Search Results (1,621)

In response to the issues of microcrack susceptibility, high brittleness, and unstable mechanical properties of desert sand recycled aggregate concrete (DSRAC), this study experimentally investigated the mechanical performance of DSRAC reinforced with hybrid steel–FERRO fibers. By testing macroscopic properties (compressive, splitting tensile, and flexural strengths) under different desert sand replacement ratios and fiber dosages, combined with microscopic analysis, the fiber-matrix interfacial behavior and toughening mechanism were clarified. The results showed that (1) DSRAC achieved optimal compressive strength when desert sand replaced 30% natural sand, with an obvious early strength enhancement; (2) both steel fibers and FERRO fibers independently improved DSRAC’s mechanical properties, while their hybrid combination (especially F0.15-S0.5 group) exhibited a superior synergistic strengthening effect, significantly outperforming single-fiber groups; (3) the established constitutive model accurately described the stress–strain response of hybrid fiber-reinforced DSRAC; (4) microscopic observations confirmed fibers inhibited crack propagation via bridging and stress dispersion, with hybrid fibers exerting multi-scale synergistic effects. This study provided theoretical–technical support for resource utilization of desert sand and recycled aggregates, and offered practical references for localized infrastructure materials (e.g., rural road subgrades and small-span culverts) in desert-rich regions and high-value reuse of construction waste in prefabricated components, advancing eco-friendly concrete in sustainable construction. Full article

This study investigates the feasibility of landfill expansion using the limit equilibrium and finite element methods. A 15.5 m high reinforced fill structure (RFS) was analyzed to assess how fill type, consolidation rate, geometric configuration, waste strength, compaction and the inclusion of banquettes affect horizontal displacement, differential settlement, reinforcement strain and facing behavior. The baseline configuration demonstrated acceptable settlement, reinforcement strain, and gabion performance but exceeded allowable horizontal displacement limits. The scenarios including increasing consolidation rate and substitution with sand backfill further aggravated displacements, whereas banquettes significantly reduced lateral movement and settlement, demonstrating their effectiveness in stabilizing slopes. Enhancing the industrial waste properties decreased displacements substantially improving overall stability. Geometric modifications, such as widening the reinforced zone, enhanced displacement control, while higher compaction achieved the best global performance, albeit with increased gabion compressibility. Extending geogrid length provided only marginal improvements beyond a certain threshold. Overall, banquettes, enhanced waste properties, and improved compaction were identified as the most effective strategies for stable efficient landfill expansion, emphasizing the importance of displacement control and reinforcement–facing interaction. Full article

Flexible polyurethane foam (FPUF) is widely used in buffer protection, biomedical, and wearable fields due to its light weight, high resilience, and adjustable mechanical properties. However, the traditional water foaming system is often accompanied by bottleneck problems such as cyclic fatigue attenuation, insufficient thermal stability, and surface hydrophilicity while achieving low density. In this study, a dense Si-O-Si cross-linked layer was in situ constructed on the surface of the foam by systematically regulating the water content of the foaming agent (1.5~2.5 wt%) and coupling with methyltrimethoxysilane (MTMS) chemical vapor deposition. Experiments show that the foam foamed with 2 wt% water content still maintains 0.0466 MPa compressive strength and 0.0532 MPa compressive modulus (modulus loss is only 16.6%) after 500 cycles of compression at 90% strain after MTMS deposition. MTMS modification drives the surface wettability to change from hydrophilic (70.4°) to hydrophobic (128.7°), and significantly improves thermal stability (the carbon residue rate at 800 °C increased to 25.5%, an increase of 59.4%). This study not only improves the resilience, but also endows the FPUF surface with hydrophobicity and thermal protection ability, which provides the feasibility for its wide application. Full article

This study focuses on the performance evolution of Engineering Geopolymer Composites (EGCs) in long-term thermal environments, investigating the mechanical properties and microstructural evolution of alkali-activated fly ash–slag composites under sustained 60 °C thermal conditions. The research results indicate that sustained exposure to 60 °C significantly enhances the static and impact loading compressive strength of EGCs; however, single-slag or high-alkalinity systems exhibit strength retrogression due to insufficient long-term thermal stability. After exposure to elevated temperatures, the tensile strain-hardening curve of EGCs becomes smoother, with a reduced number of cracks but increased crack width, leading to a transition from a distributed multicrack propagation pattern to rapid widening of primary cracks. Due to the bridging effect of PVA fibers, sustained elevated temperature significantly enhances the peak impact load stress of the S50-6 sample. Microscopic analysis attributes this improvement to the matrix-strengthening effect caused by accelerated C-(A)-S-H gel polymerization and refined pore structure under continuous heat, as well as the energy dissipation role of the fiber system. The study recommends an optimal EGC system formulation with a fly ash–slag mass ratio of 1:1 and a Na₂O concentration of 4–6%. This research provides a theoretical foundation for understanding the performance evolution and strength stability of EGC materials under sustained elevated temperature. Full article

14CrMoR steel, possessing excellent low-temperature impact toughness and corrosion resistance, is an important material for core equipment in the coal chemical industry. In this paper, 14CrMoR steel was subjected to single-pass compression tests at deformation temperatures ranging from 900 to 1150 °C and strain rates of 0.1, 1, 5, and 10 s⁻¹. The hot deformation behavior and constitutive relationship were investigated. The strain rate sensitivity factor m, power dissipation coefficient η, and instability parameter ξ were calculated, respectively. A power dissipation map was plotted, and a hot processing map was established. The results showed that the stress of 14CrMoR steel increased with the decrease in deformation temperature and the increase in strain rate. Dynamic recrystallization was likely to occur at high deformation temperatures and low strain rates. When the strain rate was 10 s⁻¹, in the temperature range of 900–950 °C, the power dissipation rate was the lowest. With the increase in temperature, the power dissipation rate rose, and the maximum power dissipation rate was reached in the temperature range of 1100–1150 °C. The research on the hot deformation behavior of 14CrMoR steel has important guiding significance for the design and optimization of the process. Full article

Coal gangue manufactured sand (CGS), a sustainable substitute for natural sand, offers both resource and environmental benefits; however, the micro-mechanisms underlying performance deterioration at different replacement levels remain unclear. In this study, cube specimens with 25%, 50%, 75%, and 100% CGS were tested in uniaxial compression, and the results were integrated with PFC2D discrete-element simulations and SEM observations to establish an energy–force-chain–crack coupling framework. Experiments and simulations showed close agreement in peak stress, peak strain, and overall curve shape (errors generally <5%). With increasing replacement, the interfacial transition zone (ITZ) evolves from a dense three-phase ITZ (NS–CGS–CA; natural sand–CGS–coarse aggregate) to a degraded two-phase ITZ (CGS–CA), accompanied by more pores and microcracks; the proportion of Adhesive cracks decreases while Cohesive (intra-particle) cracks increase. Concurrently, continuous force-chain networks deteriorate into localized short-chain clusters; the peak and fraction of strain-energy decrease, whereas frictional/damping dissipation rises—together driving a macroscopic transition from ductile to brittle behavior. At 28 d, SEM images and DEM evolution of cracks/force chains/energy exhibit strong consistency, further confirming that low replacement (25% and 50%) favors stable load-transfer paths and suppresses early cracking, whereas high replacement (75% and 100%)—through ITZ degradation and force-chain instability—induces more concentrated cracking and higher energy dissipation, thereby diminishing mechanical performance. Full article

This study investigates the impact of expanding and reducing deformation ratios on the performance of L360 straight-seam welded pipes formed by the JCO process for offshore oil and gas transportation. The Split Hopkinson Pressure Bar (SHPB) experimental technique was used to examine the stress/strain relationships, yield strength, and compressive strength of the pipe materials subjected to high strain rates. The results indicated that the impact performance of the pipes significantly improves with both expansion and reduction processes, demonstrating an enhancement effect of deformation. The impact of yield strength and compressive strength increases with higher expansion ratios, reaching maximum values of 1009 MPa and 847 MPa, respectively, at an expansion ratio of 1.2%. At a reduction ratio of 0.8%, the impact yield strength increased by 64% and the compressive strength by 14%. These findings not only provide theoretical support for optimizing the expansion and reduction processes and their associated equipment but also have direct and significant practical implications for enhancing the performance and safety of offshore oil and gas transmission pipelines, thereby contributing to the advancement of the field. Full article

With 23.4 billion pairs made and 22 billion discarded in 2023, post-consumer footwear waste is a major environmental challenge, demanding a shift toward circular economy practices. In this work, post-consumer footwear waste is repurposed into thermal/acoustic insulation materials for building construction, producing four needle-punched nonwovens (two of them compressed) composed of a post-consumer leather (30%) and footwear waste mixture (40%) with recycled polyester fibers. Nonwovens exhibited higher strain values (95.9 and 77.1% for leather residue and footwear mixture residue, respectively) but lower tensile strength (1694 and 104.9 kPa) and Young’s modulus (1767.8 and 136.10 kPa). The compressed nonwovens demonstrated higher tensile strength (7360 and 3559 kPa) and Young’s modulus values (12992 and 4020.4 kPa) and reduced strain (56.6 and 96.9%). The thermal conductivity results revealed that the nonwovens exhibited lower values (0.040 and 0.046 W/(m·K)), indicating better insulation performance when compared with their compressed counterparts (0.060 and 0.058 W/(m·K)). The nonwovens demonstrated high sound absorption at higher frequencies, reaching peak absorption coefficients of 0.917 and 0.995, ideal for acoustic insulation. The compressed nonwovens exhibited improved absorption at lower and mid-frequencies, with maximum values of 0.510 and 0.519. Given the current lack of applications for recycled materials derived from post-consumer footwear, the findings offer a novel approach to address their recycling. Full article

Marine shale is highly prone to wellbore collapse due to its high pore pressure, propensity for hydration and swelling, distinct bedding planes, and low tensile strength. Horizontal in situ stress serves as a critical parameter for wellbore stability analysis; however, its accurate prediction is extremely challenging in complex geological environments. Conventional studies often simplify the wellbore as a circular shape, neglecting its natural elliptical deformation under non-uniform in situ stress, which leads to reduced predictive accuracy. To address this limitation, this study establishes an elliptical wellbore model that incorporates the strain-softening characteristics of shale. Theoretical models for stress distribution in both elastic and plastic zones were derived. The strain-softening behavior was validated through triaxial compression tests, providing a foundation for analytical solutions of stress distributions around circular and elliptical wellbores. Furthermore, an elliptical wellbore-based model was developed to derive a new prediction equation for horizontal in situ stress. Numerical programming was employed to compute stress distributions, and finite element simulations under various aspect ratios corroborated the theoretical results, showing excellent agreement. Results demonstrate that the elliptical wellbore model captures the near-wellbore stress state more accurately. As the aspect ratio increases, the extreme values of radial and tangential stresses increase significantly, with pronounced stress concentrations observed around the 180° and 360° positions. Predictions of horizontal in situ stress based on the proposed model achieved over 89% accuracy when verified against field data, confirming its reliability. This study overcomes the limitations inherent in the traditional circular wellbore assumption, providing a more precise analytical method for wellbore stability assessment in Marine shale under complex geological conditions. The findings offer a valuable theoretical basis for wellbore stability management and drilling engineering design. Full article

The deformation mechanism during the hot compression of PM nickel-based superalloy FGH99 and its micro-structural evolution, especially the evolution of γ’ phases, are the key factors affecting the final molding quality of aero-engine hot forged turbine disks. In this study, a new constitutive model of viscoplasticity with micro-structures as physical internal parameters were developed to simulate the hot compression behavior of FGH99 by incorporating the strengthening effect of the γ’ phase. The mechanical behavior of high-temperature (>1000 K) compressive deformation of typical superalloys under a wide strain rate (0.001~1 s⁻¹) is investigated using the Gleeble thermal-force dynamic simulation tester. The micro-structure after the hot deformation was characterized using EBSD and TEM. Work hardening as well as dynamic softening were observed in the hot compression tests. Based on the mechanical responses and micro-structural features, the model considered the coupled effects of dislocation density, DRX, and γ’ phase during hot flow. The model is programmed into a user subroutine based on the Fortran language and called in the simulation of the DEFORM-3D V6.1 software, thus realizing the multiscale predictive simulation of FGH99 alloy by combining macroscopic deformation and micro-structural evolution. The established viscoplastic constitutive model shows a peak discrepancy of 10.05% between its predicted hot flow stresses and the experimental values. For the average grain size of FGH99, predictions exhibit an error below 7.20%. These results demonstrate the high accuracy of the viscoplastic constitutive model developed in this study. Full article

Clarifying the differential effects of temperature gradient and temperature change rate on the evolution of rock fractures and damage mechanism under thermal shock is of great significance for the development and utilization of deep geothermal resources. In this study, granite samples at different temperatures (20 °C, 150 °C, 300 °C, 450 °C, 600 °C, and 750 °C) were subjected to rapid cooling treatment with liquid nitrogen. After the thermal treatment, a series of tests were conducted on the granite, including wave velocity test, uniaxial compression experiment, computed tomography scanning, and scanning electron microscopy test, to explore the influence of thermal shock on the physical and mechanical parameters as well as the meso-structural damage of granite. The results show that with the increase in heat treatment temperature, the P-wave velocity, compressive strength, and elastic modulus of granite gradually decrease, while the peak strain gradually increases. Additionally, the failure mode of granite gradually transitions from brittle failure to ductile failure. Through CT scanning experiments, the spatial distribution characteristics of the pore–fracture structure of granite under the influence of different temperature gradients and temperature change rates were obtained, which can directly reflect the damage degree of the rock structure. When the heat treatment temperature is 450 °C or lower, the number of thermally induced cracks in the scanned sections of granite is relatively small, and the connectivity of the cracks is poor. When the temperature exceeds 450 °C, the micro-cracks inside the granite develop and expand rapidly, and there is a gradual tendency to form a fracture network, resulting in a more significant effect of fracture initiation and permeability enhancement of the rock. The research results are of great significance for the development and utilization of hot dry rock and the evaluation of thermal reservoir connectivity and can provide useful references for rock engineering involving high-temperature thermal fracturing. Full article

Concrete materials undergo a series of physical and chemical changes under high temperature, leading to the degradation of mechanical properties. This study investigates basalt fiber-reinforced concrete (BFRC) through high-temperature testing using the split Hopkinson pressure bar (SHPB) apparatus. Impact compression tests were conducted on specimens after exposure to elevated temperatures to analyze the effects of varying fiber content, temperature levels, and impact rates on the mechanical behaviors of BFRC. Based on fractional calculus theory, a dynamic constitutive equation was established to characterize the viscoelastic properties and high-temperature damage of BFRC. The results indicate that the dynamic compressive strength of BFRC decreases significantly with increasing temperature but increases gradually with higher impact rates, demonstrating fiber-toughening effects, thermal degradation effects, and strain rate strengthening effects. The proposed constitutive model aligns well with the experimental data, effectively capturing the dynamic mechanical behaviors of BFRC after high-temperature exposure, including its transitional mechanical characteristics across elastic, viscoelastic, and viscous states. The viscoelastic behaviors of BFRC are fundamentally attributed to the synergistic response of its multi-phase composite system across different scales. Basalt fibers enhance the material’s elastic properties by improving the stress transfer mechanism, while high-temperature exposure amplifies its viscous characteristics through microstructural deterioration, chemical transformations, and associated thermal damage. Full article

Developing high-activity and high-durability Pd-based electrocatalysts is an important strategy to promote their commercial application. Herein, a smaller particle size and ultrathin sheet-like PdCu alloy metallene (PdCuene) were successfully prepared by using a one-pot wet chemistry method for FAOR. Experimental measurements indicated that the introduction Cu into Pd lattice induces a significant compressive strain effect through lattice mismatch between Pd and Cu, and the strain effect optimizes the electronic structure of Pd, as well as the high electrochemical surface area, increased exposure of active sites, and appropriate lattice strain have been demonstrated as factors that influence the enhancement of intrinsic activity and the acceleration of kinetics, thereby improving FAOR performance. Moreover, the stronger lattice strain of 0.85% would facilitate surface adsorption and dissociation of formic acid. Specifically, the optimized PdCuene exhibits enhanced mass activity and specific activity with current densities of 2.31 A mg_Pd⁻¹ and 4.09 mA cm⁻², respectively, which transcend the activities of Pd metallene (1.44 A mg_Pd⁻¹ and 2.73 mA cm⁻²) and commercial Pd/C (0.6 A mg_Pd⁻¹ and 1.53 mA cm⁻²). Meanwhile, PdCuene displayed obvious enhanced durability. The work provides an approach to modulate the lattice strain engineering, which represents a highly promising strategy for designing efficient FAOR electrocatalysts. Full article

The mechanical properties of screw-thread steel bars used for prestressing concrete and their threaded ribs’ bearing mechanism have not been quantitatively studied, in contrast to the extensive qualitative research on ordinary steel mechanical connection splices. A quantitative investigation was conducted under various design parameters and working conditions to examine the mechanical connection splices of screw-thread steel bars used for prestressing concrete. The splices’ connection performance and their threaded ribs’ bearing mechanism were also examined. Analyzing the force on the threads of the splices under monotonic tensile loading allowed for the theoretical computation of the axial force coefficients for threaded ribs. The validated revised three-dimensional numerical model of splices is based on the findings of the theoretical calculations. Afterwards, rigorous numerical simulations of monotonic tensile loading, repeated tensile and compressive loading with high stress, and repeated tensile and compressive loading with large strain were performed on 45 splices with varying nominal rebar diameters, coupler outer diameters and lengths, and thread rib spacings. The results show that rebar pullout and rebar fracture are the two main ways in which splices might fail. After cyclic loading, the splices’ ultimate bearing capacity changed by 0.83% to 2.81%, and their ductility changed by 2.13% to 4.75% compared to after monotonic tensile loading. Although the splice load-carrying capacity and plastic deformation capacity were reduced by 2.11%~7.48% and 3.98%~25.78%, respectively, when the thread rib spacing was increased from the specified value to 0.6~0.8 times the nominal diameter of the rebar, the splice connection performance was still able to meet the requirements for class I splices. Approximately half of the splices’ load-bearing capability is provided by the 1–2 turns of threads close to the coupler ends; after cyclic loading, their stress rises by between 4.52% and 12.63% relative to monotonic tension. Stresses in all threaded ribs of the splices are increased by 5.49% to 27.76% as the distance between the threaded ribs increases to 1.0 and 1.2 times the nominal diameter of the rebar, which reduces the splice’s load-bearing capacity. Full article

To investigate the failure characteristics and high-strain-rate mechanical response of polyvinyl alcohol-modified alkali-activated materials (PAAMs) under static and dynamic impact loads, quasi-static and uniaxial impact compression tests were performed on AAMs with varying PVA content. These tests employed a universal testing machine and an 80 mm diameter split Hopkinson pressure bar (SHPB). Digital image correlation (DIC) was then utilized to study the surface strain field of the composite material, and the crack propagation process during sample failure was analyzed. The experimental results demonstrate that the compressive strength of AAMs diminishes with higher PVA content, while the flexural strength initially increases before decreasing. It is suggested that the optimal PVA content should not exceed 5%. When the strain rate varies from 25.22 to 130.08 s⁻¹, the dynamic compressive strength, dissipated energy, and dynamic compressive increase factor (DCIF) of the samples all exhibit significant strain rate effects. Furthermore, the logarithmic function model effectively fits the dynamic strength evolution pattern of AAMs. DIC observations reveal that, under high strain rates, the crack mode of the samples gradually transitions from tensile failure to a combined tensile–shear multi-crack pattern. Furthermore, the crack propagation rate rises as the strain rate increases, which demonstrates the toughening effect of PVA on AAMs. Full article