Search Results (5,623)

This work investigates the fabrication and performance of axially compressed isotropic epoxy-bonded NdFeB-type magnets produced from melt-spun powders with partial substitution of (Nd,Pr) by (La,Ce). Four alloy compositions were synthesized and processed into bonded magnets using two powder-to-binder weight ratios (95:5 and 96.5:3.5). Structural analysis confirms that all substituted alloys retain the tetragonal Nd₂Fe₁₄B phase (up to ~95 wt%) even at high substitution levels, while the lattice parameters decrease slightly with increasing (La,Ce) content. Microscopy analysis confirms a homogeneous distribution of the binder phase around the powder particles, demonstrating uniform binder–powder integration. Thermal analysis reveals composition-dependent Curie temperatures and enhanced crystallization onset in highly substituted powders. Magnetic measurements on both powders and bonded magnets show that increasing substitution leads to a gradual reduction in remanence, coercivity, and energy product, though all samples maintain strong hard-magnetic behavior. Increasing the powder fraction to 96.5 wt.% significantly improves all magnetic parameters due to higher magnetic-phase density and enhanced interparticle coupling, yielding bonded magnets with densities up to ~80% of the theoretical value. The resulting magnets achieve competitive performance, uniform field distribution and isotropic magnetization with (BH)max values about 65 kJ/m³, a coercivity around 660 kA/m, and superior thermal stability compared with commercial bonded NdFeB magnets. Overall, partial substitution with light rare-earth elements (La,Ce) provides a cost-effective route to high-density bonded NdFeB magnets that combine strong magnetic performance, enhanced thermal stability, and suitability for lightweight, complex-shaped industrial applications. Surprisingly, the coefficients of the temperature variation of coercivity and (BH)_max are much better compared to the commercial NdFeB bonded magnets. Full article

This study developed an optimized processing strategy for γ-aminobutyric acid (GABA) instant white tea (GABA-IT) using GABA-enriched white tea as raw material, systematically characterizing its chemical composition and volatile profile. In contrast to the conventional instant tea production process, this work integrates response surface methodology with spray-drying parameter optimization. This integrated approach enables the simultaneous enhancement of functional components and sensory quality. A response surface design was employed to refine the extraction and spray-drying variables following preliminary single-factor trials, and the optimal parameter combination was subsequently determined (40% ethanol concentration, material-to-liquid ratio of 1:15, extraction time of 3 days, atomization speed of 300 rpm, and inlet temperature of 120 °C); the resulting GABA-IT exhibited significantly improved quality characteristics. Specifically, the GABA content increased by 209% (reaching 4.42 mg/g), and theanine, catechins, and caffeine were enriched by 200–300%. Regarding volatile profiles, processing led to a reduction in esters but an increase in aldehydes and hydrocarbons. Relative odor activity value (rOAV) analysis revealed that epoxy-β-ionone and linalool were the key contributors to the characteristic aroma of GABA-IT. Collectively, this study demonstrates the technical feasibility of producing GABA-rich instant tea with enhanced functional components and improved sensory quality, providing practical guidance for the large-scale industrial production of functional tea beverages. Full article

This study explores the use of banana pseudostem fibers from Córdoba, Colombia, as reinforcement in polymer composites manufactured through vacuum-assisted resin transfer molding (VARTM). The fibers were decorticated, oven-dried at 40 °C, and subjected to mercerization and epoxy coating treatments. Plain-weave fabrics were produced using continuous yarns composed of 10 and 15 fibers, both treated and untreated. Experimental analyses included pull-out tests, thermogravimetric analysis, fourier-transform infrared spectroscopy, winding speed, surface twist angle, and tensile strength tests for yarns, as well as tensile load, adhesion, and permeability tests for fabrics and tensile and flexural strength tests for composites. Treated yarns exhibited a slight increase in diameter and a lower extraction (25%) compared to untreated yarns (33%). Although treated fabrics showed enhanced permeability and improved resin infiltration, untreated fabrics demonstrated superior mechanical performance, with a tensile load of 2.33 kN in comparison to 1.37 kN for treated yarns. The highest tensile strength of 76.56 MPa was achieved in composites reinforced with three layers of untreated fabric, while the best flexural strength of 86.93 MPa was observed in single-layer composites with the same configuration. These results emphasize the potential of untreated banana fiber fabrics as promising reinforcement in structural composite applications. Full article

Tourmaline nanoparticle-reinforced DGEBA/MTHPA epoxy nanocomposites were developed to obtain mechanically robust insulating materials with reduced dielectric loss. Composites containing 0–20 phr tourmaline were prepared by mechanical mixing, vacuum degassing, and stepwise curing, and FTIR verified successful curing and network formation. Tourmaline delivered stiffness-dominated reinforcement, increasing the flexural modulus from 2.585 to 4.07 GPa. At 5 phr, the composites reached simultaneous maxima in flexural strength and impact strength, corresponding to improvements of 5.02% and 57.4% over the unfilled resin, respectively. Moreover, the modified epoxy thermosets still maintained excellent T_g and thermal decomposition temperature. Electrical insulation improved concurrently, as volume resistivity increased from 1.36 × 10¹⁶ Ω·cm for EP-0 to 1.89 × 10¹⁶ Ω·cm for EP-20, and surface resistivity rose from 1.72 × 10¹⁵ to 2.49 × 10¹⁵ Ω, giving 9.6–39.0% and 14.2–44.9% gains for EP-5 to EP-20. Notably, at 50 Hz, 5 phr tourmaline preserved a low permittivity of 4.360 while reducing dielectric loss tangent (tan δ) from 0.0270 to 0.0190, a 29.6% decrease. Collectively, these improvements reduce dielectric heating and support reliable operation of epoxy-based insulation in power equipment. Full article

Developing polymer composites with improved mechanical and thermal properties requires strategies to overcome the problem of agglomeration and weak interfacial interactions of carbon nanofillers. This paper presents an effective strategy for the covalent functionalization of graphene oxide (GO) with melamine to create high-performance epoxy nanocomposites. The functionalization results in the formation of nitrogen-containing heterocyclic structures on the GO surface, as confirmed by FTIR and Raman spectroscopy. The addition of the obtained modified filler (mel-GO) into the epoxy matrix provides a synergistic effect: the melamine amino groups catalytically accelerate curing, reducing the gelation time from 146 to 48 min and increasing the maximum self-heating temperature from 94 to 122 °C, thus indicating enhanced interfacial interaction. This interaction results in a remarkable overall improvement in mechanical properties: tensile and flexural strengths increase by more than 20%, and elastic moduli by 31% and 58%, respectively, compared to the composite containing unmodified GO. At the same time, impact strength (from 14 to 23 kJ/m²) and hardness (up to 87 Shore D) increase. A key achievement is a dramatic increase in thermal and thermal-oxidative stability: the onset temperature of decomposition (T₅%) increases by 27 °C, the half-decomposition temperature (T₅₀%) by 45 °C, and the thermal stability index (THRI) increases from 119.3 to 128.9 °C. A more than twofold increase in coke residue yield (to 9.29%) and an increase in the Vicat softening point to 175 °C confirm the formation of an effective thermally stabilizing barrier layer due to the combined action of nitrogen-containing groups and dispersed graphene flakes. The proposed approach to functionalizing graphene oxide with melamine opens the way for the creation of next-generation epoxy composites with a record-breaking combination of strength, impact toughness, and thermal stability for applications in aerospace, electronics, and composite structures operating under extreme conditions. Full article

This paper investigates the fatigue and residual strength behavior of recycled carbon fiber reinforced plastics (rCFRPs) with different fiber architectures in an epoxy resin matrix: a unidirectional (UD) rCFRP and a non-crimp fabric (NCF) composite. Due to the research gap in fatigue testing of recycled carbon fiber-reinforced plastics with quasi-continuous fiber reinforcement, their fatigue properties are investigated in this article. The objective of the present study is to contribute to the broader goal of integrating recycled carbon fibers as quasi-continuous fiber reinforcement in structural applications by understanding their failure behavior. To determine suitable stress levels for fatigue testing, quasi-static tensile tests are conducted first. Subsequently, fatigue tests are performed with a stress ratio of 0.1. Damage evolution is documented by a continuous recording of the stiffness degradation. For the unidirectional material, an S-N_f curve is created based on three stress levels. The curve can be described with a logarithmic equation. Fatigue testing of the NCF laminate is performed at a single stress level. Subsequent residual strength tests using standard specimens show no clear correlation between the number of load cycles of pre-cycling and residual strength, but indicate a sudden-death behavior for both composites. For further investigation of the damage behavior, in situ residual strength tests are carried out using a combination of acoustic emission analysis and micro-computed tomography (µCT) imaging. This investigation is intended to illustrate crack initiation and propagation three-dimensionally after pre-cycling and during residual strength tests. The results demonstrate a significant influence of the microstructure on the failure behavior. Full article

The main purpose of this study was to investigate the effects of 10, 20, and 40 wt% micron-sized particles (aluminum nitride, aluminum oxide, silicon nitride, and silicon oxide) on the thermal performance of an epoxy resin used in microelectronic devices. Specimens were produced via a solution mixing technique followed by molding and curing. Although there were slight differences between the particle types used, various thermal analyses revealed that increasing the amount of all particle types significantly improved the thermal performance of the epoxy resin. The property that influences the thermal performance of microelectronic devices the most is thermal conductivity (λ). Heat produced during operation should be released via heat diffusion, which requires a certain level of λ. In this study, the use of a 40 wt% particle content increased the thermal conductivity (λ) by more than 3 times compared to neat epoxy (0.15 W/m·K). Another significant problem during the operation of these devices is the formation of “thermal strain mismatch” due to the different thermal expansion coefficients (α) of the materials used in the device that might lead to a loss of dimensional stability and malfunctioning. In this study, a particle content of 40 wt% decreased the thermal expansion coefficient of epoxy (49 × 10⁻⁶/K) down to 28 × 10⁻⁶/K, a decrease of −43%. Thermal performance also depends on the Glass Transition Temperature (T_g) values. In this study, a particle content of 40 wt% increased the T_g from 51 °C (neat epoxy) to 68 °C, an increase of 17 °C, and increased the Thermal Degradation Temperature (T_d) from 324 °C (neat epoxy) to 356 °C, an increase of 32 °C. Moreover, it was also revealed that there was no decrease in the lap shear adhesion strength of the epoxy resin after incorporation of any of the particle types. Additionally, the particles also increased the mechanical rigidity of the epoxy in terms of Storage Modulus at 25 °C and 50 °C. Full article

A composite meeting the UL94 V-0 rating was produced by adding 30 wt% epoxy silane-modified aluminum trihydrate (EPATH) to a 60/40 epoxy/benzoxazine matrix. Various bimodal and trimodal composites containing 20–40 wt% of three types of ceramic fillers, i.e., aluminum oxide (Al₂O₃), boron nitride (BN), and magnesium oxide (MgO), were prepared to simultaneously achieve flame-retardant and thermal conductive properties. The bimodal composites with 40 wt% of Al₂O₃ and MgO exhibited thermal conductivities of 1.22 W/m∙K and 1.29 W/m∙K, respectively, which were superior to that of the composite containing the same amount of ATH (1.0 W/m∙K). In contrast, both the coefficient of thermal expansion (CTE) and shear strength decreased with increasing ceramic filler content. For agglomerated BN, the filler loading was constrained above 30 wt% because its high specific volume caused a significant rise in the viscosity. In the trimodal composites with a total filler content of 40 wt% of Al₂O₃ and BN, a BN fraction of 7.5 wt% yielded the highest thermal conductivity of 1.64 W/m∙K and the lowest water absorption of 0.69%. When the trimodal composites were exposed to −55 °C and 150 °C for 1000 h, they exhibited a reduction in shear strength of less than 30% compared to their initial values. Full article

Melamine polyphosphate (MPP) is a widely employed additive-type flame retardant for polyamide 6. Generally, a higher loading of MPP leads to improved flame retardancy of polyamide 6 composites. Nevertheless, excessive addition tends to cause problems such as flame-retardant migration, leakage, and exudation. Against this background, this work focuses on covalently grafting melamine polyphosphate onto the surface of carbon nanotubes via a facile chemical reaction, with the aim of alleviating the migration and leakage of the flame retardant in the polyamide 6 matrix. Carbon nanotubes (CNTs) were surface modified with a silane coupling agent (KH560) to obtain CNTs bearing epoxy groups (CNT-KH560). Subsequently, a ring-opening addition reaction was conducted between the CNT-KH560 and melamine polyphosphate (MPP) yielding carbon nanotubes with surface-bonded flame-retardant MPP (CNTM). Polyamide 6 composite slices (PA6/CNTM) were prepared via twin-screw extrusion blending and compounding and then by hot-press molding into test specimens. The modified carbon nanotubes were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The results confirmed the successful grafting of MPP onto the carbon nanotube surface, with a grafting degree of 9.1 g/100 g measured. The flame retardancy of the PA6/CNTM composites were evaluated through UL 94 vertical burning and limiting oxygen index (LOI) tests and cone calorimeter. These flame retardancy results indicated that when the content of flame-retardant-modified carbon nanotubes was 10 wt%, the PA6/CNTM10 composites achieved UL 94 V-2 and the limiting oxygen index increased from 24.5% of pure PA6 to 29.1%. The PHRR value of pure PA6 decreased from 750 kW/m² to 614 kW/m². This design of surface-grafted flame retardant provides a new strategy for the preparation and application of high-performance polyamide 6 flame-retardant composites. Full article

Molybdenum disulfide (MoS₂)-based composite systems are widely used as solid lubricating coatings. However, further optimization towards lower friction and higher wear resistance remains necessary to meet the extreme operating conditions and high reliability requirements of next-generation aerospace equipment. This study investigated the tribological performance of MoS₂/epoxy composite coatings by comparing the effects of individual and combined additions of nano nickel (Ni) and magnesium silicate hydroxide (MSH). The coating preparation process adopted in this study is the bonding method. Experimental results showed that, under a load of 2 N and a rotational speed of 500 r/min, the coating containing 0.3 g Ni and 0.1 g MSH (labeled W03Ni01MSH) achieved a 22% reduction in wear scar width compared to the coating with only Ni, demonstrating a distinct synergistic effect. This is attributed to the complementary roles of the two additives: Ni promotes the formation of flaky wear debris, facilitating rapid formation and stabilization of a transfer film, thereby reducing friction; MSH enhances the load carrying capacity of the coating and suppresses wear propagation, thereby improving wear resistance. Furthermore, this composite coating exhibited optimal performance under the conditions of 500 r/min and 2 N. The results of this study significantly improved the friction-reducing and wear-resistant properties of the MoS₂/epoxy composite coating. This provides a new strategy for the formulation design of high-performance solid lubricating coatings. Full article

Conventional Fiber-Reinforced Polymer (FRP) materials may exhibit certain performance uncertainties in harsh environments, limiting their reliability for structural strengthening. To address this, Basalt Fiber-Reinforced Polymer (BFRP) plates fabricated with silicate-modified epoxy resin are proposed for the flexural strengthening of reinforced concrete (RC) beams. The research aims to evaluate their short-term strengthening performance and establish a reliable calculation method for flexural capacity. Four-point bending tests were conducted to investigate the effects of BFRP plate thickness and end anchorage configuration on failure modes, flexural capacity, and ductility. Finite element simulations incorporating interfacial bond–slip behavior reproduced typical debonding failures, followed by a comprehensive parametric analysis. Based on the experimental and numerical results, a modified BFRP plate strain formula at debonding was proposed to establish a calculation method for the flexural capacity of BFRP-strengthened beams governed by debonding failure. The results indicate that beams without end anchorage were prone to interfacial debonding, where increasing the plate thickness from 0.5 mm to 2 mm raised the flexural capacity gain from 4.5% to 15% but intensified the ductility reduction from 42.9% to 64.9%. Conversely, applying mechanical anchorage improved the ductility index by over 20% compared to unanchored counterparts. The adopted FRP–concrete bond–slip constitutive model accurately characterizes interfacial debonding behavior, and the proposed flexural capacity model demonstrates high accuracy with overall deviations within 5%. It can be concluded that the novel BFRP plates exhibit strengthening behavior comparable to existing FRP systems. Effective end anchorage further enhances flexural capacity and prevents brittle failure. The proposed debonding strain formula for the novel BFRP system offers a reliable basis for capturing the critical onset of interfacial failure. Building upon this, the developed flexural capacity model provides a reliable theoretical basis for the design and assessment of RC beams strengthened with the novel BFRP plates. Full article

Hydrogen storage vessels are critical components in hydrogen energy systems, and improving their manufacturing efficiency and structural performance is essential for next-generation Type IV vessel designs. Compared with conventional wet filament winding, towpreg dry filament winding offers higher efficiency, reduced environmental impact, and better adaptability to complex structures. In this study, key process parameters, including winding tension, heating temperature, and winding speed were systematically optimized using the tensile strength and interlaminar shear strength of NOL ring specimens as evaluation metrics. A response surface methodology (RSM) regression model was established to correlate process variables with mechanical properties, followed by multi-objective optimization using the non-dominated sorting genetic algorithm II (NSGA-II) and final parameter selection through the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) method. The results indicate that shear strength is primarily affected by heating temperature, whereas tensile strength is mainly governed by winding tension. The optimal parameter combination (79 N, 360 °C, and 11 m/min) yielded tensile and shear strengths of 2462.2 MPa and 64.4 MPa, respectively, with prediction errors below 0.5%. A 9 L Type IV hydrogen storage vessel manufactured under these conditions showed approximately 15.4% lower mass and about 17% higher gravimetric hydrogen storage efficiency than a comparable wet wound vessel. Full article

The application of fiber-reinforced polymer bars has been considered an alternative for the non-metallic reinforcement of concrete structures. Basalt fiber-reinforced polymer (BFRP) is a new composite used to reinforce concrete structures. However, the main drawback of BFRP is its low modulus of elasticity. Therefore, hybrid reinforced fiber polymers, in which carbon fibers replace part of the basalt fibers, might be considered as a relatively “simple” modification that can increase the modulus of elasticity. The literature data suggest that modification of the epoxy matrix with nanosilica particles can positively influence resistance to high temperatures. Besides the mechanical characteristics of FRPs, the evaluation of alkali resistance is necessary for technical approval for construction applications. This paper focuses on testing the alkali resistance of basalt fiber-reinforced polymer (BFRP) bars and its modification through the partial substitution of basalt fibers with carbon fibers (HFRP) and the addition of nanosilica to the epoxy binder (nHFRP). The alkali resistance was tested based on the most common method described in ACI report 440.3R-04—part B6. This method consists of three procedures carried out at 60 °C on the specimens immersed in an alkaline solution, both with and without load. The changes in the mass and tensile strength of the bars are examined after 1, 2, 3, 4, and 6 months. The test procedures are time-consuming and expensive, particularly Procedures B (in alkaline solution) and C (in concrete cover), in which longitudinal tested specimens must be immersed in alkaline solution and subjected to constant strain at an elevated temperature for a 6-month period. Therefore, this study proposes a test setup to achieve a less time-consuming and cheaper assessment of the alkali resistance of FRP bars. Additionally, the usefulness of the shear strength test for the evaluation of alkali resistance of FRP bars is also discussed. The results (Procedure A) indicate that modification of the composition of BFRP did not decrease the resistance to the alkaline environment in the case of HFRP (5% lower than in the case of BFRP). Under the same conditions, the decrease in the tensile strength of nHFRP was 40% higher than in the case of BFRP. This indicates that additional modification of the composition by adding nanosilica to the epoxy binder did not provide the expected stability of tensile properties at elevated temperatures. The results of the evaluation of alkali resistance according to Procedure B show that the device proposed for maintaining constant strain during the seasoning is promising. At this stage, the device makes it possible to conduct the tests at ambient temperature and yields a significantly lower decrease in tensile strength (10–14%) after 6 months, demonstrating a significant effect of temperature on the results of the FRP alkali resistance test. Full article

Recently, epoxy resin concrete (ERC) has shown significant potential in rapid repair applications, such as bridge expansion joints, owing to its early strength gain, rapid hardening, excellent adhesion, and durability. Based on the background of rapid repair scenarios for small- and medium-span bridges, this study designed a mix proportion of ERC. A systematic investigation was conducted on its mechanical properties and constitutive model under various curing temperatures (5 °C, 20 °C, and 35 °C) and ages. Experimental results indicate that the designed ERC cures within 2 to 6 h and achieves a compressive strength of 15 MPa at 1 day, meeting the requirement for early traffic reopening. Both material strength and elastic modulus increase significantly with age, reaching a compressive elastic modulus of 16 GPa at 90 days. Based on the measured uniaxial compressive and tensile stress–strain data, a temperature-dependent constitutive model was established. The fitting parameters exhibit a quadratic functional relationship with curing temperature. The model demonstrates high fitting accuracy under all tested conditions (R² ≥ 0.9293). This study provides a theoretical basis and data support for the application and numerical simulation of ERC in bridge engineering. Full article

The integration of shape-memory alloy (SMA) wires into composite laminates offers a promising approach for active vibration damping. Towards this goal, this study investigates the damping behavior of hybrid random mat E-glass/epoxy composite plates with embedded SMA wires under electrically active and inactive conditions. The composites are tested using a Laser Doppler Vibrometer (LDV) and an impact hammer to assess the effect of SMA wire activation on the natural frequencies and vibration behavior of composites. For a fixed number of active SMA wires, differences in vibration behavior are evaluated between outer- and inner-wire activation configurations in both two-ply and four-ply composite plates. The results show that SMA wire activation significantly affects damping behavior, while the mode shapes remain unchanged. The magnitude and frequency of the first natural frequency as well as the quality factor (Q-factor) decrease in composites with activated SMA wires compared to the inactive configuration, indicating enhanced energy dissipation. Under the fully active condition, a reduction in vibrational amplitude of approximately 42–60% and a frequency shift of approximately 10–17% are observed. Compared to outer-wire activation, inner-wire activation results in greater reductions in vibration magnitude, reaching approximately 7–13%. Full article