Search Results (474)

We report a low-temperature plasma–liquid synthesis of crystalline β-Ga₂O₃ nanoparticles directly from aqueous solution. Pulsed discharge plasma bubbles generate reactive species that drive in situ dehydration and crystallization, bypassing the high-temperature calcination required by conventional methods. By varying the carrier gas, we tune morphology from uniform nanorice structures (He, Ar, and N₂) to amorphous microspheres (O₂ and air), revealing how plasma composition governs interfacial hydroxyl radical chemistry and growth kinetics. This approach demonstrates that localized plasma heating and reactive-species flux can achieve phase-selective oxide crystallization under ambient conditions, establishing plasma bubble reactors as a broadly applicable, low-temperature route for direct aqueous synthesis of crystalline wide-bandgap oxides that bridge solution chemistry and plasma nanomaterials design. Full article

Ultrastrong magnetic fields, ranging from 100 T to 1000 T, are generated exclusively by destructive pulsed magnets. While various generation methods exist, this review focuses on the Single-Turn Coil (STC) and Electromagnetic Flux Compression (EMFC) techniques, which provide optimal environments for high-precision measurements in materials science. First, we present recent technological breakthroughs in the EMFC method that have successfully achieved fields exceeding 1000 T. We then describe specialized measurement infrastructures for magneto-optics, magnetization, and magneto-transport, highlighting the development of miniaturized all-plastic cryostats and custom sample holders designed for the dual extremes of cryogenic temperatures and megagauss fields. Representative physical phenomena revealed through these techniques are discussed, including quantum phase transitions in frustrated magnets, Aharonov–Bohm effects in carbon nanotubes, and semiconductor-to-metal transitions in strongly correlated systems. Furthermore, we address emerging measurement platforms such as magnetostriction, specific heat, and ultrasound velocity. Throughout this review, we emphasize the instrumentation and experimental refinements that ensure reliable data acquisition in the ultrastrong pulsed field regime. Full article

Wire-arc directed energy deposition (arc-DED) of maraging 250 (M250) steel is of growing interest for aerospace, tooling, and defense applications, yet systematic process characterization data remain limited. This study presents a mixed quantitative–qualitative factorial comparison of three Fronius synergic transfer modes, GMAW-CMT-Mix, GMAW-CMT-Universal, and GMAW-Pulsed-Arc, for single-bead M250 deposition across wire feed speeds of 4.45 to 8.26 m/min and travel speeds of 0.3 to 1.5 m/min. Bead geometry and process behavior are characterized using non-contact optical profilometry and destructive methods (i.e., metallographic sectioning, optical microscopy, and Vickers microhardness). The material feed rate ratio, R_wt, is introduced as a unifying process descriptor; heat input and cross-sectional area scale linearly with R_wt, while travel speed primarily governs bead height and wire feed speed primarily governs bead width. At the highest travel speed tested, GMAW-CMT-Mix and GMAW-Pulsed-Arc exhibit bead humping, rendering those conditions unsuitable, while GMAW-CMT-Universal maintains stable deposition with consistent dilution and the lowest heat input at equivalent R_wt. GMAW-CMT-Mix yielded the highest dilution and hardness. Linear regression of process responses against R_wt gives $R^2$ exceeding 0.83 for both height and width across all modes. These results establish a characterization baseline supporting future multi-layer studies. Full article

Current manual laser cleaning methods often require highly skilled operators to achieve fast and reliable cleaning. This study investigated the feasibility of measuring thermal processes during laser metal cleaning to support the development of an automated and intelligent laser cleaning system. The measurement system was based on fast infrared (IR) diagnostics and used a field programmable gate array (FPGA) for fast signal analysis. Experiments were conducted on steel substrates covered with paint, scale, or corrosion. Thermal response in real-time for every laser pulse was monitored. Paints showed no solidification plateau, while steel exhibited a clear plateau above the ablation threshold. The scaled surface showed longer time intervals and higher heat accumulation. A histogram of time intervals enabled statistical analysis of the process. Time-resolved temperature values revealed hidden processes. These findings demonstrated the potential of IR thermal diagnostics for evaluating surface conditions and providing real-time data to optimise, monitor, and control laser cleaning processes. Full article

Dissimilar 7075-T6 and 6061-T6 aluminum alloy joints were fabricated using pulsed metal inert gas (P-MIG) welding with ER5356 filler wire. The effects of welding current (224 A, 234 A, and 244 A) on macro-morphology, microstructure, mechanical properties, and corrosion behavior were systematically investigated. As welding current increased, the top and bottom reinforcements first increased and then decreased, reaching maximum values at 234 A, while the front weld width exhibited the opposite trend. The weld zone consisted of equiaxed and dendritic grains, with partial remelting of AlFeMnSi intermetallic compounds observed in the heat-affected zones. The microhardness and tensile strength of the joints followed a similar trend of first decreasing and then increasing with welding current, achieving a maximum tensile strength of 203.9 MPa at 244 A, corresponding to 89.5% of the 6061-T6 base metal strength. Corrosion resistance varied across regions depending on the evaluation method. In intergranular corrosion tests, the 7075-HAZ showed the highest susceptibility due to grain boundary segregation of Mg and Zn. In electrochemical tests, the WZ exhibited the poorest corrosion resistance. For the 7075-HAZ, optimal corrosion resistance was achieved at 234 A, attributed to a stable passive film and uniform precipitate distribution. These findings provide valuable guidance for optimizing P-MIG welding parameters for dissimilar 7075/6061 aluminum alloy joints. Full article

Low-temperature atmospheric plasma (LTP) is widely used in industrial processes, such as disinfection, surface modification and wastewater treatment. The dielectric barrier discharge (DBD) is regarded as one of the most robust and reliable methods for generating LTP in ambient air. Compared to conventional AC excitation, pulsed powering offers several advantages (i.e., lower energy use and heat production). The present trend is to use short and fast pulses (in the nano- and picosecond range). In this review, the key design parameters of a DBD (barrier thickness, relative permittivity and gap distance) are discussed. Material-specific phenomena like surface charging and degradation are analyzed. The complex interactions between the pulse source and DBD are examined. By mapping the interdependencies, this review aims to support the rational design and optimization of pulsed DBD systems, and to facilitate their broader industrial use. Full article

Light-based therapies are becoming increasingly = more mainstream, not only within the medical science space, but also within the fields of cosmetic dermatology and personal grooming. Intense Pulsed Light (IPL) harnesses the ability of the natural chromophore–melanin to absorb light energy, which is translated into heat energy and consequently results in targeted thermolysis of cells rich in melanin. This mechanistic pathway lends itself to a wide range of applications, including long-term hair removal, skin rejuvenation, the treatment of unwanted pigmentation, and the treatment of ophthalmic conditions. The development of home use devices (HUDs) for the delivery of IPL-mediated hair removal has facilitated the self-administration of photothermal treatments and reduced reliance on clinical settings. In this study, we demonstrate a pioneering approach to model aspects of IPL-induced thermal induction and selective thermolysis in a complex human skin tissue equivalent. Our approach utilised a deactivated HUD with disabled safety features that allowed for the exposure of tissue constructs to high-fluence IPL. We demonstrate an increase in biomarkers consistent with increased cellular temperature, induction of apoptosis, and increased pro-inflammatory cytokine release following extreme treatment regimens, all of which correlate with an increased fluence and/or increased number of IPL pulses delivered. This method allowed for the identification of cellular events evoked by increasing fluence and extreme-exposure regimes. Full article

Urban trees are increasingly deployed as nature-based infrastructure to mitigate heat and manage stormwater, yet quantitative guidance on how species traits and site context shape transpiration remains fragmented. We conducted a systematic metadata analysis of seven field studies that measured daily transpiration rate in urban settings using heat-pulse methods. The units and spatial scales reported were harmonized with the sap flow density across active sapwood (J_s, g H₂O/${\mathrm{cm}}^2$/day) by converting reported stand transpiration and the outer 2 cm of sapwood sap flux using established Gaussian radial distribution functions for angiosperms and gymnosperms, which account for the non-linear decline in sap flux from the vascular cambium to the heartwood boundary. We then summarized distributions and tested group differences with Kruskal–Wallis and Dunn post hoc comparisons across wood anatomy, climate, soil texture, and planting configuration. Conifers exhibited significantly lower median $J_s$ (39.76 g/${\mathrm{cm}}^2$/day) than angiosperms, while the ring-porous group (median $J_s$ = 92.25 g/${\mathrm{cm}}^2$/day) and diffuse-porous groups (median $J_s$ = 96.70 g/${\mathrm{cm}}^2$/day) had similar distributions overall. Climate-modulated responses within wood anatomy groups differed, with diffuse-porous species exhibiting the highest median $J_s$ (152.59 g/${\mathrm{cm}}^2$/day) in semi-arid regions, ring-porous species maintaining comparatively stable median $J_s$ across climates (varying slightly between 80.72 and 99.32 g/${\mathrm{cm}}^2$/day), and conifers reaching their highest median $J_s$ (69.90 g/${\mathrm{cm}}^2$/day) in humid continental sites. Soil texture effects were consistent with moisture availability: sandy loam generally reduced $J_s$ relative to loam or silt loam for conifers and diffuse-porous species. Across anatomies, single trees transpired more than clustered trees or closed canopies. For example, planting as single trees increased median $J_s$ by 86% in conifers (from 33.01 to 61.37 g/${\mathrm{cm}}^2$/day) and by 45% in diffuse-porous species (from 81.31 to 118.25 g/${\mathrm{cm}}^2$/day). These results provide actionable ranges and contrasts to inform species selection and planting design for urban greening and runoff reduction, while highlighting data gaps for future research. Ultimately, by matching specific wood anatomies and planting configurations to local soil and climatic conditions, urban planners and ecohydrologists can strategically optimize urban forests to maximize targeted ecosystem services. Full article

The exponential growth of the fruit-processing industry generates significant quantities of organic by-products, such as peels, seeds, and pomace, which represent a rich but underutilized source of bioactive polyphenols. Valorizing these residues is critical for the transition toward a circular bioeconomy, yet conventional extraction methods remain solvent-intensive and kinetically inefficient. This review provides a comprehensive analysis of emerging green extraction technologies, specifically Ultrasound-Assisted (UAE), Microwave-Assisted (MAE), Enzyme-Assisted (EAE), Pressurized Liquid (PLE), and Supercritical Fluid Extraction (SFE), and Pulsed Electric Field (PEF), applied to key industrial matrices including apple, citrus, grape, olive, and coffee. Comparative data demonstrate that intensification technologies significantly outperform conventional maceration, with UAE and MAE reducing processing times by up to 90% while enhancing polyphenol yields by 20–55% through mechanisms such as acoustic cavitation and dipole rotation. Furthermore, high-pressure methods exhibit tunable selectivity, enabling the specific recovery of heat-sensitive anthocyanins and bound phenolics without the use of toxic organic solvents. The study concludes that the future of industrial valorization lies in the adoption of hybrid technologies and sequential biorefinery strategies to achieve high-purity isolates with minimal environmental impact. Full article

Phenolic compounds contribute to the color, flavor, and functionality of foods but are often degraded during conventional heat treatments, prompting interest in non-thermal techniques. Thermal methods produce heat-driven changes that are more directly interpretable, whereas non-thermal methods require compound-resolved interpretation because higher post-treatment signals may reflect release from bound pools rather than true preservation. This review evaluates liquid chromatography–mass spectrometry (LC–MS) evidence on how ultrasound, high-pressure processing, pulsed electric fields, and cold plasma reshape polyphenol fingerprints across food matrices (2021–early 2026). Ultrasound and high-pressure processing preserve constitutive structures while increasing measurable phenolics through cell disruption and bound-pool release. Pulsed electric fields show similar release behavior but may shift toward oxidative losses when electroporation increases enzyme contact or downstream operations amplify degradation. Cold plasma introduces reactive oxygen and nitrogen species, with the clearest LC–MS/MS evidence for oxidation and nitration. In fresh-cut tissues, stress responses elevate phenylpropanoid products. Bulk assays such as total phenolic content (TPC) cannot separate preservation from release or true chemical conversion alone. LC–MS offers the compound-level detail needed to understand how each non-thermal technique changes polyphenol structure and functionality across food matrices. Full article

Pulse repetition frequency (PRF) controls pulse off-time and, therefore, the extent of thermal accumulation, melt expulsion, and dielectric recovery in finishing electrical discharge machining (EDM). This study clarifies how PRF modifies crater evolution and surface integrity in finishing EDM of 4Cr13 martensitic stainless steel, a corrosion-resistant mold steel used in precision dies and molds. A 2D axisymmetric electro-thermo-fluid model was established in COMSOL, where Gaussian current density, heat-flux, and plasma pressure were periodically imposed at PRFs of 25–100 kHz, while pulse-on time (6 μs) and peak current (8 A) were kept constant. The simulations tracked the transient pressure, heat-flux, velocity, and temperature fields over a common elapsed time of 25 μs. Finishing experiments were then carried out on flat 4Cr13 coupons at 50, 75, and 100 kHz using a copper electrode and deionized water, followed by characterization by laser confocal microscopy, SEM/EDS, and X-ray diffraction using the cosα method. Increasing PRF localized the coupled pressure-heat-flow fields near the crater rim, but shortened off-time and intensified inter-pulse heat accumulation. Accordingly, the surface roughness decreased from Ra = 1.18 μm at 50 kHz to 0.63 μm at 75 kHz, and then slightly increased to 0.71 μm at 100 kHz because of crater overlap, re-melting, and incomplete gap recovery. SEM observations confirmed large irregular craters with cracks at 50 kHz, more uniform fine craters at 75 kHz, and overlapping re-solidified traces at 100 kHz. The residual stress remained compressive for all tested conditions (−341 to −409 MPa). Overall, 75 kHz offers the best compromise between crater uniformity, roughness, and compressive stress for finishing EDM of 4Cr13 steel. Full article

The single-heat-exchanger dual-channel water circulation structure is a critical process configuration in laboratory-scale bioreactors. However, frequent switching between heating and cooling modes and the difficulty of establishing an accurate mechanistic model make precise temperature regulation challenging. To address this issue, a model-free adaptive temperature control scheme based on a second-order universal model is proposed, together with a real-time implementation algorithm. Separate controllers are designed for the heating and cooling processes to ensure accurate regulation under different operating conditions. Pulse-width modulation is employed to achieve equivalent continuous actuation of switching-type actuators, and a temperature dead-zone mechanism is introduced to suppress excessive actuator switching. For practical implementation, controller parameters are initialized offline using particle swarm optimization based on experimental data. Experimental results demonstrate that the proposed method satisfies the ±0.1 °C process requirement while achieving small steady-state fluctuations, low overshoot, and short settling time, thereby verifying its effectiveness for bioreactor temperature regulation under mode-switching conditions. Full article

Issues related to the environmental safety of transport vehicles, the operation of which leads to environmental pollution, continue to be highly relevant. In this work, we consider the use of biofuel mixed with diesel fuel for internal combustion engines operating at low temperatures. This approach does not reduce the efficiency of transport, while also solving the issue of organic waste recycling. In this work, we address the possibility of reducing environmental pollution using carbon-neutral blended fuels based on esters of waste cooking oil (WCO), biobutanol, and diesel fuel for transport, tractor, and other equipment powered by a diesel internal combustion engine. In terms of the rate of biofuel implementation, Russia is still lagging behind the EU, China, and Japan, largely due to, inter alia, its climatic conditions with cold and long winters. The article also provides data on the possibility of using mixed biofuels under sub-zero temperatures. The process of forming a volumetric fuel supply through the common rail injector of the D4CB engine under changes in fuel pressure and drive pulse duration was also investigated, with the corresponding regression dependencies being presented. The losses of heat supplied into the cylinder when using a blend of diesel fuel and biodiesel (with 20 wt% butanol) in comparison with diesel fuel were analytically calculated. This made it possible to identify a function for adjusting fuel supply to compensate for power losses. The lubricity of fuel blends was assessed using the HFRR method. Full article

Improving the quality of welded joints, as well as the advancement of equipment and materials, inevitably requires deep theoretical knowledge of the physical phenomena occurring in the arc column and in the cathode and anode regions. Achievements in the field of controlling metal transfer at the micro- and nanoscale through the regulation of current and voltage in welding power sources have encountered the problem of the formation of cathode and anode spots, which affect the stability of welding arcs and the quality of the weld. Under short current pulses and pauses, the stability of the arc discharge depends on the ability to form a cathode spot, melt the wire metal, and transfer it through the arc column. In this article, based on the generalization of known experimental facts and studies performed using a high-speed camera, it is shown that the current-carrying channel of the electric arc has a discrete structure consisting of a multitude of thin channels through which the main discharge current flows. The cathode spot of the arc discharge represents a highly heated and brightly luminous region on the cathode surface. Electron emission sustaining the discharge and the removal of cathode material occur from this region. A new method is proposed for investigating the reverse side of the cathode spot, which makes it possible to identify a structure consisting of individual cells or fragments of the cathode spot. For the first time, anode spots recorded with a high-speed camera are presented. An analysis of the spot structure is carried out. The parameters influencing the mobility of cathode and anode spots are determined. Based on the obtained experimental facts, a hypothesis is proposed regarding the non-uniform structure of cathode and anode spots in the arc discharge. Full article

Ice accretion along aircraft leading edges, particularly at stagnation line parting strips, remains difficult to remove using conventional electrothermal anti-icing systems. These systems require continuous high-power heating to maintain the stagnation region above the melting point, often exceeding 10–12 kW/m². This study introduces an Ice Cavitation Deicer (ICD) that removes ice through rapid, localized cavitation generated within a thin melt layer formed at the ice–surface interface. In the proposed approach, a short pulse of electric current melts a 1–10 µm interfacial layer and causes a cavitation impulse of approximately 1–10 MPa. This impulse ejects the stagnation-line ice in a direction normal to the surface, often against the external airflow, enabling the immediate aerodynamic removal of the remaining ice. Analytical modeling based on the energy conservation principle was used to determine the optimal foil geometry, thermal pulse parameters, thermal stress, and material selection. Experiments with various metallic foils and substrate materials validated the predicted ejection behavior. The impulses were sufficient to fracture and eject ice 1–10 mm thick. The observed ice fragment velocities varied from 1 m/s to 10 m/s. Compared with conventional thermal anti-icing, the ICD concept reduces power consumption by approximately two orders of magnitude while offering rapid and reliable leading-edge deicing. The low power requirements, rapid response, and compatibility with thin-foil heater architectures make ICD a promising technology for both conventional and electrified aircrafts, UAVs, rotorcrafts, and other platforms where power availability is limited. This manuscript presents the first theoretical and experimental research on the ICD method and is a concept-proof work. Further research and development are required before the ICD is ready to be tested in flight. Full article