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34 pages, 1156 KiB  
Systematic Review
Mathematical Modelling and Optimization Methods in Geomechanically Informed Blast Design: A Systematic Literature Review
by Fabian Leon, Luis Rojas, Alvaro Peña, Paola Moraga, Pedro Robles, Blanca Gana and Jose García
Mathematics 2025, 13(15), 2456; https://doi.org/10.3390/math13152456 - 30 Jul 2025
Viewed by 258
Abstract
Background: Rock–blast design is a canonical inverse problem that joins elastodynamic partial differential equations (PDEs), fracture mechanics, and stochastic heterogeneity. Objective: Guided by the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) protocol, a systematic review of mathematical methods for geomechanically informed [...] Read more.
Background: Rock–blast design is a canonical inverse problem that joins elastodynamic partial differential equations (PDEs), fracture mechanics, and stochastic heterogeneity. Objective: Guided by the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) protocol, a systematic review of mathematical methods for geomechanically informed blast modelling and optimisation is provided. Methods: A Scopus–Web of Science search (2000–2025) retrieved 2415 records; semantic filtering and expert screening reduced the corpus to 97 studies. Topic modelling with Bidirectional Encoder Representations from Transformers Topic (BERTOPIC) and bibliometrics organised them into (i) finite-element and finite–discrete element simulations, including arbitrary Lagrangian–Eulerian (ALE) formulations; (ii) geomechanics-enhanced empirical laws; and (iii) machine-learning surrogates and multi-objective optimisers. Results: High-fidelity simulations delimit blast-induced damage with ≤0.2 m mean absolute error; extensions of the Kuznetsov–Ram equation cut median-size mean absolute percentage error (MAPE) from 27% to 15%; Gaussian-process and ensemble learners reach a coefficient of determination (R2>0.95) while providing closed-form uncertainty; Pareto optimisers lower peak particle velocity (PPV) by up to 48% without productivity loss. Synthesis: Four themes emerge—surrogate-assisted PDE-constrained optimisation, probabilistic domain adaptation, Bayesian model fusion for digital-twin updating, and entropy-based energy metrics. Conclusions: Persisting challenges in scalable uncertainty quantification, coupled discrete–continuous fracture solvers, and rigorous fusion of physics-informed and data-driven models position blast design as a fertile test bed for advances in applied mathematics, numerical analysis, and machine-learning theory. Full article
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14 pages, 2566 KiB  
Review
Improved Biomass Production and Secondary Metabolism: A Critical Review of Grafting in Cannabis sativa
by S. M. Ahsan, Md. Injamum-Ul-Hoque, Md. Mezanur Rahman, Sang-Mo Kang, In-Jung Lee and Hyong Woo Choi
Plants 2025, 14(15), 2347; https://doi.org/10.3390/plants14152347 - 30 Jul 2025
Viewed by 460
Abstract
Cannabis sativa L. is a versatile plant with applications in various sectors such as agriculture, medicine, food, and cosmetics. The therapeutic properties of cannabis are often linked to its secondary compounds. The worldwide cannabis market is undergoing swift changes due to varying legal [...] Read more.
Cannabis sativa L. is a versatile plant with applications in various sectors such as agriculture, medicine, food, and cosmetics. The therapeutic properties of cannabis are often linked to its secondary compounds. The worldwide cannabis market is undergoing swift changes due to varying legal frameworks. Medicinal cannabis (as a heterozygous and dioecious species) is distinct from most annual crops grown in controlled environments, typically propagated through stem cutting rather than seeds to ensure genetic uniformity. Consequently, as with any commercially cultivated crop, biomass yield plays a crucial role in overall productivity. The key factors involved in cultivation conditions, such as successful root establishment, stress tolerance, and the production cycle duration, are critical for safeguarding, improving, and optimizing plant yield. Grafting is a long-established horticultural practice that mechanically joins the scion and rootstock of distinct genetic origins by merging their vascular systems. This approach can mitigate undesirable traits by leveraging the strengths of particular plants, proving beneficial to various applications. Grafting is not used commercially in Cannabis. Only three very recent investigations suggest that grafting holds significant promise for enhancing both the agronomic and medicinal potential of Cannabis. This review critically examines the latest advancements in cannabis grafting and explores prospects for improving biomass (stem, root, flower, etc.) yield and secondary metabolite production. Full article
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28 pages, 2549 KiB  
Article
A 25K Wheat SNP Array Revealed the Genetic Diversity and Population Structure of Durum Wheat (Triticum turgidum subsp. durum) Landraces and Cultivars
by Lalise Ararsa, Behailu Mulugeta, Endashaw Bekele, Negash Geleta, Kibrom B. Abreha and Mulatu Geleta
Int. J. Mol. Sci. 2025, 26(15), 7220; https://doi.org/10.3390/ijms26157220 - 25 Jul 2025
Viewed by 1171
Abstract
Durum wheat, the world’s second most cultivated wheat species, is a staple crop, critical for global food security, including in Ethiopia where it serves as a center of diversity. However, climate change and genetic erosion threaten its genetic resources, necessitating genomic studies to [...] Read more.
Durum wheat, the world’s second most cultivated wheat species, is a staple crop, critical for global food security, including in Ethiopia where it serves as a center of diversity. However, climate change and genetic erosion threaten its genetic resources, necessitating genomic studies to support conservation and breeding efforts. This study characterized genome-wide diversity, population structure (STRUCTURE, principal coordinate analysis (PCoA), neighbor-joining trees, analysis of molecular variance (AMOVA)), and selection signatures (FST, Hardy–Weinberg deviations) in Ethiopian durum wheat by analyzing 376 genotypes (148 accessions) using an Illumina Infinium 25K single nucleotide polymorphism (SNP) array. A set of 7842 high-quality SNPs enabled the assessments, comparing landraces with cultivars and breeding populations. Results revealed moderate genetic diversity (mean polymorphism information content (PIC) = 0.17; gene diversity = 0.20) and identified 26 loci under selection, associated with key traits like grain yield, stress tolerance, and disease resistance. AMOVA revealed 80.1% variation among accessions, with no significant differentiation by altitude, region, or spike density. Landraces formed distinct clusters, harboring unique alleles, while admixture suggested gene flow via informal seed exchange. The findings highlight Ethiopia’s rich durum wheat diversity, emphasizing landraces as reservoirs of adaptive alleles for breeding. This study provides genomic insights to guide conservation and the development of climate-resilient cultivars, supporting sustainable wheat production globally. Full article
(This article belongs to the Special Issue Latest Research on Plant Genomics and Genome Editing, 2nd Edition)
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10 pages, 1134 KiB  
Viewpoint
McDonald’s McLean Deluxe and Planetary Health: A Cautionary Tale at the Intersection of Alternative Meats and Ultra-Processed Marketing
by Susan L. Prescott and Alan C. Logan
Challenges 2025, 16(3), 33; https://doi.org/10.3390/challe16030033 - 17 Jul 2025
Viewed by 250
Abstract
Dietary choices and patterns have enormous consequences along the lines of individual, community, and planetary health. Excess meat consumption has been linked to chronic disease risk, and at large scales, the underlying industries maintain a massive environmental footprint. For these reasons, public and [...] Read more.
Dietary choices and patterns have enormous consequences along the lines of individual, community, and planetary health. Excess meat consumption has been linked to chronic disease risk, and at large scales, the underlying industries maintain a massive environmental footprint. For these reasons, public and planetary health experts are unified in emphasizing a whole or minimally processed plant-based diet. In response, the purveyors of ultra-processed foods have added “meat alternatives” to their ultra-processed commercial portfolios; multinational corporations have been joined by “start-ups” with new ultra-processed meat analogues. Here, in our Viewpoint, we revisit the 1990s food industry rhetoric and product innovation, a time in which multinational corporations pushed a great “low-fat transition.” We focus on the McLean Deluxe burger, a carrageenan-rich product introduced by the McDonald’s Corporation in 1991. Propelled by a marketing and media-driven fear of dietary fats, the lower-fat burger was presented with great fanfare. We reflect this history off the current “great protein transition,” a period once again rich in rhetoric, with similar displays of industry detachment from concerns about the health consequences of innovation. We scrutinize the safety of carrageenan and argue that the McLean burger should serve as a cautionary tale for planetary health and 21st century food innovation. Full article
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22 pages, 3313 KiB  
Article
Transcriptome Analysis and CFEM Gene Overexpression in Metschnikowia bicuspidata Under Hemocyte and Iron Ion Stress
by Bingnan Zuo, Xiaodong Li, Ji Zhang, Bingyu Li, Na Sun and Fang Liang
Pathogens 2025, 14(7), 691; https://doi.org/10.3390/pathogens14070691 - 14 Jul 2025
Viewed by 349
Abstract
The “milky disease” in Chinese mitten crabs (Eriocheir sinensis), caused by Metschnikowia bicuspidata, poses significant threats to aquaculture, though its pathogenic mechanisms remain poorly understood. This study employs transcriptomic sequencing to analyze gene expression changes in Metschnikowia bicuspidata under hemocyte [...] Read more.
The “milky disease” in Chinese mitten crabs (Eriocheir sinensis), caused by Metschnikowia bicuspidata, poses significant threats to aquaculture, though its pathogenic mechanisms remain poorly understood. This study employs transcriptomic sequencing to analyze gene expression changes in Metschnikowia bicuspidata under hemocyte challenge, iron overload (1 mmol/mL), and combined stress, with functional validation through Common in Fungal Extracellular Membrane (CFEMgene) overexpression strains. Key findings reveal that (1) hemocyte challenge activated base excision repair (−log10[P] = 7.58) and ribosome biogenesis pathways, indicating fungal adaptation through DNA repair and enhanced protein synthesis to counter host immune attacks (e.g., ROS-mediated damage). (2) Iron overload induced glutathione metabolism and pentose phosphate pathway enrichment, demonstrating mitigation of ferroptosis through NADPH/GSH antioxidant systems and autophagy/proteasome coordination. (3) Under combined stress, ribosome biogenesis (−log10[P] = 1.3) and non-homologous end-joining pathways coordinated DNA repair with stress protein synthesis, complemented by vacuolar V-ATPase-mediated iron compartmentalization. (4) CFEM genes showed significant upregulation under hemocyte stress, with overexpression strains exhibiting enhanced biofilm formation (35% increased MTT cytotoxicity) and infectivity (40% higher infection rate), confirming CFEM domains mediate pathogenesis through iron homeostasis and virulence factor production. This work elucidates how M. bicuspidata employs metabolic reprogramming, oxidative stress responses, and CFEM-mediated iron regulation to establish infection, providing critical insights for developing targeted control strategies against milky disease. Full article
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26 pages, 2151 KiB  
Article
Belt and Road Initiative and Sustainable Development: Evidence from Bangladesh
by Syeda Nasrin Akter, Shuoben Bi, Mohammad Shoyeb, Muhammad Salah Uddin and Md. Mozammel Haque
Sustainability 2025, 17(14), 6234; https://doi.org/10.3390/su17146234 - 8 Jul 2025
Viewed by 703
Abstract
The Belt and Road Initiative (BRI) prioritizes infrastructure investment to enhance regional connectivity and foster sustainable economic development. Therefore, this empirical study aims to examine the impact of the BRI, specifically through Chinese foreign direct investment (CFDI) on sustainable growth in Bangladesh. The [...] Read more.
The Belt and Road Initiative (BRI) prioritizes infrastructure investment to enhance regional connectivity and foster sustainable economic development. Therefore, this empirical study aims to examine the impact of the BRI, specifically through Chinese foreign direct investment (CFDI) on sustainable growth in Bangladesh. The study employs the Mann–Kendall trend analysis and the generalized method of moments (GMM). For the Mann–Kendall trend analysis, sectoral FDI and output data from four major industrial sectors, obtained from Bangladesh Bank and CEIC for the period 1996–2020, are used to analyze trends in industrial development. Additionally, to assess the BRI’s role in sustainable development, this study compares green gross domestic product (GGDP) and gross domestic product (GDP) using a GMM analysis of CFDI inflows across 16 industrial sectors from 2013 to 2022, sourced from various databases. Findings reveal that CFDI significantly contributes to domestic industrial growth, particularly in the manufacturing and construction sectors. Although Bangladesh joined the BRI in 2016, a notable surge in CFDI appears from 2011–2012, partially driven by Bangladesh’s economic liberalization policies, and reflects early strategic investment consistent with China’s expanding economic diplomacy, which was later formalized under the BRI framework. The two-step system GMM results demonstrate that CFDI has a stronger impact on GGDP (0.0350) than on GDP (0.0146), with GGDP showing faster convergence (0.6027 vs. 0.1800), highlighting more robust and rapid sustainable growth outcomes. This underscores the significant Chinese investment in green sectors in Bangladesh. The study also demonstrates that the BRI supports the achievement of Sustainable Development Goals (SDGs) 7 (green energy) and 9 (sustainable infrastructure). These insights offer valuable direction for future research and policy, suggesting that Bangladesh should prioritize attracting green-oriented CFDI in sectors like energy, manufacturing, and construction, while also strengthen. Full article
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31 pages, 423 KiB  
Article
The Behavior of Tree-Width and Path-Width Under Graph Operations and Graph Transformations
by Frank Gurski and Robin Weishaupt
Algorithms 2025, 18(7), 386; https://doi.org/10.3390/a18070386 - 25 Jun 2025
Viewed by 457
Abstract
Tree-width and path-width are well-known graph parameters. Many NP-hard graph problems admit polynomial-time solutions when restricted to graphs of bounded tree-width or bounded path-width. In this work, we study the behavior of tree-width and path-width under various unary and binary graph transformations. For [...] Read more.
Tree-width and path-width are well-known graph parameters. Many NP-hard graph problems admit polynomial-time solutions when restricted to graphs of bounded tree-width or bounded path-width. In this work, we study the behavior of tree-width and path-width under various unary and binary graph transformations. For considered transformations, we provide upper and lower bounds for the tree-width and path-width of the resulting graph in terms of those of the initial graphs or argue why such bounds are impossible to specify. Among the studied unary transformations are vertex addition, vertex deletion, edge addition, edge deletion, subgraphs, vertex identification, edge contraction, edge subdivision, minors, powers of graphs, line graphs, edge complements, local complements, Seidel switching, and Seidel complementation. Among the studied binary transformations, we consider the disjoint union, join, union, substitution, graph product, 1-sum, and corona of two graphs. Full article
(This article belongs to the Special Issue Graph and Hypergraph Algorithms and Applications)
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16 pages, 1699 KiB  
Article
Climate Change Adaptation Knowledge Among Rice Farmers in Lake Toba Highland, Indonesia
by Rizabuana Ismail, Erika Revida, Suwardi Lubis, Emmy Harso Kardhinata, Raras Sutatminingsih, Ria Manurung, Bisru Hafi, Rahma Hayati Harahap and Devi Sihotang
Sustainability 2025, 17(13), 5715; https://doi.org/10.3390/su17135715 - 21 Jun 2025
Viewed by 708
Abstract
Climate change has increasingly disrupted traditional farming systems, particularly in highland areas where environmental changes are more pronounced. This study explores how rice farmers in the Lake Toba highlands, Indonesia—both irrigated and non-irrigated—have gradually shifted away from traditional knowledge (TK) in response to [...] Read more.
Climate change has increasingly disrupted traditional farming systems, particularly in highland areas where environmental changes are more pronounced. This study explores how rice farmers in the Lake Toba highlands, Indonesia—both irrigated and non-irrigated—have gradually shifted away from traditional knowledge (TK) in response to climate challenges and what new adaptation strategies have emerged to sustain rice production. This study employed a descriptive qualitative approach with a broad and holistic perspective. Data were collected from 130 purposively selected rice farmers in two sub-districts: Harian (irrigated) and Pangururan (non-irrigated). Data were gathered through in-depth interviews guided by semi-structured statements, focusing on farmers’ lived experiences and adaptation strategies across the rice farming cycle—from planting to harvesting. The findings revealed that while the two groups differ in water access and environmental conditions, they show similar trends in shifting away from traditional indicators. Farmers increasingly adopted new adaptation strategies such as joining farmer groups, using water pumps in non-irrigated areas, switching to more climate-resilient crop varieties, and adjusting planting calendars based on personal observation rather than inherited natural signs. This shift from traditional to practical, experience-based strategies reflects farmers’ responses to the fading reliability of traditional knowledge under changing climatic conditions. Despite the loss of symbolic TK practices, farmers continue to demonstrate resilience through peer collaboration and contextual decision-making. This study highlights the need to strengthen farmer-led adaptation while preserving valuable elements of TK. Future research should expand across the Lake Toba highlands and incorporate quantitative methods to capture broader patterns of local adaptation. Full article
(This article belongs to the Section Social Ecology and Sustainability)
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21 pages, 2043 KiB  
Review
A Review on the Impact of Fallback Factor on Intermittent Gas and Gas-Assisted Plunger Lifts
by Erasmus Mensah and Smith Leggett
Geosciences 2025, 15(7), 237; https://doi.org/10.3390/geosciences15070237 - 20 Jun 2025
Viewed by 265
Abstract
In intermittent gas lift (IGL), not all the liquid initially in the tubing is usually produced at the surface in one cycle. This is due to a concept known as fallback, which occurs when some amount of the initial liquid column drops back [...] Read more.
In intermittent gas lift (IGL), not all the liquid initially in the tubing is usually produced at the surface in one cycle. This is due to a concept known as fallback, which occurs when some amount of the initial liquid column drops back to join the next slug. We conducted a review of earlier works on IGL and the behavior of the fallback factor. The dependence on the fallback factor on the operational conditions such as slug velocity, valve opening pressure, valve closing pressure, casing–tubing pressure ratio, diameter of tubing, and amount of gas injected during IGL are discussed in this paper. The effect on the shape and stability of the nose of the Taylor bubble on the lifting efficiency of the bubble is also explained. In trying to reduce the fallback factor per cycle, there have been recommendations to combine gas lift with plunger lift. We also present the results of this combination and the effects on the fallback factor in gas-assisted plunger lift (GAPL). More light is shed on the behavior of the velocity of the liquid slug and how it affects the fallback factor during IGL. The behavior of the fallback factor with an increase or decrease in plunger velocity during GAPL is also presented in this paper. This review is categorized into experimental and numerical studies on fallback factor to evaluate their impact on production efficiency in IGL and GAPL. Additionally, different formulas for fallback proposed by different literature are compiled. Full article
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28 pages, 2810 KiB  
Article
Conceptual Recycling Chain for Proton Exchange Membrane Water Electrolyzers—Case Study Involving Review-Derived Model Stack
by Malena Staudacher, Dominik Goes, Sohyun Ahn, Dzeneta Vrucak, Tim Gießmann, Bernhard Bauer-Siebenlist, Thomas Leißner, Martin Rudolph, Jürgen Fleischer, Bernd Friedrich and Urs A. Peuker
Recycling 2025, 10(3), 121; https://doi.org/10.3390/recycling10030121 - 19 Jun 2025
Viewed by 1151
Abstract
The recycling of proton exchange membrane water electrolyzer (PEMWE) raw materials is imperative due to their scarcity, cost, complexity and environmental impact. This is particularly true in the context of expanding electrolyzer manufacturing and reducing production costs. Developing comprehensive recycling strategies requires the [...] Read more.
The recycling of proton exchange membrane water electrolyzer (PEMWE) raw materials is imperative due to their scarcity, cost, complexity and environmental impact. This is particularly true in the context of expanding electrolyzer manufacturing and reducing production costs. Developing comprehensive recycling strategies requires the creation of a model stack due to the diversity in stack design, structure and materials. The review-derived model presented here provides a sound basis and summarizes the variety of approaches found in the literature and industry. The holistically developed recycling chain, including dismantling, mechanical processing, hydrometallurgical processes and carbon reuse, is characterized by the complete recycling of materials, the reduced application of energy-intensive process steps and the avoidance of environmentally harmful processes. Emphasis is placed on demonstrating the non-destructive disassembly of joined components, the dry mechanical decoating of catalyst-coated membranes, membrane dissolution, the separation of anode and cathode particles and the environmentally friendly hydrometallurgical processing of platinum. Full article
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20 pages, 2376 KiB  
Review
Scientific Production on Physical Activity, Physical Education, Global Warming and Climate Change: A Bibliometric Analysis
by Antonio Castillo-Paredes, Angel Denche-Zamorano, Mario Fuentes-Rubio, Matias Portela-Estinto, José Carmelo Adsuar and Diana Salas-Gómez
Societies 2025, 15(6), 161; https://doi.org/10.3390/soc15060161 - 11 Jun 2025
Viewed by 941
Abstract
Physical activity allows people to obtain multidimensional benefits. Regular practice and following the recommendations can provide the benefits mentioned above. However, it has been evidenced that the variability in the environmental temperature is a determining factor to adhere to the regular practice of [...] Read more.
Physical activity allows people to obtain multidimensional benefits. Regular practice and following the recommendations can provide the benefits mentioned above. However, it has been evidenced that the variability in the environmental temperature is a determining factor to adhere to the regular practice of physical activity. From this point of view, it has become evident that researchers have joined criteria to explore the effects of climate change or global warming on physical activity or physical education. This study is the first bibliometric analysis of the scientific literature related to physical activity, physical education, global warming, and climate change. The objective of the present bibliometric review was to examine annual publication trends, identifying the categories, journals, and countries with the highest number of publications on this topic. In addition, the secondary objective was to identify the most productive and prominent authors, highlight the most cited articles, and determine the keywords most used by the authors. We analyzed 261 papers published in journals indexed in the Web of Science, examining the trend followed by annual publications, identifying prolific and prominent co-authors, leading countries and journals, most cited papers, and most used author keywords. The annual publications followed an exponential growth trend (R2 = 90%), which means that there is great interest in the scientific community for this object of study. The Journal of Physical Activity & Health was the journal with the most published papers. M.S. Tremblay and E.Y. Lee were the most prominent co-authors, and as reference authors on the subject, M. Nieuwenhuijsen and H. Khreis were the most prominent authors. The three countries with the highest productivity are the USA, the UK, and Canada. Although a total of 29 keywords were identified, only 25 of them were commonly recurrent, with the most used being climate change and physical activity. Full article
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16 pages, 1810 KiB  
Article
Occurrence and Genetic Variation of Monolepta hieroglyphica (Motschulsky, 1858) (Coleoptera: Chrysomelidae), a Newly Emerging Pest, Among Hosts in Northeast China
by Wei Sun, Xiuhua Zhang, Jiachun Zhou and Yuebo Gao
Insects 2025, 16(6), 605; https://doi.org/10.3390/insects16060605 - 8 Jun 2025
Viewed by 1109
Abstract
The northeast region of China plays a crucial role in crop production. The leaf beetle Monolepta hieroglyphica (Motschulsky, 1858) (Coleoptera: Chrysomelidae) has emerged as a potential threat to food security in the region. With a wide distribution spanning Asia and Russia, this beetle [...] Read more.
The northeast region of China plays a crucial role in crop production. The leaf beetle Monolepta hieroglyphica (Motschulsky, 1858) (Coleoptera: Chrysomelidae) has emerged as a potential threat to food security in the region. With a wide distribution spanning Asia and Russia, this beetle affects various crops. However, limited information is available regarding its occurrence patterns and genetic diversity among major crops in the region. Based on systematic observations across various hosts, coupled with genetic variation analysis using mitochondrial DNA markers, the main results were as follows. Leaf beetle occurrence varied among hosts, peaking from late July to mid-August, with maize and soybean fields exhibiting higher infestation rates compared with other crops. Notably, late-cultivated maize fields harbored the highest beetle numbers due to the species’ preference for young leaves. The host transfer trajectory may have originated in soybean and weeds, with subsequent alternation between host plants and other crops, before the final migration to cabbage and late-cultivated maize fields. Genetic analysis revealed nine COI haplotypes, four COII haplotypes, eleven Cytb haplotypes, and twenty-one combined haplotypes. No clear relationship existed between genetic diversity and occurrence, and no distinct host-based genetic patterns emerged from neighbor-joining tree and haplotype network analyses. High gene flow rates were observed, likely contributing to decreased genetic variation. An analysis of molecular variance results indicated major genetic variation within populations, although genetic distance and haplotype distribution indicated divergence among host populations. These results provide foundational data for developing effective M. hieroglyphica pest management strategies. Full article
(This article belongs to the Special Issue Corn Insect Pests: From Biology to Control Technology)
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31 pages, 7884 KiB  
Article
Magnetic Pulse Welding of Dissimilar Materials: Weldability Window for AA6082-T6/HC420LA Stacks
by Mario A. Renderos Cartagena, Edurne Iriondo Plaza, Amaia Torregaray Larruscain, Marie B. Touzet-Cortina and Franck A. Girot Mata
Metals 2025, 15(6), 619; https://doi.org/10.3390/met15060619 - 30 May 2025
Viewed by 668
Abstract
Magnetic pulse welding (MPW) is a promising solid-state joining process that utilizes electromagnetic forces to create high-speed, impact-like collisions between two metal components. This welding technique is widely known for its ability to join dissimilar metals, including aluminum, steel, and copper, without the [...] Read more.
Magnetic pulse welding (MPW) is a promising solid-state joining process that utilizes electromagnetic forces to create high-speed, impact-like collisions between two metal components. This welding technique is widely known for its ability to join dissimilar metals, including aluminum, steel, and copper, without the need for additional filler materials or fluxes. MPW offers several advantages, such as minimal heat input, no distortion or warping, and excellent joint strength and integrity. The process is highly efficient, with welding times typically ranging from microseconds to milliseconds, making it suitable for high-volume production applications in sectors including automotive, aerospace, electronics, and various other industries where strong and reliable joints are required. It provides a cost-effective solution for joining lightweight materials, reducing weight and improving fuel efficiency in transportation systems. This contribution concerns an application for the automotive sector (body-in-white) and specifically examines the welding of AA6082-T6 aluminum alloy with HC420LA cold-rolled micro-alloyed steel. One of the main aspects for MPW optimization is the determination of the process window that does not depend on the equipment used but rather on the parameters associated with the physical mechanisms of the process. It was demonstrated that process windows based on contact angle versus output voltage diagrams can be of interest for production use for a given component (shock absorbers, suspension struts, chassis components, instrument panel beams, next-generation crash boxes, etc.). The process window based on impact pressures versus impact velocity for different impact angles, in addition to not depending on the equipment, allows highlighting other factors such as the pressure welding threshold for different temperatures in the impact zone, critical transition speeds for straight or wavy interface formation, and the jetting/no jetting effect transition. Experimental results demonstrated that optimal welding conditions are achieved with impact velocities between 900 and 1200 m/s, impact pressures of 3000–4000 MPa, and impact angles ranging from 18–35°. These conditions correspond to optimal technological parameters including gaps of 1.5–2 mm and output voltages between 7.5 and 8.5 kV. Successful welds require mean energy values above 20 kJ and weld specific energy values exceeding 150 kJ/m2. The study establishes critical failure thresholds: welds consistently failed when gap distances exceeded 3 mm, output voltage dropped below 5.5 kV, or impact pressures fell below 2000 MPa. To determine these impact parameters, relationships based on Buckingham’s π theorem provide a viable solution closely aligned with experimental reality. Additionally, shear tests were conducted to determine weld cohesion, enabling the integration of mechanical resistance isovalues into the process window. The findings reveal an inverse relationship between impact angle and weld specific energy, with higher impact velocities producing thicker intermetallic compounds (IMCs), emphasizing the need for careful parameter optimization to balance weld strength and IMC formation. Full article
(This article belongs to the Topic Welding Experiment and Simulation)
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15 pages, 444 KiB  
Article
Exploring the Crossing Numbers of Three Join Products of 6-Vertex Graphs with Discrete Graphs
by Michal Staš and Mária Švecová
Mathematics 2025, 13(10), 1694; https://doi.org/10.3390/math13101694 - 21 May 2025
Viewed by 325
Abstract
The significance of searching for edge crossings in graph theory lies inter alia in enhancing the clarity and readability of graph representations, which is essential for various applications such as network visualization, circuit design, and data representation. This paper focuses on exploring the [...] Read more.
The significance of searching for edge crossings in graph theory lies inter alia in enhancing the clarity and readability of graph representations, which is essential for various applications such as network visualization, circuit design, and data representation. This paper focuses on exploring the crossing number of the join product G*+Dn, where G* is a graph isomorphic to the path on four vertices P4 with an additional two vertices adjacent to two inner vertices of P4, and Dn is a discrete graph composed of n isolated vertices. The proof is based on exact crossing-number values for join products involving particular subgraphs Hk of G* with discrete graphs Dn combined with the symmetrical properties of graphs. This approach could also be adapted to determine the unknown crossing numbers of two other 6-vertices graphs obtained by adding one or two additional edges to the graph G*. Full article
(This article belongs to the Special Issue Advances in Mathematics: Equations, Algebra, and Discrete Mathematics)
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44 pages, 7325 KiB  
Article
Synthesis and Characterization of Bio-Composite Based on Urea–Formaldehyde Resin and Hydrochar: Inherent Thermal Stability and Decomposition Kinetics
by Bojan Janković, Vladimir Dodevski, Marija Janković, Marija Milenković, Suzana Samaržija-Jovanović, Vojislav Jovanović and Milena Marinović-Cincović
Polymers 2025, 17(10), 1375; https://doi.org/10.3390/polym17101375 - 16 May 2025
Viewed by 599
Abstract
This work reports a study on the structural characterization, evaluation of thermal stability, and non-isothermal decomposition kinetics of urea–formaldehyde (UF) resin modified with hydrochar (obtained by the hydrothermal carbonization of spent mushroom substrate (SMS)) (UF-HC). The structural characterization of UF-HC, performed by scanning [...] Read more.
This work reports a study on the structural characterization, evaluation of thermal stability, and non-isothermal decomposition kinetics of urea–formaldehyde (UF) resin modified with hydrochar (obtained by the hydrothermal carbonization of spent mushroom substrate (SMS)) (UF-HC). The structural characterization of UF-HC, performed by scanning electron microscopy (SEM), Fourier transform infrared (FTIR), and X-ray diffraction analyses, showed that UF-HC consists of a large number of spheroidal particles, which are joined, thus forming clusters. It constitutes agglomerates, which are composed of crystals that have curved plate-like forms, including crystalline UF structure and graphite lattices with an oxidized face (graphene oxide, GO). The measurement of inherent thermal stability and non-isothermal decomposition kinetic analysis was carried out using simultaneous thermogravimetric–differential thermal analyses (TGA-DTA) at various heating rates. Parameters that are obtained from thermal stability assessment have indicated the significant thermal stability of UF-HC. Substantial variation in activation energy and the pre-exponential factor with the advancement of decomposition process verifies the multi-step reaction pathway. The decomposition process takes place through three independent single-step reactions and one consecutive reactions step. The consecutive stage represents a path to the industrial production of valuable heterocyclic organic compounds (furan) and N-heterocyclic compounds (pyrroles), building a green-protocol trail. It was found that a high heating rate stimulates a high production of furan from cellulose degradation via the ring opening step, while a low heating rate favors the production of urea compounds (methylolurea hemiformal (HFn)) by means of methylene ether bridges breaking. Full article
(This article belongs to the Collection Biopolymers: Synthesis and Properties)
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