Search Results (4,957)

Hydrogen, as an alternative energy carrier, presents significant prospects for the transition to more environmentally friendly energy solutions. However, its efficient and safe storage remains a challenge, as materials with high adsorbent capacity and long-term storage capability are required. This study focuses on the synthesis and characterization of a composite material comprising carbon fiber and manganese dioxide (MnO₂/CFs), for the purpose of hydrogen storage. Carbon fiber was chosen as the basis for the composition of the composite material due to its large active surface area and its excellent mechanical, thermal, and electrochemical properties. The deposition of MnO₂ on the surface of carbon fibers took place through two different synthetic pathways: electrochemical deposition and chemical synthesis under different conditions. The electrochemical method enabled the production of a greater amount of oxide with optimized structural and chemical properties, whereas the chemical method was simpler but required more time to achieve comparable or lower-capacity performance. Elemental analysis of the electrochemically produced composites showcased an average of 40.5 ± 0.05 wt% Mn presence, which is an indicator of the quantity of MnO₂ on the surface responsible for hydrogen storage, while the chemically produced composites showcased an average of 7.6 ± 0.05 wt% Mn presence. Manganese oxide’s high specific capacity and reversible redox reaction participation make it suitable for hydrogen storage applications. The obtained results of the hydrogenated samples through physicochemical characterization indicated the formation of the MnOOH intermediate. Regarding these findings it may be remarked that carbon fiber/MnO₂ composites are promising candidates for hydrogen storage technologies. Finally, the fabricated carbon fiber/MnO₂ composites were applied successfully as working electrodes for analysis of the [Fe(CN)₆]^3−/4− redox system in aqueous KCl solutions. Full article

Petroleum-based plastics are non-renewable and degrade poorly, persisting in the environment and causing serious ecological pollution, so urgent development of alternatives is needed. In this study, all-bamboo fiber thermosetting plastics (BTPs) were successfully prepared through selective sodium periodate oxidation of bamboo fibers followed by hot-pressing. The results demonstrate that the oxidation treatment effectively enhanced fiber reactivity and facilitated the formation of dense composite materials during hot-pressing. Compared with petroleum-based plastics (e.g., PVC), BTPs exhibit outstanding mechanical properties: flexural strength reaches 100.73 MPa, tensile strength reaches 83.31 MPa, while the 72 h water absorption and thickness swelling rates are as low as 5.36% and 4.59%, respectively. This study also reveals the mechanism by which residual lignin affects material microstructure formation through competitive oxidation reactions. Although it imparts initial hydrophobicity, it hinders complete fiber activation, leading to the formation of micro-defects. Furthermore, BTPs can completely degrade in 1% NaOH solution within 24 h, demonstrating excellent degradability. This research provides a new strategy for developing high-performance, degradable all-bamboo-based materials and promotes the value-added utilization of bamboo resources. Full article

This work presents the design, modeling, and experimental validation of an innovative, highly autonomous, and economically viable photovoltaic solar cooker, integrating a robust battery storage system. The system combines 1200 Wp photovoltaic panels, a control block with DC/DC power converters and digital control for intelligent energy management, and a thermally insulated heating plate equipped with two resistors. The objective of the system is to reduce dependence on conventional fuels while overcoming the limitations of existing solar cookers, particularly insufficient cooking temperatures, the need for continuous solar orientation, and significant thermal losses. The optimization of thermal insulation using a ceramic fiber and glass wool configuration significantly reduces heat losses and increases the thermal efficiency to 64%, nearly double that of the non-insulated case (34%). This improvement enables cooking temperatures of 100–122 °C, heating element surface temperatures of 185–464 °C, and fast cooking times ranging from 20 to 58 min, depending on the prepared dish. Thermal modeling takes into account sheet metal, strengths, and food. The experimental results show excellent agreement between simulation and measurements (deviation < 5%), and high converter efficiencies (84–97%). The integration of the batteries guarantees an autonomy of 6 to 12 days and a very low depth of discharge (1–3%), allowing continuous cooking even without direct solar radiation. Crucially, the techno-economic analysis confirmed the system’s strong market competitiveness. Despite an Initial Investment Cost (CAPEX) of USD 1141.2, the high performance and low operational expenditure lead to a highly favorable Return on Investment (ROI) of only 4.31 years. Compared to existing conventional and solar cookers, the developed system offers superior energy efficiency and optimized cooking times, and demonstrates rapid profitability. This makes it a sustainable, reliable, and energy-efficient home solution, representing a major technological leap for domestic cooking in rural areas. Full article

This study investigates the synergistic effects of steel fibers and waste rubber powder on the properties of ultra-high-performance concrete (UHPC) to advance its sustainable development. A comprehensive experimental program was conducted, incorporating three types of steel fibers (8 mm straight, and 14 mm and 20 mm hook-end) at volumes up to 2.5%, and rubber powder as quartz sand replacement at levels from 5% to 30%. The flowability, compressive strength, splitting tensile strength, abrasion resistance, and chloride ion penetration resistance of the mixtures were evaluated. The results indicate that steel fiber reinforcement significantly enhances the mechanical and durability properties. Specifically, a 2.5% steel fiber content increased the compressive strength, splitting tensile strength, and abrasion resistance by 28.9%, 55.3%, and 72.4%, respectively. Conversely, the incorporation of rubber powder improved flowability (optimal at 10% replacement) and abrasion resistance (increased by 41.1% at 30% content) but at the expense of reduced mechanical strength and increased chloride ion permeability. The primary novelty of this work lies in systematically quantifying the trade-offs and synergistic interactions between a wide range of steel fiber geometries and high-volume rubber powder content, providing a practical basis for designing UHPC with balanced performance and enhanced sustainability. Full article

We propose an external-cavity laser that combines wide tunability with narrow linewidth. The design utilizes a low-loss Si₃N₄ waveguide and a thermally tuned cascaded triple-ring resonator to enable continuous wavelength tuning. The numerical simulations indicate that the proposed laser exhibits a tuning range of 64 nm with a sub-kHz linewidth, an SMSR of more than 80 dB, an output power of 24 mW and a linewidth of 193 Hz at 1550 nm. Furthermore, we perform comparative system-level simulations using QPSK and 16QAM coherent optical fiber links at 50 Gbaud over 100 km. Under identical conditions, when the laser linewidth is reduced from 1 MHz level to 193 Hz, the BER of 16QAM decreases from 1.5 × 10⁻³ to 5.3 × 10⁻⁵. These results indicate that a narrow linewidth effectively mitigates phase noise degradation in high-order modulation formats. With its narrow linewidth, wide tuning range, high SMSR, and high output power, this laser serves as a promising on-chip light source for high-resolution sensing and coherent optical communications. Full article

The structural analysis of paper fibers is vital for the noninvasive classification and conservation of traditional handmade paper in cultural heritage. Although digital still cameras (DSCs) offer a low-cost and noninvasive imaging solution, their inferior image quality compared to white-light confocal microscopy (WCM) limits their effectiveness in fiber classification. To address this modality gap, we propose an unpaired image-to-image translation approach using cycle-consistent adversarial networks (CycleGANs). Our study targets a multifiber setting involving kozo, mitsumata, and gampi, using publicly available domain-specific datasets. Generated WCM-style images were quantitatively evaluated using peak signal-to-noise ratio, structural similarity index measure, mean absolute error, and Fréchet inception distance, achieving 8.24 dB, 0.28, 172.50, and 197.39, respectively. Classification performance was tested using EfficientNet-B0 and Inception-ResNet-v2, with F1-scores reaching 94.66% and 98.61%, respectively, approaching the performance of real WCM images (99.50% and 98.86%) and surpassing previous results obtained directly from DSC inputs (80.76% and 84.19%). Furthermore, Grad-CAM visualization confirmed that the translated images retained class-discriminative features aligned with those of the actual WCM inputs. Thus, the proposed CycleGAN-based image conversion effectively bridges the modality gap, enabling DSC images to approximate WCM characteristics and support high-accuracy paper fiber classification, which is a practical alternative for noninvasive material analysis. Full article

The mechanical properties of carbon fiber composites (CFRCs) are governed by the carbon fibers (CFs) themselves and the fiber–matrix interface (FMI), with the synergy between the two being crucial. This study focused on how microstructural heterogeneity affects the compression after impact (CAI) of the same epoxy resin (EP) composites. The research was conducted using two variants of dry-jet wet-spun T800G CFs, labeled CF-low and CF-high. The results indicated that while CF-low exhibited a higher number of deep axial grooves and a greater surface micro-zone compressive modulus, their pronounced skin–core structure and the excessively strong interfacial bonding formed by mechanical interlocking aggravated fiber core collapse and stress concentration under mechanical loading. In contrast, the homogeneous structure and moderate interfacial characteristics of CF-high facilitated efficient stress transfer between the CFs and EP. Compared with CF-low composites, CF-high composites exhibited a 9% increase in CAI strength and a 35% reduction in damage area, significantly improving the damage tolerance of the composites. This research underscores that optimizing the synergy between the fiber properties and the interfacial behavior is key to enhancing CFRC performance. Full article

This study investigates the differences in flexural behavior of ultra-high-performance concrete (UHPC) arising from variations in test methods and key experimental parameters. Flexural tensile tests were conducted on 51 specimens representing 17 combinations of test variables, including steel fiber length (13 mm and 19.5 mm), specimen cross-sectional dimensions (75 × 75 mm, 100 × 100 mm, and 150 × 150 mm), presence or absence of a notch, and loading configuration (three-point and four-point loading). The tests were performed in accordance with ASTM C1609 and EN 14651, and both deflection and crack mouth opening displacement (CMOD) were normalized by the span length to compare the influence of each parameter. The notched specimens demonstrated significantly improved reliability, exhibiting up to an 8.4-fold reduction in standard deviation due to the consistent initiation of cracking. Regarding size effects, the 75 × 75 mm specimens showed an overestimation of flexural performance due to the wall effect of fiber distribution, whereas the 100 × 100 mm and 150 × 150 mm specimens exhibited similar flexural responses. The comparison of loading configurations revealed that three-point loading produced up to 11.7% higher flexural tensile strength than four-point loading, attributable to concentrated moment–shear interaction and the combined effects of fiber bridging and shear resistance mechanisms. In addition, specimens with longer steel fibers (19.5 mm) exhibited 5.2–9.7% higher flexural performance than those with shorter fibers (13 mm), which is attributed to enhanced interfacial bonding and improved crack dispersion capacity. Full article

Traditional firefighting protective clothing materials, such as meta- and para-aramid fibers, provide significant thermal protection but often fail to adequately manage heat stress and moisture, especially due to the incorporation of semi-permeable membranes within the three-layer garment structure known as turnout gear. Integrating hydrogels into textiles for firefighting personal protective clothing (PPC) could enhance thermoregulation and moisture management, providing firefighters with improved comfort and safety. Hydrogels are three-dimensional, hydrophilic polymer networks capable of holding substantial amounts of water. Their high water content and excellent thermal properties make them ideal for cooling applications. Therefore, this review focuses on the potential of hydrogel-infused textiles to improve firefighters’ PPC by enhancing thermal comfort and moisture management. Specifically, hydrogel structures and engineered properties for enhanced performance are presented, including smart hydrogels and hydration customization mechanisms. Hydrogel integration into firefighting PPC for moisture management and improved thermoregulation is explored, including current and future market projections and state-of-the-art clinical trial findings. Overall, the future of hydrogel-integrated textiles for firefighting PPC is bright, with numerous advancements and trends poised to enhance the safety, comfort, and performance of protective gear. Full article

Human health is profoundly influenced by external factors, with stress being a primary contributor. In this context, the digestive system is particularly susceptible. The prevalence of diseases affecting the small intestine and colon is increasing. Consequently, insoluble plant fibers, such as cellulose and hemicellulose, play a crucial role in promoting intestinal transit and maintaining colon health. Lettuce is a widely consumed leafy vegetable with high nutritional value and has been intensively studied through hydroponic cultivation. This study aims to optimize the cultivation conditions and freeze-drying process of Lugano and Carmesi lettuce varieties (Lactuca sativa L.) by identifying the optimal growth conditions, freeze-drying duration, and sample surface area in order to achieve an optimal percentage of insoluble fibers. Carmesi and Lugano varieties were selected based on their contrasting growth characteristics and leaf morphology, allowing to assess whether treatments and processing conditions have consistent effects on different types of lettuce. The optimal freeze-drying parameters were determined to include a 48 h freeze-drying period, a maximum sample surface area of 144 cm², and growth under combined conditions of supplementary oxygenation and LED light exposure. The optimal fiber composition, cellulose (21.61%), hemicellulose (11.84%) and lignin (1.36%), was found for the Lugano variety, which exhibited lower lignin and higher cellulose contents than the Carmesi variety. The quantification of hemicellulose, cellulose and lignin was performed using the well-known NDF, ADF and ADL methods. Therefore, optimized freeze-dried lettuce powder, particularly from the Lugano variety, presents a high-value functional ingredient for enriching foods and developing nutritional supplements aimed at digestive health. Full article

Agave lechuguilla fibers exhibit high tensile strength, low density and durability, but their use in natural rubber composites is underexplored. This study investigates alkaline-treated fibers (149–180 µm) as reinforcements for natural latex. Fibers were pretreated with a methanol–acetone mixture, followed by immersion in 10% NaOH at 70 °C for 1 h, removing lignin and hemicellulose as confirmed by FTIR and SEM. Thermogravimetric analysis showed three weight-loss stages: moisture/volatiles (9.4%), hemicellulose (peak at 341 °C), and cellulose/lignin (peak at 482 °C), with <3% residue above 500 °C. Treated composites exhibited enhanced tensile strength (4.68 ± 1.2 MPa vs. 1.3 ± 0.8 MPa for untreated) and elongation at break (530 ± 51% vs. 452 ± 32%). Hardness increased from 21.8 (neat latex) to 30.3, and compression resistance was improved. Optical microscopy revealed strong fiber–matrix adhesion with uniform dispersion. Alkaline treatment enhances interfacial bonding and mechanical performance, making A. lechuguilla fibers a sustainable reinforcement for eco-friendly composites in automotive, construction, and packaging sectors. Full article

Objectives: This study aimed to investigate the association between optical coherence tomography angiography (OCTA) parameters and cardiovascular (CV) risk scores in individuals with type 1 diabetes (T1D). Methods: A cross-sectional analysis of a large-scale prospective OCTA trial cohort (ClinicalTrials.gov NCT03422965) was performed. Demographic, systemic, and ocular data—including OCTA imaging—were collected. T1D participants were stratified into three CV risk categories: moderate (MR), high (HR), and very high risk (VHR). Individualized predictions for fatal and non-fatal CV events at 5 and 10 years were calculated using the STENO T1 Risk Engine calculator. Results: A total of 501 individuals (1 eye/patient; 397 T1D, 104 controls) were included. Subjects with MR (n = 37), HR (n = 152) and VHR (n = 208) exhibited significantly reduced vessel density (VD) (20.9 ± 1.3 vs. 20.2 ± 1.6 vs. 19.3 ± 1.8 mm⁻¹, p < 0.05), perfusion density (PD) (0.37 ± 0.02 vs. 0.36 ± 0.02 vs. 0.35 ± 0.02%, p < 0.05) and foveal avascular zone circularity (0.69 ± 0.06 vs. 0.65 ± 0.07 vs. 0.63 ± 0.09, p < 0.05). Statistically significant negative correlations were observed between CV risk and OCTA parameters including VD, PD, and retinal nerve fiber layer thickness, while central macular thickness (CMT) showed a positive correlation (p < 0.05). Notably, CMT was significantly associated with 5-year CV risk. Conclusions: OCTA-derived metrics, particularly reduced retinal VD and PD, are associated with elevated CV risk scores in T1D patients. These findings suggest that OCTA may serve as a valuable non-invasive tool for identifying individuals with increased CV risk scores. Full article

For hot-rolled ferritic stainless steels with preferential α-fiber texture, the strong α-fiber texture is retained after annealing, greatly affecting the texture and plastic formability during the subsequent cold-rolling process. For optimizing the texture of hot-rolled steels toward the favorable γ-fiber type, it is essential to control the annealing temperature in the annealing process. To investigate the evolution of the microstructure, texture, and properties of hot-rolled ferritic stainless steel with preferential α-fiber orientation, a series of annealing tests was performed at the lab scale at 800, 840, 880, 910, 930, and 950 °C for 3 min. The microstructure, texture, and grain boundary characteristics of the tested samples were analyzed using optical microscopy (OM) and electron back-scattered diffraction (EBSD). The mechanical properties and plastic strain ratio (r-value) were determined through universal tensile testing. The results show that at temperatures above 840 °C, more than 93% of recrystallization occurs, leading to significant microstructural refinement. The α-fiber texture intensity typically diminishes with rising temperature, whereas the γ-fiber texture initially weakens during the early stages of recrystallization (below 840 °C) and subsequently exhibits a slight increase at higher temperatures. The improved formability of the material is mainly attributed to microstructural refinement and texture refinement, as reflected by the I(γ)/I(α) texture intensity ratio. At an annealing temperature of 930 °C, the I(γ)/I(α) ratio peaks at 0.85, static toughness is maximized, the strain-hardening exponent (n) reaches a high value of 0.28, and the maximum average plastic strain ratio ($\overline{r}$) is 0.96. This result represents the optimum balance between mechanical properties and formability, making it suitable for subsequent cold-rolling. Full article

Biaxially stretched polytetrafluoroethylene (PTFE) membranes are promising media for high-efficiency air filtration because of their stable node–fiber microstructure and environmental durability. To clarify how resin properties and microstructure govern filtration behavior, ten PTFE resins with different average molecular weights (Mn) and particle size characteristics were processed into membranes under essentially identical biaxial stretching and sintering conditions. Resin particle size, fiber diameter and pore size distributions were quantified, and coefficients of variation (CVs), together with Spearman rank correlations, were used to analyze material–structure–performance links. Filtration efficiency, pressure drop and quality factor (QF) were measured according to ISO 29463-3 using 0.1–0.3 μm aerosols. Higher Mn combined with lower particle-size dispersion favored finer fibers and narrower pores, yielding efficiencies close to 100%, but increased pressure drop and slightly reduced QF, indicating a trade-off between efficiency and flow resistance. The sample with the lowest Mn in its group and a high machine-direction draw ratio (12×), showed pronounced fibril breakage, node coalescence, broadened pore-size distribution and degraded QF, illustrating the sensitivity of structure and performance to resin-process mismatch. Overall, the study establishes a hierarchical material–fiber–pore–performance relationship that can guide resin selection, structural tuning and process optimization of biaxially stretched PTFE membranes. Full article

This study presents the techno-economic optimization of a hybrid distillation-membrane process for the complete fractionation of liquefied petroleum gas (LPG), targeting high-purity propane, n-butane, and isobutane recovery. The process employs an initial distillation column to separate propane (99% purity) from a propane-enriched stream, which is subsequently fed to a two-stage membrane system using an MFI zeolite hollow-fiber membrane for n-butane/isobutane separation. Through systematic simulation and sensitivity analysis, different membrane configurations were evaluated. The two-stage process with a partial residue-side reflux configuration demonstrated superior economic performance, achieving a total operating cost of 31.58 USD/h. Key membrane parameters—area, permeance, and separation factor—were optimized to balance separation efficiency with energy consumption and cost. The analysis identified an optimal configuration: a membrane area of 800 m², an n-butane permeance of 0.9 kg·m⁻²·h⁻¹, and a separation factor of 40. This setup ensured high n-alkane recovery while effectively minimizing energy use and capital investment. The study concludes that the optimized distillation-membrane hybrid process offers a highly efficient and economically viable strategy for the full utilization of LPG components. Full article