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Keywords = heat-resistant polymer

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17 pages, 4946 KB  
Review
Hygrothermal Performance and Sustainability of Wool or/and Expanded Polystyrene (EPS) Insulation
by Adriana-Mariana Asoltanei, Sebastian George Maxineasa, Constantin Eugen Ailenei, Marius Sebastian Secula, Ioan Mamaligă and Dorina-Nicolina Isopescu
Sustainability 2026, 18(13), 6468; https://doi.org/10.3390/su18136468 (registering DOI) - 25 Jun 2026
Abstract
This study critically addresses the challenge of selecting optimal insulation materials for contemporary, energy-efficient building envelopes, a decision with profound environmental, structural, and occupational health consequences. The paper responds to the growing demand for sustainable, resilient solutions by comparing wool, a bio-based, regenerative [...] Read more.
This study critically addresses the challenge of selecting optimal insulation materials for contemporary, energy-efficient building envelopes, a decision with profound environmental, structural, and occupational health consequences. The paper responds to the growing demand for sustainable, resilient solutions by comparing wool, a bio-based, regenerative material, and expanded polystyrene (EPS), a synthetic polymer widely implemented in the construction industry, and advanced laboratory testing (thermal conductivity, moisture buffering, freeze–thaw resistance) is discussed in a comprehensive synthesis of the recent literature. Also, field evaluations from European retrofits and pilot projects (UK, Denmark, Finland, Iceland, Norway, Sweden, Germany and France) further contextualize performance outcomes, and life cycle impacts are considered. Recent results reveal that wool insulation achieves a moisture buffering value (MBV) between 1.8 and 2.7 (g/m2) % RH, minimal vapor resistance (mvr = 1–2), and preserves functional and structural integrity through more than 100 freeze–thaw cycles, leading to significant stabilization of the interior microclimate and enhanced durability. In contrast, EPS delivers lower thermal conductivity (0.032–0.037 (W/mK), critical for reducing heating/cooling demand, but exhibits limited vapor permeability (lvp = 60–150 MN·s/(g·m)), increased risk of condensation and mold, and reduced compressive strength (<22% after 30 cycles), especially when ventilation details are inadequate. Hybrid envelope systems leveraging both EPS and wool are demonstrated to optimize energy efficiency (up to 23% seasonal savings) and reduce interior humidity fluctuations, while lifecycle and recycling assessments show wool panels to be markedly superior in carbon footprint reduction and circularity. The stratification of insulation layers incorporating wool for vapor and moisture control, and EPS for pure thermal resistance is emerging as best practice in sustainable retrofit and new-build projects. Recommendations highlight the necessity for rigorous laboratory validation, international standards alignment, and integrated material design for robust hygrothermal comfort and environmental performance. The review also covers wool- and EPS-based hybrid composites, showing how natural fibers can improve key mechanical properties without compromising thermal insulation performance or environmental benefits. Full article
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31 pages, 4805 KB  
Review
Ti3C2Tx-Based Materials and Coatings for De-Icing and Defogging of Wind Turbine Blades: Materials Basis, Structural Design, Engineering Integration, and Future Opportunities
by Weiwei Wu, Kening Peng, Kunqi Zhang, Zhifang Liu and Nana Yao
Nanomaterials 2026, 16(12), 784; https://doi.org/10.3390/nano16120784 (registering DOI) - 22 Jun 2026
Viewed by 227
Abstract
In cold, humid environments, even a small amount of ice accumulation on the blade surface can degrade aerodynamic performance, increase drag, induce premature stall and vibration, and raise the risks of shutdown, fatigue, and ice throw. Existing blade anti-icing and de-icing strategies (such [...] Read more.
In cold, humid environments, even a small amount of ice accumulation on the blade surface can degrade aerodynamic performance, increase drag, induce premature stall and vibration, and raise the risks of shutdown, fatigue, and ice throw. Existing blade anti-icing and de-icing strategies (such as passive coatings, electrothermal heating, hot-air systems, and hybrid designs) struggle to simultaneously meet the requirements of lightweight construction, low-voltage rapid heating, conformability to curved surfaces, erosion resistance, long-term durability, and scalable manufacturing. MXenes, particularly Ti3C2Tx, have attracted attention due to their high electrical conductivity, broadband optical absorption, solution processability, tunable interfacial chemistry, and good compatibility with polymer matrices. However, their oxidation issue and blade-scale deployment challenges (coating chemistry, scalable fabrication, real-world testing) remain obstacles. Based on this, this review discusses Ti3C2Tx-based anti-icing, de-icing, and defogging strategies for wind turbine blades, with emphasis on material properties, functional mechanisms, coating architectures, fabrication routes, durability, and scalability, and highlights their potential for lightweight and energy-efficient all-weather blade protection. Finally, future research directions for Ti3C2Tx-based blade anti-icing and de-icing are prospected. This review not only aims to identify key knowledge gaps in current research but also strives to provide a theoretical reference for the application of Ti3C2Tx in the complex service environment of real wind turbine blades, thereby moving beyond idealized laboratory conditions. Full article
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16 pages, 3370 KB  
Article
Optimized Interfacial Layers for High-Adhesion and Damp-Heat-Resistant Cu Meshes with Aperiodic Geometries on PET Substrates
by Xiao Lu, Jia Li, Biyou Bao, Chengli Zhang, Qiang Wang, Guanglong Xu, Xianfa Rao, Hongliang Zhang and Weijie Song
Materials 2026, 19(12), 2608; https://doi.org/10.3390/ma19122608 - 17 Jun 2026
Viewed by 184
Abstract
Copper (Cu) thin films and meshes on polyethylene terephthalate (PET) substrates are promising flexible transparent conductive electrodes (TCEs), yet their practical use is limited by insufficient interfacial adhesion and poor oxidative stability on inert polymer substrates. This work addresses these issues via a [...] Read more.
Copper (Cu) thin films and meshes on polyethylene terephthalate (PET) substrates are promising flexible transparent conductive electrodes (TCEs), yet their practical use is limited by insufficient interfacial adhesion and poor oxidative stability on inert polymer substrates. This work addresses these issues via a synergistic strategy of interfacial layer engineering and maskless laser lithography-based aperiodic mesh patterning, systematically comparing ceramic (Al2O3) and metallic (NiCr) interfacial layers for PET-supported Cu films and fabricating Linear/Sinusoidal aperiodic Cu meshes with tailored performance. Magnetron sputtering shows that Ar plasma-activated NiCr interfacial layers form a gradient-alloyed interface with Cu via interdiffusion, achieving 5B-level adhesion, mitigating bending-induced stress concentration, and enhancing damp-heat resistance (85 °C/85% RH) by suppressing oxidation—outperforming brittle Al2O3 layers. Patterning the optimized Cu/NiCr/PET structure into micrometer-scale meshes yields a Linear design with superior optoelectronic performance (~10.8 Ω/sq sheet resistance, >87% transmittance at 550 nm) and a Sinusoidal design with enhanced bending robustness via stress delocalization. Microstructural and elemental analyses clarify the NiCr layer’s interfacial toughening and anti-oxidation mechanisms. Practical validation in flexible transparent heaters demonstrates rapid thermal response and >20 h continuous operational stability. This study provides a scalable design strategy for high-performance PET-supported Cu meshes, offering insights for interface and structural optimization of flexible metallic TCEs for next-generation optoelectronics. Full article
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19 pages, 5182 KB  
Article
Graphene-Enriched Acrylic Paint to Protect Unheated and Heat-Treated Wood Species Against Coniophora puteana
by Hamid R. Taghiyari, Elham Nadali, Antonio Pizzi, Roya Majidi, Jakub Kawalerczyk, Ioanna A. Papadopoulou, Olaf Schmidt and Antonios N. Papadopoulos
Polymers 2026, 18(12), 1462; https://doi.org/10.3390/polym18121462 - 11 Jun 2026
Viewed by 176
Abstract
Graphene was added to acrylic paint to be coated on two sets of unheated and heat-treated specimens of three commercial wood species (namely beech, poplar, and spruce) to protect against Coniophora puteana. Heat treatment was carried out at the mild temperature of [...] Read more.
Graphene was added to acrylic paint to be coated on two sets of unheated and heat-treated specimens of three commercial wood species (namely beech, poplar, and spruce) to protect against Coniophora puteana. Heat treatment was carried out at the mild temperature of 185 °C for four hours in a laboratory oven and under atmospheric pressure. Each of the two sets were divided into three sub-groups of uncoated (control), coated with plain paint, and coated with graphene-enriched paint to be exposed to the fungus. Results showed that coating of specimens with the plain acrylic paint significantly protected all three wood species against the fungus. Still, reinforcing effect of graphene resulted in an even higher degree of protection, and it slightly increased compression strength compared to grain as well. Heat treatment also improved biological resistance in all three wood species, which is seen in the drastic decrease of the mass losses. It also increased compression strength as a result of hornification and thermal alterations of cell-wall polymers. It was concluded that graphene-added acrylic paint can be recommended as an easy and available superficial protecting method to significantly protect both hard- and softwoods against C. puteana. Full article
(This article belongs to the Special Issue Chemical Treatments of Wood and Wood-Polymer Composites)
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28 pages, 3981 KB  
Review
Friction Stir Welding of Dissimilar Materials: A Review on Joining Mechanism, Defects, and Process Optimization
by Yuan Zhang, Shuo Wang, Yibo Sun, Changlong Zhao and Wei Li
Materials 2026, 19(11), 2327; https://doi.org/10.3390/ma19112327 - 1 Jun 2026
Viewed by 356
Abstract
The dissimilar joining of aluminum alloy and carbon fiber-reinforced polymer (CFRP) is critical for lightweight manufacturing in transportation and aerospace sectors, yet it remains challenging due to their substantial differences in physical and chemical properties. This paper systematically reviews friction stir welding (FSW) [...] Read more.
The dissimilar joining of aluminum alloy and carbon fiber-reinforced polymer (CFRP) is critical for lightweight manufacturing in transportation and aerospace sectors, yet it remains challenging due to their substantial differences in physical and chemical properties. This paper systematically reviews friction stir welding (FSW) of aluminum alloy and CFRP, and compares it with laser welding, induction welding, resistance welding, and ultrasonic welding. The comparative analysis indicates that while each alternative process presents distinct limitations in thermal management, heating uniformity, or joint configuration, FSW demonstrates the most balanced overall performance, uniquely combining single-pass long-distance capability, low heat input, and broad industrial applicability. Through systematic parametric analysis, the optimal FSW processing window is quantitatively established as a tool rotation speed of 1200–1500 rpm combined with a traverse speed of 30–50 mm/min. Under these optimized conditions, the CFRP side remains below its thermal degradation threshold of 350 °C, the defect volume fraction is reduced from 12% to below 3%, and the maximum joint tensile strength reaches 78 MPa, representing 65% of the base CFRP strength. The interfacial bonding mechanisms are identified as mechanical interlocking and localized chemical bonding, which however cover only approximately 30% of the interfacial area. Optimization strategies, including surface modification, auxiliary structures, nanoparticle reinforcement, and external field assistance, are evaluated for their effectiveness in improving joint quality. Finally, critical challenges and future research directions toward engineering application are outlined. Full article
(This article belongs to the Section Metals and Alloys)
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18 pages, 7003 KB  
Article
Fire-Retardant and Tribological Performance of Painted Ultem 9085 Polymer–Coating Composites Produced via Fused Deposition Modeling
by Elīna Vīndedze, Didzis Dejus, Jānis Jātnieks, Michael Folkert Telkamp, Armands Leitans, Janis Lungevics, Behnam Boobani and Tatjana Glaskova-Kuzmina
J. Compos. Sci. 2026, 10(6), 295; https://doi.org/10.3390/jcs10060295 - 29 May 2026
Viewed by 561
Abstract
Materials applied in interior and non-structural aircraft components are required to satisfy rigorous safety and performance criteria, especially with respect to flame retardancy and wear resistance. Ultem 9085, a high-performance polyetherimide thermoplastic, is extensively used in aerospace applications owing to its advantageous strength-to-weight [...] Read more.
Materials applied in interior and non-structural aircraft components are required to satisfy rigorous safety and performance criteria, especially with respect to flame retardancy and wear resistance. Ultem 9085, a high-performance polyetherimide thermoplastic, is extensively used in aerospace applications owing to its advantageous strength-to-weight ratio and compliance with flame, smoke, and toxicity (FST) requirements. Nevertheless, the application of surface coatings, including paints, may modify their fire-retardant and tribological performance, with potential implications for service behavior and regulatory compliance. This work provides new insight into the behavior of painted Ultem 9085 components under fire exposure and frictional loading, addressing the critical need to determine whether surface finishing affects the material’s inherent performance advantages. Thus, the effects of different paint coatings on the fire-retardant and tribological properties of Ultem 9085 are investigated. Test specimens were manufactured using a Stratasys F900 system with 100% infill density and geometries adapted for standard vertical burn and heat release tests. Fire performance testing, including vertical burn, smoke and toxicity, and heat release rate, was performed in accordance with CS/FAR 25 Appendix F and AITM 3-0005 requirements. Tribological behavior was assessed using a ball-on-flat tribometer under dry-sliding conditions, while surface texture was analyzed using 3D profilometry. Seven polymer–coating composites were examined. It was experimentally confirmed that all coatings reduced vertical burn length but increased peak heat release rate and smoke density relative to unmodified Ultem 9085. Tribological results varied significantly, highlighting the critical role of paint selection in achieving optimal fire safety and wear resistance. Full article
(This article belongs to the Special Issue Additive Manufacturing of Composites and Nanocomposites, 2nd Edition)
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34 pages, 10700 KB  
Article
Heat Propagation Through Fins Made of Polymeric Materials Manufactured by 3D Printing
by Florin Negoescu, Vasile Merticaru, Andrei Marius Mihalache, Vasile Ermolai, Oana Dodun, Nicolae-Răzvan Mititelu, Gheorghe Nagîț, Marius-Ionuț Rîpanu, Adelina Hrițuc and Laurențiu Slătineanu
Polymers 2026, 18(11), 1315; https://doi.org/10.3390/polym18111315 - 26 May 2026
Viewed by 761
Abstract
To investigate simultaneously both the effect of fin cross-sectional shape on heat transfer and the influence of different polymeric materials, test samples were manufactured by 3D printing in the form of bushings with attached radial fins of varying cross-sections. Through the research undertaken, [...] Read more.
To investigate simultaneously both the effect of fin cross-sectional shape on heat transfer and the influence of different polymeric materials, test samples were manufactured by 3D printing in the form of bushings with attached radial fins of varying cross-sections. Through the research undertaken, the aim was to obtain information regarding the length of the fin at which a certain temperature is reached; therefore, the length that ensures efficient heat transfer to the external environment. Dedicated testing equipment was designed and built to test the thermal transfer in fins made of three different materials (polylactic acid (PLA)-based materials, i.e., standard PLA, PLA with carbon black (protopasta), and PLA with graphene (prografen)) and, respectively, with different sizes and shapes of the cross-section (circular, square, equilateral triangular, and rectangular). The experimental results were mathematically processed to develop empirical models that illustrate both the direction and the intensity of the influence of the input factors on the fin length at which a specific temperature is reached. Under certain conditions, radial components with a circular cross-sectional area of 20 mm2 showed significant differences depending on the polymer type. For the polylactic acid material, this length was 42% higher than for prografen and 25% higher than for protopasta. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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15 pages, 1690 KB  
Article
Carbonation Performance and Characterization of Alkali-Activated Cementitious Materials Incorporating Superabsorbent Polymers
by Wanguo Zhang, Yunjuan Chen, Yuanshun Xiong, Yichen Zhang, Yuanhui Qiao, Quansheng Sun and Zhen Wang
Buildings 2026, 16(9), 1797; https://doi.org/10.3390/buildings16091797 - 30 Apr 2026
Cited by 1 | Viewed by 273
Abstract
To effectively mitigate the early-age shrinkage and cracking of alkali-activated cementitious materials (AAMs), superabsorbent polymers (SAPs) were adopted in this study to absorb and store water in the mixture, which is continuously released during the setting and hardening process. This approach prolongs the [...] Read more.
To effectively mitigate the early-age shrinkage and cracking of alkali-activated cementitious materials (AAMs), superabsorbent polymers (SAPs) were adopted in this study to absorb and store water in the mixture, which is continuously released during the setting and hardening process. This approach prolongs the setting and hardening process of AAM, improves the stability of its microstructure, and reduces crack formation. Meanwhile, the influence mechanism of CO2 curing on the strength of SAP-modified AAM was investigated. Through mechanical strength testing, X-ray diffraction (XRD), thermogravimetric analysis (TGA), heat release measurement during setting and hardening, and pore size distribution testing of specimens with different mix proportions and curing conditions, effective methods to improve the mechanical strength and microstructural development of AAM were explored. The results show that CO2 curing can significantly enhance the early-age strength of AAM, promote the formation of carbonation products, and optimize the pore structure of AAM at the micro-level. An appropriate amount of SAP can prolong the setting and hardening process of AAM and improve the degree of its setting and hardening; however, excessive SAP reduces the concentration of alkaline solution in the mixture matrix, increasing resistance to the setting and hardening of AAM. Full article
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31 pages, 4195 KB  
Review
Applications of Aramid Fiber-Reinforced Polymer Composites in Civil Engineering: A Review
by Anni Wang, Runping Lan, Qun Chen, Weichen Kong, Haoyu Liu, Qingrui Yue and Xiaogang Liu
Polymers 2026, 18(9), 1102; https://doi.org/10.3390/polym18091102 - 30 Apr 2026
Viewed by 838
Abstract
Aramid fiber is a high-performance fiber with excellent mechanical properties, heat resistance, and corrosion resistance. Its exceptional shear and fatigue properties make it a promising material for civil engineering applications. This study summarizes the basic properties and current development of aramid fiber, as [...] Read more.
Aramid fiber is a high-performance fiber with excellent mechanical properties, heat resistance, and corrosion resistance. Its exceptional shear and fatigue properties make it a promising material for civil engineering applications. This study summarizes the basic properties and current development of aramid fiber, as well as the applications of aramid fiber and its composites in civil engineering, including aramid fiber-reinforced composite (AFRP)-concrete/steel composite structures, AFRP rebars, and AFRP rock anchors. The results indicate that the poor interfacial bonding performance between aramid fibers and the resin matrix is the primary bottleneck restricting the application of AFRP composites in civil engineering. Consequently, developing a continuous surface treatment method suitable for industrial-scale production remains a key challenge for the widespread adoption of these composites. Furthermore, in certain specific working conditions and environments—such as seismic retrofitting of rectangular concrete columns, impact/explosion resistance reinforcement, and rock anchoring—AFRPs show the potential to replace traditional inorganic fiber-reinforced polymer composites. However, systematic investigation into the fundamental mechanical properties and long-term service performance of AFRP is still required prior to their practical application. Full article
(This article belongs to the Special Issue Fiber-Reinforced Polymeric Composites)
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18 pages, 2730 KB  
Review
Photodegradation Mechanisms and Anti-Aging Strategies of Wood Coatings: A Comprehensive Review
by Meng Xia, Hanyun Gao, Xinhao Feng and Xinyou Liu
Polymers 2026, 18(9), 1090; https://doi.org/10.3390/polym18091090 - 29 Apr 2026
Viewed by 585
Abstract
Wood coatings play a critical role in protecting wood substrates from environmental degradation, particularly ultraviolet (UV)-induced photodegradation. This review comprehensively examines the mechanisms of wood coating photodegradation, the factors influencing their durability, and current anti-aging strategies. Photodegradation arises from polymer chain scission, chemical [...] Read more.
Wood coatings play a critical role in protecting wood substrates from environmental degradation, particularly ultraviolet (UV)-induced photodegradation. This review comprehensively examines the mechanisms of wood coating photodegradation, the factors influencing their durability, and current anti-aging strategies. Photodegradation arises from polymer chain scission, chemical structure reorganization, and photo-oxidation of lignin and cellulose, leading to coating chalking, cracking, gloss loss, and color changes, ultimately compromising wood mechanical properties and service life. Key anti-aging strategies include UV absorbers, which convert harmful UV radiation into heat; hindered amine light stabilizers (HALSs) that capture free radicals and quench excited-state molecules; barrier and shielding materials that form dense physical or nanostructured networks to block UV penetration and enhance mechanical and water resistance; and antioxidants that neutralize free radicals or decompose peroxides at the molecular level. Each approach can be employed individually or synergistically to enhance coating durability. Challenges remain in achieving long-term outdoor stability, balancing transparency and UV shielding, optimizing nanoparticle dispersion, and maintaining the activity of natural antioxidants. Future research should focus on multifunctional composite coatings integrating bio-based materials and nanotechnology, smart responsive systems, adaptive protection mechanisms, and standardized long-term evaluation protocols. These advancements will facilitate the development of high-performance, sustainable wood coatings and promote the value-added utilization of wood resources. Full article
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11 pages, 1458 KB  
Opinion
Lasting Aftermaths of the First Incitement for High-Temperature Superconductivity
by Serguei Brazovskii and Natasha Kirova
Condens. Matter 2026, 11(2), 15; https://doi.org/10.3390/condmat11020015 - 27 Apr 2026
Viewed by 418
Abstract
Six decades ago, the scientist from Stanford University, W.P. Little, announced a crusade to search for superconductivity, assumed to be heat-resistant in organic materials. Although such an ambitious goal was never realized in practice, this proposal gave rise to the entire ecosystem of [...] Read more.
Six decades ago, the scientist from Stanford University, W.P. Little, announced a crusade to search for superconductivity, assumed to be heat-resistant in organic materials. Although such an ambitious goal was never realized in practice, this proposal gave rise to the entire ecosystem of studies on “synthetic metals,” creating a diverse community of material, experimental, and theoretical activities in low-dimensional electronic systems. We shall briefly review some key steps in this history, examine its main branches, and recall the consequences that remain on the agenda today. Particularly, we shall focus on a phenomenon of electronic ferroelectricity, whose roots can be found in the suggestion of a would-be superconducting polymer. Full article
(This article belongs to the Special Issue Superstripes Physics, 4th Edition)
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44 pages, 7897 KB  
Review
Recent Advances in Thermally Insulated Drilling Pipes: Materials, Design Strategies, and Future Directions
by Izaz Ali, Muhammud Arqam Khan, Yang Ding, Chaozheng Liu and Mei-Chun Li
Polymers 2026, 18(8), 1004; https://doi.org/10.3390/polym18081004 - 21 Apr 2026
Viewed by 745
Abstract
The increasing global demand for oil and gas, together with the depletion of shallow reservoirs, has driven exploration toward deep and ultra-deep formations characterized by high-temperature and high-pressure (HTHP) conditions. In such environments, conventional drill pipes often experience thermal stress, corrosion, and mechanical [...] Read more.
The increasing global demand for oil and gas, together with the depletion of shallow reservoirs, has driven exploration toward deep and ultra-deep formations characterized by high-temperature and high-pressure (HTHP) conditions. In such environments, conventional drill pipes often experience thermal stress, corrosion, and mechanical degradation, which can reduce drilling efficiency and compromise operational reliability. Thermal insulated drilling pipes (TIDPs) have therefore emerged as an effective solution to minimize heat transfer between drilling fluids and the surrounding formation. This review summarizes recent advances in TIDP materials, structural design strategies, fabrication technologies, and critical performance. Relevant studies were collected from major scientific databases, including Web of Science and Google Scholar, with a focus on insulation materials, coating technologies, and thermal management approaches used in drilling systems. The analysis indicates that advanced insulation systems, including polymer-based coatings, silica aerogels, vacuum-insulated layers, and phase-change materials, can significantly enhance thermal management in drilling operations. These technologies can reduce heat loss by approximately 40–60% (i.e., 400–600 W·m−2) and maintain drilling-fluid temperature differentials of 10–18 °C under HTHP conditions. In addition, fabrication techniques such as plasma spraying, composite fabrication, and additive manufacturing enable the development of multifunctional insulation systems with improved thermal, mechanical, and corrosion-resistant properties. Hybrid TIDP systems integrating nanocomposites and advanced polymers show strong potential for improving drilling safety and efficiency. However, challenges related to durability, scalability, and cost remain, highlighting the need for further research on multilayer insulation architectures and sustainable materials. Full article
(This article belongs to the Section Polymer Applications)
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36 pages, 4882 KB  
Review
Emerging Trends in Ultrasonic and Friction Stir Spot Welding of Polymers and Metal-Polymer Hybrids: A Review of Process Mechanics, Microstructure, and Joint Performance
by Kanchan Kumari, Swastik Pradhan, Chitrasen Samantra, Manisha Priyadarshini, Abhishek Barua and Debabrata Dhupal
Materials 2026, 19(8), 1602; https://doi.org/10.3390/ma19081602 - 16 Apr 2026
Viewed by 730
Abstract
The growing need for lightweight, multifunctional, and high-performance structures in the automotive, aerospace, electronics, and medical industries has driven the development of advanced joining technologies for polymers and metal-polymer combinations. Among these, ultrasonic welding (USW) and friction stir spot welding (FSSW) have emerged [...] Read more.
The growing need for lightweight, multifunctional, and high-performance structures in the automotive, aerospace, electronics, and medical industries has driven the development of advanced joining technologies for polymers and metal-polymer combinations. Among these, ultrasonic welding (USW) and friction stir spot welding (FSSW) have emerged as promising solid-state techniques capable of producing reliable joints with minimal thermal degradation and enhanced interfacial bonding. This review focuses on recent developments in USW and FSSW of thermoplastics, fiber-reinforced composites, and hybrid metal–polymer systems, with a particular emphasis on process mechanics, microstructural evolution, and joint performance. The mechanisms of heat generation, material flow behavior, and consolidation are discussed in relation to key process parameters, including applied pressure, rotational speed, vibration amplitude, plunge depth, and dwell time. Microstructural transformations such as polymer chain orientation, recrystallization, interfacial diffusion, and defect formation are analyzed to establish process–structure–property relationships. Mechanical performance metrics, including lap shear strength, fatigue resistance, impact behavior, and environmental durability, are critically compared across different materials and welding methods. Furthermore, recent advances in numerical and thermo-mechanical modeling, in situ process monitoring, and data-driven optimization are discussed to highlight pathways toward predictive and scalable manufacturing. Current industrial applications and existing limitations such as challenges in automation, thickness constraints, and hybrid material compatibility are also evaluated. Finally, key research gaps and future directions are identified to improve joint reliability, sustainability, and broader industrial adoption of advanced solid-state welding technologies. Full article
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18 pages, 7239 KB  
Article
Nano-Engineered Sandwich Interlayers for Simultaneous Functionalization and Delamination Resistance in CFRPs
by Pengzhe Ji, Yunxiao Zhang, Yunfu Ou, Juan Li and Dongsheng Mao
Polymers 2026, 18(8), 957; https://doi.org/10.3390/polym18080957 - 14 Apr 2026
Viewed by 494
Abstract
Carbon fiber-reinforced polymers (CFRP) are widely employed in advanced manufacturing sectors such as aerospace, wind energy, and new energy vehicles owing to their high specific strength and stiffness. The growing demand for lightweight, high-performance, and multifunctional materials has accelerated the development of structurally [...] Read more.
Carbon fiber-reinforced polymers (CFRP) are widely employed in advanced manufacturing sectors such as aerospace, wind energy, and new energy vehicles owing to their high specific strength and stiffness. The growing demand for lightweight, high-performance, and multifunctional materials has accelerated the development of structurally and functionally integrated CFRP. Introducing functional interlayers between composite laminates is an effective strategy to impart additional functionalities; however, such interlayers are often multi-component and structurally complex. A critical challenge remains to integrate functionality without compromising, and preferably enhancing, the load-bearing capability of CFRP, particularly their resistance to interlaminar delamination. In this study, electrically heated CFRP incorporating a sandwich-structured interlayer composed of glass fiber mesh fabric/CNT veils doped with carbon nanotubes/glass fiber mesh fabric (GF/CNTs-CNTv/GF) was investigated. The effects of interlayer architecture and CNT loading on the Mode II interlaminar fracture toughness were systematically examined. Delamination failure modes and interlaminar toughening mechanisms were analyzed using scanning electron microscopy and ultra-depth-of-field three-dimensional microscopy. The results demonstrate that an optimal CNT pre-impregnation concentration of 1.0 wt% yielded a maximum GIIC of 1644.8 J/m2, corresponding to a 103.06% increase relative to the reference laminate. The enhanced performance is attributed to simultaneous optimization of interfacial “nano-engineering” effects, including matrix toughening and a pronounced “nano-anchoring” mechanism induced by CNT. These effects promote a transition in failure mode from weak interfacial debonding to a mesh-block composite delamination pattern, thereby activating multiple energy-dissipation mechanisms such as crack deflection, fiber pull-out, rupture, and bridging. This work highlights the effectiveness of CNT-modified sandwich interlayers in improving delamination resistance and provides both theoretical insight and experimental validation for the design of multifunctional CFRP with superior interlaminar fracture toughness. Full article
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24 pages, 5955 KB  
Article
Effect of Different Carbon-Supported Catalysts on the Thermal Decomposition of Energetic Thermoplastic Elastomers
by Zhu Wang, Wenhao Liu, Haoyu Yu, Tianqi Li, Yunjun Luo and Yonghao Xiao
Materials 2026, 19(8), 1542; https://doi.org/10.3390/ma19081542 - 12 Apr 2026
Viewed by 563
Abstract
To enhance the thermal decomposition properties of glycidyl azide polymer energetic thermoplastic elastomer (GAP-ETPE), the effects of nano-CuO supported on different carbon carriers (GO and CNT) were systematically investigated in this study. The structural characteristics and catalytic performances were comprehensively analyzed using XRD, [...] Read more.
To enhance the thermal decomposition properties of glycidyl azide polymer energetic thermoplastic elastomer (GAP-ETPE), the effects of nano-CuO supported on different carbon carriers (GO and CNT) were systematically investigated in this study. The structural characteristics and catalytic performances were comprehensively analyzed using XRD, Raman, XPS, UPS, BET, SEM, and TEM, coupled with thermal analysis techniques including TG-DSC and TG-MS. The results indicate that the catalytic performance follows the descending order of CuO/CNT > CuO/GO > CuO. Notably, CuO/CNT exhibits the optimal catalytic activity, advancing the exothermic peak temperature of the azide groups by approximately 33 °C and resulting in a more concentrated heat release process. The superior synergistic catalytic effect of CuO/CNT is attributed to the following: the three-dimensional network constructed by CNT effectively overcomes the agglomeration of CuO nanoparticles and the restacking defects typical of GO nanosheets, thereby significantly reducing the gas–solid mass transfer resistance. Simultaneously, the highly graphitized sp2 conjugated skeleton of CNT provides an exceptional electron transport capability, facilitating rapid electron migration. These findings demonstrate that the structure of carbon supports profoundly influences the synergistic catalytic effect of CuO, offering valuable insights into the design of highly efficient catalysts for energetic binders. Full article
(This article belongs to the Section Catalytic Materials)
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