Search Results (54)

This study investigated microstructural, optical, and thermal changes in spruce wood (Picea abies) exposed to controlled laboratory heating to identify indicators associated with the transition from progressive thermal degradation to the initial char formation. Cubic specimens measuring 20 × 20 × 20 mm were exposed to selected temperatures between 240 and 300 °C under atmospheric conditions, with a 15 min isothermal exposure period. Microstructural changes were evaluated by scanning electron microscopy (SEM) and quantitative tracheid double cell wall measurements, supported by simultaneous thermal analysis (STA) and color and reflectance analyses. Simultaneous thermal analysis (TG/DTG/DSC) was performed on separate specimens from the same wood material to provide complementary thermal evidence. The most pronounced microstructural changes were observed between 250 and 260 °C, including substantial thinning of tracheid cell walls, degradation of bordered pits, increased brittleness, and localized structural collapse. Quantitative measurements showed reductions in double cell wall thickness exceeding 50% at 260 °C. TG/DTG analysis indicated the onset of intensive thermal degradation at 254.2 ± 1.48 °C, while optical measurements showed pronounced darkening and reduced differentiation of reflectance spectra above approximately 260 °C. The combined evaluation of complementary analytical methods indicates that the 250–260 °C interval represents a condition-dependent microstructural transition associated with accelerated thermal degradation and the early development of a charred structure under the applied experimental conditions. These findings provide complementary experimental evidence for interpreting the early stages of wood charring and may support the interpretation and future refinement of heat transfer and pyrolysis models. They complement, rather than replace, the conventional 300 °C engineering char line criterion used in structural fire design. Full article

The increasing demand for sustainable materials has accelerated the development of biodegradable polymer composites with enhanced multifunctional performance for engineering, packaging, and biomedical applications. In this study, poly(lactic acid) (PLA)/polyhydroxyalkanoate (PHA) biocomposites reinforced with microcrystalline cellulose (MCC) and a compatibilizer were fabricated by melt blending followed by compression molding. Fourier-transform infrared spectroscopy confirmed enhanced hydrogen-bonding interactions between MCC and the PLA/PHA matrix, indicating improved interfacial compatibility. X-ray diffraction and Differential scanning calorimetry revealed that MCC acted as an significant heterogeneous nucleating agent, increasing the crystallinity from 28.6% for the neat PLA/PHA blend (S0) to 40.1% while reducing the cold crystallization temperature from 115.2 to 110.5 °C and increasing the melting enthalpy from 29.8 to 38.9 J g⁻¹. Thermogravimetric analysis demonstrated improved thermal stability, with the maximum degradation temperature increasing from 325.1 to 343.8 °C and the residual char yield increasing from 5.6% to 16.8%. Specimen S7, containing 6 wt.% MCC and 2 wt.% compatibilizer exhibited the optimum overall performance, achieving a tensile strength of 64 MPa, Young’s modulus of 2500 MPa, impact strength of 5.8 kJ/m², cell viability of 98%, and 88.5% weight loss after 180 days of soil burial. These findings demonstrate that interfacial engineering with MCC and compatibilizer significantly enhances the structural, thermal, mechanical, biological, and biodegradation performance of PLA/PHA biocomposites, making them promising candidates for sustainable advanced packaging and biomedical applications. Full article

Polybenzoxazines (PBz) represent a versatile class of high-performance thermosetting polymers that have attracted significant attention for advanced composite applications due to their unique combination of properties including high glass transition temperatures, low polymerization shrinkage, excellent thermal stability, and molecular design flexibility. This comprehensive review examines the structure–property relationships governing PBz composite performance, from molecular design principles through network formation, composite reinforcement strategies, and ultimate application performance. The review systematically addresses benzoxazine monomer structure and its influence on polymer network architecture, explores the polymerization mechanism, and critically evaluates composite design strategies incorporating carbon-based nanofillers, fiber reinforcements, and hybrid filler systems. Detailed analysis of structure–property relationships reveals how molecular and composite architecture control thermal stability (glass transition temperatures exceeding 350 °C and char yields up to 92%), mechanical performance, electrical properties (dielectric constants as low as 2.67), and chemical durability. Processing techniques ranging from conventional compression molding to emerging additive manufacturing approaches are discussed in the context of morphological control and property optimization. Applications spanning aerospace structures, high-frequency electronics and protective coatings demonstrate the technological relevance of PBz composites. Critical challenges including network brittleness, high cure temperatures, and recyclability limitations are addressed alongside recent advances in dynamic covalent networks, vitrimer chemistry, and self-healing systems that promise to overcome these barriers. This review provides a comprehensive framework for understanding and engineering polybenzoxazine composites for next-generation advanced applications. Full article

Efficient fire safety engineering of insulated timber modular blocks requires an integrated assessment of material behavior, compartment fire dynamics, and structural response under thermal exposure. This study presents a performance-based framework that evaluates fire risk in modular timber systems combining combustible wood elements with polymer-based insulation. Key parameters—including ignition delay, heat release rate (HRR), charring rate, and encapsulation integrity—are modeled to quantify fire growth and structural degradation. A hybrid methodology integrating material characterization, compartment fire simulation, and mitigation analysis is applied to assess system performance under varying protection strategies. The results indicate that fire behavior is strongly governed by encapsulation reliability and cavity fire propagation pathways, with unprotected insulation leading to rapid HRR escalation and early flashover conditions. Conversely, the use of multi-layer fire-resistant linings and cavity barriers significantly delays ignition and preserves structural stability. Predictive modeling demonstrates that optimized configurations can achieve fire resistance levels comparable to conventional systems while maintaining modular efficiency. The findings highlight that efficient fire safety in insulated timber modular blocks depends on the coordinated design of materials, interfaces, and protective systems, supporting the adoption of performance-based fire engineering in modern modular construction. Full article

Under China’s “carbon peaking before 2030 and carbon neutrality before 2060” targets, the low-carbon transformation of the ironmaking stage—which contributes approximately 70% of the CO₂ emitted per ton of steel in the dominant blast furnace–basic oxygen furnace (BF–BOF) route—is decisive for decarbonizing the steel industry. In contrast to earlier reviews that describe individual technologies in isolation, this review provides a structured, cross-technology synthesis: the main routes are classified into short-/medium-term low-carbon blast furnace technologies (hydrogen-rich carbon-recycling oxygen blast furnace, hydrogen-rich injection, biomass char injection and ultimate energy-efficiency measures) and medium-/long-term non-blast furnace technologies (hydrogen-based shaft furnace direct reduction, smelting reduction, rotary hearth furnace, fluidized-bed reduction and electric smelting reduction) and are then compared on a common set of quantitative indicators—CO₂ mitigation, specific energy and hydrogen demand, technology readiness level (TRL) and relative cost. On this basis, emerging hydrogen-based flash ironmaking, developed from the interdisciplinary integration of “iron and steel–non-ferrous metallurgy–hydrogen metallurgy–plasma”, is critically assessed, with a clear separation between laboratory/pilot feasibility and industrial readiness. We conclude that low-carbon blast furnace technologies, owing to low retrofit cost and high maturity, will dominate near-term mitigation, whereas hydrogen-based shaft furnaces and, in the longer term, hydrogen-based flash ironmaking define the pathway toward near-zero-carbon ironmaking—conditional on the availability of green hydrogen and low-carbon electricity and on overcoming key engineering barriers. Full article

Cellulose-based aerogels are promising sustainable thermal-insulation materials, but their practical application is often limited by insufficient mechanical robustness and intrinsic flammability. Herein, a multiscale network-engineering strategy is proposed to fabricate a cellulose-based composite aerogel integrating structural stability, thermal insulation, and fire safety. By synergistically introducing in situ generated aluminum trihydroxide (ATH) and microencapsulated APP@ATH–MEL into the cellulose scaffold, the flame-retardant components function not only as active fire-safety agents but also as structural regulators that promote the formation of a highly interconnected hierarchical framework. This regulated architecture enhances interfacial interactions, improves load-transfer efficiency, suppresses structural collapse during freeze-drying, and introduces tortuous pathways and abundant interfaces for heat-transfer regulation. As a result, the optimized composite aerogel exhibits a low thermal conductivity of 35 mW·m⁻¹·K⁻¹ together with improved compression resistance. Thermal analysis reveals a reduced mass-loss rate and increased char yield, while cone calorimetry confirms suppressed heat release, reduced gaseous emissions, and improved residue stability. The enhanced fire safety is attributed to a synergistic multi-phase mechanism involving endothermic shielding, gas-phase dilution, condensed-phase char formation, and inorganic-residue reinforcement, which collectively inhibit heat and mass transfer during combustion. This work provides an effective strategy for the design of lightweight, mechanically robust, and fire-safe cellulose-based composite aerogels for advanced thermal-insulation applications. Full article

The development of sustainable polymer composites reinforced with renewable resources and advanced nanomaterials has attracted considerable attention for multifunctional engineering applications. In this study, an environmentally friendly epoxy-based biocomposite (EBC) reinforced with coconut shell powder (CSP) and graphene nanopowder (GNP) was successfully produced through a casting process. CSP was employed as a bio-based filler, while GNP was incorporated at concentrations ranging from 0 to 0.75 wt.% to improve the overall performance of the composites. The effects of GNP loading on bulk density, tensile strength, elongation at break, Shore D hardness, thermal conductivity, dielectric properties, thermal stability, mechanical and microstructural characteristics were systematically investigated. The results demonstrated that the incorporation of GNP significantly enhanced the multifunctional properties of the improved EBCs. Bulk density increased from 1137.5 to 1143.1 kg m⁻³ with increasing GNP content. The optimum tensile strength of 28.6 MPa and Shore D hardness of 77.4 were achieved at 0.45 wt.% GNP, indicating effective stress transfer and strong interfacial interactions between the epoxy matrix, CSP, and GNP. Thermal conductivity increased from 0.110 to 0.149 W m⁻¹ K⁻¹, while the dielectric constant increased from 3.06 to 4.25 with increasing GNP concentration. Thermogravimetric analysis revealed improved thermal stability and enhanced char formation in graphene-containing composites. FTIR analysis confirmed that graphene acted primarily as a physical reinforcement without altering the fundamental chemical structure of the epoxy network. SEM and EDX investigations demonstrated improved structural compactness, homogeneous filler dispersion, and successful graphene incorporation. The findings indicate that GNP and CSP reinforced EBCs possess significant potential for lightweight structural materials, thermal management systems, dielectric components, and sustainable multifunctional engineering applications. Full article

Magnesium hydroxide is attracting growing interest as a versatile, halogen-free flame retardant, and this review surveys its production routes, structure–property relationships and use in polymer systems from commodity polyolefins to advanced bio-based materials. Industrial Mg(OH)₂ is still predominantly obtained from mining or hydration of MgO, but increasing attention is being devoted to recovery from seawater and saltwork brines, where precipitation from Mg²⁺-rich streams followed by controlled rehydration or direct precipitation yields fine, high-purity powders suitable for flame retardant use and simultaneously valorizes saline wastes. In parallel, hydrothermal synthesis has been extensively explored to tailor particle size and morphology by adjusting the precursor, solvent, temperature and time, enabling high-surface-area Mg(OH)₂ or MgO with narrow size distributions that are attractive for high-performance composites also evaluated via ball milling, crushing and refining. More recently, process intensification strategies such as microwaves and ultrasounds have been proposed to shorten reaction times, lower temperatures and better control nucleation and growth, opening paths toward energy efficient production of structured Mg(OH)₂ from both conventional and brine-derived precursors. The second part of the review analyzes how the intrinsic endothermic decomposition and basic character of Mg(OH)₂ can be utilized across a broad range of polymer matrices and how surface functionalization strategies extend its applicability. In addition to “as received” powders, stearic acid and other fatty acids, metal soaps and various organic coupling agents are widely used to render the surface more hydrophobic, enhance dispersion and interfacial adhesion, and in some cases introduce additional char-forming or barrier functionality. In terms of the application, the review methodically synthesizes and contrasts fire and mechanical data for Mg(OH)₂-containing polyolefins (HDPE, LLDPE, PP and EVA) utilized in cables and building products, expandable polymers and foams, biopolymers (PLA and PBS), and elastomers. The review places particular emphasis on the balance between loading level, processability, flame performance and mechanical integrity. This review aims to provide a comprehensive framework for designing next-generation Mg(OH)₂-based flame-retardant systems for both conventional and emerging polymer technologies. To this end, it integrates advances in sustainable feedstocks, controlled synthesis and surface engineering with the rapidly expanding application space. Full article

A rapid accumulation of plastic waste has created an urgent need for efficient and sustainable recycling technologies. Among various approaches, pyrolysis stands out as promising method of thermochemical recycling of plastic waste; however, the process needs optimization and further research to make it more energy-efficient and sustainable. The conventional approaches for optimization focus on the enhancement of yield, only overlooking efficiency and system-level sustainability. In this study, a machine learning-enabled surrogate-assisted multi-objective artificial intelligence (AI) optimization framework is developed for plastic pyrolysis to maximize product recovery and minimize energy consumption. The model integrates energy return on investment (EROI) and higher heating value (HHV) into process design. A curated dataset of 312 experimental cases covering polyolefins, PET, nylon, and mixed plastics was used to train multiple machine learning algorithms, such as polynomial regression, Gaussian process regression, and Random Forest models. The Random Forest algorithm demonstrated superior predictive robustness across oil yield, HHV, char formation, and EROI. Pareto front analysis using NSGA-II revealed that moderate reaction severities (400–450 °C, 40–70 min) maximize net energy performance while minimizing solid residues. The conditional variational autoencoder as a GenAI model was incorporated to work as a generative proposal engine, which enhances the exploration of chemically feasible operating regions under uncertainty-aware active learning. The integration of techno-economic and life-cycle assessment demonstrates that energy-positive configurations outperform high-yield scenarios, achieving IRR > 15%, energy intensity < 10 MJ kg⁻¹, and CO₂ reductions up to 47% relative to incineration. The proposed framework establishes a data-driven methodology for aligning polymer pyrolysis optimization with circular economy and energy sustainability objectives. Full article

The development of high-performance flame-retardant (FR) polypropylene (PP) with high mechanical integrity remains a challenge. Herein, we demonstrate a synergistic flame retardancy system for PP achieved via partial substitution of piperazine pyrophosphate (PAPP) with 1 wt.% magnesium borate whiskers (MBW) for improved flame retardancy, and thermal and mechanical properties. The optimized PP/24PAPP/1MBW exhibits exceptional FR performance, driven by the formation of a highly ordered, continuous phosphorus–boron hybrid char in the condensed phase. Cone calorimetry test results reveal an 80% reduction in peak heat release rate, a 54% reduction in total heat release, and a 33% reduction in total smoke production compared to neat PP, while the UL-94 test confirms a V-0 rating with complete suppression of flaming drips. Morphological study of the char residue using Raman spectroscopy and SEM attributes this performance to enhanced char graphitization and structural coherence enabled by boron-mediated cross-linking. More importantly, this transformative flame retardancy performance is achieved without severe compromise to mechanical properties, retaining over 89% of the original tensile strength. This work confirms the PAPP/MBW system as a highly efficient, low-additive approach to creating advanced fire-safe polymer composites for engineering applications. Full article

Epoxy resins (EP) are widely used in aerospace, electronics, and coatings due to their excellent mechanical and thermal properties. However, their inherent flammability and brittleness limit high-end applications. In this work, a novel reactive flame retardant epoxy monomer (EP-DVGA) containing DOPO and triazole units was designed and synthesized via a molecular engineering strategy. The chemical structure was confirmed by FTIR and NMR. A series of modified epoxy thermosets were prepared by co-curing EP-DVGA with bisphenol A epoxy resin (E51) using DDM as curing agent. The results showed that EP-DVGA significantly enhanced flame retardancy: At 16.31 wt% loading, the limiting oxygen index increased from 25.9% to 34.3% with UL-94 V-0 rating, and cone calorimetry revealed 73.2% and 69.2% reductions in peak heat release rate and total heat release, respectively. Mechanistic studies demonstrated a dual flame retardant effect involving phosphorus radical quenching in the gas phase and formation of a dense graphitized char layer in the condensed phase. Remarkably, EP-DVGA also improved mechanical properties—impact strength increased by 47% and tensile strength by 33.1% at optimal loadings—attributed to energy dissipation through reversible hydrogen bonding and π–π interactions. This molecular design successfully overcomes the traditional trade-off between flame retardancy and mechanical performance, offering a promising strategy for developing high-performance intrinsically flame retardant epoxy materials. Full article

This study experimentally investigated the movement, combustion, and potassium (K) and chlorine (Cl) migration behaviors of three biomass types: densified wood pellets (heavy), corn straw (lightweight), and wheat straw (lightweight, friable). The experiments were conducted under conditions representative of industrial coal-fired circulating fluidized bed (CFB) boilers, with a temperature range of 850–950 °C and a fluidization velocity of 6–8 m/s. Results show that densified wood pellets sink into the dense-phase zone and release volatiles slowly, in about 50 s. As the volatiles are nearly fully released, the pellets fracture multiple times along their length, eventually forming nearly spherical particles. Their movement and combustion processes closely resemble those of coal, making them suitable for direct co-firing in coal-fired CFB boilers. Conversely, corn straw and wheat straw exhibit low density, high volatile release rates (2 and 10 times that of wood pellets, respectively), rapid char fragmentation and abrasion, and high inherent K and Cl content (with >50% of K and >90% of Cl released). These properties lead to particle segregation, shortened gas-phase combustion time, an upward shift in heat release distribution, and potential risks such as high-temperature KCl corrosion, HCl dew point corrosion, ash slagging, and bed agglomeration. Therefore, untreated corn straw and wheat straw are unsuitable for co-firing in conventional coal-fired CFB boilers. This study provides essential data and engineering guidance: strict quality control is necessary for wood pellets to prevent Cl contamination, while pretreatment is mandatory for straw fuels. These findings offer practical insights for implementing diverse biomass co-firing strategies in coal-fired CFB boilers. Full article

Timber beams have assumed a prominent role in contemporary structural engineering, driven by sustainability requirements and the advancement of engineered wood products. Despite the evident environmental and building advantages, the performance of timber beam elements under fire conditions remains one of the main design challenges, due to the strong nonlinearity of thermal behavior, progressive charring, and degradation of mechanical properties. In this context, numerical simulations have become a central tool for the thermal and thermomechanical assessment of timber beams exposed to fire. This study presents a technical and critical review of numerical approaches applied to timber beam elements, with emphasis on finite element–based models, thermal modeling strategies, representation of charring, thermomechanical coupling, and the use of reduced-order and surrogate models. The distinctive contribution of this work lies in an integrated and critical analysis of these approaches, explicitly articulating high-fidelity numerical models with reduced-order and symbolic models, aiming at their use as complementary tools in structural design. The analysis was conducted thematically, based on literature selected from major international databases, emphasizing modeling assumptions, levels of numerical complexity, and methodological limitations. The results indicate a predominance of transient finite element (FEM) models, widespread use of two-dimensional cross-sectional analyses, increasing adoption of enthalpy-based formulations for charring, and a prevalence of sequential thermomechanical coupling strategies. In contrast, the literature reveals strong heterogeneity in thermal parameters, limited standardization of validation procedures, restricted use of probabilistic approaches, and still incipient integration of reduced-order and symbolic models. It is concluded that future advances in the field depend on the standardization of modeling strategies, the expansion of thermal property databases, and, above all, the integration of high-fidelity models with interpretable reduced-order models, capable of supporting parametric analyses and performance-based structural design methodologies. Full article

Silica-rich rice husk ash (RHA) was upcycled as an inorganic filler to engineer cellulose acetate (CA) films with tunable properties for higher-value sustainable packaging. Composite films were produced by solvent casting, varying RHA loading with and without glycerol plasticization. FTIRconfirmed the chemical integrity of CA and indicated an increase in hydroxyl interactions in glycerol-plasticized films. Optical microscopy showed that RHA progressively induces particle domains and aggregation, while glycerol improves dispersion and surface uniformity. These microstructural effects translated into controllable optical–mechanical trade-offs: neat CA remained highly transparent, whereas RHA reduced transmittance. Glycerol had a minor effect effect on transmittance, indicating that shielding is primarily governed by the ash-derived inorganic domains and tensile testing highlighted an optimal low-filler regime. A small RHA addition maximized strength and stiffness in non-plasticized films. Contact-angle measurements in neutral and alkaline media indicated pH-sensitive wetting, with faster deterioration under alkaline conditions. Thermogravimetric analysis confirmed increased char residue with RHA addition and that glycerol introduces an early mass-loss stage. Overall, the CA/RHA platform offers a simple and potentially scalable route to upcycled, silica-reinforced films, and the formulation of CA and 1.33 wt% RHA (without glycerol) stands out as a robust secondary layer with low transmittance in the UV-Vis range, making it suitable for high-value light-sensitive flexible healthcare packaging, such as protective overwraps or translucent pouches. Full article

Bio-based bismaleimide (BMI) resins can reduce environmental impact and impart intrinsic flame retardancy, but achieving a high glass transition temperature (Tg) remains challenging. Here, we replace the conventional petrochemical co-monomer O,O′-diallyl bisphenol A (DABPA) with a synthesized tri-allyl derivative of curcumin (AEC) in 4,4′-bismaleimidodiphenylmethane (BDM)-based resins. The AEC monomer, synthesized via exhaustive O- and C-alkylation of curcumin, acts as a trifunctional crosslinker. By systematically varying the imide:allyl molar ratio, we optimized the network properties. We optimize the network’s thermal and fire-safety properties. The optimized formulation (BDM: AEC = 1:0.87, denoted BA-0.87) yields 43.06% char at 800 °C and reduces the peak heat release rate (PHRR) by 13.2% compared to the conventional BDM/DABPA control (BD-0.87). Meanwhile, BA-0.87 passes UL-94 V-0 with no dripping and attains a Tg above 400 °C—nearly 100 °C higher than BD-0.87. These enhancements arise from curcumin’s rigid conjugated structure, which increases crosslink density and promotes char formation during decomposition. Our work demonstrates a viable, bio-derived pathway to engineer BMI resins that simultaneously improve thermal stability and intrinsic flame retardancy. Such resins are promising for demanding aerospace and high-temperature electronic applications that require both fire safety and stability. Full article