Search Results (19)

Shale gas extraction is underway in the Karoo Basin. Previous oil and gas explorers abandoned several wells, and the abandonment statuses of these wells are unknown. Critically, improperly abandoned wells can provide a pathway for the leakage of stray gas into shallow aquifers and degrade water quality. To understand the abandonment integrity risk posed by these wells, a qualitative risk model was developed to assess the likelihood of well-barrier failure leading to a potential leak. The potential leak paths identified include zones with cement losses during grouting, casing corrosion, cement channels, failure to case and cement risk zones, uncased and uncemented sources, uncemented annuli, and unplugged wells. To confirm whether these wells are leaking, geochemical tracing of stray gas was integrated. Eleven of the fifty samples collected had dissolved hydrocarbon gas concentrations that were high enough to use isotopic analysis to determine the source. The results revealed microbial gas via fermentation and carbon dioxide reduction, thermogenic gas, and geothermal gas, as evidenced by larger δ¹³C₁ values and isotopic reversals associated with dolerite intrusions. The thermogenic-type gas detected in legacy abandoned wells and <1 km water boreholes adjacent to these wells serves as evidence that the downhole plugs did not maintain their integrity or were improperly plugged, whereas the thermogenic gas detected in >1 km water boreholes indicates leakage contamination due to natural fracture pathways. The presence of thermogenic gas in legacy wells and in groundwater boreholes <1 km from legacy wells implies that shale gas extraction using hydraulic fracturing cannot be supported in these situations. However, using safety buffer zones greater than 1 km from the legacy wells for shale gas drilling could be supported. Full article

Tight sandstone gas constitutes a strategically significant resource in the exploration of unconventional hydrocarbon systems. Current understanding of the geochemical composition and genesis of tight sandstone gas in the Daning–Jixian Block, southeastern Ordos Basin, is insufficient, which hampers a comprehensive assessment of its resource potential. This study is the first to systematically investigate the geochemical characteristics and genetic origin of high-maturity tight sandstone gas in the southeastern Ordos Basin’s Daning–Jixian Block. Gas specimens were systematically acquired from multiple stratigraphic units within the reservoir interval and subjected to compositional and carbon–hydrogen isotope analysis. Compared with other gas fields in the Ordos Basin, the Daning–Jixian Block has higher average methane concentration, and notably lower ethane and propane concentrations; its average δ¹³C₁ and δ²H-CH₄ is heavier, while δ¹³C₂ and δ¹³C₃ are lighter. Based on the δ¹³C₁-δ²H-CH₄ diagram, all gas samples from the block and other basin gas fields fall into the geothermal, hydrothermal and crystalline gas domain, indicating gas genesis associated with over-mature organic matter interacting with external hydrogen. Milkov genetic diagram analysis reveals that the natural gas consists of primarily early-stage kerogen-cracking gas, with a minor contribution from crude oil-derived gas originating from Carboniferous–Permian source rocks. Notably, samples from Daning–Jixian exhibit a unique δ¹³C₁ > δ¹³C₂ reversal, attributed to mixing effects between gas from highly mature kerogen and gas from secondary cracking of crude oil. Consequently, ethane carbon isotopes alone are insufficient for definitive genetic classification. These findings provide a new geochemical interpretation framework for analogous high-maturity tight gas reservoirs. Full article

The Muji Fault Zone (MJF) in the northeastern Pamir Plateau hosts a well-developed non-volcanic geothermal system, characterized by widespread hot springs and mud volcanoes—where core processes of geothermal fluids, including atmospheric precipitation recharge, shallow crustal circulation, carbonate-driven water–rock interactions, and CO₂-rich fluid discharge, are tightly coupled with regional intense crustal deformation and frequent seismic activity. We collected and analyzed 22 geothermal water samples and 8 bubbling gas samples from the MJF periphery, finding that the geothermal waters are predominantly of the HCO₃-Ca·Mg hydrochemical type, with hydrogen (δD: −103.82‰ to −70.21‰) and oxygen (δ¹⁸O: −14.89‰ to −10.10‰) isotopes indicating atmospheric precipitation as the main recharge source. The Na-K-Mg ternary diagram classified the waters as immature, reflecting low-temperature water–rock interactions in the shallow crust (<3 km), while noble gas isotopes (³He/⁴He: 0.03–0.09 Ra, Ra = 1.43 × 10⁻⁶) and carbon isotopes (δ¹³C-CO₂) confirmed fluid origin from crustal carbonate dissolution; SiO₂ geothermometry estimated thermal reservoir temperatures at 67–155 °C. Long-term monitoring (May 2019–April 2024) of Tahman (THM) and Bulake (BLK) springs revealed significant pre-seismic anomalies: before the 2023 Tajikistan Ms7.2 and 2024 Wushi Ms7.1 earthquakes, Na⁺, Cl⁻, and SO₄²⁻ concentrations showed notable negative anomalies (exceeding 2σ of background values) with synchronous trends between the two springs. Integrating these findings, a “Fault-Spring-Mud Volcano-Earthquake” fluid response model was established, providing direct evidence of deep-shallow fluid coupling in mud volcano–geothermal fluid interactions. This study enhances understanding of the dynamic evolution of non-volcanic geothermal systems under tectonic stress and clarifies the mechanisms of hydrogeochemical variations in fault-controlled geothermal systems, offering a robust scientific basis for advancing research on tectonic–fluid interactions in active fault zones of the northeastern Pamir Plateau. Full article

This study investigates geothermal clusters in the middle reaches of the Dawen River Basin, focusing on the developmental characteristics and genetic mechanisms of typical geothermal water exposures at key sites, including Daidaoan (Taishan), Qiaogou (Culai Town), and Anjiazhuang (Feicheng). Utilizing hydrogeochemical and environmental isotope analyses, we identify a dual groundwater recharge mechanism: (1) rapid infiltration via preferential flow through fissure media and (2) slow seepage with evaporative loss along gas-bearing zones. Ion sources are influenced by water–rock interactions and positive cation exchange. The hydrochemical types of surface water and geothermal water can be divided into five categories, with little difference within the same geothermal area. The thermal reservoir temperatures range from 53.54 to 101.49 °C, with the Anjiazhuang and Qiaogou geothermal areas displaying higher temperatures than the Daidaoan area. Isotope calculations indicate that the recharge elevation ranges from 2865.76 to 4126.69 m. The proportion of cold water mixed in the shallow part is relatively large. A comparative analysis of the genetic models of the three geothermal water groups shows that they share the common feature of being controlled by fault zones. However, they differ in that the Daidao’an geothermal area in Mount Tai is of the karst spring type with a relatively low geothermal water temperature, whereas the Qiaogou geothermal area in Culai Town and the Anjiazhuang geothermal area in Feicheng are of the gravel or sandy shale spring types with a relatively high geothermal water temperature. Full article

High-enthalpy geothermal resources in volcanic settings often lack clear surface manifestations, requiring integrated, data-driven approaches to identify hidden reservoirs. In this study, we apply a multivariate clustering technique—genetic K-Means clustering (GKMC)—to a comprehensive soil gas dataset collected from 1050 sampling sites across the ~100 km² Garehagua mining license, located in the southern rift zone of Tenerife (Canary Islands). The survey included diffuse CO₂ flux measurements and concentrations of key soil gases (He, H₂, CH₄, O₂, N₂, Ar isotopes, and ²²²Rn, among others). Statistical-graphical analysis using the Sinclair method allowed for an objective classification of geochemical anomalies relative to background populations. The GKMC algorithm segmented the dataset into geochemically coherent clusters. One cluster, defined by elevated CO₂, helium, and ²²²Rn levels, showed a clear spatial correlation with inferred tectonic lineaments in the southern rift zone. These anomalies are interpreted as structurally controlled conduits for the ascent of deep magmatic-hydrothermal fluids. The findings support the presence of a concealed geothermal system structurally constrained in the southern region of Tenerife. This study demonstrates that integrating GKMC clustering with soil gas geochemistry offers a robust methodology for detecting hidden geothermal anomalies. By enhancing anomaly detection in areas with subtle or absent surface expression, this approach contributes to reducing exploration risk and provides a valuable decision-support tool for targeting future drilling operations in volcanic terrains. Full article

This study investigates the impact of the Emeishan Large Igneous Province (ELIP) on hydrocarbon formation within the Anyue gas field in the Sichuan Basin. As a major Middle to Late Permian large igneous province, the ELIP hosted intense mantle plume activity that reshaped regional tectonics and thermal structures, indirectly influencing hydrocarbon accumulation. This paper examines three primary factors in hydrocarbon evolution linked to the ELIP: its thermal influence, induced fluid activity, and role in hydrocarbon cracking. Data reveal that the thermal effects of the ELIP extend to the central Sichuan Basin, where an elevated paleogeothermal gradient has driven hydrocarbon evolution in the Anyue gas field. Petrographic characteristics, chronological data, fluid inclusion features, and C–O, S, and Pb isotopic signatures collectively indicate that around 260 Ma, a hydrothermal event occurred in the Sichuan Basin, closely aligned with a natural gas charging event. The combined effects of a heightened geothermal gradient and hydrothermal fluids (with temperatures up to 320 °C) suggest that paleo-oil reservoirs had already cracked into natural gas during the peak ELIP activity. Full article

Compared to the southern Tibetan Plateau, the northern part has been regarded as relatively lacking geothermal resources. However, there is no lack of natural hot springs exposed in beads along large-scale fracture systems, and research on them is currently limited to individual hot springs or geothermal systems. This paper focuses on the Wahongshan-Wenquan Fracture Zone (WWFZ), analyzes the formation of five hydrothermal activity zones along the fracture zone in terms of differences in hot water hydrochemical and isotopic composition, and then explores the hot springs’ hydrothermal control in the fracture zone. The results show that the main fractures of the WWFZ are the regional heat control structures, and its near-north–south- and near-east–west-oriented fractures form a fracture system that provides favorable channels for deep hydrothermal convection. Ice and snow meltwater from the Elashan Mountains, with an average elevation of more than 4,500 m above sea level, infiltrates along the fractures, and is heated by deep circulation to form deep geothermal reservoirs. There is no detectable mantle contribution source heat to the hot spring gases, and the heat source is mainly natural heat conduction warming, but the “low-velocity body (LVB)” in the middle and lower crust may be the primary heat source of the high geothermal background in the area. The hot springs’ hydrochemical components show a certain regularity, and the main ionic components, TDS, and water temperature tend to increase away from the main rupture, reflecting the WWFZ controlling effect on hydrothermal transport. In the future, the geothermal research in this area should focus on the hydrothermal control properties of different levels, the nature of fractures, and the thermal contribution of the LVB in the middle and lower crust. Full article

The existence of high-temperature geothermal anomalies in the Gonghe Basin on the northeastern margin of the Tibetan Plateau has highlighted a new perspective on the geothermal system of the Himalayan-Tibetan Plateau orogen. In this study, we collected 32 groups of liquid and gas samples from geothermal water, rivers, and boreholes in the Gonghe basin to analyze hydrochemistry, stable isotopes, and geochronology, which allow us to further reveal the geothermal fluid circulations of geothermal reservoirs. The ion contents of liquids identify two distinguished types of water, namely the Na-SO₄-Cl type primarily from geothermal water and the Na-SO₄-HCO₃ and Na-Ca-CO₃-SO₄ types primarily from cold water. The compositions of the hydrogen and oxygen isotopes of the samples indicate geothermal waters were recharged by atmospheric precipitation and 3000–4600 m high snow mountain meltwater, which may have experienced circulation of 16,300–17,300 years and mixtures of submodern and recent recharge water sources evidenced by isotopes of ³H, ¹³C, and ¹⁴C data. The ³He/⁴He ratios of these geothermal waters varying from 0.03 to 0.84 Ra further highlighted a crustal-dominated heat source in the region. The deep thermal reservoir temperature in the Gonghe Basin at 160 ± 10 °C and the depth of circulation of geothermal water is 2200–2500 m. Based on this evidence, we have established a geothermal fluid circulation model and refined the exchange processes of fluids and geothermal heat, further enriching the details of the geothermal system in Gonghe Basin. Full article

Natural hydrogen is known to be generated in the crust by water/rock interactions, especially the oxidation of iron-rich rock or radiolysis. However, other sources, especially deeper ones, exist. In the context of subduction, the dehydration of the slab, the destabilization of the NH₄, and the hydration of the mantle wedge above the subducting lithosphere may generate H₂. We present here a compilation of the known gases in the central part of the Pacific subduction and the results of a first field acquisition dedicated to H₂ measurements in Bolivia between La Paz and South Lipez. Various zones have been studied: the emerging thrust faults of the western borders of the Eastern Cordillera, the Sajama area that corresponds to the western volcanic zone near the Chile border northward from the Uyuni Salar, and finally, the Altiplano-Puna Volcanic Complex in South Lipez. Soil gas measurement within and around the Salar itself was not fully conclusive. North of the Uyuni Salar, the gases are very rich in CO₂, enriched in N₂ and poor in H₂. On the opposite, southward, all the samples contain some H₂; the major gas is nitrogen, which may overpass 90% after air correction, and the CO₂ content is very limited. On the western border of the Cordillera, the δC13 isotope varies between −5 and −13‰_, and it is not surprisingly compatible with volcanic gas, as well as with asthenospheric CO₂. The methane content is close to 0, and only a few points reach 1%. The isotopes (−1‰) indicate an abiotic origin, and it is thus related to deep H₂ presence. The high steam flow in the geothermal area of South Lipez combined with the H₂ content in the water results in at least 1 ton of H₂ currently released per day from each well and may deserve an evaluation of its economic value. The nitrogen content, as in other subduction or paleo-subduction areas, questions the slab alteration. Full article

Hydrogeochemical characterization studies are regarded as an important method for determining the origin of hot springs. The major elements, trace elements, and stable isotopes of four groups of hot spring water samples and two groups of gas samples collected from the intersection of the Altyn Tagh fault zone and the East Kunlun fault belt were investigated in this study. The hot spring water temperature ranged between 6 °C and 14 °C. The water chemistry types of the hot springs were Na·Mg-Cl, Mg·Na-Cl·HCO₃, Na-Cl·SO₄, and Na-Cl·HCO₃. The δD values ranged from −50.00% to −68.60%, while the δ¹⁸O values ranged from −6.90% to −8.60%. The hot spring water was recharged mainly by infiltrating precipitation, with a recharge elevation of 3390~3676 m. The heat storage temperature ranged from 66.7 to 164.9 °C. The circulation depth was estimated to range between 1043 and 2679 m. The strontium isotopic composition of the water samples in response to the main weathering sources comprised carbonate and sulfate. CO₂ was the main component in the hot spring gas in the study region, and its content was over 95%. The ³He/⁴He-R/Ra relationship diagram revealed that the mantle-sourced helium from the Yitunbulake spring was 3.06%. In comparison, that from the Aiken spring was 7.38%, which indicated an intrusion of mantle-source material mixed into the hot springs in the study region. The crustal marine limestone contributed significantly to the carbon inventory of the hot spring gas samples (>75%). The dissolution of the marl aquifer resulted in the release of CO₂. Carbon was primarily obtained through metamorphism and hydrothermal reactions in the basement lithologies. The Yitunbulake and Aiken hot springs are found near the intersection of the Arjin and East Kunlun fractures, where the water–rock response is relatively strong and the depth of circulation and thermal storage temperature are both high. This causes relatively high ambient pressure to be released from the deep fluid, resulting in microseismic activity in this region. The continuous observation of Aiken spring water chemistry allows for the monitoring of fracture activity in the region. The results of the study could serve as a foundation for further exploration of the relationship between geothermal water and deep faults, shallow geological formations, hydrogeological conditions, and geothermal resource development in the region. Full article

There are 30 carbonate hot springs in Yaoshuitan geothermal field, Xining Basin, China, with a temperature of 18~41.5 °C; and there are 10 carbonate hot springs in Qijiachuan geothermal field, with a temperature of 10~19.5 °C. Both geothermal fields are carbonate hot springs containing large amounts of CO₂ gas. In order to reveal the origin of the carbonated hot springs in Yaoshuitan and Qijiachuan of Xining Basin, this paper offers a comprehensive study of the regional deep geology, tectonic setting, total analysis of carbonated hot springs, δ²H, δ¹⁸O, δ¹³C isotopes, main gas composition, and geochemical characteristics of travertine dating, travertine δ¹³C, and rare earth elements. The geological process of carbonated hot spring formation and the evolution of H⁺ content from deep to shallow is revealed, and the genetic mechanism of the carbonated hot spring in Xining Basin is systematically summarized. The results show that: (1) The characteristics of δ²H and δ¹⁸O isotopes indicate that the recharge source of carbonated thermal water springs in Xining Basin is mainly atmospheric precipitation. The age of carbonated thermal water springs at ¹⁴C is more than 20 ka, indicating that some of them may come from deep fluid (gas) sources. The R/Ra in carbonated thermal water springs is mostly less than 1, indicating that the helium in geothermal water is mainly crustal source helium, and there is no deep mantle source material. (2) The Piper three-plot indicates that the direction of groundwater evolution from the recharge area at the edge of Xining Basin to Yaoshuitan and Qijiachuan carbonated thermal water spring area near the edge of the basin is opposite to the normal path of groundwater evolution in the basin, which is due to the large amount of CO₂ gas mixed in the deep fault along the northern margin of Laji Mountain. The ratio of (Ca²⁺ + Mg²⁺) and (HCO₃⁻ + SO₄²⁻) in the Potan and Qijiachuan carbonated thermal water springs is close to 1, and the ratio of (Na⁺ + K⁺)/HCO₃⁻ is less than 1. It indicates that the chemical composition of the Yaoshuitan carbonated thermal water spring and the Qijiachuan carbonated thermal water spring in Xining Basin is dominated by the dissolution of calcite, dolomite, and gypsum in deep carbonate reservoirs, supplemented by the dissolution of silicate minerals. The relationship between the volume fraction of CO₂ and the δ¹³C value of carbon isotope of CO₂ indicates that the source of CO₂ is inorganic, which is mainly formed by metamorphism and decomposition of deep carbonate and marble. The δEu < 1 and δCe > 1 of the rare earth elements in the calcium center of the carbonated thermal water springs indicate that the groundwater supplying the travertine material has been in the acidic environment receiving CO₂ from the deep crust for a long time. (3) A series of tectonic activities, such as late collision and post-collision between the Indian and Eurasian plates, has led to the uplift, asthenosphere upwelling, and thermal invasion of the northern Tibetan Plateau and other deep dynamic processes. The deep faults in the northern margin of the Laji Mountain and other deep faults with obvious neotectonic activity have provided channels for the up-invasion of deep thermal materials, and local geothermal anomalies were formed near the deep faults. The hidden carbonate rocks and silicate rocks with large thickness undergo thermal metamorphism under high temperature and high pressure in the deep geothermal anomaly area and form a large amount of CO₂, which is dissolved in water and enhances the acidity of water. At the same time, the dissolution reaction of acidic water to carbonate rocks consumes H⁺, which keeps the carbonated thermal water spring weakly acidic. (4) The composition of travertine in carbonated thermal water springs is dominated by calcite, indicating that travertine may be formed in a deep geological environment with a temperature of 150~200 °C, indicating that there are abnormal heat sources in shallow carbonate strata with a burial depth of 3000~4000 m. The abnormal heat source may be caused by the deep fault in the northern margin of Laji Mountain, as well as other deep and large faults channeled in the deep crust and mantle heat source, indicating that the deep fault in the northern margin of Laji Mountain has an obvious heat-controlling effect, and there is a good prospect of geothermal resources exploration near the fault. Full article

Volatiles transported from the Earth’s interior to the surface through permeable faults provide insights on the gas composition of deep reservoirs, mixing and migration processes, and can also be applied as gas-geothermometer. Here, we present carbon (δ¹³C), hydrogen (δ²H) and nitrogen (δ¹⁵N) isotopic data of CO₂, CH₄, and N₂ from gas samples collected from the Kızıldere and Tekke Hamam geothermal fields, located along the eastern segment of the Büyük Menderes Graben, Turkey. The stable isotopic composition of carbon (δ¹³C) ranges from +0.30 to +0.99‰ (PDB) for CO₂ from Kızıldere and is slightly more variable (−0.95 to +1.3‰) in samples from Tekke Hamam. Carbon isotope data in combination with CO₂/³He data reveal that ~97% (Tekke Hamam) to ~99% (Kızıldere) of CO₂ derives from limestone sources, with the residual CO₂ being magmatic in origin with no evidence for CO₂ from organic sources. The slightly higher contribution of limestone-derived CO₂ in Kızıldere, compared to Tekke Hamam can be attributed to the higher temperatures of the Kızıldere reservoir and resulting amplified fluid–limestone interaction, as well as helium depletion during phase separation for Kızıldere samples. In contrast to the carbon isotopic composition of CO₂, the δ¹³C values of methane from Kızıldere and Tekke Hamam are clearly distinct and vary between −23.6 and −20.8‰ for Kızıldere and −34.4 and −31.7‰ for Tekke Hamam, respectively. The δ²H-CH₄ composition is also distinct, measured as −126.7‰ for Kızıldere and −143.3‰ for Tekke Hamam. CO₂-CH₄ carbon isotope geothermometry calculations based on the isotopic fractionation of δ¹³C between the dominant component CO₂ and the minor component CH₄ reveals temperatures 20–40 °C and 100–160 °C higher than the bottom–hole temperatures measured for Tekke Hamam and Kızıldere, respectively. Based on the CO₂-CH₄ carbon isotope disequilibrium, unusual high methane concentrations of ~0.3 to 0.4 vol.-% and CH₄/³He-δ¹³C-CH₄ relationships we suggest thermal decomposition of late (Tekke Hamam) to over-mature (Kızıldere) organic matter and, to some extent, also abiogenic processes as principal source of methane. The N₂/³⁶Ar ratios of most samples reveal the existence of a non–atmospheric nitrogen component within the gas mixture issuing from both fields, in addition to a constant contribution of atmospheric derived nitrogen accompanied into the system via the meteoric recharge of the geothermal system. Based on the δ¹⁵N isotopic ratios (varying between −4.44‰ and 4.54‰), the non–atmospheric component seems to be a mixture of both sedimentary (crustal organic) and mantle nitrogen. The thick Pliocene sedimentary sequence covering the metamorphic basement is the likely major source for the thermogenic content of CH₄ and crustal N₂ gas content in the samples. Full article

Constraining the magmatic ³He/⁴He signature of fluids degassed from a magmatic system is crucial for making inferences on its mantle source. This is especially important in arc volcanism, where variations in the composition of the wedge potentially induced by slab sediment fluids must be distinguished from the effects of magma differentiation, degassing, and crustal contamination. The study of fluid inclusions (FIs) trapped in minerals of volcanic rocks is becoming an increasingly used methodology in geochemical studies that integrates the classical study of volcanic and geothermal fluids. Here, we report on the first noble gas (He, Ne, Ar) concentrations and isotopic ratios of FI in olivine (Ol) and pyroxene (Px) crystals separated from eruptive products of the Telica and Baru volcanoes, belonging to the Nicaraguan and Panamanian arc-segments of Central America Volcanic arc (CAVA). FIs from Telica yield air corrected ³He/⁴He (Rc/Ra) of 7.2–7.4 Ra in Ol and 6.1–7.3 in Px, while those from Baru give 7.1–8.0 Ra in Ol and 4.2–5.8 Ra in Px. After a data quality check and a comparison with previous ³He/⁴He measurements carried out on the same volcanoes and along CAVA, we constrained a magmatic Rc/Ra signature of 7.5 Ra for Telica and of 8.0 Ra for Baru, both within the MORB range (8 ± 1 Ra). These ³He/⁴He differences also reflect variations in the respective arc-segments, which cannot be explained by radiogenic ⁴He addition due to variable crust thickness, as the mantle beneath Nicaragua and Panama is at about 35 and 30 km, respectively. We instead highlight that the lowest ³He/⁴He signature observed in the Nicaraguan arc segment reflects a contamination of the underlying wedge by slab sediment fluids. Rc/Ra values up to 9.0 Ra are found at Pacaya volcano in Guatemala, where the crust is 45 km thick, while a ³He/⁴He signature of about 8.0 Ra was measured at Turrialba volcano in Costa Rica, which is similar to that of Baru, and reflects possible influence of slab melting, triggered by a change in subduction conditions and the contemporary subduction of the Galapagos hot-spot track below southern Costa Rica and western Panama. Full article

A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ${}^{18}$O and ${}^{87}$Sr/${}^{86}$Sr were obtained from groundwater of 24 deep Upper Jurassic geothermal wells and coupled with a few analyses of noble gases (${}^3$He/${}^4$He, ${}^{40}$Ar/${}^{36}$Ar) and noble gas infiltration temperatures. Hierarchical cluster analysis revealed three major water types and allowed a hydrochemical zoning of the SGMB, while exploratory factor analyses identified the hydrogeological processes affecting the water chemical composition of the thermal water. Water types 1 and 2 are of Na-[Ca]-HCO${}_3$-Cl type, lowly mineralised and have been recharged under meteoric cold climate conditions. Both water types show ${}^{87}$Sr/${}^{86}$Sr signatures, stable water isotopes values and calculated apparent mean residence times, which suggest minor water-rock interaction within a hydraulically active flow system of the Northeastern and Southeastern Central Molasse Basin. This thermal groundwater have been most likely subglacially recharged in the south of the SGMB in close proximity to the Bavarian Alps with a delineated northwards flow direction. Highly mineralised groundwater of water type 3 (Na-Cl-HCO${}_3$ and Na-Cl) occurs in the Eastern Central Molasse Basin. In contrast to water types 1 and 2, this water type shows substantial water-rock interaction with terrestrial sediments and increasing ${}^{40}$Ar/${}^{36}$Ar ratios, which may also imply a hydraulic exchange with fossil formation waters of overlying Tertiary sediments. Full article

Hypogene karst is a special manifestation of karst development in spatial scale. Intensive study of its development mechanism has significant meaning for engineering construction, shale gas and geothermal exploitation. To reveal the developing pattern of hypogene karst in Huanjiang syncline, karst groundwater at different depths in wells HD1-2 and HD1-4 and karst springs was selected as the research object. Through the analysis of geochemistry and stable isotopes of karst groundwater, it was revealed that the circulation pattern of deep karst water came from the common recharge of meteoric water and fossil water hosted in karst caves, runoff of deep faulting belts and discharge of large karst springs, over Huanjiang syncline, which provides good hydrodynamic conditions for hypogene karst development. Meanwhile, the widely developed faulting belts and structural fissures provide primitive dissolution space. Through the above analysis, the paper constructs a hypogene karst development pattern controlled by the deep cycle of groundwater in Huanjiang syncline. Full article