Search Results (47)

Urban morphology’s effects on carbon dioxide reduction and sustainable development have drawn more attention. The county scale is crucial in influencing urban development and is the central element of China’s recent urbanization. To achieve scientific urban planning and fully explore its potential in carbon emission reduction, local governments need to investigate the impact of urban morphology on carbon emissions (CE). However, previous studies have predominantly focused on provincial capitals and urban clusters. To address this gap, this study quantified four aspects of urban form, combined energy consumption, and nighttime light data to estimate CE in Chinese counties from 2000 to 2020 and analyzed the effects of these factors on CE using multiscale geographically weighted Regression(MGWR) models and geographic detectors. The following are the main findings: (1) Total CE at the county scale in China has consistently increased from 2000 to 2020. (2) The largest patch index (LPI) is the most influential urban morphological factor on CE, while the impact of Class Area (CA) has been increasing. (3) Bi-factor enhancement and nonlinear enhancement are the two primary interaction types of urban morphological factors; the most important interaction is between LSI and CA. (4) The urban morphological factors exhibit varying degrees of spatial heterogeneity, with the influencing factors ranked as CA > LPI > path density (PD) > edge density (ED) > patch cohesion index (COHESION), where LPI and CA consistently show a positive effect on CE. This study’s findings establish a scientific foundation for land spatial planning and tailored emission reduction methods at the county scale in China. Full article

Aluminum nanoparticles (Al NPs) are interesting for energetic and plasmonic applications due to their enhanced size-dependent properties. Passivating the surface of these particles is necessary to avoid forming a native oxide layer, which can degrade energetic and optical characteristics. This work utilized a radiofrequency (RF)-driven capacitively coupled argon/hydrogen plasma to form surface-modified Al NPs from aluminum trichloride (AlCl₃) vapor and 5% silane in argon (dilute SiH₄). Varying the power and dilute SiH₄ flow rate in the afterglow of the plasma led to the formation of varying nanoparticle morphologies: Al–SiO₂ core–shell, Si–Al₂O₃ core–shell, and Al–Si Janus particles. Scanning transmission electron microscopy with a high-angle annular dark-field detector (STEM-HAADF) and energy-dispersive X-ray spectroscopy (EDS) were employed for characterization. The surfaces of the nanoparticles and sample composition were characterized and found to be sensitive to changes in RF power input and dilute SiH₄ flow rate. This work demonstrates a tunable range of Al–SiO₂ core–shell nanoparticles where the Al-to-Si ratio could be varied by changing the plasma parameters. Thermal analysis measurements performed on plasma-synthesized Al, crystalline Si, and Al–SiO₂ samples are compared to those from a commercially available 80 nm Al nanopowder. Core–shell particles exhibit an increase in oxidation temperature from 535 °C for Al to 585 °C for Al–SiO₂. This all-gas-phase synthesis approach offers a simple preparation method to produce high-purity heterostructured Al NPs. Full article

The NUCLEUS experiment, currently being commissioned at the Technical University of Munich, is designed to observe coherent elastic neutrino-nucleus scattering ($\mathrm{CE}\nu \mathrm{NS}$) from reactor neutrinos and measure its cross-section with a percent-level precision at recoil energies below $100 \mathrm{eV}$. As a Standard Model process, $\mathrm{CE}\nu \mathrm{NS}$ provides a unique probe into neutrino properties, potential new physics, and background suppression techniques relevant to dark matter experiments. The experiment utilizes gram-scale cryogenic calorimeters operating at $10 \mathrm{mK}$ with an energy threshold of $20 \mathrm{eV}$. Situated at a shallow overburden of 3 m of water equivalent, the experimental site necessitates an advanced shielding strategy combining active vetoes and passive layers to reduce background rates to approximately $100\mathrm{counts}/(\mathrm{kg}·\mathrm{day}·\mathrm{keV})$, as confirmed by full setup simulations. The commissioning phase has successfully demonstrated the stable operation of the cryogenic target detectors, achieving baseline resolutions below $10 \mathrm{eV}$, and the integration of the various shielding systems. Following this milestone, the experiment is set to transition to the EdF Chooz B nuclear reactor in France in 2025, where it will enable precise measurements of $\mathrm{CE}\nu \mathrm{NS}$, contributing to the understanding of neutrino interactions and advancing the field of astroparticle physics. Full article

The high yttria content of a stabilized zirconia (YSZ) (38 wt% Y₂O₃) coating was deposited by atmospheric plasma spraying (APS) from Metco 207 powders on an Inconel 718 (Ni-based superalloy) substrate. As a metal coating connection, a layer of cermet powder (Ni-20% Al—410NS) was used before the ceramic layer deposition. The electro-chemical corrosion resistance of these materials was tested using Inconel cylinders with a diameter of 10 mm and a thickness of 1 mm, with and without the ceramic layer. Linear and cyclic measurements were obtained in H₂SO₄ electrolyte media at pH = 2. Electro-impedance spectroscopy (EIS) experiments were performed on the sample covered with the ceramic layer to evaluate the interface behavior. Scanning electron microscopy (SEM), along with equipment to determine chemical composition, and an energy dispersive spectrometry (EDS) detector were used to characterize the material surface before and after corrosion tests. It was observed that the corrosion resistance of Inconel was influenced by the bonding layer and the ceramic coating. Full article

Al–Zn–Mg–Si alloy coatings have been developed to inhibit the corrosion of cold-rolled steel sheets by offering galvanic and barrier protection to the substrate steel. It is known that Fe deposited from the steel strip modifies the microstructure of the alloy. We cast samples of Al–Zn–Mg–Si coating alloys containing 0.4 wt% Fe and directionally solidified them using a Bridgman furnace to quantify the effect of this Fe addition between $600 °\mathrm{C}$ and $240 °\mathrm{C}$. By applying a temperature gradient, growth is encouraged, and by then quenching the sample in coolant, the microstructure may be frozen. These samples were analysed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) to determine the morphological effects of the Fe distribution across the experimental temperature range. However, due to the sub 1 wt% concentration of Fe, synchrotron X-ray fluorescence microscopy (XFM) was applied to quantitatively confirm the Fe distribution. Directionally solidified samples were scanned at 7.05 keV and 18.5 keV using X-ray fluorescence at the Australian Synchrotron using the Maia array detector. It was found that a mass nucleation event of the Fe-based τ₆ phase occurred at $495 °\mathrm{C}$ following the nucleation of the primary α-Al phase as a result of a peritectic reaction with remaining liquid. Full article

The influence of the chemical composition and structural state of Zn–Ti alloys on corrosion behaviour and mechanical properties was studied. Zn-based alloys were investigated, more precisely, pure technical Zn and Zn with 0.10, 0.25 and 1.00 wt.% Ti. The microstructure and chemical composition of these materials were analysed using light optical microscopy (LOM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). The chemical composition of the alloys and the surface after immersion were analysed using an EDS detector from Bruker. The alloys’ electro-chemical corrosion resistance was further investigated through linear (LP) and cyclic (CP) potentiometry and open-circuit potential (OCP) analysis. A tensile/compression equipment (Instron 34SC-5) was used to determine the compression behaviour. UMT testing equipment was used to determine microhardness (by Rockwell indentation) and COF vs. length. For percentages higher than 0.25 wt.% Ti, the formation of a primary TiZn₁₆ intermetallic compound in the (α-Zn + TiZn₁₆) eutectic matrix was observed, a slight influence of TiZn₁₆ on the Zn corrosion resistance results, and a greater influence on the mechanical properties was confirmed. Full article

Single-source dual energy (SSDECT) and detector-based spectral computed tomography (DBSCT) are emerging technologies allowing the interrogation of materials that have different attenuation properties at different energies. Both technologies enable the calculation of effective atomic number (EAN), an index to determine tissue composition, and electron density (ED), which is assumed to be associated with cellularity in tissues. In the present prospective observational study, EAN and ED values were determined for 16 zones in normal subchondral and trabecular bone of 37 equine cadaver limbs. Using both technologies, the following findings were obtained: 1. palmar/plantar EAN zone values in the fetlock increased significantly with increasing age of the horse; 2. all EAN and ED values were significantly lower in the trabecular bone than in the subchondral bone of all phalanges; 3. in the distal phalanx and navicular bone, most EAN and ED values were significantly lower compared to the proximal and middle phalanx; and 4. some EAN and ED values were significantly different between front and hind limbs. Several EAN and ED values significantly differed between SSDECT and DBSCT. The reported EAN and ED values in the subchondral and trabecular bone of the equine distal limb may serve as preliminary reference values and aid future evaluation and classification of diseases. Full article

The development of direct dimethyl ether (DME) solid oxide fuel cells (SOFCs) has several drawbacks, due to the low catalytic activity and carbon deposition of conventional Ni–zirconia-based anodes. In the present study, the insertion of 2.0 wt.% Ru-Ce_0.7Zr_0.3O_2−δ (ruthenium–zirconium-doped ceria, Ru-CZO) as an anode catalyst layer (ACL) is proposed to be a promising solution. For this purpose, the CZO powder was prepared by the sol–gel synthesis method, and subsequently, nanoparticles of Ru (1.0–2.0 wt.%) were synthesized by the impregnation method and calcination. The catalyst powder was characterized by BET-specific surface area, X-ray diffraction (XRD), field emission scanning electron microscopy with an energy-dispersive spectroscopy detector (FESEM-EDS), and transmission electron microscopy (TEM) techniques. Afterward, the catalytic activity of Ru-CZO catalyst was studied using DME partial oxidation. Finally, button anode-supported SOFCs with Ru-CZO ACL were prepared, depositing Ru-CZO onto the anode support and using an annealing process. The effect of ACL on the electrochemical performance of cells was investigated under a DME and air mixture at 750 °C. The results showed a high dispersion of Ru in the CZO solid solution, which provided a complete DME conversion and high yields of H₂ and CO at 750 °C. As a result, 2.0 wt.% Ru-CZO ACL enhanced the cell performance by more than 20% at 750 °C. The post-test analysis of cells with ACL proved a remarkable resistance of Ru-CZO ACL to carbon deposition compared to the reference cell, evidencing the potential application of Ru-CZO as a catalyst as well as an ACL for direct DME SOFCs. Full article

Dual-energy CT has shown promising results in determining tumor characteristics and treatment effectiveness through spectral data by assessing normalized iodine concentration (nIC), normalized effective atomic number (nZeff), normalized electron density (nED), and extracellular volume (ECV). This study explores the value of quantitative parameters in contrast-enhanced dual-layer spectral detector CT (SDCT) as a potential tool for detecting lymph node activity in lymphoma patients. A retrospective analysis of 55 lymphoma patients with 289 lymph nodes, assessed through ¹⁸FDG-PET/CT and the Deauville five-point scale, revealed significantly higher values of nIC, nZeff, nED, and ECV in active lymph nodes compared to inactive ones (p < 0.001). Generalized linear mixed models showed statistically significant fixed-effect parameters for nIC, nZeff, and ECV (p < 0.05). The area under the receiver operating characteristic curve (AUROC) values of nIC, nZeff, and ECV reached 0.822, 0.845, and 0.811 for diagnosing lymph node activity. In conclusion, the use of g nIC, nZeff, and ECV as alternative imaging biomarkers to PET/CT for identifying lymph node activity in lymphoma holds potential as a reliable diagnostic tool that can guide treatment decisions. Full article

The subjects of this research are the burial clothes of Polish King Sigismund III Vasa and his wife Constance, which were woven and embroidered with silk and metal threads. Fragments of the textiles underwent spectroscopic, spectrometric, and thermogravimetric analyses. The hydrofluoric acid extraction method was improved to isolate various classes of dyes from the textile samples that had direct contact with human remains. High-performance liquid chromatography, coupled with diode array and tandem mass spectrometry detectors with electrospray ionization (HPLC-DAD-ESI-MS/MS) facilitated the detection and identification of colorants present in the textiles. Cochineal, indigo-, madder-, orchil-, and tannin-producing plants were identified as the sources of dyes used. Scanning electron microscopy with an energy-dispersive X-ray detector (SEM-EDS) was employed to identify and characterize the silk fibers and mordants and the metal threads. The presence of iron, aluminum, sodium, and calcium in the silk threads suggests their potential use as mordants. The analysis of the metal threads revealed that most of them were made from flattened gilded silver wire, with only a few being cut from a sheet of metal. Typical degradation mechanisms of metal threads were shown, resulting from both burial environment and earlier manufacturing process, and the use of the textiles in clothing, i.e., a significant loss of the gold layer was observed in most of silver gilt threads, caused by abrasion and delamination. The results of the thermal analysis confirmed the presence of silk and silver threads in the examined textiles. Full article

The purpose of the study is to compare the hardness of different metallic brackets to enamel and to determine their chemical composition and microstructure. Five metallic brackets (0.022″ × 0.028″ inch) from seven orthodontic firms produced in different alloys (Discovery^® Smart/Empower^®/Genius^®2 Metal/Victory^TM series/Equilibrium^®/Damon Q) were chosen (n = 35). The hardness of the brackets and enamel was measured using a microhardness tester. The study of the chemical composition of brackets was carried out on a single bracket per series. A scanning electron microscope (SEM) equipped with an energy dispersive spectroscopy (EDS) detector was used. Analysis of the chemical composition of metallic brackets was obtained with Oxford Instruments Ultim Max Aztec software. Metallic brackets’ hardness varied from 203 to 439 HV. A significant difference exists between Ti Equilibrium^® brackets, the rest of the brackets and the enamel (p-value = 0.003). No significant difference was found between SS_a(stainless-steel alloy), Co-Cr_a(Cobalt-Chrome) brackets and the enamel. The chemical study confirms that the alloys used to produce metallic brackets validate all the data of the manufacturers except for Genius^®2 Metal; according to this study, they are considered to be Co-Cr_a alloys. The study of the composition of brackets made it possible to confirm manufacturers’ data. Genius^®2 Metal brackets, Empower^®2 and Victory^TM series brackets filled the properties needed for orthodontic treatment. The hardness of metallic brackets is influenced by the alloy used and manufacturing method. Co-Cr_a brackets with hardness comparable to enamel can be considered as an alternative to SS_a brackets in patients allergic to nickel. Full article

In cognitive radio (CR), cooperative spectrum sensing (CSS) employs a fusion of multiple decisions from various secondary user (SU) nodes at a central fusion center (FC) to detect spectral holes not utilized by the primary user (PU). The energy detector (ED) is a well-established technique of spectrum sensing (SS). However, a major challenge in designing an energy detector-based SS is the requirement of correct knowledge for the distribution of decision statistics. Usually, the Gaussian assumption is employed for the received statistics, which is not true in real practice, particularly with a limited number of samples. Another big challenge in the CSS task is choosing an optimal fusion strategy. To tackle these issues, we have proposed a beamforming-assisted ED with a heuristic-optimized CSS technique that utilizes a more accurate distribution of decision statistics by employing the characterization of the indefinite quadratic form (IQF). Two heuristic algorithms, genetic algorithm with multi-parent crossover (GA-MPC) and constriction factor particle swarm-based optimization (CF-PSO), are developed to design optimum beamforming and optimum fusion weights that can maximize the global probability of detection $p_d$ while constraining the global probability of false alarm $p_f$ to below a required level. The simulation results are presented to validate the theoretical findings and to asses the performance of the proposed algorithm. Full article

Biodegradable metallic materials are increasingly gaining ground in medical applications. Zn-based alloys show a degradation rate between those recorded for Mg-based materials with the fastest degradation rate and Fe-based materials with the slowest degradation rate. From the perspective of medical complications, it is essential to understand the size and nature of the degradation products developed from biodegradable materials, as well as the stage at which these residues are eliminated from the body. This paper presents investigations conducted on the corrosion/degradation products of an experimental material (ZnMgY alloy in cast and homogenized state) after immersion tests in three physiological solutions (Dulbecco’s, Ringer’s and simulated body fluid (SBF)). Scanning electron microscopy (SEM) was used to highlight the macroscopic and microscopic aspects of corrosion products and their effects on the surface. An X-ray energy dispersive detector (EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) provided general information about the compounds based on their non-metallic character. The pH of the electrolyte solution was recorded for 72 h during immersion. The pH variation of the solution confirmed the main reactions proposed for the corrosion of ZnMg. The agglomerations of corrosion products were on the micrometer scale, mainly oxides, hydroxides and carbonates or phosphates. The corrosion effects on the surface were homogeneously spread, with a tendency to connect and form cracks or larger corrosion zones, transforming the pitting corrosion pattern into a generalized one. It was noticed that the alloy’s microstructure strongly influences the corrosion characteristics. Full article

The subject of the research involved fly ashes from several power plants in Poland, produced in the process of hard coal and lignite combustion. The objective of this article was to determine the concentration and distribution of elements strategic for the EU economy in ashes and in their two finest grain classes (below 20 µm and 45 µm). The differences in grain size of these ashes, as shown by granulometric tests, were significant. The concentrations of elements in the ashes and in grain classes were compared with the world average (Clarke value) for this raw material. For the majority of critical elements, a dependence of the concentration on the size of ash particles was observed. The content of REY (Rare earth elements and yttrium) and other critical elements in hard coal ashes increases with decreasing particle size. Despite the increase in the concentration of REY in the class below 20 µm, the Clarke value of these elements was not exceeded. Pearson’s correlation coefficients confirmed the interdependence between some elements of the ashes. The distribution of trace elements in grain classes of the ash was determined on the basis of observations using a scanning electron microscope equipped with an EDS (Energy Dispersive Spectroscopy) detector. Components of fly ashes that can be treated as an alternative source of strategic elements for the European Union were indicated. Full article

N₂ and O₂ adsorption isotherms in chemically modified clinoptilolite-Ca zeolites were experimentally estimated by inverse adsorption chromatography. Natural zeolites (CLINA) were chemically treated with HCl at different concentrations (H1-H4). The adsorption of N₂ and O₂ on these zeolites was studied in the temperature zone of 398–498 K using gas chromatography. This technique used a thermal-conductivity detector and He as carrier gas, at a rate of 30 mL min⁻¹. The Langmuir and Henry equations were used to describe the experimental results of these gases’ adsorption. To evaluate the selectivity of the components of atmospheric air, the chemical activation of the zeolite clinoptilolite-Ca has been carried out. The results are attractive because of the ability to separate the gases these nanomaterials present under dynamic conditions. The structural modifications of the crystalline phases of the studied zeolites were carried out through X-ray diffraction, where the average crystal size was evaluated with the Scherrer equation, finding values of 25.86 nm for CLINA and 15.12 nm for H3 zeolites. The variation of their chemical composition was carried out by energy-dispersive EDS, while the adsorption of N₂ carried out their texture properties at 77 K. The selectivity coefficients (α) were evaluated for these gases in pure form and in a mixture (atmospheric air), finding the highest values in zeolites H4 and H3. The interaction energies between these gases with the porous structures of the studied zeolites were evaluated from the evolution of the isosteric enthalpies of adsorption through the Clausius–Clapeyron equation. Full article