Search Results (16)

Traditional coal quality assessment methods rely exclusively on the laboratory testing of physical samples, which impedes detailed stratigraphic evaluation and limits the integration of intelligent precision mining technologies. To resolve this challenge, this study investigates geophysical logging as an innovative method for coal quality prediction. By integrating scanning electron microscopy (SEM), X-ray analysis, and optical microscopy with interdisciplinary methodologies spanning mathematics, mineralogy, and applied geophysics, this research analyzes the coal quality and mineral composition of the Shanxi Formation coal seams in northern Jiangsu, China. A predictive model linking geophysical logging responses to coal quality parameters was established to delineate relationships between subsurface geophysical data and material properties. The results demonstrate that the Shanxi Formation coals are gas coal (a medium-metamorphic bituminous subclass) characterized by low sulfur content, low ash yield, low fixed carbon, high volatile matter, and high calorific value. Mineralogical analysis identifies calcite, pyrite, and clay minerals as the dominant constituents. Pyrite occurs in diverse microscopic forms, including euhedral and semi-euhedral fine grains, fissure-filling aggregates, irregular blocky structures, framboidal clusters, and disseminated particles. Systematic relationships were observed between logging parameters and coal quality: moisture, ash content, and volatile matter exhibit an initial decrease, followed by an increase with rising apparent resistivity (LLD) and bulk density (DEN). Conversely, fixed carbon and calorific value display an inverse trend, peaking at intermediate LLD/DEN values before declining. Total sulfur increases with density up to a threshold before decreasing, while showing a concave upward relationship with resistivity. Negative correlations exist between moisture, fixed carbon, calorific value lateral resistivity (LLS), natural gamma (GR), short-spaced gamma-gamma (SSGG), and acoustic transit time (AC). In contrast, ash yield, volatile matter, and total sulfur correlate positively with these logging parameters. These trends are governed by coalification processes, lithotype composition, reservoir physical properties, and the types and mass fractions of minerals. Validation through independent two-sample t-tests confirms the feasibility of the neural network model for predicting coal quality parameters from geophysical logging data. The predictive model provides technical and theoretical support for advancing intelligent coal mining practices and optimizing efficiency in coal chemical industries, enabling real-time subsurface characterization to facilitate precision resource extraction. Full article

Biogas produced by anaerobic digestion contains different types of contaminants, and it is preferable to eliminate those contaminants before biogas’ energetic valorization or upgrading to biomethane as they are harmful to human health and detrimental to combustion engines. This study presents the biogas cleanup system optimized by an Italian full-scale anaerobic digester treating food waste (FW) and represented by micro-oxygenation, chemical scrubber, cooling, and activated carbon sections. The cleaned biogas is upgraded to biomethane using a membrane-based upgrading unit and injected into the natural gas network for transport sector use. H₂S and volatile organic compound (VOC) concentration in raw biogas was reduced from an annual average value of 1207 ppm_v and 895 mg/Nm³, respectively, to below 0.1 mg/Nm³ in the final biomethane. In the summer, the H₂S average content in raw biogas was 833 ppm_v due to a greater presence of low-sulfur-containing vegetables in FW, while in the winter it was an average of 1581 ppm_v due to a larger portion of protein-containing FW. On the other hand, raw biogas VOC content in the winter was an average of 1149 mg/Nm³, with respect to 661 mg/Nm³ in the summer, due to the greater consumption of citrus fruits containing high amount of terpene compounds. The concentration of other trace contaminants, such as HCl, NH_3, and siloxanes, was lowered from 17, 36, and 0.6 mg/Nm³ in raw biogas, respectively, to below 0.1 mg/Nm³ in the final biomethane. All the considerations and evaluations underlying the technological and plant engineering choices together with the individuation of the best operating conditions are discussed. Full article

Environmental concerns surrounding the use of high-sulfur fuel oil (HFO), a marine fuel derived from refinery vacuum residue, motivate the exploration of alternative solutions. Burning high-sulfur fuel oil (HFO) is a major source of air pollution, acid rain, ocean acidification, and climate change. When HFO is burned, it releases sulfur dioxide (SO₂) into the air, a harmful gas that can cause respiratory problems, heart disease, and cancer. SO₂ emissions can also contribute to acid rain, which can damage forests and lakes. Several countries and international organizations have taken steps to reduce HFO emissions from ships. For example, the International Maritime Organization (IMO) has implemented a global sulfur cap for marine fuels, which limits the sulfur content of fuel to 0.5% by mass. In addition, there is a worldwide effort to encourage the use of low-carbon gases to help reduce greenhouse gas (GHG) emissions. There are several alternative fuels that can be used in ships instead of HFO, such as liquefied natural gas (LNG), methanol, and hydrogen. These fuels are cleaner and more environmentally friendly than HFO. The aim of this study is to develop a process integration framework to co-produce methanol and hydrogen from vacuum residue while minimizing the sulfur and carbon emissions. Two process models have been developed in this study to produce methanol and hydrogen from vacuum residue. In case 1, vacuum residue is gasified using oxygen—steam and the syngas leaving the gasifier is processed to produce both methanol and hydrogen. Case 2 shares the same process model as case 1 except it is concentrated on mainly methanol production from vacuum residue. Both models are techno-economically compared in terms of methanol and H₂ production rates, specific energy requirements, carbon conversion, CO₂ specific emissions, overall process efficiencies, and project feasibility while considering the fluctuation of vacuum residue feed price from 0.022 $/kg to 0.11 $/kg. The comparative analysis showed that case 2 offers an 86.01% lower specific energy requirement (GJ) for each kilogram (kg) of fuel produced. The CO₂ specific emission also decreased in case 2 by 69.76% compared to case 1. In addition, the calculated total net fuel production cost is 0.453 $/kg and 0.223 $/kg at 0.066 $/kg for case 1 and 2, respectively. Overall, case 2 exhibits better project feasibility compared to case 1 with higher process performance and lower production costs. Full article

Petroleum oil pollution is a worldwide problem that results from the continuous exploration, production, and consumption of oil and its products. Petroleum hydrocarbons are produced as a result of natural or anthropogenic practices, and their common source is anthropogenic activities, which impose adverse effects on the ecosystem’s nonliving and living components including humans. Phytoremediation of petroleum hydrocarbon-polluted soils is an evolving, low-cost, and effective alternative technology to most traditional remediation methods. The objective of this study is to evaluate the phytoremediation potentiality of Vinca rosea for crude oil-contaminated soil by understanding its properties and involvement in the enhanced degradation of crude oil. The remediation potentiality was determined by evaluating the total petroleum hydrocarbon degradation percentage (TPH%) and changes in the molecular type composition of saturated and aromatic hydrocarbon fractions. TPH% was estimated gravimetrically, and changes in the molecular type composition of saturated and aromatic fractions were measured using gas chromatography and high-performance liquid chromatography, respectively. Sulfur concentration was measured using X-ray fluorescence. Cadmium and lead quantification was measured using Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES). The results revealed that V. rosea enhanced total petroleum hydrocarbon (TPH) degradation and altered the molecular composition of the crude oil. The saturated hydrocarbons increased and the aromatic hydrocarbons decreased. The saturated hydrocarbon fraction in the crude oil showed a wider spectrum of n-paraffin peaks than the oil extracted from unplanted and V. rosea-planted soils. Polyaromatic hydrocarbon degradation was enhanced in the presence of V. rosea, which was reflected in the increase of monoaromatic and diaromatic constituents. This was parallel to the increased sulfur levels in planted soil. The determination of sulfur and heavy metal content in plant organs indicated that V. rosea can extract and accumulate high amounts from polluted soils. The ability of V. rosea to degrade TPH and alter the composition of crude petroleum oil by decreasing the toxicity of polyaromatic hydrocarbons in soil, as well as its capability to absorb and accumulate sulfur and heavy metals, supports the use of plant species for the phytoremediation of crude oil-polluted sites. Full article

The deposition of sulfur particles in gathering and transportation pipeline system can cause serious safety problems and economic losses. When the high sulfur content natural gas (HSCNG) flows through the throttle valve of the gathering and transportation system, it will cause the supersaturation of elemental sulfur in the gas phase, and then the sulfur crystal nuclei and sulfur particles will appear in the pipeline system. Studying the initial growth behavior of sulfur crystal nuclei and sulfur particles can lay a necessary prerequisite for the accurate prediction of sulfur particle deposition in high sulfur content natural gas gathering and transportation (HSCNGGT) pipelines. Based on the homogeneous nucleation theory in crystallization kinetics, a mathematical model of elemental sulfur nucleation was established. Taking the throttling condition in the process of HSCNGGT as an example, the effects of temperature, pressure and H₂S concentration in HSCNG on the critical nucleation radius and nucleation rate of elemental sulfur were explored. The results show that: (1) after the supersaturation of elemental sulfur, sulfur crystal nuclei with nanoscale radius will be precipitated. The temperature and pressure after throttling have great influence on the nucleation radius, and the influence of H₂S concentration on the nucleation radius is more complex. (2) The temperature, pressure and H₂S concentration after throttling also have great influence on the nucleation rate. By solving the growth kinetics model of sulfur particles based on Brownian condensation, it is found that the nano-sized sulfur crystal nuclei can grow into micron-sized sulfur particles in a very short time. Full article

The effect of gathering pipeline pressure, temperature, and key components on the solubility of monomeric sulfur in high-sulfur-content natural gas is directly related to the prediction and prevention of sulfur deposition in surface gathering pipelines. Based on our previous study on a prediction model of sulfur solubility in gas with a new formula for the binary interaction coefficient between sulfur and H₂S, a new gas–solid thermodynamic phase equilibrium solubility prediction model for monomeric sulfur in high-sulfur-content natural gas was improved based on the gas–solid phase equilibrium principle considering both physical and chemical solution mechanisms. Two new expressions for binary interaction coefficients between sulfur and CO₂ and CH₄, considering both temperature and solvent density, are proposed in this new solubility prediction model. In this paper, the main factors, such as the gathering pipeline pressure, gathering pipeline temperature, H₂S, and CO₂, affecting the solubility law of elemental sulfur in high-sulfur-content natural gas are investigated. The results show that the total solubility of elemental sulfur in high-sulfur-bearing natural gas tends to decrease with an increase in the gathering temperature, in which the increase in temperature promotes physical solution, and the physical solution mechanism prevails. Conversely, chemical solution is promoted, and the chemical solution mechanism prevails. With an increase in the gathering pressure, the total solubility of elemental sulfur in high-sulfur-content gas tends to increase, where the physical solubility decreases slightly at first and then increases continuously, with a pressure inflection point of about 2.0 MPa, and the pressure increase has a significant promoting effect on the chemical solubility of elemental sulfur. The increase in the H₂S concentration promotes the solution of elemental sulfur in the gas phase in general and significantly promotes the chemical solution of elemental sulfur. The effect on elemental sulfur solubility can be neglected when the molar concentration of CO₂ in the gas phase does not exceed 10%. Full article

This paper presents an analysis of bio-oil quality depending on the type of input biomass, the process conditions and the catalytic systems used. Analysis of various catalytic system choices showed the prospects of using nickel and iron metal salts as homogeneous catalysts given that their use provided increases of 24.5% and 22.2%, respectively, in the yield of light-boiling bio-oil fractions (with a boiling point of up to 350 °C). Composition analysis of the bio-oils carried out using gas chromatography and nuclear magnetic resonance spectroscopy showed that fatty acids are the predominant group of substances in bio-oils produced from sewage sludge. Bio-oil synthesized from bark and wood waste contains phenolic alcohols and a limited range of cyclic hydrocarbons as the main components. In bio-oil produced from macroalgae, oxygen and nitrogen compounds of the piperazinedione and amides type are predominant. The sulfur and nitrogen content in all types of bio-oils is at an acceptable level. The results allow researchers to assert that organic waste processing enables production of sufficiently high-quality fuel, which can then be jointly processed with natural oil. Bio-oil produced from secondary sludge has the best quality, characterized by a high content of low-weight aliphatic compounds (with a boiling point of up to 350 °C), along with insignificant levels of nitrogen, sulfur and oxygen. Full article

Lignin is the second-most available biopolymer in nature. In this work, lignin was employed as the carbon precursor for the one-step synthesis of sulfur-doped nanoporous carbons. Sulfur-doped nanoporous carbons have several applications in scientific and technological sectors. In order to synthesize sulfur-doped nanoporous carbons from lignin, sodium thiosulfate was employed as a sulfurizing agent and potassium hydroxide as the activating agent to create porosity. The resultant carbons were characterized by pore textural properties, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The nanoporous carbons possess BET surface areas of 741–3626 m²/g and a total pore volume of 0.5–1.74 cm³/g. The BET surface area of the carbon was one of the highest that was reported for any carbon-based materials. The sulfur contents of the carbons are 1–12.6 at.%, and the key functionalities include S=C, S-C=O, and SO_x. The adsorption isotherms of three gases, CO₂, CH₄, and N₂, were measured at 298 K, with pressure up to 1 bar. In all the carbons, the adsorbed amount was highest for CO₂, followed by CH₄ and N₂. The equilibrium uptake capacity for CO₂ was as high as ~11 mmol/g at 298 K and 760 torr, which is likely the highest among all the porous carbon-based materials reported so far. Ideally adsorbed solution theory (IAST) was employed to calculate the selectivity for CO₂/N₂, CO₂/CH₄, and CH₄/N₂, and some of the carbons reported a very high selectivity value. The overall results suggest that these carbons can potentially be used for gas separation purposes. Full article

Developing eco-friendly strategies to produce green fuel has attracted continuous and extensive attention. In this study, a novel gas-templating method was developed to prepare 2D porous S-doped g-C₃N₄ photocatalyst through simultaneous pyrolysis of urea (main g-C₃N₄ precursor) and ammonium sulfate (sulfur source and structure promoter). Different content of ammonium sulfate was examined to find the optimal synthesis conditions and to investigate the property-governed activity. The physicochemical properties of the obtained photocatalysts were analyzed by X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), scanning transmission electron microscopy (STEM), specific surface area (BET) measurement, ultraviolet-visible light diffuse reflectance spectroscopy (UV/vis DRS), X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) spectroscopy and reversed double-beam photo-acoustic spectroscopy (RDB-PAS). The as-prepared S-doped g-C₃N₄ photocatalysts were applied for photocatalytic H₂ evolution under vis irradiation. The condition-dependent activity was probed to achieve the best photocatalytic performance. It was demonstrated that ammonium sulfate played a crucial role to achieve concurrently 2D morphology, controlled nanostructure, and S-doping of g-C₃N₄ in a one-pot process. The 2D nanoporous S-doped g-C₃N₄ of crumpled lamellar-like structure with large specific surface area (73.8 m² g⁻¹) and improved electron−hole separation showed a remarkable H₂ generation rate, which was almost one order in magnitude higher than that of pristine g-C₃N₄. It has been found that though all properties are crucial for the overall photocatalytic performance, efficient doping is probably a key factor for high photocatalytic activity. Moreover, the photocatalysts exhibit significant stability during recycling. Accordingly, a significant potential of S-doped g-C₃N₄ has been revealed for practical use under natural solar radiation. Full article

Allium tenuissimum L. as a kind of food condiment in northern China, is popular among more and more consumers owning to its special flavor from the flower. However, its composition has not been widely studied. Hence, the aim of this study was to investigate the chemical composition and antimicrobial and antioxidant activity of essential oil from Allium tenuissimum L. flowers. Gas chromatography–mass spectrometry (GC-MS) was applied to detect the chemical composition. The antimicrobial activity against foodborne pathogens was evaluated by measuring the zones of inhibition (ZOI), the minimal inhibitory concentration (MIC), and the minimal bactericidal concentration (MBC). The antioxidant effect was tested by the scavenging capacity on DPPH, ABTS⁺•, and •OH. The results of GC-MS showed that 72 volatile components were isolated and the structures 68 of them were identified, which comprised about 91.92% of the total composition of the oil. Among these compounds, terpenoid compounds and sulfurous compounds had the highest contents, especially dimethyl trisulfide. Our investigation demonstrated that the essential oil has better antimicrobial efficiency to Staphylococcus aureus, Bacillus subtilis, Escherichia coli, Aspergillus flavus, and Saccharomyces cerevisiae. In addition, the essential oil had a strong stability to UV. Furthermore, the essential oil exhibited a high radical-scavenging effect on DPPH, ABTS⁺•, and •OH, which is significant for application in the food industry. In conclusion, the essential oil could be used as an inexpensive and natural antibacterial and antioxidant agent in food. Full article

Since 1 January 2020, the sulfur content allowed in exhaust gas plume generated by marine vessels decreased to 0.5% m/m. To be compliant, a hybrid scrubber was installed on-board, working in closed loop and generating a high volume of alkaline wastewater. The alkaline water suspension was treated by a silicon carbide multitubular membrane to remove pollutants, and to allow the water discharge into the natural environment. In this paper, membrane filtration behavior was analyzed for the maritime scrubber wastewater. A range of operating parameters were obtained for several feedwater quality-respecting industrial constraints. The objective was an improvement of (I) the water recovery rate, (II) the filtration duration, and (III) the permeate quality. Thus, in high-fouling water, a low permeate flow (60 L h⁻¹ m⁻²) with frequent backflushing (every 20 min) was used to maintain membrane performance over time. In terms of water quality, the suspended solids and heavy metals were retained at more than 99% and 90%, respectively. Other seawater discharge criteria in terms of suspended solids concentration, pH, and polyaromatic hydrocarbons were validated. The recommended operating conditions from laboratory study at semi-industrial scale were then implemented on a vessel in real navigation conditions with results in agreement with expectations. Full article

The Uragen giant sandstone-hosted Zn–Pb deposit has a proven reserve of 5.90 Mt metals in the southern ore zone and potentially 10 Mt metals for the whole deposit, and orebodies are strictly confined to the bleached clastic rocks of the Lower Cretaceous red beds. The bleaching has been used to guide lead–zinc exploration; however, its nature and origin, as well as the relationship with Zn–Pb mineralization, remains unclear, although it is closely related to regional oil–gas infillings. Detailed field investigation and petrographic observation, TESCAN-integrated mineral analyzer (TIMA), and X-ray fluorescence (μ-XRF) analysis of the red and bleached sandstone at the same sedimentary layer demonstrate that the bleaching is mainly caused by the reductive dissolution of hematite pigment, which probably resulted from the interaction with H₂S formed by in situ sulfate reduction during hydrocarbon migration. The calcite cements in the bleached sandstones show δ¹³C and δ¹⁸O values of −5.36~−5.94‰ and 20.94~27.91‰, respectively, and these samples fall close to the evolution line of decarboxylation of organic matter in δ¹³C-δ¹⁸O diagram, also suggesting a genetic relationship between the bleaching and hydrocarbon-bearing fluids. Petrol–mineral composition changes and sulfide characteristics of red, bleached, mineralized zones, as well as pyrite locally replaced by coarse-grained galena in the mineralized zone, imply that the bleaching may occurred before Zn–Pb mineralization. Mass balance calculation and μ-XRF analysis indicate that large amounts of Fe and minor Zn were extracted from red beds with little or no sulfates; however, the red beds with abundant sulfates may be a sink for leached ore metals during the bleaching process. We therefore propose that the former accumulations of iron sulfides and reduced sulfur in the bleached zones may provide an ideal chemical trap for later Zn–Pb mineralization, and the bleached zones with high ∑S contents are the favorable prospective targets of the Uragen-style sandstone-hosted Zn–Pb deposits. Full article

Biogas, with its high carbon dioxide content (30–50 vol%), is an attractive feed for catalytic methanation with green hydrogen, and is suitable for establishing a closed carbon cycle with methane as energy carrier. The most important questions for direct biogas methanation are how the high methane content influences the methanation reaction and overall efficiency on one hand, and to what extent the methanation catalysts can be made more resistant to various sulfur-containing compounds in biogas on the other hand. Ni-based catalysts are the most favored for economic reasons. The interplay of active compounds, supports, and promoters is discussed regarding the potential for improving sulfur resistance. Several strategies are addressed and experimental studies are evaluated, to identify catalysts which might be suitable for these challenges. As several catalyst functionalities must be combined, materials with two active metals and binary oxide support seem to be the best approach to technically applicable solutions. The high methane content in biogas appears to have a measurable impact on equilibrium and therefore CO₂ conversion. Depending on the initial CH₄/CO₂ ratio, this might lead to a product with higher methane content, and, after work-up, to a drop in-option for existing natural gas grids. Full article

Ships are an important part in international trade transportation and a major source of pollution. Therefore, the International Maritime Organization (IMO) implemented an amendment to the International Convention for the Prevention of Pollution from Ships (MARPOL) Annex VI, which stipulates that the sulfur content in marine fuel oil shall not exceed 0.5 wt.% starting in 2020. In order to meet the IMO low sulfur policy, shipping lines could adopt one of the following strategies: (1) using very low sulfur fuel oil (VLSFO), i.e., with sulfur content less than 0.5 wt.%; (2) installing scrubbers or other exhaust gas aftertreatment systems; or (3) replacing current fuels with clean alternative fuels such as natural gas. This study evaluates the feasibility and benefits of these strategies for shipping lines in order to determine the most cost-effective measures. First, according to the feasibility of the strategies evaluated by SWOT analysis, although scrubbers can reduce emissions of sulfur oxides into the atmosphere, more and more countries are restricting the discharge of wastewater from open-loop scrubbers into their waters. Instead, VLSFO and liquefied natural gas (LNG) are good choices in terms of environmental protection and economic benefits. Therefore, this study further evaluates the two strategies of replacing high sulfur fuel oil (HSFO) with VLSFO and converting diesel engines to LNG engines based on a cost-benefit methodology. This study took an 8500 TEU container vessel, which is powered by a marine diesel engine with the nominal power of 61,800 kW, sailing the Asian-European route as an example, and calculated the total incremental costs, pollutant emission reductions, and cost benefits arising from the implementation of the VLSFO and LNG strategies, respectively. According to the results of this study, the total incremental cost of LNG is higher than that of VLSFO in the first 4.7 years, but this gradually decreases, making the gap of the total incremental costs between the two strategies wider year by year. In comparison with using HSFO without any improvement, the total incremental costs of the VLSFO and LNG strategies increase by 12.94% and 22.16% over the following five years, respectively. The use of LNG can significantly reduce SOx, PM, NOx, and CO₂ emissions; on the other hand, it leads to more CH₄ emissions than the VLSFO strategy. Compared to doing nothing, the cumulative reduction rates of SOx, PM, NOx, and CO₂ emissions over the next five years after the adoption of the LNG strategy are 3.6%, 7.0%, 70.4%, and 15.7%, respectively. The higher emission reduction rates of LNG compared to VLSFO illustrate that the former has a good effect on the suppression of exhaust gas pollution. In terms of the cost-benefit evaluation of the two strategies, this study shows that the VLSFO strategy is more cost-effective than the LNG strategy in the first 2.5 years, but that the cost-benefit ratio of the latter increases year by year and exceeds that of the former, and the gap between them widens year by year. Based on the evaluation results of this study, the LNG strategy is suitable for ocean-going container vessels with fixed routes and younger or larger sized vessels to meet the IMO low sulfur policy. In contrast, the VLSFO strategy is appropriate for old merchant ships with fewer container spaces. LNG is a suitable medium- and long-term strategy, i.e., for more than 2.5 years, for shipping lines to meet the IMO low sulfur policy, while VLSFO is a suitable short-term strategy. Full article

The necessity of economical and rational use of natural energy sources caused a rapid development of research on the possibilities of using non-conventional energy resources. Taking the above into account, a new technological process of thermochemical conversion of biomass and communal waste, commonly known as High Temperature Air/Steam Gasification (HTA/SG) and Multi-Staged Enthalpy Extraction Technology (HTAG-MEET), was developed. In relation to traditional techniques of gasification or combustion of hydrocarbon fuels, the presented concept is characterized by higher thermal efficiency of the process, low emission of harmful compounds of carbon, sulfur, nitrogen, dioxins, furans and heavy metals. The use of a high-temperature gasification factor causes an increased thermochemical decomposition of solid fuels, biomass and municipal waste into gaseous fuel (syngas), also with increased hydrogen content and Lower Calorific Value (LCV). In this study, the possibility of using a batch type reactor (countercurrent gasifier) was analyzed for gasification of biomass and municipal waste in terms of energy recovery and environmental protection. The proposed research topic was aimed at examining the possibility of using the thermal utilization of biomass and municipal waste through their high-temperature decomposition in the presence of air, a mixture of air and steam. The main goals of the research were achieved during the implementation of several parallel stages of the schedule, which included, primarily: (a) study of the possibility of using thermal utilization of biomass and municipal waste through their high-temperature gasification in the presence of air or a mixture of air and steam and, secondary (b) analytical and numerical modeling of high-temperature gasification of biomass and municipal waste with the use of ANSYS CFD Fluent 6.3 software. Selected results of the experimental and numerical studies are properly presented. The higher temperature gasification concept shows the capability of this technology for maximizing the gaseous product yield in an up-draft fixed bed gasifier. It was also observed that at a high temperature, steam addition contributed to the thermal conversion of biofuels to gas with higher production of hydrogen. Full article