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24 pages, 6195 KB  
Article
Current Loop Decoupling and Disturbance Rejection for PMSM Based on a Resonant Control Periodic Disturbance Observer
by Jiawei Jin, Liang Guo and Wenqi Lu
Appl. Sci. 2025, 15(17), 9469; https://doi.org/10.3390/app15179469 - 28 Aug 2025
Abstract
In the vector control of permanent magnet synchronous motor (PMSM), non-periodic disturbances such as cross-coupling between axes and variations in electrical parameters, along with periodic harmonic disturbances caused by inverter nonlinearities and magnetic field harmonics, influence the dq-axis currents. To address these challenges, [...] Read more.
In the vector control of permanent magnet synchronous motor (PMSM), non-periodic disturbances such as cross-coupling between axes and variations in electrical parameters, along with periodic harmonic disturbances caused by inverter nonlinearities and magnetic field harmonics, influence the dq-axis currents. To address these challenges, this paper proposes a current loop disturbance rejection strategy based on a Resonant Control Periodic Disturbance Observer (RC-PDOB). First, this paper constructs a disturbance observer-based current loop decoupling model that mitigates dq-axis current coupling due to parameter variations and reduces the impact of non-periodic disturbances. Then this paper introduces proportional–resonant terms into the disturbance observer to suppress the 6th and 12th harmonics of the dq-axis, thereby reducing periodic current disturbances. This paper analyzes the disturbance rejection mechanism of RC-PDOB in detail and presents the design methodology and stability criteria of the proposed observer. Finally, experimental results demonstrate the effectiveness of the proposed approach. Full article
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31 pages, 9665 KB  
Article
Motor Airgap Torque Harmonics Due to Cascaded H-Bridge Inverter Operating with Failed Cells
by Hamid Hamza, Ideal Oscar Libouga, Pascal M. Lingom, Joseph Song-Manguelle and Mamadou Lamine Doumbia
Energies 2025, 18(16), 4286; https://doi.org/10.3390/en18164286 - 12 Aug 2025
Viewed by 303
Abstract
This paper proposes the expressions for the motor airgap torque harmonics induced by a cascaded H-bridge inverter operating with failed cells. These variable frequency drive systems (VFDs), are widely used in oil and gas applications, where a torsional vibration evaluation is a critical [...] Read more.
This paper proposes the expressions for the motor airgap torque harmonics induced by a cascaded H-bridge inverter operating with failed cells. These variable frequency drive systems (VFDs), are widely used in oil and gas applications, where a torsional vibration evaluation is a critical challenge for field engineers. This paper proposes mathematical expressions that are crucial for an accurate torsional analysis during the design stage of VFDs, as required by international standards such as API 617, API 672, etc. By accurately reconstructing the electromagnetic torque from the stator voltages and currents in the (αβ0) reference frame, the obtained expressions enable the precise prediction of the exact locations of torque harmonics induced by the inverter under various real-world operating conditions, without the need for installed torque sensors. The neutral-shifted and peak-reduction fault-tolerant control techniques are commonly adopted under faulty operation of these VFDs. However, their effects on the pulsating torques harmonics in machine air-gap remain uncovered. This paper fulfils this gap by conducting a detailed evaluation of spectral characteristics of these fault-tolerant methods. The theoretical analyses are supported by MATLAB/Simulink 2024 based offline simulation and Typhoon based virtual real-time simulation results performed on a (4.16 kV and 7 MW) vector-controlled induction motor fed by a 7-level cascaded H-bridge inverter. According to the theoretical analyses- and simulation results, the Neutral-shifted and Peak-reduction approaches rebalance the motor input line-to-line voltages in the event of an inverter’s failed cells but, in contrast to the normal mode the carrier, all the triplen harmonics are no longer suppressed in the differential voltage and current spectra due to inequal magnitudes in the phase voltages. These additional current harmonics induce extra airgap torque components that can excite the lowly damped eigenmodes of the mechanical shaft found in the oil and gas applications and shut down the power conversion system due torsional vibrations. Full article
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14 pages, 710 KB  
Article
Exploring Harmonic Evolute Geometries Derived from Tubular Surfaces in Minkowski 3-Space Using the RM Darboux Frame
by Emad Solouma, Sayed Saber and Haci Mehmet Baskonus
Mathematics 2025, 13(15), 2329; https://doi.org/10.3390/math13152329 - 22 Jul 2025
Viewed by 231
Abstract
In this study, We explore for Minkowski 3-space E13 harmonic surfaces’ geometric features by employing a common tangent vector field along a curve situated on the surface. Our analysis is grounded in the rotation minimizing (RM) Darboux frame, which offers a [...] Read more.
In this study, We explore for Minkowski 3-space E13 harmonic surfaces’ geometric features by employing a common tangent vector field along a curve situated on the surface. Our analysis is grounded in the rotation minimizing (RM) Darboux frame, which offers a robust alternative to the classical Frenet frame particularly valuable in the Lorentzian setting, where singularities frequently arise. The RM Darboux frame, tailored to curves lying on surfaces, enables the expression of fundamental invariants such as geodesic curvature, normal curvature, and geodesic torsion. We derive specific conditions that characterize harmonic surfaces based on these invariants. We also clarify the connection between the components of the RM Darboux frame and thesurface’s mean curvature vector. This formulation provides fresh perspectives on the classification and intrinsic structure of harmonic surfaces within Minkowski geometry. To support our findings, we present several illustrative examples that demonstrate the applicability and strength of the RM Darboux approach in Lorentzian differential geometry. Full article
(This article belongs to the Special Issue Differential Geometric Structures and Their Applications)
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24 pages, 4652 KB  
Article
A Machine Learning-Based Assessment of Proxies and Drivers of Harmful Algal Blooms in the Western Lake Erie Basin Using Satellite Remote Sensing
by Neha Joshi, Armeen Ghoorkhanian, Jongmin Park, Kaiguang Zhao and Sami Khanal
Remote Sens. 2025, 17(13), 2164; https://doi.org/10.3390/rs17132164 - 24 Jun 2025
Viewed by 567
Abstract
The western region of Lake Erie has been experiencing severe water-quality issues, mainly through the infestation of algal blooms, highlighting the urgent need for action. Understanding the drivers and the intricacies associated with algal bloom phenomena is important to develop effective water-quality remediation [...] Read more.
The western region of Lake Erie has been experiencing severe water-quality issues, mainly through the infestation of algal blooms, highlighting the urgent need for action. Understanding the drivers and the intricacies associated with algal bloom phenomena is important to develop effective water-quality remediation strategies. In this study, the influences of multiple bloom drivers were explored, together with Harmonized Landsat Sentinel-2 (HLS) images, using the datasets collected in Western Lake Erie from 2013 to 2022. Bloom drivers included a group of physicochemical and meteorological variables, and Chlorophyll-a (Chl-a) served as a proxy for algal blooms. Various combinations of these datasets were used as predictor variables for three machine learning models, including Support Vector Regression (SVR), Extreme Gradient Boosting (XGB), and Random Forest (RF). Each model is complemented with the SHapley Additive exPlanations (SHAP) model to understand the role of predictor variables in Chl-a estimation. A combination of physicochemical variables and optical spectral bands yielded the highest model performance (R2 up to 0.76, RMSE as low as 8.04 µg/L). The models using only meteorological data and spectral bands performed poorly (R2 < 0.40), indicating the limited standalone predictive power of meteorological variables. While satellite-only models achieved moderate performance (R2 up to 0.48), they could still be useful for preliminary monitoring where field data are unavailable. Furthermore, all 20 variables did not substantially improve model performance over models with only spectral and physicochemical inputs. While SVR achieved the highest R2 in individual runs, XGB provided the most stable and consistently strong performance across input configurations, which could be an important consideration for operational use. These findings are highly relevant for harmful algal bloom (HAB) monitoring, where Chl-a serves as a critical proxy. By clarifying the contribution of diverse variables to Chl-a prediction and identifying robust modeling approaches, this study provides actionable insights to support data-driven management decisions aimed at mitigating HAB impacts in freshwater systems. Full article
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20 pages, 3494 KB  
Article
Space Vector Modulation Methods with Modified Zero Vector Distribution for Electrical Vehicle Drives with Six-Phase Induction Motor Operating Under Direct Field-Oriented Control
by Grzegorz Tarchała and Jacek Listwan
Energies 2025, 18(12), 3122; https://doi.org/10.3390/en18123122 - 13 Jun 2025
Viewed by 383
Abstract
This paper presents a Space Vector Modulation (SVM) method with a novel zero vector distribution system for electrical vehicle drives with a six-phase induction motor working under the Direct Field-Oriented Control (DFOC) method. Different SVM methods are described and compared, and a new [...] Read more.
This paper presents a Space Vector Modulation (SVM) method with a novel zero vector distribution system for electrical vehicle drives with a six-phase induction motor working under the Direct Field-Oriented Control (DFOC) method. Different SVM methods are described and compared, and a new approach with long vectors only and a special zero vector distribution, that compensates for the third harmonic component is proposed. The DFOC method is described and the influence of the applied modulation method on six-phase motor currents is shown. Results of our experimental studies on the DFOC method are presented and discussed. The proposed modulation method for a six-phase Voltage Source Inverter can be applied in fault-tolerant electrical vehicles. Full article
(This article belongs to the Special Issue Drive System and Control Strategy of Electric Vehicle)
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10 pages, 7380 KB  
Communication
Far-Field Topological Structure of the Second Harmonic from Higher-Order Poincaré Sphere Beam
by Yangyang Li, Ziping Zhu, Yuanxiang Wang, Jiantai Dou, Li Fan, Bo Li and Youyou Hu
Photonics 2025, 12(5), 407; https://doi.org/10.3390/photonics12050407 - 24 Apr 2025
Viewed by 436
Abstract
In this paper, the far-field topological structures (FFTSs) of the second harmonic (SH) from higher-order Poincaré sphere (HOPS) beams, including circularly polarized vortex beams (VBs), cylindrically vector beams (CVBs) and elliptically polarized CVBs (EPCVBs), were demonstrated and reported. To begin with, the hidden [...] Read more.
In this paper, the far-field topological structures (FFTSs) of the second harmonic (SH) from higher-order Poincaré sphere (HOPS) beams, including circularly polarized vortex beams (VBs), cylindrically vector beams (CVBs) and elliptically polarized CVBs (EPCVBs), were demonstrated and reported. To begin with, the hidden FFTSs of the SH after propagating the twice Rayleigh range were simulated based on the vectorial coupled wave equations and the Collins formula. Then, the experimental setup was established to achieve the SH from the HOPS by applying two orthogonal 5% MgO: PPLN crystals, the FFTSs of which were demonstrated. The theoretical and experimental results indicate that for the circularly polarized VBs, the FFTSs of the SH still exhibit the 135°-linearly polarized VBs, which is similar to that of the SH in-source plane, because the SH is the eigen-mode of free space, while for the CVBs, the FFTSs of the SH generally show the disappearance of the central dark core, replaced by the maximum light intensity at the center due to the topological phase transition during propagation. Especially of note, for the EPCVBs, the FFTSs of the SH display the maximum light intensity at the center, but the FFTSs in the horizontal and vertical directions reveal rotational symmetry related to the chirality of the EPCVBs. The results reveal the evolution mechanisms of the SH from the HOPS in the far field, which may facilitate the applications of the SH from HOPS beam. Full article
(This article belongs to the Special Issue Fundamentals and Applications of Vortex Beams)
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8 pages, 239 KB  
Article
Characterization of Ricci Solitons and Harmonic Vector Fields on the Lie Group Nil4
by Yanlin Li, Ahmed Mohammed Cherif and Yuquan Xie
Mathematics 2025, 13(7), 1155; https://doi.org/10.3390/math13071155 - 31 Mar 2025
Cited by 3 | Viewed by 324
Abstract
This study considers a left-invariant Riemannian metric g on the Lie group Nil4. We introduce a Ricci solitons’ classification on (Nil4,g). These are expansive non-gradient Ricci solitons. We examine the existence [...] Read more.
This study considers a left-invariant Riemannian metric g on the Lie group Nil4. We introduce a Ricci solitons’ classification on (Nil4,g). These are expansive non-gradient Ricci solitons. We examine the existence of harmonic maps into (Nil4,g) from a compact Riemannian manifold. Additionally, we provide a characterization of a class of harmonic vector fields on (Nil4,g). Full article
(This article belongs to the Special Issue Geometric Topology and Differential Geometry with Applications)
25 pages, 1655 KB  
Article
Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of Any Form
by Dimosthenis Stamopoulos
Crystals 2025, 15(4), 331; https://doi.org/10.3390/cryst15040331 - 30 Mar 2025
Cited by 1 | Viewed by 576
Abstract
Spherical structures of dielectric and magnetic materials are studied intensively in basic research and employed widely in applications. The polarization, (P for dielectric and M for magnetic materials), is the parent physical vector of all relevant entities (e.g., moment, , and force, [...] Read more.
Spherical structures of dielectric and magnetic materials are studied intensively in basic research and employed widely in applications. The polarization, (P for dielectric and M for magnetic materials), is the parent physical vector of all relevant entities (e.g., moment, , and force, F), which determine the signals recorded by an experimental setup or diagnostic equipment and configure the motion in real space. Here, we use classical electromagnetism to study the polarization, , of spherical structures of linear and isotropic—however, not necessarily homogeneous—materials subjected to an external vector field, (Eext for dielectric and Hext for magnetic materials), dc (static), or even ac of low frequency (quasistatic limit). We tackle an integro-differential equation on the polarization, , able to provide closed-form solutions, determined solely from , on the basis of spherical harmonics, Ylm. These generic equations can be used to calculate analytically the polarization, , directly from an external field, , of any form. The proof of concept is studied in homogeneous dielectric and magnetic spheres. Indeed, the polarization, , can be obtained by universal expressions, directly applicable for any form of the external field, . Notably, we obtain the relation between the extrinsic, , and intrinsic, , susceptibilities (χeext and χeint for dielectric and χmext and χmint for magnetic materials) and clarify the nature of the depolarization factor, , which depends on the degree l—however, not on the order m of the mode (l,m) of the applied . Our universal approach can be useful to understand the physics and to facilitate applications of such spherical structures. Full article
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25 pages, 8016 KB  
Article
High-Fold 3D Gaussian Splatting Model Pruning Method Assisted by Opacity
by Shiyu Qiu, Chunlei Wu, Zhenghao Wan and Siyuan Tong
Appl. Sci. 2025, 15(3), 1535; https://doi.org/10.3390/app15031535 - 3 Feb 2025
Cited by 1 | Viewed by 2735
Abstract
Recent advancements in 3D scene representation have underscored the potential of Neural Radiance Fields (NeRFs) for producing high-fidelity renderings of complex scenes. However, NeRFs are hindered by the significant computational burden of volumetric rendering. To address this, 3D Gaussian Splatting (3DGS) has emerged [...] Read more.
Recent advancements in 3D scene representation have underscored the potential of Neural Radiance Fields (NeRFs) for producing high-fidelity renderings of complex scenes. However, NeRFs are hindered by the significant computational burden of volumetric rendering. To address this, 3D Gaussian Splatting (3DGS) has emerged as an efficient alternative, utilizing Gaussian-based representations and rasterization techniques to achieve faster rendering speeds without sacrificing image quality. Despite these advantages, the large number of Gaussian points and associated internal parameters result in high storage demands. To address this challenge, we propose a pruning strategy applied during the Gaussian densification and pruning phases. Our approach integrates learnable Gaussian masks with a contribution-based pruning mechanism, further enhanced by an opacity update strategy to facilitate the pruning process. This method effectively eliminates redundant Gaussian points and those with minimal contributions to scene construction. Additionally, during the Gaussian parameter compression phase, we employ a combination of teacher–student models and vector quantization to compress the spherical harmonic coefficients. Extensive experimental results demonstrate that our approach reduces the storage requirements of original 3D Gaussian models by over 30 times, with only a minor degradation in rendering quality. Full article
(This article belongs to the Special Issue Technical Advances in 3D Reconstruction)
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23 pages, 29165 KB  
Article
Parallax-Tolerant Weakly-Supervised Pixel-Wise Deep Color Correction for Image Stitching of Pinhole Camera Arrays
by Yanzheng Zhang, Kun Gao, Zhijia Yang, Chenrui Li, Mingfeng Cai, Yuexin Tian, Haobo Cheng and Zhenyu Zhu
Sensors 2025, 25(3), 732; https://doi.org/10.3390/s25030732 - 25 Jan 2025
Viewed by 751
Abstract
Camera arrays typically use image-stitching algorithms to generate wide field-of-view panoramas, but parallax and color differences caused by varying viewing angles often result in noticeable artifacts in the stitching result. However, existing solutions can only address specific color difference issues and are ineffective [...] Read more.
Camera arrays typically use image-stitching algorithms to generate wide field-of-view panoramas, but parallax and color differences caused by varying viewing angles often result in noticeable artifacts in the stitching result. However, existing solutions can only address specific color difference issues and are ineffective for pinhole images with parallax. To overcome these limitations, we propose a parallax-tolerant weakly supervised pixel-wise deep color correction framework for the image stitching of pinhole camera arrays. The total framework consists of two stages. In the first stage, based on the differences between high-dimensional feature vectors extracted by a convolutional module, a parallax-tolerant color correction network with dynamic loss weights is utilized to adaptively compensate for color differences in overlapping regions. In the second stage, we introduce a gradient-based Markov Random Field inference strategy for correction coefficients of non-overlapping regions to harmonize non-overlapping regions with overlapping regions. Additionally, we innovatively propose an evaluation metric called Color Differences Across the Seam to quantitatively measure the naturalness of transitions across the composition seam. Comparative experiments conducted on popular datasets and authentic images demonstrate that our approach outperforms existing solutions in both qualitative and quantitative evaluations, effectively eliminating visible artifacts and producing natural-looking composite images. Full article
(This article belongs to the Section Sensing and Imaging)
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17 pages, 7389 KB  
Article
Quadruple-Q Skyrmion Crystal in Centrosymmetric Body-Centered Tetragonal Magnets
by Satoru Hayami
Magnetism 2025, 5(1), 2; https://doi.org/10.3390/magnetism5010002 - 17 Jan 2025
Viewed by 2156
Abstract
We conduct a numerical investigation into the stability of a quadruple-Q skyrmion crystal, a structure generated by the superposition of four spin density waves traveling in distinct directions within three-dimensional space, hosted on a centrosymmetric body-centered tetragonal lattice. Using simulated annealing applied [...] Read more.
We conduct a numerical investigation into the stability of a quadruple-Q skyrmion crystal, a structure generated by the superposition of four spin density waves traveling in distinct directions within three-dimensional space, hosted on a centrosymmetric body-centered tetragonal lattice. Using simulated annealing applied to an effective spin model that includes momentum-resolved bilinear and biquadratic interactions, we construct a magnetic phase diagram spanning a broad range of model parameters. Our study finds that a quadruple-Q skyrmion crystal does not emerge within the phase diagram when varying the biquadratic interaction and external magnetic field. Instead, three distinct quadruple-Q states with topologically trivial spin textures are stabilized. However, we demonstrate that the quadruple-Q skyrmion crystal can become the ground state when an additional high-harmonic wave–vector interaction is considered. Depending on the magnitude of this interaction, we obtain two types of quadruple-Q skyrmion crystals exhibiting the skyrmion numbers of one and two. These findings highlight the emergence of diverse three-dimensional multiple-Q spin states in centrosymmetric body-centered tetragonal magnets. Full article
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26 pages, 1564 KB  
Article
Independent Component Analysis-Based Harmonic Transfer Impedance Estimation for Networks with Multiple Harmonic Sources
by Mateus M. de Oliveira, Leandro R. M. Silva, Igor D. Melo, Carlos A. Duque and Paulo F. Ribeiro
Energies 2025, 18(1), 85; https://doi.org/10.3390/en18010085 - 28 Dec 2024
Cited by 1 | Viewed by 981
Abstract
This paper presents a novel methodology to estimate the harmonic transfer impedances in electric power systems with multiple harmonic sources (HSs). The purpose is to determine the responsibility of each HS for the total harmonic distortion at a specific bus within the system, [...] Read more.
This paper presents a novel methodology to estimate the harmonic transfer impedances in electric power systems with multiple harmonic sources (HSs). The purpose is to determine the responsibility of each HS for the total harmonic distortion at a specific bus within the system, addressing a critical issue in the power quality field. To achieve this objective, it is necessary to estimate not only the individual HS, but also the transfer impedances between each source and the bus under analysis (BUA). Most methods for solving this problem are based on proper network modeling or restrict variations in harmonic sources to a single source at a time. The proposed methodology has overcome this limitation. For this, synchronized current and voltage phasors are measured at the BUA. Once the measurements are gathered, the Independent Component Analysis (ICA) method is applied to estimate the Norton equivalent. The harmonic transfer impedance (HTI) is then determined using the information provided by the ICA. To enhance the accuracy of HTI estimation, three procedures are employed for data mining the parameters provided by ICA over time to generate a well-conditioned system. Once the HTI is satisfactorily determined, the individual harmonic contributions (IHCs), i.e., the harmonic responsibility, can be estimated accurately. The effectiveness and performance of the method are demonstrated based on computational simulations using distribution and transmission systems. Additionally, the methodology is validated with real data collected from a Brazilian transmission system monitored by synchronized power quality measurement units. Simulated results show that the Total Vector Error (TVE) is less than 0.4%, and for the field data test, the TVE is less than 2%. Full article
(This article belongs to the Special Issue Advances in Urban Power Distribution System—2nd Edition)
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13 pages, 264 KB  
Article
Applications of Disaffinity Vectors to Certain Riemannian Manifolds
by Hanan Alohali, Sharief Deshmukh and Bang-Yen Chen
Mathematics 2024, 12(24), 3951; https://doi.org/10.3390/math12243951 - 16 Dec 2024
Viewed by 688
Abstract
A disaffinity vector on a Riemannian manifold is a vector field whose affinity tensor vanishes. In this paper, we prove that every disaffinity vector on a compact Riemannian manifold is an incompressible vector field. Then, we discover a sufficient condition for an incompressible [...] Read more.
A disaffinity vector on a Riemannian manifold is a vector field whose affinity tensor vanishes. In this paper, we prove that every disaffinity vector on a compact Riemannian manifold is an incompressible vector field. Then, we discover a sufficient condition for an incompressible vector field to be disaffinity. Next, we study trans-Sasakian 3-manifolds whose Reeb vector field is disaffinity and obtain two sufficient conditions for a trans-Sasakian 3-manifold to be homothetic to a Sasakian 3-manifold. Finally, we prove that a complete Riemannian manifold admitting a non-harmonic disaffinity function satisfying the Eikonal equation and a Ricci curvature inequality is isometric to a Euclidean space. Full article
(This article belongs to the Special Issue Recent Studies in Differential Geometry and Its Applications)
14 pages, 1485 KB  
Article
Short-Period Skyrmion Crystals in Itinerant Body-Centered Tetragonal Magnets
by Satoru Hayami
Magnetochemistry 2024, 10(10), 78; https://doi.org/10.3390/magnetochemistry10100078 - 16 Oct 2024
Viewed by 1353
Abstract
In this study, we investigate the stability of a magnetic skyrmion crystal with short-period magnetic modulations in a centrosymmetric body-centered tetragonal system. By performing the simulated annealing for the spin model, incorporating the effects of the biquadratic interaction and high-harmonic wave–vector interaction in [...] Read more.
In this study, we investigate the stability of a magnetic skyrmion crystal with short-period magnetic modulations in a centrosymmetric body-centered tetragonal system. By performing the simulated annealing for the spin model, incorporating the effects of the biquadratic interaction and high-harmonic wave–vector interaction in momentum space, we find that the double-Q square skyrmion crystal consisting of two spin density waves is stabilized in an external magnetic field. We also show that double-Q states appear in both low- and high-field regions; the low-field spin configuration is characterized by an anisotropic double-Q modulation consisting of a superposition of the spiral wave and sinusoidal wave, while the high-field spin configuration is characterized by an isotropic double-Q modulation consisting of a superposition of two sinusoidal waves. Furthermore, we show that the obtained multiple-Q instabilities can be realized for various ordering wave vectors. The results provide the possibility of realizing the short-period skyrmion crystals under the body-centered tetragonal lattice structure. Full article
(This article belongs to the Special Issue Spin and Charge Transport in Novel Quantum and Topological Materials)
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16 pages, 3778 KB  
Article
A Novel Sensing Method to Detect Malachite Green Contaminant on Silicon Substrate Using Nonlinear Optics
by Muhammad Ahyad, Hendradi Hardhienata, Eddwi Hesky Hasdeo, Sasfan Arman Wella, Faridah Handayasari, Husin Alatas and Muhammad Danang Birowosuto
Micromachines 2024, 15(10), 1227; https://doi.org/10.3390/mi15101227 - 30 Sep 2024
Cited by 1 | Viewed by 1627
Abstract
We propose a nonlinear-optics-based nanosensor to detect malachite green (MG) contaminants on semiconductor interfaces such as silicon (Si). Applying the simplified bond hyperpolarizability model (SBHM), we simplified the second-harmonic generation (SHG) analysis of an MG-Si(111) surface and were able to validate our model [...] Read more.
We propose a nonlinear-optics-based nanosensor to detect malachite green (MG) contaminants on semiconductor interfaces such as silicon (Si). Applying the simplified bond hyperpolarizability model (SBHM), we simplified the second-harmonic generation (SHG) analysis of an MG-Si(111) surface and were able to validate our model by reproducing experimental rotational anisotropy (RA) SHG experiments. For the first time, density functional theory (DFT) calculations using ultrasoft pseudopotentials were implemented to obtain the molecular configuration and bond vector orientation required by the SBHM to investigate and predict the second-harmonic generation contribution for an MG-Si 001 surface. We show that the SBHM model significantly reduces the number of independent components in the nonlinear tensor of the MG-Si(111) interface, opening up the possibility for real-time and non-destructive contaminant detection at the nanoscale. In addition, we derive an explicit formula for the SHG far field, demonstrating its applicability for various input polarization angles. Finally, an RASHG signal can be enhanced through a simulated photonic crystal cavity up to 4000 times for more sensitivity of detection. Our work can stimulate more exploration using nonlinear optical methods to detect and analyze surface-bound contaminants, which is beneficial for environmental monitoring, especially for mitigating pollution from textile dyes, and underscores the role of nonlinear optics in real-time ambient-condition applications. Full article
(This article belongs to the Special Issue The 15th Anniversary of Micromachines)
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