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Keywords = fluid geochemistry

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25 pages, 16803 KB  
Article
Characteristics and Sources of Ore-Forming Fluids in the Hailijin Uranium Deposit, Songliao Basin
by Ziying Li, Mingming Tian, Menghua Li, Junxian Wang, Jun Ning, Jianfang Cai and Linfei Qiu
Geosciences 2026, 16(8), 301; https://doi.org/10.3390/geosciences16080301 - 28 Jul 2026
Viewed by 219
Abstract
The Hailijin uranium (U) deposit is one of the super-large U-deposits recently discovered in the Qianjiadian ore field, southwestern Songliao Basin. The ore bodies are mainly hosted in the lower member sandstones of the Upper Cretaceous Yaojia Formation and occur as multilayered tabular [...] Read more.
The Hailijin uranium (U) deposit is one of the super-large U-deposits recently discovered in the Qianjiadian ore field, southwestern Songliao Basin. The ore bodies are mainly hosted in the lower member sandstones of the Upper Cretaceous Yaojia Formation and occur as multilayered tabular bodies. The nature and source of the ore-forming fluids remain unclear, limiting the understanding of the genetic type of the deposit. This study integrated drill-core observation, mineralogy, whole-rock geochemistry, in situ pyrite trace elements and sulfur isotopes, fluid-inclusion, and Raman spectroscopy to constrain ore-forming fluids. The host sandstones experienced hematitization, limonitization, carbonate cementation, clay alteration, sulfidation and bleaching. Pitchblende and coffinite occur as submicron grains in dissolution pores of quartz and feldspar, on clay-mineral surfaces and within mobile organic matter (OM), commonly associated with pyrite and sphalerite. The ores and gray mineralized sandstones are enriched in U, Mo, Re, Co, Ni, Zn and Pb, and syn-ore pyrite shows positive correlations between U and As, Mo, Cu, Zn, Se and Sb. Mineralization-related fluid-inclusion assemblages occur mainly in syn-ore dolomite/ankerite cements and in secondary trails along microfractures in detrital quartz; they yield homogenization temperatures of 130–190 °C and salinities of 3–8 wt.% NaCl eq., higher than the normal burial temperature of the basin (80–90 °C), especially meteoric fluid. Raman and gas-chromatographic analyses indicate carbonaceous matter, CH4, CO2, H2 and minor O2. Pyrite δ34S values of −49.24‰ to −23.1‰ indicate isotopically light reduced sulfur ultimately related to microbial sulfate reduction and/or thermal decomposition of sulfur-bearing OM, whereas thermochemical sulfate reduction was unlikely to be dominant. Therefore, the ore-forming fluid is interpreted as a low-temperature, low-salinity organic-rich fluid, most likely derived from U-enriched source rocks at depth, and the uranium mineralization is closely associated with the exudation of such deep-derived organic fluids. Full article
(This article belongs to the Special Issue Isotope Geochemistry: New Techniques and Applications)
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25 pages, 21967 KB  
Article
Multi-Stage Tungsten Mineralization: Insights from Scheelite Trace Elements and Geochronology of the Kalatawu–Kalasayi System (Western Tianshan, NW China)
by Peng Yuan, Xuexiang Gu and Yongmei Zhang
Minerals 2026, 16(8), 782; https://doi.org/10.3390/min16080782 - 27 Jul 2026
Viewed by 241
Abstract
The Kalasayi tungsten deposit is a medium-sized quartz-vein scheelite tungsten deposit in the Western Tianshan, Central Asia Orogenic Belt. The Kalatawu pluton yielded Late Carboniferous zircon U–Pb ages (313.99–310.32 Ma), and molybdenite Re–Os dating gives an isochron age of 302.3 ± 1.8 Ma [...] Read more.
The Kalasayi tungsten deposit is a medium-sized quartz-vein scheelite tungsten deposit in the Western Tianshan, Central Asia Orogenic Belt. The Kalatawu pluton yielded Late Carboniferous zircon U–Pb ages (313.99–310.32 Ma), and molybdenite Re–Os dating gives an isochron age of 302.3 ± 1.8 Ma for W mineralization, indicating an ~8–12 Myr magmatic-hydrothermal system. Whole-rock geochemistry classifies the pluton as aluminous A2-type granite formed in a post-collisional extensional setting. Zircon Hf isotopes (εHf(t) = +2.8 to +8.3) suggest a mixed juvenile lower crust source with mantle input. In situ LA-ICP-MS scheelite trace element analysis and REE geochemistry distinguish two populations: proximal Group I (high Mo, low Sr, low ΣREE, right-inclined REE patterns) is precipitated from oxidizing magmatic fluid, and distal Group II (low Mo, high Sr, high ΣREE, flat REE patterns, strong positive Eu anomalies) records reduced, mixed fluid with intense fluid–rock interaction. Fluid inclusion data show decreasing temperature and salinity proximally to distally, confirming that mixing of magmatic and meteoric water led to cooling and pH increase that caused W precipitation. A four-stage metallogenic model is proposed for a post-collisional extensional setting, providing robust evidence for A-type granite-related, multi-stage W mineralization and establishing exploration indicators for the southwestern Central Asia Orogenic Belt. Full article
(This article belongs to the Section Mineral Deposits)
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23 pages, 4651 KB  
Article
Geochemical Heterogeneity of Fracture-Filling Vein Pyrobitumen in Tectonically Reworked Reservoirs of the Western Jiangnan–Xuefeng Uplift, South China
by Chongjing Wang, Daiyong Cao and Guoshu Huang
Minerals 2026, 16(7), 753; https://doi.org/10.3390/min16070753 - 19 Jul 2026
Viewed by 358
Abstract
Vein-type pyrobitumen, widely developed along the western margin of the Jiangnan–Xuefeng Uplift, preserves important records of structural modification and post-accumulation alteration within tectonically reworked reservoirs. In this study, Rock-Eval pyrolysis, molecular geochemistry, Raman spectroscopy, X-ray diffraction (XRD), trace and rare earth element (REE) [...] Read more.
Vein-type pyrobitumen, widely developed along the western margin of the Jiangnan–Xuefeng Uplift, preserves important records of structural modification and post-accumulation alteration within tectonically reworked reservoirs. In this study, Rock-Eval pyrolysis, molecular geochemistry, Raman spectroscopy, X-ray diffraction (XRD), trace and rare earth element (REE) geochemistry, and fluid inclusion analyses were integrated to investigate the origin of geochemical heterogeneity and the evolution of residual hydrocarbons. The analyzed samples are uniformly overmature, with high Tmax values (527–594 °C), extremely low S1 and HI values, and poorly ordered turbostratic carbon structures composed of defect-rich aromatic domains. Despite the comparable thermal maturity, marked variations occur in n-alkane distributions, NSO fractions, asphaltene abundance, and aromatic hydrocarbon compositions. These differences are not systematically related to maturity parameters but instead appear to reflect selective retention and localized redistribution of pyrobituminous material during structural reworking. Late Indosinian–Early Yanshanian compression generated NE-trending shear fractures together with NW-oriented extensional faults, forming a fault–fracture network that served as the principal pathways for fluid circulation and localized emplacement of pyrobituminous material. Trace-element and REE signatures, together with fluid inclusion microthermometry, suggest localized fluid–rock interaction and possible hydrothermal overprinting during pyrobitumen emplacement. The combined results suggest that tectonically driven mobilization, selective compositional fractionation, and late-stage fluid–rock interaction collectively contributed to the observed compositional heterogeneity of the vein-type pyrobitumen. This study provides additional constraints on hydrocarbon redistribution and fluid evolution in structurally reworked, highly evolved petroleum reservoirs. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 33075 KB  
Article
Regional Reservoir Assessment Using Sr and δ2H-δ18O Isotopes in Jinlun, Taiwan
by Yi-Chi Chen, Po-Kuei Chen, Pei-Jyuan Gao, Wen-Dar Tai, Kai-Chun Fan, Yen-Che Liao and Yin-Lung Han
Water 2026, 18(14), 1732; https://doi.org/10.3390/w18141732 - 17 Jul 2026
Viewed by 511
Abstract
Geothermal energy is a low-carbon baseload renewable energy that plays a key role in global energy transition. Jinlun of Taitung is a region with high potential for geothermal energy. However, sustainable resource utilization requires a comprehensive understanding of fluid sources, recharge mechanisms, and [...] Read more.
Geothermal energy is a low-carbon baseload renewable energy that plays a key role in global energy transition. Jinlun of Taitung is a region with high potential for geothermal energy. However, sustainable resource utilization requires a comprehensive understanding of fluid sources, recharge mechanisms, and circulation systems. This study integrated δ18O, δD, 87Sr/86Sr and elemental geochemistry to clarify the underlying hydrogeochemical mechanism and develop an underground fluid circulation model for Jinlun. The water compositions indicate that water–rock interactions are the dominant control on fluid chemistry. Hydrogen and oxygen isotope analysis revealed a geothermal water recharge elevation of 1321–1478 m, slightly higher than that of hot spring water (951–1459 m). The natural recharge amount of a corresponding area was approximately 13.57 × 106 t/yr. A strontium isotope mixing model indicated that the fluids were affected by three end members of deep geothermal water, shallow groundwater, and seawater. Shallow groundwater had a contribution rate of 92–98% to noncoastal hot spring water and up to 81% to geothermal water. The coastal hot spring was most affected by seawater at 48%. Rainwater infiltrated into E2 to form shallow groundwater. Some of the infiltrated water reached a deep circulation into the M3 layer and formed deep-source thermal water. Overall, this study establishes a hydrogeochemical model for Jinlun and provides scientific foundation for geothermal well design and sustainable resource management. Full article
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20 pages, 8417 KB  
Article
Magmatic Controls on Contrasting Molybdenum Fertility of Caledonian Granitoids in Eastern Guangxi, South China
by Lian Mo, Yizhi Liu, Guicong Fang, Zonglin Jiang, Er Wu, Lei Qin and Bachtiar Wahyu Mutaqin
Minerals 2026, 16(7), 739; https://doi.org/10.3390/min16070739 - 16 Jul 2026
Viewed by 329
Abstract
Caledonian hydrothermal vein-type Mo deposits are largely restricted to eastern Guangxi, South China, yet the magmatic controls on molybdenum (Mo) mineralization remain poorly constrained. The adjacent Guiling (Mo–mineralized) and Daning (Mo–barren) plutons in this region represent a natural pair for deciphering these issues. [...] Read more.
Caledonian hydrothermal vein-type Mo deposits are largely restricted to eastern Guangxi, South China, yet the magmatic controls on molybdenum (Mo) mineralization remain poorly constrained. The adjacent Guiling (Mo–mineralized) and Daning (Mo–barren) plutons in this region represent a natural pair for deciphering these issues. Zircon U–Pb dating, whole-rock geochemistry, and mineralogical characteristics indicate that the Daning pluton (~440 Ma) is an I-type granite, whereas the younger Guiling pluton (~425 Ma) is a more evolved I-type granite, with higher SiO2 contents (avg. 71.17 wt.% vs. 65.88 wt.%), stronger negative Eu anomalies (avg. 0.53 vs. 0.63), lower Nb/Ta ratios (avg. 6.5 vs. 9.9), and Zr/Hf ratios (avg. 30.6 vs. 33.4), as well as higher Rb/Sr ratios (avg. 3.6 vs. 1.1). Sr–Nd–Hf isotopes are consistent with a Paleoproterozoic crustal source for both plutons, whereas coeval mafic microgranular enclaves in the Guiling pluton exhibit positive εNd(t) values (+3.43 to +3.58), providing evidence for mantle input. Biotite geochemistry shows that the Guiling pluton is enriched in F and Cl, as reflected by lower log(ƒH2OHF)fluid values and higher log(ƒH2OHCl)fluid values. Our integrated study suggests that the Daning and Guiling plutons were emplaced in an intracontinental orogenic setting during the transition from compression to extension, but the more pronounced extension facilitated a greater input of mantle-derived heat and volatiles into the Guiling pluton, favoring Mo enrichment. However, the similar biotite crystallization temperatures and moderate oxygen fugacities of both plutons suggest that these factors were not the decisive factors. Collectively, we propose that the contrasting Mo fertility between the two plutons reflects the interplay of magmatic and structural factors. Magmatically, crust–mantle source mixing, high degrees of fractionation, and volatile enrichment promoted Mo concentration, whereas ductile shear zones likely served as fluid conduits that facilitated mineralization. Accordingly, the southwestern segment of the Yingyangguan (YYG) ductile shear zone between the Daning and Guiling plutons could be a prospective target for Mo prospecting in eastern Guangxi. Full article
(This article belongs to the Special Issue Geochemical Exploration for Critical Mineral Resources, 2nd Edition)
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26 pages, 15575 KB  
Article
Assessment of Hydrodynamic Connectivity and Compartmentalization of Petroleum Reservoirs Based on Oil Fingerprinting
by Sarkulova Zhadyrassyn, Orazbekova Riza, Gusmanova Aigul, Karazhanova Maral, Issengaliyeva Gulya, Shayakhmetov Saulet, Sarsenbekov Nariman and Bazilevskaya Ekaterina
Energies 2026, 19(14), 3254; https://doi.org/10.3390/en19143254 - 10 Jul 2026
Viewed by 395
Abstract
This study presents an assessment of the hydrodynamic connectivity and compartmentalization of petroleum reservoirs in the Caspian Basin using integrated oil fingerprinting and biomarker geochemistry approaches. The aim of the study was to identify inter-reservoir fluid communication, reconstruct hydrocarbon migration pathways, and determine [...] Read more.
This study presents an assessment of the hydrodynamic connectivity and compartmentalization of petroleum reservoirs in the Caspian Basin using integrated oil fingerprinting and biomarker geochemistry approaches. The aim of the study was to identify inter-reservoir fluid communication, reconstruct hydrocarbon migration pathways, and determine the factors controlling the geochemical heterogeneity of reservoir systems. The investigation was based on the analysis of 43 oil samples collected from 15 fields within the Caspian Basin using gas chromatography, gas chromatography–mass spectrometry, carbon isotope analysis, and multivariate statistical methods, including principal component analysis (PCA) and hierarchical cluster analysis. The results revealed the presence of both hydrodynamically connected reservoirs characterized by similar molecular and biomarker compositions and compartmentalized reservoir blocks showing significant geochemical differences and variations in thermal maturity. It was established that the internal heterogeneity of the reservoirs is controlled by tectonic segmentation, multi-stage hydrocarbon migration, and differences in source rock characteristics. The obtained results confirm the effectiveness of oil fingerprinting methods for diagnosing hydrodynamic connectivity and reservoir compartmentalization in complex petroleum systems. Full article
(This article belongs to the Section B: Energy and Environment)
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18 pages, 14650 KB  
Article
Geology, Fluid Inclusion and Stable Isotope Characteristics of the Litun Skarn Iron Deposit in the North China Craton, Eastern China
by Zhaonian Zhang, Lijun Shen, Lei Zhang, Nengwen Cao, Yang Zhao, Wenhai Huang, Yuzhen Zhu, Xing Wang and Yunhe Lv
Minerals 2026, 16(7), 703; https://doi.org/10.3390/min16070703 - 5 Jul 2026
Viewed by 343
Abstract
The North China Craton hosts abundant skarn iron resources, yet the regional large-scale mineralization mechanism remains incompletely understood. The Litun deposit is a newly discovered skarn iron deposit in the North China Craton. Integrated field geological investigations, petrographic observations, fluid inclusion microthermometry and [...] Read more.
The North China Craton hosts abundant skarn iron resources, yet the regional large-scale mineralization mechanism remains incompletely understood. The Litun deposit is a newly discovered skarn iron deposit in the North China Craton. Integrated field geological investigations, petrographic observations, fluid inclusion microthermometry and stable isotope geochemistry are applied to constrain evaporite contributions to metallogenic processes. Four mineralization stages are identified: skarn, oxide, sulfide, and carbonate. Early skarn-stage fluids are iron-rich magmatic hydrothermal fluids with high temperatures (498 to >550 °C), high salinities (18.6 to 59.4 wt% NaCl eqv.), and magmatic δ18O values of 8.3 to 10.8‰. Subsequent oxide to late carbonate stages record continuous infiltration of meteoric water, supported by H–O isotopic trends of rising meteoric water proportions. Pyrite from the magnetite ores has δ34SV-CDT values between 12.0 and 15.0‰, significantly higher than those of pyrite in the Litun diorite (−0.8 to 1.1‰), indicating the contributions of sulfur from evaporites (δ34SV-CDT 26.9 to 28.6‰) in the mineralization process. Moreover, vein pyrite formed in later stages displays even higher δ34S values (17.3 to 20.9‰), demonstrating progressive enrichment of evaporite-derived sulfur as hydrothermal activity evolves. Synchronous rises in meteoric water fraction and evaporite sulfur proportion indicate evaporites are delivered into the ore-forming system via meteoric water mixing. The mixing of meteoric water containing dissolved evaporites and iron-rich magmatic-hydrothermal fluids may be the major mechanism of magnetite precipitation in the Litun deposit. Full article
(This article belongs to the Section Mineral Deposits)
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27 pages, 68524 KB  
Article
Metallogenic Mechanism of the Mangyahedong Gold Deposit in the Qimantage Area, Qinghai Province, NW China: Constraints from Hydrothermal Apatite U-Pb Dating and Trace Elements of Pyrite
by Shaonan Li, Tingmei Huang, Hailin Xie, Yu Han, Sulong Chen, Bin Wang, Haiyun Ma, Wenjun Ma, Rucai Ma, Ming Ma, Siyu Jiang and Zhen Wang
Processes 2026, 14(13), 2185; https://doi.org/10.3390/pr14132185 - 3 Jul 2026
Viewed by 393
Abstract
The Mangyahedong gold deposit—recently discovered in the Qimantage segment of the East Kunlun orogenic belt—is a high-priority exploration target. Key unknowns include its mineralization age, the sources of sulfur and gold, and the tectonic–magmatic–hydrothermal controls on formation. These gaps have hindered genetic classification [...] Read more.
The Mangyahedong gold deposit—recently discovered in the Qimantage segment of the East Kunlun orogenic belt—is a high-priority exploration target. Key unknowns include its mineralization age, the sources of sulfur and gold, and the tectonic–magmatic–hydrothermal controls on formation. These gaps have hindered genetic classification and stage-specific research. We addressed them through integrated petrography, TIMA mineral mapping, in situ LA-ICP-MS analysis of pyrite from three mineralization stages, and U-Pb dating of hydrothermal apatite spatially and temporally linked to the main sulfide-precipitation event. The stages are: (I) early sericite–quartz alteration; (II) main ore stage—carbonate–chlorite–sulfide + native gold; and (III) late calcite–pyrite veins. Pyrite zoning shows that early pyrite cores are enriched in As and Au. In contrast, the main-stage pyrite has As-poor cores, with As, Au, and Co progressively enriched toward the rims. This zoning pattern indicates evolving fluid redox conditions and metal complexation during ore deposition. A 207Pb/206Pb age of 406 ± 13 Ma from apatite in gold-bearing quartz–sulfide veins constrains gold deposition to the Late Silurian–Early Devonian transition. Age, texture, and geochemistry collectively support a regional metamorphic–deformational origin, consistent with the orogenic gold model. Isotopic and elemental data point to the Qimantage Group volcanic rocks as the dominant source of ore-forming elements—indicating strong potential for discovery along strike and at depth. Full article
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38 pages, 23973 KB  
Article
Tracking Crystals Evolution in Episodes of Magma Mixing
by Antonella Longo, Deepak Garg and Paolo Papale
Appl. Sci. 2026, 16(13), 6563; https://doi.org/10.3390/app16136563 - 1 Jul 2026
Viewed by 200
Abstract
Petrology and geochemistry reconstruct from plutons and eruptive products the underground chemical and thermodynamic conditions of magma at the time of crystallization. Accretionary layers in crystals record the composition of the surrounding melt, as well as the confining pressure and temperature. Such a [...] Read more.
Petrology and geochemistry reconstruct from plutons and eruptive products the underground chemical and thermodynamic conditions of magma at the time of crystallization. Accretionary layers in crystals record the composition of the surrounding melt, as well as the confining pressure and temperature. Such a backward reconstruction should be paired with a forward computation of the solidifying crystals during their transport in convective motions inside a refilled magmatic reservoir. This work develops a framework for the solution of magma fluid-dynamics and for the related Lagrangian trajectories of suspended crystals. Episodes of magma mixing due to injection of fresh magma into a shallow chamber are simulated at first in a Eulerian reference system. Afterwards, the Lagrangian trajectories of passive tracers are computed, tracking the magma composition, pressure and temperature through which these particles move. On the base of the compositional, pressure and temperature conditions, the crystallizing phases are computed with the MELTS code. The history of accretionary layers is thus obtained by interface-controlled growth and solid-state diffusion. Our results show that crystals residing in different parts of the underground system acquire a distinctive signature and are well mixed together. A small population will register the successive refilling episodes, while a substantial one will record each fresh injection. Full article
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34 pages, 9622 KB  
Article
Geochemical, REE and Multivariate Statistical Constraints on Fe–Mn Mineralization in Durmuştepe Area (Maden, Elazığ, Türkiye)
by Alican Öztürk and Osman Altay
Minerals 2026, 16(7), 687; https://doi.org/10.3390/min16070687 - 30 Jun 2026
Cited by 1 | Viewed by 755
Abstract
In this study, we examined the mineralogy, geochemistry and origin of Fe–Mn mineralization occurring as lenses within siliceous mudstones of the Middle Eocene Maden Complex (Durmuştepe, Elazığ, Türkiye) using multivariate statistical methods and Compositional Data Analysis (CoDA). Major-oxide, trace-element and REE analyses were [...] Read more.
In this study, we examined the mineralogy, geochemistry and origin of Fe–Mn mineralization occurring as lenses within siliceous mudstones of the Middle Eocene Maden Complex (Durmuştepe, Elazığ, Türkiye) using multivariate statistical methods and Compositional Data Analysis (CoDA). Major-oxide, trace-element and REE analyses were performed on 21 samples (n = 21), comprising 11 ore and 10 host-rock samples. Ore microscopy, discrimination diagrams, PAAS-normalized REE patterns, Principal Component Analysis (PCA), Hierarchical Cluster Analysis (HCA), factor analysis, Kendall correlation and CLR-transformed CoDA-PCA were applied. The ore consists of pyrolusite, braunite, manganite, magnetite and hematite. Massive and felty textures indicate rapid precipitation linked to abrupt physicochemical changes near the vents. Fe/Mn ≈ 1.62 and Co/Ni = 0.03–0.04 support an exhalative origin; Ce/Ce* = 0.10–0.15 (mean 0.11) records a pronounced negative Ce anomaly; and Eu/Eu* = 1.06–1.18 suggests vent-fluid temperatures below ~250 °C. CoDA-PCA shows that Ce is decoupled from the other lanthanides; HCA separates ore from host-rock populations; and factor analysis indicates that Ti–Al–K detrital input diluted ore accumulation. Integrating these results, we interpret Durmuştepe as a proximal volcano-sedimentary hydrothermal-exhalative Fe–Mn system that formed during magmatism in the Maden marginal basin under oxic seawater mixing and contemporaneous detrital sedimentation. The multivariate workflow also provides a reproducible approach for source characterization in similar mixed-origin deposits. Full article
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20 pages, 14940 KB  
Article
Origin, Charging History, and Migration–Accumulation Patterns of Crude Oils in the Eocene Dainan Formation, Southeastern Gaoyou Sag, Subei Basin
by Juan Zhang, Wenting Liao, Lixin Fan, Yuezhe Li and Xiangdong Yin
Energies 2026, 19(13), 2990; https://doi.org/10.3390/en19132990 - 25 Jun 2026
Viewed by 219
Abstract
Deep lacustrine rift basins present persistent challenges in hydrocarbon provenance determination, charging-history reconstruction, and migration pathway prediction within heterogeneous deep reservoirs. This study applies an integrated approach combining biomarker and light-hydrocarbon geochemistry, fluid-inclusion microthermometry, and two-dimensional migration modelling to the deep Eocene Dainan [...] Read more.
Deep lacustrine rift basins present persistent challenges in hydrocarbon provenance determination, charging-history reconstruction, and migration pathway prediction within heterogeneous deep reservoirs. This study applies an integrated approach combining biomarker and light-hydrocarbon geochemistry, fluid-inclusion microthermometry, and two-dimensional migration modelling to the deep Eocene Dainan Formation in the southeastern Gaoyou Sag, Subei Basin. Based on 20 analytical entries from Dainan oils/reservoir samples and Funing Formation source-rock extracts, the results indicate mixed contributions from the E1f2 and E1f4 source intervals rather than a single-source origin. Maturity parameters place most oils within the early- to main-oil window, while hydrocarbon inclusions with dominantly blue fluorescence and homogenization temperatures of 85–110 °C are consistent with a dominant Sanduo-period charging episode. Integrated migration modelling identifies two accumulation styles: a northern fault-slope migration system and a southern Zhenwu fault-conduit system, with effective accumulation favoured by the coupling of active faults and connected sand bodies. The established genetic model offers a transferable framework for derisking exploration in analogous deep lacustrine rift basins. Full article
(This article belongs to the Section I1: Fuel)
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23 pages, 12045 KB  
Article
Carboniferous Slab Rollback in the Eastern Tianshan, NW China: Insights from Basalts of the Qi’Eshan Group in the Dananhu Arc
by Jixiang Dai, He Yang, Hongming Cai, Yuyu Zong and Feng Gao
Minerals 2026, 16(6), 642; https://doi.org/10.3390/min16060642 - 18 Jun 2026
Viewed by 439
Abstract
Volcanic rocks of the Qi’eshan Group, which are widely distributed in the Dananhu arc of the Eastern Tianshan, NW China, have long been debated in terms of their formation age and tectonic setting. In this study, we conducted an integrated study of U-Pb [...] Read more.
Volcanic rocks of the Qi’eshan Group, which are widely distributed in the Dananhu arc of the Eastern Tianshan, NW China, have long been debated in terms of their formation age and tectonic setting. In this study, we conducted an integrated study of U-Pb apatite geochronology, whole-rock major and trace element geochemistry, in situ major element analyses of clinopyroxene, and “Rhyolite-MELTS” thermodynamic modeling on the basalts from the Qi’eshan Group. Geochronological data show that the weighted mean of 206Pb/238U ages of apatite is 329 ± 10 Ma. The basalts belong to the tholeiitic series and are characterized by enrichment in large ion lithophile elements (LILEs), depletion in high field strength elements (HFSEs), and enrichment of light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs) with weak negative Eu anomalies. They were derived by partial melting of garnet-spinel lherzolite in a depleted mantle source metasomatized by subduction-related fluids, followed by fractional crystallization of spinel, olivine, and clinopyroxene. Clinopyroxene is dominated by augite, characterized by high Mg and Ca contents and low Al and Na contents. Machine-learning-based thermobarometry indicates that clinopyroxene crystallized at temperatures of 1027–1033 °C and pressures of 1.1–1.6 kbar. “Rhyolite-MELTS” isobaric crystallization simulations suggest that mantle-derived magma, with an initial water content of 4 wt.% and oxygen fugacity of FMQ, can generate melts compositionally similar to the volcanic rocks of the Qi’eshan Group through fractional crystallization at a pressure of 1.5 kbar. Combined with previous studies, we propose that the Qi’eshan Group basalts formed in an extensional arc setting related to southward rollback of the northward-subducting Kanguer oceanic slab, which caused asthenosphere upwelling and lithospheric extension, thereby promoting partial melting of the subduction-metasomatized mantle. Our data provide new insights into the Carboniferous rollback of the Kanguer oceanic slab in the northern part of the Eastern Tianshan. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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34 pages, 7618 KB  
Article
Characteristics of Lower Cretaceous Calcite Veins and Their Relationship with Hydrocarbon Dissipation and Uranium Mineralization in the Qianjiadian Uranium Mining Area, Songliao Basin
by Bailin Wu, Mengdi Yang, Xiaorui Zhang, Songlin Yang, Yu Sun, Liangliang Zhang, Yaxin Ma, Yu Hou, Guoquan Sun, Siyuan Wang, Yeerzati Dawulietbieke and Quan Liu
Minerals 2026, 16(6), 631; https://doi.org/10.3390/min16060631 - 12 Jun 2026
Viewed by 387
Abstract
Current research suggests that the uranium enrichment in the Qianjiadian deposit, southwestern Songliao Basin (China), is closely related to hydrocarbon dissipation and deep thermal fluids. However, previous investigations have not carried out systematic in-depth research on the abundant calcite veins hosted in diabase [...] Read more.
Current research suggests that the uranium enrichment in the Qianjiadian deposit, southwestern Songliao Basin (China), is closely related to hydrocarbon dissipation and deep thermal fluids. However, previous investigations have not carried out systematic in-depth research on the abundant calcite veins hosted in diabase within the ore district, especially regarding their types, genetic mechanisms, formation ages, and genetic links to uranium enrichment. In particular, whether their genesis is associated with the two critical ore-controlling factors (hydrocarbon dissipation and thermal fluid activities) remains poorly constrained and to be elucidated. Through analyses of major and trace element geochemistry, scanning electron microscopy, and fluid inclusion microthermometry on calcite veins within fractures of Lower Cretaceous diabase, this study confirms that the veins are products of epigenetic fluid infill with a medium-to-low temperature hydrothermal nature (115–215 °C). The direction of fluid migration was from north to south, consistent with the trend of hydrocarbon dissipation. In situ U-Pb dating yields Eocene (~42.9 Ma) and Pleistocene (1.57–2.82 Ma) ages for the calcite veins, which are highly consistent with the timing of diabase intrusion (early Eocene) and the main episodes of uranium mineralization (Eocene–Oligocene and Pleistocene). Carbon and oxygen isotope compositions and inclusion components indicate that the carbon source was mainly derived from dissipated hydrocarbons, rather than from sedimentary diagenesis or direct source rock generation. The C-O isotopic signatures reflect further carbon isotope fractionation following the interaction between dissipated hydrocarbons and groundwater, and the inclusion fluids, composed mainly of hydrocarbon gases and water, suggest that the carbon source for calcite vein formation was provided by dissipated hydrocarbons. The temporal coupling of hydrocarbon dissipation, calcite vein formation, uranium mineralization, and thermal input from diabase intrusion reflects the dynamic processes of basin evolution and tectonic reworking. The key dynamic backgrounds for this series of diagenetic and metallogenic events include Late Cretaceous tectonic inversion, Eocene–Oligocene tectonic uplift and erosion, and Pleistocene differential uplift and subsidence. The thermal effects from hydrocarbon dissipation and diabase intrusion were the primary factors driving the anomalous uranium enrichment that formed this super-large deposit. The formation of the calcite veins, along with their characteristics indicative of medium-to-low temperature hydrothermal activity and hydrocarbon dissipation, provides a critical window for understanding these processes and offers robust scientific evidence for this genetic model. This study, for the first time, systematically reveals that the calcite veins within the diabase of the Qianjiadian uranium mining area are of medium-to-low temperature hydrocarbon-bearing hydrothermal origin, and constrains their formation ages to the Eocene (~42.9 Ma) and Pleistocene (1.57–2.82 Ma), which are highly coupled with diabase intrusion and two episodes of uranium mineralization events. C-O isotopic and fluid inclusion evidence indicates that the formation of calcite veins directly records the process of hydrocarbon dissipation–groundwater mixing, providing a new mineralogical and geochronological evidence chain for thermal–hydrocarbon–uranium-coupled mineralization. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 7697 KB  
Article
The Nam Xan Gold Deposit, Laos: Evidence for a Distal Intrusion-Related Gold System in the Truong Son Fold Belt
by Bounheuang Phanpasert, Ruidong Yang, Jun Chen, Patthana Bounliyong, Yifan Wen and Xinzheng Li
Minerals 2026, 16(6), 600; https://doi.org/10.3390/min16060600 - 3 Jun 2026
Viewed by 693
Abstract
The Nam Xan gold deposit is located in the central Truong Son Fold Belt of Laos. It is a newly identified distal intrusion-related gold system (IRGS) in a continental arc setting. This study uses whole-rock geochemistry, Pb and S isotope systematics, and mineral-scale [...] Read more.
The Nam Xan gold deposit is located in the central Truong Son Fold Belt of Laos. It is a newly identified distal intrusion-related gold system (IRGS) in a continental arc setting. This study uses whole-rock geochemistry, Pb and S isotope systematics, and mineral-scale analyses to trace magmatic evolution and ore-forming processes. Whole-rock data indicate that the associated intrusive suite is a calc-alkaline volcanic-arc granite (VAG) series, derived from a subduction-modified mantle source with notable crustal contributions. Pb isotopes reveal mixing arrays rather than true isochrons. Monte Carlo modeling shows binary mantle–crust mixing for igneous rocks and ternary mixing with an additional radiogenic component in ore samples, indicating enhanced fluid–rock interaction during mineralization. Sulfur isotope data show a shift from magmatic sulfur (δ34S ≈ −5‰) in early skarn-stage pyrite to heavier values (δ34S ≈ +6‰) in gold-bearing stages, reflecting fluid evolution driven by cooling and redox changes. Mineral chemistry data demonstrate that gold is present both as invisible gold within arsenian pyrite and as free gold in late-stage fractures. Strong correlations between Au and As, along with elevated Co/Ni ratios and enrichments in Bi, W, and F, collectively support a magmatic-hydrothermal origin. These findings define a three-stage mineralization process: an initial phase involving high-temperature magmatic fluids, a main stage characterized by sulfidation and gold deposition, and a final stage marked by polymetallic overprinting. The Nam Xan deposit is therefore interpreted as the distal manifestation of a Permian arc-related magmatic system in which magmatic fluids migrated along structural conduits and precipitated gold through interaction with carbonate host rocks. The identification of these intrusions in the distal IRGS at Nam Xan informs regional exploration models in the Truong Son Fold Belt, demonstrating the potential of carbonate platforms near Permian intrusions for future mineral exploration. Full article
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20 pages, 41743 KB  
Article
Hydrochemical Tracing for Solute Sources and Enrichment Mechanisms in Inland Lake Waters of the Qiangtang Plateau, Northern Tibet, China
by Yuanqing Liu, Dongguang Wen, Le Zhou, Lin Lv, Xuejun Ma, Jianhua Feng, Yanwei Guo, Jian Cao and Tao Lv
Minerals 2026, 16(6), 599; https://doi.org/10.3390/min16060599 - 3 Jun 2026
Viewed by 295
Abstract
To elucidate the solute sources, migration and enrichment mechanisms of water bodies in the endorheic lake region of the Qiangtang Plateau on the Tibetan Plateau and clarify the hydrogeochemical cycling patterns in alpine arid environments, this study focuses on two core scientific objectives: [...] Read more.
To elucidate the solute sources, migration and enrichment mechanisms of water bodies in the endorheic lake region of the Qiangtang Plateau on the Tibetan Plateau and clarify the hydrogeochemical cycling patterns in alpine arid environments, this study focuses on two core scientific objectives: quantitative identification of the multi-source contributions of aquatic solutes, and revelation of the key processes governing the enrichment of strategic elements including lithium (Li) and boron (B). To achieve these goals, we conducted systematic hydrogeological field investigations and collected 28 multi-type water samples, covering springs, rivers, thermal springs, freshwater lakes, salt lake brines, atmospheric precipitation, and glacial meltwater. The physicochemical properties, major ions, and trace elements of all samples were comprehensively analyzed. On this basis, the hydrogeochemical characteristics, evolutionary processes, and solute origins of regional waters were systematically explored. Combined with PHREEQC numerical simulation, principal component analysis (PCA), and Pearson correlation analysis, the dominant controlling factors of water geochemistry were quantified, and a conceptual hydrogeochemical evolution model was established. The results reveal a clear hydrogeochemical evolutionary gradient across the study area: water bodies evolve from low-salinity HCO3-Ca recharge end-members and transitional HCO3·SO4-Ca(Mg) type water to highly mineralized Cl-Na (SO4·Cl-Na) salt lake brines, accompanied by synchronous enrichment of Li, B, arsenic (As), and other characteristic elements. Solute accumulation in regional waters is governed by the ternary coupling effects of evaporative concentration, rock weathering and leaching, and deep geothermal fluid input, while cation exchange and mineral dissolution–precipitation reactions further modulate ionic composition and ratios. Elements including As, Li, B, and chloride (Cl) exhibit conservative migration behaviors in non-hydrothermal waters, whereas thermal springs possess unique geochemical signatures driven by deep fluid recharge. PCA results indicate that evaporative concentration serves as the primary controlling factor with a contribution rate of 55.39%; rock weathering provides the basic solute load (17.09%); and the coupled processes of deep fluid mixing and carbonate precipitation regulate elemental fractionation (14.21%). These findings systematically clarify the hydrogeochemical evolution laws and multi-source coupling mechanisms of inland lake waters in the Qiangtang Plateau. Furthermore, this study establishes a conceptual framework of “multi-source recharge–water–rock interaction–evaporative concentration”, advances the understanding of alpine hydrological cycling under climate change, and provides a solid scientific foundation for hydrological cycle research and green exploration of strategic mineral resources in endorheic salt lake regions. Full article
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