Search Results (560)

We examined the associations between individual differences in intensive longitudinal data-derived affective dynamics (i.e., positive and negative affect variability and inertia and positive affect–negative affect bipolarity) and concurrent stress, drinking levels, and affect-regulation drinking motives across three time points spanning early adulthood. This allowed us to evaluate the stability of the affective dynamics and whether their associations with alcohol outcomes varied across this critical developmental period. Moderate-to-heavy college drinkers (N = 1139, 51% women) reported on their affective states, stress, drinking levels, and drinking motives daily for 30 days using a web-based daily diary in three assessment waves: during college and at two post-college waves, approximately 5 and 10 years after the initial assessment. Findings indicated moderate stability of the affect dynamic indicators, except for inertia. Negative affect variability showed the strongest positive association with mean daily stress. Individuals who demonstrated stronger affect bipolarity had lower drinking levels and higher enhancement motivation. None of the other dynamic indicators were consistently related to the drinking outcomes in the predicted direction after controlling for mean affect levels, and we found little evidence for changes in these effects across time. Our results add to the inconsistent literature regarding the associations between affective dynamics and alcohol-related outcomes. Full article

High water quality in reservoirs used for drinking water supply and located within protected areas is of crucial importance for sustainable water-resource management. This study aims to evaluate the multi-depth water quality dynamics of the Ribnica Reservoir in western Serbia, combining two standardized assessment tools: the Serbian Water Quality Index (SWQI) and the Canadian Water Quality Index (CWQI). Data collected at various depths during 2021 and 2022 were analyzed to assess physico-chemical parameters and their impact on water quality, while the absence of microbiological data was noted as a limitation affecting the comprehensiveness of the assessment. The SWQI results indicated a general improvement in water quality over time, with values ranging from medium (82) to excellent (95) in 2021 and increasing from good (89) to excellent (98) in 2022. In contrast, the CWQI revealed specific risks, notably elevated concentrations of aluminum, mercury, and chromium, and reduced dissolved oxygen levels, with overall CWQI values ranging from poor (40) to good (88) depending on depth and parameter variability. The study highlights the necessity for continuous, comprehensive monitoring, including microbiological analyses and seasonal assessments, both within the reservoir and in the Crni Rzav River and its tributaries, to better understand pollutant sources and catchment influences. Strengthening microbiological and heavy metal monitoring, along with implementing proactive management strategies, is essential for preserving the Ribnica Reservoir’s ecological integrity and securing its long-term role in drinking water provision. Full article

Acid rain alters soil chemistry significantly and is a key driver of heavy metal pollution. This study investigates the environmental impact of acid rain-induced heavy metal migration in the Siding Lead–Zinc mining area in south China. Tailings, surrounding soils, and riverbed sediments were examined through simulated acid rain soil column leaching experiments. Leachate parameters—including pH, redox potential (Eh), total dissolved solids (TDSs) and heavy metal concentrations—were used to develop machine learning models (Random Forest and Support Vector Machine) to quantify the influence of environmental factors on metal migration. The results showed that leachates were generally alkaline and reductive after leaching, with Cd, Pb, and Zn as the dominant migrating metals. Leachates from tailings and nearby soils exceeded safe drinking water standards, with significantly higher cumulative metal release than other samples. The RF model outperformed the SVM model in predicting heavy metal concentrations. Feature importance analysis revealed that, beyond sample characteristics, pH and Eh were critical factors driving metal migration. Zn and Cd showed strong sensitivity to these parameters, with pH and Eh contributing over 80% to their migration. The findings highlight that acid rain can enhance the solubility and migration of heavy metals, posing a serious threat to the quality of surrounding water and underscoring the requirement for effective mitigation strategies to protect the ecological environment in mining areas. Full article

Heavy metal pollution poses a significant threat to aquatic ecosystems and drinking water sources, necessitating comprehensive environmental assessments. This study investigated the spatial distribution, potential ecological risks, and sources of heavy metals in the surface sediments of Wanfeng Lake to inform effective pollution management strategies. Twelve sediment samples were collected and analyzed for eight heavy metals (Hg, As, Cu, Pb, Cd, Cr, Ni, Zn) using inductively coupled plasma mass spectrometry. The geo-accumulation index (I_geo) and potential ecological risk index (RI) were applied to assess contamination levels and ecological risks. Cluster analysis and Kriging interpolation were used to identify potential pollution sources and spatial patterns. Results revealed that heavy metal concentrations decreased in the order Zn > Pb > Cu > Cr > Ni > As > Cd > Hg, with Hg concentrations exceeding the national average for Chinese lake sediments. Ecological risk assessments identified Hg (0.06 μg/g) and Cd (0.10 μg/g) as the priority pollutants. The Hg posed a moderate ecological risk, particularly in upstream areas, while Cd pollution was concentrated downstream. Atmospheric deposition was identified as the primary source of Hg, whereas agricultural activities were determined to be the main driver of Cd contamination. These findings provide a scientific basis for developing targeted pollution control measures in Wanfeng Lake. Full article

Ferrochrome pollution, a by-product of the ferroalloy industry, is emerging as a significant environmental concern due to its potential to contaminate groundwater resources. This contamination occurs primarily through the leaching of heavy metals, such as chromium, into the soil and water systems. This review article presents a strategic framework for assessing environmental and health risks associated with the ferrochrome industry pollution rather than focusing on a case study. The suggested methodology is designed to guide future field investigations in areas impacted by ferrochrome industrial activities. The presence of chromium in groundwater poses serious risks to both ecosystems and human health. In aquatic ecosystems, elevated chromium levels can disrupt the balance of microbial communities, affect biodiversity, and harm aquatic organisms. For humans, long-term exposure to chromium-contaminated groundwater is associated with a range of health issues, including carcinogenic effects, skin rashes, respiratory problems, and potential damage to vital organs. The widespread use of groundwater for drinking, irrigation, and industrial purposes exacerbates the risks to public health. This paper explores the sources, pathways, and mechanisms of ferrochrome contamination, examines its impact on groundwater ecosystems, and highlights the health consequences for affected populations. Strategies for mitigating ferrochrome pollution, including treatment technologies and policy interventions, are also discussed to help safeguard both environmental and public health. Full article

The Limpopo Province, situated in the northern part of South Africa, is mainly comprising rural areas that lack adequate facilities for drinking water. Boreholes are the main source of drinking water in rural and urbanized areas of Limpopo Province. Sixty-three water samples, from three locations in Limpopo Province, namely Mankweng, Dalmada, and Polokwane, plus two samples from a river in Magoebaskloof and still water as controls, were collected and subjected to analysis. The Sodium Absorption Ratio (SAR) analysis ranged from 1.4 to 35.6, revealing that 25% of the samples from Mankweng bear low quality with a high amount of sodium. Piper plot showed that two major water types exist in the samples, 33% and 67% of the water samples were of Na-Cl and Ca-Cl types, respectively. To identify the leading natural and anthropogenic processes causing variation in groundwater chemistry, principal component analysis (PCA) was used. The most detected heavy metal was V (vanadium) with 0.00 to 0.59 (mg/mL). The PCA results grouped all water samples from Dalmada together. However, the water samples from Mankweng were divided into three groups by PCA, with borehole samples showing a correlation with heavy metals. In conclusion, the study revealed that natural and anthropogenic activities cause groundwater variation in the Limpopo Province. All the boreholes sampled showed the presence of total coliform, but no E. coli was detected. In addition, regarding microbial contamination, water samples were suitable for drinking and irrigation purposes. Full article

The content and health impact of harmful heavy metals in agricultural products from strong geological background concentration areas have received increasing attention. To investigate the impact of soil heavy metal contamination on the tea plantation gardens of Guizhou Province, a major tea-producing area with strong geological background concentrations in China, a total of 37 paired soil–tender tea leaf samples (containing one bud and two leaves) were collected and analyzed for eight harmful heavy metals. The results showed that the average contents of Hg, As, Pb, Cd, Cr, Ni, Sb, and Tl in the surface soil (0–20 cm) were 0.26, 23.9, 37.9, 0.29, 75.9, 37, 2.78, and 0.84 mg/kg, respectively. The majority of the soil Hg, As, Pb, Sb, and Tl levels exceeded their background values for cultivated land soil in Guizhou Province to some extent. The geo-accumulation index revealed that Sb and As are the main pollutants of tea garden soil. The average contents of Hg, As, Pb, Cd, Cr, Ni, Sb, and Tl in the tea leaves were 4, 49, 310, 55, 717, 12,100, 30, and 20 μg/kg (on a dry weight basis), respectively, all of which were significantly lower than their national recommended limits for tea. The bioconcentration factors of these eight heavy metals in tea leaves were relatively low when compared with those in soil, ranging between 0.003 (for As) and 0.603 (for Ni). The health risk assessment indicated that the total hazard quotient (THQ) due to drinking tea was in the order of Tl > Ni > As > Pb > Cd >Sb > Hg > Cr, with both the THQ for each heavy metal and the health risk index (HI) being less than 0.29, indicating that the risk of exposure to these heavy metals through drinking Guizhou green tea is low. Although some harmful heavy metals are present in the tea garden soil of Guizhou, their bioavailability for young tea leaves is extremely low. This may be related to the physical and chemical properties of the soil, such as the high proportion of organic matter (up to 9%) which strongly binds with these elements. Full article

Olive mill wastewater (OMW) is deemed a substantial environmental pollutant, particularly in Mediterranean regions. Lower and middle-income countries, including Jordan, suffer from water scarcity and increasing demand for water, especially for drinking and irrigation purposes. Subsequently, the management and treatment of OMW represents a major concern. This study investigates the feasibility of utilizing Jordanian kaolinite as a simple, readily available, green, and sustainable adsorbent to mitigate the environmental impact of untreated or partially treated OMW. In this work, purified kaolinite (PK) was activated with sodium ions at room temperature. The characterization of PK and sodium-activated kaolinite (PK-NaCl) was accomplished using FTIR, XRD, TGA, and BET surface area analyses. The adsorption performance of both PK and PK-NaCl for OMW treatment were evaluated through batch and column experiments. The key physiochemical parameters of OMW were systematically analyzed in all influent and effluent samples to evaluate the treatment efficiency. In all cases, sodium-activated kaolinite significantly enhances treatment efficiency. The adsorption of total phenolic compounds (TPCs) onto both PK and PK-NaCl adsorbents was studied with respect to initial concentration, adsorbent dosage, and temperature. The maximum adsorption capacity was 8.88 mg/g for PK-NaCl, which was higher than that of PK, at an adsorbent dose of 1.0 g and a temperature of 323 K. The Langmuir and Freundlich isotherm models to describe the adsorption equilibrium were implemented, and both displayed good fit with the experimental data. Additionally, the removal efficiencies of heavy metal (i.e., Zn, Fe and Mn) ions were also evaluated. The findings demonstrated that the PK-NaCl completely removed all tested heavy metal ions, regardless of their initial concentrations. Therefore, the cost-effective and easily prepared PK-NaCl significantly improved the adsorption capacity and presents a promising treatment solution for OMW. This approach could be highly beneficial for olive mills across the Mediterranean regions to mitigate the environmental impact of OM waste. Full article

In this paper, the modification of natural clinoptilolite and mordenite zeolites from Almaty using acid treatment is addressed for the purposes of improving adsorption performance and for drinking water purification. Structural chemical transformation was characterized by the use of X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and Scanning electron microscope (SEM) techniques. Acid treatment led to a partial dealumination that was responsible for an increase in the number of surface defects and micropores, improvement in ion exchange capacity, and selectivity toward heavy metals. Additionally, modifications greatly enhance the uptake capacities of Pb²⁺, Cd²⁺, and As³⁺. The clinoptilolite post-modification removal efficiencies reached 94%, 86%, and 84%, respectively, while mordenite zeolites achieved 95%, 90%, and 87% removal efficiencies, respectively. The enhancement of performance was related to the increase in surface area and active sites for ion exchange, verified from analysis of the Brunauer-Emmett-Teller (BET) surface area. The use of different Bhatt and Kothari methods has revealed that adsorption processes followed Langmuir isotherm models for Pb²⁺ and Cd²⁺, whereas As³⁺ adsorption was better described by the Freundlich isotherm model. However, second-order kinetics indicate that chemisorption was the dominant mechanism. Such evidence indicates spontaneity and an endothermic process, as shown from thermodynamic studies. Results showed that modified zeolites indeed had a high degree of reusability, with over 80% of the adsorption capacity retained even after five cycles. Acid-modified zeolites can provide cheaper, greener methods of purification, generating only negligible secondary waste when compared to conventional methods of water purification, for example, activated carbon and membrane filtration. Results from this study proved that modified clinoptilolite and mordenite zeolites have the potential for sustainable heavy metal treatment in drinking water purification systems. Full article

Riverine heavy metal (HM) pollution, a critical global environmental issue, severely affects water quality, ecosystem health, and human well-being. The Huaihe River, once among China’s most polluted, has seen water quality improvements due to strict pollution controls, yet the extent of HM pollution reduction remains uncertain. Here, we investigated the distribution, sources, and potential ecological and health risks of nine typical HMs (Cr, Mn, Ni, Cu, Zn, As, Cd, Pb, and Hg) in surface water and sediment in the Anhui section of the river. Seasonal variations in HM concentrations were observed, with most values below drinking water safety limits, except for Mn and Cd at specific sites and seasons. Indices including the HPI, HEI, HQ, and HI showed low contamination and health risks, yet children are more vulnerable to non-carcinogenic hazards, notably from Cd and As. Sediment HMs trends decreased as Mn > Zn > Cr > Pb > Ni > Cu > As > Cd > Hg, with moderate pollution from Cd, Mn, and Pb based on CF, EF, and I_geo assessments. PLI and NPI suggested moderate ecological risks in midstream areas due to HM accumulation. The correlation analysis and PCA revealed that HMs in uncontaminated sediments were mainly of geogenic origin, while contaminated sediments were largely influenced by anthropogenic activities, including agricultural runoff, industrial waste, and domestic sewage discharge. Overall, our findings highlight that control of anthropogenic activities within the Huaihe River basin is essential for reducing HM pollution in the river. Full article

This study aimed to assess the pollution levels, sources, ecological risk, and human health risks of metal(loid)s in water, sediment, and muscle tissue of Prochilodus lineatus and Pimelodus maculatus from rivers in the state of Mato Grosso do Sul, Brazil. The metal(loid)s content in river sediment, water, and fish tissue were determined by inductively coupled plasma optical emission spectrometry. Sediment pollution assessment was carried out by geo-accumulation index, contamination factor, enrichment factor, and pollution load index. There were significant differences in concentration values for Al, As, Cd, Co, Cr, Cu, Mo, Ni, Pb, and Hg. There was greater tendency for the elements Cu, Ni, Cu, N, Co, As, Hg, Al, and Co in the waters of the Anhanduí River in 2020 and Cr and Pb in 2021. The concentrations of As, Cd, Co, Cr, and Hg in the waters of the Anhanduí River are above the permitted limit values for heavy metal ions in drinking water established by the WHO. The concentrations of heavy metals in the sediments of rivers are above the limit set by Conama/Brazil and other countries. The sediments were very highly contaminated by Cd and Mo, and with moderate contamination of Pb. All sediments of rivers showed a decline in site quality, which indicates that it is polluted. Sediments were classified with severe enrichment by Cd and Mo. The content of Al was the highest in P. lineatus and P. maculatus in relation to other elements analyzed. There was also the presence of elements such as Cr, Cu, Cd, Hg, Ni, As, Pb, Mo, and Co in the tissues of the fish species. Therefore, the contamination of these rivers is a concern due to human consumption of fish, since there is a carcinogenic risk related mainly to As and Cd. Full article

This research investigates the elemental composition of 78 drinking water samples collected during the summer, autumn, and winter of 2023 in different districts of Almaty city. Seasonal average concentrations and standard deviations were calculated for a range of chemical elements, including arsenic (As), beryllium (Be), cobalt (Co), cadmium (Cd), copper (Cu), lithium (Li), molybdenum (Mo), nickel (Ni), lead (Pb), selenium (Se), uranium (U), mercury (Hg), aluminum (Al), barium (Ba), chromium (Cr), iron (Fe), manganese (Mn), strontium (Sr), vanadium (V), zinc (Zn), calcium (Ca), potassium (K), magnesium (Mg), and sodium (Na), across three distinct datasets. The sites of sampling represent various categories of drinking water sources. The quality of drinking water was assessed by comparing the obtained data with current national, international, and World Health Organization (WHO) standards. Drinking water contaminant indices for the heavy metal groups were calculated and the water quality compliance with the hygienic criteria adopted in the Republic of Kazakhstan was determined. With the exception of two sampling points, the levels of non-carcinogenic risk remained below the acceptable threshold. The predominant pathway for exposure for both adults and children was identified as the oral ingestion of hazardous elements. Carcinogenic risks linked to Ni, Pb, and Cr presence in the drinking water of Almaty were identified, with risk values at the majority of sampling sites categorically classified within the “high risk” designation. No substantial differences in carcinogenic risk levels were detected between adults and children. These results underscore the necessity for enhanced water purification methodologies and ongoing surveillance to protect public health. Full article

Based on the characteristics and effective components of steel slag and desulfurization gypsum, a new type of permeable reactive material was prepared by combining steel slag and desulfurization gypsum, and a simulation experiment of arsenic- and antimony-contaminated groundwater remediation was carried out. A combination of X-ray fluorescent, BGRIMM Process Mineralogy Analyzing System (BPMA), ICP-MS, and SEM-EDS detection and analysis methods was used to investigate the effects of steel slag particle size, desulfurization gypsum particle size, steel slag and desulfurization gypsum ratio, and steel slag-desulfurization gypsum mixed test block particle size on the performance of the permeable reactive wall to remove arsenic and antimony. The results show that a permeable reactive wall composed of steel slag (−4.75 + 1.18 mm) and desulfurization gypsum (−13.2 + 9.5 mm) in a 4:1 ratio achieved removal rates of 91.85% for As and 90.58% for Sb, reducing their concentrations below the drinking water standard. The purpose of using steel slag and desulfurization gypsum to intercept heavy metals and toxic ions in surface runoff was achieved. Arsenic was adsorbed, physically encapsulated, and lattice solidified by C-S-H gel. This research provides a cost-effective and environmentally friendly solution for the storage of steel slag and desulfurization gypsum while addressing heavy metal pollution in groundwater. Full article

This study aims to assess the vulnerability of groundwater in the Nile Delta to contamination and evaluate its suitability for drinking and irrigation. A total of 28 groundwater wells (ranging from 23 to 120 m in depth) and two Nile surface water samples were analyzed for total dissolved solids (TDS), heavy metals, groundwater quality index (GWQI), and hazard quotient (HQ). The findings reveal that deep groundwater (60–120 m) displays paleo-water characteristics, with low TDS, total hardness, and minimal heavy metal contamination. In contrast, shallow groundwater (<60 m) is categorized into three groups: paleo-water-like, recent Nile water with elevated TDS and heavy metals, and mixed water. Most groundwater samples (64%) are of the Ca-HCO₃ type, while 28% are Na-HCO₃, and 8% are Na-Cl, the latter associated with sewage infiltration. Most groundwater samples were deemed suitable for irrigation, but drinking water quality varied significantly—4% were classified as “excellent”, 64% as “good”, and 32% as “poor”. HQ analysis identified manganese as a significant health risk, with 56% of shallow groundwater samples exceeding safe levels. These findings highlight the varying groundwater quality in the Nile Delta, emphasizing concerns regarding health risks from heavy metals, particularly manganese, and the need for improved monitoring and management. Full article

Recently, the only UNESCO river in Nigeria has become polluted, with its color turning dark brown. Osun River serves not only domestic purposes in the city of Osogbo, but also spiritual purposes during the annual Osun Osogbo Festival (OOF). This study examines the physicochemical properties and presence of heavy metals in Osun River, and the air quality at the heritage site before, during, and after the festival. Water samples from Osun River at the UNESCO site were collected before, during, and after the 2024 festival. The water was analyzed at the Department of Environmental Health Sciences of Osun State University, Nigeria, to determine the quantity of heavy metals present in the river. Additionally, an air quality detector was used to assess the quantity of pollutants (CO₂, CO, PM_2.5, PM₁₀, TVOC, and HCHO) in the air before, during, and after the festival. In Osun River, the quantities of arsenic and copper were within the permissible levels set by the World Health Organization (WHO) for drinking water, while those of lead, chromium, and cadmium were far above the safety standards set by the WHO. The pollution rate of the river was in the order of festival day > before the festival > after the festival. The air quality on the festival day was hazardous to human health, as particulate matter (PM_2.5 and PM₁₀) and carbon dioxide were found to be far above the permissible levels set by the WHO. The implications of the findings of this study are discussed, and measures to ensure the future sustainability of this important UNESCO site in the city of Osogbo are recommended. Full article