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6 pages, 706 KB  
Proceeding Paper
AI-Driven Predictive Analytics for Kapok Supply Chain Governance
by Nila Firdausi Nuzula and Sopyan
Eng. Proc. 2026, 128(1), 24; https://doi.org/10.3390/engproc2026128024 - 12 Mar 2026
Viewed by 356
Abstract
The kapok (Ceiba pentandra) fiber industry plays a vital role in Indonesia’s rural bioeconomy, particularly in regions with high production intensity such as Pasuruan Regency. Despite its economic potential and alignment with the green economy agenda, the industry faces increasing volatility [...] Read more.
The kapok (Ceiba pentandra) fiber industry plays a vital role in Indonesia’s rural bioeconomy, particularly in regions with high production intensity such as Pasuruan Regency. Despite its economic potential and alignment with the green economy agenda, the industry faces increasing volatility due to seasonal harvest cycles, climate-induced disruptions, global demand fluctuations, and exchange rate instability. These conditions necessitate an adaptive and predictive approach to supply chain risk governance. We evaluated the performances of predictive analytics models, including linear regression, random forest, gradient boosting, XGBoost 3.2.0 libraries, K-nearest neighbors, and stacking regressor. Using multi-year monthly data on production volume, residual stock, and exchange rates, the stacking regressor was the most accurate model, achieving the lowest root mean square error and highest R2 values. The results bridge the gap by applying predictive analytics to a resource-based, seasonal small industry sector. Practically, the results also enable leveraging AI in strengthening the long-term sustainability of agribusiness supply chains. Full article
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22 pages, 3776 KB  
Article
Nutritional Profiles of Plants Consumed by Military Macaw During the Breeding and Non-Breeding Seasons in the Alto Balsas Basin, Mexico
by Valeria López-Hernández, Leopoldo D. Vázquez-Reyes, Ana María Contreras-González, Victor H. Jiménez-Arcos, Jorge Tanit Rodríguez-Malacara, Megan P. Trejo-Boyso, Taisha Lara-Moreno, Jose Alfredo Rodriguez, Cesar Mateo Flores-Ortiz and Francisco Alberto Rivera-Ortiz
Birds 2026, 7(1), 2; https://doi.org/10.3390/birds7010002 - 25 Dec 2025
Viewed by 2163
Abstract
The Military Macaw is a Neotropical psittacid that is endangered in Mexico. It faces significant threats due to habitat loss and the illegal pet trade. However, little is known about the nutritional characteristics of the plant resources available to this species throughout its [...] Read more.
The Military Macaw is a Neotropical psittacid that is endangered in Mexico. It faces significant threats due to habitat loss and the illegal pet trade. However, little is known about the nutritional characteristics of the plant resources available to this species throughout its annual cycle. This study aimed to characterize the nutritional profile of the fruits consumed by macaws in the Alto Balsas Basin, Mexico, and to infer potential seasonal patterns in the availability of the fruits they feed on in relation to the Macaws’ reproductive phenology. We identified 13 plant species that have been consistently reported as components of the diet of the macaws within the Alto Balsas Basin using a literature review, field observations, and local interviews. We conducted bromatological analyses to assess the content of moisture, protein, lipids, carbohydrates, and fiber for the pulp and seeds of all 13 identified plant species. Although we did not measure quantitative food intake, we integrated these data with reproductive phenology and resource availability to infer potential patterns of nutritional use. The results revealed significant differences in nutritional content among the different species, as well as seasonal variation in the nutritional profiles of available resources that coincide with the physiological demands of the macaw life cycle. During the non-breeding season, the availability of species whose fruits have high lipid and carbohydrate contents, such as Bursera spp., hackberry and madras thorn, may provide essential energy. Conversely, during the breeding season, resources with higher lipid and protein content (such as Mexican kapok tree and red mombin) could support the increased energetic investment associated with courtship, egg production, and chick provisioning. Although our study did not directly quantify the amount of each food item consumed, the integration of nutritional and ecological data provides a preliminary view of how resource quality may influence seasonal foraging patterns, offering valuable insights for the conservation and management of this species. Full article
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14 pages, 2719 KB  
Article
In Situ Growth of Cross-Linked Ti2Nb10O29 Nanoparticles on Inner/Outer Surfaces of Carbon Microtubes for High-Efficiency Lithium Storage
by Zhi Nie, Hualin Xiong, Changlong Du, Lei Yu, Lianrui Li, Gengping Wan and Guizhen Wang
Batteries 2025, 11(12), 462; https://doi.org/10.3390/batteries11120462 - 16 Dec 2025
Viewed by 510
Abstract
Improving electronic and ionic transport and the structural stability of electrode materials is essential for the development of advanced lithium-ion batteries. Despite its great potential as a high-power anode, Ti2Nb10O29 (TNO) still underperforms due to its unsatisfactory electronic [...] Read more.
Improving electronic and ionic transport and the structural stability of electrode materials is essential for the development of advanced lithium-ion batteries. Despite its great potential as a high-power anode, Ti2Nb10O29 (TNO) still underperforms due to its unsatisfactory electronic and ionic conductivity. Here, a TNO/carbon microtube (TNO@CMT) composite is constructed via an ethanol-assisted solvothermal process and controlled annealing. The hollow carbon framework derived from kapok fibers provides a lightweight conductive skeleton and abundant nucleation sites for uniform TNO growth. By tuning precursor concentration, the interfacial structure and loading are precisely regulated, optimizing electron/ion transport. The optimized TNO@CMT-2 exhibits uniformly dispersed TNO nanoparticles anchored on both inner and outer CMT surfaces, enabling rapid electron transfer, short Li+ diffusion paths, and high structural stability. Consequently, it delivers a reversible capacity of 314.9 mAh g−1 at 0.5 C, retains 75.8% capacity after 1000 cycles at 10 C, and maintains 147.96 mAh g−1 at 40 C. Furthermore, the Li+ diffusion coefficient of TNO/CMT-2 is 5.4 × 10−11 cm2 s−1, which is nearly four times higher than that of pure TNO. This work presents a promising approach to designing multi-cation oxide/carbon heterostructures that synergistically enhance charge and ion transport, offering valuable insights for next-generation high-rate lithium-ion batteries. Full article
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13 pages, 2665 KB  
Article
Kapok-Derived Super Hollow Porous Carbon Fibers and Their Greenhouse Gases Adsorption
by Hun-Seung Jeong, Cheol-Ki Cho, Dong-Chul Chung, Kay-Hyeok An and Byung-Joo Kim
Fibers 2025, 13(7), 92; https://doi.org/10.3390/fib13070092 - 4 Jul 2025
Viewed by 1436
Abstract
Industrialization and modernization have significantly improved the quality of life but have also led to substantial pollution. Cost-effective technologies are urgently needed to mitigate emissions from major polluting sectors, such as the automotive and transport industries. In this study, we synthesized naturally derived, [...] Read more.
Industrialization and modernization have significantly improved the quality of life but have also led to substantial pollution. Cost-effective technologies are urgently needed to mitigate emissions from major polluting sectors, such as the automotive and transport industries. In this study, we synthesized naturally derived, kapok-based porous carbon fibers (KP-PCFs) with hollow structures. We investigated their adsorption/desorption behavior for the greenhouse gas n-butane following ASTM D5228 standards. Scanning electron microscopy and X-ray diffraction analyses were conducted to examine changes in fiber diameter and crystalline structure under different activation times. The micropore properties of KP-PCFs were characterized using Brunauer–Emmett–Teller, t-plot, and non-localized density functional theory models based on N2/77K adsorption isotherm data. The specific surface area and total pore volume ranged from 500 to 1100 m2/g and 0.24 to 0.60 cm3/g, respectively, while the micropore and mesopore volumes were 0.20–0.45 cm3/g and 0.04–0.15 cm3/g, respectively. With increasing activation time, the n-butane adsorption capacity improved from 62.2% to 73.5%, whereas retentivity (residual adsorbate) decreased from 6.0% to 1.3%. The adsorption/desorption rate was highly correlated with pore diameter: adsorption capacity was highest for diameters of 1.5–2.5 nm, while retentivity was greatest for diameters of 3.5–5.0 nm. Full article
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14 pages, 2237 KB  
Article
Comparative Analysis of Physicochemical and Biological Activities of Meads from Five Mekong Region Honeys Pre- and Post-Fermentation
by Sahutchai Inwongwan, Thanaporn Kitcharoen, Pitchayapak Wongsasuk, William Le Masurier, Chanon Saksunwiriya, Phuwasit Takioawong, Hataichanok Pandith, Sitthisak Intarasit, Nuttapol Noirungsee and Terd Disayathanoowat
Fermentation 2025, 11(4), 190; https://doi.org/10.3390/fermentation11040190 - 3 Apr 2025
Viewed by 2186
Abstract
This study examines the physicochemical and biological changes in meads produced from five honey types sourced from the Mekong region: Tree Marigold (Tithonia diversifolia, Myanmar), Coffee (Coffea canephora, Vietnam), Kapok (Ceiba pentandra, Cambodia), Rubber (Hevea brasiliensis [...] Read more.
This study examines the physicochemical and biological changes in meads produced from five honey types sourced from the Mekong region: Tree Marigold (Tithonia diversifolia, Myanmar), Coffee (Coffea canephora, Vietnam), Kapok (Ceiba pentandra, Cambodia), Rubber (Hevea brasiliensis, China), and Mixed Floral (Thailand). Honey musts were fermented with Saccharomyces cerevisiae at 25 °C for two weeks. After fermentation, meads exhibited lighter coloration, a stable pH (3.5–4.5), and varying bioactivities. All meads showed antimicrobial activity against Escherichia coli, while activity against Staphylococcus aureus and Klebsiella pneumoniae varied by honey source and depended on fermentation. Antioxidant activity ranged from 19.25 to 68.11% inhibition, and peaked in Tree Marigold honey after fermentation. Total phenolic and flavonoid contents fluctuated, with Mixed Floral mead showing the highest post-fermentation phenolic levels. The results of a sensory analysis ranked Tree Marigold mead the highest across taste, mouthfeel, aftertaste, and overall preference. These findings underscore the influence of honey origin and fermentation on the physicochemical, antimicrobial, and sensory properties of mead. Full article
(This article belongs to the Special Issue Safety and Quality in Fermented Beverages)
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25 pages, 21504 KB  
Article
Impacts of Plant Configuration on the Outdoor Wind Comfort of Subtropical Coastal Campuses: Evidence from a Study of Quanzhou
by Jing Chen, Jiushan Zeng, Tiantian Huang, Yaolong Wang, Haosen Yang, Xiaofang Yu and Zefa Wang
Forests 2025, 16(3), 461; https://doi.org/10.3390/f16030461 - 5 Mar 2025
Cited by 6 | Viewed by 1424
Abstract
Even though the interaction between plants and the outdoor wind environment has been a focus of interest for scholars from various disciplines in recent years, the relationship between campus outdoor wind comfort and plant configuration in subtropical coastal areas remains poorly understood. Using [...] Read more.
Even though the interaction between plants and the outdoor wind environment has been a focus of interest for scholars from various disciplines in recent years, the relationship between campus outdoor wind comfort and plant configuration in subtropical coastal areas remains poorly understood. Using the outdoor space of a typical subtropical coastal campus (the Donghai Campus of Quanzhou Normal University) as a case study, we explore the connection between plant configuration and outdoor wind comfort. The campus outdoor area is segmented into roads, squares, and courtyards to investigate this relationship. To achieve this goal, a 9-h fixed-point measurement method and the PHOENICS software (2016) were utilized. The following are the findings of the research: (1) Within the realm of trees, the banyan, Bischofia javanica, and kapok species exhibit a notable impact on wind speed reduction, with respective wind reduction ratios of 1.22, 1.31, and 1.29. Notably, among shrubs, waringin stands out with a wind reduction ratio of 1.83. (2) The tree + shrub + grass combination is the most effective method for reducing wind among the three plant facade configurations. Specifically, the combination of Bischofia javanica, waringin, and carpet grass has the best wind reduction effect, with a wind reduction ratio of 2.55. (3) Adding Bischofia javanica, waringin, and grass plants in areas with high wind speeds can effectively improve wind comfort. This provides directions for creating a comfortable wind environment on university campuses situated in subtropical coastal areas. Full article
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19 pages, 5621 KB  
Article
Modified Kapok Fibers (Ceiba pentandra (L.) Gaerth) for Oil Spill Remediation
by Leonardo M. T. M. Oliveira, Eduardo J. S. Fonseca, Vanderson B. Bernardo, Carmem L. P. S. Zanta, Laís F. A. M. Oliveira, Jennifer N. S. R. de Oliveira, Samuel T. de Souza and José Leandro da Silva Duarte
Appl. Sci. 2024, 14(24), 11995; https://doi.org/10.3390/app142411995 - 21 Dec 2024
Cited by 3 | Viewed by 4590
Abstract
The search for efficient oil spill remediation techniques leads to the use of physical, chemical, and biological methods, featuring both natural and modified lipophilic materials. Kapok fibers (Ceiba pentandra (L.) Gaerth) have been studied as a result of their unusual natural oil [...] Read more.
The search for efficient oil spill remediation techniques leads to the use of physical, chemical, and biological methods, featuring both natural and modified lipophilic materials. Kapok fibers (Ceiba pentandra (L.) Gaerth) have been studied as a result of their unusual natural oil sorption capacity, which can be improved even further through physical or chemical treatments that augment their rugosity and alter their functional properties. Furthermore, the exact role of fiber morphology is not completely clear regarding the sorption process. Hence, this study investigated the efficacy of kapok fibers using different treatments, based on chemical and physical approaches, and characterized using advanced techniques (FTIR, SEM, AFM), aiming to improve the understanding of application possibilities in oil contamination scenarios. The results indicate that treatments using a low thermal intensity and low concentration do not lead to variation in sorption properties nor in surface structural features. Fiber rugosity varied from 4.40 to 12.35 nm, whereas an excessive increase in roughness was observed when the material was subject to more extreme conditions, such as a temperature of 120 °C and high concentrations (2.0 M) of both acid or alkali, accompanied by a loss in functionality and affecting the material sorption capacity. Thus, the study provides conditions to suggest that these treatments are not necessary for this type of material when inserted into sorption processes. Full article
(This article belongs to the Special Issue New Approaches to Water Treatment: Challenges and Trends)
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15 pages, 5395 KB  
Article
Transcriptome and Expression Analysis of Glycerol Biosynthesis-Related Genes in Glenea cantor Fabricius (Cerambycidae: Lamiinae)
by Taihui Lan, Ranran Su, Zishu Dong, Xin Tong, Xialin Zheng and Xiaoyun Wang
Int. J. Mol. Sci. 2024, 25(21), 11834; https://doi.org/10.3390/ijms252111834 - 4 Nov 2024
Cited by 2 | Viewed by 1618
Abstract
Glenea cantor Fabricius (Cerambycidae: Lamiinae) is an important pest that damages kapok trees in Southeast Asia with a wide adaptability to temperature. Glycerol is a protectant and energy source for insects in low-temperature environments. However, glycerol biosynthesis-related genes at the molecular level are [...] Read more.
Glenea cantor Fabricius (Cerambycidae: Lamiinae) is an important pest that damages kapok trees in Southeast Asia with a wide adaptability to temperature. Glycerol is a protectant and energy source for insects in low-temperature environments. However, glycerol biosynthesis-related genes at the molecular level are limited in G. cantor. In this study, the supercooling points and freezing points at different stages were measured, and the cold hardiness of male and female pupae significantly differed. Moreover, a full-length transcriptome of G. cantor was established; glycerol kinase (GK) and glycerol-3-phosphate dehydrogenase (GPDH) genes, which are related to glycerol metabolism, were identified, with a special focus on their expression profiles. A total of 24,476 isoforms stemmed from the full-length transcriptome, along with 568 lncRNAs, 56 transcription factor (TF) families, and 1467 alternative splicing (AS) events. The KEGG pathway enrichment analysis revealed that the isoforms associated with AS were enriched primarily in glycerolipid and glycerophospholipid metabolism. In total, three GK genes and one GPDH gene were identified, and GcGK1 and GcGK3 presented differential sex expression during the pupal stage, which may play a role in thermal adaptability. This study provides a valuable transcriptional database of G. cantor and helps to elucidate the function of glycerol in the thermal adaptation mechanism of longhorn beetles. Full article
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15 pages, 4134 KB  
Article
BioTemplated Fe3+-Doped g-C3N4 Heterojunction Micromotors for the Degradation of Tetracycline through the Photo-Fenton Reaction
by Qingbao Gan, Jianwei Zhang, Jinglin Wang, Yuntian Wei, Shikun Chen, Shuguang Cai, Xueqing Xiao and Chan Zheng
Catalysts 2024, 14(9), 579; https://doi.org/10.3390/catal14090579 - 30 Aug 2024
Cited by 4 | Viewed by 2183
Abstract
The excessive discharge of antibiotics into aquatic systems is a major issue in many countries worldwide and poses a threat to human health and the sustainable development of society. Hence, developing efficient treatment methods and purification technologies to degrade antibiotics is essential. Herein, [...] Read more.
The excessive discharge of antibiotics into aquatic systems is a major issue in many countries worldwide and poses a threat to human health and the sustainable development of society. Hence, developing efficient treatment methods and purification technologies to degrade antibiotics is essential. Herein, we present the synthesis of low-cost, self-propelled tubular Fe3+-incorporated graphitic carbon nitride (g-C3N4-Fe@KF) micromotors using kapok fibers (KFs) as templates and their application as photo-catalysts for the photo-Fenton degradation of tetracycline (TC) under visible-light irradiation. The g-C3N4-Fe@KF micromotors moved rapidly when being propelled by oxygen bubbles generated in a hydrogen peroxide (H2O2) solution as a result of a photo-assisted Fenton reaction. The motion behavior of the g-C3N4-Fe@KF micromotors was dependent on the concentration of H2O2 and the length of the micromotors. The propulsion mechanism was discussed in detail. The micromotors efficiently degraded antibiotics via the photo-Fenton process. Photo-Fenton degradation efficiency was attributed to the synergistic effects of the doped Fe3+ and g-C3N4 under visible-light irradiation and self-propulsion of the micromotors. In addition, the micromotors possessed good reusability, thereby efficiently realizing multiple cycles of degradation. The current work offers an avenue for the design of micromotors, using inexpensive approaches, for various potential environmental applications. Full article
(This article belongs to the Section Catalytic Materials)
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12 pages, 9479 KB  
Article
An Efficient and Economic Approach for Producing Nanocellulose-Based Aerogel from Kapok Fiber
by Minjie Hou, Qi Wang, Shunyu Wang, Zeze Yang, Xuefeng Deng and Hailong Zhao
Gels 2024, 10(8), 490; https://doi.org/10.3390/gels10080490 - 25 Jul 2024
Cited by 6 | Viewed by 2580
Abstract
Cellulose nanofibers (NF) were extracted from kapok fibers using TEMPO oxidation, followed by a combination of mechanical grinding and ultrasonic processing. The TEMPO-mediated oxidation significantly impacted the mechanical disintegration behavior of the kapok fibers, resulting in a high NF yield of 98%. This [...] Read more.
Cellulose nanofibers (NF) were extracted from kapok fibers using TEMPO oxidation, followed by a combination of mechanical grinding and ultrasonic processing. The TEMPO-mediated oxidation significantly impacted the mechanical disintegration behavior of the kapok fibers, resulting in a high NF yield of 98%. This strategy not only improved the fibrillation efficiency but also reduced overall energy consumption during NF preparation. An ultralight and highly porous NF-based aerogel was successfully prepared using a simple ice-templating technique. It had a low density in the range of 3.5–11.2 mg cm−3, high compressional strength (160 kPa), and excellent thermal insulation performance (0.024 W m−1 K−1). After silane modification, the aerogel displayed an ultralow density of 7.9 mg cm−3, good hydrophobicity with a water contact angle of 128°, and excellent mechanical compressibility with a high recovery of 92% at 50% strain. Benefiting from the silene support structure, it showed a high oil absorptive capacity (up to 71.4 g/g for vacuum pump oil) and a remarkable oil recovery efficiency of 93% after being reused for 10 cycles. These results demonstrate that our strategy endows nanocellulose-based aerogels with rapid shape recovery and high liquid absorption capabilities. Full article
(This article belongs to the Special Issue Preparation and Characteristics of Aerogel-Based Materials)
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14 pages, 3814 KB  
Article
Utilization of Waste Natural Fibers Mixed with Polylactic Acid (PLA) Bicomponent Fiber: Incorporating Kapok and Cattail Fibers for Nonwoven Medical Textile Applications
by Tanyalak Srisuk, Khanittha Charoenlarp and Piyaporn Kampeerapappun
Polymers 2024, 16(1), 76; https://doi.org/10.3390/polym16010076 - 26 Dec 2023
Cited by 10 | Viewed by 4030
Abstract
Disposable surgical gowns are usually made from petroleum-based synthetic fibers that do not naturally decompose, impacting the environment. A promising approach to diminish the environmental impact of disposable gowns involves utilizing natural fibers and/or bio-based synthetic fibers. In this study, composite webs from [...] Read more.
Disposable surgical gowns are usually made from petroleum-based synthetic fibers that do not naturally decompose, impacting the environment. A promising approach to diminish the environmental impact of disposable gowns involves utilizing natural fibers and/or bio-based synthetic fibers. In this study, composite webs from polylactic acid (PLA) bicomponent fiber and natural fibers, cattail and kapok fibers, were prepared using the hot press method. Only the sheath region of the PLA bicomponent fiber melted, acting as an adhesive that enhanced the strength and reduced the thickness of the composite web compared with its state before hot pressing. The mechanical and physical properties of these composite webs were evaluated. Composite webs created from kapok fibers displayed a creamy yellowish-white color, while those made from cattail fibers showed a light yellowish-brown color. Additionally, the addition of natural fibers endowed the composite webs with hydrophobic properties. The maximum natural fiber content, at a ratio of 30:70 (natural fiber to PLA fiber), can be incorporated while maintaining proper water vapor permeability and mechanical properties. This nonwoven material presents an alternative with the potential to replace petroleum-based surgical gowns. Full article
(This article belongs to the Special Issue Polymer Composites in Waste Recycling)
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25 pages, 33182 KB  
Article
Sacred Pathway, Devotional Praxis: Actors, Aché, and Landscape at the Sanctuary of Regla, Cuba
by Paul Barrett Niell
Religions 2023, 14(12), 1545; https://doi.org/10.3390/rel14121545 - 15 Dec 2023
Viewed by 3542
Abstract
The ferry from Havana to Regla, Cuba, transports visitors from today’s cruise ship docks across a brief stretch of water in about 20 min. Despite its brevity, this watery passage symbolically foregrounds the Marian devotion on the southern rim of the grand harbor. [...] Read more.
The ferry from Havana to Regla, Cuba, transports visitors from today’s cruise ship docks across a brief stretch of water in about 20 min. Despite its brevity, this watery passage symbolically foregrounds the Marian devotion on the southern rim of the grand harbor. In this way, water conjoins African diasporic histories of enslavement, labor, survival, resistance, daily life, and religiosity within Havana Bay, into which two urban geographies project. Regla historically served as a municipality for dockworkers and shipwrights and became an enclave for identity creation, civil association, and religious worship for people of African descent. The church and sanctuary of Nuestra Señora de Regla (“Our Lady of Regla”) has nurtured this connection as it houses effigies of the venerated Virgin, adorned in blue. The Virgin of Regla represents one of two, along with El Cobre, of the most important Marian devotions on the island of Cuba and is the focus of insular and diasporic pilgrimage. In Regla, the Virgin’s nautical iconography decorates the sanctuary and historically connects her to the working populations who sustained this devotion as they serviced Havana Harbor with their labor. Adjacent to the church is a waterfront park that looks out on the water and the city of Havana beyond. Bordered on one side by a low wall, the park incorporates a large ceiba tree, ceiba pentandra, also known as the silk cotton or kapok tree, a tropical species with a large trunk and spreading tree canopy native to Mexico and Central America, the Caribbean, northern South America, and West Africa (with a similar variety found in South and Southeast Asia). This article considers landscape as a methodology for examining the interplay of this tree and the adjacent church as interwoven and mutually reinforcing sites of devotion for the worship of the Virgin Mary and the oricha Yemayá in Regla, Cuba, with a view toward a broader set of local and global spaces. Full article
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15 pages, 4705 KB  
Article
Oil Adsorption Kinetics of Calcium Stearate-Coated Kapok Fibers
by Aimee Lorraine M. Blaquera, Marvin U. Herrera, Ronniel D. Manalo, Monet Concepcion Maguyon-Detras, Cybelle Concepcion M. Futalan and Mary Donnabelle L. Balela
Polymers 2023, 15(2), 452; https://doi.org/10.3390/polym15020452 - 15 Jan 2023
Cited by 20 | Viewed by 6239
Abstract
This study used a simple and efficient dipping method to prepare oleophilic calcium stearate-coated kapok fibers (CaSt2-KF) with improved hydrophobicity. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) confirmed the deposition of calcium stearate particles on [...] Read more.
This study used a simple and efficient dipping method to prepare oleophilic calcium stearate-coated kapok fibers (CaSt2-KF) with improved hydrophobicity. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) confirmed the deposition of calcium stearate particles on the surface of the kapok fibers. This led to higher surface roughness and improved static water contact angle of 137.4°. The calcium stearate-coated kapok fibers exhibited comparable sorption capacities for kerosene, diesel, and palm oil. However, the highest sorption capacity of 59.69 g/g was observed for motor oil at static conditions. For motor oil in water, the coated fibers exhibited fast initial sorption and a 65% removal efficiency after 30 s. At equilibrium, CaSt2-KF attained a sorption capacity of 33.9 g/g and 92.5% removal efficiency for motor oil in water. The sorption kinetics of pure motor oil and motor oil in water follows the pseudo-second-order kinetic model, and the Elovich model further described chemisorption. Intraparticle diffusion and liquid film diffusion were both present, with the latter being the predominant diffusion mechanism during motor oil sorption. Full article
(This article belongs to the Special Issue Functional Nano/Microfiber Based Polymer Materials)
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13 pages, 5788 KB  
Article
Preparation and Mechanism of Toughened and Flame-Retardant Bio-Based Polylactic Acid Composites
by Kai Xu, Chentao Yan, Chunlin Du, Yue Xu, Bin Li and Lubin Liu
Polymers 2023, 15(2), 300; https://doi.org/10.3390/polym15020300 - 6 Jan 2023
Cited by 14 | Viewed by 3489
Abstract
As a biodegradable thermoplastic, polylactic acid (PLA) shows great potential to replace petroleum-based plastics. Nevertheless, the flammability and brittleness of PLA seriously limits its use in emerging applications. This work is focused on simultaneously improving the flame-retardancy and toughness of PLA at a [...] Read more.
As a biodegradable thermoplastic, polylactic acid (PLA) shows great potential to replace petroleum-based plastics. Nevertheless, the flammability and brittleness of PLA seriously limits its use in emerging applications. This work is focused on simultaneously improving the flame-retardancy and toughness of PLA at a low additive load via a simple strategy. The PLA/MKF/NTPA biocomposites were prepared by incorporating alkali-treated, lightweight, renewable kapok fiber (MKF) and high-efficiency, phosphorus-nitrogenous flame retardant (NTPA) into the PLA matrix based on the extrusion–injection molding method. When the additive loads of MKF and NTPA were 0.5 and 3.0 wt%, respectively, the PLA/MKF/NTPA biocomposites (PLA3.0) achieved a rating of UL-94 V-0 with an LOI value of 28.3%, and its impact strength (4.43 kJ·m−2) was improved by 18.8% compared to that of pure PLA. Moreover, the cone calorimetry results confirmed a 9.7% reduction in the average effective heat of combustion (av-EHC) and a 0.5-fold increase in the flame retardancy index (FRI) compared to the neat PLA. NTPA not only exerted a gas-phase flame-retardant role, but also a condensed-phase barrier effect during the combustion process of the PLA/MKF/NTPA biocomposites. Moreover, MKF acted as an energy absorber to enhance the toughness of the PLA/MKF/NTPA biocomposites. This work provides a simple way to prepare PLA biocomposites with excellent flame-retardancy and toughness at a low additive load, which is of great importance for expanding the application range of PLA biocomposites. Full article
(This article belongs to the Special Issue Green Flame-Retardant Polymer Material)
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14 pages, 5281 KB  
Article
Phosphorylation of Kapok Fiber with Phytic Acid for Enhanced Flame Retardancy
by Xin-Lin Jiang and Ren-Cheng Tang
Int. J. Mol. Sci. 2022, 23(23), 14950; https://doi.org/10.3390/ijms232314950 - 29 Nov 2022
Cited by 14 | Viewed by 4202
Abstract
Kapok fiber (KF), with the characteristics of a natural hollow structure, light weight, and low density, can be used as acoustic and thermal insulation, buoyancy, adsorption, filling, and composite material. The flame-retardant treatment can expand the functionality and application of KF. In this [...] Read more.
Kapok fiber (KF), with the characteristics of a natural hollow structure, light weight, and low density, can be used as acoustic and thermal insulation, buoyancy, adsorption, filling, and composite material. The flame-retardant treatment can expand the functionality and application of KF. In this work, the phosphorylation of KF using phytic acid (PA) in the presence of urea at a high temperature was used to enhance its flame retardancy. The phosphorylation reaction conditions were discussed, and the surface topography, thermal degradation, heat release, and combustion properties of phosphorylated KF were studied. The Fourier transform infrared spectroscopy and 31P solid-state nuclear magnetic resonance spectroscopy analyses confirmed the grafting of PA on cellulose by the formation of phosphate ester bonds. Due to the covalent binding of PA, phosphorylated KF exhibited good washing durability. The surface topography, Raman spectroscopy, thermogravimetric (TG), and microcalorimetry analyses revealed the excellent charring ability of phosphorylated KF. In the TG test in nitrogen, the char residue increased to 42.6% of phosphorylated KF from 8.3% of raw KF at 700 °C. In the vertical combustion, raw KF sheet was almost completely burned out within 30 s, while phosphorylated KF was very difficult to catch fire. In the microcalorimetry analysis, the heat release capacity and total heat release of phosphorylated KF decreased to 67 J/g∙K and 3.9 kJ/g, respectively from 237 J/g∙K and 18.1 kJ/g of raw KF. This work suggests that phosphorylated KF is an excellent flame-retardant material. Full article
(This article belongs to the Special Issue Bio-Polymer Materials and Bio-Refinery)
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