Search Results (135)

Traditional cement-based foamed lightweight soils suffer from high construction costs, poor durability, and low solid waste utilization efficiency, which severely restrict their engineering application. A novel polyvinyl alcohol (PVA)-reinforced solid waste-based foamed lightweight soil is fabricated using Bayer red mud, mineral powder, and fly ash. To clarify the durability evolution mechanisms, systematic freeze–thaw cycling, long-term water immersion, and sodium sulfate erosion tests were conducted on PVA-reinforced solid waste-based, unreinforced solid waste-based, and pure cement-based specimens. The results demonstrate that the PVA-reinforced specimen achieves optimal freeze–thaw resistance with only 17.10% strength loss after 50 cycles, owing to the internal three-dimensional fiber network that restrains crack propagation and enhances matrix toughness. It also exhibits excellent long-term water immersion stability, with a mild strength increment of 4.04–10.33% after 120 days. In contrast, the CN exhibited a strength increase of 43.62%, attributed to its lower initial strength caused by incomplete hydration; however, its final strength remained between those of the other two groups. In sulfate environments, unreinforced solid waste-based specimens present superior corrosion resistance, while PVA fiber-induced interconnected pores slightly weaken sulfate erosion resistance. Microscopic analysis confirms that the generation of alunite and gypsum hydration products fundamentally causes performance discrepancies among different specimens. Different from previous studies focusing on single fiber modification or single solid waste partial replacement of cement, this study innovatively adopts a composite modification strategy of “multi-solid waste alkali-activated matrix + PVA fiber toughening”, and systematically reveals the durability evolution mechanism under multiple harsh environments. Full article

Bedrock channel evolution is shaped by the combined effects of mechanical incision and weathering processes that operate under seasonal variability. This study employs numerical simulations to examine how bedload-impact abrasion and freeze–thaw weathering interact to drive bedrock channel cross-sectional adjustment under seasonal forcing of discharge and temperature. A set of numerical experiments systematically varies initial alluvial thickness, bedrock tensile strength, high-flow discharge, and freeze–thaw erosion depth. The results indicate sediment cover exerts strong control on abrasion efficiency. Thin alluvial cover enhances the tool effect and promotes center-focused incision, whereas thicker cover increasingly suppresses abrasion across the channel bed and stabilizes cross-sectional geometry. Higher bedrock tensile strength weakens only abrasion-driven incision, resulting in a reduced abrasion-to-weathering removal area ratio in more resistant substrates. Discharge shows a threshold-like influence on incision, with abrasion intensifying sharply once discharge exceeds the threshold and producing a deeper incision near the channel center. Freeze–thaw weathering removal is concentrated along channel banks and margins, promoting lateral modification at moderate prescribed erosion depths but becoming strongly suppressed at the largest depth due to enhanced debris production. Together, these responses define three characteristic regimes: abrasion-dominated, interaction-dominated, and freeze–thaw-dominated. These regimes offer a framework for interpreting coupled seasonal processes in bedrock channel evolution. Full article

As tangible witnesses and cultural carriers of the evolution of Chinese civilization, earthen heritage sites embody outstanding historical, cultural, and scientific value. However, due to the heterogeneity among sites and their long-term exposure to complex environmental and anthropogenic pressures, their conservation faces numerous challenges. This paper provides a comprehensive review of the deterioration mechanisms of earthen heritage sites in China induced by environmental and anthropogenic factors, with particular emphasis on the effects of individual factors, such as salt-induced erosion, wetting–drying cycles, wind erosion, microbial activity, freeze–thaw cycles, and human activities, as well as the coupled actions of multiple factors. It further summarizes recent progress in protective technologies developed in response to these mechanisms, as well as integrated conservation strategies for coping with coupled deterioration effects. In recent years, the intrinsic linkage mechanisms between external environmental conditions and the engineering performance of earthen heritage sites have become a research focus. This review aims to deepen the understanding of environmental degradation processes in earthen heritage sites and to provide theoretical and technical support for the scientific formulation of targeted preventive conservation, repair, and strengthening measures. Full article

Asphalt pavement wearing courses are directly exposed to hydrodynamic scouring, fuel erosion, freeze–thaw action, and traffic abrasion, leading to accelerated surface deterioration, skid-resistance loss, frequent maintenance, and increased life-cycle carbon emissions. To address these challenges, this study developed an organosilicon-based erosion- and skid-resistant asphalt wearing course (OES-AWC) through a stepwise material design strategy. An organosilicon-treated asphalt concrete matrix was first prepared to improve resistance to moisture damage, fuel erosion, and ice adhesion, and its curing behavior and optimal dosage were determined. A skid-resistant surface layer was then designed by optimizing the anti-skid aggregate type, organosilicon-to-aggregate ratio, and surface texture. Finally, waterborne epoxy resin was introduced to enhance aggregate anchorage, and the integrated OES-AWC was evaluated in terms of abrasion durability, rutting resistance, long-term skid resistance, and life-cycle impacts. The results show that organosilicon treatment forms a hydrophobic siloxane network, which improves the moisture damage, fuel erosion, and anti-icing resistance of asphalt concrete by 22.0–41.1%. Emery aggregates and the optimized surface structure enhance friction stability, while waterborne epoxy resin significantly suppresses aggregate stripping under repeated wheel loading. Compared with conventional asphalt wearing courses, the optimized OES-AWC increased wear durability by 148.1% while maintaining stable skid resistance under prolonged abrasion. Life-cycle assessment further demonstrates that OES-AWC can reduce carbon emissions by 47.2% and overall costs by 25.0%, with a probability exceeding 90% according to the uncertainty analysis. These findings indicate that OES-AWC provides a durable, low-carbon, and cost-effective maintenance strategy for asphalt pavements exposed to complex service environments. Full article

Pisha sandstone (PS) is a weakly cemented soft rock widely distributed in the middle reaches of the Yellow River, China. PS disintegrates rapidly upon contact with water and has poor erosion resistance, making it a major source of coarse sediment in the Yellow River. However, PS is rich in aluminosilicate minerals and clay fractions, offering great potential as a sustainable precursor for geopolymer cementitious materials and as an amendment for degraded soils. The sustainable resource utilization of PS provides a new pathway for coordinated ecological and economic development in the PS areas. This paper first reviews the mineralogical and chemical characteristics of PS, clarifying that low diagenetic degree and high montmorillonite content cause poor erosion resistance, and that compound erosion from freeze–thaw, water, wind, and gravity erosion creates a superimposed amplification effect, which is the primary driver of severe soil erosion. Subsequently, three major control measures for soil erosion in the PS areas are summarized, namely biological measures using sea-buckthorn (Hippophae rhamnoides), chemical solidification, and microbially induced calcium carbonate precipitation (MICP), with analyses of their mechanisms, efficiency, and limitations. Furthermore, the research progress on the sustainable resource utilization of PS in the preparation of geopolymer cementitious materials and the amelioration of degraded soils is elaborated. Finally, future research directions are discussed to support the control of soil erosion and the green, sustainable resource utilization of PS. Full article

Geopolymer concrete contains inorganic aluminosilicate polymer gels formed through the activation of industrial solid wastes. This study investigated the effects of fly ash (FA) and silica fume (SF) on the durability and microstructure of geopolymer concrete exposed to freeze–thaw cycles and single-side salt erosion. Five mixtures were prepared using Baioheng geopolymer cement, with FA replacement levels of 15% and 25% and SF replacement levels of 3% and 5%. Mechanical tests, freeze–thaw tests, single-side salt-freezing tests, SEM-EDS, XRD, and CT analysis were conducted to evaluate the relationship between macroscopic performance and inorganic polymer gel structure. The results showed that 25% FA reduced compressive strength and freeze–thaw resistance, mainly due to insufficient reaction products and increased defect connectivity. In contrast, 3% SF improved the 56 d compressive strength by 13.24%, maintained the relative dynamic elastic modulus at 86.64% after 100 freeze–thaw cycles, and limited the mass loss to 0.72%. SEM-EDS and XRD results indicated that appropriate SF addition increased the Si/Al ratio and promoted the formation of C-(A)-S-H/N-A-S-H-related gel products, leading to a denser inorganic polymer matrix. However, excessive SF weakened the improvement effect, possibly due to local heterogeneity and dispersion difficulty. These results indicate that controlling the composition and spatial distribution of inorganic aluminosilicate polymer gels is essential for improving the salt-frost durability of geopolymer concrete. Full article

Traditional Chinese sticky rice–lime mortar, a key material for restoring historic masonry buildings, suffers significant degradation under combined salt erosion and freeze–thaw cycling. This study experimentally investigated the coupled effects of chloride, sulfate, and freeze–thaw action on sticky rice–lime mortar under simulated service conditions. Specimens prepared using traditional methods were subjected to freeze–thaw cycling in pure water, 5% Na₂SO₄ solution, 5% NaCl solution, and 5% NaCl + 5% Na₂SO₄ solution. Their mechanical properties, phase compositions, and pore structures were characterized through compressive, dynamic elastic modulus, X-ray diffraction (XRD), and mercury intrusion porosimetry (MIP) tests. After six freeze–thaw cycles, the relative dynamic elastic modulus (0.72, 0.58, 0.57, 0.55), mass loss (1.7%, 3.69%, 4.82%, 5.60%), and compressive strength loss (30.05%, 43.90%, 47.56%, 52.43%) progressively worsened from pure water to Na₂SO₄ to NaCl to compound salt conditions, indicating that under the same concentration, the deterioration induced by sodium chloride freeze–thaw is more severe than that caused by sodium sulfate, while the compound salt freeze–thaw condition leads to the most severe deterioration. Under compound salt freeze–thaw, the deterioration mechanisms include expansion due to gypsum formation, salt crystallization, ice formation, and the dissolution of cementitious phases driven by CaCl₂ attack. Furthermore, clear correlations are observed among the mass loss rate, compressive strength loss rate, and relative dynamic elastic modulus, as well as between the peak strain and secant modulus. These findings provide valuable insights for improving the durability of historic restoration mortars. Full article

Soil erosion in mountain environments is governed by the interaction of climatic drivers, surface conditions, and geomorphic connectivity. Recently, disturbance by large herbivores has been recognized as a potentially important but poorly quantified geomorphic driver. However, the combined effects of freeze–thaw processes and ungulate disturbance on sediment production remain unclear. This study provides quantitative field-based evidence linking deer activity to hillslope sediment flux in a montane forest catchment in central Japan. A six-year dataset (2019–2025), including climatic conditions, deer detections from camera traps, understory vegetation cover, and hillslope sediment flux (<9.5 mm) was analyzed. Multiple regression analysis was conducted using daily sediment flux as the response variable and maximum 1 h rainfall, freeze–thaw frequency, and daily deer detections as explanatory variables. The results showed that deer detections had a significant positive effect on sediment flux, whereas rainfall intensity and freeze–thaw frequency did not exhibit strong independent effects. Particle-size analysis further indicated that eroded sediment was markedly coarser than the surface soil, suggesting that short-term climatic drivers alone did not control sediment transport. These findings demonstrate that biotic disturbance by large herbivores can play a dominant role in hillslope sediment flux under cold, high-elevation conditions by modifying surface conditions and sediment connectivity. From a sustainability perspective, these results highlight the importance of managing deer populations to maintain ecosystem stability, prevent land degradation, and support sustainable forest and watershed management under changing environmental conditions. Full article

Alkali-activated solid waste-based geopolymer represents a novel form of inorganic cementitious material, which is one of the key research directions in the building materials field to achieve the targets of carbon peak and carbon neutrality. Therefore, taking solid waste materials as raw materials to prepare the alkali-activated solid waste-based geopolymers with better mechanical properties is of significant importance for expanding the utilization channels of industrial solid waste materials in Hebei Province. In this study, three solid waste materials, slag, iron tailings sand and coal gangue powder, were used as the precursors of geopolymer, and solid sodium silicate was used as the activator to prepare the solid waste-based geopolymer. Response surface methodology was adopted to design the composition of the geopolymer, and the dosages of slag, Na₂O and coal gangue powder were taken as design variables, and the compressive strength of the geopolymer at 7 days and 28 days were taken as response variables. The results show that it is feasible to optimize the composition of solid sodium silicate-activated solid waste-based geopolymer (SSG) by using response surface methodology. The error value of the SSG-mortar compressive strength prediction model is below 2.0%. The slag contents exhibit a positive correlation with the compressive strength of SSG-mortar, but the coal gangue powder contents and Na₂O contents have a negative correlation. The optimized compositions of SSG-mortar are 20% iron tailings sand, 26% coal gangue powder, 54% slag, and 6.41% Na₂O (regulated by 6.23% solid sodium silicate and 6.23% solid NaOH granules), and the corresponding compressive strengths of SSG-mortar at 7 days and 28 days are 37.1 MPa and 44.9 MPa, respectively. In addition, dry shrinkage tests, wet–dry cycling tests, freeze–thaw cycling tests, salt corrosion tests, SEM analysis and XRD analysis were conducted on the SSG-mortar with the optimal composition to evaluate its shrinkage behavior, freeze–thaw resistance, salt corrosion resistance and microstructural strengthening mechanisms. The results show that SSG-mortar has relatively good frost resistance and salt erosion resistance. The mass loss rate value and compressive strength loss rate value of SSG-mortar are 1.67% and 18.7%, respectively, after 100 freeze–thaw cycles. Furthermore, the corrosion resistance coefficient value of SSG-mortar is greater than 92%, and the mass loss rate value is lower than 2.4%. The SEM and XRD test results display that, in an alkaline environment, the interwoven consolidation of hydrated gels (including C-S-H gel, C-A-S-H gel, C-(N)-A-S-H gel and N-A-S-H gel) and the filling effect of solid wastes jointly achieve an improvement in the properties of SSG-mortar. Full article

This study investigated the enhancement mechanisms and optimal mix proportion of basalt fiber (BF) in concrete for ship lock galleries. It focused on improving crack resistance, freeze–thaw resistance, impermeability, and abrasion–erosion resistance under complex hydraulic environments. Single-factor tests first determined the reasonable parameter ranges, which were subsequently used in a three-factor, four-level orthogonal experiment to analyze the effects of the water-to-binder ratio, fiber content, and fiber length on concrete’s mechanical properties. Range analysis of the orthogonal experiment indicated that the water-to-binder ratio was the most dominant factor (R = 57.4), followed by fiber content. Based on this, further durability tests were conducted, including ring restraint cracking, impermeability, freeze–thaw resistance, and abrasion–erosion resistance. Multi-objective optimization was performed using full factorial experiments and a comprehensive performance evaluation system. The final optimal mix proportion was determined as: a water-to-binder ratio of 0.35, a fiber content of 0.2%, and a fiber length of 12 mm. With this mix, the concrete’s ring cracking time was extended by 69.9%, the relative dynamic elastic modulus retention reached 73.0% after 100 freeze–thaw cycles, the relative permeability coefficient was 1.04 × 10⁻⁶ cm/h, and the abrasion–erosion resistance strength increased to 7.05 h·m²/kg, which achieved an optimal synergy among the mechanical properties, key durability indicators, and their workability. Mechanism analysis revealed that BF formed a three-dimensional, randomly distributed fiber network that comprehensively enhanced concrete performance through multi-scale mechanisms, including bridging, pore refinement, and energy dissipation. This research has provided systematic experimental evidence and mix proportion support for the durability design and engineering application of BF concrete in ship lock galleries. Full article

To enhance the comprehensive performance and interfacial adhesion of conventional emulsified asphalt, an epoxy-functionalized waterborne polyurethane modified emulsified asphalt (EFPU-MEA) was developed using an epoxy-functionalized waterborne polyurethane (EFPU) emulsion and an isocyanate curing agent. Experimental evaluations show that the EFPU-MEA achieves a tensile strength of 1.11 ± 0.05 MPa and an elongation at break of 782.5 ± 45%, demonstrating a well-balanced flexibility and deformation resistance. The interfacial bond between EFPU-MEA and aggregates exhibited robust durability under various stressors, including thermal fluctuations, low-temperature cracking, chemical corrosion, and moisture damage. Quantitative “sandwich” pull-out and shear tests determined the optimal modifier content and spraying quantity to be 15–20% and 1.0 kg/m², respectively. Under these conditions, the system maintained high bond strength following severe freeze–thaw cycles and chemical erosion. Mechanistically, fluorescence microscopy (FM) confirmed a uniform dispersion of EFPU within the asphalt matrix, providing effective physical reinforcement. Furthermore, surface free energy (SFE) analysis and Fourier Transform Infrared (FTIR) spectroscopy revealed that internal chemical crosslinking restructures the binder’s surface thermodynamics, significantly increasing the surface polarity and adhesion work. Finally, road performance tests—including marshall stability, wet track abrasion, and rutting resistance—verified the engineering durability of the EFPU-MEA mixture. These findings provide a theoretical and practical basis for the use of EFPU-MEA in extending the service life of high-grade highway pavements. Full article

Against the backdrop of global warming, changes in the frequency and intensity of freeze–thaw cycles in cold regions profoundly impact soil physical structure. This review examines the mechanisms by which freeze–thaw cycles influence soil aggregate stability and pore structure evolution, focusing on revealing their synergistic evolution patterns. Results indicate that ice crystal growth during freeze–thaw processes directly disrupts soil cementation systems through expansion pressure and wedging effects, leading to aggregate disintegration and pore restructuring. This process is not unidirectional but forms a coupled feedback cycle of “ice crystal action–aggregate disintegration–pore restructuring.” Aggregate stability governs the initial pore restructuring, while the pore structure, in turn, influences aggregate stability by regulating water migration and colloidal dynamics. Responses of soil aggregates and pore structures to freeze–thaw cycles are comprehensively regulated by multiple factors, including soil physicochemical properties, freeze–thaw parameters, and anthropogenic disturbances. This synergistic evolution mechanism profoundly impacts soil water and heat transport, nutrient cycling, and erosion resistance. The paper also identifies current research gaps in regional coverage, cross-scale coupling, and in situ monitoring techniques. It envisions future efforts integrating multi-scale observations with intelligent technologies to deepen understanding of freeze–thaw-driven soil structure evolution mechanisms, thereby providing theoretical support for sustainable agriculture and ecological conservation in cold regions. Full article

Seasonal freeze–thaw cycles profoundly alter soil physical properties in cold-region agroecosystems, yet their effects on the mechanical behavior of the ice–soil interface remain poorly quantified. This interface plays a critical role in governing soil structural stability, detachment resistance, and subsequent erosion processes during thaw periods, particularly in the black soil region of Northeast China. In this study, controlled laboratory experiments were conducted to investigate the evolution of ice–soil interface mechanical properties under varying freeze–thaw conditions using cultivated black soils. Key parameters, including interface shear strength and bonding characteristics, were quantified across different freeze–thaw cycles. The results demonstrate that freeze–thaw action significantly weakens the mechanical integrity of the ice–soil interface, with pronounced reductions in shear strength observed after repeated cycles. This degradation is attributed to ice lens formation, pore structure disruption, and the redistribution of interfacial water films during freezing and thawing. Notably, the rate and magnitude of strength loss exhibit strong sensitivity to freeze–thaw frequency, highlighting the cumulative nature of freeze-induced damage at the interface scale. These findings provide mechanistic insights into how freeze–thaw processes modulate soil resistance to external forces during early thaw periods, offering an improved physical basis for understanding soil erosion vulnerability in cold agricultural regions. The results have direct implications for soil conservation strategies and erosion modeling under ongoing climate warming, which is expected to intensify freeze–thaw dynamics in seasonally frozen farmlands. Full article

To address the engineering challenge of durability deterioration in concrete structures in the cold and saline regions in northern China, this study investigated PVA fiber-reinforced concrete under combined sulfate attack and freeze–thaw cycles using PVA fiber volume fractions (0%, 0.1%, 0.3%, 0.5%) and salt-freeze cycles (0, 25, 50, 75, 100, 125, 150 cycles) as key variables. By testing the mechanical and microscopic properties of the specimens after salt-freeze, the degradation law of macroscopic performance and the evolution mechanism of microscopic structure of PVA fiber concrete under different volume fractions are analyzed, and the salt-freeze damage evolution equation is established based on the loss rate of relative dynamic elastic modulus. The results show that the addition of PVA fibers has no significant inhibitory effect on the surface erosion of concrete, and the degree of surface spalling of concrete still increases with the increase in the number of salt-freeze cycles. With the increase in the number of salt-freezing cycles, the mass, relative dynamic elastic modulus and cube compressive strength of the specimens first increase and then decrease, while the splitting tensile strength continuously decreases. The volume fraction of 0.3% PVA fibers has the most significant effect on improving the cube compressive strength and splitting tensile strength of concrete, and at the same time, it allows concrete to reach its best salt-freezing resistance. PVA fibers contribute to a denser microstructure, inhibit the development of micro-cracks, delay the formation of erosion products, and enhance the salt-freezing resistance of concrete. The damage degree D of relative dynamic elastic modulus for PVA fiber concrete exhibits a cubic functional relationship with the number of salt-freeze cycles N, and the correlation coefficient R² is greater than 0.88. The equation can accurately describe the damage and deterioration law of PVA fiber concrete in the salt-freeze coupling environment. In contrast to numerous studies on single-factor exposures, this work provides new insights into the degradation mechanisms and optimal fiber dose for PVA fiber concrete under the synergistic effect of combined sulfate and freeze-thaw attacks, a critical scenario for infrastructure in cold saline regions. This study can provide theoretical guidance for the durability assessment and engineering application of PVA fiber concrete in cold and saline regions. Full article

This study focuses on the core issue of sustainably utilizing shells to enhance the performance of cement mortar. The influence of shell powder on the slump flow, setting time, mechanical strengths, drying shrinkage rate and carbonation depth of cement mortar is investigated. The flexural and compressive strengths of cement mortar incorporating calcium formate after 12 h, 3-day and 28-day curing periods are examined. The effect of basalt fibers on the attenuation of cement mortar’s mechanical properties (flexural and compressive strengths) after NaCl freeze–thaw cycles is also studied. Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) is employed to elucidate the underlying mechanisms. Results show that the slump flow, setting time and mechanical strengths have cubic function relationships with the shell powder’s mass ratio, while the drying shrinkage rate and carbonation depth follow quadratic function changes. Cement mortar with 15% shell powder by mass of the total binder materials demonstrates the highest slump flow and mechanical strengths. At this shell powder mass ratio, cement mortar shows the lowest drying shrinkage rate and carbonation depth. Calcium formate positively influences the 12-h mechanical strengths. After 3 days of curing, the mechanical strengths of cement mortar with 0.3% calcium formate are the highest. The calcium carbonate powder reduces the drying shrinkage rate of mortar and increases the content of Ca and C elements. The mass ratio of calcium formate exhibits a negative correlation with the cement mortar’s mechanical strengths after being cured for 28 days. The addition of basalt fibers enhances resistance to chloride salt freeze–thaw and dry-wet alternations erosion performance. These findings will provide a sustainable and effective strategy for utilizing agricultural by-products in concrete structures. Full article