Search Results (1,383)

The Pushbroom Imager for Cloud and Aerosol Research and Development (PICARD) visible through shortwave infrared imaging spectrometer was developed to carry a calibration laboratory environment to high altitudes, while also providing high-dynamic-range bright cloud-top radiance measurements across a field of view just under 50 degrees. The in-flight performance of this new spectroradiometer was validated in comparison to multiple reference data sources and targets using imagery collected aboard NASA’s ER-2 high-altitude aircraft during the Western Diversity Time Series (WDTS) airborne science campaign in April 2023 and the September 2024 Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) Postlaunch Airborne eXperiment (PACE-PAX), both operating out of southern California. PICARD measurements from flights over Railroad Valley Playa, Nevada, USA, were compared to high-resolution radiance spectra of the dry lakebed provided by the Radiometric Calibration Network (RadCalNet) Working Group. Direct comparison to satellite cloud radiometry was enabled by the ER-2 flying in coordination with simultaneous overpasses of the Terra, Aqua, and NOAA-20 Earth-observing satellites during WDTS and with the PACE observatory during PACE-PAX. To account for large spectral differences between incandescent laboratory sources and solar illumination, PICARD calibration relies on measurements using the Goddard Laser for Absolute Measurements of Radiance (GLAMR) to characterize and minimize spectral stray light from the instrument’s twin Offner grating spectrometers. Good agreement in comparison to reference measurements demonstrates PICARD’s ability to provide imagery for environmental science or for testing new sensor designs and retrieval algorithms for cloud and aerosol research with verified laboratory calibrations at high altitudes. Full article

Moisture content is a key quality attribute in dried areca nuts, affecting subsequent processing performance and storage stability, yet routine measurement by oven-drying is time-consuming and destructive. This study developed a rapid and non-destructive method for determining moisture content in dried areca nuts by integrating near-infrared spectroscopy with chemometric and machine learning-assisted methodologies. Various spectral preprocessing methods, feature wavelength selection algorithms, and modeling approaches were compared. The results indicated that Multiplicative Scatter Correction (MSC) most effectively eliminated physical scattering interference. The Partial Least Squares Regression (PLSR) model established using full-wavelength spectra demonstrated optimal predictive performance. It achieved a coefficient of determination for the prediction set (Rp²), root mean square error of prediction (RMSEP), and residual predictive deviation (RPD) of 0.9639, 0.1960, and 10.3461, respectively, indicating excellent predictive accuracy and robustness. Feature wavelength selection did not enhance model performance in this study, which can be attributed to the broad absorption bands of water in the near-infrared spectrum and its complex interactions with the sample matrix where the full spectrum data retains essential information more comprehensively. This research provides a reliable and practical technical means for moisture management in areca nuts, offering important support for quality assurance and standardized production practices within the areca industry. Full article

Background: Beets are enriched in bioactive compounds with beneficial effects on cardiovascular function. Nitrate is a precursor for nitric oxide synthesis, exhibiting an effect on cardiomyocytes and myocardial ischemia/reperfusion, improving endothelial function and reducing arterial stiffness. Betanin, saponins and phenolic compounds, other beet compounds, can limit the generation of reactive oxygen species and modulate gene expression. However, it has been a challenge to develop beetroot formulations for the oral administration of these compounds while preserving pleasant sensory characteristics. Objective: The objective of this study was to develop an innovative dairy–beetroot powder drink, microencapsulated in polysaccharides, i.e., maltodextrin, cassava starch or a combination of both, that could be easily reconstituted. Key Results: The microencapsulated formulation following freeze-drying displayed low water activity (<0.30) and high solubility (>90%), with rapid dispersion in aqueous medium. Fourier transform infrared spectroscopy confirmed the preservation of functional groups from the dairy base and sugar beetroots. Thermogravimetry analyses pointed out a slight increase in thermal stability for the powder formulation. The microencapsulation efficiency of betalains reached 81% in the powder formulation that combined cassava starch and maltodextrin as encapsulation agents. The novel dairy–beetroot powder drink can be stored at room temperature, ensuring microbiological safety and preserving good sensory acceptance. Conclusions: Dairy–beetroot powder microcapsules emerge as an efficient food strategy to provide bioaccessible dietary nitrate and antioxidant compounds, overcoming flavor and stability limitations but still aiding in terms of its vascular and hemodynamic-protective effects. Full article

Background/Objectives: Enteric drug forms are developed to delay drug release to avoid drug degradation in the acidic environment of the stomach or to prevent irritation of the stomach mucosa. The bioavailability of posaconazole (POS) after oral administration depends on stomach pH and food intake. Delayed-release tablets and unmodified oral suspension are the POS formulations currently available on the market. The oral suspension formulation is characterized by highly variable bioavailability, which may significantly affect therapy effectiveness. Methods: In this study, multi-unit drug forms with delayed and sustained POS release were designed. Polymeric microparticles consisting of sodium alginate (ALG), methacrylic acid–ethyl acrylate copolymer (EUD), or both, were prepared using the spray-drying technique. The formulations that met the pharmacopoeia enteric release standards in the in vitro dissolution test were subjected to further in vitro evaluation via swelling and mucoadhesion assays, an antifungal activity test, attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR), and thermal analysis. Results: It was shown that EUD formulations at concentrations of 5% and 6% provided enteric release, whereas ALG at 1.5% concentration exhibited a sustained, although not delayed, POS release profile. The optimal blended formulations (EAP15–EAP18), comprising 4% EUD with 1.5–2.0% ALG and either 1% or 4% POS, met the pharmacopoeia criteria for enteric dosage forms. Furthermore, these blends demonstrated the most favorable sustained-release profiles in the buffer phase, ranging from 2 to 3 h. The microparticles exhibited beneficial swelling and mucoadhesive properties, which are essential for prolonging contact with the intestinal mucosa; combined with antifungal properties. Conclusions: Obtained carrier may provide a promising preliminary basis for developing a multi-unit, sustained-release enteric dosage form for POS and future in vivo investigations. Full article

The Amazonian açaí waste is promising for producing charcoal through pyrolysis and bioenergy through combustion, but the property losses from its poor disposal in the environment remain unknown. Therefore, this work aimed to analyze how different storage conditions of the açaí waste over time, which mimic the reality throughout the Amazon, modify its bioenergetic properties. The samples were stored in a covered greenhouse for nine months in the following conditions: immersed in water, on the soil, and in open plastic bags. The biomass was analyzed by Fourier-transformed near-infrared spectroscopy, physical properties, stereomicroscopy, proximate composition, and thermogravimetry. The degraded waste showed endocarp attack and fungi proliferation. The chemical groups of primary cell wall components were concentrated, unlike water-soluble materials, raising the fixed carbon from 22% to 25% after 30 days. Consequently, higher heating values were kept (≈19 MJ/kg). However, water immersion storage sharply decreased the waste basic density from 0.81 g/cm³ to 0.56 g/cm³, dropping the energy density from 12 GJ/m³ to 8 GJ/m³. Moreover, storage raised ash content from 1.1% up to 1.9%. The storage hindered the start of the main phases of combustion and pyrolysis, which were later intensified, especially for soil-stored waste. Therefore, more stable combustion and pyrolysis require fresh waste. Besides natural drying, plastic bag storage over time kept the waste quality closer to that of the fresh waste. Full article

With the growing trend toward insulator hybridization, higher requirements are imposed on the synergistic improvement of interfacial durability and pollution flashover performance. Machining annular grooves at the green-body stage and embedding silicone rubber enables the construction of an embedded structure with improved durability, forming hydrophilic/hydrophobic alternating surfaces. However, the outdoor insulation characteristics of such hybrid surfaces remain insufficiently investigated, and their engineering feasibility requires further validation. In this study, a series of hydrophilic/hydrophobic alternating surfaces were fabricated, and artificial pollution tests were conducted. The results show that the AC pollution flashover voltage exhibits a saturated increasing trend as the hydrophobic interfaces become more dispersed. When twenty 4 mm wide hydrophobic interfaces were distributed along a 16 cm creepage distance, the flashover voltage was 12.4% higher than that of a fully hydrophobic surface. These results indicate that appropriate design of hydrophobic interface distribution can achieve excellent pollution flashover performance even at relatively low hydrophobic coverage (≤50%). High-speed imaging combined with infrared thermography reveals the discharge mechanism governed by hydrophobic interface distribution from an electro–thermal coupling perspective. The coexistence of multiple dry bands induced by discrete hydrophobic interfaces is identified as the key factor enhancing flashover withstand capability. A static pollution flashover model was established to quantitatively estimate the AC flashover voltage, confirming the external insulation feasibility of the embedded hybrid concept. Full article

The growing demand for sustainable agriculture requires strategies that simultaneously recover soil quality, improve crop yield, and add value to food products. This study evaluates walnut shell biochar (450 °C) as a circular amendment applied at 0, 10, and 20 t ha⁻¹ to an arid soil cultivated with pea (Pisum sativum L. cv. Onward) in San Juan, Argentina. Biochar enhanced soil porosity, respiration, organic carbon, and cation exchange capacity, resulting in higher plant biomass and a 30.9% increase in pod yield for the 20 t ha⁻¹ treatment. Pea grains were dehydrated by far-infrared drying at 70 °C, producing flour with improved lipid content, water absorption, and swelling capacity, which increased from 0.21 to 0.26 mL g⁻¹ under the 20 t ha⁻¹ treatment. The combined use of biochar and controlled drying highlights a viable pathway to close the soil–plant–food loop through resource valorization. This work contributes practical evidence of biochar’s multifunctional role in sustainable agri-food systems, aligned with circular economy principles. Full article

This study explored the feasibility of near-infrared (NIR) spectroscopy for detecting total water, free water and bound water in carrot slices during freeze-drying, with low-field nuclear magnetic resonance (LF-NMR) characterizing water state distribution and oven-drying determining moisture content (MC). NIR spectra (10,000–4000 cm⁻¹) were processed via optimized sample partitioning, preprocessing and feature extraction; partial least squares regression (PLSR), support vector regression (SVR), back-propagation artificial neural network (BPANN), extreme gradient boosting (XGBoost) and particle swarm optimization–random forest (PSO-RF) models were established and evaluated. Results showed that SVR and BPANN performed robustly, with CARS being the optimal feature extraction method. The full-moisture system achieved high total/free water prediction accuracy ($R_p^2$ = 0.9902/0.9740), while the low-moisture system improved bound water prediction ($R_p^2$ = 0.9709). The established NIR models exhibited excellent fitting and generalization ability, enabling rapid and non-destructive quantitative prediction of moisture content during carrot freeze-drying. Full article

This study systematically investigated the combined effects of drying method (mid- and short-wave infrared drying, MSID; hot air drying, HAD; radio frequency-hot air combined drying, RF-HAD), drying temperature (35, 45, 55, 60 °C), and initial wet-basis moisture content (20%, 25%, 30%) on drying characteristics, nutritional quality, texture, and oxidative stability of peanuts. RF-HAD achieved the shortest drying time, followed by MSID and HAD. Protein content remained stable across all treatments. Fat, oleic acid, and total amino acids were significantly affected by all three factors with significant two-way interactions; linoleic acid exhibited significant method × moisture and three-way interactions. Hardness, adhesiveness, springiness, gumminess, and chewiness showed significant three-way interactions, indicating interdependent effects. All samples met national standards for acid value and peroxide value. MSID yielded the lowest acid value and peroxide value immediately after drying, suggesting better initial oxidative quality. Acid value was primarily influenced by method and temperature, with significant two-way interactions, whereas peroxide value showed significant main effects and a highly significant three-way interaction. No single drying condition optimized all quality attributes. RF-HAD excels in drying efficiency and texture enhancement but requires temperature control to limit oxidation; MSID offers superior initial oxidative stability and amino acid retention. Initial moisture content acts as an active variable that modulates the effects of drying method and temperature. Full article

As the demand for sustainable and bio-based alternatives to petroleum-derived membranes grows, polysaccharides have emerged as promising candidates. In this study, we fabricated free-standing membranes from konjac glucomannan (KGM), a neutral polysaccharide, using a simple base-induced insolubilization process. Fourier transform infrared spectroscopy revealed that the deacetylation of KGM chains promotes extensive intermolecular hydrogen bonding, creating a robust and stable three-dimensional network without the need for chemical cross-linkers. The resulting KGM free-standing membranes exhibited excellent mechanical properties, characterized by high tensile strength in the dry state and remarkable flexibility when hydrated. Furthermore, the membranes demonstrated superior chemical resistance to organic solvents such as acetone and n-hexane. Transport studies showed that the membranes possess a highly dense structure with no detectable pressure-driven pure-water permeation up to 0.25 MPa. Solute permeation experiments using eight model molecules (molecular weight = 144–14,600 Da) indicated that transport behavior is consistent with diffusion through a hydrated polymer network. The effective diffusion coefficient D_eff showed a strong correlation with molecular weight M, following the relationship D_eff ∝ M^−1.7. Furthermore, the permeation behavior remained stable across a wide pH range (2–12), and, within the investigated range of monovalent solutes, D_eff was insensitive to solute charge, indicating that mass transport is dominated by size-based diffusion rather than electrostatic interactions. These findings suggest that KGM free-standing membranes enable reliable molecular fractionation based on size-dependent diffusion within a stable, neutral matrix, offering significant potential for sustainable separation technologies and biomedical applications. Full article

To clarify the effect of surface characteristics on the interfacial properties of T1100-grade carbon fiber (CF)/bismaleimide (BMI) composites, three CFs (F1, F2, and F3) with different surface treatments and sizing agents were studied. Surface physicochemical properties and sizing–resin reaction behavior were characterized; nano-infrared spectroscopy was innovatively used to quantify interfacial structure. The correlation among surface features, interfacial structure, and mechanical properties was established. All dry-jet wet-spun T1100 CFs show smooth surfaces with similar roughness, and mechanical interlocking contributes little to interfacial adhesion. F3 possesses the highest active carbon, oxygen content, and epoxy value. Its sizing agent exhibits strong reactivity with BMI, forming a ~200 nm thick interface and the highest interfacial shear strength (IFSS) of 95.9 MPa. Constructing a “thick and strong” interface promotes shear failure from brittle to tough, significantly enhancing 90° tensile and interlaminar shear strength (ILSS). This work provides guidance for interface design and engineering applications of T1100/BMI composites in aerospace primary load-bearing structures. Full article

Moringa oleifera leaves are recognized as a nutrient-dense plant material of compositional and nutritional interest. This study aimed to characterize the nutritional and physicochemical properties of M. oleifera dried leaves through nutritional assessment and spectroscopic fingerprinting. Amino acid profiling, antioxidant activity assessment using ferric reducing antioxidant power (FRAP), 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), and oxygen radical absorbance capacity (ORAC) assays, chromatographic analysis of organic acids and sugars, color measurement, techno-functional characterization, and vibrational spectroscopy including Fourier Transform infrared with attenuated total reflectance (FT-IR/ATR) and Raman were employed. The crude protein content was 16.13 ± 0.43%. Moringa leaves contained all essential amino acids, with notably high tryptophan content (amino acid score, AAS = 200.00%). The amino acids limiting the nutritional value of the protein were primarily sulfur-containing amino acids (AAS = 49.57%) and lysine (AAS = 49.79%). Histidine, leucine, and valine also showed levels below the reference protein. Antioxidant activity exhibited solvent-dependent patterns: the 80% ethanolic extract demonstrated significantly higher FRAP activity (27.05 ± 1.05 mg Trolox Equivalent (TxE)/g dry matter (DM)) and ORAC values (107.24 ± 6.80 mg TxE/g DM), while no statistically significant differences between extracts were observed for DPPH, ABTS, or total phenolic content. Chromatographic profiling identified fructose and glucose as the predominant sugars, alongside citric, succinic, lactic, and acetic acids. The leaves exhibited favorable techno-functional properties, including high water holding capacity and water solubility index. Spectroscopic analysis revealed bands consistent with proteins, lipids, carbohydrates, and glycoside-related structures, while the preserved green-yellow coloration (hue angle 101.68°) indicated retention of pigment-related features during processing. These findings provide compositional and physicochemical characteristics of Moringa leaves relevant to their evaluation as a plant-derived food material. Full article

Parboiling enhances the nutritional, structural, and economic value of rice, yet its adoption in the United States remains limited despite rising domestic and export demand. This review summarizes key stages of the parboiling process and their effects on milling yield, grain integrity, nutrient retention, and glycemic response. It outlines major industry challenges, including high energy and water use, uneven heating and drying, handling of defective kernels, limited automation in smaller mills, labor shortages, and emerging climate-related risks. Advances such as vacuum soaking, infrared and microwave-assisted drying, smart sensors, and AI-driven control systems show strong potential to improve efficiency and product quality. Circular-economy strategies, including biomass energy recovery, water reuse, and by-product valorization, offer additional sustainability gains. Continued research, modernization, and policy support are critical to strengthen competitiveness and positioning of the U.S. parboiled rice sector for a more resilient and sustainable future. Full article

The concepts of food matrix and holistic analysis have been used in a wide range of scientific disciplines to describe the sum of the parts of a whole that provide a specific property or functionality to the sample. Traditional chemical and physical analysis needs to destroy the sample (e.g., dilution, extraction, drying) before analysis. The utilization of vibrational spectroscopy techniques, like near (NIR), mid infrared (MIR) and Raman spectroscopy, allows for the non-destructive analysis of food ingredients and products. The resulting output of this analysis is based on the information provided by the vibrational modes of atoms present in the different molecules, allowing the measurement of different chemical and physical characteristics of the food. The objective of this paper is to discuss the ability of vibrational spectroscopy methods to provide robust tools to analyze the food matrix holistically, moving away from the traditional analysis of individual compounds or chemical parameters. Studies discussed and presented in this review demonstrated the ability of vibrational spectroscopy (e.g., NIR, MIR and Raman spectroscopy, hyperspectral imaging) to assess the whole food matrix beyond the traditional notion of developing a calibration model. Full article

Natural deep eutectic solvents (NADESs) have emerged as promising green alternatives to conventional solvents for the extraction of bioactive compounds from plant materials. In this study, eight natural deep eutectic solvents were synthesized and evaluated for their efficiency in extracting betulin from birch bark. Extraction yield was assessed using high-performance liquid chromatography with ultraviolet detection. Among the tested systems, N3 (choline chloride and urea in a 1:1 molar) and N4 (choline chloride and fructose in a 1:1 molar) were the most effective, yielding 101.26 ± 0.03 and 243.32 ± 0.26 mg betulin per gram of dry extract, respectively. Fourier transform infrared spectroscopy analysis confirmed the structural similarity of the N4 extract to pure betulin. In addition to increased extraction performance, the N4 extract demonstrated the greatest antioxidant activity (DPPH (1,1-diphenyl-2-picrylhydrazyl): 63% and ABTS (2,2′-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid)): 97% inhibition) and total phenolic content (12.12 mg GAE/g extract), and betulin yield was strongly correlated with total phenolic content (TPC) and antioxidant activity (FRAP (ferric ion reducing antioxidant power), DPPH, and ABTS), indicating the preservation of bioactivity. These findings underscore the potential of NADESs as sustainable solvents for the extraction of bioactive compounds from birch bark, supporting greener extraction technologies for biomass valorization and natural product processing. Full article