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Keywords = karstic critical zone

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15 pages, 3197 KiB  
Article
Experimental and Numerical Investigation of Seepage and Seismic Dynamics Behavior of Zoned Earth Dams with Subsurface Cavities
by Iman Hani Hameed, Abdul Hassan K. Al-Shukur and Hassnen Mosa Jafer
GeoHazards 2025, 6(3), 37; https://doi.org/10.3390/geohazards6030037 - 17 Jul 2025
Viewed by 316
Abstract
Earth fill dams are susceptible to internal erosion and instability when founded over cavity-prone formations such as gypsum or karstic limestone. Subsurface voids can significantly compromise dam performance, particularly under seismic loading, by altering seepage paths, raising pore pressures, and inducing structural deformation. [...] Read more.
Earth fill dams are susceptible to internal erosion and instability when founded over cavity-prone formations such as gypsum or karstic limestone. Subsurface voids can significantly compromise dam performance, particularly under seismic loading, by altering seepage paths, raising pore pressures, and inducing structural deformation. This study examines the influence of cavity presence, location, shape, and size on the behavior of zoned earth dams. A 1:25 scale physical model was tested on a uniaxial shake table under varying seismic intensities, and seepage behavior was observed under steady-state conditions. Numerical simulations using SEEP/W and QUAKE/W in GeoStudio complemented the experimental work. Results revealed that upstream and double-cavity configurations caused the greatest deformation, including crest displacements of up to 0.030 m and upstream subsidence of ~7 cm under 0.47 g shaking. Pore pressures increased markedly near cavities, with peaks exceeding 2.7 kPa. Irregularly shaped and larger cavities further amplified these effects and led to dynamic factors of safety falling below 0.6. In contrast, downstream cavities produced minimal impact. The excellent agreement between experimental and numerical results validates the modeling approach. Overall, the findings highlight that cavity geometry and location are critical determinants of dam safety under both static and seismic conditions. Full article
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16 pages, 4809 KiB  
Article
First-Arrival Tomography for Mountain Tunnel Hazard Assessment Using Unmanned Aerial Vehicle Seismic Source and Enhanced by Supervirtual Interferometry
by Jun Zhang, Rongyi Qian, Zhenning Ma, Xiaoqiong Lei, Jianyu Ling, Xu Liu and Guibin Zhang
Remote Sens. 2025, 17(10), 1686; https://doi.org/10.3390/rs17101686 - 11 May 2025
Viewed by 463
Abstract
Preliminary tunnel surveys are essential for identifying geological hazards such as aquifers, faults, and karstic zones. While first-arrival tomography is effective for imaging shallow anomalies, traditional seismic sources face significant limitations in forested mountainous regions due to mobility, cost, and environmental impact. To [...] Read more.
Preliminary tunnel surveys are essential for identifying geological hazards such as aquifers, faults, and karstic zones. While first-arrival tomography is effective for imaging shallow anomalies, traditional seismic sources face significant limitations in forested mountainous regions due to mobility, cost, and environmental impact. To address this, we deployed a seismic source delivered by an unmanned aerial vehicle (UAV) for a highway tunnel survey in Lijiang, China. The UAV system, paired with nodal geophones, enabled rapid, low-impact, and high-resolution data acquisition in rugged terrain. To enhance the weak far-offset refractions affected by near-surface attenuation, we applied supervirtual refraction interferometry (SVI), which significantly improved the signal-to-noise ratio and expanded the usable first-arrival dataset. The combined use of UAV excitation and SVI processing produced a high-precision P-wave velocity model through traveltime tomography, aligned well with borehole data. This model revealed the spatial distribution of weathered zones and bedrock interfaces, and allowed us to infer potential fracture zones. The results offer critical guidance for tunnel alignment and hazard mitigation in complex geological settings. Full article
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21 pages, 14647 KiB  
Article
Modeling Monthly Nitrate Concentration in a Karst Spring with and without Discrete Conduit Flow
by Yuan Gao, Zexuan Xu, Shen Li and Wenjie Yu
Water 2022, 14(10), 1622; https://doi.org/10.3390/w14101622 - 18 May 2022
Cited by 3 | Viewed by 1952
Abstract
Understanding the coupled continuum pipe-flow framework for modeling contaminant transport in karst systems is critical for protecting water resources therein. This study simulated point and non-point source nitrate concentration in a karst spring and investigated the results generated from the flow and transport [...] Read more.
Understanding the coupled continuum pipe-flow framework for modeling contaminant transport in karst systems is critical for protecting water resources therein. This study simulated point and non-point source nitrate concentration in a karst spring and investigated the results generated from the flow and transport model with and without discrete conduit flow. CFPv2 and CMT3D models were integrated to address the changes in nitrate concentration at a monthly scale in a karst spring, and the results were compared with that from an equivalent porous media (EPM) model with high-hydraulic conductivity (K) zones set in the main karstified area to represent conduits. The results show that the CFPv2+CMT3D model is able to describe well the recession of nitrate concentration in spring discharge, and the relatively larger deviation (slower nitrate recession) from the observed trend for the EPM model is probably a result of the limitation of utilizing high hydraulic conductivity cells to represent conduit. Moreover, simulated hydraulic heads in poorly karstified areas from the two models both show slight differences from the observations (the head RMSE values of calibration/validation for CFPv2 and MODFLOW models are 0.16 m/0.25 m and 0.26 m/0.17 m, respectively), indicating the inclusion of conduits may not affect the simulation considerably, and the lower the proportion of karstic area, the slight effects brought from the inclusion of conduits in the model. For highly karstified areas, the CFPv2+CMT3D model could provide more accurate results (head RMSE of calibration/validation for CFPv2 and MODFLOW are 0.22 m/0.06 and 0.52 m/0.47 m, respectively), showing the coupled continuum pipe-flow framework may be more appropriate for applying to highly and maturely karstified areas where the variations in the behavior of flow and contaminant transport are more affected by turbulent flow regime. Full article
(This article belongs to the Section Hydrogeology)
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12 pages, 4060 KiB  
Article
Geospatial Applications of Cave Resource Data to Better Understand Epikarst and Unsaturated Zone Groundwater Flow Path Development
by Sierra M. Heimel and Benjamin W. Tobin
Geosciences 2022, 12(2), 47; https://doi.org/10.3390/geosciences12020047 - 18 Jan 2022
Cited by 4 | Viewed by 4035
Abstract
The unsaturated zone is a critical component of karstic groundwater systems and is shown to provide substantial storage capacities. Understanding the spatial patterns and controls on flow path activation is often a challenge. Previous research focused on remotely sensed data or inferential analyses [...] Read more.
The unsaturated zone is a critical component of karstic groundwater systems and is shown to provide substantial storage capacities. Understanding the spatial patterns and controls on flow path activation is often a challenge. Previous research focused on remotely sensed data or inferential analyses to quantify these patterns. Here, we use two cave systems—one in Arizona, USA and a second in Kentucky, USA—to show the value of the cave survey and inventory data in the direct observation of speleogenesis and unsaturated zone processes. Using geospatial statistical analyses, we show that passage size varies with distance from some faults, indicating that these faults play a major role in transporting fluid into the limestone and creating increased permeability in the form of cave passages. Additionally, the close relationship between water, calcite resources and geology provide clear evidence for the activation of unsaturated zone flow paths through these cave systems. While both cave systems represent a large area of greatly increased permeability, only isolated sections of the caves show evidence of this active flow. In both cases, modern vadose zone flow occurs proximal to faults and contacts with overlying insoluble lithology. These results suggest that an expanded use of cave survey and inventory data may provide a greater insight into unsaturated zone processes. Full article
(This article belongs to the Special Issue Karst Unsaturated Zone)
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25 pages, 13575 KiB  
Article
Stream Hydrochemical Response to Flood Events in a Multi-Lithological Karstic Catchment from the Pyrenees Mountains (SW France)
by Francesco Ulloa-Cedamanos, Anne Probst, Vanessa Dos-Santos, Thierry Camboulive, Franck Granouillac and Jean-Luc Probst
Water 2021, 13(13), 1818; https://doi.org/10.3390/w13131818 - 30 Jun 2021
Cited by 10 | Viewed by 5562
Abstract
Hydrological variations hold a significant influence over the water chemistry in the karstic critical zone. In this context, the karstic Baget Catchment (BC) has been monitored at a high resolution over two years at the outlet in order to set up a typology [...] Read more.
Hydrological variations hold a significant influence over the water chemistry in the karstic critical zone. In this context, the karstic Baget Catchment (BC) has been monitored at a high resolution over two years at the outlet in order to set up a typology of the flood events. The objective was to assess the multiple streamwater physico-chemical patterns in response to hydrological variations, streamflow component (quick-response, subsurface, and baseflow) and lithological contributions, and biogeochemical processes. The karstic catchment exhibited an impulsive response to flood events in relation to the typical structural and morphological characteristics of the karst. In addition, this response was constrained by the magnitude of the rainfall and the preceding hydroclimatic conditions. The variability of the dissolved load in streamflow was closely associated with the characteristics of the weathered rocks and the hydrological conditions throughout the year. Two simple indicators allow to characterize the concentration–discharge relationships with different hysteresis patterns on a set of floods with various intensities and shapes of the hydrograph and under different hydrological conditions before the flood. Almost all elements exhibited either clockwise loops or more complex behaviors, suggesting a higher overall concentration when the major water contribution comes from the quick-response flow (karst and surface runoff fraction). Besides, the epikarst flushing under dry conditions led counterclockwise hysteresis patterns for calcium (Ca2+) and bicarbonate (HCO3) which revealed an overall chemostatic behavior as a result of carbonate dissolution in the karst. On the contrary, sulfate (SO42−) exhibited the widest relative variation during flooding and showed a significant sensitivity to the dilution process with increasing discharge. For medium flood episodes (Qmax < 4.4 m3·s−1), an overall concentration increase or chemostatic behavior could be observed during the rising limb of the hydrograph. On the opposite, under extreme flood episodes (Qmax > 8.3 m3·s−1) occurring after several rain events, a dilution pattern was noted for all elements originating from rock weathering. Finally, high-frequency sampling during storm events improved the understanding of the factors controlling the hydrochemical dynamic in karstic catchments. Full article
(This article belongs to the Special Issue Water and the Ecosphere in the Anthropocene)
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24 pages, 11291 KiB  
Article
Hydrogeochemical and Hydrodynamic Assessment of Tirnavos Basin, Central Greece
by Ioannis Vrouhakis, Evangelos Tziritis, Andreas Panagopoulos and Georgios Stamatis
Water 2021, 13(6), 759; https://doi.org/10.3390/w13060759 - 11 Mar 2021
Cited by 5 | Viewed by 3875
Abstract
A combined hydrogeochemical and hydrodynamic characterization for the assessment of key aspects related to groundwater resources management was performed in a highly productive agricultural basin of the Thessaly region in central Greece. A complementary suite of tools and methods—including graphical processing, hydrogeochemical modeling, [...] Read more.
A combined hydrogeochemical and hydrodynamic characterization for the assessment of key aspects related to groundwater resources management was performed in a highly productive agricultural basin of the Thessaly region in central Greece. A complementary suite of tools and methods—including graphical processing, hydrogeochemical modeling, multivariate statistics and environmental isotopes—have been applied to a comprehensive dataset of physicochemical analyses and water level measurements. Results revealed that the initial hydrogeochemistry of groundwater was progressively impacted by secondary phenomena (e.g., ion exchange and redox reactions) which were clearly delineated into distinct zones according to data processing. The progressive evolution of groundwater was further verified by the variation of the saturation indices of critical minerals. In addition, the combined use of water level measurements delineated the major pathways of groundwater flow. Interestingly, the additional joint assessment of environmental isotopes revealed a new pathway from E–NE (which had never before been validated), thus highlighting the importance of the joint tools/methods application in complex scientific tasks. The application of multivariate statistics identified the dominant processes that control hydrogeochemistry and fit well with identified hydrodynamic mechanisms. These included (as dominant factor) the salinization impact due to the combined use of irrigation water return and evaporitic mineral leaching, as well as the impact of the geogenic calcareous substrate (mainly karstic calcareous formations and dolostones). Secondary factors, acting as processes (e.g., redox and ion exchange), were identified and found to be in line with initial assessment, thus validating the overall characterization. Finally, the outcomes may prove to be valuable in the progression toward sustainable groundwater resources management. The results have provided spatial and temporal information for significant parameters, sources, and processes—which, as a methodological approach, could be adopted in similar cases of other catchments. Full article
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11 pages, 3036 KiB  
Proceeding Paper
What Can Be Learned about the Relationships between Water Discharge and Composition during Flood Events in a Forested Karstic Catchment from the Pyrenees Mountains (Southwestern France)?
by Francesco Ulloa-Cedamanos, Anne Probst, Vanessa Dos-Santos and Jean-Luc Probst
Environ. Sci. Proc. 2021, 7(1), 9; https://doi.org/10.3390/ECWS-5-08058 - 13 Nov 2020
Viewed by 1101
Abstract
Hydrological variations hold a significant influence over the water chemistry in the karst systems within the critical zone. In this context, the Baget Catchment (BC) was monitored at high-resolution over 2 hydrological years. The high-frequency survey at the outlet of BC displayed multiple [...] Read more.
Hydrological variations hold a significant influence over the water chemistry in the karst systems within the critical zone. In this context, the Baget Catchment (BC) was monitored at high-resolution over 2 hydrological years. The high-frequency survey at the outlet of BC displayed multiple hydrochemical patterns in response to hydrological variations, mixing water sources, and biogeochemical processes. Among the major elements, sulfate exhibited the widest relative variation during flooding and showed a significant dilution, whereas calcium and bicarbonate revealed a chemostatic behavior as a result of carbonate dissolution in the karst. Hysteretic analysis evidenced the control of different hydrological reservoirs over the stream transport processes of dissolved elements. The concentration of dissolved organic carbon increased during the hydrograph rising limb and was controlled by surface runoff. The relationships between Ca2+ and HCO3 concentrations and stream discharge exhibited hysteresis patterns with counterclockwise loops, unlike all other elements, due to the carbonate weathering by biogenic CO2-rich water. Finally, high-frequency sampling during storm events improved the understanding of the factors controlling the hydrochemical dynamic of the Baget stream water. The relative contributions of the karst and epikarst zones, of rainwater, as well as the role of different biogeochemical processes and the hydrological conditions were highlighted. Full article
(This article belongs to the Proceedings of 5th International Electronic Conference on Water Sciences)
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26 pages, 4023 KiB  
Article
A Multi-Disciplinary Approach to Understand Hydrologic and Geochemical Processes at Koiliaris Critical Zone Observatory
by Maria A. Lilli, Dionissis Efstathiou, Daniel Moraetis, Jonathan Schuite, Sofia D. Nerantzaki and Nikolaos P. Nikolaidis
Water 2020, 12(9), 2474; https://doi.org/10.3390/w12092474 - 3 Sep 2020
Cited by 9 | Viewed by 4964
Abstract
Koiliaris CZO is a European Critical Zone Observatory (CZO) typical of the Mediterranean karstic geomorphology, which represents watersheds affected by humans over the centuries. This study aims to provide information that underpins the hydrologic and geochemical processes functioning at Koiliaris CZO. Linking geomorphologic [...] Read more.
Koiliaris CZO is a European Critical Zone Observatory (CZO) typical of the Mediterranean karstic geomorphology, which represents watersheds affected by humans over the centuries. This study aims to provide information that underpins the hydrologic and geochemical processes functioning at Koiliaris CZO. Linking geomorphologic and tectonic analysis improved the delineation of a karstic area which extends outside of the Koiliaris watershed and identified how structural elements influence the regional hydrology. The fluctuation in the river flow represents processes occurring in the karst and the periodic signal is related to Earth tide stressing of the karstic reservoirs. The conceptualization of a two-reservoir, well-mixed karstic system is confirmed by both the geomorphologic and tidal analysis. The hydrologic response is fast and it is manifested especially during extreme events where 70% of the precipitation becomes surface runoff, creating major flood events. The different sampling sites in the Koiliaris CZO were geochemically clustered and the quantification of the weathering fluxes showed that 25 mm/1000 years and 39 mm/1000 years of carbonate were removed by chemical weathering for the Keramianos ephemeral river and the springs, respectively. These studies illustrate the importance of critical zone science and transdisciplinary studies on water and soil management. Full article
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29 pages, 4006 KiB  
Article
A Forty-Year Karstic Critical Zone Survey (Baget Catchment, Pyrenees-France): Lithologic and Hydroclimatic Controls on Seasonal and Inter-Annual Variations of Stream Water Chemical Composition, pCO2, and Carbonate Equilibrium
by Francesco Ulloa-Cedamanos, Jean-Luc Probst, Stephane Binet, Thierry Camboulive, Virginie Payre-Suc, Corinne Pautot, Michel Bakalowicz, Sandra Beranger and Anne Probst
Water 2020, 12(5), 1227; https://doi.org/10.3390/w12051227 - 25 Apr 2020
Cited by 21 | Viewed by 6243
Abstract
The long-term trends and seasonal patterns of stream water chemical composition in a small remote forested karst catchment, were investigated from 1978 to 2018. Calcium, magnesium, and bicarbonates, the dominant ions, increased over the period together with temperature, while sulfates decreased. Carbonate and [...] Read more.
The long-term trends and seasonal patterns of stream water chemical composition in a small remote forested karst catchment, were investigated from 1978 to 2018. Calcium, magnesium, and bicarbonates, the dominant ions, increased over the period together with temperature, while sulfates decreased. Carbonate and sulfate mineral dissolution was the main source of these elements. These trends and the seasonal opposite patterns of discharge vs. temperature, calcite saturation index vs. pCO2 and bicarbonate vs. sulfates, suggested the influence of discharge, of reduced long-range atmospheric pollution, and of increasing air temperature on biological activity and carbonate dissolution. Furthermore, the hydrological regime controlled the seasonal stream water chemical composition and fluxes by: (i) a dilution during the high discharge period, (ii) a change in the contribution rate of the waters draining different lithological areas in the catchment, e.g., the increased sulfates to bicarbonates ratio during summer low flows, with a maximum alkalinity decrease of 24%, and (iii) a “piston” and a “flushing” effects of dissolved elements stored in soils and epikarst with the first autumn heavy rains. Long-term stream water hydrochemical surveys of karst system have proved to be powerful indicators of biogeochemical processes, water sources and pathways under variable natural and anthropogenic environmental pressure conditions. Full article
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