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19 pages, 5998 KB  
Article
Comparative Study of Nanostructured Multilayer Cr/(Cr/a-C)ml Coatings Deposited on HS6-5-2 Steel by Magnetron Sputtering
by Rayna Dimitrova, Krum Petrov, Yavor Sofronov, Valentin Mishev, Milko Angelov, Boriana Tzaneva, Boyan Dochev, Antonio Nikolov, Milko Yordanov and Krassimir Marchev
Materials 2026, 19(6), 1073; https://doi.org/10.3390/ma19061073 - 11 Mar 2026
Viewed by 107
Abstract
Comparative analysis of nanostructured multilayer Cr/(Cr/a-C)ml coatings on HS6-5-2 steel was carried out. The coatings were deposited at various chromium target power values using PVD technology, particularly the magnetron sputtering method. The effect of different technological regimes on the properties of the nanostructured [...] Read more.
Comparative analysis of nanostructured multilayer Cr/(Cr/a-C)ml coatings on HS6-5-2 steel was carried out. The coatings were deposited at various chromium target power values using PVD technology, particularly the magnetron sputtering method. The effect of different technological regimes on the properties of the nanostructured multilayer Cr/(Cr/a-C)ml coatings was studied. Identical characterization methods were used for the three types of coatings obtained. Cross-sections of the coated samples were prepared in order to directly determine the thickness of the resulting coatings, their uniformity, and the presence of defects or imperfections, both at the substrate–coating interface and within the coatings themselves. Calotest and Daimler-Benz adhesion test were also performed to evaluate the coated layers’ thickness and evaluate their adhesion strength. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) analyses were carried out to define the chemical composition of the multilayered coatings. To evaluate the hardness and modulus of elasticity of the resulting coatings, nanoindentation measurements were also conducted. The data obtained under the three different deposition regimes were analyzed and compared, which allowed us to assess the influence of the chromium target power during the deposition process on the properties of the obtained coatings. Full article
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28 pages, 6121 KB  
Article
Numerical Investigation on the Axial Behavior and Confinement Effect of Concrete-Filled Steel Tube Stub Columns
by Yao Wang, Shufeng Zhang, Feng Zhang, Minjie Tu, Hongguang Xu and Dong Li
Buildings 2026, 16(5), 990; https://doi.org/10.3390/buildings16050990 - 3 Mar 2026
Viewed by 186
Abstract
Concrete-filled steel tubes (CFST) exhibit superior axial performance compared with hollow steel tubes due to the confinement interaction between steel and concrete. Understanding how geometric and material parameters influence this enhancement is essential for rational composite design. In this study, a three-dimensional finite [...] Read more.
Concrete-filled steel tubes (CFST) exhibit superior axial performance compared with hollow steel tubes due to the confinement interaction between steel and concrete. Understanding how geometric and material parameters influence this enhancement is essential for rational composite design. In this study, a three-dimensional finite element model is developed in ABAQUS to investigate the monotonic axial behavior of steel tube stub columns with and without concrete infill. The model incorporates geometric imperfections, nonlinear constitutive laws, and a contact-based steel–concrete interface, and is validated against published experimental results. A parametric study is then conducted by varying the diameter-to-thickness ratio, steel yield strength, and concrete infill condition. The axial load–displacement responses, stress evolution, and damage development are examined, and two quantitative indices are introduced to evaluate performance: the load enhancement factor associated with concrete confinement and the deformation capacity ratio. The results show that concrete infill significantly improves axial capacity and deformation stability, while the effectiveness of confinement decreases with increasing section slenderness. Higher steel strength increases peak load but alters the post-peak response depending on tube thickness. The findings provide numerical evidence for optimizing tube geometry and material combinations in CFST stub columns under axial compression. Full article
(This article belongs to the Section Building Structures)
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23 pages, 2589 KB  
Article
Design and Simulation-Based Validation of an Embedded Acquisition Architecture for In Situ PCB Integrity Monitoring in Biomedical Devices
by Filippo Laganà
Electronics 2026, 15(4), 833; https://doi.org/10.3390/electronics15040833 - 15 Feb 2026
Cited by 2 | Viewed by 435
Abstract
The reliability of biomedical devices is closely linked to the quality and long-term stability of the electronic circuits that support their operation. Printed circuit boards (PCBs), in particular, can be affected by manufacturing imperfections, thermal stress and progressive ageing, which may lead to [...] Read more.
The reliability of biomedical devices is closely linked to the quality and long-term stability of the electronic circuits that support their operation. Printed circuit boards (PCBs), in particular, can be affected by manufacturing imperfections, thermal stress and progressive ageing, which may lead to failures during the device life cycle. In this study, we present the design and simulation-based validation of an embedded acquisition circuit aimed at monitoring PCB electrical integrity in a non-invasive and remote manner. The presented solution is based on Hall-effect current sensing combined with a 16-bit analog-to-digital conversion stage and a digital communication interface managed by a Raspberry Pi. This configuration allows the system not only to acquire integrity-related electrical signals but also to process them locally and transmit them wirelessly for supervision purposes. A lightweight artificial intelligence model is implemented directly on the embedded platform to analyse the acquired signals and to classify different PCB operating conditions in real time. Simulation results show that the system is able to identify small current variations caused by micro-discontinuities and abnormal conductive paths. The classification accuracy exceeds 97% for PCB integrity states, confirming the suitability of the approach for remote monitoring, predictive maintenance and safety support in electromedical devices. Full article
(This article belongs to the Special Issue Circuit Design for Embedded Systems)
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29 pages, 2740 KB  
Article
An HCI-Centered Experiences of ICT Integration and Its Impact on Professional Competencies Supporting Formative Assessment in Higher Education e-Learning
by Abdelaziz Boumahdi, Fadwa Ammari and Mohammed Ammari
Multimodal Technol. Interact. 2026, 10(2), 14; https://doi.org/10.3390/mti10020014 - 2 Feb 2026
Viewed by 518
Abstract
As universities expand their e-learning systems, it becomes increasingly important to understand how the use of information and communication technologies (ICTs) changes the skills needed for effective formative assessment. This study uses the principles of human–computer interaction (HCI) to create a framework for [...] Read more.
As universities expand their e-learning systems, it becomes increasingly important to understand how the use of information and communication technologies (ICTs) changes the skills needed for effective formative assessment. This study uses the principles of human–computer interaction (HCI) to create a framework for examining how digital tools, interfaces, and modes of interaction influence the way teachers assess students in higher education. The research relies on the information provided by 115 Mohammed V University teachers, who filled out a competency-based assessment grid regarding online assessment practices. The results remain exploratory and context-dependent and do not make claims of statistical representativeness beyond the studied institutional context. The findings attest to the virtues of digital technology in improving methodological and techno-pedagogical skills, without excluding the existence of serious shortcomings in semio-ethical and evaluative skills. It is certainly useful to leverage feedback to correct imperfections in evaluation practices and make them more responsive to digital interfaces. It is becoming imperative to rethink professional skills as the regulatory halo of the online formative assessment system, in order to evaluate a more synergistic framework that can give better visibility to virtual classrooms. Full article
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30 pages, 22347 KB  
Article
Enhancing V2V Communication by Parsimoniously Leveraging V2N2V Path in Connected Vehicles
by Songmu Heo, Yoo-Seung Song, Seungmo Kang and Hyogon Kim
Sensors 2026, 26(3), 819; https://doi.org/10.3390/s26030819 - 26 Jan 2026
Viewed by 292
Abstract
The rapid proliferation of connected vehicles equipped with both Vehicle-to-Vehicle (V2V) sidelink and cellular interfaces creates new opportunities for real-time vehicular applications, yet achieving ultra-reliable communication without prohibitive cellular costs remains challenging. This paper addresses reliable inter-vehicle video streaming for safety-critical applications such [...] Read more.
The rapid proliferation of connected vehicles equipped with both Vehicle-to-Vehicle (V2V) sidelink and cellular interfaces creates new opportunities for real-time vehicular applications, yet achieving ultra-reliable communication without prohibitive cellular costs remains challenging. This paper addresses reliable inter-vehicle video streaming for safety-critical applications such as See-Through for Passing and Obstructed View Assist, which require stringent Service Level Objectives (SLOs) of 50 ms latency with 99% reliability. Through measurements in Seoul urban environments, we characterize the complementary nature of V2V and Vehicle-to-Network-to-Vehicle (V2N2V) paths: V2V provides ultra-low latency (mean 2.99 ms) but imperfect reliability (95.77%), while V2N2V achieves perfect reliability but exhibits high latency variability (P99: 120.33 ms in centralized routing) that violates target SLOs. We propose a hybrid framework that exploits V2V as the primary path while selectively retransmitting only lost packets via V2N2V. The key innovation is a dual loss detection mechanism combining gap-based and timeout-based triggers leveraging Real-Time Protocol (RTP) headers for both immediate response and comprehensive coverage. Trace-driven simulation demonstrates that the proposed framework achieves a 99.96% packet reception rate and 99.71% frame playback ratio, approaching lossless transmission while maintaining cellular utilization at only 5.54%, which is merely 0.84 percentage points above the V2V loss rate. This represents a 7× cost reduction versus PLR Switching (4.2 GB vs. 28 GB monthly) while reducing video stalls by 10×. These results demonstrate that packet-level selective redundancy enables cost-effective ultra-reliable V2X communication at scale. Full article
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13 pages, 2036 KB  
Review
Defect Physics and Nanoscale Passivation Strategies in BaSi2 Thin-Film Photovoltaics
by Xiqiu Wang, Yehua Tang, Kaitao Xin, Liping Pan and Weiping Lu
Nanomaterials 2025, 15(23), 1750; https://doi.org/10.3390/nano15231750 - 21 Nov 2025
Viewed by 613
Abstract
Barium disilicide (BaSi2) was identified as a promising silicon-based photovoltaic absorber due to its near-optimal bandgap, strong optical absorption, and earth-abundant composition. However, the performance of BaSi2 thin-film solar cells was severely restricted by structural defects and interfacial instabilities that [...] Read more.
Barium disilicide (BaSi2) was identified as a promising silicon-based photovoltaic absorber due to its near-optimal bandgap, strong optical absorption, and earth-abundant composition. However, the performance of BaSi2 thin-film solar cells was severely restricted by structural defects and interfacial instabilities that introduced localized electronic states and facilitated non-radiative recombination. These imperfections degraded carrier lifetime, mobility, and open-circuit voltage. This review systematically examined the formation, energetics, and electronic roles of intrinsic and extrinsic defects in BaSi2 thin films, and evaluated nanoscale passivation strategies developed to mitigate defect-induced losses. Chemical, dielectric, and interfacial approaches were critically analyzed with emphasis on their underlying mechanisms, limitations, and integration potential. The convergence of in situ characterization, first-principles modeling, and data-driven process optimization was expected to enable predictive defect control and rational interface design, thereby advancing BaSi2-based photovoltaics toward practical implementation. Full article
(This article belongs to the Section Physical Chemistry at Nanoscale)
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18 pages, 5697 KB  
Article
Stability Analysis of Basic Load-Bearing Units in Independent Scaffolding Systems
by Xingyu Song, Ingwe Lusekelo Henry, Yan Liu, Jun Hao, Xiaolun Hu and Lingkun Chen
Buildings 2025, 15(22), 4190; https://doi.org/10.3390/buildings15224190 - 19 Nov 2025
Viewed by 471
Abstract
Scaffolds, as temporary structural support systems in civil engineering, play an essential role during construction. Independent steel scaffold systems, typically composed of assembled steel tubes, can be erected and function as standalone supports without mutual interference. This feature offers notable advantages over conventional [...] Read more.
Scaffolds, as temporary structural support systems in civil engineering, play an essential role during construction. Independent steel scaffold systems, typically composed of assembled steel tubes, can be erected and function as standalone supports without mutual interference. This feature offers notable advantages over conventional scaffolding, including easier dismantling and higher reusability efficiency. However, the absence of specific design and construction codes for this type of scaffolding has hindered its broader application, underscoring the need for further research into its structural reliability. This study investigates the stability of basic load-bearing units in independent scaffolding through vertical loading tests on three specimens with varying heights and end conditions. The failure modes of the specimens are systematically compared, and the load-transfer mechanism and mechanical behavior of the scaffold units are analyzed. Experimental results, validated against ABAQUS finite element simulations, reveal that the critical region under axial compression lies at the junction between the inner and outer tubes. As specimen height increases, a plastic hinge develops in this region under load. In shorter specimens, the inner and outer tubes interact in a nearly fixed-end condition, without failure of the connecting pins. All three specimens failed by instability, and reducing the specimen height significantly enhanced the load-bearing capacity. When the top of the specimen is pin-supported, the material’s compressive strength is not fully utilized. To improve the axial stability of independent scaffolding, several structural improvements are proposed: replacing the pinned top with a plate-supported end to enhance compressive stability; integrating transverse bracing at the ends to connect individual units into an integrated system, thereby improving overall stability without compromising spatial flexibility; and applying mechanical reinforcement with external collars at the inner–outer tube interface to increase local bending stiffness and reduce initial imperfection, thus strengthening the global buckling resistance of the independent scaffolding system. Full article
(This article belongs to the Section Building Structures)
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20 pages, 3141 KB  
Article
Solid Lubricants for the Wheel–Rail Interface: Practical Experience and Computational Estimation of Their Effects
by Tomáš Michálek, Petr Voltr, Stanislava Liberová and Jiří Šlapák
Machines 2025, 13(11), 1041; https://doi.org/10.3390/machines13111041 - 11 Nov 2025
Viewed by 754
Abstract
This paper deals with solid lubricants for the wheel–rail interface; the topic is viewed from two different but complementary perspectives. By means of simulations, the potential contribution of these lubricants, applied for purposes of wheel flange lubrication on curved tracks, to the reduction [...] Read more.
This paper deals with solid lubricants for the wheel–rail interface; the topic is viewed from two different but complementary perspectives. By means of simulations, the potential contribution of these lubricants, applied for purposes of wheel flange lubrication on curved tracks, to the reduction in the wheel–rail wear level is estimated. Further, the relationship between frictional work in wheel–rail contact and guiding forces is investigated. The aim of this paper is to contribute to the knowledge of a physical basis for this relationship and to help understand the capability of these quantities to quantify the damaging effects of running vehicles on curved tracks. The mechanism of the observed increase in quasi-static guiding force on the leading wheel with lubricated wheel flanges is described in detail, using different quantities characterizing the steady running of a vehicle through a curve. The limitation of the contribution of wheel flange lubrication to the reduction in total frictional power on all wheels of the vehicle is also explained. In the second part, attention is paid to a practical assessment of the performance of solid lubricant samples using the testing methodology of the European standards EN 15427-2-1 and EN 16028. The aim of this part of the paper is to summarize the authors’ experience with twin-disc machine measurements, showing imperfections in the standardized testing methodology, as well as the significantly different performance of various solid lubricant samples, which is influenced by many factors. Based on their experience, further research on solid lubricant performance using wheel–rail roller rigs is outlined. Full article
(This article belongs to the Section Friction and Tribology)
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19 pages, 999 KB  
Review
Real-Time Rail Electrification Systems Monitoring: A Review of Technologies
by Jose A. Sainz-Aja, João Pombo, Jordan Brant, Pedro Antunes, José M. Rebelo, José Santos and Diego Ferreño
Sensors 2025, 25(21), 6625; https://doi.org/10.3390/s25216625 - 28 Oct 2025
Cited by 1 | Viewed by 1539
Abstract
Most electrified railway networks are powered through a pantograph–overhead contact line (OCL) interface to ensure safe and reliable operation. The OCL is one of the most vulnerable components of the train traction power system as it is subjected to multiple impacts from the [...] Read more.
Most electrified railway networks are powered through a pantograph–overhead contact line (OCL) interface to ensure safe and reliable operation. The OCL is one of the most vulnerable components of the train traction power system as it is subjected to multiple impacts from the pantographs and to unpredictable environmental conditions. Wear, mounting imperfections, contact incidents, weather conditions, and inadequate maintenance lead to increased degradation of the pantograph–OCL current collection performance, causing degradation on contacting elements and assets failure. Incidents involving the pantograph–OCL system are significant sources of traffic disruption and train delays, e.g., Network Rail statistics show that, on average, delays due to OCL failures are 2500 h per year. In recent years, maintenance strategies have evolved significantly with improvements in technology and the increased interest in using real-time and historical data in decision support. This has led to an expansion in sensing systems for structures, vehicles, and machinery. The railway industry is currently investing in condition monitoring (CM) technologies in order to achieve lower failure rates and increase the availability, reliability, and safety of the railway service. This work presents a comprehensive review of the current CM systems for the pantograph–OCL, including their advantages and disadvantages, and outlines future trends in this area. Full article
(This article belongs to the Section Fault Diagnosis & Sensors)
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18 pages, 4462 KB  
Article
Finite Element Modelling Approaches for Assessing Column Stability in Heritage Structures: A Case Study of the Mosque–Cathedral of Córdoba
by Maria-Victoria Requena-Garcia-Cruz, Jose-Carlos Gómez-Sánchez, Isabel Gónzalez-de-León and Antonio Morales-Esteban
Modelling 2025, 6(4), 130; https://doi.org/10.3390/modelling6040130 - 16 Oct 2025
Viewed by 1024
Abstract
This study has investigated the structural and seismic performance of monolithic stone columns in the historical Mosque–Cathedral of Córdoba, with a focus on the earliest section constructed during the reign of Abd al-Rahman I (VIII century). An advanced 3D finite element (FE) model [...] Read more.
This study has investigated the structural and seismic performance of monolithic stone columns in the historical Mosque–Cathedral of Córdoba, with a focus on the earliest section constructed during the reign of Abd al-Rahman I (VIII century). An advanced 3D finite element (FE) model has been developed to assess the effects of geometric imperfections and component interactions on the stability of columns under both vertical and horizontal static loading. Three distinct modelling strategies have been employed in OpenSees 3.7.1, incorporating column inclination and contact elements to simulate mortar interfaces. Material properties have been calibrated using experimental data and in situ observations. The gravitational analysis has shown no significant damage in any of the configurations, aligning with the observed undamaged state of the structure. Conversely, horizontal analyses have revealed that tensile damage has predominantly occurred at the lower shaft. The inclusion of contact elements has led to a significant reduction in lateral resistance, highlighting the importance of accounting for friction and interface behaviour. Column inclination has been found to have a significant influence on failure patterns. These findings have highlighted the critical role of detailed modelling in evaluating structural vulnerabilities. Such features are generally included in the numerical modelling and evaluation of heritage buildings. Consequently, they can contribute to a better understanding of the seismic behaviour of historic masonry structures. Full article
(This article belongs to the Section Modelling in Engineering Structures)
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15 pages, 385 KB  
Article
Influence of Flexoelectric Coupling and Interfacial Imperfection on Shear Horizontal Wave Propagation in a Piezoflexoelectric Layer over an Elastic Substrate
by Ayman Alneamy, Kulandhaivel Hemalatha and Mohammed Tharwan
Mathematics 2025, 13(18), 2915; https://doi.org/10.3390/math13182915 - 9 Sep 2025
Cited by 1 | Viewed by 834
Abstract
This study analytically investigates shear horizontal (SH) wave propagation in a layered structure consisting of a piezoflexoelectric (PFE) layer bonded to an elastic substrate, considering an imperfect interface. A frequency equation is derived by applying appropriate boundary and interfacial conditions, capturing the effects [...] Read more.
This study analytically investigates shear horizontal (SH) wave propagation in a layered structure consisting of a piezoflexoelectric (PFE) layer bonded to an elastic substrate, considering an imperfect interface. A frequency equation is derived by applying appropriate boundary and interfacial conditions, capturing the effects of flexoelectric coupling, interface imperfections, the layer thickness, and the material properties. The resulting dispersion relation reveals that both interface imperfections and the flexoelectric strength significantly alter the phase velocity of SH waves. Numerical simulations show that increasing flexoelectric coefficients or interface imperfections lead to notable changes in dispersion behavior. Comparative analyses under electrically open (EO)- and electrically short (ES)-circuited boundary conditions demonstrate their impacts on wave propagation. These findings offer new insights into the design and analysis of piezoflexoelectric devices with realistic interface conditions. Full article
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18 pages, 1519 KB  
Article
Static and Vibration Analysis of Imperfect Thermoelastic Laminated Plates on a Winkler Foundation
by Jiahuan Liu, Yunying Zhou, Yipei Meng, Hong Mei, Zhijie Yue and Yan Liu
Materials 2025, 18(15), 3514; https://doi.org/10.3390/ma18153514 - 26 Jul 2025
Cited by 1 | Viewed by 608
Abstract
This study introduces an analytical framework that integrates the state-space method with generalized thermoelasticity theory to obtain exact solutions for the static and dynamic behaviors of laminated plates featuring imperfect interfaces and resting on a Winkler foundation. The model comprehensively accounts for the [...] Read more.
This study introduces an analytical framework that integrates the state-space method with generalized thermoelasticity theory to obtain exact solutions for the static and dynamic behaviors of laminated plates featuring imperfect interfaces and resting on a Winkler foundation. The model comprehensively accounts for the foundation-structure interaction, interfacial imperfection, and the coupling between the thermal and mechanical fields. A parametric analysis explores the impact of the dimensionless foundation coefficient, interface flexibility coefficient, and thermal conductivity on the static and dynamic behaviors of the laminated plates. The results indicate that a lower foundation stiffness results in higher sensitivity of structural deformation with respect to the foundation parameter. Furthermore, an increase in interfacial flexibility significantly reduces the global stiffness and induces discontinuities in the distribution of stress and temperature. Additionally, thermal conductivity governs the continuity of interfacial heat flux, while thermo-mechanical coupling amplifies the variations in specific field variables. The findings offer valuable insights into the design and reliability evaluation of composite structures operating in thermally coupled environments. Full article
(This article belongs to the Section Materials Simulation and Design)
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17 pages, 3213 KB  
Article
Influence of Surface Damage on Weld Quality and Joint Strength of Collision-Welded Aluminium Joints
by Stefan Oliver Kraus, Johannes Bruder, Florian Schuller and Peter Groche
Materials 2025, 18(13), 2944; https://doi.org/10.3390/ma18132944 - 21 Jun 2025
Viewed by 1019
Abstract
Collision welding represents a promising solid-state joining technique for combining both similar and dissimilar metals without the thermal degradation of mechanical properties typically associated with fusion-based methods. This makes it particularly attractive for lightweight structural applications. In the context of collision welding, it [...] Read more.
Collision welding represents a promising solid-state joining technique for combining both similar and dissimilar metals without the thermal degradation of mechanical properties typically associated with fusion-based methods. This makes it particularly attractive for lightweight structural applications. In the context of collision welding, it is typically assumed that ideally smooth and defect-free surface conditions exist prior to welding. However, this does not consistently reflect industrial realities, where surface imperfections such as scratches are often unavoidable. Despite this, the influence of such surface irregularities on weld integrity and quality has not been comprehensively investigated to date. In this study, collision welding is applied to the material combination of AA6110A-T6 and AA6060-T6. Initially, the process window for this material combination is determined by systematically varying the collision velocity and collision angle—the two primary process parameters—using a special model test rig. Subsequently, the effect of surface imperfections in the form of defined scratch geometries on the resulting weld quality is investigated. In addition to evaluating the welding ratio and tensile shear strength, weld quality is assessed through scanning electron microscopy (SEM) of the bonding interface and high-speed imaging of jet formation during the collision process. Full article
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17 pages, 1049 KB  
Article
The Philosophical Symbolism and Spiritual Communication System of Daoist Attire—A Three-Dimensional Interpretive Framework Based on the Concept of “Dao Following Nature”
by Qiu Tan and Chufeng Yuan
Religions 2025, 16(6), 688; https://doi.org/10.3390/rel16060688 - 27 May 2025
Cited by 1 | Viewed by 3359
Abstract
This paper examines the philosophy of “Dao follows nature” (道法自然) and investigates how Daoist clothing transforms abstract cosmological concepts into a “wearable interface for spiritual practice” through the use of materials, colors, and patterns. By integrating symbol system analysis, material culture theory, and the [...] Read more.
This paper examines the philosophy of “Dao follows nature” (道法自然) and investigates how Daoist clothing transforms abstract cosmological concepts into a “wearable interface for spiritual practice” through the use of materials, colors, and patterns. By integrating symbol system analysis, material culture theory, and the philosophy of body practice, this study uncovers three layers of symbolic mechanisms inherent in Daoist attire. First, the materials embody the tension between “nature and humanity”, with the intentional imperfections in craftsmanship serving as a critique of technological alienation. Second, the color coding disrupts the static structure of the Five Elements system by dynamically shifting between sacred and taboo properties during rituals while simultaneously reconstructing symbolic meanings through negotiation with secular power. Third, the patterns (such as star constellations and Bagua) employ directional arrangements to transform the human body into a miniature cosmos, with dynamic designs offering a visual path for spiritual practice. This paper introduces the concept of a “dynamic practice interface”, emphasizing that the meaning of Daoist clothing is generated through the interaction of historical power, individual experience, and cosmological imagination. This research fills a critical gap in the symbolic system of Daoist art and provides a new paradigm for sustainable design and body aesthetics, framed from the perspective of “reaching the Dao through objects”. Full article
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13 pages, 5748 KB  
Article
Recovery of Palladium and Silver from Copper Sludge and Spent Petrochemical Catalysts via Effective Pyrometallurgical Processing
by Hyunju Kim, Hyunsik Park and Joohyun Park
Metals 2025, 15(4), 466; https://doi.org/10.3390/met15040466 - 21 Apr 2025
Viewed by 1830
Abstract
Copper-containing sludge and spent petrochemical catalyst (SPC) were investigated for recovering palladium (Pd) and silver (Ag). Increasing the mixing ratio of alumina-based SPC leads to reduced recovery rates at 1500 °C. Specifically, as the SPC mixing ratio increases from 10% to 30%, the [...] Read more.
Copper-containing sludge and spent petrochemical catalyst (SPC) were investigated for recovering palladium (Pd) and silver (Ag). Increasing the mixing ratio of alumina-based SPC leads to reduced recovery rates at 1500 °C. Specifically, as the SPC mixing ratio increases from 10% to 30%, the recovery rate of Pd and Ag sharply decreases to 62.1% and 91.0%, respectively. This is attributed to an increase in the slag viscosity as well as to the higher sulfur content in the metal phase by decreasing the CaO/Al2O3 ratio of the slag. An increase in the slag viscosity causes a decrease in the metal recovery, as it lowers the settling velocity of metal droplets, resulting in imperfect metal separation, i.e., an increase in physical loss. Additionally, the presence of sulfur at the slag–metal interface was found to reduce interfacial tension, facilitating the entrapment of copper droplets within the slag. This further hindered phase separation and contributed to an increase in physical loss. This study highlights that physical loss is more serious in metal recovery rather than chemical loss, which is dependent on the thermochemical solubility of the target metals in the slag. The results emphasize the need for the precise control of slag properties to maximize the metal recovery processes in conjunction with a mitigation of CO2 emissions. Full article
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