Search Results (183)

Lead-free polymer composites containing high-atomic-number fillers are promising alternatives to conventional lead shielding for nuclear medicine applications. In this study, Bi₂O₃-, WO₃-, and hybrid Bi₂O₃/WO₃ nanoparticle-filled epoxy resin composites were fabricated and evaluated for attenuation of the 140 keV photons emitted by technetium-99m (Tc-99m). The synthesized Bi₂O₃ and WO₃ nanoparticles exhibited hydrodynamic diameters of 638.2 ± 11.3 and 404.2 ± 3.2 nm, respectively, with polydispersity indices below 0.30 and zeta potentials of −33.73 ± 0.63 and −32.47 ± 0.75 mV, indicating acceptable dispersion characteristics and colloidal stability. SEM–EDX confirmed successful incorporation of Bi- and W-containing phases into the epoxy matrix, while the XRD and FTIR analyses verified retention of the crystalline metal oxide phases and the principal chemical structure of the cured epoxy network. Tensile testing revealed a composition-dependent strength–ductility relationship, with the Bi₂O₃-filled composite exhibiting the highest tensile strength among the developed formulations and the hybrid composite showing the greatest elongation at break. XCOM and Phy-X/PSD simulations demonstrated that increasing high-Z filler content enhanced the mass and linear attenuation coefficients and reduced the half-value layer, tenth-value layer, and mean free path. Experimental shielding performance was evaluated using Hp(10) measurements with optically stimulated luminescence dosimeters positioned on an anthropomorphic thorax phantom under a fixed Tc-99m exposure geometry. The transmitted dose decreased with increasing filler loading, and nanoparticle-filled formulations generally outperformed the corresponding conventional-particle composites. The hybrid 75:25 Bi₂O₃/WO₃ NP composite exhibited the lowest mean Hp(10) value of 0.016 µSv, corresponding to a 50% reduction relative to the lead reference under the investigated geometry. The combined structural, mechanical, computational, and dosimetric results demonstrate that hybrid filler design enables simultaneous optimization of attenuation efficiency and mechanical tolerance. These findings identify the Bi-rich hybrid epoxy composite as a promising lead-free material for customized shielding components, including vial holders, syringe-shield housings, protective panels, and workstation accessories used during Tc-99m handling in nuclear medicine. Full article

Chronic wounds constitute a major clinical and socioeconomic burden owing to prolonged inflammation, persistent bacterial infection, impaired angiogenesis, and defective extracellular matrix remodeling. Advanced wound dressings have traditionally been developed to promote tissue regeneration, control bacterial infection, and restore the wound microenvironment. Recent advances have focused on multifunctional biomaterials integrating regenerative, antibacterial, anti-inflammatory, antioxidant, and controlled drug-delivery properties. Within this context, antiviral biointerface engineering has emerged as a promising, although still exploratory, materials-engineering perspective rather than an established function of wound dressings. Hydrogel–metal–organic framework (MOF) hybrid polymer composites have emerged as versatile platforms for multifunctional wound dressings. Hydrogels provide hydrated three-dimensional matrices with tunable porosity, swelling behavior, mechanical compliance, and biocompatibility, whereas MOFs contribute high surface area, adjustable pore architectures, chemically tailorable active sites, and controlled ion release. Their integration generates synergistic systems whose performance is governed by structure–function relationships involving polymer crosslinking density, MOF dispersion, pore hierarchy, interfacial adhesion, swelling dynamics, and surface functionalization. Collectively, these parameters regulate mass transport, mechanical stability, therapeutic delivery, and cytocompatibility while potentially influencing virus–material interactions through engineered biointerfaces. Current evidence indicates that direct experimental demonstrations of antiviral performance in hydrogel–MOF wound dressing systems remain limited. Accordingly, antiviral biointerface functions should be regarded as emerging engineering opportunities requiring further experimental validation before clinical translation. This review critically analyzes the structure–function engineering principles governing hydrogel–MOF hybrid systems and examines how established regenerative functions may be integrated with emerging antiviral biointerface concepts. Unlike previous reviews focused primarily on drug delivery, antibacterial activity, or tissue engineering, this review emphasizes the relationships between polymer architecture, MOF chemistry, interfacial design, and transport phenomena while explicitly distinguishing experimentally supported evidence from prospective mechanistic concepts. Particular attention is given to current limitations, translational challenges, and future directions for the rational design of next-generation multifunctional hydrogel–MOF wound dressings. Full article

Carbon fibre-reinforced polymer (CFRP) composites represent promising lightweight materials for automotive powertrain systems, where increasing demands for weight reduction, energy efficiency, and emission reduction are driving the replacement of conventional metallic components. However, automotive powertrain environments expose CFRP materials to elevated temperatures, cyclic mechanical loading, chemical exposure, and tribological interactions, creating complex degradation conditions that significantly influence long-term durability and reliability. This review systematically analyzes CFRP composites for automotive powertrain applications, focusing on the relationship between operational requirements, material selection, reinforcement architecture, manufacturing technologies, and degradation mechanisms. High-performance thermoplastic systems such as CF/PEEK, CF/PPS, and CF/PEKK are critically compared with conventional thermoset composites. CF/PEEK systems demonstrate superior thermomechanical stability, maintaining significant mechanical performance at temperatures approaching 250 °C and tensile strengths of approximately 1400–1600 MPa, whereas CF/PPS composites provide a more economically efficient compromise between thermal resistance, chemical stability, manufacturability, and recyclability for medium-temperature applications. The review further analyzes dominant degradation mechanisms, including creep deformation, fatigue damage, delamination, fibre–matrix interface degradation, and tribological wear. CFRP degradation is shown to result from the interaction of multiple coupled mechanisms rather than from isolated material failure modes. Tribological wear rates typically range from 10⁻⁶ to 10⁻⁵ mm³/(N·m), while creep–fatigue interactions may reduce component lifetime by up to 40–60% under combined thermomechanical loading. Advanced design strategies, including fibre orientation optimization, laminate architecture tailoring, thickness gradation, and hybrid metal–composite structures, are evaluated together with major manufacturing technologies such as injection moulding, compression moulding, overmoulding, automated fibre placement, and additive manufacturing. The presented review establishes an integrated framework linking material systems, operating conditions, manufacturing processes, and durability requirements for automotive powertrain applications. The analysis demonstrates that no universal CFRP system exists for all powertrain components and that optimal material selection requires balancing thermal stability, fatigue resistance, tribological performance, manufacturability, recyclability, and economic constraints according to the specific operating conditions of each component category. Full article

The aim of the presented study is to verify the possibility of forming hybrid adhesive-mechanical joints between aluminum sheet and PP matrix composites reinforced with carbon and glass fibers using thermal drilling technology. The research responds to weight reduction trends in the automotive and aerospace industries, seeking joining methods that preserve the continuity of reinforcing fibers. The methodology included applying an experimental organosilicate agent to the aluminum, sequential thermal drilling, and an innovative modification of bushing geometry using a 9.3 mm diameter tool. Joint quality was evaluated via tensile shear testing and non-destructive analysis using computed tomography (CT). Results showed that the organosilicate layer significantly increased the load-bearing capacity and adhesion of glass fiber joints. Hybrid joints exhibited higher energy absorption than purely adhesive joints. The proposed bushing geometry modification led to a statistically significant increase in total dissipated energy (by 28% to 37%) and a desired change in the failure mechanism from composite pull-out to bushing shear. CT analysis confirmed the preservation of fiber integrity through radial deflection. Consequently, hybrid joining via thermal drilling with modified geometry effectively utilizes the mechanical properties of metallic materials in multi-material structures. Full article

Accurately predicting the mechanical response and failure of composite–metal hybrid bolted joints under thermo-mechanical coupled loads remains a critical challenge in aerospace engineering. This paper develops a temperature-dependent multi-scale progressive failure analysis model based on micromechanical failure theory. A hexagonal representative volume element (RVE) incorporating fibers, matrix and interphase is constructed, with a stress amplification factor enabling macro–meso stress–strain transformation. Dimensionless temperature corrections are applied to resin and interphase mechanical properties, and temperature-influenced mesoscopic failure criteria with corresponding stiffness degradation schemes are proposed. The nonlinear progressive damage simulation is implemented via the ABAQUS/UMAT subroutine. Static tensile tests on AC531/CCF800H composite-7075 aluminum alloy three-bolt double-shear joints are conducted at −70 °C, 20 °C and 120 °C. The results show excellent agreement between the simulations and experiments, with ultimate load errors < 5%. Low temperature increases load capacity by 3.91% via resin hardening and enhanced interfacial bonding, while high temperature reduces it by 9.07% due to resin softening. Failure modes shift from end-hole tensile fracture (−70 °C, 20 °C) to full-hole bearing failure (120 °C), governed by altered bolt load distribution and damage evolution paths. The proposed model provides reliable support for thermo-mechanical design and strength verification of aerospace composite structures. Full article

In this study, epoxy composites reinforced with kraft lignin, a promising green biofiller, and Fe–Mn–Si alloy particles as metallic functional fillers were developed, and their morphological properties, elemental distribution, mechanical properties, corrosion behavior, and thermally activated dimensional recovery behavior were investigated. Epoxy resin was used as the matrix, while kraft lignin and Fe–Mn–Si particles were incorporated as hybrid fillers. The composites were fabricated by casting with kraft lignin loadings of 1, 3, and 5 wt.% and a fixed Fe–Mn–Si alloy content of 3 wt.%. Neat epoxy was also prepared as a control sample. The specimens were characterized using scanning electron microscopy, energy-dispersive spectroscopy with elemental mapping, tensile testing, Shore D hardness measurements, electrochemical corrosion testing, and dimensional recovery tests. SEM–EDS observations showed that the composite containing 1 wt.% lignin exhibited a relatively uniform fracture morphology and more locally dispersed filler-related elemental signals, whereas higher lignin contents promoted particle-rich regions, microvoid-like features, and increased microstructural heterogeneity. The composite containing 1 wt.% lignin exhibited the highest tensile strength and elongation at break, with values of 39.09 MPa and 2.11%, respectively, and also showed the highest dimensional recovery ratio of 2.5%. The composite containing 3 wt.% lignin exhibited the lowest measured corrosion rate of 0.08 µm/year, while the composite containing 5 wt.% lignin showed the highest elastic modulus and Shore D hardness, with values of 5.80 GPa and 79, respectively. Overall, low lignin loading provided the most balanced mechanical and recovery-related performance, whereas higher lignin contents increased stiffness and hardness but also promoted greater microstructural heterogeneity. Full article

Face milling of aluminum 7075 hybrid metal matrix composites with 10 wt.% TiO₂ and 3 wt.% graphite (HMMCs) are needed to improve performance and sustainability. This study focuses on optimizing the milling process for Al7075 HMMCs using the desirability approach and advanced multi-criteria decision-making (MCDM) methodologies, including the Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS) and the Combined Distance-based Assessment (CODAS). Surface roughness (SR), cutting force (CF), carbon emissions (CE), and energy consumption (EC) were systematically evaluated and ranked using the L₁₈ Taguchi Orthogonal Array. Minimum Quantity Lubrication (MQL) and cryogenic CO₂ cooling techniques were used to achieve a superior surface finish and reduce friction at the tool-workpiece interface, thereby minimizing scratches and thermal damage. Desirability evaluation results showed the optimal machining conditions for milling of Al7075 (HMMCs) occurred at a cutting speed (V_c) of 200 m/min, a feed rate (f) of 0.02 mm/rev, and a depth of cut (a_p) of 0.3 mm, proving the potential of integrating MCDM tools with effective cooling strategies. The desirability method favored a balanced compromise, while entropy-weighted TOPSIS/CODAS emphasized energy and carbon-related responses. Improvements of 6% in cutting force, 7% in surface roughness, and a 7% reduction in energy consumption, along with 8% lower carbon emissions, were achieved, demonstrating the effectiveness of hybrid cooling strategies in promoting eco-friendly and resource-efficient processes. Full article

Thermoplastic fiber metal laminates (TFMLs) are lightweight hybrid materials combining metallic layers with fiber-reinforced thermoplastic composites, offering a high strength-to-weight ratio. Existing studies indicate a limited range of polymer matrices used in such structures, most commonly polyamide 6 (PA6). In this work, polybutylene terephthalate (PBT) was selected as a potential alternative matrix because literature data indicate its lower moisture absorption and good dimensional stability compared with PA6. A comparative analysis of TFMLs based on aluminum and carbon fabric-reinforced composites with PA6 and PBT matrices was conducted. Static tensile tests were performed on base materials, composites, and laminates, supported by analytical modeling using the superposition method and fractographic analysis. The results showed that fiber orientation and polymer content significantly affect stiffness, strength, and damage evolution. Fiber orientation remains the governing factor, controlling load transfer and damage initiation. Laminates with 0/90° fibers exhibited the highest strength, while ±45° configurations showed reduced performance due to shear-dominated deformation. The polymer primarily acts as a matrix, ensuring structural integrity, with comparable mechanical properties for both systems. Delamination at the metal–composite interface was identified as the dominant failure mechanism. Full article

For the removal of hexavalent chromium [Cr(VI)] from drinking water, a hybrid biosorbent designated chitosan–natural diatomaceous earth (CNDE) was developed and thoroughly characterized. The material couples the ion-exchange and chelating capacity of chitosan—applied at an 85% degree of deacetylation—with the high-surface-area mineral framework of natural diatomaceous earth, onto which the polymer was deposited as a conformal coating. Surface morphology and internal microstructure were examined by scanning and transmission electron microscopy (SEM/TEM), while elemental composition across the hybrid matrix was resolved by energy-dispersive X-ray spectroscopy (EDX). Fourier transform infrared (FTIR) spectroscopy was employed to identify the surface functional groups responsible for chromate binding, and streaming current measurements established the pH of zero charge (pH_pzc), which governs the electrostatic environment at the sorbent–solution interface. Specific surface area was quantified by the Brunauer–Emmett–Teller (BET) method, and the balance of surface acidic and basic sites was determined through titrimetric analysis of total acidity and alkalinity. Thermogravimetric analysis (TGA) was conducted to assess thermal stability. Batch equilibrium isotherm experiments were performed to evaluate Cr(VI) uptake from model drinking water prepared using dilute potassium dichromate solutions adjusted to target pH levels. The effects of solution pH and competing anions (chloride and sulfate) were also investigated. Kinetic studies were conducted to determine the rate of Cr(VI) adsorption, and residual metal concentrations were measured using inductively coupled plasma mass spectrometry (ICP-MS). Results indicated that CNDE containing 30% chitosan (CNDE30) achieved effective Cr(VI) removal at pH 5. Adsorption was strongly pH-dependent, decreasing as pH increased from 5 to 8. Equilibrium data were well described by both Langmuir and Freundlich isotherm models, while kinetic data followed a pseudo-second-order model. The presence of chloride ions (15 mg/L) reduced adsorption capacity by approximately one-third, whereas sulfate at the same concentration significantly inhibited Cr(VI) removal. Overall, the isotherm results suggest that CNDE30 is a promising material for Cr(VI) removal from drinking water. Its cost-effectiveness, ease of synthesis, and potential for reuse make it particularly attractive for small-scale and decentralized water treatment applications. Full article

High-purity copper features excellent electrical conductivity but generally low mechanical properties. Adding a three-dimensional graphene network as reinforcement to make a copper–graphene metal matrix composite is promising for a wide range of applications with better mechanical performance and functional capabilities. However, direct application in a metal matrix is difficult due to unfavorable wetting, which causes poor dispersion and weak interfacial bonding in the graphene–metal system. Here, the powder metallurgy method was used to construct a three-dimensional continuous graphene network in the copper matrix combined with high-pressure torsion. Optimized deformation/thermomechanical treatment enhanced the microstructural development processed by the severe plastic deformation method of high-pressure torsion. The primary advantage of this hybrid process is that it enables us to achieve grains with a size in the ultra-fine or even nanoscale. A homogeneous equiaxed nanostructure without segregation was observed during microstructural characterization, with a grain size of ~300 nm. This study investigated structural development during progressive deformation, and the samples were evaluated from the viewpoint of grain size and grain boundaries. The process significantly increased the microhardness of the copper–graphene composite. The tensile strength reached ~500 MPa at room temperature. The interpenetrating structural feature of graphene promoted interfacial shear stress to a high level, whereas plastic deformation increased the dislocation density and grain boundaries, thus resulting in significantly enhanced load transfer strengthening and crack-bridging toughness simultaneously. Full article

Semiconducting metal oxides are gaining attention in thermoelectric applications, where performance is evaluated by the figure of merit (ZT), which depends on the power factor (S²σ) and thermal conductivity (κ). However, achieving high ZT values in these materials remains challenging. This study introduces a distinct strategy to enhance thermoelectric performance by infiltrating aluminum-doped zinc oxide (AZO) into poly(methyl methacrylate) (PMMA) films using the vapor-phase infiltration (VPI) technique. The resulting AZO/PMMA hybrid films exhibit a unique composite structure with AZO nanocrystals embedded within an amorphous PMMA matrix. This structure facilitates energy-dependent carrier scattering (the energy filtering effect) at the AZO/PMMA interfaces, thereby enhancing the Seebeck coefficient, while phonon scattering at the interfaces reduces thermal conductivity. By precisely controlling VPI parameters, we achieved a uniform dispersion of AZO nanocrystals within the PMMA matrix. The optimized AZO/PMMA hybrid film demonstrated a power factor of 1306 μW m⁻¹ K⁻² and a thermal conductivity of 1.02 W m⁻¹ K⁻¹, resulting in a ZT value of approximately 0.384 at 300 K, which is one of the highest reported for metal oxide thermoelectric materials near room temperature. The successful integration of AZO into the PMMA matrix via VPI opens new pathways for developing high-performance, flexible thermoelectric materials. Full article

Electrochemical sensors have emerged as promising tools for rapid pesticide screening in food and environmental samples because they combine simple instrumentation, fast response, portability, and compatibility with disposable electrodes. This review organizes recent progress through a cross-system framework linking pesticide class, interfacial electrochemical process, and material design. Carbon materials, metal–organic frameworks and their derivatives, metal nanoparticles, metal compounds, conducting polymers, MXene-based composites, and selected emerging materials are compared in terms of enrichment capability, charge-transfer regulation, catalytic amplification, recognition-layer integration, and suitability for real-sample analysis. Emphasis is placed on issues that are often under-discussed in performance-centered surveys, including matrix interference, electrode fouling, batch-to-batch reproducibility, storage stability, scalability, and cost-effectiveness. Representative examples show that the most useful advances arise not simply from lowering the limit of detection but from improving structure–function understanding and translating interfacial design into robust analytical performance. Future work should prioritize standardized fabrication and benchmarking protocols, in situ and operando identification of active sites and interface evolution, matrix-specific antifouling validation, multiresidue and metabolite analysis, and hybrid portable devices coupled with intelligent readout. Full article

Accurate prediction of the behavior of alloys and metal matrix composites during high-temperature deformation requires strict consideration of the loading history. To address this problem, a hybrid rheological model for flow stress prediction has been developed, combining a phenomenological description of the yield stress with a recurrent neural network based on the NARX (Nonlinear AutoRegressive with eXogenous inputs) architecture. The memory effect is formed by expanding the input parameters with the response values from the previous step. The identification of the weight coefficients of the NARX neural network is implemented by training an equivalent multilayer perceptron. To improve the generalization ability of the model and eliminate its dependence on a fixed discretization step, the training dataset includes data obtained under non-monotonic changes in the strain rate over time and a variable time interval. The article justifies the structure of the model input parameters, excluding the accumulated strain from the input set due to its lack of informativeness during active softening processes. Verification of the hybrid model on the 7075/2.5% TiC composite in the temperature range of 300–500 °C demonstrated an average relative error of 1.5% when predicting modes that were not involved in the training. The predicted flow stress values fall within the experimental scatter interval of ±5% and accurately reproduce the local features of the flow stress curves. The proposed model and its identification technique provide correct consideration of the deformation history under the complex interaction of hardening and softening processes. Full article

Aluminum alloy (AA5083) is widely used in the aerospace and marine industries. However, its use is sometimes limited by its low surface hardness, wear resistance, and thermal stability. The microstructural, mechanical, tribological, and dynamic behavior of AA5083 matrix composites incorporated with mono-reinforcements (hexagonal boron nitride (hBN), graphene (G), and carbon nanotubes (CNTs)) and hybrid reinforcements (hBN+CNTs, G+hBN, and CNTs+G) by friction stir processing (FSP) is thoroughly investigated. Microstructural examination demonstrated that extensive dynamic recrystallization was induced by FSP, reducing the base-metal grains (about 215 μm) to very small sizes. The hybrid hBN+CNT composite had the smallest grain size (about 4.5 μm), the mono-CNT composite had the highest microhardness (~60 HV), whereas the hybrid CNTs+G composite had the highest ultimate compressive strength (~350 MPa). This enhancement was attributed to the formation of a 3D network within the hybrid composite, which hindered graphene agglomeration and restacking. Tribological tests revealed that hybridization greatly reduced wear; in particular, hBN-containing hybrids (hBN+CNTs and hBN+G) had the lowest wear rates (~0.037 mg/bar.min), owing to hBN’s solid-lubrication effect. Moreover, dynamic mechanical analysis and free-vibration testing showed the tunability of vibrational characteristics; the mono-CNT composite had the greatest structural stiffness (storage modulus ~72.75 GPa), whereas the G+CNTs hybrid had the best damping ratio (damping ratio ~4.82%). These results demonstrate that hybrid nanoreinforcements can tailor the multifunctional characteristics of AA5083 composites. Full article

Silicomanganese slag (SiMnS), a Mn-bearing by-product from silicomanganese alloy production, is often stockpiled in large quantities and may pose environmental concerns due to potential metal leaching. This study develops an OPC-rich hybrid SiMnS–steel slag–fly ash–OPC-activated composite binder, referred to as SMSAB, in which OPC accounts for 55% of the solid precursor mass. Different alkali contents and sodium silicate moduli were investigated, and the optimised paste was characterised in terms of mechanical strength, reaction products, pore structure, carbon-footprint and heavy-metal leaching. The best performance was obtained at an alkali content of 4% and a sodium silicate modulus of 1.0, giving 28-day compressive and flexural strengths of 65.13 MPa and 3.37 MPa, respectively. XRD, SEM-EDS, FTIR and MIP results showed that the main reaction products were C-(A)-S-H, N-A-S-H and C-N-A-S-H gels, which refined the pore structure and produced a dense matrix. The reduction in Mn leaching may be associated with physical encapsulation, possible charge-balancing interactions within gel structures, changes in Mn-related bonding environments and the presence of Mn-bearing phases. Leaching concentrations of Zn, Mn, Cr, Cu and Ni satisfied the Grade III groundwater limits used in China. The calculated carbon intensity of SMSAB was 3.97 kg·(m³·MPa)⁻¹, indicating a favourable strength-to-emission balance compared with the reference systems considered. It should be noted that the present work examines paste specimens only; aggregate skeleton, traffic loading, freeze–thaw cycling and wet–dry/moisture cycling were not included. Therefore, the results demonstrate binder-level potential rather than direct qualification of SMSAB as a pavement base or subbase material. Full article