher ring beam input, while Case 2 achieves excellent reliability with relatively lower inputs. Case 3 introduces wobble welding, yielding superior resolution and consistent weld quality. These results confirm that precise ring beam modulation enhances weld reliability, minimizes thermal distortions, and optimizes energy consumption. The manuscript advances the state of knowledge in laser welding technology by demonstrating a scalable, energy-efficient method for joining dissimilar materials. This contribution supports the fabrication of lightweight, high-reliability assemblies, paving the way for innovative applications in the automotive, medical, aerospace, and shipbuilding industries. Full article
(This article belongs to the Special Issue Advances in Dissimilar Metal Joining and Welding)
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17 pages, 830 KB  
Systematic Review
Laser Applications in Metal Orthodontic Bracket Debonding: A Systematic Review
by Patryk Woś, Sylwia Kiryk, Tomasz Dyl, Jan Kiryk, Tomasz Horodniczy, Magdalena Szablińska, Magdalena Aleksandra Dubowik, Wojciech Dobrzyński, Marcin Mikulewicz, Jacek Matys and Maciej Dobrzyński
Appl. Sci. 2025, 15(2), 927; https://doi.org/10.3390/app15020927 - 18 Jan 2025
Cited by 3 | Viewed by 4567
Abstract
Objective: The aim of this systematic review was to evaluate the effectiveness and safety of various laser wavelengths for debonding orthodontic metal brackets compared to traditional plier-based methods. The primary outcomes assessed were enamel damage, pulp temperature changes, adhesive remnant index (ARI), and [...] Read more.
Objective: The aim of this systematic review was to evaluate the effectiveness and safety of various laser wavelengths for debonding orthodontic metal brackets compared to traditional plier-based methods. The primary outcomes assessed were enamel damage, pulp temperature changes, adhesive remnant index (ARI), and shear bond strength (SBS). Materials and Methods: In September 2024, an electronic search was performed across the PubMed, Web of Science (WoS), and Scopus databases, adhering to the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) guidelines and the PICO framework. The initial search yielded 453 records. After eliminating 256 duplicates, 197 unique records were left for screening, which ultimately led to the qualification of 8 articles that met the inclusion criteria for both qualitative and quantitative analyses. The risk of bias in the articles was assessed by two independent reviewers. Results: The included studies demonstrated that laser-assisted debonding generally resulted in less adhesive residue on the enamel surface compared to conventional methods, as evidenced by the reductions in ARI scores reported in two studies. Temperature increases during laser use varied depending on the laser type and power settings. The Nd:YAG (neodymium-yttrium, aluminum, garnet) laser was found to cause significant temperature rises, posing a potential risk to pulp tissue, while the Er:YAG (erbium—yttrium, aluminum, garnet) and Er,Cr:YSGG (erbium, chromium—yttrium, scandium, gallium, garnet) lasers produced only negligible increases in pulp temperature. SBS comparisons revealed no significant differences between the laser-assisted and traditional debonding methods. Additionally, diode lasers demonstrated the potential to minimize enamel damage, particularly when operated at lower power settings. Four publications were assessed as high quality (low risk of bias), and another four as moderate quality (average risk of bias). Conclusions: In conclusion, laser-assisted orthodontic metal bracket debonding, when conducted with appropriately calibrated parameters, is a safe method for preserving tooth tissue. However, its advantages appear to be minimal compared to conventional plier-based methods, highlighting the need for further research to justify its broader clinical application. Full article
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13 pages, 20364 KB  
Article
The Effect of In Situ Laser-Assisted Plasma Spraying on the Plasma Etching Resistance of Yttrium Oxide Coating
by Xutao Zhao, Tian Xie, Panpan Zhang, Zhehe Yao, Qunli Zhang, Jiake Deng, Yongfeng Sui and Jianhua Yao
Coatings 2024, 14(11), 1427; https://doi.org/10.3390/coatings14111427 - 10 Nov 2024
Cited by 2 | Viewed by 2715
Abstract
In recent years, yttrium oxide coatings prepared by atmospheric plasma spraying (APS) have been employed extensively in semiconductor processing equipment. Meanwhile, defects in yttrium oxide coating, such as unmelted particles and pores, reduce the etching resistance of the coating. In this work, two [...] Read more.
In recent years, yttrium oxide coatings prepared by atmospheric plasma spraying (APS) have been employed extensively in semiconductor processing equipment. Meanwhile, defects in yttrium oxide coating, such as unmelted particles and pores, reduce the etching resistance of the coating. In this work, two yttrium oxide coatings were prepared by in situ laser-assisted plasma spraying (LAPS) coupled with a 500 W and 600 W laser for comparison with a coating prepared by APS, and the effects of the laser on the coating properties were investigated. The results show that the surface roughness was reduced by 25.7% (500 W) and 25.3% (600 W) and the porosity was reduced by 52.3% (500 W) and 36.9% (600 W) after laser coupling. After being etched by CF4/CHF3 for a long time, it was observed from SEM, EDS and XPS analyses that the intensity ratios of the Y-F bonds in the coating were 1 (APS):1.3 (LAPS+500W):1.1 (LAPS+600W), which indicated that the LAPS+500W coating had a thicker fluorination layer. It was also observed that the fluorination layer at the defect was first eroded; then, the erosion area gradually spread to the surrounding area, and finally, the fluorination layer was etched. This indicated that the defects had a significant impact on the etching resistance. Consequently, the LAPS+500W coating with fewer defects and a thicker fluorination layer showed the lowest etching rate. Therefore, in situ laser-assisted plasma spraying coupled with an appropriate laser power is an effective method to improve the performance of yttrium oxide coatings. Full article
(This article belongs to the Special Issue Advances in Deposition and Characterization of Hard Coatings)
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16 pages, 4421 KB  
Article
Synthesis and Mass Spectrometry Structural Assessment of Polyesteramides Based on ε-Caprolactone and L-Phenylalanine
by Slim Salhi, Houcine Ammar, Joanna Rydz and Cristian Peptu
Polymers 2024, 16(21), 2955; https://doi.org/10.3390/polym16212955 - 22 Oct 2024
Viewed by 2038
Abstract
L-Phenylalanine-ε-caprolactone-based polyesteramides (PCPs) were synthesized via melt polycondensation across a diverse range of molar compositions. The copolymer structure was extensively characterized using nuclear magnetic resonance (NMR) and matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS). NMR analysis confirmed the intercalation of the L-Phenylalanine comonomer [...] Read more.
L-Phenylalanine-ε-caprolactone-based polyesteramides (PCPs) were synthesized via melt polycondensation across a diverse range of molar compositions. The copolymer structure was extensively characterized using nuclear magnetic resonance (NMR) and matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS). NMR analysis confirmed the intercalation of the L-Phenylalanine comonomer units within the polyester backbone. MALDI MS characterization further demonstrated the formation of linear PCP chains with carboxyl end groups. A detailed structural analysis through MALDI MS/MS fragmentation indicated that ester bond scission was the predominant fragmentation mechanism, depicting the polyesteramide sequence in the copolymers. The resulting copolymers were primarily amorphous, except for those with molar compositions of 90/10 and 80/20, which exhibited semi-crystalline structures. Additionally, these PCPs showed an increase in glass transition temperatures with higher amino acid contents and demonstrated good thermal stabilities, as evidenced by a 10% mass loss at elevated temperatures. Full article
(This article belongs to the Section Polymer Chemistry)
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11 pages, 6183 KB  
Article
Brittle Fracture Behavior of Sn-Ag-Cu Solder Joints with Ni-Less Surface Finish via Laser-Assisted Bonding
by Seonghui Han, Sang-Eun Han, Tae-Young Lee, Deok-Gon Han, Young-Bae Park and Sehoon Yoo
Materials 2024, 17(14), 3619; https://doi.org/10.3390/ma17143619 - 22 Jul 2024
Cited by 4 | Viewed by 2779
Abstract
In this study, we investigated the brittle fracture behavior of Sn-3.0Ag-0.5Cu (SAC305) solder joints with a Direct Electroless Gold (DEG) surface finish, formed using laser-assisted bonding (LAB) and mass reflow (MR) techniques. Commercial SAC305 solder balls were used to ensure consistency. LAB increases [...] Read more.
In this study, we investigated the brittle fracture behavior of Sn-3.0Ag-0.5Cu (SAC305) solder joints with a Direct Electroless Gold (DEG) surface finish, formed using laser-assisted bonding (LAB) and mass reflow (MR) techniques. Commercial SAC305 solder balls were used to ensure consistency. LAB increases void fractions and coarsens the primary β-Sn phase with higher laser power, resulting in a larger eutectic network area fraction. In contrast, MR produces solder joints with minimal voids and a thicker intermetallic compound (IMC) layer. LAB-formed joints exhibit higher high-speed shear strength and lower brittle fracture rates compared to MR. The key factor in the reduced brittle fracture in LAB joints is the thinner IMC layer at the joint interface. This study highlights the potential of LAB in enhancing the mechanical reliability of solder joints in advanced electronic packaging applications. Full article
(This article belongs to the Section Electronic Materials)
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33 pages, 13561 KB  
Article
The Effect of Scanning Strategy on the Thermal Behavior and Residual Stress Distribution of Damping Alloys during Selective Laser Melting
by Zhiqiang Yan, Kaiwen Wu, Zhongmin Xiao, Jizhuang Hui and Jingxiang Lv
Materials 2024, 17(12), 2912; https://doi.org/10.3390/ma17122912 - 14 Jun 2024
Cited by 3 | Viewed by 1962
Abstract
The manufacture of damping alloy parts with stable damping properties and high mechanical performances in the selective laser melting (SLM) process is influenced by temperature evolution and residual stress distribution. Choosing an appropriate scanning strategy, namely the specific trajectory along which the laser [...] Read more.
The manufacture of damping alloy parts with stable damping properties and high mechanical performances in the selective laser melting (SLM) process is influenced by temperature evolution and residual stress distribution. Choosing an appropriate scanning strategy, namely the specific trajectory along which the laser head scans powders within given area, is crucial, but clearly defined criteria for scanning strategy design are lacking. In this study, a three-dimensional finite element model (FEM) of the SLM process for manufacturing a WE43 alloy component was established and validated against the published experimental data. Eleven different scanning strategies were designed and simulated, considering variables such as scanning track length, direction, Out–In or In–Out strategy, start point, and interlayer variation. The results showed that scanning strategy, geometry, and layer number collectively affect temperature, melt pool, and stress outputs. For instance, starting scanning at a colder part of the powder layer could lead to a high peak temperature and low melt pool depth. A higher layer number generally results in lower cooling rate, a lower temperature gradient, a longer melt pool life, and larger melt pool dimensions. Changing the start point between scanning circulations helps mitigate detrimental residual stress. This work highlights the potential of analyzing various scanning strategy-related variables, which contributes to reducing trial-and-error tests and selecting optimal scanning strategies under different product quality requirements. This article can assist in the design of appropriate scanning strategies to prevent defects such as element loss due to evaporation, poor bonding, and deformation or cracking from high residual stress. Additionally, identifying stress concentration locations and understanding the effects of geometry and layer number on thermal and mechanical behaviors can assist in geometry design. Full article
(This article belongs to the Special Issue Advances in Laser Processing Technology of Materials)
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