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Keywords = fiber pull-out test

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19 pages, 5806 KB  
Article
Ballistic Failure Analysis of Hybrid Natural Fiber/UHMWPE-Reinforced Composite Plates Using Experimental and Finite Element Methods
by Eduardo Magdaluyo, Ariel Jorge Payot, Lorenzo Matilac and Denisse Jonel Pavia
J. Manuf. Mater. Process. 2026, 10(1), 33; https://doi.org/10.3390/jmmp10010033 - 13 Jan 2026
Viewed by 313
Abstract
This study evaluated the ballistic performance and failure mechanisms of epoxy-based hybrid laminates reinforced with abaca/UHMWPE and pineapple leaf fiber (PALF)/UHMWPE fabrics fabricated by using vacuum-assisted hand lay-up. Ballistic tests utilized 9 mm full metal jacket (FMJ) rounds (~426 m/s impact velocity) under [...] Read more.
This study evaluated the ballistic performance and failure mechanisms of epoxy-based hybrid laminates reinforced with abaca/UHMWPE and pineapple leaf fiber (PALF)/UHMWPE fabrics fabricated by using vacuum-assisted hand lay-up. Ballistic tests utilized 9 mm full metal jacket (FMJ) rounds (~426 m/s impact velocity) under NIJ Standard Level IIIA conditions (44 mm maximum allowable BFS). This experimental test was complemented by finite element analysis (FEA) incorporating an energy-based bilinear fracture criterion to simulate matrix cracking and fiber pull-out. The results showed that abaca/UHMWPE composites exhibited lower backface signature (BFS) and depth of penetration (DOP) values (~23 mm vs. ~42 mm BFS; ~7 mm vs. ~9 mm DOP) than PALF/UHMWPE counterparts, reflecting superior interfacial adhesion and more ductile failure modes. Accelerated weathering produced matrix microcracking and delamination in both systems, reducing overall ballistic resistance. Scanning electron microscopy confirmed improved fiber–matrix bonding in abaca composites and interfacial voids in PALF laminates. The FEA results reproduced major failure modes, such as delamination, fiber–matrix debonding, and petaling, and identified stress concentration zones that agreed with experimental observations, though the extent of delamination was slightly underpredicted. Overall, the study demonstrated that abaca/UHMWPE hybridcomposites offer enhanced ballistic performance and durability compared with PALF/UHMWPE laminates, supporting their potential as sustainable alternatives for lightweight protective applications. Full article
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28 pages, 4499 KB  
Article
Analytical and Experimental Study on Bond Behavior of Embedded Through-Section FRP Bar-to-Concrete Joints Using a Trilinear Cohesive Material Law
by Wensheng Liang, Jiang Lu, Jinping Fu, Bi Zhang, Baowen Zhang and Yanjie Wang
Buildings 2026, 16(1), 164; https://doi.org/10.3390/buildings16010164 - 29 Dec 2025
Viewed by 184
Abstract
The embedded through-section (ETS) technique is a promising method for fiber-reinforced polymer (FRP)-strengthening reinforced concrete (RC) structures, offering higher bond resistance and reduced surface preparation compared to externally bonded or near-surface mounted FRP systems. A common failure in ETS applications is debonding at [...] Read more.
The embedded through-section (ETS) technique is a promising method for fiber-reinforced polymer (FRP)-strengthening reinforced concrete (RC) structures, offering higher bond resistance and reduced surface preparation compared to externally bonded or near-surface mounted FRP systems. A common failure in ETS applications is debonding at the FRP bar-to-concrete interface. However, current design standards often assume uniform bond stress and lack predictive models that account for debonding propagation and its effect on load capacity. Furthermore, a detailed analysis of interfacial stress development, including debonding initiation and progression along varying bond lengths, remains limited. To address these gaps, this study introduces an analytical model that describes the complete debonding process in ETS FRP bar-to-concrete joints, incorporating both long and short bond lengths and frictional effects. Based on a trilinear cohesive material law (CML), closed-form expressions are deduced for the load–slip response, maximum load, interfacial shear stress and strain distribution along the FRP bar. The proposed model is validated experimentally through pull-out tests on glass FRP (GFRP) bars adhesively bonded to concrete with different strength grades. The results show that the analytical predictions agree well with both the self-conducted experimental data for short joints and existing test results for long joints given in the literature. Therefore, the developed design-oriented solution enables accurate evaluation of the actual contribution of ETS FRP reinforcement to RC members by explicitly modeling debonding behavior. This provides a rigorous and mechanics-based tool for performance-based design of ETS FRP-to-concrete joints, addressing a critical gap in the future refinement of current design standards. Full article
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19 pages, 6950 KB  
Article
Synergistic Effects of Glass and Flax Fibers Reinforced in Fly Ash Geopolymer Matrix
by Kacper Oliwa, Semanur Efe, Beata Figiela and Kinga Korniejenko
Materials 2026, 19(1), 102; https://doi.org/10.3390/ma19010102 - 27 Dec 2025
Viewed by 392
Abstract
This study compares fly-ash-based geopolymers reinforced with short glass fibers (GF) or flax fibers (FF). Four mixes were produced: reference (FA), 1 wt% GF, 1 wt% FF, and a hybrid (0.5 wt% GF + 0.5 wt% FF). These compositions were cast into prism [...] Read more.
This study compares fly-ash-based geopolymers reinforced with short glass fibers (GF) or flax fibers (FF). Four mixes were produced: reference (FA), 1 wt% GF, 1 wt% FF, and a hybrid (0.5 wt% GF + 0.5 wt% FF). These compositions were cast into prism and cube molds, cured at 75 °C for 24 h, and tested after 28 days. Mechanical testing included compressive strength and three-point bending, phase composition by XRD, and microstructure by optical and SEM microscopy. The GF composite showed the highest compressive strength (mean up to ~28–34 MPa versus ~17 MPa for the reference), while FF gave intermediate values (~11–22 MPa). During bending, the reference achieved the highest flexural strength (~5.5 MPa); fiber-reinforced mixes ranged from ~2.9 to 4.4 MPa. XRD indicated a typical amorphous aluminosilicate gel over crystalline remnants; SEM/optical observations revealed a denser, more compact matrix with fewer voids for GF systems, whereas FF and hybrid mixes exhibited localized porosity and fiber pull-out imprints affecting crack initiation/propagation. Overall, 1 wt% GF effectively enhances compressive performance and matrix densification, while fiber addition at the tested dosages does not improve flexural strength; optimizing fiber content/dispersion and interfacial treatment is recommended. Full article
(This article belongs to the Special Issue Geopolymers and Fiber-Reinforced Concrete Composites (Second Edition))
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29 pages, 9432 KB  
Article
Optimization of Activator Modulus to Improve Mechanical and Interfacial Properties of Polyethylene Fiber-Reinforced Alkali-Activated Composites
by Heng Yang, Dong Liu, Yu Guo, Mingkui Jia, Yingcan Zhu and Junfei Zhang
Buildings 2026, 16(1), 57; https://doi.org/10.3390/buildings16010057 - 23 Dec 2025
Viewed by 321
Abstract
With the growing demand for sustainable and high-performance construction materials, alkali-activated materials (AAM) have attracted significant interest as eco-friendly al-ternatives to cement-based systems. Nevertheless, the tensile ductility and AAM–concrete interfacial bonding of polyethylene fiber-reinforced AAM remain insufficiently understood, and systematic knowledge on how [...] Read more.
With the growing demand for sustainable and high-performance construction materials, alkali-activated materials (AAM) have attracted significant interest as eco-friendly al-ternatives to cement-based systems. Nevertheless, the tensile ductility and AAM–concrete interfacial bonding of polyethylene fiber-reinforced AAM remain insufficiently understood, and systematic knowledge on how activator modulus governs these multi-scale properties is still limited. This study aims to clarify how activator modulus (Ms = 0, 0.5, 0.8, 1.1, 1.4) influences the mechanical, interfacial, and microstructural behavior of an engineered AAM reinforced with polyethylene fibers. The effects are investigated through uniaxial tensile tests, single-fiber pull-out experiments, bond tests with concrete, and microstructural analyses (SEM, XRD, CT). Results show that an activator modulus of 1.1 yields the best overall performance, achieving a 28-day tensile strength of 3.77 MPa and ultimate tensile strain of 3.68%, representing increases of 231% and 64.6% compared with a modulus of 0. Microstructural observations confirmed that the optimized modulus promotes extensive gel formation, improves fiber–matrix interfacial bonding, and enhances strain-hardening with multiple microcracks. Interfacial tests further demonstrated that Ms strongly affects bond performance between AAM and concrete, with 1.0–1.1 providing balanced adhesion and matrix ductility, while excessive activation (Ms = 1.4) caused interfacial defects and bond deterioration. These findings deepen the understanding of the micromechanical role of activator modulus and provide guidance for the mix design of durable, high-ductility AAM suitable for sustainable infrastructure. Full article
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25 pages, 5342 KB  
Article
Evaluation of Jute–Glass Ratio Effects on the Mechanical, Thermal, and Morphological Properties of PP Hybrid Composites for Sustainable Automotive Applications
by Tunahan Özyer and Emre Demirci
Polymers 2025, 17(24), 3335; https://doi.org/10.3390/polym17243335 - 17 Dec 2025
Viewed by 474
Abstract
This study investigates polypropylene (PP)–based biocomposites reinforced with systematically varied jute and glass fiber ratios as sustainable, lightweight alternatives for semi-structural automotive parts. Four formulations (J20/G0, J15/G5, J10/G10, J5/G15) with a constant 20 wt% total fiber were produced by injection molding and characterized [...] Read more.
This study investigates polypropylene (PP)–based biocomposites reinforced with systematically varied jute and glass fiber ratios as sustainable, lightweight alternatives for semi-structural automotive parts. Four formulations (J20/G0, J15/G5, J10/G10, J5/G15) with a constant 20 wt% total fiber were produced by injection molding and characterized through mechanical, thermal, and morphological analyses. Tensile, flexural, and Charpy impact tests showed progressive improvements in strength, stiffness, and energy absorption with increasing glass fiber content, while ductility was maintained or slightly enhanced. SEM revealed a transition from fiber pull-out in jute-rich systems to fiber rupture and stronger matrix adhesion in glass-rich hybrids. Thermal analyses confirmed the benefits of hybridization: heat deflection temperature increased from 75 °C (J20/G0) to 103 °C (J5/G15), and thermogravimetry indicated improved stability and higher char residue. DSC showed negligible changes in crystallization and melting, confirming that fiber partitioning does not significantly affect PP crystallinity. Benchmarking demonstrated mechanical and thermal performance comparable to acrylonitrile–butadiene–styrene (ABS) and acrylonitrile–styrene–acrylate (ASA), widely used in automotive components. Finally, successful molding of a prototype exterior mirror cap from J20/G0 validated industrial processability. These findings highlight jute–glass hybrid PP composites as promising, sustainable alternatives to conventional engineering plastics for automotive engineering applications. Full article
(This article belongs to the Special Issue Advances in Composite Materials: Polymers and Fibers Inclusion)
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19 pages, 10305 KB  
Article
Graphene Nanofiller Type Matters: Comparative Analysis of Static and Fatigue Delamination Resistance in Modified Carbon Fiber Composites
by Konstantina Zafeiropoulou, Christina Kostagiannakopoulou, George Sotiriadis and Vassilis Kostopoulos
Polymers 2025, 17(24), 3299; https://doi.org/10.3390/polym17243299 - 12 Dec 2025
Viewed by 418
Abstract
Delamination remains a critical failure mode in carbon fiber-reinforced polymer (CFRP) composites, particularly under cyclic loading in aerospace and automotive applications. This study explores whether nanoscale reinforcement with graphene-based materials can enhance delamination resistance and identifies the most effective nanofiller type. Two distinct [...] Read more.
Delamination remains a critical failure mode in carbon fiber-reinforced polymer (CFRP) composites, particularly under cyclic loading in aerospace and automotive applications. This study explores whether nanoscale reinforcement with graphene-based materials can enhance delamination resistance and identifies the most effective nanofiller type. Two distinct graphene nanospecies—reduced graphene oxide (rGO) and carboxyl-functionalized graphene nanoplatelets (HDPlas)—were incorporated at 0.5 wt% into CFRP laminates and tested under static and fatigue mode I loading using double cantilever beam (DCB) tests. Both nanofillers enhanced interlaminar fracture toughness compared to the neat composite: rGO improved the energy release rate by 36%, while HDPlas achieved a remarkable 67% enhancement. Fatigue testing showed even stronger effects, with the fatigue threshold energy release rate rising by 24% for rGO and 67% for HDPlas, leading to a fivefold increase in fatigue life for HDPlas-modified laminates. A compliance calibration method enabled continuous monitoring of crack growth over one million cycles. Fractography analysis using scanning electron microscopy revealed that both nanofillers activated crack bifurcation, enhancing energy dissipation. However, the HDPlas system further exhibited extensive nanoparticle pull-out, creating a more tortuous crack path and superior resistance to crack initiation and growth under cyclic loading. Full article
(This article belongs to the Special Issue Advances in Fatigue and Fracture of Fiber-Reinforced Polymers)
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16 pages, 9834 KB  
Article
Study on the Dynamic Mechanical Properties of Polypropylene Fiber-Reinforced Concrete Based on a 3D Microscopic Model
by Shiliang Liu, Zhimin Du, Yanan Wang, Jiawei Wang and Zhibo Dong
Buildings 2025, 15(24), 4427; https://doi.org/10.3390/buildings15244427 - 8 Dec 2025
Viewed by 302
Abstract
Polypropylene (PP) fibers, known for their high fracture strength, low density, and cost-effectiveness, can significantly enhance the impact resistance of concrete, making the material suitable for specialized engineering applications. This study combined Split Hopkinson Pressure Bar (SHPB) tests with a three-dimensional mesoscale numerical [...] Read more.
Polypropylene (PP) fibers, known for their high fracture strength, low density, and cost-effectiveness, can significantly enhance the impact resistance of concrete, making the material suitable for specialized engineering applications. This study combined Split Hopkinson Pressure Bar (SHPB) tests with a three-dimensional mesoscale numerical model to investigate the dynamic compressive behavior of PP fiber-reinforced concrete (PFRC). The model, developed using MATLAB, explicitly represented polyhedral aggregates, mortar, the interfacial transition zone (ITZ), and PP fibers. Numerical simulations of impact compression were then performed using LS-DYNA and validated against experimental results. The simulated results exhibit close agreement with the experimental data in terms of peak stress, peak strain, and failure characteristics. The incorporation of 0.1% polypropylene fibers significantly enhanced the dynamic compressive strength of the specimen by 24.45%, with a mere 2.10% deviation from the experimental measurement. When the impact velocity was increased to 8 m/s and 10 m/s, the peak stress showed increases of 6.14% and 22.62%, respectively, while the peak strain increased by 11.72% and 23.32%. Damage analysis revealed that the aggregates experienced minimal failure, with cracks primarily initiating from the mortar and the ITZ. The polypropylene fibers improved the dynamic mechanical performance by dissipating energy through both fiber fracture and pull-out mechanisms. Furthermore, as the impact velocity increased, the fibers absorbed more energy, leading to a progressive increase in their own damage. Full article
(This article belongs to the Topic Sustainable Building Materials)
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27 pages, 4878 KB  
Article
Bond Stress Analysis Between High-Performance Steel Fiber Reinforced Mortar and Deformed Steel Bars Under Pull-Out Test
by Ramdane Sidali Amrouche, Samira Djaknoun, Messaoud Saidani, Zineb Abeoub and Giangiacomo Minak
Fibers 2025, 13(12), 164; https://doi.org/10.3390/fib13120164 - 5 Dec 2025
Viewed by 467
Abstract
Despite increased utilization of high-performance mortars in construction, there remains a paucity of research concerning the bond performance of steel reinforcement, particularly within masonry structures. This study characterizes the bond stress behavior in high-performance steel fiber mortar (HPSFRM) to define critical design bond [...] Read more.
Despite increased utilization of high-performance mortars in construction, there remains a paucity of research concerning the bond performance of steel reinforcement, particularly within masonry structures. This study characterizes the bond stress behavior in high-performance steel fiber mortar (HPSFRM) to define critical design bond stress parameters. Pull-out tests were performed, incorporating three primary variables: compressive resistance, steel fiber volume, and steel rebars diameter. To support safe and reliable bond design in HPSFRM precast members, various methods for analyzing bond strength, alongside empirical predictive equations, were evaluated. The results revealed that although the rate of increase in bond strength was impacted by the incorporation of steel fibers, the bond strength demonstrated significant improvement in the mortar compressive strength. Introducing steel fibers at a volumetric content of 1% doubled the bond strength. The optimum fiber content was found at 1%, where bond strength increased by 6% and slip by 102% due to effective fiber bridging. Increasing the dosage to 2% yielded only a marginal 2–5% gain, hindered by clustering and poor dispersion. Variations in steel bar diameter had a more pronounced effect on bond stress behavior. The proposed model addresses the underestimation of bond strength and ductility by existing empirical models and code provisions. Full article
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22 pages, 3525 KB  
Article
CFRP–Concrete Interfacial Bond Behavior on Circular Concrete Surfaces in Hygrothermal Marine Environments
by Jia-Wei Zhang and Xiao-Hui Wang
J. Mar. Sci. Eng. 2025, 13(12), 2292; https://doi.org/10.3390/jmse13122292 - 2 Dec 2025
Viewed by 330
Abstract
The strengthening performance of carbon-fiber-reinforced polymer (CFRP) in concrete structures primarily depends on the CFRP–concrete interfacial bond behavior. For CFRP-strengthened circular reinforced concrete (RC) pipe piles in marine environments, the interfacial bond behavior is susceptible to hygrothermal conditions. In this study, cylindrical concrete [...] Read more.
The strengthening performance of carbon-fiber-reinforced polymer (CFRP) in concrete structures primarily depends on the CFRP–concrete interfacial bond behavior. For CFRP-strengthened circular reinforced concrete (RC) pipe piles in marine environments, the interfacial bond behavior is susceptible to hygrothermal conditions. In this study, cylindrical concrete specimens were designed and subjected to pull-off tests to evaluate the CFRP–concrete interfacial performance under simulated marine environmental attacks (3 days in a 50 °C salt spray followed by 4 days of seawater immersion). The deterioration mechanism and failure modes of the CFRP–concrete bond behavior in such environments were analyzed, and relationship equations describing the interfacial bond degradation were proposed and validated. Test results indicated that the CFRP–concrete bond strength at circular interfaces is approximately 21% lower than that at planar interfaces. Under hygrothermal marine conditions, the average CFRP–concrete bond strength remained relatively stable in the early stages due to the competing effects of epoxy plasticization and post-curing, while variability increased significantly in later stages. For test specimens in Group A without concrete surface grinding before CFRP wrapping, an initial bond strength of 1.5 MPa was exhibited, while, for test specimens in Group B, with surface grinding, the initial bond strength started at 2.0 MPa. Both groups experienced a significant CFRP–concrete bond strength reduction of 0.4 MPa after the first wet–dry cycle, with the subsequent average strength stabilizing near initial values. Notably, Group B achieved a peak strength of 3.88 MPa at 84 days, attributed to surface grinding, which enhanced bond strength by 33% and delayed bond failure. The overall stable average strength resulted from averaging high-strength and degraded points. A bond degradation model based on averaged strength reduction was proposed: demonstrating a strength loss of 27%–36% after 98 days of accelerated marine environmental exposure. The proposed equations describing the interfacial bond degradation on a circular concrete surface predict well the flexural capacity of CFRP-wrapped RC beams under similar environmental conditions, where the calculated flexural capacity is 0.8 times the experimental value, confirming the model’s conservative and safe design applicability. Full article
(This article belongs to the Section Coastal Engineering)
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16 pages, 4810 KB  
Article
Thermal Influence on the Mechanical Performance and Deformation Characteristics of Symmetric and Asymmetric GFRP Laminates
by Juveriya Sayyed, Prashantha Acharya, Sriharsha Hegde, Gururaj Bolar, Manjunath Shetty, Thara Reshma I. V. and Padmaraj N. H.
J. Compos. Sci. 2025, 9(11), 636; https://doi.org/10.3390/jcs9110636 - 18 Nov 2025
Viewed by 657
Abstract
The present study investigated the tensile behavior, failure mechanisms and deformation characteristics of glass fiber-reinforced polymer (GFRP) composites with symmetric [0°/90°/90°/0°] and asymmetric [0°/90°/0°/90°] stacking sequences across a temperature range of 30–150 °C. Tensile testing revealed superior mechanical performance in the symmetric lay-up, [...] Read more.
The present study investigated the tensile behavior, failure mechanisms and deformation characteristics of glass fiber-reinforced polymer (GFRP) composites with symmetric [0°/90°/90°/0°] and asymmetric [0°/90°/0°/90°] stacking sequences across a temperature range of 30–150 °C. Tensile testing revealed superior mechanical performance in the symmetric lay-up, with higher tensile strength and failure strain sustained across elevated temperatures. Failure mode analysis revealed a transition from ductile failure to brittle failure with increasing temperature, which was more pronounced in the asymmetric lay-up, along with increased delamination and reduced fiber pull-out. Failure surface examination supported these findings, revealing better interfacial bonding and matrix integrity in the symmetric lay-up. Deformation analysis further confirmed a more homogeneous distribution of strain and longer failure time in symmetric laminates. Across all the metrics, including toughness, energy absorption, and strain uniformity, the symmetric configuration outperformed the asymmetric counterpart, underscoring the critical role of balanced stacking in enhancing the thermal durability. The observed temperature-induced degradation and its impact on mechanical and failure behavior emphasize the need for temperature-sensitive design strategies in GFRP-based structures. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, 3rd Edition)
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31 pages, 17051 KB  
Article
From Nature to Function: Green Composites Using Camphoric Acid-Based Unsaturated Polyester Resin and Bamboo/Flax Non-Woven Reinforcements
by Slavko Mijatov, Sanja Savić, Saša Brzić, Stefan Ivanović, Milena Simić, Milena Milošević and Aleksandar Marinković
Polymers 2025, 17(22), 3038; https://doi.org/10.3390/polym17223038 - 17 Nov 2025
Viewed by 873
Abstract
Unsaturated polyester resins (UPRs) were synthesized from camphoric acid and diluted with styrene, partially replaced (up to 30%) by trimethylolpropane triacrylate (TMPTA). Rheological tests showed increased but sustainable viscosity due to TMPTA’s higher polarity. These UPRs served as matrices for composites reinforced with [...] Read more.
Unsaturated polyester resins (UPRs) were synthesized from camphoric acid and diluted with styrene, partially replaced (up to 30%) by trimethylolpropane triacrylate (TMPTA). Rheological tests showed increased but sustainable viscosity due to TMPTA’s higher polarity. These UPRs served as matrices for composites reinforced with non-woven bamboo and flax mats from recycled waste. Mechanical testing revealed that Cf-UPR/TMPTA30 exhibited the highest tensile strength (25.2 MPa) and modulus (0.96 GPa), compared to 18.7 MPa and 0.74 GPa for the styrene-based resin, respectively, attributed to greater cross-link density. Bamboo composites showed lower tensile properties (13.6 MPa) due to random fiber orientation and porosity, while flax-reinforced systems, especially Cf-UPR/TMPTA30–FLAX, reached 42.7 MPa tensile and 95.5 MPa flexural strength, indicating synergy between TMPTA-modified resin and flax fibers. Dynamic-mechanical analysis confirmed stable thermo-mechanical behavior, and water uptake tests showed reduced absorption (by ~10%), suggesting improved fiber/matrix adhesion. SEM images revealed brittle fracture and fiber pull-out in styrene systems, but fiber breakage and ductile textures in TMPTA-based ones, proving better stress transfer. Thermal analysis indicated slightly earlier degradation onset for TMPTA-modified resins but higher char yield in fiber composites. Overall, TMPTA substitution and flax reinforcement enhance the mechanical, interfacial, and thermal properties of bio-based UPRs, supporting sustainable high-performance composites. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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24 pages, 4712 KB  
Article
Bond Properties of Steel Bar in Polyoxymethylene-Fiber-Reinforced Coral Aggregate Concrete
by Zhuolin Xie, Lin Chen, Lepeng Huang, Junlong Jin, Jianmin Hua, Pow-Seng Yap and Yi Zhang
Polymers 2025, 17(21), 2954; https://doi.org/10.3390/polym17212954 - 6 Nov 2025
Viewed by 886
Abstract
The rapid expansion of island and reef infrastructure has intensified the demand for sustainable concrete materials, yet the scarcity of conventional aggregates and freshwater severely constrains their supply. More critically, the fundamental bonding mechanism between steel reinforcement and coral aggregate concrete (CAC) remains [...] Read more.
The rapid expansion of island and reef infrastructure has intensified the demand for sustainable concrete materials, yet the scarcity of conventional aggregates and freshwater severely constrains their supply. More critically, the fundamental bonding mechanism between steel reinforcement and coral aggregate concrete (CAC) remains poorly understood due to the highly porous, ion-rich nature of coral aggregates and the complex interfacial reactions at the steel–cement–coral interface. Moreover, the synergistic effect of polyoxymethylene (POM) fibers in modifying this interfacial behavior has not yet been systematically quantified. To fill this research gap, this study develops a C40-grade POM-fiber-reinforced CAC and investigates the composition–property relationship governing its bond performance with steel bars. A comprehensive series of pull-out tests was conducted to examine the effects of POM fiber dosage (0, 0.2%, 0.4%, 0.6%, 0.8%, and 1.0%), protective layer thickness (32, 48, and 67 mm), bar type, and anchorage length (2 d, 3 d, 5 d, and 6 d) on the interfacial bond behavior. Results reveal that a 0.6% POM fiber addition optimally enhanced the peak bond stress and restrained radial cracking, indicating a strong fiber-bridging contribution at the micro-interface. A constitutive bond–slip model incorporating the effects of fiber content and c/d ratio was established and experimentally validated. The findings elucidate the multiscale coupling mechanism among coral aggregate, POM fiber, and steel reinforcement, providing theoretical and practical guidance for the design of durable, low-carbon marine concrete structures. Full article
(This article belongs to the Special Issue Polymers in Civil Engineering)
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19 pages, 8459 KB  
Article
Bond Properties Between Bimetallic Steel Bar and Polyoxymethylene Fiber-Reinforced Seawater Sea–Sand Concrete
by Fei Wang, Xuanyi Xue, Neng Wang, Shuai Li, Zhengtao Yang and Yuruo Chang
Polymers 2025, 17(21), 2866; https://doi.org/10.3390/polym17212866 - 27 Oct 2025
Viewed by 535
Abstract
With the development of infrastructure construction, seawater sea–sand concrete (SWSSC) is expected to solve the shortage of freshwater and river sand. Polyoxymethylene (POM) fiber, owing to its excellent corrosion resistance, provides a novel approach to enhancing the bond performance of SWSSC. This study [...] Read more.
With the development of infrastructure construction, seawater sea–sand concrete (SWSSC) is expected to solve the shortage of freshwater and river sand. Polyoxymethylene (POM) fiber, owing to its excellent corrosion resistance, provides a novel approach to enhancing the bond performance of SWSSC. This study systematic study of the bond properties of bimetallic steel bars (BSBs) in POM fiber-reinforced SWSSC and develops a predictive model. Mechanical property tests of SWSSC and pull-out tests of BSB and SWSSC were conducted with various POM fiber contents. The results showed that the optimal volume fraction of POM fibers was 0.6%. At this fraction, the compressive strength and splitting tensile strength of SWSSC were improved by 17.7% and 20.3%, respectively, compared with the group without fibers. All pull-out specimens experienced splitting failure. The bond strength increased monotonically with the increase in relative cover thickness and exhibited a trend of first increasing and then stabilizing with rising POM fiber volume fraction. In addition, a bond stress–slip prediction model between BSBs and POM fiber-reinforced SWSSC was established based on the test results, which can provide theoretical support for the numerical simulation and design of BSB-SWSSC structures. Full article
(This article belongs to the Special Issue Polymers Reinforced Civil Engineering Materials and Components)
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31 pages, 6324 KB  
Article
Interfacial Pull-Out Properties of Surface-Grown Carbon Nanotubes (gCNTs) on Para-Aramid Fabric Material by Chemical Vapor Deposition (CVD)
by Erman Bilisik, Mahmut Korkmaz and Kadir Bilisik
Nanomaterials 2025, 15(21), 1637; https://doi.org/10.3390/nano15211637 - 27 Oct 2025
Viewed by 1433
Abstract
Carbon nanotubes (MWCNTs) were synthesized in situ on para-aramid fabrics (gCPO) via a low-temperature (450 °C) chemical vapor deposition (CVD) process to enhance interfacial pull-out, frictional, and fracture toughness characteristics. FESEM analysis confirmed CNT coverage on fiber surfaces, while FTIR, Raman, and XRD [...] Read more.
Carbon nanotubes (MWCNTs) were synthesized in situ on para-aramid fabrics (gCPO) via a low-temperature (450 °C) chemical vapor deposition (CVD) process to enhance interfacial pull-out, frictional, and fracture toughness characteristics. FESEM analysis confirmed CNT coverage on fiber surfaces, while FTIR, Raman, and XRD results indicated limited structural modification without significant polymer degradation. The CNT-functionalized fabrics exhibited a 66.19% increase in maximum pull-out force, 55.32% improvement in interlacement rupture strength, and a three-fold rise in intra-yarn shear resistance compared with control fabrics (KPO). The static and kinetic friction coefficients increased by 26.67% and 16.67%, respectively, due to CNT-induced surface roughness, enhancing inter-fiber load transfer and reducing slippage. Single-yarn pull-out tests revealed notable gains in energy dissipation and fracture toughness (up to 1769 J/m2), whereas multi-yarn pull-out performance decreased due to excessive friction surpassing filament strength. The study demonstrates that low-temperature MWCNT growth enables effective interfacial reinforcement of soft para-aramid fabrics, establishing a novel framework for meso-scale mechanical screening of flexible nano-ballistic composites. Full article
(This article belongs to the Special Issue Fabrication and Applications of Polymer Nanocomposite Materials)
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23 pages, 3685 KB  
Article
Ballistic Performance of Raffia Fabric-Reinforced Epoxy Composites as an Intermediate Layer in Multilayered Armor Systems
by Douglas Santos Silva, Raí Felipe Pereira Junio, Leticia dos Santos Aguilera, Sergio Neves Monteiro and Marcelo Henrique Prado da Silva
Polymers 2025, 17(21), 2827; https://doi.org/10.3390/polym17212827 - 23 Oct 2025
Cited by 1 | Viewed by 750
Abstract
This study investigates the ballistic performance of epoxy matrix composites reinforced with raffia fabric, aiming to evaluate their potential as the second layer in multilayered armor systems (MAS), replacing conventional synthetic aramid (Kevlar™) laminates. Composite plates with different volumetric fractions of raffia fabric [...] Read more.
This study investigates the ballistic performance of epoxy matrix composites reinforced with raffia fabric, aiming to evaluate their potential as the second layer in multilayered armor systems (MAS), replacing conventional synthetic aramid (Kevlar™) laminates. Composite plates with different volumetric fractions of raffia fabric (10, 20, and 30%) were manufactured and integrated with a ceramic front layer (Al2O3/Nb2O5) in MAS structures, which were then subjected to ballistic impact tests using high-energy 7.62 mm caliber ammunition. The backface signature (indentation depth) measured in ballistic clay, used as a human body simulant, showed that only the 10% raffia-reinforced composite (ER10) met the National Institute of Justice (NIJ 0101.06) safety threshold of 44 mm. Higher raffia contents (20% and 30%) led to increased indentation, compromising ballistic integrity. Scanning electron microscopy (SEM) of the fractured surfaces revealed typical energy dissipation mechanisms, such as fiber rupture, fiber pull-out, and interfacial delamination. The results indicate that raffia fabric composites with 10% fiber content can serve as a cost-effective and sustainable alternative to Kevlar™ in personal armor applications, while maintaining compliance with ballistic protection standards. Full article
(This article belongs to the Special Issue Fiber-Reinforced Polymer Composites: Progress and Prospects)
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