Search Results (7,441)

Steel/tin bimetallic components fabricated using traditional casting processes have inherent drawbacks, including complicated preparation procedures and a relatively low interfacial bonding strength. To efficiently create metallurgical composite steel/tin bimetallic structures under complex service conditions, we utilized TIG-based additive manufacturing with front wire feeding to prepare the components. The effects of the substrate inclination angle on the macroscopic morphology of the deposited layer, interfacial phase composition, the growth behavior of intermetallic compounds (IMCs) at the bimetallic interfaces, and interfacial mechanical properties were investigated. Our results show that macro-structural defects like cracks, voids and pores were not observed at the steel/tin interfaces. The grains of the interface IMCs were mainly composed of Fe₃Sn, FeSn₂ and FeSb₂ phases; Fe-rich microspheres were dispersed inside the deposited tin layer. Under horizontal substrate conditions, deposited layer morphology and IMC layer thickness presented symmetric distributions. When the inclination angle of the substrate reached 30°, the deposited layers exhibited an asymmetric teardrop morphology, resulting in an increased layer height and width and penetration depth. Meanwhile, tin alloy grains were significantly refined; more high-angle grain boundaries (HAGBs) were formed at the spreading fronts of molten droplets. Tin alloy hardness was improved via synergistic dispersion and grain boundary strengthening. This work reveals the inclination–morphology–microstructure–property correlation, fills the research gap in inclined substrate arc additive manufacturing of steel/tin bimetals, and provides a theoretical foundation for engineering applications. Full article

This study investigated physically and chemically activated chimney soot to evaluate the influence of the activation process on the textural properties and porous structure of materials intended for use in supercapacitors. The materials were characterized by Raman spectroscopy to analyze molecular structure and composition, as well as BET analysis to determine porosity and structural properties based on N₂ adsorption-desorption isotherms. Their electrochemical characteristics were evaluated using a two-electrode configuration with cyclic voltammetry, galvanostatic charge–discharge measurements, and long-term cycling tests of up to 10,000 cycles within a voltage window of 0.05–1.0 V in a 1 M KOH electrolyte. Soot-based symmetric supercapacitors activated with KOH at а ratio of 3:1 exhibit a specific capacitance of 74–78 F g⁻¹ at 0.2 A g⁻¹ and achieve an energy density of 2.3 Wh kg⁻¹ at a power density of 32 W kg⁻¹. The results demonstrate that, by carefully controlling the type and quantity of the activating agent, chemical activation is an effective method for increasing the specific surface area and improving the electrochemical characteristics of the resulting materials. Chemical activation significantly expands the microporous framework, optimizing ion transport at the electrode–electrolyte interface. The results demonstrate the successful valorization of chimney soot as functional carbon electrodes for next-generation energy storage applications. Full article

Biomass-derived nanoengineered carbon materials have emerged as key platforms in environmental technologies due to their high surface area, electrical conductivity, chemical stability, and sustainable synthetic route starting from renewable feedstock. This broad family comprises dimensionally nanoscale materials, such as carbon dots, carbon nanofibers, and graphene-based structures, as well as biochars, hydrochars, activated carbons, and related porous carbonaceous materials whose pore architecture, surface chemistry, or defects are deliberately engineered at the nanometer scale. Beyond their traditional role as passive supports, these materials can actively regulate adsorption phenomena, charge transport, and catalytic microenvironments through precise control of heteroatom doping, graphitic domains, and hierarchical porosity. Among current environmental priorities, carbon dioxide (CO₂) management represents one of the most pressing challenges. Biomass-derived nanocarbons offer tunable adsorption sites for selective CO₂ capture while simultaneously serving as active matrices for catalytic conversion. Tailored doped-carbon frameworks can stabilize key reaction intermediates, suppress competing pathways such as hydrogen evolution, and promote selective transformation into fuels and high-value chemicals. In addition, these materials are excellent hosts for atomically dispersed metals, dual-site catalysts, and semiconductor hybrids used in electrochemical and photocatalytic CO₂ reduction. By combining renewable sourcing with nanoscale control of reactivity, carbon materials create a bridge between environmental remediation and carbon valorization. This review critically examines recent progress in biomass-derived nanoengineered carbon materials for integrated CO₂ capture and conversion, with emphasis on structure-property-performance relationships, mechanistic roles, scalability, and sustainability. Particular attention is also devoted to catalytic conversion and electrochemical CO₂ sensing, where carbon-based and hybrid interfaces enable the transduction of CO₂ recognition into measurable electrical responses. These materials represent a promising yet underexplored pathway toward circular carbon management and the development of next-generation low-carbon chemical technologies. Full article

Monolithic precast reinforced concrete (RC) frames with cast-in-place joint cores and grouted-sleeve splices are increasingly adopted in seismic regions, yet connection degradation is not carried through to system-level fragility: existing studies take hinge properties from code tables or one test, or stop at the joint. This study closes that gap with a reproducible transfer route in which the degrading, pinched M–θ hysteresis identified from a refined joint model becomes structure-level hinge parameters, with every intermediate quantity reported so that the route can be reproduced elsewhere. The joint model is an explicit finite-element interface-spring/contact strategy with Mohr–Coulomb interface behavior, tension cut-off, local spring failure, and sleeve–grout–rebar bond slip. Incremental dynamic analysis and fragility assessment of a six-story monolithic precast frame and a comparable cast-in-place frame show larger inter-story drift demands in the precast frame. At PGA = 0.40 g, its collapse exceedance probabilities are higher by 0.73 and 0.44 percentage points in X and Y, respectively. Global performance is broadly comparable, but the precast frame shows a consistent, modest unfavorable tendency caused by connection pinching and reduced ultimate rotation. Interface treatment, sleeve grouting quality, and connection-level ductility should therefore be explicitly considered in seismic performance assessment and design. Full article

The sturdy and stable unique polyhedral structure of FeOOH nanoparticles facilitates stress and load transfer, thereby forming a tighter mechanical interlock at the carbon fiber–matrix interface. In this work, the FeOOH nanocrystal layer in situ grown on flexible carbon fiber cloth was rationally designed and fabricated through hydrothermal synthesis. Then, the non-covalent cation–π bond was constructed at the interface between the iron ion-loaded FeOOH nanoparticles and indole-based poly(hexahydrotriazine) (In-PHT). Owing to the collaborative effects of physical anchoring and chemical bonding, the resultant composite exhibited an outstanding tensile strength of 322 MPa, and the friction coefficient significantly decreased by 63% compared with the composites without FeOOH nanoparticles. Moreover, the resultant worn composite showed an excellent self-healing property owing to the introduction of polyethylene wax (PEW) with a low melting point, and the healed friction coefficient remained almost unchanged. Extensive analyses verify that the phase-separated structure and Fe³⁺–π interactions across multiscale interfaces achieve the combined advantages of wear resistance and durability for recyclable carbon fiber-reinforced poly(hexahydrotriazine) composites (PHT-CFRPs). Full article

Spray cosmetics couple formulation composition with actuator design and biological targets, so their performance is governed by rapid, nonequilibrium interfacial processes that cannot be predicted from in-bottle stability or equilibrium surface tension alone. This targeted narrative review integrates evidence across storage stability, atomization, droplet flight and evaporation, deposition, film formation, active delivery, inhalation safety and environmental fate. It examines how surfactant molecular structure, micellar replenishment, dynamic surface tension, interfacial viscoelasticity and extensional rheology influence droplet-size distributions, wetting, spreading and deposition. Particular attention is given to competing effects: enhanced breakup may increase airborne fine fractions; stronger interfacial films may impair sprayability; enhanced penetration may reduce barrier tolerance; and bio-based origin does not necessarily imply a lower life-cycle burden. Across moisturizing, sunscreen, hair- and scalp-care, makeup-setting, cleansing-foam and emerging functional sprays, this review develops an interface-to-outcome framework and a multiobjective operating-window concept linking formulation and device variables to efficacy, manufacturability, safety and sustainability. The available evidence supports product-specific, whole-process validation rather than optimization against any single equilibrium property, while highlighting the need for spray-relevant dynamic measurements, realistic exposure assessment and validated formulation–device co-design. Full article

The increasing generation of construction and demolition waste, along with the depletion of natural aggregates, has driven growing interest in recycled concrete aggregate (RCA) and reclaimed asphalt pavement (RAP) as sustainable alternatives in concrete production. However, a direct and systematic comparison between the two materials remains limited. This review addresses this gap by applying PRISMA guidelines to analyze 82 peer-reviewed studies published between 2010 and 2026. Both materials are evaluated across three key domains: physical properties, mechanical performance, and microstructural characteristics. The findings indicate that RCA can reduce compressive strength by up to 26%, mainly due to the presence of porous adhered mortar and a complex interfacial transition zone (ITZ). In contrast, RAP weakens bonding with cement paste because of its hydrophobic bituminous coating, leading to adhesive failure at the mortar asphalt interface. Despite these limitations, RCA and RAP exhibit distinct behaviors in terms of shear capacity, ductility, energy absorption, and durability. Enhancement techniques such as surface treatment, carbonation, supplementary cementitious materials, and fiber reinforcement show potential in improving performance. Additionally, life cycle and economic analyses reveal that RAP can reduce total costs and carbon emissions when efficiently processed. This study provides a unified comparative framework to support sustainable material selection and design optimization. Full article

To develop ultraviolet (UV)-curable resin with excellent mechanical, thermal-resistant and self-healing properties, epoxidized soybean oil was utilized as a bio-based raw material in this paper, and its epoxy groups were ring-opened and modified with methanol and tert-butyl acetoacetate to introduce hydroxyl groups and flexible segments, yielding a functionalized polyol, which was reacted with isophorone diisocyanate to prepare a hydroxyl-terminated polyurethane prepolymer containing dynamic covalent bonds. The prepolymer was further end-capped with hydroxyethyl acrylate to obtain a UV-curable polyurethane acrylate resin. The physico-mechanical properties and self-healing efficiency of the samples were systematically investigated. The results showed that the prepared specimens had efficient self-healing capability and could achieve efficient repair of damaged interfaces through appropriate heat treatment without the need for external catalysts; the onset decomposition temperatures of all the samples were greater than 225 °C, demonstrating good thermal stability; the tensile strength, tensile modulus, flexural strength and flexural modulus could be as great as 31.1 MPa, 393.7 MPa, 29.6 MPa and 851.6 MPa, respectively. All these indicated that the prepared samples had good overall performances. This study provides a new strategy for the design and preparation of self-healing photocurable resins based on renewable resources. Full article

Two 4-piperazine-1,8-naphthalimides were designed as fluorescent probes for exploring the local polarity and proton concentration at the interface of micelles. Designed with an anchor₁-fluorophore-spacer-receptor-anchor₂ layout, the hydrophobicity of the pH probes was tuned by substitution of the anchor modules with different alkyl chains (methyl, butyl and octyl) to facilitate the micellar penetration depth. Fluorescence switching ‘on’ in methanol/water media upon protonation of the piperazine receptor is driven by a competition between solvent polarity and photoinduced charge transfer. The solvatochromic properties were investigated to enhance visual naked-eye communication. The fluorescent probes were tasked with reporting on the local polarity and proton content within sodium dodecyl sulphate (SDS), cetyltrimethylammonium chloride (CTAC) and Triton X-100 micelles. The dimethyl-substituted probe reported on the environment about the micelle/bulk water interface. The more hydrophobic octyl-butyl-substituted probe explored deeper into the micelles. Insight was gained into the local polarity and proton gradients inside micelles, as corroborated by emission wavelength, fluorescence quantum yield and ΔpK_a values. The findings are discussed in the context of the benzofurazan polarity–ΔpK_a maps reported by Uchiyama and de Silva. Full article

While ion correlation is known to enhance molecular-scale solvation forces, its capacity to improve macroscale boundary lubrication on engineering surfaces remains unverified. This study demonstrates that multivalent electrolyte-induced ion correlation significantly reduces macroscopic boundary friction, achieving up to a 67% reduction on alumina surfaces. This macroscopic enhancement is driven by interfacial electrochemical properties, where highly charged polar oxide interfaces trigger strong electrostatic correlation to restructure confined solvents into a rigid, load-bearing barrier. Ultimately, this work proves that interfacial ion correlation directly dictates and enhances macroscale boundary lubrication, bridging molecular-level force control with practical tribological applications. Full article

22Cr12NiMoWV martensitic heat-resistant steel serves as a candidate material for underground coiler sector plates, whereas the coupling relationship between partial austenitization, precipitate/carbide evolution, martensitic interfaces and mechanical response under medium-temperature quenching–tempering conditions is still ambiguous. This work systematically explores four key heat treatment variables to clarify the microstructure–property correlation and strengthening rebalance mechanism. In the 790–830 °C partial austenitization interval, the austenite fraction increases from 36.49 wt.% to 72.32 wt.% with a concurrent decline of M₂₃C₆ carbides from 5.34 wt.% to 4.92 wt.%, demonstrating competitive evolution between austenite generation and carbide retention. Specimens quenched at 810 °C for 2 h deliver a yield strength of 1015.4 ± 13.8 MPa and tensile strength of 1192.9 ± 17.8 MPa, 24.9% and 19.9% higher than conventional QT samples, owing to synergistic reinforcement from α′ martensite matrix, orientation interfaces and Cr-Mo-W-V-rich precipitates. After 400 °C × 4 h tempering, the steel still maintains superior strength, and its average misorientation falls from 40.41° to 31.17°. Though its engineering ductility is inferior to the quenched state, the mixed dimple–quasi-cleavage fracture mode suggests a partial recovery of ductile fracture characteristics compared with over-treated samples. The uncovered strengthening mechanism provides microstructural theoretical support for process optimization. Compared with the conventional quenching and tempering process, the optimized medium-temperature process (810 °C × 2 h quenching + 400 °C × 4 h tempering) reduces energy consumption and the production cycle and provides solid theoretical and experimental data for a green and low-cost industrial heat treatment of coil plates. Full article

We introduce the Soil–Plant Coupling Principle (SPCP), a conceptual framework proposing that ecosystem stability emerges from the integrity of biological interactions rather than the condition of individual ecosystem components. Although current ecological assessments primarily rely on soil properties, plant performance, and microbial diversity, growing evidence indicates that ecosystems can remain apparently functional while progressively losing the coordination among processes that sustain resilience. This gap limits the ability of conventional diagnostics to capture interactional changes underlying early ecosystem vulnerability. Unlike ecosystem multifunctionality and resilience, which primarily describe the provision of multiple functions and the capacity to resist or recover from disturbance, respectively, SPCP focuses on the coordination among the processes that sustain these functions and resilience. SPCP reframes ecosystem degradation as progressive decoupling among carbon allocation, nutrient cycling, hydrological processes, and microbial interactions at the soil–plant interface. By integrating recent advances in soil ecology, plant physiology, microbiome science, ecological networks, and biogeochemistry, the framework provides a unified conceptual basis for understanding how interactional connectivity regulates ecosystem resilience. The objectives of this Perspective are to: (i) establish the theoretical basis for viewing ecosystem stability through soil–plant coupling; (ii) define the core dimensions of coupling integrity; and (iii) outline how coupling integrity could be operationalized using structural, functional, and interaction-based indicators. We further discuss the potential of coupling integrity as an early-warning property and identify key limitations and research needs for testing and validating the framework. By proposing an integrative and potentially testable framework, the manuscript provides a new lens for understanding ecosystem vulnerability and resilience across scales. Full article

The development of sustainable, biocompatible scaffolds with enhanced structural stability remains a primary challenge in bone tissue engineering. In this study, structurally reinforced nanocomposite scaffolds were successfully fabricated by integrating green-synthesized carbon quantum dots (CQDs) into a gelatin (G) matrix, offering an innovative platform that mimics the organic–inorganic interfaces of natural bone tissue. The CQDs were derived from oatmeal via a sustainable, green hydrothermal route, serving simultaneously as zero-dimensional reinforcing fillers and bioactive agents within the biopolymer network. To ensure an additive-free fabrication process that avoids toxic chemical cross-linkers, dehydrothermal (DHT) treatment was employed, successfully modulating the interfacial and chemical cross-linking interactions between the gelatin chains and the oxygen-rich surface groups of the CQDs. Structural characterization confirmed the uniform dispersion of CQDs (average diameter 7–8 nm) within the porous gelatin framework. The incorporation of CQDs significantly improved the physicochemical properties of the scaffolds; the G/CQD 5% formulation emerged as the optimal composition, exhibiting a 118% increase in compression modulus compared to pristine gelatin. The composite demonstrated tuned swelling kinetics and a significantly reduced degradation rate, restricting mass loss after 14 days of incubation to approximately 24% compared to 40% for pristine gelatin, which is essential for maintaining a structural template during the initial stages of tissue formation. Bioactivity assays in simulated body fluid (SBF) confirmed the rapid, biomimetic induction of a crystalline hydroxyapatite layer with a natural Ca/P ratio of 1.61 within 14 days. Furthermore, preliminary in vitro assessments using Human Skin Fibroblasts (HSFs) confirmed excellent general cytocompatibility, with cell viability exceeding 90%. This study highlights the unique potential of utilizing biomass-derived carbon nanostructures and clean manufacturing processing to engineer multifunctional scaffolds with enhanced structural stability and intrinsic bioactivity for potential bone defect repairs. Full article

Transition joints between lightweight aluminum alloys and high-strength steel are widely employed in the transportation industry, and especially in shipbuilding, as intermediate inserts between structural components made of dissimilar metals. While traditional fusion welding presents considerable difficulties in joining such metals, explosive welding is particularly suitable for producing thick plates with large contact surfaces between aluminum and steel. The process setup and the various parameters involved have been described in several articles, as also documented by some recent overviews. However, there has been no review of the most recent papers specifically dealing with the metallurgical characteristics of these interfaces, as well as with their mechanical properties. Thus, the present article aims to fill this gap by outlining a review on the state of the art to correlate the process parameter setting, interface characteristics, and weldability of aluminum/steel transition joints, and then focusing on the most relevant studies concerning the mechanical behavior under static and fatigue conditions of trimetallic joints (Al alloy/commercially pure Al/structural steel) for shipbuilding applications. The effects of welding-induced thermal fields during structural joint insertion are also taken into account, and the most recent proposals for strategies to improve mechanical performance are examined. Full article

The development of efficient photocatalysts for hydrogen production is a key challenge for sustainable energy technologies. In this study, strontium titanate (SrTiO₃) was synthesized via a citrate-assisted sol-gel method and subsequently modified by deposition-precipitation using nominal HAuCl₄ precursor concentrations of 1.0, 1.5, and 2.0 mM. The resulting materials were characterized by XRD, Raman spectroscopy, UV-Vis diffuse reflectance spectroscopy, SEM with EDS, and X-ray fluorescence (XRF). Au incorporation did not produce detectable changes in the SrTiO₃ crystalline phase or its optical band gap, which remained at 3.19–3.20 eV. The additional absorption band centered near 550 nm was consistent with the localized surface plasmon resonance of metallic Au nanoparticles. Microscopy indicated increasing surface coverage and aggregation at the highest nominal precursor concentration. Under irradiation with a low-pressure Hg lamp, all Au-containing materials presented substantially greater H₂ evolution than pristine SrTiO₃, whereas the comparatively small differences among the Au-modified samples indicated an apparent activity plateau across the evaluated concentration range. Because the Au-associated absorption band near 550 nm lies outside the main 254 nm emission of the lamp and the SrTiO₃ band gap remained mostly unchanged, the enhanced H₂ evolution is consistent with improved interfacial charge separation in the Au/SrTiO₃ system. A Schottky-junction-mediated pathway is proposed based on the observed activity trends and the electronic properties reported for Au/SrTiO₃ interfaces, rather than to a plasmonic or band-gap-tuning effect. The selected STO/Au 2.0 mM material retained approximately 97% of its initial apparent H₂ evolution rate after three consecutive cycles, indicating favorable short-term activity retention. Overall, this comparatively simple synthesis route provides a practical baseline for investigating the influence of nominal Au precursor concentration on H₂ evolution over SrTiO₃. Full article