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Search Results (552)

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Keywords = heat transport enhancement

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26 pages, 5677 KiB  
Article
CFD Investigation on the Thermal Comfort for an Office Room
by Mazen M. Othayq
Buildings 2025, 15(15), 2802; https://doi.org/10.3390/buildings15152802 (registering DOI) - 7 Aug 2025
Abstract
Heating, Ventilating, and Air Conditioning (HVAC) systems are important and essential for use in our daily comfort, either in homes, work, or transportation. And it is crucial to study the air movement coming from the inlet diffuser for a better design to enhance [...] Read more.
Heating, Ventilating, and Air Conditioning (HVAC) systems are important and essential for use in our daily comfort, either in homes, work, or transportation. And it is crucial to study the air movement coming from the inlet diffuser for a better design to enhance thermal comfort and energy consumption. The primary objective of the presented work is to investigate the thermal comfort within a faculty office occupied by two faculty members using the Computational Fluid Dynamics (CFD) methodology. First, an independent mesh study was performed to reduce the uncertainty related to the mesh size. In addition, the presented CFD approach was validated against available experimental data from the literature. Then, the effect of inlet air temperature and velocity on air movement and temperature distribution is investigated using Ansys Fluent. To be as reasonable as possible, the persons who occupy the office, lights, windows, tables, the door, and computers are accounted for in the CFD simulation. After that, the Predicted Mean Vote (PMV) was evaluated at three different locations inside the room, and the approximate total energy consumption was obtained for the presented cases. The CFD results showed that, for the presented cases, the sensation was neutral with the lowest energy consumption when the supply air velocity was 1 m/s and the temperature was 21 °C. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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12 pages, 2376 KiB  
Article
Investigating Helium-Induced Thermal Conductivity Degradation in Fusion-Relevant Copper: A Molecular Dynamics Approach
by Xu Yu, Hanlong Wang and Hai Huang
Materials 2025, 18(15), 3702; https://doi.org/10.3390/ma18153702 - 6 Aug 2025
Abstract
Copper alloys are critical heat sink materials for fusion reactor divertors due to their high thermal conductivity (TC) and strength, yet their performance under extreme particle bombardment and heat fluxes in future tokamaks requires enhancement. While neutron-induced transmutation helium affects the properties of [...] Read more.
Copper alloys are critical heat sink materials for fusion reactor divertors due to their high thermal conductivity (TC) and strength, yet their performance under extreme particle bombardment and heat fluxes in future tokamaks requires enhancement. While neutron-induced transmutation helium affects the properties of copper, the atomistic mechanisms linking helium bubble size to thermal transport remain unclear. This study employs non-equilibrium molecular dynamics (NEMD) simulations to isolate the effect of bubble diameter (10, 20, 30, 40 Å) on TC in copper, maintaining a constant He-to-vacancy ratio of 2.5. Results demonstrate that larger bubbles significantly impair TC. This reduction correlates with increased Kapitza thermal resistance and pronounced lattice distortion from outward helium diffusion, intensifying phonon scattering. Phonon density of states (PDOS) analysis reveals diminished low-frequency peaks and an elevated high-frequency peak for bubbles >30 Å, confirming phonon confinement and localized vibrational modes. The PDOS overlap factor decreases with bubble size, directly linking microstructural evolution to thermal resistance. These findings elucidate the size-dependent mechanisms of helium bubble impacts on thermal transport in copper divertor materials. Full article
(This article belongs to the Special Issue Advances in Computation and Modeling of Materials Mechanics)
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24 pages, 6356 KiB  
Article
Tectonic Rift-Related Manganese Mineralization System and Its Geophysical Signature in the Nanpanjiang Basin
by Daman Cui, Zhifang Zhao, Wenlong Liu, Haiying Yang, Yun Liu, Jianliang Liu and Baowen Shi
Remote Sens. 2025, 17(15), 2702; https://doi.org/10.3390/rs17152702 - 4 Aug 2025
Viewed by 226
Abstract
The southeastern Yunnan region in the southwestern Nanpanjiang Basin is one of the most important manganese enrichment zones in China. Manganese mineralization is mainly confined to marine mud–sand–carbonate interbeds of the Middle Triassic Ladinian Falang Formation (T2f), which contains several [...] Read more.
The southeastern Yunnan region in the southwestern Nanpanjiang Basin is one of the most important manganese enrichment zones in China. Manganese mineralization is mainly confined to marine mud–sand–carbonate interbeds of the Middle Triassic Ladinian Falang Formation (T2f), which contains several medium to large deposits such as Dounan, Baixian, and Yanzijiao. However, the geological processes that control manganese mineralization in this region remain insufficiently understood. Understanding the tectonic evolution of the basin is therefore essential to unravel the mechanisms of Middle Triassic metallogenesis. This study investigates how rift-related tectonic activity influences manganese ore formation. This study integrates global gravity and magnetic field models (WGM2012, EMAG2v3), audio-frequency magnetotelluric (AMT) profiles, and regional geological data to investigate ore-controlling structures. A distinct gravity low–magnetic high belt is delineated along the basin axis, indicating lithospheric thinning and enhanced mantle-derived heat flow. Structural interpretation reveals a rift system with a checkerboard pattern formed by intersecting NE-trending major faults and NW-trending secondary faults. Four hydrothermal plume centers are identified at these fault intersections. AMT profiles show that manganese ore bodies correspond to stable low-resistivity zones, suggesting fluid-rich, hydrothermally altered horizons. These findings demonstrate a strong spatial coupling between hydrothermal activity and mineralization. This study provides the first identification of the internal rift architecture within the Nanpanjiang Basin. The basin-scale rift–graben system exerts first-order control on sedimentation and manganese metallogenesis, supporting a trinity model of tectonic control, hydrothermal fluid transport, and sedimentary enrichment. These insights not only improve our understanding of rift-related manganese formation in southeastern Yunnan but also offer a methodological framework applicable to similar rift basins worldwide. Full article
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16 pages, 4328 KiB  
Article
High-Throughput Study on Nanoindentation Deformation of Al-Mg-Si Alloys
by Tong Shen, Guanglong Xu, Fuwen Chen, Shuaishuai Zhu and Yuwen Cui
Materials 2025, 18(15), 3663; https://doi.org/10.3390/ma18153663 - 4 Aug 2025
Viewed by 188
Abstract
Al-Mg-Si (6XXX) series aluminum alloys are widely applied in aerospace and transportation industries. However, exploring how varying compositions affect alloy properties and deformation mechanisms is often time-consuming and labor-intensive due to the complexity of the multicomponent composition space and the diversity of processing [...] Read more.
Al-Mg-Si (6XXX) series aluminum alloys are widely applied in aerospace and transportation industries. However, exploring how varying compositions affect alloy properties and deformation mechanisms is often time-consuming and labor-intensive due to the complexity of the multicomponent composition space and the diversity of processing and heat treatments. This study, inspired by the Materials Genome Initiative, employs high-throughput experimentation—specifically the kinetic diffusion multiple (KDM) method—to systematically investigate how the pop-in effect, indentation size effect (ISE), and creep behavior vary with the composition of Al-Mg-Si alloys at room temperature. To this end, a 6016/Al-3Si/Al-1.2Mg/Al KDM material was designed and fabricated. After diffusion annealing at 530 °C for 72 h, two junction areas were formed with compositional and microstructural gradients extending over more than one thousand micrometers. Subsequent solution treatment (530 °C for 30 min) and artificial aging (185 °C for 20 min) were applied to simulate industrial processing conditions. Comprehensive characterization using electron probe microanalysis (EPMA), nanoindentation with continuous stiffness measurement (CSM), and nanoindentation creep tests across these gradient regions revealed key insights. The results show that increasing Mg and Si content progressively suppresses the pop-in effect. When the alloy composition exceeds 1.0 wt.%, the pop-in events are nearly eliminated due to strong interactions between solute atoms and mobile dislocations. In addition, adjustments in the ISE enabled rapid evaluation of the strengthening contributions from Mg and Si in the microscale compositional array, demonstrating that the optimum strengthening occurs when the Mg-to-Si atomic ratio is approximately 1 under a fixed total alloy content. Furthermore, analysis of the creep stress exponent and activation volume indicated that dislocation motion is the dominant creep mechanism. Overall, this enhanced KDM method proves to be an effective conceptual tool for accelerating the study of composition–deformation relationships in Al-Mg-Si alloys. Full article
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19 pages, 4765 KiB  
Article
Dehydration-Driven Changes in Solid Polymer Electrolytes: Implications for Titanium Anodizing Efficiency
by Andrea Valencia-Cadena, Maria Belén García-Blanco, Pablo Santamaría and Joan Josep Roa
Materials 2025, 18(15), 3645; https://doi.org/10.3390/ma18153645 - 3 Aug 2025
Viewed by 217
Abstract
This study investigates the thermal stability and microstructural evolution of the solid electrolyte medium used in DLyte® dry electropolishing and dry anodizing processes. Samples were thermally aged between 30 °C and 45 °C to simulate Joule heating during industrial operation. Visual and [...] Read more.
This study investigates the thermal stability and microstructural evolution of the solid electrolyte medium used in DLyte® dry electropolishing and dry anodizing processes. Samples were thermally aged between 30 °C and 45 °C to simulate Joule heating during industrial operation. Visual and SEM analyses revealed shape deformation and microcrack formation at temperatures above 40 °C, potentially reducing particle packing efficiency and electrolyte performance. Particle size distribution shifted from bimodal to trimodal upon aging, with an overall size reduction of up to 39.5% due to dehydration effects, impacting ionic transport properties. Weight-loss measurements indicated a diffusion-limited dehydration mechanism, stabilizing at 15–16% mass loss. Fourier transform infrared analysis confirmed water removal while maintaining the essential sulfonic acid groups responsible for ionic conductivity. In dry anodizing tests on titanium, aged electrolytes enhanced process efficiency, producing TiO2 films with improved optical properties—color and brightness—while preserving thickness and uniformity (~70 nm). The results highlight the need to carefully control thermal exposure to maintain electrolyte integrity and ensure consistent process performance. Full article
(This article belongs to the Special Issue Novel Materials and Techniques for Dental Implants)
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23 pages, 2950 KiB  
Article
Thermal Conductivity of UO2 with Defects via DFT+U Calculation and Boltzmann Transport Equation
by Jiantao Qin, Min Zhao, Rongjian Pan, Aitao Tang and Lu Wu
Materials 2025, 18(15), 3584; https://doi.org/10.3390/ma18153584 - 30 Jul 2025
Viewed by 262
Abstract
Accurate evaluation of the thermal conductivity of UO2 with defects is very significant for optimizing fuel performance and enhancing the safety design of reactors. We employed a method that combines the Boltzmann transport equation with DFT+U to calculate the thermal conductivity of [...] Read more.
Accurate evaluation of the thermal conductivity of UO2 with defects is very significant for optimizing fuel performance and enhancing the safety design of reactors. We employed a method that combines the Boltzmann transport equation with DFT+U to calculate the thermal conductivity of UO2 containing fission products and irradiation-induced point defects. Our investigation reveals that the thermal conductivity of UO2 is influenced by defect concentration, defect type, and temperature. Fission products and irradiation defects result in a decrease in thermal conductivity, but they have markedly different impacts on phonon scattering mechanisms. Metal cations tend to scatter low-frequency phonons (less than 5.8 THz), while the fission gas xenon scatters both low-frequency and high-frequency phonons (greater than 5.8 THz), depending on its occupancy at lattice sites. Uranium vacancies scatter low-frequency phonons, while oxygen vacancies scatter high-frequency phonons. When uranium and oxygen vacancies coexist, they scatter phonons across the entire frequency spectrum, which further results in a significant reduction in the thermal conductivity of UO2. Our calculated results align well with experimental data across a wide temperature range and provide fundamental insights into the heat transfer mechanisms in irradiated UO2. These findings are essential for establishing a thermal conductivity database for UO2 under various irradiation conditions and benefit the development of advanced high-performance UO2 fuel. Full article
(This article belongs to the Section Energy Materials)
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13 pages, 3319 KiB  
Technical Note
Intensification Trend and Mechanisms of Oman Upwelling During 1993–2018
by Xiwu Zhou, Yun Qiu, Jindian Xu, Chunsheng Jing, Shangzhan Cai and Lu Gao
Remote Sens. 2025, 17(15), 2600; https://doi.org/10.3390/rs17152600 - 26 Jul 2025
Viewed by 380
Abstract
The long-term trend of coastal upwelling under global warming has been a research focus in recent years. Based on datasets including sea surface temperature (SST), sea surface wind, air–sea heat fluxes, ocean currents, and sea level pressure, this study explores the long-term trend [...] Read more.
The long-term trend of coastal upwelling under global warming has been a research focus in recent years. Based on datasets including sea surface temperature (SST), sea surface wind, air–sea heat fluxes, ocean currents, and sea level pressure, this study explores the long-term trend and underlying mechanisms of the Oman coastal upwelling intensity in summer during 1993–2018. The results indicate a persistent decrease in SST within the Oman upwelling region during this period, suggesting an intensification trend of Oman upwelling. This trend is primarily driven by the strengthened positive wind stress curl (WSC), while the enhanced net shortwave radiation flux at the sea surface partially suppresses the SST cooling induced by the strengthened positive WSC, and the effect of horizontal oceanic heat transport is weak. Further analysis revealed that the increasing trend in the positive WSC results from the nonuniform responses of sea level pressure and the associated surface winds to global warming. There is an increasing trend in sea level pressure over the western Arabian Sea, coupled with decreasing atmospheric pressure over the Arabian Peninsula and the Somali Peninsula. This enhances the atmospheric pressure gradient between land and sea, and consequently strengthens the alongshore winds off the Oman coast. However, in the coastal region, wind changes are less pronounced, resulting in an insignificant trend in the alongshore component of surface wind. Consequently, it results in the increasing positive WSC over the Oman upwelling region, and sustains the intensification trend of Oman coastal upwelling. Full article
(This article belongs to the Section Ocean Remote Sensing)
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25 pages, 15938 KiB  
Article
Coastal Eddy Detection in the Balearic Sea: SWOT Capabilities
by Laura Fortunato, Laura Gómez-Navarro, Vincent Combes, Yuri Cotroneo, Giuseppe Aulicino and Ananda Pascual
Remote Sens. 2025, 17(15), 2552; https://doi.org/10.3390/rs17152552 - 23 Jul 2025
Viewed by 495
Abstract
Mesoscale coastal eddies are key components of ocean circulation, mediating the transport of heat, nutrients, and marine debris. The Surface Water and Ocean Topography (SWOT) mission provides high-resolution sea surface height data, offering a novel opportunity to improve the observation and characterization of [...] Read more.
Mesoscale coastal eddies are key components of ocean circulation, mediating the transport of heat, nutrients, and marine debris. The Surface Water and Ocean Topography (SWOT) mission provides high-resolution sea surface height data, offering a novel opportunity to improve the observation and characterization of these features, especially in coastal regions where conventional altimetry is limited. In this study, we investigate a mesoscale anticyclonic coastal eddy observed southwest of Mallorca Island, in the Balearic Sea, to assess the impact of SWOT-enhanced altimetry in resolving its structure and dynamics. Initial eddy identification is performed using satellite ocean color imagery, followed by a qualitative and quantitative comparison of multiple altimetric datasets, ranging from conventional nadir altimetry to wide-swath products derived from SWOT. We analyze multiple altimetric variables—Sea Level Anomaly, Absolute Dynamic Topography, Velocity Magnitude, Eddy Kinetic Energy, and Relative Vorticity—highlighting substantial differences in spatial detail and intensity. Our results show that SWOT-enhanced observations significantly improve the spatial characterization and dynamical depiction of the eddy. Furthermore, Lagrangian transport simulations reveal how altimetric resolution influences modeled transport pathways and retention patterns. These findings underline the critical role of SWOT in advancing the monitoring of coastal mesoscale processes and improving our ability to model oceanic transport mechanisms. Full article
(This article belongs to the Special Issue Satellite Remote Sensing for Ocean and Coastal Environment Monitoring)
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14 pages, 1928 KiB  
Article
Thermal and Flammability Analysis of Polyurethane Foams with Solid and Liquid Flame Retardants: Comparative Study
by Dorota Głowacz-Czerwonka, Patrycja Zakrzewska, Beata Zygmunt-Kowalska and Iwona Zarzyka
Polymers 2025, 17(14), 1977; https://doi.org/10.3390/polym17141977 - 18 Jul 2025
Viewed by 280
Abstract
The thermal properties and flammability of rigid polyurethane foams (RPUFs) containing various flame retardants, including solid (melamine, expanded graphite (EG), Exolit OP 935, ammonium polyphosphate (APP)) and liquid (Roflam B7, Roflam PLO) types, added at 30 wt.% and 60 wt.% by weight have [...] Read more.
The thermal properties and flammability of rigid polyurethane foams (RPUFs) containing various flame retardants, including solid (melamine, expanded graphite (EG), Exolit OP 935, ammonium polyphosphate (APP)) and liquid (Roflam B7, Roflam PLO) types, added at 30 wt.% and 60 wt.% by weight have been evaluated. Thermogravimetric analysis (TGA) demonstrated enhanced thermal stability, with the maximum 10% weight loss temperature (292 °C, +34 °C vs. reference) observed for foams containing 60 wt.% Exolit OP 935 and APP. The limiting oxygen index (LOI) test demonstrated the optimal performance for 30 wt.% APP and melamine (26.4 vol.% vs. 18.7 vol.% reference). In the UL-94 test, Exolit OP 935 and APP achieved a V-0 rating. The 60 wt.% Exolit with an EG blend also demonstrated a substantial reduction in heat release rate. These findings underscore the cooperative effects of hybrid flame retardants, thereby supporting their utilization in fire-safe RPUFs for construction and transport. Full article
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18 pages, 1814 KiB  
Article
AI-Based Damage Risk Prediction Model Development Using Urban Heat Transport Pipeline Attribute Information
by Sungyeol Lee, Jaemo Kang, Jinyoung Kim and Myeongsik Kong
Appl. Sci. 2025, 15(14), 8003; https://doi.org/10.3390/app15148003 - 18 Jul 2025
Viewed by 217
Abstract
This study analyzed the probability of damage in heat transport pipelines buried in urban areas using pipeline attribute information and damage history data and developed an AI-based predictive model. A dataset was constructed by collecting spatial and attribute data of pipelines and defining [...] Read more.
This study analyzed the probability of damage in heat transport pipelines buried in urban areas using pipeline attribute information and damage history data and developed an AI-based predictive model. A dataset was constructed by collecting spatial and attribute data of pipelines and defining basic units according to specific standards. Damage trends were analyzed based on pipeline attributes, and correlation analysis was performed to identify influential factors. These factors were applied to three machine learning algorithms: Random Forest, eXtreme gradient boosting (XGBoost), and light gradient boosting machine (LightGBM). The model with optimal performance was selected by comparing evaluation indicators including the F2-score, accuracy, and area under the curve (AUC). The LightGBM model trained on data from pipelines in use for over 20 years showed the best performance (F2-score = 0.804, AUC = 0.837). This model was used to generate a risk map visualizing the probability of pipeline damage. The map can aid in the efficient management of urban heat transport systems by enabling preemptive maintenance in high-risk areas. Incorporating external environmental data and auxiliary facility information in future models could further enhance reliability and support the development of a more effective maintenance decision-making system. Full article
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15 pages, 2521 KiB  
Article
Interface-Driven Electrothermal Degradation in GaN-on-Diamond High Electron Mobility Transistors
by Huanran Wang, Yifan Liu, Xiangming Dong, Abid Ullah, Jisheng Sun, Chuang Zhang, Yucheng Xiong, Peng Gu, Ge Chen and Xiangjun Liu
Nanomaterials 2025, 15(14), 1114; https://doi.org/10.3390/nano15141114 - 18 Jul 2025
Viewed by 321
Abstract
Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device [...] Read more.
Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device performance. In this work, TCAD simulations were employed to systematically investigate the effects of thermal boundary layer (TBL) thickness (dTBL) and thermal conductivity (κTBL) on the electrothermal behavior of GaN-on-diamond HEMTs. Results show that increasing the TBL thickness (5–20 nm) or decreasing its thermal conductivity (0.1–1.0 W/(m·K)) leads to elevated hotspot temperatures and degraded electron mobility, resulting in a notable deterioration of IV characteristics. The nonlinear dependence of device performance on κTBL is attributed to Fourier’s law, where heat flux is inversely proportional to thermal resistance. Furthermore, the co-analysis of substrate thermal conductivity and interfacial quality reveals that interface TBR has a more dominant impact on device behavior than substrate conductivity. Remarkably, devices with low thermal conductivity substrates and optimized interfaces can outperform those with high-conductivity substrates but poor interfacial conditions. These findings underscore the critical importance of interface engineering in thermal management of GaN–diamond HEMTs and provide a theoretical foundation for future work on phonon transport and defect-controlled thermal interfaces. Full article
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22 pages, 1906 KiB  
Article
Explainable and Optuna-Optimized Machine Learning for Battery Thermal Runaway Prediction Under Class Imbalance Conditions
by Abir El Abed, Ghalia Nassreddine, Obada Al-Khatib, Mohamad Nassereddine and Ali Hellany
Thermo 2025, 5(3), 23; https://doi.org/10.3390/thermo5030023 - 15 Jul 2025
Viewed by 391
Abstract
Modern energy storage systems for both power and transportation are highly related to lithium-ion batteries (LIBs). However, their safety depends on a potentially hazardous failure mode known as thermal runaway (TR). Predicting and classifying TR causes can widely enhance the safety of power [...] Read more.
Modern energy storage systems for both power and transportation are highly related to lithium-ion batteries (LIBs). However, their safety depends on a potentially hazardous failure mode known as thermal runaway (TR). Predicting and classifying TR causes can widely enhance the safety of power and transportation systems. This paper presents an advanced machine learning method for forecasting and classifying the causes of TR. A generative model for synthetic data generation was used to handle class imbalance in the dataset. Hyperparameter optimization was conducted using Optuna for four classifiers: Support Vector Machine (SVM), Multi-Layer Perceptron (MLP), tabular network (TabNet), and Extreme Gradient Boosting (XGBoost). A three-fold cross-validation approach was used to guarantee a robust evaluation. An open-source database of LIB failure events is used for model training and testing. The XGBoost model outperforms the other models across all TR categories by achieving 100% accuracy and a high recall (1.00). Model results were interpreted using SHapley Additive exPlanations analysis to investigate the most significant factors in TR predictors. The findings show that important TR indicators include energy adjusted for heat and weight loss, heater power, average cell temperature upon activation, and heater duration. These findings guide the design of safer battery systems and preventive monitoring systems for real applications. They can help experts develop more efficient battery management systems, thereby improving the performance and longevity of battery-operated devices. By enhancing the predictive knowledge of temperature-driven failure mechanisms in LIBs, the study directly advances thermal analysis and energy storage safety domains. Full article
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11 pages, 3779 KiB  
Article
Synergistic Enhancement of LiNO3-NaNO3-KNO3-NaNO2 Thermophysical Properties Through Dual Nano-Additives: SiO2 and MgO
by Chuang Zhu, Wenxuan He, Manting Gu, Dan Zhang and Baiyuan Tian
Nanomaterials 2025, 15(14), 1094; https://doi.org/10.3390/nano15141094 - 14 Jul 2025
Viewed by 281
Abstract
LiNO3-NaNO3-KNO3-NaNO2 has a relatively low phase-change temperature, making it suitable for low-temperature heat utilization systems. This study focuses on the performance optimization of the quaternary molten salt to advance its applicability. A series of nanocomposites consisting [...] Read more.
LiNO3-NaNO3-KNO3-NaNO2 has a relatively low phase-change temperature, making it suitable for low-temperature heat utilization systems. This study focuses on the performance optimization of the quaternary molten salt to advance its applicability. A series of nanocomposites consisting of nano-SiO2/MgO and the quaternary salt are prepared. Core thermophysical properties, including phase transition behaviors and thermal transport parameters, are quantified. The incorporation of nano-SiO2/MgO induces moderate adjustments to the melting point and latent heat yet demonstrates an obvious enhancement in specific heat capacity. Optimal doping at 0.7 wt.% SiO2 and 0.3 wt.% MgO yields a molten-state specific heat of 1.51 J/(g·K), representing a 6% increase over the undoped base salt (1.42 J/(g·K)). By combining the thermal diffusivity properties of the samples, this study found that the doping of nanoparticles typically induces new structures in molten salts that tend to enhance the specific heat capacity while simultaneously reducing thermal diffusivity. Full article
(This article belongs to the Special Issue Advances in Nano-Enhanced Thermal Functional Materials)
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17 pages, 3986 KiB  
Article
Titanate-Coupled Aluminum as an Interfacial Modifier for Enhanced Thermal and Mechanical Performance in Hybrid Epoxy Composites
by Hai-Long Cheng, Seul-Yi Lee, Na Chu, Se-Yeol Lee, Fan-Long Jin and Soo-Jin Park
Polymers 2025, 17(14), 1922; https://doi.org/10.3390/polym17141922 - 11 Jul 2025
Viewed by 467
Abstract
Thermally conductive polymer composites are essential for effective heat dissipation in electronic packaging, where both thermal management and mechanical reliability are critical. Although diglycidyl ether of bisphenol-A (DGEBA)-based epoxies exhibit favorable properties, their intrinsically low thermal conductivity limits broader applications. Incorporating conductive fillers, [...] Read more.
Thermally conductive polymer composites are essential for effective heat dissipation in electronic packaging, where both thermal management and mechanical reliability are critical. Although diglycidyl ether of bisphenol-A (DGEBA)-based epoxies exhibit favorable properties, their intrinsically low thermal conductivity limits broader applications. Incorporating conductive fillers, such as expanded graphite (EG) and metal powders, enhances heat transport but often compromises mechanical strength due to poor filler–matrix compatibility. In this study, we address this trade-off by employing a titanate coupling agent to surface-modify aluminum (Al) fillers, thereby improving interfacial adhesion and dispersion within the DGEBA matrix. Our results show that incorporating 10 wt% untreated Al increases thermal conductivity from 7.35 to 9.60 W/m·K; however, this gain comes at the cost of flexural strength, which drops to 18.29 MPa. In contrast, titanate-modified Al (Ti@Al) not only preserves high thermal conductivity but also restores mechanical performance, achieving a flexural strength of 35.31 MPa (at 5 wt% Ti@Al) and increasing impact strength from 0.60 to 1.01 kJ/m2. These findings demonstrate that interfacial engineering via titanate coupling offers a compelling strategy to overcome the thermal–mechanical trade-off in hybrid composites, enabling the development of high-performance materials for advanced thermal interface and structural applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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37 pages, 6674 KiB  
Article
Marangoni Convection of Self-Rewetting Fluid Layers with a Deformable Interface in a Square Enclosure and Driven by Imposed Nonuniform Heat Energy Fluxes
by Bashir Elbousefi, William Schupbach and Kannan N. Premnath
Energies 2025, 18(13), 3563; https://doi.org/10.3390/en18133563 - 6 Jul 2025
Viewed by 275
Abstract
Fluids that exhibit self-rewetting properties, such as aqueous long-chain alcohol solutions, display a unique quadratic relationship between surface tension and temperature and are marked by a positive gradient. This characteristic leads to distinctive patterns of thermocapillary convection and associated interfacial dynamics, setting self-rewetting [...] Read more.
Fluids that exhibit self-rewetting properties, such as aqueous long-chain alcohol solutions, display a unique quadratic relationship between surface tension and temperature and are marked by a positive gradient. This characteristic leads to distinctive patterns of thermocapillary convection and associated interfacial dynamics, setting self-rewetting fluids apart from normal fluids (NFs). The potential to improve heat transfer using self-rewetting fluids (SRFs) is garnering interest for use in various technologies, including low-gravity conditions and microfluidic systems. Our research aims to shed light on the contrasting behaviors of SRFs in comparison to NFs regarding interfacial transport phenomena. This study focuses on the thermocapillary convection in SRF layers with a deformable interface enclosed inside a closed container modeled as a square cavity, which is subject to nonuniform heating, represented using a Gaussian profile for the heat flux variation on one of its sides, in the absence of gravity. To achieve this, we have enhanced a central-moment-based lattice Boltzmann method (LBM) utilizing three distribution functions for tracking interfaces, computing two-fluid motions with temperature-dependent surface tension and energy transport, respectively. Through numerical simulations, the impacts of several characteristic parameters, including the viscosity and thermal conductivity ratios, as well as the surface tension–temperature sensitivity parameters, on the distribution and magnitude of the thermocapillary-driven motion are examined. In contrast to that in NFs, the counter-rotating pair of vortices generated in the SRF layers, due to the surface tension gradient at the interface, is found to be directed toward the SRF layers’ hotter zones. Significant interfacial deformations are observed, especially when there are contrasts in the viscosities of the SRF layers. The thermocapillary convection is found to be enhanced if the bottom SRF layer has a higher thermal conductivity or viscosity than that of the top layer or when distributed, rather than localized, heating is applied. Furthermore, the higher the magnitude of the effect of the dimensionless quadratic surface tension sensitivity coefficient on the temperature, or of the effect of the imposed heat flux, the greater the peak interfacial velocity current generated due to the Marangoni stresses. In addition, an examination of the Nusselt number profiles reveals significant redistribution of the heat transfer rates in the SRF layers due to concomitant nonlinear thermocapillary effects. Full article
(This article belongs to the Section J1: Heat and Mass Transfer)
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