Search Results (109)

Background/Objectives: Hot-melt injection molding (HMIM) was evaluated as a solvent-free process for the preparation of glibenclamide (GLB), a poorly soluble BCS Class II drug, glassy solutions with the objective of improving dissolution and bioavailability for diabetes. Methods: GLB was blended at a concentration of 10% w/w with PVP K25, PVP VA64, and Soluplus^® (SOL) matrices. The miscibility of the GLB–polymer systems (matrices) was calculated based on the Hansen solubility parameters and validated using differential scanning calorimetry (DSC) analysis. The HMIM extrudates were milled into granules and analysed for their solid-state properties (DSC, XRPD, FTIR, and SEM studies), and flow properties. The produced granules were compressed into immediate release tablets and assessed for in vitro performance, stability, and in vivo bioavailability using 20 healthy male Sprague Dawley rats. Results: Findings revealed the formation of single-phase glassy solutions, specifically for PVP VA64 and SOL, which also exhibited advantageous manufacturing and extrudate clarity. The glassy solution formulations showed considerably improved dissolution characteristics compared with the crystalline GLB and the commercial product. The glassy solution formulations displayed fast drug release for PVP K25 and PVP VA64, and biphasic drug release for SOL. Stability testing confirmed the capability of PVP VA64 and SOL to maintain GLB in a molecularly dispersed, amorphous state for 12 months. The in vivo assessment revealed an increase in relative bioavailability to 246.3% and 124.5% for the SOL and PVP VA64 formulations when compared to the commercial formulation. Conclusions: Overall, the findings demonstrate the potential of HMIM-processed glassy solutions, especially those prepared using SOL, as promising platforms for promoting oral delivery of the poorly soluble antidiabetic GLB. Full article

Natural-fiber biocomposites are increasingly viewed as promising materials for sustainable engineering. However, their broader adoption remains constrained by coupled challenges related to interfacial compatibility, moisture sensitivity, environmental durability, processing limitations, and end-of-life trade-offs. Rather than treating fiber selection, matrix chemistry, processing routes, durability, and sustainability as independent considerations, this review emphasizes their interdependence through the fiber–matrix interface, which governs stress transfer, moisture transport, and long-term property evolution. It provides a comprehensive and integrative analysis of natural-fiber–reinforced polymer composites, encompassing plant-, animal-, and emerging bio-derived reinforcements combined with bio-based, biodegradable, and selected synthetic matrices. Comparative analysis across the literature demonstrates that interfacial engineering consistently dominates mechanical performance, moisture resistance, and property retention, while mediating trade-offs among stiffness, toughness, recyclability, and biodegradability. Moisture transport and environmental ageing are examined using thermodynamic and diffusion-controlled frameworks that link fiber chemistry, interfacial energetics, swelling, and debonding to performance degradation. Fire behavior and flame-retardant strategies are reviewed with attention to heat-release control and their implications for durability and circularity. Processing routes, including extrusion, injection molding, compression molding, resin transfer molding, and additive manufacturing, are assessed with respect to fiber dispersion, thermal stability, scalability, and compatibility with bio-based systems. By integrating structure–property relationships, processing science, durability mechanisms, and sustainability considerations, this review clarifies how natural-fiber biocomposites can be designed to achieve balanced performance, environmental stability, and circular life-cycle behavior, thereby providing guidance for the development of systems suitable for near-term engineering applications. Full article

To address the thermal management challenges in electronic devices, this study systematically investigates the effects of injection molding and compression molding on the microstructure and thermal conductivity of poly(vinylidene fluoride)/boron nitride nanosheet (PVDF/BNNs) composites. Using 10 μm diameter BNNs as thermal conductive fillers and PVDF as the matrix, the composites were characterized via scanning electron microscopy (SEM), thermal conductivity measurements, rheological analysis, X-ray diffraction (XRD), and mechanical tests. The results demonstrate that the strong shear stress in injection molding induces significant alignment of BNNs along the flow direction, leading to remarkable thermal conductivity anisotropy. At a PVDF/BNNs mass ratio of 90/10, the in-plane thermal conductivity of the injection-molded composite reaches 1.26 W/(m·K), while the through-plane conductivity is only 0.40 W/(m·K). In contrast, compression molding, which involves minimal shear, results in randomly dispersed BNNs and isotropic thermal conductivity, with both in-plane and through-plane values around 0.41 W/(m·K) at the same filler loading. Both processing methods preserve the coexistence of α- and β-crystalline phases in PVDF. However, injection molding enhances matrix crystallinity through stress-induced crystallization, yielding composites with higher density and superior tensile properties. Compression molding, due to slower cooling, leads to incomplete PVDF crystallization, as evidenced by a shoulder peak near 164 °C in differential scanning calorimetry (DSC) curves. This study elucidates the mechanism by which processing methods regulate the structure and properties of PVDF/BNNs composites, offering theoretical and practical guidance for designing high-performance thermally conductive materials. Full article

To address the severe wear of the hole wall and orifice in ejector pin guide holes of injection molds caused by frequent hole-shaft sliding, this study proposes a composite strengthening method that combines nitriding with oblique laser shock peening (N-OLSP). The strengthening uniformity in both circumferential and axial directions was evaluated by defining a laser shock peening uniformity coefficient ($k$). By strictly controlling the uniformity coefficient ratio of two adjacent spots to be no less than 0.98, the optimal step angles for circumferential and axial directions were determined. Comparative experiments were conducted on three types of samples: Untreated, Nitrided, and N-OLSP treated. The results demonstrate that N-OLSP significantly enhances both surface hardness and residual compressive stress of the guide hole, and the degree of improvement increases with a higher value of $k$. Among the tested samples, N-OLSP exhibited the best wear resistance at the orifice, reducing the wear rate to 0.60 μm/h. Compared with the untreated and nitrided samples, the wear rate reduction achieved by N-OLSP was 66.85% and 16.67%, respectively. Full article

The injection compression molding using dynamic mold control (ICM-DT) represents a promising technological approach to the manufacturing of highly filled, modified thermoplastic components with tight geometric tolerances. While the numerical prediction of flow states is, to date, predominantly based on the Cross–WLF modeling of viscoelastic characteristics of the melt, new material-related developments necessitate the assessment of process- and material-related boundaries. The present paper employs a highly filled graphite–polypropylene system, exhibiting a graphite mass fraction of 80%, for the quantitative comparison of Cross–WLF predictions and experimentally derived flow states. Based on coupled counter pressure-chamber high-pressure capillary rheometry (CPC-HCR) and counterpressurized viscometry (CPV) alongside the ICM-DT of thin-walled specimens, pressure-induced crystallization was identified to induce significant deviations from Cross–WLF predictions. Cross–WLF modeling strongly overestimates the processability of the applied graphite–polypropylene system under both injection molding (IM) and ICM regimes. We therefore observe a predominant influence of pressure-induced crystallization mechanisms in dynamic mold temperature process domains, in which the pressure-induced, crystallization-related exponential viscosity increase cannot be adequately modeled through both pressure-dependent and pressure-agnostic Cross–WLF models. The numerical approximation of flow states under dynamic mold temperature regimes hence necessitates the consideration of solidification-induced, self-intensifying pressure excursions. Full article

Isotactic polypropylene (iPP), solidified under high-pressure in the orthorhombic γ-form, can exhibit enhanced mechanical properties compared to iPP crystallized in the common monoclinic α-form under atmospheric pressure. The aim of the study was to enhance the mechanical performance of injection-molded iPP and its nanocomposite containing 5 wt% of multiwall carbon nanotubes (MWCNTs) through high-pressure processing, which induced the formation of the γ-phase. Initially, the materials were crystallized in a high-pressure cell. To simulate the conditions during molding, crystallization was carried out by pressurizing the molten polymer to 250 MPa. For comparison, crystallization was also performed during cooling under 200 MPa and 1.4 MPa. Subsequently, the injection molding was conducted under optimized conditions, under pressure of 250 MPa, to promote the formation of the γ-phase, and, for comparison, under 20 MPa, to favor the α-phase formation. The injection-molded nanocomposite crystallized in the γ-form, tested in compression, exhibited an elastic modulus, yield stress, and stress at break higher by approx. 50%, 35% and 40–50%, respectively, compared to injection-molded neat iPP solidified predominantly in the α-form. These results demonstrate that substantial improvements in mechanical performance can be achieved through the incorporation of MWCNTs into iPP and the optimization of high-pressure injection-molding conditions. Full article

In response to the problems encountered during the pressure-driven oil recovery process in low-permeability oil reservoirs, such as slow pressure transmission, poor liquid supply, vulnerability of the reservoir to damage, and difficulties in injection and production, in order to achieve the goal of high-quality water injection development, based on the theories of rock mechanics and seepage mechanics, combined with large-scale physical model experiments, acoustic emission crack monitoring, and microscopic scanning technology, an oil reservoir and fracture model was established to conduct a feasibility analysis of pressure-driven assisted pressure reduction and enhanced injection, and it was successfully applied in the exploration and development practice of the Shengli Oilfield. The research shows the following: (1) During the pressure-driven process, the distribution of the fracture network system is relatively limited. In the early stages of the process, there will be minor fractures, but they do not communicate or activate effectively. The improvement of physical properties and pore-throat structure is negligible. As the injection flow rate increases, the effective fracture network system begins to be established, and the range of fluid coverage begins to expand. With the progress of the pressure-driven process, the hydraulic fractures gradually extend, the number of activated original fractures gradually increases, the communication area between hydraulic fractures and original fractures gradually increases, and the reservoir modification effect gradually improves. (2) Based on the compression cracking experiment of large object molds, it is concluded that generating effective micro-cracks and activating them to form efficient diversion channels is the key to pressure flooding injection. Combining the mechanical characteristics of the rock in the target layer to precisely control the injection speed and injection pressure can maximize the fracture network, thereby improving the reservoir to achieve the purpose of pressure reduction and injection increase. (3) Different pressure flooding injection parameters were set for the low-permeability oil reservoirs in the study area to simulate the fracture network expansion. Finally, it was concluded that the optimal injection speed for fracture expansion was 1.2 m³/min and the optimal total injection volume was 20,000 m³. Through research, the mechanism of pressure-driven injection and the extent of reservoir modification caused by this pressure-driven process have been enhanced in terms of understanding. Full article

The transportation and automotive industries are slowly integrating biocomposite materials into products where the economics make sense; this typically means a short manufacturing cycle time, not using expensive prepreg, and with little waste generated from the process. In a previous investigation into the use of biocomposites for electric bus seats and backs, three different material systems (hemp, flax, and pure cellulosic fibers, each paired with a high-bio-content epoxy) and two manufacturing processes (wet layup followed by compression molding, vacuum-assisted resin transfer molding) were investigated, but neither process proved to be viable. In this paper, a relatively obscure process called Wet Compression Molding (WCM) is considered for economical production of the biocomposite bus seats using the same three material systems. Darcy’s law predictions of full impregnation time for a nominally 3.5 mm thick part using experimentally determined permeability values are all less than 2 s. Furthermore, prepreg is not used, and net-shape parts without excess resin show potential. Important design details of the WCM mold set, used in the manufacturing of flat test panels from each material system, that are generally not discussed in the literature include a high-pressure O-ring seal, and semi-permeable membranes covering injection pins and vacuum vents (evacuates trapped air) to prevent resin ingress. Biocomposite laminate specimens are fabricated using the mold set in a thermal press and a vacuum pump. Part characterization includes fiber volume fraction estimates and measurements of thickness, density, flexural modulus, and outer fiber maximum stress at failure. Due to its rapid impregnation with just enough resin, WCM should be considered for the economical manufacture of parts similar in shape and size to electric bus seats and backs. Full article

In this paper, we develop technology to improve the stability and quality of boat equipment manufacturing through vacuum injection process fusion to increase the safety of boats. Safe mold design and fabrication are carried out to determine the resin flow rate and water flow rate of a boat, and the performance of vacuum maintenance work is guaranteed through the tensile and compressive strength of the manufactured hull and deck. When manufacturing the boat air mechanism (Aerostat), the adhesion between equipment materials and the deformation of the joints are very important factors for safety. Due to the nature of equipment manufacturing, process fusion to minimize manual process minimizes deformation after manufacturing through accurate manufacturing ratio. Accordingly, it is possible to accurately control the mixing ratio of resin and hardener as optimal conditions for boat drying and securing safety, and to convert optimal information into a database by analyzing working conditions over time such as resin flow rate and flow rate, thereby improving durability and quality. Through this, it is expected that production efficiency and safety design will be improved by enabling efficient production process management with a small number of personnel. Full article

The agricultural sector faces growing pressure to enhance productivity and sustainability, prompting innovation in machinery design. Traditional materials such as steel still dominate but are a cause of increased weight, soil compaction, increased fuel consumption, and corrosion. Composite materials—and, more specifically, fiber-reinforced polymers (FRPs)—offer appealing alternatives due to their high specific strength and stiffness, corrosion resistance, and design flexibility. Meanwhile, increasing environmental awareness has triggered interest in biocomposites, which contain natural fibers (e.g., flax, hemp, straw) and/or bio-based resins (e.g., PLA, biopolyesters), aligned with circular economy principles. This review offers a comprehensive overview of synthetic composites and biocomposites for agricultural machinery and equipment (AME). It briefly presents their fundamental constituents—fibers, matrices, and fillers—and recapitulates relevant mechanical and environmental properties. Key manufacturing processes such as hand lay-up, compression molding, resin transfer molding (RTM), pultrusion, and injection molding are discussed in terms of their applicability, benefits, and limits for the manufacture of AME. Current applications in tractors, sprayers, harvesters, and planters are covered in the article, with advantages such as lightweighting, corrosion resistance, flexibility and sustainability. Challenges are also reviewed, including the cost, repairability of damage, and end-of-life (EoL) issues for composites and the moisture sensitivity, performance variation, and standardization for biocomposites. Finally, principal research needs are outlined, including material development, long-term performance testing, sustainable and scalable production, recycling, and the development of industry-specific standards. This synthesis is a practical guide for researchers, engineers, and manufacturers who want to introduce innovative material solutions for more efficient, longer lasting, and more sustainable agricultural machinery. Full article

Conventional horticultural fertilization frequently leads to nutrient loss and environmental contamination, driving interest in biodegradable controlled-release systems. This work developed soy protein isolate (SPI) matrices containing 5 wt.% FeSO₄·7H₂O using injection. The matrices were evaluated for crosslinking, mechanical properties, water uptake (WUC), soluble matter loss (SML), iron-release kinetics in water and soil, and biodegradability under composting conditions. Injection-molded samples achieved very high crosslinking with moderate rigidity and water absorption and delivered iron rapidly in water, while compression-molded samples exhibited slightly lower crosslinking but greater stiffness, higher WUC, minimal SML, and sustained iron release. Notably, both processing methods yielded comparable iron-release profiles in soil and complete biodegradation within 71 days. Overall, compression molding produces SPI-based matrices with superior mechanical strength and water retention, positioning them as an ideal solution for long-lasting, sustainable nutrient delivery in horticulture. Full article

Three-dimensional (3D) printing has become a promising alternative to conventional methods in plastic part production, particularly for customized or low-volume applications such as toys. This study compares toy components produced by Fused Deposition Modeling (FDM) using polylactic acid (PLA) and acrylonitrile butadiene styrene (ABS) filaments and those produced by traditional injection molding using ABS pellets. Unlike in many previous studies based on standardized test samples, a real toy part was evaluated in terms of compressive strength, dimensional accuracy, surface quality, and cost. Experimental results revealed that ABS parts produced by injection molding exhibited the highest compressive strength (3.93 kN), followed by PLA-FDM (2.97 kN) and ABS-FDM (0.95 kN). Similarly, injection-molded parts showed superior surface smoothness and dimensional accuracy. Cost analysis indicated that injection molding is economically viable only when production exceeds 735 pieces, while FDM becomes more attractive for smaller batches due to its low initial cost. A multi-criteria decision-making analysis using the TOPSIS method was conducted to integrate technical and economic factors. Results showed that injection molding is preferable for mass production, whereas PLA-FDM is more suitable for low-quantity, cost-sensitive scenarios. Full article

This study explores the use of Polypropylene (PP) as a cost-effective matrix in composite materials, employing marble dust (MD) as a readily available filler. PP’s affordability and suitable strength make it ideal for various applications. MD, composed of CaCO₃, alumina, and silica, enhances mechanical strength and is commonly used in construction applications like concrete. Composite specimens were fabricated using the injection molding technique, and their mechanical properties (tensile, flexural, and compressive strength) were analyzed following ASTM standards. Tribological properties were assessed through a pin-on-disc apparatus with varying MD proportions. SEM and EDS analyses visually inspected the fracture types and filler distribution in the composites. Full article

The metal injection molding (MIM) manufacturing process has made relevant advances for applications in components with complex geometries, small dimensions, and high production volumes. New technologies such as hot isostatic pressing (HIP), uniform polymer extraction, and sintering with reduced temperature variations improve metallurgical and mechanical properties. However, there are still knowledge gaps in understanding these technologies and the behavior of catalytic low-alloy steels obtained by the MIM process and cyclic applications. This study aims to analyze the behavior of Catamold 100Cr6 steel subjected to quenching and tempering heat treatment in different microhardness ranges and the effect of compressive stresses on the samples obtained by polishing using ceramic microchips. The samples were characterized using optical microscopy, scanning electron microscopy, an EDS microprobe, and X-ray diffraction and subjected to elastic return cycling and an experimental device developed to apply a 19° bending angle. The findings show a significant increase in fatigue life due to the compressive stresses (up to—430 MPa) generated by the reduction in retained austenite and surface plastic microdeformation, indicating the effectiveness of 100Cr6 Catamold steel in cyclic applications. Full article

Jute fiber-reinforced composites have become a promising alternative to synthetic fiber composites because of their favorable environmental characteristics, cost efficiency, and good mechanical properties. The present review provides a comprehensive examination of the manufacturing processes and mechanical properties of polymer composites reinforced with jute fibers. This study investigates the influence of several fabrication methods, such as hand lay-up, compression molding, injection molding, pultrusion, etc., on the mechanical properties of the composites. It also provides SWOT analyses of various manufacturing processes of jute fiber-reinforced composites. Important aspects, including fiber orientation, fiber/matrix adhesion, and the effects of different surface treatments on improving mechanical characteristics, such as tensile strength, flexural strength, and impact resistance, are discussed. The difficulties associated with moisture absorption, degradation, and the lack of uniformity in jute fibers, as well as approaches to alleviate these problems, are presented. The goal of this study is to establish a basis for future investigation and advancement in enhancing the mechanical properties of jute fiber-reinforced composites. Full article