Search Results (169)

Accurate simulation modeling of the danger zone and real-time visualization of the toxic cloud spread during a fire and explosion at an industrial facility in a nearby urban area are in demand by rescue services conducting evacuation. Using a cellular automaton method allows us to create an optimal predictive model of the danger zone spread, combine modeling accuracy with computational speed, and consider multiple input variables and the cascading nature of an accident during visualization. The objective of this study was to develop a mobile application for calculating the parameters of the danger zone during an accident at an industrial facility caused by a toxic cloud spreading into an urban area, based on the selection of a cellular automaton algorithm. The primary objective of the study was a highly detailed visualization of the danger zone with several predicted values of toxic substance concentrations in the air. The authors developed a cellular automaton-based model, which forms the basis of the mobile application. It takes into account several variables characterizing chemicals in the explosion and fire zone, climate factors, occupancy, building parameters, and the availability of respiratory protection. The FireSoft Mobile app was developed using the Visual Studio 2022 development environment, C# 10.0, and .NET MAUI, adapted for Android 8.0 and higher. The mobile app was tested to visualize a cloud of toxic pollutants forming a hazardous zone in an urban agglomeration for cases involving an ammonia tank explosion and a large fire involving a large amount of polyvinyl chloride. The results demonstrate the app’s feasibility and effectiveness in predicting, planning, and managing evacuation measures during accidents at an industrial facility. Full article

Microplastics (MPs) adsorb hazardous substances and are ingested by a wide range of organisms; therefore, indicators for managing their environmental concentrations are needed. Ideally, threshold values should be based on health impacts. However, the diversity of MPs and the complexity of their environmental behavior make it difficult to establish unified environmental concentration standards. In this study, we propose a threshold for the presence of MPs on sandy beaches based on “visual cleanliness,” derived from the amount of MPs that people find psychologically unacceptable. Three types of MPs were used: white polypropylene (PP), blue PP, and white polystyrene (PS; expanded polystyrene). The survey was conducted in Japan, and the number of valid responses was 245. For defining a narrow-range cleanliness threshold, volume concentration was more appropriate than mass concentration. White particles were expected to be less noticeable because they tended to blend with white shell fragments, which are ubiquitous on beaches. In contrast, blue particles were expected to be less acceptable owing to their rarity. However, we found no difference in unacceptability between white PP and blue PP. The threshold, defined as the volume concentration at which half of the respondents find MPs psychologically unacceptable, ranged from 1 to 2 cm³-MPs/m²-sand. Gender, age, travel time to the beach, and frequency of beach visits did not influence unacceptability. Strong concern about marine plastic pollution and experience in cleaning public spaces were associated with a tendency toward low tolerance for MP contamination on beaches. Full article

Occupational safety is increasingly addressed through engineering-based, proactive risk management approaches that emphasize early identification and mitigation of hazards within industrial systems. In manufacturing environments, the analysis of minor process deviations, near misses, and low-impact operational failures provides critical insights for improving system reliability and safety performance. This paper proposes an integrated engineering framework that combines the 5M model (Environment, Man, Method, Material, Machine) with Source–Detection Matrix analysis to support structured identification, classification, and control of safety-related process deviations. The approach enables systematic root-cause analysis by categorizing contributing factors according to the 5M model, followed by mapping each deviation based on its origin and point of detection within production processes. The methodology was validated through case studies conducted in cosmetics and perfumery manufacturing, involving process-related hazards such as electrical failures and exposure to volatile substances. Validation was also supported by operational data collected over two 6-month periods before (n₁) and after implementation (n₂), based on incident reports, near-miss records, nonconformity reports, and internal audit data (n₁ = 128; n₂ = 95). Quantitative results show improved safety performance, including an increase in Detection at Source Rate from 42% to 74% and a reduction in Minor Incident Frequency from 11 to 5 cases/month. The results demonstrate that integrating causal analysis with detection mapping enhances early-stage identification of process deviations, effectively limiting failure propagation across operational stages and improving overall process safety performance. The proposed framework provides a practical and data-driven tool for improving process reliability, operational safety, and continuous improvement in complex manufacturing environments. Full article

Decoration waste, because of its complex composition and the presence of volatile toxic and hazardous substances, has always been a difficult point in the management of urban construction waste. And with the continuous expansion of the town scale, the volume of decoration waste is gradually expanding, which constitutes a major challenge to the sustainable development of the construction industry. In order to solve this difficult problem, this paper took Henan Province as an example, and realized the accurate control of decoration waste based on GF-2 remote sensing images and a BP neural network model. The results of GF-2 remote sensing image interpretation and analysis showed that the spatial distribution of construction waste in the study area was extracted through a combination of manual visual interpretation and machine learning recognition, and as of 2021, the construction waste pile occupied a large proportion of the land area, of which the proportion of decoration waste was about 10%. Based on the trained BP neural network, the goodness-of-fit result was R = 0.95463. Selecting the research data from 2010 to 2021, the error of the predicted annual generation of decoration waste in Henan Province compared with the actual value was less than 15%, which had a high prediction accuracy. Based on the arithmetic sum of the projected figures for each year from 2022 to 2030, it is estimated that by 2030, the cumulative volume of construction and renovation waste generated in Henan Province will reach 49,827,200 tons. Visualization of spatial and temporal distribution characteristics was realized through ArcGIS, and the high production area of decoration waste was distributed from the beginning to the end of the distribution of multi-points to show the characteristics of a concentrated large area distribution, centrally located in southwestern and southeastern Henan Province, with the key cities of Zhumadian City, Luoyang City, Zhoukou City, and Xinyang City, which had obvious regional characteristics. At the same time, as the provincial capital, Zhengzhou has long ranked first in the province in terms of absolute case numbers and is therefore also a key focus of control measures. Uncertainty analysis indicates that the 95% confidence interval for the long-term forecast values is approximately ±12%. It is recommended to use the upper limit of this interval for the redundancy design of the absorption facilities to enhance the robustness of the decision. This study provides a theoretical basis and technical support for the governmental supervision of decoration waste during the development of national urban agglomerations, effectively solves regional urban planning and construction management problems, and promotes the sustainable development of the construction industry. Full article

Wastewater is a complex and dynamic issue, particularly at the human–animal–environment interface, bearing biological and chemical hazards that may serve as a resource for transmission pathways for pathogens, antimicrobial resistance (AMR) determinants, heavy metals, pharmaceutical residues, per- and polyfluoroalkyl substances (PFAS), and microplastics. Rising global health issues necessitate effective wastewater treatment and advanced research to support risk-informed circular management within a one health framework, incorporating wastewater-based epidemiology (WBE), multi-omics approaches, nanobiotechnology, and green technologies. Inadequate wastewater treatment and uncontrolled discharge result in the generation of more than 380 billion cubic meters of wastewater annually worldwide, contributing to ecological degradation, the spread of AMR, and long-term toxicological risks. Despite significant advances in wastewater treatment, several challenges remain, including complex contaminant mixtures, limited detection and monitoring technologies, variable treatment efficiency, and weak regulatory and governance frameworks. This review highlights key wastewater treatment issues and presents recent advances in WBE and multi-omics approaches, such as metagenomics, resistome profiling, virome analysis, and chemical fingerprinting for contaminant monitoring and public health risk assessment. This review also examines circular reuse strategies focused on water reclamation, nutrient recovery, bioenergy production, and resource recovery, with particular emphasis on nature-based systems, hybrid biological–physicochemical treatment platforms, and green nanobiotechnology as promising approaches to improve treatment performance while minimizing environmental impacts. In conclusion, this review highlights the importance of integrated and sustainable wastewater management approaches within the One Health framework to address emerging challenges and promote environmental resilience, public health protection, and circular resource recovery. Full article

Volatile halogenated hydrocarbons (VHHs) are critical air toxic pollutants, with some ozone-depleting substances (ODSs) strictly regulated by the Montreal Protocol. However, current understanding of the pollution characteristics, sources, and health risks of atmospheric VHHs in Southwest China remains insufficient. This study performed field observations of atmospheric VHHs in summer in Mianyang, a medium-sized industrial city in the Sichuan Basin. Freon-12 (563 ± 20 ppt) and Freon-11 (264 ± 15 ppt) were the most abundant chlorofluorocarbons (CFCs); chloromethane (785 ± 261 ppt) and methylene chloride (563 ± 505 ppt) dominated among VSLSs. The mean concentration of regulated ODSs (1037 ± 33 pptv) was notably lower than unregulated very short-lived chlorinated substances (1887 ± 745 pptv), reflecting effective ODSs phase-out locally, yet enhancements relative to Northern Hemisphere background implied potential leakage from residual tanks. Methylene chloride and trichloroethylene concentrations exceeded global background levels by over 10 times, indicating strong anthropogenic industrial influences. Phased-out CFCs displayed negligible diurnal variation due to stringent emission controls, whereas unregulated VSLSs exhibited a distinct U-shaped diurnal cycle, with peaks driven by morning boundary layer dynamics and evening accumulation. Positive matrix factorization revealed that industrial sources, including electronic solvents (28.6%), industrial processes (27.8%), and solvent usage (23.7%), accounted for 80.1% of total VHHs. The total carcinogenic risk (2.3 × 10⁻⁵) surpassed the acceptable threshold (1 × 10⁻⁶), dominated by 1,2-dichloroethane, chloroform, carbon tetrachloride, and 1,2-dichloropropane. All individual compounds exhibited mean hazard quotients (HQs) below the non-carcinogenic risk threshold. The cumulative hazard index reached 1.5, suggesting combined non-carcinogenic risks to the local population. These results support VHHs health risk management and ODSs control in Southwest Chinese industrial cities. Full article

Background: Carcinogenic, Mutagenic, and Reprotoxic (CMR) substances are among the most significant occupational health hazards in healthcare and research laboratories. Despite preventive measures and regulations, exposure assessment and risk management remain complex due to varied working practices, mixed exposures, and the lack of harmonized monitoring protocols. This systematic review investigates occupational exposure to CMR substances in laboratory and healthcare environments. Methods: Searches were conducted in PubMed, Scopus, and Web of Science up to February 2025 using tailored keyword strategies. Studies published between 2020 and 2025 reporting exposure assessment, monitoring, and/or risk management of CMR chemicals were included; non-English papers and irrelevant studies were excluded. Titles/abstracts and full texts were screened independently by two reviewers with arbitration by a third. Risk of bias was assessed by three authors who independently evaluated each study. A narrative synthesis with frequency tables was performed; no meta-analysis was conducted. Results: Of 446 screened records, 50 studies were included. Formaldehyde (25 studies) and antineoplastic drugs (18 studies) were most frequently examined. Healthcare settings—e.g., hospital pharmacies, oncology wards, and pathology laboratories—were predominant, while research laboratories were underrepresented. Inhalation was the main exposure route for formaldehyde, whereas dermal uptake and surface contamination predominated for antineoplastic drugs. Monitoring methods included air sampling, surface wipe testing, and biological assays; preventive strategies varied and were inconsistently applied. Most included studies involved environmental monitoring and did not report participant numbers, so a total number of participants cannot be aggregated; for the main outcomes, participant counts were often not available. Limitations of the evidence include marked heterogeneity across settings, matrices, analytical methods, and reporting units, which precluded meta-analysis, as well as imprecision and incomplete reporting in several studies. Conclusions: Findings reveal persistent gaps in harmonized exposure limits, monitoring standards, and long-term health surveillance, underscoring the need for comprehensive prevention strategies. This review was not registered and did not receive any external funding. Full article

Electronic waste (e-waste) has emerged as one of the most critical environmental challenges of the twenty-first century. It encompasses a wide range of discarded electrical and electronic equipment, including information and communication technologies, household appliances, entertainment systems, and related components. While e-waste contains valuable recoverable materials, it also harbours hazardous substances such as toxic heavy metals, flame retardants, and persistent organic pollutants. Inadequate disposal practices, particularly open dumping and landfilling, result in the generation of toxic leachates that contaminate soil as well as surface and groundwater, posing severe threats to environmental integrity and public health. Evidence indicates that landfill leachates can infiltrate groundwater at considerable depths, exceeding permissible limits of heavy metals and metalloids and contributing to serious health disorders. Consequently, the implementation of effective e-waste management strategies and environmentally sound disposal practices is imperative to minimize its detrimental environmental and human health impacts. Microalgae systems can achieve up to 98% removal efficiency and up to five cycles reusability. In this paper, the drawbacks of the traditional methods for metal recovery from e-waste and the potential of microalgae were discussed. The downstream processing and metal extraction from microalgal biomass is critically discussed as well as strategies to support the circular economy. Full article

Marine ports located in regions of moderate seismicity can face high Natech (natural hazard-triggered technological) risk because large inventories of hazardous materials are stored near dense urban populations. This study proposes and applies a Natech risk framework to a representative port on the Saint-Laurence River in Quebec, Canada. Site-specific peak ground accelerations (PGA) are first estimated for 12 earthquake scenarios using regional ground motion prediction equations adjusted for local site conditions. These hazard levels are combined with a damage probability matrix to estimate Hazardous Release Likelihood Index (HRLi) scores for atmospheric steel storage tanks. Offsite consequences are then evaluated to obtain Maximum Distances of Effect (MDEs) for different types of hazardous materials. MDE footprints are intersected with block-level demographic data and complemented by a domino-effect based on inter-tank spacing, yielding a tank-level Natech Risk Index $NR{\mathrm{I}}_{\mathrm{i},\mathrm{s}}$ for each storage tank ($\mathrm{i}$) and seismic scenario ($\mathrm{s}$). These values are then averaged over all tanks to obtain a scenario-level mean Natech Risk Index ($\overline{NRI}$) for each tank substance. Regression equations relating $\overline{NRI}$ to PGA are provided as a practical tool for defining critical intensity thresholds for seismic Natech risk management in marine ports. Full article

Electronic waste (e-waste) is a growing solid waste stream with largely undisclosed and poorly characterized fluorinated constituents. We evaluated per- and polyfluoroalkyl substances (PFAS) leachability from four e-waste components (phone screens, phone plastics, capacitors, and Lithium-ion batteries) using a 30-day deionized water leaching test. PFAS were extracted by solid-phase extraction using weak anion exchange (WAX) cartridges and analyzed with a liquid chromatography triple-quadrupole mass spectrometer. In addition, the PFAS chemical profiles of e-waste components were characterized by non-targeted analysis. Leachable sums of detected PFAS (∑PFAS) were highest in phone screens (1739–1932 ng·kg⁻¹) and phone plastics (1575–2197 ng·kg⁻¹) and an order of magnitude lower in Lithium-ion batteries (148–158 ng·kg⁻¹) and capacitors (147–243 ng·kg⁻¹). Short-chain perfluoroalkyl acids (PFAAs) (e.g., PFBA, PFHxA) and legacy acids (e.g., PFOA, PFNA) were more prevalent in phone screens/plastics, whereas capacitors and batteries showed mixed sulfonate/carboxylate patterns (PFOS, PFHxS, and 6:2 FTS). Although capacitors and Lithium-ion batteries contained essential PFAS with high hazard potential at trace levels, phone screens and phone plastics pose a greater risk per mass due to higher ∑PFAS levels and larger volumes. Non-targeted analysis using Orbitrap Astral revealed CF₂/CF₂O homologous trends (confidence levels 2–3) with corroborating targeted findings. These findings highlight the need for PFAS-free alternatives, the disclosure of fluorinated additives, and stronger end-of-life management strategies to prevent PFAS releases from e-waste. Full article

Aquatic environments have been a critical source of nutrition for millennia, with wild fisheries supplying protein and nutrients to populations worldwide. A notable shift has occurred in recent decades with the expansion of aquaculture, now representing a fast-growing sector in food production. Aquaculture plays a key role in mitigating the depletion of wild fish stocks and addressing issues related to overfishing. Despite its potential benefits, the sustainability of both wild and farmed aquatic food systems is challenged by anthropogenic pollution. Contaminants from agricultural runoff, industrial discharges, and domestic effluents enter freshwater systems and eventually reach marine environments, where they may be transported globally through ocean currents. Maintaining water quality is paramount to food safety, environmental integrity, and long-term food security. In addition to conventional seafood products such as fish and shellfish, foods such as those derived from microalgae are gaining attention in Western markets for their high nutritional value and potential functional properties. These organisms have been consumed in Asia for generations and are now being explored as sustainable foods and ingredients as an alternative source of protein. Contaminants in aquatic food products include residues of agrochemicals, persistent organic pollutants (POPs) such as dioxins, polychlorinated biphenyls (PCBs), and per- and polyfluoroalkyl substances (PFASs), as well as brominated flame retardants and heavy metals. Public and scientific attention has intensified around plastic pollution, particularly microplastics and nanoplastics, which are increasingly detected in aquatic organisms and are the subject of ongoing toxicological and ecological risk assessments. While the presence of these hazards necessitates robust risk assessment and regulatory oversight, it is important to balance these concerns against the health benefits of aquatic foods, which are rich in omega-3 fatty acids, high-quality proteins, vitamins, and trace elements. Furthermore, beyond direct human health implications, the environmental impact of pollutant sources must be addressed through integrated management approaches to ensure the long-term sustainability of aquatic ecosystems and the food systems they support. This review covers regulatory frameworks, risk assessments, and management issues relating to aquatic environments, including the impact of climate change. It aims to serve as a comprehensive resource for researchers, policymakers, food businesses who harvest food from aquatic systems and other stakeholders. Full article

Several studies have investigated airborne chemical exposures in university teaching laboratories, where activities are typically structured and supervised. University research laboratories typically involve greater autonomy, the use of more hazardous substances, and less oversight. This industry-embedded study aimed to develop a comprehensive guideline for occupational hygiene and health monitoring (OHHM) tailored to a university context, including both teaching and research laboratories. Guidelines and policies from the Western Australian mining sector and six Australian universities were analysed to identify common elements for a draft OHHM guideline. This draft was reviewed by an industry advisory group (IAG) of five Australian university health and safety managers. Their feedback was analysed and discussed with the Chief Safety Officer at Edith Cowan University (ECU). Following the incorporation of this input and final revisions, the guideline was ratified and implemented across ECU in April 2025. The guide adopts a risk-based occupational hygiene (OH) approach, in which OH monitoring results determine the need for health monitoring (HM). Implementation is supported by central coordination and external OH consultancy. The study presents the resulting guide document, which establishes a replicable framework that may inform similar initiatives in universities internationally (especially those with laboratories). Full article

The end-of-life phase of a building, which includes demolition and waste disposal, represents a crucial aspect of sustainable construction. In Europe, construction and demolition (C&D) waste accounts for approximately 40% of the total waste generated in the EU, making its management a global challenge. The EU Construction & Demolition Waste Management Protocol (2024) emphasizes the importance of evaluating, before proceeding with the demolition of a building, whether renovation could be a more efficient solution, considering economic, environmental, and technical aspects. From an economic perspective, demolition costs vary depending on several factors, including project size, structural complexity, techniques employed (conventional or non-conventional), materials to be removed, and local regulations. In addition to the direct costs of the intervention, it is essential to consider indirect impacts, such as the management of construction and demolition (C&D) waste, the removal of hazardous substances, and potential environmental damage to be mitigated. This study analyzes a case located in Italy, in the municipality of Caivano (Metropolitan City of Naples, in Campania region), concerning a building that required energy efficiency improvements and seismic upgrades. The decision to demolish and rebuild proved to be economically more advantageous than renovation, while also allowing a 35% increase in volume, enabling the creation of a greater number of housing units. Through the analysis of this real case study, the aim is to highlight how investments in demolition, if properly planned, designed, assessed, and managed, can effectively contribute to building redevelopment, supporting the transition towards a sustainable construction model in line with the principles of the circular economy. Full article

The comprehensive utilization of hazardous waste may introduce heavy metals, organic pollutants, etc., into products, resulting in secondary pollution. The environmental risk assessment method for hazardous waste resource utilization products is an important technical means of environmental management. We have established a standardized method for hazard identification, exposure evaluation and risk characterization. This study selects waste sulfuric acid generated in the integrated circuit industry as the object and investigates the use of waste sulfuric acid to react with aluminum hydroxide to produce liquid aluminum sulfate flocculant, as well as the environmental risks brought to practitioners and the potential relevant population in the sewage treatment process. By analyzing sulfuric acid and aluminum hydroxide, toxic substances such as nitrate ions, fluorides, As, Pb, Cr, Hg, Cd, etc., were identified. Through exposure scenario analysis, the exposure levels of occupational and non-occupational populations were determined. Based on the dose–response relationship data in the IRIS database of the United States and the carcinogenic and non-carcinogenic data of skin contact routes, it was suggested that chromium and its compounds were the main contributors to carcinogenic risk, and cadmium, its compounds, and mercuric chloride were the contributors to the non-carcinogenic risk. The total carcinogenic risk to human health in occupational populations was 5.31 × 10⁻⁵, and the total non-carcinogenic risk was 8.80 × 10⁻¹. The total carcinogenic risk to human health in non-occupational populations was 1.73 × 10⁻¹⁵, and the total non-carcinogenic risk was 1.23 × 10⁻¹¹. Based on this research, it is clear that the production of liquid aluminum sulfate flocculants from waste sulfuric acid generated in the integrated circuit industry has a low impact on occupational and other populations during use, and the environmental risks generated by this product are acceptable even under the most dangerous conditions. Full article

The widespread use of agrochemicals, including inorganic and organic pesticides and fungicides, has contributed to the persistence of hazardous residues in agricultural environments, particularly through their accumulation in plastic packaging and containers. High-density polyethylene (HDPE), polypropylene (PP), and other polymer types commonly employed for agrochemical storage and transport retain significant quantities of active substances even after standard rinsing procedures. This phenomenon raises concerns over improper disposal practices, environmental contamination, and potential ecotoxicological impacts. Recent studies demonstrate that both inorganic and organic pesticide residues exhibit strong interactions with plastic polymers, influenced by factors such as polymer chemistry, surface aging, pH, ionic strength, and dissolved organic matter. These interactions not only delay degradation but also facilitate secondary release into soils and aquatic systems, where they may impair soil microorganisms, alter plant physiology, and disrupt aquatic food webs, including phytoplankton, fish, and microbial assemblages. Despite regulatory frameworks and container management schemes in some regions, major knowledge gaps remain regarding the long-term fate of pesticide residues on plastics, their transfer to ecosystems, and cumulative effects on agroecosystem sustainability. This review synthesizes current evidence on the chemical characteristics of pesticide residues in plastic packaging, their environmental mobility, and ecotoxicological effects. It further identifies urgent research needs, including long-term field assessments of polymer–pesticide interactions, improved recycling technologies, and the development of safer container designs. Effective management strategies, coupled with strengthened international stewardship programs, are essential to reduce risks to environmental health, agricultural productivity, and human safety. Full article