Search Results (84)

The voluminous Mesozoic volcanic rocks developed in the Great Xing’an Range, northeastern China, have received extensive attention in recent decades. However, the timing and petrogenesis, as well as the related geodynamic processes of the Late Mesozoic volcanism, are still controversial. In this paper, we present the whole-rock geochemistry and zircon U–Pb ages for the Late Mesozoic volcanic rocks from the western part of the central Great Xing’an Range, which provide considerable insights into the geodynamic setting of the region. The zircon U-Pb dating results indicate that two main episodes of volcanism occurred in the central Great Xing’an Range, including in the Late Jurassic (ca. 147 Ma) and Early Cretaceous (ca. 142–125 Ma). These Late Mesozoic volcanic rocks display similar geochemical compositions, which are mainly intermediate–felsic, alkaline, peraluminous to metaluminous, enriched in large ion lithophile elements and light rare earth elements, and depleted in high-field-strength elements, indicating arc affinities in the subduction zone. The trace element compositions suggest that the magmatism was related to a post-collisional extensional environment. Combined with the spatial distribution and temporal migration of the Mesozoic magmatic events in the whole northeastern China region, we propose that these Late Jurassic–Early Cretaceous volcanic rocks formed in a continental arc setting, which was mainly related to the rollback of the subducted Paleo-Pacific oceanic plate. Full article

The Baoshan Terrane, as a passive continental margin during the subduction of the Paleo-Tethys Ocean and the lower plate during collision, exhibits a poorly understood magmatic history. This region is characterized by limited magmatic activity and scarce field outcrops, which has hindered a comprehensive understanding of its petrogenesis and geological evolution. This paper presents a chronological and geochemical study of two different types of syn-collisional granites identified in the Mengnuo and Muchang areas in the southern Baoshan Terrane. Our results show that the two types of granites are high-fractionated S-type granites in Bangdong pluton from Mengnuo (zircon U-Pb ages of 230.3 ± 1.4 Ma, 228.7 ± 1.6 Ma and 230.2 ± 1.1 Ma) and A-type granites in Muchang (zircon U-Pb ages of 232.3 ± 1.8 Ma), respectively. Their formation ages are close to the timing of collision, belonging to syn-collisional granites. The Mengnuo high-fractionated S-type granites have SiO₂ contents ranging from 75.15 to 77.78 wt.% with A/CNK of 1.14 to 5.09, and are strongly peraluminous, high-K calc-alkaline granites. They display negative zircon εHf(t) values (−7.72 to −12.32), indicating derivation from partial melting of ancient crustal materials followed by extensive fractional crystallization. In contrast, the Muchang A-type granites contain 73.26 to 76.41 wt.% SiO₂, exhibit low A/CNK ratios (0.92–1.46, average = 1.07), and high Zr + Nb + Ce + Y abundances (313.7 to 3000.3 ppm), characterizing them as weakly peraluminous A-type granites. Further classification reveals that the Muchang granites belong to A1-type granites with positive εHf(t) values (+4.01 to +8.46), indicating the involvement of mantle-derived materials in their magma sources. In this case, combined with results from relevant studies in the Changming-Menglian suture zone, we propose that the Late Triassic magmatism in the Baoshan Terrane was likely triggered by slab break-off during syn-collisional stage. Slab break-off might cause mantle upwelling, resulting in large-scale Lincang batholith and associated volcanic rocks in the upper plate as well as various magmatism activities (S-type and A-type felsic rocks and intraplate basalts) in the Baoshan Terrane. Full article

The Yangtze Block provides a natural window into the tectonic evolution of Precambrian continental crusts. The Julin Group is a dominant Precambrian stratigraphic unit in the southwestern block, the depositional age of which is still poorly constrained. The lowest sequence of this group, the Pudeng Formation, is primarily composed of mica-quartz schists and quartzites intruded by a biotite monzogranite. LA–ICP–MS zircon U-Pb ages of biotite monzogranite and detrital zircons constrain the deposition of the Julin Group to between 1099 and 1052 Ma. Geochemical compositions of the mica-quartz schists and quartzites display high δCe, ΣREE, Th/Sc, and Th/U, along with low δEu, La/Sc, Ce/Th, and Al₂O₃/(Al₂O₃ + Fe₂O₃) ratios, indicating their derivation from felsic volcanic protoliths in a passive continental margin setting. The detrital zircons show distinct age peaks at 2.5, 1.85, and 1.6 Ga, with their source regions primarily located along the western and northern Yangtze Block. Integrating the magmatic records within the Yangtze Block with the ages and ε_Hf(t) values of detrital zircons indicates that the tectonic setting of the western Yangtze Block evolved from a subduction-related arc at ~2.5 Ga to an orogenic belt at ~1.86 Ga and subsequently to intracontinental extensional (rift) environments at ~1.6 Ga and ~1.2 Ga. This evolution reflects the geodynamic transition from the Arrowsmith orogeny to the assembly and development of the Columbia and Rodinia supercontinents. Full article

The Cretaceous marks the peak of magmatic activity in southeastern (SE) China, which is attributed to the subduction of the paleo-Pacific plate beneath the South China Block. This region constitutes a significant igneous belt along the active continental margin of the western Pacific. Despite extensive research, the origin and evolution of Cretaceous felsic volcanic rocks are still debated. This study investigates the characteristics of zircon U-Pb-Hf isotopes and trace elements, and whole-rock geochemistry of Cretaceous volcanic rocks from the Wenzhou–Taizhou region in SE Zhejiang, and discusses their spatio-temporal patterns and petrogenesis. The results indicate that rhyolitic volcanic rocks formed during the period ca. 114 Ma and 95 Ma, representing two distinct magmatic episodes spanning the transition from the late Early to early Late Cretaceous. The late Early Cretaceous and early Late Cretaceous volcanic rocks are of a hybrid crust–mantle origin, as evidenced by their distinct Nb/Ta ratios, zircon ε_Hf(t) values, and variable trace element enrichments (Ti, Hf, U, Nb, and Yb). These compositional signatures suggest partial melting of late Paleoproterozoic to early Mesoproterozoic basement materials, with increasing mantle contributions over time. Both volcanic phases exhibit elevated Nb/Yb, Th/Nb, and U/Yb ratios, indicating a subduction-modified source akin to arc magmas. Together with calculated initial melt temperatures (<800 °C for Early Cretaceous, >800 °C for Late Cretaceous) and whole-rock rare-earth elements (REEs) distribution patterns (U-shaped with δEu = 0.37–0.65, seagull-shaped with δEu = 0.19–0.62, respectively), it is suggested that both phases of the volcanic magmas were generated through water-assisted (hydrous) melting, whereas the later phase formed at relatively higher temperatures and with a diminished water contribution via dehydration melting under extensional conditions. The generation of voluminous high-silica magmas in the SE China coastal region is probably linked to the rollback and retreat of the paleo-Pacific plate. Full article

This study investigates the concentrations and geochemical behaviour of strategic elements—including Li, Co, Ni, Cu, Ga, Ge, rare earth elements (REEs), and yttrium (Y)—in bottom ash samples from the Afşin–Elbistan thermal power plant, Türkiye. Thirty bottom ash samples were analysed, revealing average ∑LREE and ∑HREE concentrations of 86.3 µg/g and 3.3 µg/g, respectively, resulting in an L/H ratio of 24.9, indicating pronounced enrichment in light REEs. The total ∑REE + Y concentration (111 µg/g) is comparable to the background value for coal but approximately 1.5 times lower than those reported for average Chinese coals and the upper continental crust (UCC). REE contents significantly exceed those of sedimentary (5.36 µg/g), mafic (16.77 µg/g), and felsic (3.60 µg/g) rocks. Elevated Li (30.5 µg/g) and Ni (114.4 µg/g) concentrations point to a mafic magmatic source, whereas Cu (28.7 µg/g) likely originates from basic volcanic rocks such as those of the Dağlıca Complex and the Kemaliye Formation. Chondrite-normalised REE patterns show Dy depletion relative to mafic rocks and Ho depletion compared to sedimentary rocks. Positive δEu anomalies (>1) support a mafic or UCC provenance, while slightly positive δCe values indicate hydrothermal leaching influences. The co-precipitation of Ce with Ca–Mg hydroxides and clay minerals in coal-bearing lacustrine sediments is suggested. Ga enrichment is attributed to aluminium-rich clay minerals and organic matter. Overall, these geochemical signatures reflect combined inputs from hydrothermal leaching and volcanic weathering within a coal-bearing lacustrine environment. Full article

This paper describes for the first time a lobe–hyaloclastite felsic complex on an oceanic island of intraplate setting. In the submarine volcanic succession of the Basal Complex of La Palma (Canary Islands), two main units are identified: an older felsic formation and a conformable upper basaltic–trachybasaltic formation. The felsic formation comprises three facies associations: (1) coherent facies, represented by trachytic lobes with porphyritic, aphanitic, or glass trachytes; (2) autoclastic facies, including hyaloclastites and autobreccias; and (3) syn-eruptive resedimented facies, consisting of mono- and polymictic breccias (massive or graded), and of volcaniclastic sandstones and breccias. The internal architecture and facies relationships are consistent with sedimentation in a submarine trachytic lobe–hyaloclastite complex, which predates the basaltic–trachybasaltic formation. These felsic rocks are classified as trachytes, although they exhibit extensive hydrothermal alteration. The behavior of incompatible trace elements suggests that the variety of the trachytic rocks—porphyritic or aphanitic terms—can be attributed to fractional crystallization processes. However, the features of the incompatible trace elements and the rare earth elements indicate that these trachytes are not cogenetic with the submarine basaltic–trachybasaltic rocks of the Basal Complex of La Palma. Instead, the trachytic magmas responsible for the lobe–hyaloclastite complex formation likely represent the late evolution of a precursor basaltic magma that would have led to the formation of a basaltic submarine shield not exposed nowadays. This study also presents the first robust geochronological constraints for the submarine volcanic units of the La Palma Basal Complex, based on U–Pb on zircons and Ar–Ar on amphiboles. Given that the submarine trachytic lobe–hyaloclastite complex is the oldest lithostratigraphic unit exposed on La Palma, a minimum age of 3.10 Ma is proposed for the initiation of the island submarine growth stage. Full article

Widespread Triassic granitic magmatism is archived in the East Kunlun Orogen Belt (EKOB) of Northern Qinghai–Tibet Plateau. Mafic magmatic enclaves (MMEs), commonly hosted in these plutons, are generally interpreted as products of magma mixing; however, the specific magmatic processes remain poorly understood. In this study, we present new data on the complex zoning patterns, in situ U–Pb ages, trace element compositions, and Nd isotopic characteristics of titanite grains from the MMEs and host granodiorite of Laningzaohuo Zhongyou pluton. Whole-rock geochemical data indicate that the pluton is composed of volcanic arc-related, calc-alkaline, metaluminous I-type granodiorite. Titanite in the MMEs and the granodiorite yield similar U–Pb ages of ~244 Ma but display distinct textural and compositional features. Titanite from the granodiorite is typically euhedral, characterized by magmatic core and mantle with deuteric rim, and exhibits sector and fir-tree zoning in the core. In contrast, titanite from the MMEs is generally anhedral, also showing magmatic core and mantle as well as deuteric rims, but exhibits oscillatory zoning and incomplete sector and fir-tree zoning in the core. Titanite cores in the MMEs have ε_Nd(t) ranging from −2.5 to −3.4, comparable to those of the coeval gabbro and MMEs elsewhere in the EKOB. These cores also show higher LREE/HREE ratios compared to titanite cores in the granodiorite, suggesting crystallization from mixed magmas with greater contributions from enriched lithospheric mantle sources. Titanite mantles in the MMEs yield ε_Nd(t) of −4.0 to −4.8, slightly lower than the cores in the MMEs but higher than those of titanite cores and mantles in the granodiorite (−4.6 to −5.5). The mantle can be interpreted as crystallized from mixed magmas with less mafic components. Titanite rims in the MMEs have ε_Nd(t) of −5.0 to −5.7, identical to those in the granodiorite, and have REE concentrations and Th/U and Nb/Ta ratios consistent with the titanite rims in the granodiorite, clearly indicative of crystallization from evolved, hydrated, granodioritic magmas. Plagioclase in the MMEs exhibits disequilibrium textures such as sieve texture and reverse zoning, with An_36–66, contrasting with the more uniform An contents (An_35–37) in the granodiorite. This suggests that plagioclase in the MMEs crystallized in an environment influenced by both mafic and felsic magmas. Amphibole thermobarometry indicates that amphibole in the MMEs crystallized at ~788 °C and ~295 MPa, slightly higher than the crystallization conditions in the granodiorite (~778 °C and ~259 MPa). We thus propose that the chemical and textural differences between titanite in the MMEs and granodiorite suggest that the MMEs formed within a mushy hybrid layer generated by injection of upwelling basaltic magma into a pre-existing granitic magma chamber. Titanite cores and mantles in the MMEs likely crystallized from variably mixed magmas. They subsequently underwent resorption and disequilibrium growth within the hybrid layer, and were eventually overgrown by rims formed from evolved interstitial granitic melts within the mushy enclaves. These findings demonstrate that the complex zoning and geochemical titanite in the MMEs provide valuable insights into magma mixing processes. Full article

In the absence of appropriate tools and a knowledge base for exploring high-grade metamorphic terrains, felsic gneiss complexes at granulite facies have long been considered barren and have remained undermapped and understudied. This was the case of the Bondy gneiss complex in the southwestern Grenville Province of Canada which consists of 1.39–1.35 Ga volcanic and plutonic rocks metamorphosed under granulite facies conditions at 1.19 Ga. Iron oxide–apatite and Cu-Ag-Au mineral occurrences occur among gneisses rich in biotite, cordierite, garnet, K-feldspar, orthopyroxene and/or sillimanite-rich gneisses, plagioclase-cordierite-orthopyroxene white gneisses, magnetite-garnet-rich gneisses, garnetites, hyperaluminous sillimanite-pyrite-quartz gneisses, phlogopite-sillimanite gneisses, and tourmalinites. Petrological and geochemical studies indicate that the precursors of these gneisses are altered volcanic and volcaniclastic rocks with attributes of pre-metamorphic Na, Ca-Fe, K-Fe, K, chloritic, argillic, phyllic, advanced argillic and skarn alteration. The nature of these hydrothermal rocks and the ore deposit model that best represents them are further investigated herein through lithogeochemistry. The lithofacies mineralized in Cu (±Au, Ag, Zn) are distinguished by the presence of garnet, magnetite and zircon, and exhibit pronounced enrichment in Fe, Mg, HREE and Zr relative to the least-altered rocks. In discrimination diagrams, the metamorphosed mineral system is demonstrated to exhibit the diagnostic attributes of, and is interpreted as, a metasomatic iron and alkali-calcic (MIAC) mineral system with iron oxide–apatite (IOA) and iron oxide copper–gold (IOCG) mineralization that evolves toward an epithermal cap. This contribution demonstrates that alteration facies diagnostic of MIAC systems and their IOCG and IOA mineralization remain diagnostic even after high-grade metamorphism. Exploration strategies can thus use the lithogeochemical footprint and the distribution and types of alteration facies observed as pathfinders for the facies-specific deposit types of MIAC systems. Full article

The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao Basin, which provides key insights into the tectonic development of this region. Zircon U–Pb dating of tuff samples from the Linxi Formation provides an accurate age of 251.1 ± 1.1 Ma, corresponding to the late Permian. Geochemical analyses show that the clastic rocks are rich in SiO₂ (63.5%) and Al₂O₃ (13.7%), with lower K₂O/Na₂O ratios (0.01–1.55), suggesting low compositional maturity. Additionally, the trace element data reveal enrichment in light rare earth elements (LREEs) and depletion in Nb, Sr, and Ta, with a negative Eu anomaly, which indicates a felsic volcanic arc origin. The Chemical Index of Alteration (CIA) values (53.2–65.8) reflect weak chemical weathering, consistent with cold and dry paleo-climatic conditions. These findings suggest that the Linxi Formation clastic rocks are derived from felsic volcanic arcs in an active continental margin environment, linked to the subduction of the Paleo-Asian Ocean slab. The sedimentary conditions reflect a gradual transition from brackish to freshwater environments, corresponding with the final stages of subduction or the onset of orogeny. Full article

The Ouarzazate Group in the Anti-Atlas Belt of southern Morocco, part of the West African Craton (WAC), is a significant Proterozoic lithostratigraphic unit formed during the late Ediacaran period. It includes extensive volcanic rocks associated with the early stages of Iapetus Ocean opening. Zircon U-Pb dating and geochemical analyses of the Oued Dar’a Caldera (ODC) volcanic succession in the Saghro Massif reveal two major eruptive cycles corresponding to the lower and upper Ouarzazate Group. The 1st cycle (588–563 Ma) includes pre- and syn-caldera volcanic succession characterized by basaltic andesite to rhyolitic rocks, formed in a volcanic arc setting through lithospheric mantle-derived mafic magmatism and crustal melting. A major caldera-forming eruption occurred approximately 571–562 Ma, with associated rhyolitic dyke swarms indicating a larger caldera extent than previously known. The 2nd cycle (561–543 Ma) features post-caldera bimodal volcanism, with tholeiitic basalts and intraplate felsic magmas, signaling a shift to continental flood basalts and silicic volcanic systems. The entire volcanic activity spans approximately 23–40 million years. This succession is linked to late Ediacaran intracontinental super-eruptions tied to orogenic collapse and continental extension, likely in association with the Central Iapetus Magmatic Province (CIMP), marking a significant transition in the geodynamic evolution of the WAC. Full article

The Yangtze Block, with its widespread Neoproterozoic mafic–felsic magmatic rock series and volcanic–sedimentary rock assemblages, is one of the key windows for reconstructing the assembly and fragmentation process of Rodinia. This study focuses on the Taoyuan syenogranite from the Micangshan Massif on the northern Yangtze Block, by conducting systematic chronology, mineralogy, and geochemistry analyses to investigate their source, petrogenesis, and tectonic setting. LA-ICP-MS U–Pb geochronology reveals that the medium- to coarse-grained and medium- to fine-grained syenogranites have crystallization ages of 878 ± 4.2 Ma and 880 ± 6.5 Ma, respectively. These syenogranites have aluminum saturation index (A/CNK) values ranging from 0.79 to 1.06, indicating quasi-aluminous to weakly peraluminous compositions, and are classified as calc-alkaline I-type granites. The geochemical indicators of these rocks, including Mg^# (44–48, mean 46), Zr/Hf (40.07), Nb/La (0.4), and zircon εHf(t) values (+9.2 to +10.9), collectively indicate a depleted lithospheric mantle source. The mantle source was metasomatized by subduction-derived fluids and sediment melts prior to partial melting as evidenced by their higher Mg^#, elevated Ba content, and distinctive ratios (Rb/Y, Nb/Y, Th/Yb, Th/Sm, Th/Ce, and Ba/La). Integrating regional data, this study confirms crust–mantle interaction along the northern Yangtze during the early Neoproterozoic, supporting a sustained subduction-related tectonic setting. Full article

The attributes of Late Paleozoic magmatic events are of paramount significance in elucidating the tectonic evolution of the Ulanhot region, which is located in the middle of the Hegenshan–Heihe tectonic belt (HHTB). This study undertook a comprehensive investigation of the petrography, LA–ICP–MS zircon U–Pb dating, whole rock geochemistry, and zircon Hf isotopes of the Early Carboniferous volcanic rocks. The volcanic rocks are predominantly composed of andesite, schist (which protolith is rhyolitic tuff), and rhyolitic tuff. The results of zircon U–Pb dating reveal that the formation ages of volcanic rocks are Early Carboniferous (343–347.4 Ma). Geochemical characteristics indicate that the andesites possess a comparatively elevated concentration of Al₂O₃, alongside diminished levels of MgO and TiO₂, belonging to the high-K calc-alkaline series. The zircon εHf(t) of the andesites range from −13 to 9.4, while the two-stage Hf model ages span from 697 to 1937 Ma. The felsic volcanic rocks have high contents of SiO₂ and Na₂O + K₂O, low contents of MgO and TiO₂, and belong to high-K to normal calc-alkaline series. The zircon εHf(t) values of the felsic volcanic rocks range from −12.8 to 10, while the two-stage Hf model ages span from 693 to 2158 Ma. The Early Carboniferous volcanic rocks exhibit a notable enrichment in large ion lithophile elements (LILEs, such as Rb, K, Ba) and light rare earth elements (LREEs), depletion in high-field-strength elements (HFSEs, including Nb, Ta, Ti, Hf), as well as heavy rare earth elements (HREEs). The distribution patterns of the rare earth elements (REEs) demonstrate a conspicuous right-leaning tendency, accompanied by weak negative Eu anomalies. These characteristics indicate that the andesites represent products of multistage mixing and interaction between crustal and mantle materials in a subduction zone setting. The felsic volcanic rocks originated from the partial melting of crustal materials. Early Carboniferous igneous rocks formed in a volcanic arc setting are characteristic of an active continental margin. The identification of Early Carboniferous arc volcanic rocks in the Central Great Xing’an Range suggests that this region was under the subduction background of the oceanic plate subduction before the collision and amalgamation of the Erguna–Xing’an Block and the Songnen Block in the Early Carboniferous. Full article

The Youjiang Basin is situated at the junction between the Tethyan and Pacific tectonic domains, and its Permian–Triassic volcanic rocks provide important geological archives recording the tectonic evolution and collisional interactions between the South China and Indochina blocks. This study employed LA-ICP-MS zircon U-Pb geochronology and whole-rock geochemistry to investigate interbedded Triassic felsic volcanics. Felsic volcanic rocks in Youjiang Basin were erupted during the Early–Middle Triassic period (ca. 241~251 Ma) and are situated within the strata of the Beisi, Baifeng, and Banba Formations. These rocks in the Daqingshan area are rich in SiO₂ (66.8~72.7 wt%), K₂O (1.4~5.1 wt%), U (5.2~6.7 ppm), and Th (26~32.1 ppm). Conversely, they are depleted in MgO (0.6~1.4 wt%), TiO₂ (0.5~0.9 wt%), Cr (13.1~19.7 ppm), Ni (7.3~10.1 ppm), and negative Eu anomalies (Eu/Eu* = 0.41~0.52), and they also exhibit negative zircon ε_Hf(t) values. It is inferred that these Triassic felsic volcanics originated from the partial melting of crustal rocks in high-pressure environments such as the garnet stability zone within the deep mantle. These felsic volcanic rocks were likely generated during the transitional stage from island arc subduction to syn-collisional settings. Notably, the syn-collisional interaction between South China and Indochina blocks exerted significantly greater tectonic control on the Youjiang Basin than oceanic subduction. Full article

The Kumishi ophiolitic mélange contains well-preserved large-scale serpentinites and their accompanying granulites in the eastern South Tianshan Accretionary Complex (STAC), southwestern Altaids. Previous studies have mainly focused on the thermodynamic conditions and tectonic setting of granulites. However, the petrogenesis of the widespread serpentinites in the Kumishi ophiolitic mélange remains largely unexplored. In this paper, petrological, geochemical, and geochronological studies were carried out on the Kumishi serpentinites, as well as the host sediment and intermediate–felsic volcanic rocks. The serpentinites show variable LOI values of 8.3–16.5 wt% and relatively consistent SiO₂/(sum oxides) ratios of 0.81, which demonstrate that the major elements of their protoliths have been preserved well during serpentinization. Multi-trace element and REE diagrams suggest that the protoliths of the Kumishi serpentinites have experienced varying degrees of refertilization, with distinct natures seen between the Yushugou, Tonghuashan, and Liuhuangshan serpentinites. Zircon U-Pb chronology of the Tonghuahsan serpentinites yields a mean age of 355.8 ± 7.3 Ma (MSWD = 1.0, N = 26). Detrital zircons from the host sediment record a maximum depositional age of 375 ± 10 Ma (MSWD = 0.4, N = 3), with a peak at ca.419 Ma. Subduction-related volcanic rocks yield ages of ca.437 Ma. Hence, clues are provided to the petrogenesis of the Kumishi serpentinites, with calls for future in-depth works from an isotopic perspective. Full article

Post-collisional volcanism provides valuable insights into mantle dynamics, crustal processes, and mechanisms driving orogen uplift and collapse. This study presents geological, geochemical, and geochronological data for Ediacaran effusive and pyroclastic units from the Taghdout Volcanic Field (TVF) in the Siroua Window, Anti-Atlas Belt. Two eruptive cycles are identified based on volcanological and geochemical signatures. The first cycle comprises a diverse volcanic succession of basalts, basaltic andesites, andesites, dacites, and rhyolitic crystal-rich tuffs and ignimbrites, exhibiting arc calc-alkaline affinities. These mafic magmas were derived from a lithospheric mantle metasomatized by subduction-related fluids and are associated with the gravitational collapse of the Pan-African Orogen. The second cycle is marked by bimodal volcanism, featuring tholeiitic basalts sourced from the asthenospheric mantle and felsic intraplate magmas. These units display volcanological characteristics typical of facies models for continental basaltsuccessions and continental felsic volcanoes. Precise CA-ID-TIMS U-Pb zircon dating constrains the volcanic activity to 575–557 Ma, reflecting an 18-million-year period of lithospheric thinning, delamination, and asthenospheric upwelling. This progression marks the transition from orogen collapse to continental rifting, culminating in the breakup of the Rodinia supercontinent and the opening of the Iapetus Ocean. The TVF exemplifies the dynamic interplay between lithospheric and asthenospheric processes during post-collisional tectonic evolution. Full article