Search Results (188)

A multiscale 3D CFD model of CO₂ methanation over Ni/Al₂O₃ was developed in COMSOL Multiphysics 6.3 for a lab-scale isothermal fixed-bed Sabatier reactor and validated against published data. The multiscale approach integrated bulk convection–diffusion, fluid flow, and pressure distribution with intraparticle diffusion–reaction phenomena coupled with Langmuir–Hinshelwood–Hougen–Watson-based kinetics, thus solving mass-transfer limitations without empirical effectiveness factors. Model validation was carried out by (i) kinetics, (ii) reactor performance, and (iii) hydrodynamics. Simulation results showed strong diffusion-dominated species transport at the bed entrance that lessened downstream as partial pressures decreased and products accumulated, resulting in a diffusion-relieved regime near the outlet. Sensitivity studies identified 320–350 °C and up to 10 bar as favorable conditions for high CH₄ yield. Additionally, slightly H₂-rich feed accelerated approach to equilibrium, while lower flow rates achieved near-complete conversion within the first half of the reactor bed. Simulations were carried out in COMSOL Multiphysics 6.3 on a dual Intel Xeon Platinum 8168 (48 cores at 2.7 GHz) workstation with 512 GB RAM to solve a 12-million-element mesh. The developed framework identifies a practical operating window and quantifies the conversion–throughput trade-off with flow rate, guiding operating condition selection and providing a basis for process intensification and lab-to-pilot scale-up of CO₂ methanation. Full article

This study provides the first comprehensive multiscale evaluation of raw coconut fibers as biosorbents for crude oil removal, encompassing laboratory adsorption tests, mesoscale hydrodynamic simulations, and field trials in marine environments. Fibers were characterized by SEM, FTIR, XRD, XPS, and chemical composition analysis (NREL method), confirming their lignocellulosic nature, high lignin content, and functional groups favorable for hydrocarbon adsorption. At the microscale, a 2⁵⁻¹ fractional factorial design evaluated the influence of dosage, concentration, contact time, temperature, and pH, followed by kinetic and equilibrium model fitting and regeneration tests. Dosage, concentration, and contact time were the most significant factors, while low sensitivity to salinity highlighted the material’s robustness under marine conditions. Adsorption followed pseudo-second-order kinetics, with an equilibrium adsorption capacity of 4.18 ± 0.19 g/g, and it was best described by the Langmuir isotherm, indicating chemisorption and monolayer formation. Mechanical regeneration by centrifugation allowed for reuse for up to five cycles without chemical reagents, aligning with circular economy principles. In mesoscale and field applications, fibers maintained structural integrity, buoyancy, and adsorption efficiency. These results provide strong technical support for the practical use of raw coconut fibers in oil spill response, offering a renewable, accessible, and cost-effective solution for scalable applications in coastal and marine environments. Full article

Liquids like water are not expected to produce a thermal change under shear strain or flow (away from extreme conditions). In this study, we reveal experimental conditions for which the conventional athermal hydrodynamic assumption is no longer valid. We highlight the establishment of non-equilibrium hot and cold thermal states occurring when a mesoscopic confined liquid is set in motion. Two stress situations are considered: low-frequency shear stress at large strain amplitude and microfluidic transport (pressure gradient). Two liquids are tested: water and glycerol at room temperature. In confined conditions (submillimeter scale), these liquids exhibit stress-induced thermal waves. We interpret the emergence of non-equilibrium temperatures as a consequence of the solicitation of the mesoscopic liquid elasticity. In analogy with elastic deformation, the mesoscopic volume decreases or increases slightly, which leads to a change in temperature (thermo-mechanical energy conversion). The energy acquired or released is converted to heat or cold, respectively. To account for these non-equilibrium temperatures, the mesoscopic flow is no longer considered as a complete dissipative process but as a way of propagating shear and thus compressive waves. This conclusion is consistent with recent theoretical developments showing that liquids propagate shear elastic waves at small scales. Full article

Tidal inlets regulate the exchange of water and sediment between the open sea and adjacent basins. In many locations, engineering interventions combined with coastal protections and polders have intensified erosion and scouring. This study reports on a three-year monitoring program following the implementation of a Nature-based Solution (NbS) at a previous engineering tidal inlet in the Zwin, located along the Belgian–Dutch coast. In 2019, large-scale modifications to the intertidal zone and the opening of a dyke doubled the surface area of the tidal inlet and its associated tidal marsh. Results revealed rapid and substantial morphological adjustments: the main channel deepened, widened, and migrated eastward. Sediment balance analyses showed stability at the inlet entrance but material loss further inland. Tidal prism and cross-sectional measurements indicated a fourfold increase in tidal prism immediately after NbS implementation, triggering strong channel responses. Within a year, the channel cross-sectional area reached a new equilibrium, which remained stable in the following years. These patterns highlight active sediment transport driven by coupled hydrodynamic and morphodynamic processes. Using an extensive data set, a conceptual model is presented to illustrate how the NbS influenced tidal inlet dynamics through the interaction of flow and sedimentation processes. Full article

This study develops a coupled Smoothed Particle Hydrodynamics (SPH) and the Discrete Element Method (DEM) framework to explore the sedimentation behavior of densely arranged particles in vertical pipes. An unresolved SPH-DEM model is proposed, which integrates porosity-dependent fluid governing equations through local averaging techniques to connect pore-scale interactions with macroscopic flow characteristics. Validated against single-particle settling experiments, the model accurately captures transient acceleration, drag equilibrium, and rebound dynamics. Systematic simulations reveal that particle number, arrangement patterns, and fluid domain geometry play critical roles in regulating collective settling: Increasing particle count induces nonlinear terminal velocity reduction. Systems of 16 particles show 50% lower velocity than single-particle cases due to enhanced shielding and energy dissipation. Particle configuration (compact layouts 4 × 8 vs. elongated arrangements 8 × 4) dictates hydrodynamic resistance, compact layouts facilitate faster settling by reducing cross-sectional blockage, while elongated arrangements amplify lateral resistance. The width of the fluid domain exerts threshold effects: narrow boundaries (0.03 m) intensify wall-induced drag and suppress vortices, whereas wider domains promote symmetric vortices that enhance stability. Additionally, critical transitions in multi-row/column systems are identified, where stress-chain redistribution and fluid-permeation thresholds govern particle detachment and velocity stratification. These findings deepen the understanding of granular–fluid interactions in confined spaces and provide a predictive tool for optimizing particle management in industrial processes such as wellbore cleaning and hydraulic fracturing. Full article

Understanding the morphodynamic evolution of muddy coasts under complex wave–tidal forcing is crucial for effective coastal management, particularly under the unstable hydrodynamic conditions associated with global climate change. This study employs a one-dimensional Delft3D model to investigate a tidal flat north of Dafeng Port, Jiangsu Province, China, validated with multi-year profile measurements. Under typical conditions, the profile consistently exhibits upper-flat accretion and lower-flat erosion, with threshold values of Hs ≈ 1.2 m and Tp ≈ 4.5 s triggering nonlinear bed-level changes. During storm tides, the profile displays a distinct upper flood-tide and lower ebb-tide response. Long-term simulations suggest that the profile will likely reach dynamic equilibrium by 2026. Overall, this study demonstrates the capability of one-dimensional modeling to capture nonlinear tidal flat evolution and provides valuable insights into the spatially variable morphodynamics of muddy coasts for adaptive management. Full article

Piles are common support elements for marine and coastal structures. The scour around pile foundations caused by currents is a major threat to the stability and safety of these structures. The empirical equations commonly used for estimating the equilibrium scour depth around pile groups are limited in their predicative capability, especially when the current approaches the pile group at an angle. This study applies a Multi-Layer Perceptron Backpropagation (MLP/BP) neural network to develop a general model for predicting the local maximum equilibrium scour depth around pile groups in steady currents. The input parameters for the model include all relevant non-dimensional hydrodynamic and structural variables taking full account of the effects of the pile group arrangement and its orientation relative to the approaching current. The model’s performance was evaluated by comparing its predictions against those generated by multiple other machine learning methods, as well as against results from widely used empirical formulas. A comprehensive sensitivity analysis is carried out to determine the importance ranking of the input parameters on model accuracy. Full article

This study analyzed shoreline evolution (2000–2024) at Dalian World Peace Park’s sandy tourist beach using GEE, CoastSat, and DSAS. At the same time, combined with the grain size analysis of beach sediments before and after typhoons, the impact of extreme events on the shoreline line changes was explored. The DSAS shows a spatial differentiation pattern of the southern shoreline retreat trend zone, the central shoreline dynamic balance trend zone and the northern shoreline advance trend zone. The 2008 reclamation project altered hydrodynamics, creating an artificial headland effect that triggered significant northern shoreline advancement (max 74.16 m) and southern retreat (27.14 m), demonstrating unforeseen long-term trade-offs of large-scale interventions. Subsequent cobble structures, acting as a nature-based solution, enhanced sediment retention and wave energy refraction, promoting dynamic equilibrium and shoreline resilience. However, the 2017 double typhoon caused instantaneous retreat with finer, poorly sorted sediment, highlighting persistent vulnerability to extreme events. This study underscores the critical need for adaptive management within a sustainable shoreline development framework. Full article

Enteroviruses initiate genomic replication via a highly conserved mechanism that is controlled by an RNA platform, also known as the 5’ cloverleaf (5’CL). Here, we present a biophysical analysis of the 5’CL conformation of three enterovirus serotypes under various ionic conditions, utilizing CD spectroscopy, size-exclusion chromatography, and small-angle X-ray scattering. In general, a tendency toward a smaller monomeric hydrodynamic radius in the presence of salts was observed, but the exact structural signature of each 5’CL varied depending upon the serotype. Rhinovirus B14 (RVB14) exhibited at least two monomeric conformations and a low propensity for dimerization, while poliovirus 1 (PV1) showed a high propensity for dimerization, which was enhanced by the presence of salts. Enterovirus D70 was observed to be somewhat intermediate, with primarily a monomeric structure, but possessing some potential for dimerization. The equilibrium between the two monomeric and the dimeric conformations is also discussed. These results indicate that the 5’CL conformation may be more complex than the current literature suggests, thus underscoring the need for a combined crystal and solution approach for the accurate representation of the 5’CL conformation, and the conformation of other RNA structural elements, under native conditions. Full article

Numerical simulations enable us to couple multiphase flow and geochemical processes to evaluate how sequestration impacts brine chemistry and reservoir properties. This study investigates these impacts during CO₂ storage at the San Juan Basin CarbonSAFE (SJB) site. The hydrodynamic model was calibrated through history-matching, utilizing data from saltwater disposal wells to improve predictive accuracy. Core-scale simulations incorporating mineral interactions and equilibrium reactions validated the model against laboratory flow-through experiments. The calibrated geochemical model was subsequently upscaled into a field-scale 3D model of the SJB site to predict how mineral precipitation and dissolution affect reservoir properties. The results indicate that the majority of the injected CO₂ is trapped structurally, followed by residual trapping and dissolution trapping; mineral trapping was found to be negligible in this study. Although quartz and calcite precipitation occurred, the dissolution of feldspars, phyllosilicates, and clay minerals counteracted these effects, resulting in a minimal reduction in porosity—less than 0.1%. The concentration of the various ions in the brine is directly influenced by dissolution/precipitation trends. This study provides valuable insights into CO₂ sequestration’s effects on reservoir fluid dynamics, mineralogy, and rock properties in the San Juan Basin. It highlights the importance of reservoir simulation in assessing long-term CO₂ storage effectiveness, particularly focusing on geochemical interactions. Full article

The paper outlines the hybrid framework of spin hydrodynamics, combining classical kinetic theory with the Israel–Stewart method of introducing dissipation. The local equilibrium expressions for the baryon current, the energy–momentum tensor, and the spin tensor of particles with spin 1/2 following the Fermi–Dirac statistics are obtained and compared with the earlier derived versions where the Boltzmann approximation was used. The expressions in the two cases are found to have the same form, but the coefficients are shown to be governed by different functions. The relative differences between the tensor coefficients in the Fermi–Dirac and Boltzmann cases are found to grow exponentially with the baryon chemical potential. In the proposed formalism, nonequilibrium processes are studied including mathematically possible dissipative corrections. Standard conservation laws are applied, and the condition of positive entropy production is shown to allow for the transfer between the spin and orbital parts of angular momentum. Full article

This study investigates the behavior of phosphate ion transport through two structurally distinct anion-exchange membranes—AMV (homogeneous) and HC-A (heterogeneous)—in an electrodialysis system under both static and stirred conditions at varying pH levels. Chronopotentiometric and current–voltage analyses were used to investigate the influence of pH and hydrodynamics on ion transport. Under underlimiting (ohmic) conditions, the AMV membrane exhibited simultaneous transport of H₂PO₄⁻ and HPO₄²⁻ ions at neutral and mildly alkaline pH, while such behavior was not verified at acidic pH and in all cases for the HC-A membrane. Under overlimiting current conditions, AMV favored electroconvection at low pH and exhibited significant water dissociation at high pH, leading to local pH shifts and chemical equilibrium displacement at the membrane–solution interface. In contrast, the HC-A membrane operated predominantly under strong electroconvective regimes, regardless of the pH value, without evidence of water dissociation or equilibrium change phenomena. Stirring significantly impacted the electrochemical responses: it altered the chronopotentiogram profiles through the emergence of intense oscillations in membrane potential drop at overlimiting currents and modified the current–voltage behavior by increasing the limiting current density, reducing electrical resistance, and compressing the plateau region that separates ohmic and overlimiting regimes. Additionally, both membranes showed signs of NH₃ formation at the anodic-side interface under pH 7–8, associated with increased electrical resistance. These findings reveal distinct ionic transport characteristics and hydrodynamic sensitivities of the membranes, thus providing valuable insights for optimizing phosphate recovery via electrodialysis. Full article

The salt flotation of graphite in the presence of lithium nickel manganese cobalt oxide (NMC) was assessed by performing colloidal probe atomic force microscopy (CP-AFM) on sessile gas bubbles and conducting batch flotation tests with model lithium-ion-battery black mass. The modeling of film drainage and detachment during particle–bubble interactions provides insight into the fundamental microprocesses during salt flotation, a special variant of froth flotation. The interfacial properties of particles and gas bubbles were tailored with salt solutions containing sodium chloride and sodium acetate buffer. Graphite particles can attach to gas bubbles under all tested conditions in the range pH 3 to pH 10. The attractive forces for spherical graphite are strongest at high salt concentrations and pH 3. The conditions for the attachment of NMC to gas bubbles were evaluated with simulations using the Stokes–Reynolds–Young–Laplace model for film drainage, under consideration of DLVO forces and a hydrodynamic slip to account for irregularities of the particle surface. CP-AFM measurements in the capillary force regime provide additional parameters for the modeling of salt flotation, such as the force and work of detachment. The contact angles of graphite and NMC particles during retraction and detachment from gas bubbles were obtained from a quasi-equilibrium model using CP-AFM data as input. All CP-AFM experiments and theoretical results suggest that pristine NMC particles do not attach to gas bubbles during flotation, which is confirmed by the low rate of NMC recovery in batch flotation tests. Full article

The pile group-pile cap structure is a key foundation form for deep-water bridges. However, current effective methods for calculating the earthquake-induced hydrodynamic forces on pile caps with arbitrary cross-sections remain insufficient. In this study, the hydrodynamic force is considered as the added mass, and the dynamic equilibrium equations of the isolated pile cap structure (IC model) and the pile group-pile cap structure (PC model) under earthquakes are established, respectively, based on the structural dynamics theory. Correspondingly, the relationships between the hydrodynamic added masses and the fundamental frequencies in the IC model and the PC model are derived, respectively. The fundamental frequencies of the IC model and the PC model are obtained by numerical models built with the ABAQUS (2019) finite element software, and then the added masses on the IC and PC models are calculated accurately. The calculation method proposed in this study avoids the complex fluid–structure interaction problem, which can be applied for the seismic design of deep-water bridge substructures in real practice. Full article

The dynamic non-equilibrium effect (DNE) describes the non-unique character of saturation–capillary pressure relationships observed under static, steady-state, or monotonic hydrodynamic conditions. Macroscopically, the DNE manifests as variations in soil hydraulic characteristic curves arising from varying hydrodynamic testing conditions and is fundamentally governed by soil matrix particle size distribution. Changes in the DNE across porous media with discrete particle size fractions are investigated via stepwise drying experiments. Through quantification of saturation–capillary pressure hysteresis and DNE metrics, three critical signatures are identified: (1) the temporal lag between peak capillary pressure and minimum water saturation; (2) the pressure gap between transient and equilibrium states; and (3) residual water saturation. In the four experimental sets, with the finest material (Test 1), the peak capillary pressure consistently precedes the minimum water saturation by up to 60 s. Conversely, with the coarsest material (Test 4), peak capillary pressure does not consistently precede minimum saturation, with a maximum lag of only 30 s. The pressure gap between transient and equilibrium states reached 14.04 cm H₂O in the finest sand, compared to only 2.65 cm H₂O in the coarsest sand. Simultaneously, residual water saturation was significantly higher in the finest sand (0.364) than in the coarsest sand (0.086). The results further reveal that the intensity of the DNE scales inversely with particle size and linearly with wetting phase saturation (Sw), exhibiting systematic decay as Sw decreases. Coarse media exhibit negligible hysteresis due to suppressed capillary retention; this is in stark contrast with fine sands, in which the DNE is observed to persist in advanced drying stages. These results establish pore geometry and capillary dominance as fundamental factors controlling non-equilibrium fluid dynamics, providing a mechanistic framework for the refinement of multi-phase flow models in heterogeneous porous systems. Full article