Search Results (176)

The Shenhu sea area is rich in unconsolidated hydrate reserves, but the formation mineral particles are small, the rock cementation is weak, and the coupling mechanism of hydrate phase change, fluid seepage, and formation deformation is complex, resulting in unclear productivity change law under depressurization exploitation. Therefore, a thermal–fluid–solid–chemical coupling model for natural gas hydrate depressurization exploitation in the Shenhu sea area was constructed to analyze the variation law of reservoir parameters and productivity. The results show that within 0–30 days, rapid near-well pressure drop (13.83→9.8 MPa, 36.37%) drives peak gas production (25,000 m³/d) via hydrate dissociation, with porosity (0.41→0.52) and permeability (75→100 mD) increasing. Within 30–60 days, slower pressure decline (9.8→8.6 MPa, 12.24%) and fines migration cause permeability fluctuations (120→90 mD), reducing gas production to 20,000 m³/d. Within 60–120 days, pressure stabilizes (~7.6 MPa) with residual hydrate saturation < 0.1, leading to stable low permeability (60 mD) and gas production (15,000 m³/d), with cumulative production reaching 2.2 × 10⁶ m³. This study clarifies that productivity is governed by coupled “pressure-driven dissociation–heat limitation–fines migration” mechanisms, providing key insights for optimizing depressurization strategies (e.g., timed heat supplementation, anti-clogging measures) to enhance commercial viability of unconsolidated hydrate reservoirs. Full article

Fractures in marine sediments are critical zones for hydrate formation. The kinetics and morphological characteristics of hydrates within sandstone fractures are comprehensively investigated in this study by employing a high-pressure visualization reaction vessel to examine their formation, dissociation, and reformation processes. The results are presented below: (1) In 3 mm Type I fractures, the induction time is longer than that observed in the other two fracture widths. Hydrates predominantly form on the fracture walls and gradually expand toward both sides of the fracture. (2) Gas enters the fracture from multiple directions, causing the hydrate in Type X fractures to expand toward the center from all sides, which shortens the induction time and increases the quantity of hydrate formation. (3) An increase in fracture roughness promotes nucleation of the hydrate at surface protrusions but inhibits the total quantity of hydrate formation. (4) Hydrate dissociation typically propagates from the fracture wall into the interior, exhibiting a wavy surface morphology. Gas production is influenced by the fracture width, with the highest gas production observed in a 3 mm fracture. (5) Due to the memory effect, the hydrate induction time for reformation is significantly shorter, though the quantity of hydrate formed is lower than that of the first formation. This study aims to provide micro-level insights into the distribution of hydrates in sandstone fractures, thereby facilitating more efficient and safe extraction of hydrates from fractures. Full article

This study investigated methane hydrate formation and dissociation within a temperature range of 280 to 290 K and a pressure range of 5.5 to 13 MPa. These conditions are relevant to natural gas systems, where methane is the primary component of natural gas. Either experimental or thermodynamic models were used to predict the conditions of formation of gas hydrates. The Van der Waals–Platteeuw model based on statistical thermodynamics is the basis of the existing thermodynamic models for predicting the conditions of hydrate formation. In this work, the stepwise heating method was applied to determine the thermodynamic equilibrium points of methane gas in a constant volume system. The CPA (Cubic Plus Association) equation of state and the Van der Waals–Platteeuw model were employed to simulate hydrate formation conditions. Experimental equilibrium data for pure methane were compared with results from previous studies (Deaton and Frost, Nakamura, Jhaveri and Robinson, De Roo, and others). The results showed excellent agreement, with an average absolute temperature error of less than 0.1%. This high level of accuracy confirms the reliability of the experimental procedures and thermodynamic modeling approaches used in the study to accurately predict hydrate formation conditions, being critical for designing and operating natural gas systems in order to avoid hydrate accumulation. Full article

Natural gas hydrates are a promising alternative energy source for oil and gas in the future. However, geomechanical issues, such as wellhead instability, may arise, affecting the safe and efficient development of hydrates. In the present work, a sensitivity analysis was performed on sediment subsidence and wellhead instability during the development of marine hydrates using a multi-field coupled model. This is accomplished by adjusting the corresponding parameters based on the basic data of the default case. Meanwhile, the corresponding influencing mechanisms were explored. Finally, design recommendations for operation parameters were proposed based on the research findings regarding wellhead stability. It was found that the wellhead undergoes rapid sinking during a certain period in the early stage of hydrate development, followed by a slower, continued sinking. The sensitivity analysis found that when the depressurization amplitude is small, the wellhead sinking is also minimal. To maintain wellhead stability during the development process, it is recommended that neither the depressurization amplitude or drawdown pressure exceed 3.0 MPa. Although a high heating temperature can increase gas production to some extent, the accompanying excessive hydrate dissociation may compromise the stability of both the formation and wellhead. To balance gas production and wellhead stability, it is recommended that the heating amplitude does not exceed 50 °C. In addition, the permeability influences the distribution of pore pressure, which in turn affects sediment subsidence and wellbore stability. Wellhead stability deteriorates as permeability increases. Therefore, it is crucial to accurately determine the reservoir characteristics (such as permeability) before developing hydrates to avoid wellhead instability. Finally, the investigation results reveal that using different versions of the investigation model can impact the accuracy of the results, and neglecting certain physical fields may lead to an underestimation of the wellhead sinking. Full article

The mining of CH₄ hydrate through the CO₂-CH₄ replacement method mostly occurs within CH₄ hydrate-bearing sediments. Therefore, it is crucial to investigate the replacement process on the pore scale. This study aims to explore the impacts of pore microstructure and the CH₄ hydrate non-uniform distribution on the replacement of CO₂ for CH₄. A two-dimensional numerical model has been adopted to investigate this issue. A pore-scale numerical simulation is conducted in a physical model of real porous media. Then, the replacement process in a comparative model, in which the pore microstructure and the non-uniform distribution of the CH₄ hydrate are not considered, is simulated. The findings indicate that the CH₄ hydrate dissociation and the CO₂-CH₄ mixed hydrate generation are affected by the effective throat length of pores. When the pore microstructure and CH₄ hydrate heterogeneous distribution are ignored, the replacement rate and CO₂ storage rate are underestimated. However, the effective throat length does not exert a significant impact on the pure CO₂ hydrate generation, which is produced by the reaction of water with dissolved CO₂. In addition, in terms of gas migration, ignoring the heterogeneous distribution of CH₄ hydrate will underestimate the impact of initial water on the relative permeability of gas. Full article

Natural gas hydrates (shortened as hydrates) are expected to be a prospective alternative to traditional fossil energies. The main strategy of exploring hydrates is achieved by dissociating solid hydrates into gas and water with the depressurization method. However, we have little knowledge on the changes in heat and energy, which are implicit essences compared with explicit temperature. Thus, this study for the first time investigates the evolutionary patterns of heat and energy during hydrate dissociation, by fully coupled thermal–hydraulic–mechanical–chemical modelling. A novel numerical technique (physics-based constrained conditions) is proposed to guarantee the stability and precision of the numerical computation. The classic Masuda’s experiment is used as a case study. Results show that the cumulative conduction heat tends to increase first and then decrease during the dissociation of hydrate, while the cumulative advection heat has the tendency to increase monotonically. External heat sources increase the energy, while phase change has a reduction effect on the change in energy. The role of conduction heat is minor, but the contribution of advection heat is considerable for the change in energy. Additionally, two implications are given for lab-scale experiments and in situ engineering from the perspective of energy. Our findings provide new insights into the mechanism of hydrate dissociation and are beneficial to the real-world engineering of hydrate exploration in terms of cost evaluation. Full article

Since it was proposed, the replacement process, in natural gas hydrate reservoirs, has been considered as one of the most promising options to obtain an alternative and potentially carbon-neutral energy source. However, such a process shows high complexity, and its maximum efficiency cannot exceed 75% if carried out with pure carbon dioxide. The addition of minor quantities of other guest species in mixture with carbon dioxide allows higher efficiencies to be reached. This study deepens the production of hydrates with a binary mixture containing carbon dioxide and propane, with corresponding concentrations equal to 85/15 vol%. Several experiments were carried out consecutively and with the same gas–water mixture in order to ensure the system retains memory of previous formations. The results were then discussed in terms of the quantity of hydrates produced and the evolution of the formation process as a function of time. The data collected during the dissociation of hydrates were finally used to define the phase boundary of the system. Full article

Phase transition in gas hydrate reservoirs has a significant effect on the fluid flow dynamic when performing test production, which should be carefully studied. This study systematically investigates the phase transition characteristics of natural gas hydrates during the depressurization extraction process through laboratory-scale numerical simulations. First, a laboratory-scale numerical simulation model is established with dimensions of 1 m × 1 m × 1 m. In the simulation, the nanoscale and microscale effect on phase transition is considered. Then, the analysis of how different sediment types and their properties affecting gas production dynamics is presented. The results show that hydrate dissociation and formation are significantly influenced by factors such as the pore scale, salinity, and water content. In particular, montmorillonite had the most significant effect, leading to a 525.25% increase in gas production, while the impact of silty soil was relatively smaller. The increase in salinity inhibited hydrate formation but promoted dissociation, resulting in a significant increase in gas production, especially when the salinity reached to 3.5%, where gas production increased by 590.21%. An increase in water content led to a significant decrease in production. Through monitoring temperature and pressure changes during the extraction process, the different physical fields are analyzed, providing important theoretical support and practical guidance for the efficient extraction of natural gas hydrates. Full article

Methane gas hydrate-bearing sediments hold substantial natural gas reserves, and to understand their potential roles in the energy sector as the next generation of energy resources, considerable research is being conducted in industry and academia. Consequently, safe and economically feasible extraction methods are being vigorously researched, as are methods designed to estimate site-specific reserves. In addition, the presence of methane gas hydrates and their dissociation have been known to impact the geotechnical properties of submarine foundation soils and slopes. In this paper, we advance research on gas hydrate-bearing sediments by theoretically studying the effect of the hydromechanical coupling process related to ocean wave hydrodynamics. In this regard, we have studied two geotechnically and theoretically relevant situations related to the oscillatory wave-induced hydromechanical coupling process. Our results show that the presence of initial methane gas pressure leads to excessively high oscillatory pore pressure, which confirms the instability of submarine slopes with methane gas hydrate accumulation originally reported in the geotechnical literature. In addition, our results show that neglecting the presence of initial methane gas pressure in gas hydrate-bearing sediments in the theoretical description of the oscillatory excess pore pressure can lead to improper geotechnical planning. Moreover, the theoretical evolution of oscillatory excess pore water pressure with depth indicates a damping trend in magnitude, leading to a stable value with depth. Full article

Gas hydrate inhibition using chemicals has been under continuous investigation, and several modelling studies have been published since its inception. Since it is not always feasible to conduct experimental research, it is especially crucial to forecast the conditions under which gas hydrates may form and dissociate in the presence of chemical inhibitors. As a result, a reliable forecasting tool is vital. This article provides an exhaustive review of various modelling methodologies in the context of gas hydrate chemical inhibition. The key aspects of empirical models, thermodynamic models, kinetic models, artificial intelligence-based models and quantum chemistry-based models are presented. Critical analysis of each modelling approach has been performed, highlighting strengths, limitations, and areas where further investigations are still crucial. Rapid progress has been made with respect to gas hydrate modelling approaches in the context of chemical inhibition; however, further research is still vital to bridge the gaps that have been identified in this review. Potential improvements to existing models have been proposed, particularly in terms of integrating experimental data and utilizing hybrid approaches, which could serve as valuable future directions for the field. Full article

Natural gas hydrates have great strategic potential as an energy source and have become a global energy research hotspot because of their large reserves and clean and pollution-free characteristics. Hydrate saturation affecting the electrical and acoustic properties of sediments significantly is one of the important parameters for the quantitative evaluation of natural gas hydrate reservoirs. The accurate calculation of hydrate saturation has guiding significance for hydrate exploration and development. In this paper, experiments regarding methane hydrate formation and dissociation in clay-bearing sediments were carried out based on the Ultrasound Combined with Electrical Impedance (UCEI) system, and the measurements of the joint electrical and acoustic parameters were collected. A machine learning (ML)-based model for evaluating hydrate saturation was established based on electrical–acoustic properties and a neural network ensemble. It was demonstrated that the average relative error of hydrate saturation calculated by the ML-based model is 0.48%, the average absolute error is 0.0005, and the root mean square error is 0.76%. The three errors of the ensemble network are lower than those of the Archie formula and Lee weight equation. The ML-based modeling method presented in this paper provides insights into developing new models for estimating the hydrate saturation of reservoirs. Full article

This research deals with gas hydrates formation and dissociation within a marine quartz-based porous sediment and in batch conditions. Hydrates were formed with small-chain hydrocarbons included in natural gas mixtures: methane and also ethane and propane. The dissociation values were collected and provided both graphically and numerically. The results were then compared with the theoretical hydrate-liquid-vapor phase boundary equilibrium for the same species, defined according to the existing literature. The deviation of the experimental results from the ideal ones, associated with the porous sediment, was quantified and discussed. For the scope, the grain size distribution and chemical composition of the sediment were provided along with the text. The results proved that the different size of guest species and, consequently, the different hydrate structures formed, played a relevant role in determining the promoting, inhibiting or neutral behavior of the porous sediment during the process. Full article

This study reports an investigation into both isotropic and anisotropic permeability effects on gas production behavior during depressurization-induced natural gas hydrate dissociation at site NGHP-01-10D in the Krishna-Godavari basin. Numerical simulations were performed on a reservoir-scale model incorporating a single vertical well, examining different scenarios of permeability ratios (r_rz). The investigation assessed gas and water production rates, cumulative production volumes, the gas-to-water ratio, and the spatial distribution of reservoir parameters throughout a production duration of 3 years. The findings indicate that permeability anisotropy has a substantial impact on hydrate dissociation and gas recovery. For r_rz > 1, horizontal pressure propagation was promoted and gas production increased. For example, at t = 1100 days, the total gas production improved from 7.88 × 10⁵ ST m³ for r_rz = 1 to 55.9 × 10⁵ ST m³ for r_rz = 10. For r_rz < 1, vertical pressure propagation resulted in higher water production with concomitantly lower rates of gas production rates. Spatial distribution analysis revealed that higher r_rz values led to more extensive radial propagation of pressure drop, temperature decrease, gas saturation increase, and hydrate dissociation. The study concludes that higher horizontal permeability enhances depressurization effects, resulting in higher gas production rates and more favorable gas-to-water ratios. Full article

Depressurization combined with heat (mainly hot water) injection is an important technique for exploiting natural gas hydrate (NGH). To overcome the problems of pore water intrusion and hot water energy loss in the technique, this paper employs a method of setting sealing boundaries in permeable overburden and underburden to exploit NGH. The influence of the presence of sealing boundaries on NGH exploitation performances was numerically investigated. The results indicate that the sealing boundaries in permeable overburden and underburden can inhibit water intrusion and reduce heat loss, significantly improving the efficiency of hydrate dissociation and gas production. Specifically, the hydrate dissociation and gas production efficiency increased by 22.0–30.1% and 63.9–85.1%, respectively. Moreover, there is an optimal sealing vertical distance within the range of 0–15 m, maximizing the mining efficiency of NGH at the end of production. On the other hand, the presence of sealing boundaries effectively limits the escape range of CH₄ in the permeable overburden and underburden, resulting in an increasing gas-to-water ratio and an increasing energy efficiency. These findings provide theoretical and technical support for the mining of NGH by depressurization combined with heat injection. Full article

Clathrate hydrate-based technologies are considered promising and sustainable alternatives for the effective management of the climate change risks related to emissions of carbon dioxide produced by human activities. This work presents a combined experimental and computational investigation of the effects of the operational procedures and characteristics of the experimental configuration, on the phase diagrams of CO₂-H₂O systems and CO₂ hydrates’ formation, growth and dissociation conditions. The operational modes involved (i) the incremental (step-wise) temperature cycling and (ii) the continuous temperature cycling processes, in the framework of an isochoric pressure search method. Also, two different high-pressure PVT configurations were used, of which one encompassed a stirred tank reactor and the other incorporated an autoclave of constant volume with magnetic agitation. The experimental results implied a dependence of the subcooling degree, (P, T) conditions for hydrate formation and dissociation, and thermal stability of the hydrate phase on the applied temperature cycling mode and the technical features of the utilized PVT configuration. The experimental findings were complemented by a thermodynamic simulation model and other calculation approaches, with the aim to resolve the phase diagrams including the CO₂ dissolution over the entire range of the applied (P, T) conditions. Full article