Search Results (2,613)

Multifunctional nanocarriers capable of integrating imaging, magnetic functionality, and controlled drug delivery represent an important research topic in cancer nanomedicine. Herein, Mn-doped (Fe₃O₄) magnetite nanoparticles (MNPs) were engineered and incorporated into a Maisine CC-based oil-in-water microemulsion (ME) to obtain a multifunctional nanoplatform for magnetic resonance imaging (MRI), hyperthermia, and controlled drug release. A series of Mn-doped MNPs (1–10% Mn:Fe₃O₄) was synthesized by coprecipitation. X-ray diffraction confirmed the preservation of the cubic spinel upon Mn incorporation. The Mn incorporation resulted in MNPs made of crystallites (~9–12 nm) whose magnetic properties were improved. Also, 10% Mn led to a very good magnetic heating efficiency under alternating magnetic fields with a specific absorption rate of ~111 W·g⁻¹. The obtained MNPs proved to be T₂-weighted MRI contrast agents, with an increase in the r₂ values up to ~844 mM⁻¹·s⁻¹ after incorporation into ME. The optimized composition of Mn_10% was subsequently loaded with doxorubicin (DOX) and integrated into ME. Drug-release studies revealed a biphasic profile, characterized by an initial burst phase followed by sustained release up to 48 h. These findings demonstrate that dopant-engineered MNPs combined with a ME carrier can provide a versatile platform for integrating magnetic hyperthermia potential, T₂-weighted MRI contrast enhancement, and controlled chemotherapeutic delivery within a single nanostructured system. Full article

Nanomaterials (NMs) have shown broad application potential in wastewater deep treatment, but the actual application is constrained by some issues such as nanoparticle (NP) aggregation and poor recyclability. Different from previous comprehensive reviews, this article systematically synthesizes data from over 100 peer-reviewed studies (2012 to 2026) to review the preparation methods, purification mechanisms, and removal efficiencies for various pollutants, and the technical and economic feasibility of NMs, with an emphasis on carrier-assisted immobilization and NM–microbial aggregate interactions. To start with, the methods of preparation were roughly distinguished into two categories which were “top-down” and “bottom-up” methods. The advantages, disadvantages, and utilities of the physical, chemical, and eco-friendly methods of biosynthesis were investigated while paying particular attention to the function of the loading technique in preventing NP aggregation and improving recyclability. By using the technique of loading in the carrier, the growth of NPs could be restricted up to 2–50 nm. Secondly, seven basic mechanisms that underlie the process of removing pollutants by using NPs were explained: adsorption, catalytic degradation, ion exchange, surface complexation, antibacterial action, redox transformation, and waste recycling. Particular focus was placed on understanding the interactions between NMs, microbial aggregates, and extracellular polymeric substances in wastewater treatment systems. Extracellular polymeric substances (EPS) could capture >90% NMs and mitigate their toxicity. Once again, the removal efficiency and main influencing factors associated with different types of NMs, for the treatment of heavy metals, dyes, antibiotics, and pathogenic microorganisms were summarized. Removal efficiencies of the pollutants ranged from 70% to over 99%, but these values were strongly influenced by pH and matrix and often decreased substantially in real wastewater. The existing literature was used to classify the experimental substrates (single-solute systems, multi-solute synthetic systems, municipal wastewater, industrial wastewater, secondary effluent). The performance of NMs in different categories was compared, revealing the huge performance gap between ideal laboratory conditions and practical applications. Lastly, the economic viability of the methods based on the use of NMs for purifying water was assessed taking into consideration various factors such as raw materials’ prices, energy costs of the process of making materials, recyclability of the materials, and the possibility of introducing the use of NMs on a larger scale. Unlike existing reviews, this article aims to provide a quantitative mechanistic framework bridging the rational design, safe application, and engineering promotion of NMs in deep wastewater treatment. Full article

Confronted with severe global challenges, including water scarcity, excessive use of chemical fertilizers and pesticides, and heavy metal contamination in soils, conventional agricultural technologies exhibit marked limitations in integrated water–fertilizer management and non-point source pollution control. Leveraging their excellent water retention capacity, intelligent sustained-release properties, and environmental responsiveness, hydrogels offer innovative solutions to advance sustainable agricultural development. This review comprehensively outlines the fundamental types, crosslinking mechanisms, and key functional properties of hydrogels, with a focused discussion on their agricultural deployment as high-efficiency soil conditioners, fertilizer vectors, and pesticide carriers; it deciphers the microscopic water-holding mechanisms under the tristate water model, delineates the divergent water-uptake and retention behaviors between ionic and non-ionic hydrogels, and clarifies the cyclic water-holding and release mechanisms of hydrogels during soil amelioration. Thise paper further synthesizes hydrogel-enabled environmental remediation applications, in which heavy metals and pesticide residues in soils and aquatic systems are removed via functional-group coordination adsorption or photocatalytic degradation; concurrently, hydrogels have been shown to activate plant systemic immunity through calcium-signaling pathways, thereby inducing broad-spectrum antiviral defense responses. Moreover, hydrogels can be integrated into precision agriculture frameworks to enable real-time monitoring of crop physiological status and to support targeted irrigation and fertilization management. This work also evaluates the role of hydrogels in promoting seed germination, root system development, crop metabolic regulation, and stress resilience, while introducing tailored application strategies across distinct plant growth stages. Their documented economic advantages include water conservation, enhanced crop yields, reduced dependence on synthetic fertilizers, and lower labor costs. Nevertheless, the large-scale implementation of hydrogels continues to face multifaceted challenges—particularly poor degradability and latent ecological risks, as conventional polyacrylamide (PAM)-based gels resist soil mineralization and retain potentially neurotoxic monomers, leaving a critical gap in multi-annual field data concerning their non-target interference with native soil aggregate evolution, pore distribution, and rhizospheric carbon–nitrogen footprints. Mechanistically, many hydrogels with tensile strengths below 1 MPa are highly susceptible to three-dimensional network collapse under high-salinity osmotic shock and tillage mechanical stress, exhibiting a precipitous drop in water retention after more than three wet–dry cycles due to deficient long-term structural stability. Compounding these technical gaps are elevated production costs and low farmer adoption, driven by the absence of texture-specific performance thresholds—such as an available water increment ≥ 40% for sandy soils—and the lack of established life-cycle cost models and farmer incentive mechanisms for bio-based hydrogels. Moving forward, hydrogel technology should pivot toward materials innovation and cost-reduction engineering to broaden its applicability, employ ≥3-year, multi-habitat regional trials to delineate ecological benefit–risk boundaries, and ultimately position hydrogels as pivotal enablers of sustainable, green agricultural paradigms. Full article

Leakage from water distribution networks (WDNs) are one of the most persistent inefficiencies in urban water management. Global non-revenue water (NRW) volumes have remained broadly stable over two decades despite major technical investment in detection, pressure management, and pipe deterioration modeling, implying a structural obstacle that technical solutions alone cannot resolve. This review argues that the underlying reason is conceptual. Leakage has been treated predominantly as an engineering problem. In reality, it is the visible outcome of three interacting failure domains: physical infrastructure deterioration, climate-driven stress amplification, and governance and institutional inadequacy. No existing review integrates all three domains into a unified diagnostic framework. This paper introduces the Three-Domain Systems Failure Framework (TDSFF) as a structured diagnostic approach to the root causes of WDN leakage. A structured literature review of 58 peer-reviewed and authoritative sources, including gray literature, is presented. Eight comparative tables and five original figures synthesize evidence across global contexts from high-income OECD networks to Sub-Saharan African utilities. An operational four-step classification protocol enables practitioners to apply the TDSFF directly to real utility contexts. The framework and the protocol are presented as proposals. Key findings are as follows. Infrastructure deterioration is necessary but insufficient as an explanation for observed leakage levels. Climate change is increasingly observed to accelerate pipe failure rates through soil movement, thermal cycling, and altered pressure dynamics, with impacts underrepresented in current engineering design practice. Governance failures, including deferred maintenance cycles, absent regulatory NRW targets, and chronic underinvestment, explain the persistence of leakage independent of physical deterioration. Technical solutions achieve limited system-level impact when governance preconditions for sustained management are absent. The TDSFF is offered as a practitioner-facing diagnostic aid to identify the dominant failure domain and direct investigation accordingly. Relationships between the domains rest on observational evidence and are reported as associations, not as estimated causal effects. Full article

Against the backdrop of rapid development in marine engineering, the construction industry faces practical challenges, such as water scarcity, limited availability of natural river sand, and high raw material transportation costs. This has led to an increasing demand for resource-efficient concrete production technologies and improved construction economic efficiency. Seawater–sea-sand concrete (SWSSC) offers a locally sourced solution that effectively reduces the construction sector’s overreliance on freshwater and river sand, lowers material transportation costs for coastal infrastructure projects, and supports marine engineering and infrastructure development along the Belt and Road Initiative. However, existing research lacks systematic organization and visualized quantitative analysis. Utilizing the CiteSpace 7.0.R0 knowledge graph analysis software, this study selects 982 relevant papers published in the Web of Science (WOS) Core Collection between 2016 and 2025 as the sample. By employing analytical methods—including annual publication volume statistics, collaboration networks among researchers, keyword co-occurrence patterns, and temporal evolution charts—we systematically delineate the overall research landscape, distribution of key research institutions, trends in research hotspots, and future frontier directions in this field. The analysis results indicate that: (1) The total number of publications in the global seawater–sand concrete field has been increasing year by year. From 2016 to 2018, it was the basic exploration period, with an average annual publication volume of less than 10. From 2019 to 2021, it was the deepening and expansion period, with research expanding from the performance of a single material to material modification and structural application. From 2022 to 2025, it was the rapid prosperity period, with the publication volume reaching its peak in 2024–2025 (208 articles and 203 articles), and the publication volume continued to rise. (2) China ranks first globally with 798 publications, but its centrality in international cooperation networks is only 0.24, reflecting low overall collaboration density and loose partnerships between institutions and authors, without the formation of cross-institutional core research teams with global leadership. (3) Research hotspots in this field primarily focus on material properties, durability characteristics, and mechanical strength, among which FRP reinforcement systems serve as a bridge for interdisciplinary research bridging material fundamentals and engineering applications, representing a key research branch. (4) From the perspective of evolutionary trends, the field exhibits three major developmental shifts from macroscopic mechanical performance characterization to in-depth investigation of microscopic damage mechanisms, from single-material studies to composite structural systems, and from short-term laboratory accelerated testing to full life-cycle performance evaluation, with the low-carbon potential of seawater–sand concrete increasingly becoming a prominent research focus. Therefore, this paper advocates strengthening international and inter-institutional academic collaboration, fostering multidisciplinary innovation, and prioritizing breakthroughs in key areas, such as large-scale intelligent performance prediction, long-term performance database development, and digital-twin-based operation and maintenance management, to facilitate the transition of seawater–sand concrete technology toward efficient, low-carbon, safe, and intelligent engineering applications. Full article

Natural fibres, both bio-based and mineral-derived, are increasingly investigated for use in mortar as a means of improving technical efficiency while potentially reducing reliance on synthetic fibres where performance and durability are adequate. This review synthesises mortar-focused evidence across cement-based binders, air lime and natural hydraulic lime binders, gypsum-based binders and clay-based binders, with emphasis on mix designs, fibre–matrix interactions, durability-related behaviours and engineering applications. Across binder systems, the most consistently reported benefit of fibre incorporation is improved crack control and post-crack integrity, provided that fibre dispersion, dosage, and workability are adequately controlled. Some formulations also exhibit reduced measured drying shrinkage, whereas changes in compressive and flexural strength are inconsistent, reflecting the effects of fibre type and content, water demand, density, pore structure and matrix–fibre bonding. Durability is strongly binder- and exposure-dependent. For cement-based mortars, alkaline and calcium-rich pore solution remain key limits for many plant fibres, especially under wetting–drying exposure. For lime-based, gypsum-based and clay-based mortars, chemical attack is generally less severe, but performance and property retention remain sensitive to moisture history, curing path and conditioning. Hygrothermal and hygric effects are conditional and should be considered alongside density, moisture state, pore structure and water uptake. Overall, natural fibres are most convincing when crack control, post-crack integrity, compatibility or moisture-related performance are required, rather than for universal strength or durability improvement. For that, further studies and optimisation are needed. Full article

Landfill leachate circuits that operate without discharge, by recirculating aerated leachate onto the waste mass, are widespread in South-East Europe, yet their long-term behaviour is rarely documented with sample-level data. This study reports a six-year (2020–2025) seasonal monitoring campaign at a sanitary landfill in northern Serbia (alluvial aquifer of the Sava River, transboundary Danube basin) and re-examines it with a transparent multivariate protocol. Seventy-two leachate samples (collection well, aeration lagoon, sedimentation lagoon; n = 24 each, 30 parameters), 28 realised surface-water campaigns, and six years of groundwater summaries were evaluated by principal component analysis/factor analysis (PCA/FA, Varimax normalized), hierarchical cluster analysis, PERMANOVA, non-parametric paired tests and, for benchmarking, supervised machine learning. The pooled leachate model (n = 72; 21 variables; KMO = 0.700; Bartlett χ² = 956, p < 0.001) retained four factors by parallel analysis, explaining 61.6% of total variance; after rotation the factors accounted for 27.7%, 14.3%, 10.4%, and 9.3%. Factor 1 grouped organic load with particle-reactive metals (COD, BOD₅, Fe, Ni, Cr, As, Zn), Factor 2 a reduced sulfur–fluoride–BTEX signature, Factor 3 temperature-driven nitritation, and Factor 4 a nitrate–manganese redox contrast. Crucially, paired campaign-by-campaign comparison showed no removal of the dominant pollutants along the circuit. Median COD, BOD₅ and NH₄-N were not lower in the sedimentation lagoon than in the collection well, while pH rose from 8.08 to 8.75 (p < 0.001); only Cu, Pb, NO₃-N, and NO₂-N decreased significantly. The circuit therefore homogenises and concentrates dissolved load rather than removing it. Downstream surface water was significantly enriched in electrical conductivity (+110 µS/cm), total dissolved solids, NH₄-N, and NO₂-N relative to upstream (Wilcoxon, p < 0.05), and groundwater showed episodic conductivity up to 12,760 µS/cm and NH₄-N up to 102 mg/L. Cytotoxicity (MTT) confirmed biological relevance, with MRC-5 viability falling to 37% after 24 h exposure to 50 vol.% groundwater (Pw3) versus 60% in A549 cells. A random-forest classifier separated circuit units far better than PCA-based discrimination (76.4% versus 54.2% cross-validated accuracy) and distinguished the 2020–2021 pandemic period from 2022–2025 with 94.2% accuracy, a period effect also confirmed by PERMANOVA (R² = 7.2%, p < 0.001). The results indicate that closed-loop recirculation without an engineered discharge barrier transfers, rather than eliminates, contaminant load, and that after-care of such systems requires mass-balance monitoring and polishing treatment. Full article

While continuously promoting agricultural water-saving and efficiency improvement, Ningxia is confronted with problems such as deepening groundwater tables and growing ecological vulnerability. Exploring the trade-off relationships and their evolutionary characteristics between socioeconomic development and water resource carrying capacity, as well as between water use efficiency improvement and groundwater-ecosystem maintenance, is of great significance for coordinated water resource governance in arid irrigation districts. Based on time-series data covering 2000–2024, this paper establishes a DPSIR evaluation model and constructs a progressive quantitative analytical framework coupling the entropy-weight-Tapio decoupling, rate-scissors difference and PLS-SEM models. During the study period, the growth rate of the response (R) dimension (13.76%) was far higher than that of the state (S) dimension (3.23%) from 2011 to 2020, confirming the objective existence of dual trade-offs. The two categories of trade-offs underwent a three-stage evolution of “latent-intensified-remediation”, showing the counter-intuitive feature of “effective total-volume control alongside continuous groundwater table deepening”. Hidden transmission barriers were identified for 2008–2016 (θ₁, θ₂ dropped to 0.46–1.32°): the transfer of water-saving dividends to industry caused groundwater extraction to rise rather than fall to a certain extent. PLS-SEM analysis reveals that structural lock-in acts as the core inhibiting factor for ecological protection. The total effect of socioeconomic development on ecology reaches 0.921, whereas structural lock-in produces a chained negative mediating effect of −0.192 by suppressing water use efficiency. Improvement in water use efficiency presents dual characteristics of overall ecological gain and localized groundwater-recharge loss. It can be concluded that engineering-only water-saving measures cannot balance water-intake reduction and recharge deficits. It is necessary to simultaneously advance low-water-consumption cropping-pattern restructuring, rigid enforcement of the 2.5 m ecological groundwater table threshold, and the substitution mechanism for saved-water volume between industry and agriculture, so as to build a coordinated “water-saving-recharge-ecology” regulation system. Full article

Facing the dual challenges of energy shortage and environmental degradation, photocatalysis and electrocatalysis have emerged as key technologies for converting small molecules into value-added chemicals, yet their conflicting requirements on the electronic structure of catalysts prevent a single material from freely switching between the two modes. Here, we demonstrate a feasible strategy for achieving on-demand switching between these catalytic functions in a single ferroelectric heterojunction, Pd-C₃N₄@In₂Se₃, through polarization engineering. Using first-principles density functional theory calculations, we show that reversing the polarization direction of the α-In2Se3 layer induces a nonvolatile electronic phase transition. The downward polarization (P↓) configuration exhibits metallic behavior, whereas the upward polarization (P↑) state becomes semiconducting with a type-II band alignment. This transition arises from polarization-dependent interfacial built-in electric fields and charge transfer differences. Notably, the metallicity of the P↓ configuration is localized predominantly within the In₂Se₃ layer rather than delocalized over the entire heterostructure. This arises because the enhanced interfacial charge transfer, driven by the larger work-function difference, selectively populates the conduction band of In₂Se₃, pushing its band edge across the Fermi level, while the Pd-C₃N₄ layer remains semiconducting due to charge depletion and the absence of gap-closing hybridization at the interface. In the P↑ state, the heterojunction acts as an efficient photocatalyst for overall water splitting, with band edges straddling the redox potentials. Under illumination, photogenerated electrons and holes make the hydrogen evolution reaction and oxygen evolution reaction thermodynamically spontaneous. In contrast, the metallic P↓ state serves as an excellent electrocatalyst for hydrogen evolution, delivering a limiting potential as low as −0.11 V, attributed to strengthened N 2p and H 1s orbital hybridization. These findings resolve the conflicting electronic requirements of photocatalysis and electrocatalysis and offer a new paradigm for designing smart, dual-functional catalysts adaptable to varying energy inputs, providing valuable theoretical guidance for future experimental realization of switchable catalytic systems. Full article

Oilfield production forecasting serves as the decision-making basis for monthly production allocation and injection–production system optimization. Existing mainstream prediction methods face significant limitations: the Arps decline curve extrapolates historical production trends, yet its accuracy degrades rapidly following adjustments to injection–production regimes; machine learning methods such as XGBoost can leverage extensive dynamic data but rely heavily on manual feature engineering and offer limited decision interpretability. This paper proposes the FTT-Transformer prediction model, whose core innovation is the Feature-Time Tokenizer (FTT). The FTT projects every scalar pair (time step, feature) in a multivariate time series matrix into a token of uniform dimensionality, superimposing three types of positional information—time embedding, feature embedding, and global position encoding. On this foundation, a multi-head self-attention mechanism performs end-to-end, full-capacity learning of nonlinear interactions across both the temporal and feature dimensions. The model is lightweight, requiring only 35,361 parameters for 13 input features and is readily deployable. Validation was conducted using production data from two independent waterflooding oilfields. On Dataset 2 (60 wells, 2012–2026), the model achieved an R² of 0.819, achieving performance on par with XGBoost (0.813; DM test p = 0.620, indicating no statistically significant difference) and substantially outperforming temporal Transformer baselines PatchTST (R² = 0.683) and iTransformer (R² = 0.786). On Dataset 1 (96 wells), it reached an R² of 0.930, statistically indistinguishable from XGBoost’s 0.943 (DM test p = 0.611). Five-fold temporal cross-validation yielded a mean R² of 0.840 ± 0.036, confirming the model’s stability. Ablation experiments revealed that global position encoding contributed most significantly, with its removal causing a 3.9 percentage point reduction in R² on Dataset 2. Composite feature-importance analysis showed that monthly liquid production and water cut are identified by the model as the two most predictive features, contributing 31.93% and 30.17% of the total importance, respectively. Multi-step forecasting results demonstrated that the model retains an R² of 0.640 for predictions two months ahead, spanning one complete decision cycle of monthly production reallocation. The proposed architecture is not domain-specific; by adapting the feature embeddings and time encoding, it could potentially be extended to diverse multivariate time series forecasting applications. However, cross-domain validation remains future work. Full article

The development of plant-based functional beverages is often limited by inherent matrix defects, particularly undesirable off-flavors, astringency, and colloidal instability. Water kefir (WK), a highly resilient multispecies symbiotic consortium, offers a robust biorefining platform to address these challenges. This review systematically elucidates the underlying micro-ecological logic and biochemical mechanisms of WK-mediated plant matrix remodeling. We first detail how spatial niche differentiation and cross-feeding networks among lactic acid bacteria, yeasts, and acetic acid bacteria drive ecological homeostasis. Next, we highlight core molecular events that elevate sensory quality: protein unfolding for off-flavor elimination, enzymatic depolymerization of phenolics to mitigate astringency, and exopolysaccharide synthesis for rheological and flavor diffusion control. Finally, to overcome industrial scale-up challenges, we outline a precision fermentation framework, integrating systems multi-omics, real-time biomimetic monitoring, and sensory topological modeling. Ultimately, this synthesis provides theoretical guidance for the reverse flavor engineering and targeted nutritional design of novel plant-based beverages. Full article

To address the limited cooling range of ventilation in deep, high-temperature development headings and the lack of coordinated design between coil-based cooling and the ventilation system, this study proposes a coupled “twin-forcing–coil” cooling scheme. Building on conventional overlap (forcing–exhausting) ventilation, a rear-mounted second forcing duct is added to the conventional overlap (force–exhaust combined) auxiliary ventilation system, forming a dual-duct forcing, single-exhausting configuration—hereafter termed the “twin-forcing–single-exhausting” (TFSE) system—that provides a booster (relay) air supply to mitigate the along-path attenuation of cooling capacity and the short-circuiting of cold air; an in situ heat-exchange coil wall further provides supplementary cooling where ventilation-based temperature control weakens. Using a development heading at the 790 m level of a metal mine in Yunnan as the engineering background, a three-dimensional numerical model coupling the roadway, ventilation system, and coil wall was established and validated against nine field monitoring points, showing average relative errors of approximately 1% for temperature and 2–3% for humidity, comparable to the measurement uncertainty of the field instrumentation. Because the numerical model does not account for evaporative and condensation phase-change processes, two supplementary development headings with standing water at the face were used for validation; results showed that model error increases with water accumulation and heading length, indicating the model’s applicability is limited to conditions with intact surrounding rock and minimal seepage. Six operating cases were designed with duct placement and coil spacing as variables. Results show that single-duct ventilation cooling decays markedly beyond 30 m from the face, whereas twin-forcing booster (relay) air supply effectively extends the cooling range, reducing the 30–70 m section temperature by 2.7–2.9 K; the second duct should be positioned where the first duct’s cooling capacity begins to attenuate but is not yet depleted. Based on only two spacing configurations tested (10 m and 15 m), coil-staggered spacing showed limited effect on cooling performance under the field conditions examined; this preliminary finding requires validation across a broader range of spacings. Among the chilled-water conditions tested, an inlet temperature of 280.65 K and a flow velocity of 0.5 m/s offered a reasonable trade-off between cooling uniformity and economic efficiency. Under the boundary conditions and equipment parameters of this case, energy consumption estimates further indicate that the cooling effect per unit electricity consumption of twin-forcing ventilation is roughly 6–8 times that of coil-based cooling, primarily due to pumping losses over the ~240 m chilled-water delivery distance. This energy penalty indicates that coil-based cooling is better suited as a localized, short-distance supplementary measure rather than as a means of extending the cooling range over long distances. Full article

Bottom-up ship emission inventories derived from Automatic Identification System (AIS) data are normally reported on kilometre-scale grids, which merge port waters that perform very different functions. Working with an AIS-based STEAM inventory for the Yangtze River Delta (YRD), we ask a question that gridded inventories rarely separate: are the cells where ships accumulate time the same cells where they emit? To answer it, we define the Static–Dynamic Ratio (SDR), the ratio of hotelling (auxiliary-engine) to propulsion (main-engine) emissions within a cell, and use it to classify YRD waters without recourse to external port charts. Hotelling-dominated cells occupy 17.7% of the sea area and accumulate 59.3% of all ship-hours, a ship-hour density seven times that of transit-dominated fairways, yet they carry only 22.4% of NO_x. A vessel at anchor emits about one-eighth as much NO_x per hour as one under way, and the two effects nearly cancel. The cancellation is species dependent: low-load correction factors are steeper for sulfur and particulate species than for NO_x, so hotelling zones reach relative SO₂ and PM_2.5 densities of 1.21 and 1.09 against 0.89 for NO_x. Coarsening the same activity field from 100 m to 1 km drops the share held by the busiest 1% of cells from 70% to 50%, showing how kilometre grids manufacture apparent continuity along shipping lanes. Activity hotspots are therefore not emission hotspots, and anchorage-targeted measures such as shore power are best justified by particulate and sulfur exposure near populated coasts rather than by their share of the regional NO_x burden. Full article

Earth Observation (EO) analysis increasingly relies on large and heterogeneous satellite datasets, yet developing EO workflows often requires specialized expertise in data selection, geospatial programming, and cloud-based processing. Recent advances in Large Language Models (LLMs) offer new opportunities for natural-language interaction with EO systems, although challenges related to transparency, reproducibility, and domain-specific reasoning remain. This study presents SeaScope, an explainable AI framework that integrates LLMs, Retrieval-Augmented Generation (RAG), scientific knowledge retrieval, and Google Earth Engine (GEE) to transform natural-language requests into transparent and executable EO workflows. The framework combines knowledge retrieval, code generation, cloud execution, provenance tracking, and interactive visualization within a unified environment. A pilot implementation is demonstrated through maritime and coastal monitoring applications, including oil spill detection, vessel monitoring, water quality assessment, floating debris detection, and air quality analysis. Multiple state-of-the-art LLMs are evaluated under both RAG and non-RAG configurations using representative EO case studies. The results indicate substantial differences among model families and show that retrieval augmentation can significantly improve workflow generation quality and reliability for capable models, while providing more limited benefits for smaller models. The proposed framework demonstrates the potential of explainable AI agents to support transparent, reproducible, and scalable EO analysis. Full article

With the continuous expansion of deep-sea resource exploration, marine environmental monitoring, and underwater operations, Autonomous Underwater Vehicles (AUVs) have been increasingly widely applied. Aiming at the demand for high-performance main propulsion systems of Autonomous Underwater Vehicles (AUVs), this paper conducts research on the structural design and hydrodynamic performance of a 30 kW rim-driven thruster (RDT) and its coupling mechanism with AUVs. By combining computational fluid dynamics (CFD) simulations and experimental methods, the influence of the advance coefficient on the open-water performance of the thruster is revealed. An integrated coupling simulation model of the AUV and RDT is established to analyze the performance attenuation law of the thruster and the characteristics of the coupled flow field under wake flow conditions, and to clarify the two-way interaction mechanism between the thruster and AUV. Towing tank tests were carried out at sailing speeds ranging from 1 to 4 kn, which verifies the reliability of the numerical simulation model and the matching performance between the thruster and AUV. The results show that the open-water efficiency of the thruster reaches a peak value of 0.536 at the advance coefficient $\mathrm{J}=0.8$, which is close to the optimal efficiency range with good matching performance of the propulsion system Under wake flow conditions, the attenuation range of the thrust coefficient of the thruster is 12.45–16.53% with the increase in advance coefficient. The main reasons are the uneven inflow velocity and unstable flow field pressure distribution caused by the non-uniform wake flow at the AUV stern. At the ship speeds of 2 kn, 3 kn and 4 kn, the self-propulsion rotational speeds obtained from test fitting are in good agreement with the simulation results, with all relative errors less than 8%. This study provides a theoretical basis and technical reference for the engineering design of medium and high-power rim-driven thrusters as well as the matching optimization of AUV-thruster systems. Full article