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Search Results (221)

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Keywords = fouling behavior

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20 pages, 3043 KB  
Article
Experimental Study on Element Release and Conversion of High-Alkali Coal via Fluidized Preheating
by Shengbo Jia, Jianguo Zhu, Meiheriayi Mutailipu, Yu Huang, Jingzhang Liu and Qinggang Lyu
Energies 2026, 19(3), 691; https://doi.org/10.3390/en19030691 - 28 Jan 2026
Abstract
The Zhundong coalfield in Xinjiang contains vast reserves and is a crucial source of thermal coal. However, the Zhundong coal has a high content of alkali and alkaline earth metals, which makes it prone to ash deposition and slagging in boilers, thereby limiting [...] Read more.
The Zhundong coalfield in Xinjiang contains vast reserves and is a crucial source of thermal coal. However, the Zhundong coal has a high content of alkali and alkaline earth metals, which makes it prone to ash deposition and slagging in boilers, thereby limiting its large-scale utilization. Fluidized-bed preheating is an emerging clean combustion technology that can reduce the slagging and fouling risks associated with high-alkali coal by modifying its fuel properties. This study employs circulating fluidized-bed preheating technology to treat high-alkali coal, with a focus on investigating the effect of the preheated air equivalence ratio on fuel preheating modification. Through microscopic characterization of both the raw coal and preheated char, the release and transformation behaviors of elements and substances during the preheating process are revealed. The results demonstrate that fluidized preheating promotes alkali metal precipitation, and increasing the preheated air equivalence ratio (λPr) enhances gas production and elemental release, with a volatile fraction mass conversion of up to 84.57%. As the λPr value increased from 0.28 to 0.40, the average temperature in the preheater riser increased from 904 °C to 968 °C. Compared to the raw coal, the specific surface area of the preheated char was enhanced by a factor of 3.6 to 9.1 times, with a more developed pore structure and less graphitization, thus enhancing the surface reactivity of the preheated char. The increase in λPr also facilitated the conversion from pyrrolic nitrogen to pyridinic nitrogen, thus improving combustion performance and facilitating subsequent nitrogen removal. These findings provide essential data support for advancing the understanding of preheating characteristics in high-alkali coal and for promoting the development of efficient and clean combustion technologies tailored for high-alkali coal. Full article
(This article belongs to the Special Issue Optimization of Efficient Clean Combustion Technology: 2nd Edition)
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46 pages, 20947 KB  
Review
Bioinspired Heat Exchangers: A Multi-Scale Review of Thermo-Hydraulic Performance Enhancement
by Hyunsik Yang, Jinhyun Pi, Soyoon Park and Wongyu Bae
Biomimetics 2026, 11(1), 76; https://doi.org/10.3390/biomimetics11010076 - 16 Jan 2026
Viewed by 205
Abstract
Heat exchangers are central to energy and process industries, yet performance is bounded by the trade-off between higher heat transfer and greater pressure drop. This review targets indirect-type heat exchangers and organizes bioinspired strategies through a multi-scale lens of surface, texture, and network [...] Read more.
Heat exchangers are central to energy and process industries, yet performance is bounded by the trade-off between higher heat transfer and greater pressure drop. This review targets indirect-type heat exchangers and organizes bioinspired strategies through a multi-scale lens of surface, texture, and network scales. It provides a structured comparison of their thermo-hydraulic behaviors and evaluation methods. At the surface scale, control of wettability and liquid-infused interfaces suppresses icing and fouling and stabilizes condensation. At the texture scale, microstructures inspired by shark skin and fish scales regulate near-wall vortices to balance drag reduction with heat-transfer enhancement. At the network scale, branched and bicontinuous pathways inspired by leaf veins, lung architectures, and triply periodic minimal surfaces promote uniform distribution and mixing, improving overall performance. The survey highlights practical needs for manufacturing readiness, durability, scale-up, and validation across operating ranges. By emphasizing analysis across scales rather than reliance on a single metric, the review distills design principles and selection guidelines for next-generation bioinspired heat exchangers. Full article
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34 pages, 2207 KB  
Article
Neuro-Symbolic Verification for Preventing LLM Hallucinations in Process Control
by Boris Galitsky and Alexander Rybalov
Processes 2026, 14(2), 322; https://doi.org/10.3390/pr14020322 - 16 Jan 2026
Viewed by 289
Abstract
Large Language Models (LLMs) are increasingly used in industrial monitoring and decision support, yet they remain prone to process-control hallucinations—diagnoses and explanations that sound plausible but conflict with physical constraints, sensor data, or plant dynamics. This paper investigates hallucination as a failure of [...] Read more.
Large Language Models (LLMs) are increasingly used in industrial monitoring and decision support, yet they remain prone to process-control hallucinations—diagnoses and explanations that sound plausible but conflict with physical constraints, sensor data, or plant dynamics. This paper investigates hallucination as a failure of abductive reasoning, where missing premises, weak mechanistic support, or counter-evidence lead an LLM to propose incorrect causal narratives for faults such as pump restriction, valve stiction, fouling, or reactor runaway. We develop a neuro-symbolic framework in which Abductive Logic Programming (ALP) evaluates the coherence of model-generated explanations, counter-abduction generates rival hypotheses that test whether the explanation can be defeated, and Discourse-weighted ALP (D-ALP) incorporates nucleus–satellite structure from operator notes and alarm logs to weight competing explanations. Using our 500-scenario Process-Control Hallucination Dataset, we assess LLM reasoning across mechanistic, evidential, and contrastive dimensions. Results show that abductive and counter-abductive operators substantially reduce explanation-level hallucinations and improve alignment with physical process behavior, particularly in “easy-but-wrong’’ cases where a superficially attractive explanation contradicts historian trends or counter-evidence. These findings demonstrate that abductive reasoning provides a practical and verifiable foundation for improving LLM reliability in safety-critical process-control environments. Full article
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17 pages, 5230 KB  
Article
Experimental and Numerical Investigation of Hydrodynamic Characteristics of Aquaculture Nets: The Critical Role of Solidity Ratio in Biofouling Assessment
by Wei Liu, Lei Wang, Yongli Liu, Yuyan Li, Guangrui Qi and Dawen Mao
Computation 2026, 14(1), 4; https://doi.org/10.3390/computation14010004 - 30 Dec 2025
Viewed by 253
Abstract
Biofouling on aquaculture netting increases hydrodynamic drag and restricts water exchange across net cages. The solidity ratio is introduced as a quantitative parameter to characterize fouling severity. Towing tank experiments and computational fluid dynamics (CFD) simulations were used to assess the hydrodynamic behavior [...] Read more.
Biofouling on aquaculture netting increases hydrodynamic drag and restricts water exchange across net cages. The solidity ratio is introduced as a quantitative parameter to characterize fouling severity. Towing tank experiments and computational fluid dynamics (CFD) simulations were used to assess the hydrodynamic behavior of netting under different fouling conditions. Experimental results indicated a nonlinear increase in drag force with increasing solidity. At a flow velocity of 0.90 m/s, the drag force increased by 112.2%, 195.1%, and 295.7% for netting with solidity ratios of 0.445, 0.733, and 0.787, respectively, compared to clean netting (Sn = 0.211). The drag coefficient remained stable within 1.445–1.573 across Re of 995–2189. Numerical simulations demonstrated the evolution of flow fields around netting, including jet flow formation in mesh openings and reverse flow regions and vortex structures behind knots. Under high solidity (Sn = 0.733–0.787), complex wake patterns such as dual-peak vortex streets appeared. Therefore, this study confirmed that the solidity ratio is an effective comprehensive parameter for evaluating biofouling effects, providing a theoretical basis for antifouling design and cleaning strategy development for aquaculture cages. Full article
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31 pages, 8440 KB  
Article
Parametric Characterization and Multi-Objective Optimization of Low-Pressure Abrasive Water Jets for Biofouling Removal from Net Cages Using Response Surface Methodology and the Entropy Method
by Yingjie Wu, Yongqiang Tu, Bin Deng, Hui Li, Guohong Xiao and Hu Chen
Sustainability 2026, 18(1), 215; https://doi.org/10.3390/su18010215 - 24 Dec 2025
Viewed by 273
Abstract
Deep-sea cages are highly susceptible to biofouling due to long-term seawater immersion, which promotes the attachment and growth of marine organisms on nets, significantly reducing fish survival. To address this issue, this study explores the use of low-pressure abrasive water jets (LPAWJs) for [...] Read more.
Deep-sea cages are highly susceptible to biofouling due to long-term seawater immersion, which promotes the attachment and growth of marine organisms on nets, significantly reducing fish survival. To address this issue, this study explores the use of low-pressure abrasive water jets (LPAWJs) for cage fouling removal through numerical simulation. Based on a Box-Behnken response surface design, nozzle inlet pressure X1, nozzle outlet diameter X2, and target distance X3 were selected as optimization parameters. The peak jet impact force Z1, stable jet impact force Z2, peak abrasive water jet velocity Z3, and peak abrasive particle velocity Z4 were chosen as evaluation indicators to characterize the jet’s instantaneous impact ability, sustained action ability, and dynamic particle behavior. Using the entropy method, weights for each indicator were determined, and the jet’s overall removal capability was calculated. A regression model was developed by integrating numerical simulation with the response surface methodology (RSM), and the optimal parameter combination was identified as X1 = 4.5 MPa, X2 = 10 mm, and X3 = 205.396 mm. Compared with the poorest experimental condition (Condition 1), the jet’s overall removal capability obtained under the optimal parameter combination increases by 101.35%. Experimental validation further confirms that the optimized parameters yield the best oyster-removal performance of the low-pressure abrasive jet, with the average removal rate improving by 100.55% relative to Condition 1. The methodology and results of this study provide a theoretical foundation and technical reference for the design and optimization of automated net-cleaning systems or net-cleaning robots equipped with low-pressure abrasive jets. By integrating the proposed model and operating parameters, future robotic systems will be able to predict and dynamically adjust jet conditions according to fouling characteristics, thereby improving the efficiency, cost-effectiveness, and sustainability of maintenance operations in marine aquaculture. Full article
(This article belongs to the Section Sustainable Oceans)
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18 pages, 11223 KB  
Article
Water Purification Efficiency and Membrane Fouling Behavior of Ceramic Membrane-Nanofiltration in Treating Water Treatment Plant Production Wastewater
by Yawei Xie, Zewei Liu, Jiayi Yu, Zizhang Shan, Hongyuan Liu and Yan Zhang
Membranes 2025, 15(12), 387; https://doi.org/10.3390/membranes15120387 - 18 Dec 2025
Viewed by 636
Abstract
To mitigate the risks associated with production wastewater from water treatment plants, this study evaluated the effectiveness of nanofiltration (NF) and a hybrid ceramic membrane–nanofiltration (CM–NF) process in removing natural organic matter (NOM) and Ca2+. A comprehensive analysis of changes in [...] Read more.
To mitigate the risks associated with production wastewater from water treatment plants, this study evaluated the effectiveness of nanofiltration (NF) and a hybrid ceramic membrane–nanofiltration (CM–NF) process in removing natural organic matter (NOM) and Ca2+. A comprehensive analysis of changes in specific flux and fouling resistance of the NF membrane, combined with scanning electron microscopy (SEM) observations, provided deeper insight into membrane fouling behavior. The results show that the CM–NF process achieved average removal rates of 95.60% for DOC, 98.55% for UV254, 34.50% for conductivity, and 50.71% for Ca2+. These values represent improvements of 4.70%, 1.40%, 16.37%, and 10.36%, respectively, compared to the standalone NF process. Furthermore, CM pretreatment consistently optimized the performance of the nanofiltration system. After continuous operation, the average specific membrane flux of the CM–NF system reached 0.715, 0.67, and 0.61 under varying pollutant concentrations—increases of 10.9%, 19.6%, and 17.3% over the standalone NF system—confirming a significant improvement in permeate flux. Under continuous operation, the average degree of irreversible fouling was markedly reduced across different pollutant concentrations—decreasing from 9.2%, 17.6%, and 23.6% for the standalone NF system to 8.9%, 15.6%, and 10.9% for the CM–NF system, which clearly demonstrates the efficacy of CM pretreatment in controlling irreversible fouling. SEM observations further corroborated that CM pretreatment effectively alleviated fouling on the NF membrane surface. Additionally, higher Ca2+ concentrations were found to contribute to reduced membrane fouling and enhance flux performance. Full article
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19 pages, 1439 KB  
Article
Awareness, Cultural Beliefs, and Health-Seeking Behavior of Females in Cancer Screening: A Pilot Study in Rural South Africa
by Olufunmilayo Olukemi Akapo, Mojisola Clara Hosu and Mirabel Kah-Keh Nanjoh
Epidemiologia 2025, 6(4), 90; https://doi.org/10.3390/epidemiologia6040090 - 10 Dec 2025
Viewed by 490
Abstract
Background/Objectives: Cervical cancer is one of the most common cancers among women of reproductive age, with 80% of the cases occurring in developing countries. Cervical cancer is largely preventable by effective screening programs. This study assessed the knowledge, attitudes, cultural beliefs, and screening [...] Read more.
Background/Objectives: Cervical cancer is one of the most common cancers among women of reproductive age, with 80% of the cases occurring in developing countries. Cervical cancer is largely preventable by effective screening programs. This study assessed the knowledge, attitudes, cultural beliefs, and screening practices related to cervical cancer among women in the rural community of Lutubeni, Eastern Cape Province. Methods: A descriptive cross-sectional study was conducted among 95 women aged 25 years or older attending Lutubeni Clinic. Data was collected using a structured, validated questionnaire covering demographics, reproductive health, knowledge of cervical cancer, attitudes, cultural perceptions, and screening practices. Statistical analysis involved descriptive summaries, chi-square tests, and binary logistic regression. Results: Most participants exhibited poor knowledge of cervical cancer symptoms (47.4%) and risk factors (61.1%), with only 3.2% demonstrating good overall knowledge. Vaginal bleeding (60.0%) and foul-smelling discharge (50.5%) were the most recognized symptoms. Only 40.0% were aware of human papillomavirus (HPV) vaccination. While 87.4% knew about cervical cancer screening, only 55.8% had ever been screened. Of these, 43.2% had screened only once, primarily at the clinic (33.7%), mostly initiated by health professionals (41.1%). Positive attitudes toward screening were observed in 52.6%, while 88.4% held cultural beliefs that hindered open discussion about sexual health. Statistically significant factors associated with screening uptake included educational level (p = 0.047), knowledge of symptoms (p = 0.04), risk factors (p < 0.0001), prevention (p < 0.0001), treatment (p = 0.001), and attitudes (p < 0.0001). Independent predictors of poor screening practice were holding an associate degree (OR = 0.04, p = 0.042), having good preventive knowledge (OR = 0.02, p = 0.012), and having negative attitudes (OR = 36.22, p = 0.005). Conclusions: High awareness alone does not guarantee participation in cervical cancer screening in rural South Africa. Interventions must address cultural barriers, stigma, and negative perceptions while strengthening health education that links HPV vaccination with screening awareness. The unexpected association between associate degree attainment and poor screening underscores the complexity of behavioral determinants and warrants further investigation in larger cohorts. Full article
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17 pages, 2370 KB  
Article
Study on Specific Energy Consumption of Rotating Dynamic Filtration for Ship EGC Desulfurization Wastewater Treatment
by Shiyong Wang, Baohua Yang, Juan Wu, Yanlin Wu and Wenbo Dong
Membranes 2025, 15(12), 378; https://doi.org/10.3390/membranes15120378 - 9 Dec 2025
Viewed by 449
Abstract
In recent decades, rotating dynamic filtration (RDF) has attracted considerable attention due to its high efficiency and low energy consumption. While most studies have focused on separation behavior and membrane fouling, energy consumption in RDF has received limited attention. This study investigates the [...] Read more.
In recent decades, rotating dynamic filtration (RDF) has attracted considerable attention due to its high efficiency and low energy consumption. While most studies have focused on separation behavior and membrane fouling, energy consumption in RDF has received limited attention. This study investigates the specific energy consumption (SEC) of the RDF process for ship exhaust gas cleaning (EGC) desulfurization wastewater treatment and proposes an optimization method based on both energy consumption and equipment cost. The total SEC increases with rotational velocity, circulation flow, feed concentration, and membrane size but decreases with temperature and remains unaffected by the number of membrane elements. In RDF, the total SEC is only 9.05–19.29% of that in tubular cross-flow filtration (CFF) at equivalent shear force ranging from 3.86 Pa to 121.14 Pa. Operating energy and investment costs are primarily determined by the number of membrane elements and the rotational velocity. According to the economic analysis, the lowest treatment cost for EGC wastewater is CNY 6.09 per cubic meter for a 5 m3·h−1 capacity, using 84 membrane elements (374 mm, 0.2 µm) at a rotational velocity of 200 rpm, an operating pressure of 200 kPa, and a temperature of 40 °C. Full article
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11 pages, 619 KB  
Article
Liquid Droplet Breakup Mechanisms During the Aero-Engine Compressor Washing Process
by Nicola Zanini, Alessio Suman, Andrea Cordone, Mattia Piovan, Michele Pinelli, Stefan Kuntzagk, Henrik Weiler and Christian Werner-Spatz
Int. J. Turbomach. Propuls. Power 2025, 10(4), 50; https://doi.org/10.3390/ijtpp10040050 - 2 Dec 2025
Viewed by 359
Abstract
The study of the dynamics during droplet breakup is fascinating to engineers. Some industrial applications include fire extinguishing by sprinkler systems, painting of various components, washing processes, and fuel spraying in internal combustion engines, which involve the interaction between liquid droplets, gaseous flow [...] Read more.
The study of the dynamics during droplet breakup is fascinating to engineers. Some industrial applications include fire extinguishing by sprinkler systems, painting of various components, washing processes, and fuel spraying in internal combustion engines, which involve the interaction between liquid droplets, gaseous flow field, and walls. In this work, washing operations effectiveness of civil aviation aircraft engines is analyzed. Periodic washing operations are necessary to slow down the effects of particle deposition, e.g., gas turbine fouling, to reduce the specific fuel consumption and the environmental impact of the gas turbine operation. This analysis describes the dynamics in the primary breakup, related to the breakup of droplets due to aerodynamic forces, which occur when the droplets are set in motion in a fluid domain. The secondary breakup is also considered, which more generally refers to the impact of droplets on surfaces. The latter is studied with particular attention to dry surfaces, investigating the limits for different breakup regimes and how these limits change when the impact occurs with surfaces characterized by different wettability. Surfaces with different roughness are also compared. All the tested cases are referred to surfaces at ambient temperature. Dimensionless numbers generalize the analysis to describe the droplet behavior. The analysis is based on several data reported in the open literature, demonstrating how different washing operations involve different droplet breakup regimes, generating a non-trivial data interpretation. Impact dynamics, droplet characteristics, and erosion issues are analyzed, showing differences and similarities between the literature data proposed in the last twenty years. Washing operation and the effects of gas turbine fouling on the aero-engine performance are still under investigation, demonstrating how experiments and numerical simulations are needed to tackle this detrimental issue. Full article
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23 pages, 5008 KB  
Article
Analysis of Fouling in Hollow Fiber Membrane Distillation Modules for Desalination Brine Reduction
by Hyeongrak Cho, Seoyeon Lee, Yongjun Choi, Sangho Lee and Seung-Hyun Kim
Membranes 2025, 15(12), 371; https://doi.org/10.3390/membranes15120371 - 2 Dec 2025
Viewed by 643
Abstract
Membrane distillation (MD) is a promising technology for reducing the volume of high-salinity brines generated from desalination plants, yet limited knowledge exists regarding its fouling behavior under long-term operation. In this study, fouling was investigated through the autopsy of a hollow fiber MD [...] Read more.
Membrane distillation (MD) is a promising technology for reducing the volume of high-salinity brines generated from desalination plants, yet limited knowledge exists regarding its fouling behavior under long-term operation. In this study, fouling was investigated through the autopsy of a hollow fiber MD module operated for 120 days in a direct contact membrane distillation (DCMD) configuration using real desalination brine. Despite stable salt rejection exceeding 99%, a gradual decline in flux and permeability was observed, indicating progressive fouling and partial wetting. Post-operation analyses, including SEM, EDS, ICP-OES, and FT-IR, revealed that the dominant foulants were inorganic scales, particularly calcium carbonate (CaCO3), with minor contributions from suspended particles (SiO2, Fe) and organic matter. Fouling was more severe in the inlet and inner regions of the module due to intensified temperature and concentration polarization, which promoted supersaturation and scale deposition. These combined effects led to a reduction in membrane hydrophobicity and liquid entry pressure, ultimately accelerating partial wetting and performance deterioration. The findings provide valuable insights into the spatial fouling behavior and mechanisms in MD systems, highlighting the importance of hydrodynamic optimization and fouling mitigation strategies for long-term brine concentration applications. Full article
(This article belongs to the Special Issue Membrane Distillation: Module Design and Application Performance)
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19 pages, 3214 KB  
Article
Numerical Investigations of Water-Lubricated Core Annular Flow (CAF) for Heavy Oil Transportation
by Salim Al Jadidi, Dadapeer Doddamani, Yahya Ubaid Al Shamsi, Ibrahim Nasser Al Siyabi and Siva Subramanian
Computation 2025, 13(12), 280; https://doi.org/10.3390/computation13120280 - 1 Dec 2025
Viewed by 416
Abstract
This study examines the flow behavior of water-lubricated heavy oil transport utilizing the core annular flow (CAF) technique. The goal is to enhance efficiency and minimize risks in pipeline operations. The flow was numerically simulated in a horizontal pipe using a Large Eddy [...] Read more.
This study examines the flow behavior of water-lubricated heavy oil transport utilizing the core annular flow (CAF) technique. The goal is to enhance efficiency and minimize risks in pipeline operations. The flow was numerically simulated in a horizontal pipe using a Large Eddy Simulation (LES) model within a commercial Computational Fluid Dynamics (CFD) framework. The Geo Reconstruct scheme is employed to accurately capture the oil–water interface, and both oil and water initialization methods were assessed against experimental data. Results show that the LES model accurately reproduces the main flow features observed experimentally, particularly for low-viscosity oil–water systems. This suggests that the model can be a reliable tool for predicting flow behaviour in similar fluid systems. Further validation with varying parameters could enhance its applicability across a broader range of conditions. In cases of heavy oil, the velocity profile remains nearly constant within the oil core, indicating rigid body-like motion surrounded by a turbulent water annulus. Turbulence intensity and oil volume fraction distributions were closely related, with higher turbulence in water and lower in oil. Although wall adhesion modelling limited fouling prediction, simulations confirmed that fouling can significantly increase pressure losses. This illustrates the value of considering both fluid dynamics and material interactions in such systems. Future studies could explore the impact of varying temperature and pressure conditions on fouling behaviour to further refine predictive models. Overall, the LES approach proved suitable for analysing turbulent CAF, offering insights for optimizing viscosity ratios, flow rates, and design parameters for safer and more efficient heavy oil transport. Full article
(This article belongs to the Special Issue Advances in Computational Methods for Fluid Flow)
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16 pages, 1949 KB  
Article
Batch-Process Approach to Osmotic Power Generation: Modeling and Performance Assessment
by Daniel Ruiz-Navas, Edgar Quiñones-Bolaños and Mostafa H. Sharqawy
Processes 2025, 13(11), 3410; https://doi.org/10.3390/pr13113410 - 24 Oct 2025
Viewed by 678
Abstract
This paper presents a novel batch Forward Osmosis (FO) process for hydropower generation. It focuses on analyzing the parameters needed to make the proposed osmotic power plant implementable with currently available technology. Starting from the solution–diffusion model and using flow and mass balance [...] Read more.
This paper presents a novel batch Forward Osmosis (FO) process for hydropower generation. It focuses on analyzing the parameters needed to make the proposed osmotic power plant implementable with currently available technology. Starting from the solution–diffusion model and using flow and mass balance equations, the equations that describe the behavior of the system over time are obtained. Membrane orientation, concentration polarization, reverse solute flux, and membrane fouling are not considered. The equations for calculating the operation time for the charging and discharging stages are obtained. Also, an equation for calculating the required membrane area to make the duration of the two stages the same is obtained. The results indicate that a volume of approximately 30.4 m3 discharging through a 0.84 inch diameter outflow jet towards a turbine could generate an energy of 25 kw·h. The discharging stage would take 12 h, and with a membrane with a water permeability constant Am=1.763·1012 m/(s·Pa), the charging stage would require a membrane superficial area Arm=1·104 m2 to have the same duration. The proposed osmotic power plant, whose working principle is based on volume change over time, contrary to pressure retarded osmosis, whose working principle requires expending energy to extract energy from the salinity gradient, could deliver greater net produced energy with comparatively lower operational costs as it does not require high-pressure pumps or energy recovery devices as are required in pressure-retarded osmosis. The use of several tanks that charge and discharge alternatively can make the system generate energy as if it were a continuous process. Full article
(This article belongs to the Section Energy Systems)
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16 pages, 2875 KB  
Article
Clarification of Copper Sulfide Precipitates by Polymeric Microfiltration Membranes
by Michelle Quilaqueo, Nicolás Barraza, Lorena Barros, Karla Pérez, René Ruby-Figueroa, Elizabeth Troncoso and Humberto Estay
Processes 2025, 13(10), 3292; https://doi.org/10.3390/pr13103292 - 15 Oct 2025
Viewed by 669
Abstract
The recovery of copper from metallurgical effluents is critical for advancing sustainable mining and circular economy practices. This study evaluated a hybrid process combining copper sulfide precipitation with clarification using polymeric polyvinylidene fluoride (PVDF) microfiltration membranes. Laboratory-scale experiments were performed under controlled cyanide [...] Read more.
The recovery of copper from metallurgical effluents is critical for advancing sustainable mining and circular economy practices. This study evaluated a hybrid process combining copper sulfide precipitation with clarification using polymeric polyvinylidene fluoride (PVDF) microfiltration membranes. Laboratory-scale experiments were performed under controlled cyanide conditions (100 mg/L free CN, 1800 mg/L Cu2+), focusing on permeate flux behavior, fouling mechanisms, and cleaning strategies. Optimal performance was achieved at moderate transmembrane pressures (<2.0 bar) and higher flow rates, which provided a balance between productivity and fouling control. Flux decline was attributed to a combination of pore blocking and cake layer formation, confirming the multifactorial nature of fouling dynamics. Cleaning tests revealed that oxidizing solutions (HCl + H2O2) restored up to 96% of the initial permeability, while combined treatments with NaCN achieved complete recovery (>100%), albeit with potential risks of membrane aging under prolonged exposure. A techno-economic assessment comparing polymeric and ceramic membranes revealed similar capital and operational costs, with polymeric membranes offering slight reductions in CAPEX (10%) and OPEX (2.3%). Overall, the findings demonstrate the technical feasibility and economic competitiveness of polymeric membranes for copper sulfide clarification, while emphasizing the need to improve long-term chemical resistance to ensure reliable industrial-scale implementation. Full article
(This article belongs to the Section Separation Processes)
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13 pages, 2521 KB  
Article
Evaluation of the Relationship Between Straw Fouling Tendencies and Fuel Indices in CFB
by Rafał Rajczyk and Tomasz Idziak
Appl. Sci. 2025, 15(19), 10558; https://doi.org/10.3390/app151910558 - 29 Sep 2025
Viewed by 477
Abstract
Biomass combustion for the production of electricity and heat remains one of the most widespread renewable energy technologies. Biomass is commonly utilized in fluidized bed combustion systems. Over the years, numerous issues related to the preparation and combustion of biomass in fluidized beds [...] Read more.
Biomass combustion for the production of electricity and heat remains one of the most widespread renewable energy technologies. Biomass is commonly utilized in fluidized bed combustion systems. Over the years, numerous issues related to the preparation and combustion of biomass in fluidized beds have been identified, including fouling and slagging, which involve the formation of deposits. These phenomena can be mitigated through various methods, including design modifications to boilers, the application of additives, and the careful selection and classification of fuel. Several fuel indices have been proposed to predict the behavior of fuels in terms of their tendency to cause fouling and slagging. Most of these indices were developed for fossil fuels, and the discrepancies between them suggest that although these indices are widely applied, their applicability to agricultural residues, such as straw, remains uncertain. Researchers working in this field emphasize the need for further research, particularly focusing on the comparison of developed indices with the results of biomass combustion at both laboratory and industrial scales. In this study, ten assortments of straw sourced from Poland were selected, and chemical composition analyses were conducted to determine selected fuel indices. The analyzed straw samples were then combusted in a 100 kWₜₕ laboratory-scale circulating fluidized bed unit. Using a specialized austenitic steel probe, the growth rate of the deposit was measured. The collected deposit masses for each straw type were then compared with the calculated fuel indices. The best correlation between the interpretation of the index values and the deposit mass on the probe was observed for the Rs index. However, due to the low sulfur content of straw, Rs numerical interpretation was not adequate. Overall, the indices indicating both good correlation coefficients and an appropriate numerical interpretation for fouling tendency were B/A, Fu, and Cl. Full article
(This article belongs to the Special Issue Novel Advances of Combustion and Its Emissions)
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17 pages, 6943 KB  
Article
Flux and Fouling Behavior of Graphene Oxide-Polyphenylsulfone Ultrafiltration Membranes Incorporating ZIF-67/ZIF-8 Fillers
by Azile Nqombolo, Thollwana Andretta Makhetha, Richard Motlhaletsi Moutloali and Philiswa Nosizo Nomngongo
Membranes 2025, 15(10), 289; https://doi.org/10.3390/membranes15100289 - 25 Sep 2025
Cited by 1 | Viewed by 1014
Abstract
Wider adoption of membrane technology is hindered by fouling and flux/rejection challenges. Recent practice in mitigating these is to incorporate hydrophilic and porous fillers. Herein the addition of hydrophilic graphene oxide (GO) in conjunction with porous mixed ZIFs (ZIF-67/ZIF-8) crystallites were used as [...] Read more.
Wider adoption of membrane technology is hindered by fouling and flux/rejection challenges. Recent practice in mitigating these is to incorporate hydrophilic and porous fillers. Herein the addition of hydrophilic graphene oxide (GO) in conjunction with porous mixed ZIFs (ZIF-67/ZIF-8) crystallites were used as inorganic fillers in the preparation of polyphenylenesulfone (PPSU) ultrafiltration (UF) membranes. The morphology of the resultant composite membranes was assessed using atomic force microscopy (AFM) and scanning electron microscopy (SEM) whilst surface hydrophilicity through water contact angle. The pure water flux (PWF) and membrane permeability were found to increase with increasing filler content. This was attributed to the combined hydrophilicity of GO and porous structure of the ZIF materials because of increasing alternative water pathways in the membrane matrix with increasing filler content. Furthermore, the increase in the ZIF component led to increasing bovine serum albumin (BSA) fouling resistance as demonstrated by increasing fouling recovery ratio (FRR). The dye rejection was due to a combination of electrostatic interaction between the fillers and the dyes as well as size exclusion. The chemical interactions between the ZIFs and the dyes resulted in slightly different rejection profiles for the smaller dyes, the cationic methylene blue being rejected less efficiently than the anionic methyl orange, potentially leading to their separation. The larger anionic dye, Congo red was rejected predominately through size exclusion. Full article
(This article belongs to the Special Issue Design, Preparation and Application of Nanocomposite Membranes)
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