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Keywords = laser cold ablation

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12 pages, 4320 KiB  
Article
Two-Dimensional Fin-Shaped Carbon Nanotube Field Emission Structure with High Current Density Capability
by Xiaoyu Qin, Yulong Ding, Jun Jiang, Junzhong Liang, Yanlin Ke, Juncong She, Yu Zhang and Shaozhi Deng
Electronics 2025, 14(7), 1268; https://doi.org/10.3390/electronics14071268 - 24 Mar 2025
Viewed by 495
Abstract
A vacuum electron device requires a high-performance electron source that provides high current and current density. A carbon nanotube (CNT) field emission cold cathode is the optimal choice. To achieve its higher emission current capacity, its macroscale and microscale structures should be combined. [...] Read more.
A vacuum electron device requires a high-performance electron source that provides high current and current density. A carbon nanotube (CNT) field emission cold cathode is the optimal choice. To achieve its higher emission current capacity, its macroscale and microscale structures should be combined. Here, a two-dimensional fin-shaped CNT field emission structure is proposed, integrating a macroscale CNT fin with billions of nanoscale nanotubes. The fin contributes two-dimensional heat dissipation paths, and the nanotubes provide a high field enhancement factor, both of which enhance the high-current field emission characteristics. A model combining macro- and microstructures was simulated to optimize the structure and fin-shaped array parameters. The calculation of the field enhancement factor of the compound structure is proposed. It was also determined that the fin-shaped array configuration can be densely arranged without field screen effects, thereby enhancing the emission area efficiency. The fin-shaped CNT emitter and array emitters with different parameters were fabricated by laser ablation, which demonstrated superior field emission characteristics. A 16.55 mA pulsing emission current, 1103.33 A/cm2 current density, and 6.13% current fluctuation were achieved in a single fin-shaped CNT emitter. An 87.29 mA pulsing emission current, 0.349 A/cm2 current density, and 1.9% current fluctuation were achieved in a fin-shaped CNT array. The results demonstrate that the high-current field emission electron source can be realized in a well-designed emission structure that bridges the nanoscale emitter and macroscale structure. Full article
(This article belongs to the Special Issue Vacuum Electronics: From Micro to Nano)
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17 pages, 5111 KiB  
Article
Improving Temperature Adaptation for Food Safety: Colorimetric Nanoparticle-Based Time–Temperature Indicators (TTIs) to Detect Cumulative Temperature Disturbances
by Gustavo Lanza, Jaime Andres Perez-Taborda and Alba Avila
Foods 2025, 14(5), 742; https://doi.org/10.3390/foods14050742 - 22 Feb 2025
Cited by 1 | Viewed by 1201
Abstract
The global commitment to ending hunger by 2030 has driven Colombia to align its Sustainable Development Goals (SDGs) toward reducing food waste and ensuring access to safe, nutritious food. A critical need is monitoring cumulative temperatures across food supply networks, prioritizing products over [...] Read more.
The global commitment to ending hunger by 2030 has driven Colombia to align its Sustainable Development Goals (SDGs) toward reducing food waste and ensuring access to safe, nutritious food. A critical need is monitoring cumulative temperatures across food supply networks, prioritizing products over transport or storage infrastructure. This study introduces a Functional Time–Temperature Indicator (TTI) using nanodispersions of silver (Ag) and gold (Au) nanoparticles housed in 3D-printed plant-based resin containers. Nanoparticles were synthesized via three methods: in situ reduction (AgNPs), seed-based thermal synthesis (AgTNPs), and pulsed laser ablation in liquid (AuNPs). The TTIs operate through three colorimetric mechanisms: NP concentration, geometry changes, and agglomeration. At 4 °C, AgNPs and AgTNPs maintained stable color, while at 22 °C, they exhibited significant changes, with AgNPs reaching 252% variation within 5 h. AuNPs responded at lower temperatures, showing up to 27% variation. Containers enabled effective nanodispersion incorporation due to their thermal and optical properties. AgTNP-based TTIs demonstrated the most noticeable changes at 22 °C, with a total color difference (ΔE) of 39.9, easily detectable by observers. These TTIs provide robust solutions for continuous cold chain monitoring, enhancing food safety and preserving quality throughout the supply chain. Full article
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14 pages, 2944 KiB  
Article
Application of Femtosecond Laser Processing Method in the Sustainable Conservation of Stone Cultural Relics: An Example of Green Schist in Wudang Mountain, China
by Mu Chen, Chengaonan Wang, Kai Li, Xianshi Jia, Cong Wang and Yansong Wang
Sustainability 2024, 16(8), 3169; https://doi.org/10.3390/su16083169 - 10 Apr 2024
Cited by 1 | Viewed by 1651
Abstract
The ancient building complex in Wudang Mountain, China, is known as the “Museum of Ancient Chinese Architectural Accomplishments”. However, the valuable stone components are preserved in open or semi-open environments and environmental factors such as rain seriously threaten its sustainable conservation. In this [...] Read more.
The ancient building complex in Wudang Mountain, China, is known as the “Museum of Ancient Chinese Architectural Accomplishments”. However, the valuable stone components are preserved in open or semi-open environments and environmental factors such as rain seriously threaten its sustainable conservation. In this context, a femtosecond laser processing method has been demonstrated to be able to prepare hierarchical micro-nano structures on the stone surface to regulate its wettability, achieving the purpose of sustainable conservation. In this paper, the processing mechanism and performance of the femtosecond laser on green schist, a local stone material in the Wudang Mountain, are systematically investigated. It is found that green schist, as a typical non-homogeneous material, exhibits significant differences in its absorption of femtosecond laser with different compositions. Among them, quartz, chlorite, and muscovite are the three main compositions, and they are mainly characterized by cold ablation, thermal melting, and expansion under the irradiation of the femtosecond laser (238 fs, 100 kHz, 40 μJ, 33 μm, 500–40,000 pulses), respectively, and it is difficult to achieve a uniform and stable surface structure. Based on this, we prepared grooves with a spacing of 100–400 μm by scanning the femtosecond laser. Through the characterization of surface morphology, elemental composition, and three-dimensional structure, the processing mechanism of the hierarchical micro-nano structures of green schist under the irradiation of the femtosecond laser is comprehensively revealed. Finally, the wettability modulation result of water contact angle up to 147° is achieved by processing the grooves with an optimal spacing of 400 μm. The results of this research are of guiding significance for the sustainable conservation of ancient buildings and cultural relics. Full article
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25 pages, 32156 KiB  
Review
Modification of Diamond Surface by Femtosecond Laser Pulses
by Vitali V. Kononenko
Photonics 2023, 10(10), 1077; https://doi.org/10.3390/photonics10101077 - 25 Sep 2023
Cited by 11 | Viewed by 3644
Abstract
The basic mechanisms of laser interaction with synthetic diamond are reviewed. The characteristics of the main regimes of diamond surface etching are considered. In addition to the well-known graphitization and ablation processes, nanoablation and accumulative graphitization, which have attracted relatively recent attention, are [...] Read more.
The basic mechanisms of laser interaction with synthetic diamond are reviewed. The characteristics of the main regimes of diamond surface etching are considered. In addition to the well-known graphitization and ablation processes, nanoablation and accumulative graphitization, which have attracted relatively recent attention, are described in detail. The focus is on femtosecond (fs) laser exposure, which allows for the formation of a dense cold electron–hole plasma in the focal zone and minimal overheating in the surrounding area. This potentially opens the way to the development of unique laser-based technologies that combine physical and chemical processes for precise surface treatment and functionalization. The physical limitations that determine how precisely the diamond surface can be treated by short-pulsed laser radiation and possible ways to overcome them with the ultimate goal of removing ultrathin layers of the material are discussed. Special attention is paid to the novel possibility of inducing the local formation of point active defects—nitrogen vacancy (NV) complexes in the laser-irradiated zone. Such defects have been at the forefront of solid-state physics for the past thirty years due to continuous attempts to exploit their unique properties in quantum optics, quantum computing, magnetometry, probing, and other fields. Both regimes of NV center formation with and without graphitization of the diamond lattice are considered. Thus, it is shown that intense pulsed laser irradiation is a perfect tool for the processing of synthetic diamonds at the micro-, nano-, and even at the atomic level, which can be well controlled and managed. Full article
(This article belongs to the Special Issue Ultrafast Laser Systems)
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12 pages, 1142 KiB  
Review
Transarterial Embolization and Percutaneous Ablation of Primary and Metastatic Soft Tissue Tumors
by Chang Shu, Maria Lim and Adam Fang
Life 2023, 13(7), 1485; https://doi.org/10.3390/life13071485 - 30 Jun 2023
Cited by 6 | Viewed by 3071
Abstract
Soft tissue tumors (STTs) include a range of benign and malignant tumors originating from soft tissues. Transarterial and percutaneous therapies are image-guided and minimally invasive approaches for managing primary and metastatic STTs. The objective of this review is to discuss transarterial and percutaneous [...] Read more.
Soft tissue tumors (STTs) include a range of benign and malignant tumors originating from soft tissues. Transarterial and percutaneous therapies are image-guided and minimally invasive approaches for managing primary and metastatic STTs. The objective of this review is to discuss transarterial and percutaneous therapies by examining the current literature, including indications, patient selection, safety, and effectiveness. Transarterial therapies (e.g., transarterial bland embolization and transarterial chemoembolization) involve the delivery of either embolic or chemotherapeutic particles using a catheter into arteries feeding the tumor, resulting in localized tumor destruction. Percutaneous therapies (e.g., radiofrequency ablation, cryoablation, irreversible electroporation, laser ablation, and magnetic resonance-guided high-intensity focused ultrasound) involve the delivery of either hot or cold temperatures, electrical current, laser, or ultrasound to specifically target tumor cells. Both therapies have been shown to be safe and effective for reducing morbidity and local control of STTs, specifically in patients who are surgically inoperable or who are unresponsive to conventional therapies. Accurate diagnosis, staging, and histological subtype identification are crucial for treatment selection. A multidisciplinary approach, a thorough understanding of tissue anatomy and surrounding structures, as well as individualized strategies based on assessment are essential for optimal patient care. Full article
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15 pages, 11206 KiB  
Article
Investigation of Heat Accumulation in Femtosecond Laser Drilling of Carbon Fiber-Reinforced Polymer
by Yaoyao Li, Guangyu He, Hongliang Liu and Mingwei Wang
Micromachines 2023, 14(5), 913; https://doi.org/10.3390/mi14050913 - 23 Apr 2023
Cited by 9 | Viewed by 2951
Abstract
Carbon fiber-reinforced polymer (CFRP) has indispensable applications in the aerospace field because of its light weight, corrosion resistance, high specific modulus and high specific strength, but its anisotropy brings great difficulties to precision machining. Delamination and fuzzing, especially the heat-affected zone (HAZ), are [...] Read more.
Carbon fiber-reinforced polymer (CFRP) has indispensable applications in the aerospace field because of its light weight, corrosion resistance, high specific modulus and high specific strength, but its anisotropy brings great difficulties to precision machining. Delamination and fuzzing, especially the heat-affected zone (HAZ), are the difficulties that traditional processing methods cannot overcome. In this paper, single-pulse and multi-pulse cumulative ablation experiments and drilling of CFRP have been carried out using the characteristics of a femtosecond laser pulse, which can realize precision cold machining. The results show that the ablation threshold is 0.84 J/cm2 and the pulse accumulation factor is 0.8855. On this basis, the effects of laser power, scanning speed and scanning mode on the heat-affected zone and drilling taper are further studied, and the underlying mechanism of drilling is analyzed. By optimizing the experimental parameters, we obtained the HAZ < 10 μm, a cylindrical hole with roundness > 0.95 and taper < 5°. The research results confirm that ultrafast laser processing is a feasible and promising method for CFRP precision machining. Full article
(This article belongs to the Special Issue Laser Micro/Nano Fabrication)
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7 pages, 2060 KiB  
Case Report
Pigmentation and Scaring Management after Hypodermoclysis, a Case Report
by Kamal Alhallak, Adel Abdulhafid, Salem Tomi and Dima Omran
Cosmetics 2022, 9(1), 10; https://doi.org/10.3390/cosmetics9010010 - 12 Jan 2022
Cited by 2 | Viewed by 5831
Abstract
Hypodermoclysis is the continuous subcutaneous infusion of a parenteral solution into dermal tissue, which is typically associated with skin lesions and cosmetic issues in the majority of patients. Scarring and pigmentation are two of the potential skin lesions after hypodermoclysis. The way skin [...] Read more.
Hypodermoclysis is the continuous subcutaneous infusion of a parenteral solution into dermal tissue, which is typically associated with skin lesions and cosmetic issues in the majority of patients. Scarring and pigmentation are two of the potential skin lesions after hypodermoclysis. The way skin diseases and cosmetic issues are treated has altered dramatically as a result of laser technology. This is the first article to our knowledge that describes the treatment of pigmentation and scarring produced by Hypodermoclysis cutaneous damage by using laser treatment. It was vital to select the appropriate endpoint, technology, and configuration parameters. The lesion was completely resolved after five months of treatment with four laser sessions. The first session used a fractional Er-Yag laser to perform cold ablation. The remaining sessions used 1064 and 585 nm Nd-Yag Q-switch lasers to operate in the nanosecond region. To minimize the danger of post-inflammatory hyperpigmentation (PIH), the treated region was prepped between laser treatments with 4% hydroquinone (HQ) cream. Our protocol may reduce scars and pigmentation while minimizing adverse effects and downtime. Full article
(This article belongs to the Special Issue Feature Papers in Cosmetics in 2022)
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17 pages, 11200 KiB  
Article
Adhesive Joints with Laser Shaped Surface Microstructures
by Szymon Tofil, Robert Barbucha, Marek Kocik, Rafał Kozera, Mateusz Tański, Natarajan Arivazhagan, Jianhua Yao and Andrej Zrak
Materials 2021, 14(24), 7548; https://doi.org/10.3390/ma14247548 - 9 Dec 2021
Cited by 12 | Viewed by 2298
Abstract
One of the most commonly applied methods of joining dissimilar materials is gluing. This could be mainly attributed to the applicability of this technique in various industries. The article presents a method of material surface treatment, which increases the shear strength of adhesive [...] Read more.
One of the most commonly applied methods of joining dissimilar materials is gluing. This could be mainly attributed to the applicability of this technique in various industries. The article presents a method of material surface treatment, which increases the shear strength of adhesive joints for lightweight metals such as aluminum with plastics. For this purpose, laser surface microstructuring was performed on each of the selected construction materials. As a result of the performed treatment, the active surface of the glued area was increased, which increased the adhesive strength. The picosecond laser with UV radiation used in the research is TruMicro 5325c with which material can be removed as a result of the cold ablation phenomenon. The applied parameters of the laser device did not cause thermal damage to the surface of the microstructured materials, which was confirmed by microscopic examination. Laser micromachining did not deteriorate the degree of wetting of the tested materials, either, as was confirmed by the contact angle and surface energy measurements with the use of water as the measuring liquid. In investigated cases of microstructure types, the presented method significantly increased the shear strength of the joints formed, as demonstrated by the presented strength test results. Research has shown that created joints with microstructure made according to the described method, are characterized by a significant increase in strength, up to 376%, compared to materials without microstructure. The presented results are part of a series of tests aimed at selecting the operating laser parameters for the implementation of geometric shapes of microstructures which will increase the strength of adhesive joints in selected materials. Full article
(This article belongs to the Special Issue Laser Treatment for Surface Layers)
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24 pages, 12649 KiB  
Review
Mid-Infrared Few-Cycle Pulse Generation and Amplification
by Kan Tian, Linzhen He, Xuemei Yang and Houkun Liang
Photonics 2021, 8(8), 290; https://doi.org/10.3390/photonics8080290 - 21 Jul 2021
Cited by 27 | Viewed by 7750
Abstract
In the past decade, mid-infrared (MIR) few-cycle lasers have attracted remarkable research efforts for their applications in strong-field physics, MIR spectroscopy, and bio-medical research. Here we present a review of MIR few-cycle pulse generation and amplification in the wavelength range spanning from 2 [...] Read more.
In the past decade, mid-infrared (MIR) few-cycle lasers have attracted remarkable research efforts for their applications in strong-field physics, MIR spectroscopy, and bio-medical research. Here we present a review of MIR few-cycle pulse generation and amplification in the wavelength range spanning from 2 to ~20 μm. In the first section, a brief introduction on the importance of MIR ultrafast lasers and the corresponding methods of MIR few-cycle pulse generation is provided. In the second section, different nonlinear crystals including emerging non-oxide crystals, such as CdSiP2, ZnGeP2, GaSe, LiGaS2, and BaGa4Se7, as well as new periodically poled crystals such as OP-GaAs and OP-GaP are reviewed. Subsequently, in the third section, the various techniques for MIR few-cycle pulse generation and amplification including optical parametric amplification, optical parametric chirped-pulse amplification, and intra-pulse difference-frequency generation with all sorts of designs, pumped by miscellaneous lasers, and with various MIR output specifications in terms of pulse energy, average power, and pulse width are reviewed. In addition, high-energy MIR single-cycle pulses are ideal tools for isolated attosecond pulse generation, electron dynamic investigation, and tunneling ionization harness. Thus, in the fourth section, examples of state-of-the-art work in the field of MIR single-cycle pulse generation are reviewed and discussed. In the last section, prospects for MIR few-cycle lasers in strong-field physics, high-fidelity molecule detection, and cold tissue ablation applications are provided. Full article
(This article belongs to the Special Issue Laser Amplifiers)
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14 pages, 3547 KiB  
Article
Cold Ablation Robot-Guided Laser Osteotome (CARLO®): From Bench to Bedside
by Matthias Ureel, Marcello Augello, Daniel Holzinger, Tobias Wilken, Britt-Isabelle Berg, Hans-Florian Zeilhofer, Gabriele Millesi, Philipp Juergens and Andreas A. Mueller
J. Clin. Med. 2021, 10(3), 450; https://doi.org/10.3390/jcm10030450 - 24 Jan 2021
Cited by 23 | Viewed by 5569
Abstract
Background: In order to overcome the geometrical and physical limitations of conventional rotating and piezosurgery instruments used to perform bone osteotomies, as well as the difficulties in translating digital planning to the operating room, a stand-alone robot-guided laser system has been developed by [...] Read more.
Background: In order to overcome the geometrical and physical limitations of conventional rotating and piezosurgery instruments used to perform bone osteotomies, as well as the difficulties in translating digital planning to the operating room, a stand-alone robot-guided laser system has been developed by Advanced Osteotomy Tools, a Swiss start-up company. We present our experiences of the first-in-man use of the Cold Ablation Robot-guided Laser Osteotome (CARLO®). Methods: The CARLO® device employs a stand-alone 2.94-µm erbium-doped yttrium aluminum garnet (Er:YAG) laser mounted on a robotic arm. A 19-year-old patient provided informed consent to undergo bimaxillary orthognathic surgery. A linear Le Fort I midface osteotomy was digitally planned and transferred to the CARLO® device. The linear part of the Le Fort I osteotomy was performed autonomously by the CARLO® device under direct visual control. All pre-, intra-, and postoperative technical difficulties and safety issues were documented. Accuracy was analyzed by superimposing pre- and postoperative computed tomography images. Results: The CARLO® device performed the linear osteotomy without any technical or safety issues. There was a maximum difference of 0.8 mm between the planned and performed osteotomies, with a root-mean-square error of 1.0 mm. The patient showed normal postoperative healing with no complications. Conclusion: The newly developed stand-alone CARLO® device could be a useful alternative to conventional burs, drills, and piezosurgery instruments for performing osteotomies. However, the technical workflow concerning the positioning and fixation of the target marker and the implementation of active depth control still need to be improved. Further research to assess safety and accuracy is also necessary, especially at osteotomy sites where direct visual control is not possible. Finally, cost-effectiveness analysis comparing the use of the CARLO® device with gold-standard surgery protocols will help to define the role of the CARLO® device in the surgical landscape. Full article
(This article belongs to the Special Issue Innovation in Head and Neck Reconstructive Surgery)
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22 pages, 6208 KiB  
Article
Early Permian Granitic Magmatism in Middle Part of the Northern Margin of the North China Craton: Petrogenesis, Source, and Tectonic Setting
by Longxue Li, Qingye Hou, Dingling Huang and Xinyu Wang
Minerals 2021, 11(2), 99; https://doi.org/10.3390/min11020099 - 20 Jan 2021
Cited by 3 | Viewed by 2614
Abstract
The late Palaeozoic was an important period of tectonic evolution for the northern margin of the North China Craton (NCC). The source(s) and tectonic setting of early Permian granitoid rocks emplaced along the northern margin of the NCC are still unclear. These granitoids [...] Read more.
The late Palaeozoic was an important period of tectonic evolution for the northern margin of the North China Craton (NCC). The source(s) and tectonic setting of early Permian granitoid rocks emplaced along the northern margin of the NCC are still unclear. These granitoids formed between ~295.4–276.1 Ma (uncertainties ranging from ±1.5 to ±7.8 Ma) according to zircon laser ablation inductively coupled mass spectrometry (LA-ICP-MS) and sensitive high-resolution ion microprobe (SHRIMP) U-Pb data. The Dadongou (DDG) pluton is an A1-type granite and the Dananfangzi (DNFZ) pluton is an A2-type granite. The Erdaowa (EDW), Lisicun (LSC), Wuhai (WH) and Gehuasitai (GHST) plutons are I-type granites. The Yuanbaoshan (YBS) dykes are diorite and syenodiorite. All the granitoids are enriched in large ion lithophile elements and light rare earth elements, depleted in high field strength elements and have negative εNd(t) and εHf(t) values. The A1-type granite was formed by the melting of the mafic crust. The A2-type granite was derived from partial melting of tonalite gneiss from the NCC crust and mantle materials. The EDW, LSC, WH and GHST granites mainly originated from partially melted granulite, with some mantle input. The YBS dykes are formed by the magma mixing of hot mantle melt and the relatively cold crustal magma. The northern margin of the NCC experienced anorogenic and collision tectonic stages, and the structural setting started to transform to post-collision at the later period of early Permian. Full article
(This article belongs to the Section Mineral Deposits)
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20 pages, 7480 KiB  
Article
Application of Ultraviolet Laser Working in Cold Ablation Conditions for Cutting Labels Used in Packaging in the Food Industry
by Łukasz Bohdal, Leon Kukiełka, Radosław Patyk, Rafał Gryglicki and Piotr Kasprzak
Materials 2020, 13(22), 5245; https://doi.org/10.3390/ma13225245 - 20 Nov 2020
Cited by 2 | Viewed by 2447
Abstract
This work presents experimental studies aiming at the development of new technology and guidelines for shaping labels from polypropylene multilayer foil using an ultraviolet (UV) laser cutting operation. Currently on production lines, the shaping of labels is undertaken by mechanical cutting or laser [...] Read more.
This work presents experimental studies aiming at the development of new technology and guidelines for shaping labels from polypropylene multilayer foil using an ultraviolet (UV) laser cutting operation. Currently on production lines, the shaping of labels is undertaken by mechanical cutting or laser cutting, taking into account the phenomenon of hot ablation. These technologies cause many problems such as burr formation on labels sheared edges, rapid tool wear, or heat-affected zone (HAZ) formation. The experimental tests were carried out on a specially designed laser system for cutting polypropylene foil using the phenomenon of cold ablation. Parametric analyses were conducted for several foil thicknesses t = 50, 60, 70 and 80 µm. The process parameters were optimized in terms of high efficiency and high labels-cut surface quality. A new criterion has been developed for assessing the quality of UV laser cutting of polypropylene foils. The results indicate a significant effect of the cutting speed and laser frequency on the width of the degraded zone on the sheet cut edge. As a result of a developed optimization task and reverse task solution it is possible to cut labels at high speeds (v = 1.5 m/s) while maintaining a high quality of cut edge free of carbon, delamination and color changes. A degraded zone does not exceed in the examined cases s ≤ 0.17 mm. Full article
(This article belongs to the Special Issue Trends and Prospects in Surface Engineering)
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11 pages, 4326 KiB  
Article
Droplet Impact on the Cold Elastic Superhydrophobic Membrane with Low Ice Adhesion
by Chenlu Qian, Qiang Li and Xuemei Chen
Coatings 2020, 10(10), 964; https://doi.org/10.3390/coatings10100964 - 9 Oct 2020
Cited by 13 | Viewed by 3210
Abstract
The elastic membranes with different surface stiffness were fabricated via spin-coating followed by the laser ablation. The as-fabricated elastic membrane exhibited superhydrophobicity with a rough microstructure. The droplet impacting experiment on the cold elastic superhydrophobic membrane was conducted, and the influence of surface [...] Read more.
The elastic membranes with different surface stiffness were fabricated via spin-coating followed by the laser ablation. The as-fabricated elastic membrane exhibited superhydrophobicity with a rough microstructure. The droplet impacting experiment on the cold elastic superhydrophobic membrane was conducted, and the influence of surface stiffness and impacting speed on the droplet impacting process were investigated. It was found that the elastic superhydrophobic membrane exhibits a robust anti-icing performance compared with the elastic hydrophobic membrane. A lower surface stiffness corresponds to a larger deformation degree of the elastic membrane and to a smaller maximum droplet spreading diameter. Moreover, the contact time decreases with the increase of impacting speed as for the same stiffness of the cold elastic superhydrophobic membrane. The underlying mechanism of the cold elastic membrane with low ice adhesion may be due to the face that the deformation of the superhydrophobic membrane provides an elastic force for the droplet to detach from the surface and thus reduce the heat transfer between the droplet and the surface. Full article
(This article belongs to the Special Issue Low Ice Adhesion Coatings)
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15 pages, 2384 KiB  
Article
Characterization of Carbonate Crust from a Recently Discovered Methane Seep on the North Atlantic Continental Margin of the USA
by Rinat Gabitov, Chiara Borrelli, Jacob Buettner, Brenda Kirkland, Adam Skarke, Dustin Trail, Brittany Garner, Maurice Testa, Mahnaz Wahidi, Christopher Hoff, Salavat Khasanov, Giuliana Panieri, Roobanvenkatesh Thirumalai, Jay Thomas, Jeremy Weremeichik and Irina Zverkova
Minerals 2019, 9(3), 138; https://doi.org/10.3390/min9030138 - 26 Feb 2019
Cited by 4 | Viewed by 5546
Abstract
This study is focused on mineralogical and chemical characterization of an authigenic carbonate rock (crust) collected at a recently discovered cold seep on the US North Atlantic continental margin. X-ray diffraction (XRD) and scanning electron microscopy (SEM) indicate that the carbonate rock is [...] Read more.
This study is focused on mineralogical and chemical characterization of an authigenic carbonate rock (crust) collected at a recently discovered cold seep on the US North Atlantic continental margin. X-ray diffraction (XRD) and scanning electron microscopy (SEM) indicate that the carbonate rock is composed of microcrystalline aragonite cement, white acicular aragonite crystals (AcAr), equant quartz crystals, small microcrystalline aluminosilicates, and trace amounts of iron sulfide microcrystals. Element/calcium ratios were measured with laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) using a calcite standard, which was prepared by annealing USGS certified carbonate powder (MACS-3). The occurrence of microscopic, non-carbonate inclusions precluded evaluation of trace elements in the aragonite cement, but allowed for in situ analysis of AcAr crystals. Carbon and oxygen isotopes were analyzed via isotope ratio mass spectrometry (IRMS) and expressed as δ13C and δ18O. Low δ13C values suggest that aragonite grew as a result of anaerobic oxidation of methane and observed δ18O values indicate that the temperature of aragonite crystallization was 1.7–1.9 °C. Full article
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