Search Results (68)

The treatment of contaminants from road infrastructure poses significant challenges due to their variable composition and the high concentrations of chloride ions, heavy metals, and oil-derived substances. Traditional methods for protecting groundwater environments are often insufficient. A promising alternative is permeable reactive barrier (PRB) technology, which utilizes recycled materials and construction waste as reactive components within the treatment zone of the ground. This paper delves into the potential of employing a composite (MIX) consisting of modified construction aggregate (as recycled material) and activated carbon (example of reactive material) to address environmental contamination from a mixture of heavy metals and chloride. The research involved chemical modifications of the road aggregate, activated carbon, and their composite, followed by laboratory tests in glass reactors and non-flow batch tests to evaluate the kinetics and chemical equilibrium of the reactions. The adsorption process was stable and conformed to the pseudo-second-order kinetics and Langmuir, Toth, and Redlich–Peterson isotherm models. Studies using MIX from a heavy metal model solution showed that monolayer adsorption was a key mechanism for removing heavy metals, with strong fits to the Langmuir (R² > 0.80) and Freundlich models, and optimal efficiencies for Cd and Ni (R² > 0.90). The best fit, at Cd, Cu, Ni = 0.96, however, was with the Redlich–Peterson isotherm, indicating a mix of physical and chemical adsorption on heterogeneous surfaces. The Toth model was significant for all analytes, fitting Cl and Cd well and Pb and Zn moderately. The modifications made to the composite significantly enhanced its effectiveness in removing the contaminant mixture. The test results demonstrated an average reduction of chloride by 85%, along with substantial removals of heavy metals: lead (Pb) by 90%, cadmium (Cd) by 86%, nickel (Ni) by 85%, copper (Cu) by 81%, and zinc (Zn) by 79%. Further research should focus on the removal of other contaminants and the optimization of magnesium oxide (MgO) dosage. Full article

The acidification modification treatment of coal is a key technical means to improve the permeability of coal seams and enhance the efficiency of coalbed methane extraction. Yet, current acidic fracturing fluids are highly corrosive, corroding downhole pipelines and contaminating groundwater. By compounding environmentally friendly and non-polluting acidic fracturing fluids and combining fractal theory and the Frenkel–Halsey–Hill (FHH) model, this paper systematically investigates their effects on the pore structure, permeability, and mechanical properties of coal bodies. It was found that the complex acid treatment significantly reduced the surface fractal dimension D₁ and spatial fractal dimension D₂ of the coal samples and optimized pore connectivity, thus improving gas transport efficiency. Meanwhile, a static splitting test and digital image analysis showed that the fracture evolution pattern of the treated coal samples changed from a centralized strain extension of the original coal to a discrete distribution, peak stress and strain were significantly reduced, and permeability was significantly increased. These findings can offer dramatic support for the optimal optimization of acidic fracturing fluids. Full article

Excessive nitrogen fertilizer use has resulted in growing nitrate contamination of groundwater. In this study, an in situ bioelectrochemical reactor (isBER) reinforced with woodchips was developed for the treatment of actual nitrate-contaminated groundwater. During the 75-day experiment, the denitrification performance, grid permeability, and microbial community structure were investigated under different flow rates and current densities. The reactor achieved a remarkable nitrate removal efficiency of 97.6% ± 0.4% and a rate of 2.09 ± 0.14 mg-N/(L·h). These results were obtained at a temperature of 18.5 ± 0.8 °C, a current density of 350 mA/m², and a flow rate of 10 cm/d. Notably, the reactor can adapt to a wide flow-rate range of 5~20 cm/d and the operation proceeded smoothly without any blockages. Furthermore, the cathode module demonstrated enrichment of hydrogen autotrophic denitrifying bacteria (Pseudomonas, Stenotrophomonas) and heterotrophic denitrifying bacteria (Brucella, Enterobacteriaceae). Conversely, the anode module exhibited relatively high enrichment levels of aerobic microorganisms and lignin-degrading bacteria (Cellvibrio). The research results can provide novel insights and technical support for in situ remediation of groundwater nitrate contamination. Full article

Elevated fluoride levels in drinking water pose a significant health risk for communities relying on groundwater in the Ethiopian Central Rift Valley. This study aims at characterizing real groundwater samples from the Ethiopian Central Rift Valley and evaluating the performance of an integrated membrane process based on reverse osmosis (RO) and membrane crystallization (MCr) for fluoride removal and its recovery as mixed fluoride salts. Groundwater analysis revealed fluoride concentrations of 20.8 mgL⁻¹ at the Meki-01 site and 22.7 mgL⁻¹ at the Meki-02 site, both exceeding the WHO guideline of 1.5 mgL⁻¹. In addition, total dissolved solids exceeded 1000 mgL⁻¹ at both sites, classifying the water as brackish. A commercial RO membrane demonstrated excellent fluoride and ion rejection, with fluoride removal rates exceeding 99%. The total dissolved solids (TDS) removal efficiency reached 89%. The mean water permeability of the membrane was 4.52 Lm⁻²h⁻¹bar⁻¹. The retentate produced in the RO unit reached a concentration of 70 mgL⁻¹, which was then treated using osmotic membrane distillation–crystallization (OMD-Cr) and/or vacuum membrane crystallization (VM-Cr). This process facilitated the recovery of mixed salts while achieving an almost zero-liquid discharge. The study confirms the successful removal of fluoride and its recovery as mixed salt, along with the recovery of water in an environmentally friendly and manageable way. Full article

Ensuring access to clean water for drinking, agriculture, and recreational activities remains a global challenge. Groundwater, supplying approximately 50% of domestic water and 40% of agricultural irrigation, faces increasing threats from climate change, population growth, and unsustainable agricultural practices. These factors contribute to groundwater contamination, notably nitrate pollution resulting from excessive fertilizer use, which poses risks to water quality and public health. Addressing this issue demands innovative, efficient, and sustainable remediation technologies. Permeable reactive barriers (PRBs) have emerged as promising solutions for in situ groundwater treatment, using reactive media to transform contaminants into less toxic forms. PRBs offer advantages like low energy consumption and minimal maintenance. This study uses bibliometric analysis to explore the scientific production of PRBs for nitrate remediation, revealing research trends, key focus areas, and significant contributions. It included 141 articles published from 1975 to 2023. Early research focused on basic mechanisms and materials like zero-valent iron (ZVI), while recent studies emphasize sustainability and cost-effectiveness using low-cost materials such as agricultural byproducts. The findings highlight a growing focus on the circular economy and the need for more in situ studies to assess PRB performance under varying conditions. PRBs show significant potential for enhancing groundwater management and long-term water quality in agricultural contexts. Full article

This study examines the effects of natural organic matter (NOM) and dissolved solids on fluoride (F⁻) retention in polyelectrolyte multilayer-based hollow-fiber nanofiltration membranes (dNF40). Lab-scale filtration experiments were conducted under varying operating conditions (initial salt concentration, NOM concentration, permeate flux, crossflow velocity, and recovery rate). dNF40 membranes exhibited F⁻ retention above 70% ± 1.2 in the absence of NOM and competing ions. However, when filtering synthetic model water (SMW) designed to simulate groundwater contaminated with high total dissolved solids (TDSs) and NOM, F⁻ retention decreased to approximately 60% ± 0.7, which was generally attributed to ion competition. Furthermore, despite limited declines in normalized permeability, the addition of NOM to SMW notably deceased F⁻ retention in the steady state to~20% due to fouling effects. The facilitated transport of the divalent cations Ca²⁺ and Mg²⁺ could be observed, as they accumulated in the organic fouling layer. While SO₄²⁻ retention remained relatively stable, the retention of monovalent anions (NO₃⁻, Cl⁻, and F⁻) decreased substantially due to drag effects. Na⁺ retention improved slightly to maintain electroneutrality. Feed salinity was shown to significantly affect separation efficiency, with PEC layers undergoing swelling and certain structural changes as the ionic strength increased. During batch filtration experiments at varying recovery rates, the retention of monovalent anions further decreased, with F⁻ retention reducing to just ~10% at a 90% recovery rate. This study provides valuable insights into better understanding and optimizing the performance of PEC-based NF membranes across diverse water treatment scenarios. Full article

Mercury contamination in groundwater seriously affects human health and ecosystem security. The remediation of Hg-contaminated groundwater remains a challenging task. The applicability of an as-synthesized supramolecular polymer (SP) for low-concentration mercury in a high-salinity groundwater matrix has been verified through a batch process and column test. The remediation of mercury-contaminated groundwater, particularly in complex high-salinity environments, represents a significant and enduring challenge in environmental science. The batch test study demonstrated that the SP can efficiently adsorb Hg from groundwater with superior selectivity and a high uptake capacity (up to 926.1 ± 165.3 mg g⁻¹). Increasing the pH and dissolved organic matter (DOM) and reducing the ionic strength can facilitate Hg adsorption; the coexistence of heavy metal ions slightly weakens the removal. In terms of its performance as a permeable reactive barrier, the SP can intercept Hg in flowing groundwater with a capacity of up to 3187 mg g⁻¹. A low influent mercury concentration, low pore velocity, and high SP dosage can effectively extend the breakthrough time in column tests. Additionally, the Yan model (R² = 0.960−0.989) can accurately depict the whole dynamic interception process (150 PVs) of SPs in a fixed column, and the Adams–Bohart model (R² = 0.916−0.964) describes the initial stage (≤35 PVs) well. Considering the functional group in the SP and the Hg species in groundwater, complexation, electrostatic attraction, ion exchange, and precipitation/co-precipitation are the plausible mechanisms for mercury removal based on the characterization results of scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectrometer (FT-IR). These impressive features render the SP a promising candidate for the remediation of trace Hg in saline groundwater using permeable reactive barrier (PRB) technology. Full article

The reclamation of illegal landfills poses a significant threat to the environment. An example of such a case is Łomianki near Warsaw, where an illegal landfill contained alarming levels of arsenic and chromium, posing a potential risk to the health of local residents due to the possibility of these metals contaminating a nearby drinking water source. Initial geochemical tests revealed high concentrations of these metals, with chromium reaching up to 24,660 mg/kg and arsenic up to 10,350 mg/kg, well above international environmental standards. This study presents effective reclamation strategies that can be used in similar situations worldwide. The reclamation allowed this land to be used for the construction of the M1 shopping center while minimizing environmental hazards. The study is based on a case study of the reclamation of this illegal landfill. The methods used in this project included the relocation of approximately 130,000 m³ of hazardous waste to a nearby site previously used for sand mining. Bentonite mats and geotextiles were used to prevent the migration of contaminants into the groundwater. The waste was layered with sand to assist in the structural stabilization of the site. In addition, proper waste segregation and drainage systems were implemented to manage water and prevent contamination. Eight years after the reclamation, post-remediation soil surveys showed significant improvements in soil quality and structural stability. Specifically, the Proctor Compaction Index (I_S) increased from an estimated 0.5–0.7 (for uncontrolled slope) to 0.98, indicating a high degree of compaction and soil stability, while arsenic and chromium levels were reduced by 98.4% and 98.1%, respectively. Reclamation also significantly reduced permeability and settlement rates, further improving the site’s suitability for construction. The cost-benefit analysis showed a cost saving of 37.7% through local waste relocation compared to off-site disposal, highlighting the economic efficiency and environmental benefits. The main conclusions of this study are that land reclamation effectively reduced environmental hazards; innovative solutions, such as bentonite mats, advanced waste sorting, geotextiles, and drainage systems, improved environmental quality; and the Łomianki case serves as a model for sustainable waste management practices. Full article

The Integrated Valuation of Ecosystem Services and Trade-Offs (InVEST) model with the distributed hydrological model Soil and Water Assessment Tool (SWAT) were implemented. The SWAT model quantifies and visualizes water production and groundwater reserves in the Mudanjiang River Basin, employing the groundwater runoff modulus method to calculate groundwater recharge in the basin. This study aims to assess the model’s applicability in cold basins and subsequently analyze groundwater distribution characteristics, water reserves, and the exploitable volume. It serves as a reference for the judicious allocation of groundwater resources and the preservation of the local aquatic ecosystem. The study indicates the following: (1) Utilizing the monthly runoff data from the Mudan River hydrologic station, SWAT simulation and calibration were conducted, yielding a determination coefficient (R²) of 0.75 and a Nash–Sutcliffe efficiency coefficient (NS) of 0.77, thereby satisfying fundamental scientific research criteria. The water yield predicted by the InVEST model aligns closely with the water resources bulletin of the research region. (2) The data from the water production module of the InVEST model indicate that the average annual water production during the research period was 6.725 billion m³, with an average annual water production depth of 148 mm. In 2018, characterized by ample water supply, the water output was at its peak, with a depth of 242 mm. In 2014, the water depth recorded was merely 16 mm. (3) Throughout the study period, the average annual flow of the Mudan River was 4.2 billion m³, whereas the groundwater reserve was 24.13 (10⁸ m³·a⁻¹). In 2013, the maximum groundwater reserve was 38.42 (10⁸ m³·a⁻¹), while the minimum reserve in 2014 was 2.36 (10⁸ m³·a⁻¹), suggesting that the region was predominantly experiencing sustainable exploitation. (4) The mean groundwater runoff modulus is 0.28 L/(s·km²), with a peak annual recharge of 15.4 (10⁸ m³·a⁻¹) in 2013 and a lowest recharge of just 3.2 (10⁸ m³·a⁻¹) in 2011. Full article

The Environmental Consulting Industry in the United States has historically prioritized engineering approaches over geologic science in addressing groundwater contamination. This engineering-centric bias has often resulted in oversimplified conceptual site models (CSMs) that fail to capture subsurface heterogeneity, limiting the effectiveness of groundwater remediation strategies. Recognizing the critical role of geology, the industry is increasingly adopting a Remediation Geology approach, which emphasizes the development of robust geologic models as the foundation for remediation programs. Geologic models optimize site lithologic data to define subsurface permeability architecture. The geologic model primarily serves as the structure to develop a Process-Based CSM, which is a holistic model that supports the entire remediation life cycle. A Process-Based CSM addresses the physical, chemical, and biological processes governing contaminant occurrence with the goal of modeling and predicting subsurface conditions for improved decision making with respect to monitoring programs and remediation design. Case studies highlight the transformative impact of Remediation Geology and Process-Based CSMs, demonstrating significant improvements in cleanup efficiency and resource optimization across diverse hydrogeologic settings. By addressing site complexities such as fine-grained units and fracture networks, Remediation Geology and Process-Based CSMs have proven effective for contaminants ranging from chlorinated solvents to per- and polyfluoroalkyl substances (PFASs) and radionuclides. Full article

This study addresses the persistent issue of urban waterlogging in Wujin District, Changzhou City, Jiangsu Province, using a comprehensive approach integrating an optimized drainage network and low-impact development (LID) measures. Utilizing the Storm Water Management Model (SWMM), calibrated with extensive hydrological and hydraulic data, the model was refined through genetic algorithm-based optimization to enhance drainage efficiency. Key results indicate a substantial reduction in the average duration of waterlogging from 7.43 h to 3.12 h and a decrease in average floodwater depth from 21.27 cm to 8.65 cm. Improvements in the drainage network layout, such as the construction of new stormwater mains, branch drains, and rainwater storage facilities, combined with LID interventions like permeable pavements and rain gardens, have led to a 56.82% increase in drainage efficiency and a 63.88% reduction in system failure rates. The implementation effectively minimized peak flood flow by 25.38%, reduced runoff, and improved groundwater recharge and rainwater utilization. The proposed solutions offer a replicable, sustainable framework for mitigating flooding in urban environments, enhancing ecological resilience, and ensuring the safety and quality of urban life in densely populated areas. Full article

In many projects, it is important to monitor the direction of groundwater flow, but conventional methods make it difficult. Through streaming potential detection technology, under the action of external pressure, liquid can be forced to flow through solid pores to generate directional flow, and a flow potential can be generated at both ends of solid pores. The phenomenon of different streaming potentials can help engineers determine the direction of fluid flow. In this study, tests were conducted using a core injection system and a streaming potential tester to carry out injections on sandstone samples of two different structures to study the effects of different injection pressures and different salinities on the variation in the streaming potential in sandstone. Moreover, a small-scale field water injection monitoring experiment was also carried out to observe the actual situation of the streaming potential generated during water injection in the field formation structure. The laboratory test results show that the flow potential is accompanied by the liquid injection process in the sandstone sample, and the flow potential produced by the sandstone with different porosities is obviously different, Therefore, the flow potential associated with the actual rock injection process can be used to infer porosity and permeability. This study provides a new method for monitoring underground fluids and is expected to improve the efficiency of oil extraction and geothermal development. Full article

In acidic groundwater, effectively removing both ammonia nitrogen (NH₄⁺-N) and nitrate nitrogen (NO₃⁻-N) poses a challenge. This study focused on studying the removal of NH₄⁺-N and NO₃⁻-N combined contaminations by zero-valent iron (ZVI) combined with microbial agents in both laboratory and field pilot-scale studies. Laboratory experiments showed that ZVI could reduce the denitrification stage from 15 days to 10 days by increasing solution pH and improving NO₃⁻-N reduction efficiency. In a field pilot test (at Qingyuan, Guangdong Province, China), high-pressure injection pumps were used to inject alkaline reagents to raise the pH to 7~8. Meanwhile, compressors were applied to aerate the groundwater to increase the dissolved oxygen (DO) concentration above 2 mg·L⁻¹. Subsequently, microbial agents of nitrobacteria were injected to initiate aerobic nitrification. As the DO level dropped below 2 mg·L⁻¹, agents of micro-ZVI and denitrifying bacteria were injected to stimulate autotrophic denitrification. Intermittent aeration was employed to modify the redox conditions in the groundwater to gradually eliminate NH₄⁺-N and NO₃⁻-N. However, due to the effect of the low-permeability layers, adjustments in the frequency of remediation agent injection and aeration were necessary to achieve removal efficiencies exceeding 80% for both NH₄⁺-N and NO₃⁻-N. This work aims to overcome the limitations of microbial remediation methods in the laboratory and the field and advance nitrogen pollution remediation technologies in groundwater. Full article

In China, groundwater loss caused by underground coal mining is becoming increasingly serious. The key to groundwater restoration is to repair mining-induced water-conducting fractures (WCFs) in the overlying strata. In this study, the adsorption–consolidation sealing characteristics of chemical precipitates were used to conduct permeability reduction (PR) experiments, including adding mixed CaCO₃ and Fe(OH)₃ to a sandstone specimen with a single fracture at room temperature. An aqueous solution of Na₂CO₃ was used as the simulated groundwater, and a solution of mixed CaCl₂ and FeCl₂ was used as the repair reagent to simulate the water seepage conditions of a fractured rock mass. The two aqueous solutions were simultaneously injected into a single-fractured rock specimen at a constant flow rate. The experimental results show that the Fe(OH)₃ colloid encapsulated CaCO₃ crystals in a mixed precipitate, reducing the overall structural stability of the mixed precipitate and restricting repair and PR efficiency. However, the Fe(OH)₃ precipitate had better PR efficiency in the initial stage of the experiment. Therefore, a better scheme was put forward to repair the WCF, utilizing a mixed Fe(OH)₃ and CaCO₃ precipitate with a molar ratio close to 1:4 in the early stage and a single CaCO₃ precipitate in the later stage. Full article

Groundwater pollution poses a significant threat to ecosystems and public safety. Traditional remediation methods have limitations, necessitating innovative approaches. This study integrates numerical modeling and bioremediation to address groundwater contamination in an industrial site. It explores the potential of chemotactic bacteria to enhance remediation efficiency. The research establishes groundwater pollutant transport models, analyzes flow fields, and assesses the distribution of various pollutants. The results demonstrate the effectiveness of chemotactic bacteria, particularly chemotactic bacteria that can rapidly adapt as the pollutant concentration decreases, the concentration of chemotactic bacteria in the low-permeability area has increased by 112%. This study provides insights into the practical application of bioremediation and the promising role of bacterial chemotaxis in treating contaminated groundwater. Full article