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Keywords = electric arc melting

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19 pages, 1869 KB  
Article
Stirring Optimization of Consteel EAF Based on Multi-Phase Flow Water-Model Simulation
by Jiahui Jin, Bing Ni, Fangqin Shangguan, Xiuping Li, Xiaoping Lin, Ge Zhao, Tao Li and Fangbo Shao
Processes 2026, 14(3), 482; https://doi.org/10.3390/pr14030482 - 29 Jan 2026
Abstract
Optimizing stirring methods is crucial for enhancing the efficiency of the Electric Arc Furnace (EAF) production process. This study explores the mixing characteristics of a 150-ton Consteel EAF. The similarity ratio between the water model and the prototype is 1:8. The average mixing [...] Read more.
Optimizing stirring methods is crucial for enhancing the efficiency of the Electric Arc Furnace (EAF) production process. This study explores the mixing characteristics of a 150-ton Consteel EAF. The similarity ratio between the water model and the prototype is 1:8. The average mixing time (AMT) was employed as the criterion to evaluate various stirring methods, including the horizontal deflection angle of side-blowing, non-uniform bottom-blowing layouts, and their combinations. A new ice whose composition was a 35 wt% sugar solution was used to simulate the movement and bonding of scrap steel. The melting and temperature difference were compared in this way. The conclusions are as follows: (1) The side blowing lances with a certain angle of horizontal deflection are more conducive to the mixing of the molten pool. The preferred side-blowing lances’ horizontal deflection angle is 10°. (2) The preferred bottom blowing layout is EKO. The bottom blowing layout needs to pay attention to the offset between the bottom blowing nozzles. Bottom blowing nozzles cannot be too far or too close. Rational non-uniform layout of bottom blowing is better than uniform. (3) The preferred combined stirring layout is the EKN, combined with side blowing, with counterclockwise deflection of 10° in the horizontal direction. Gas injection of side blowing and bottom blowing exhibits complementary action zones, thereby achieving enhanced stirring uniformity in the molten bath. But it is necessary to consider the bottom-blowing and side-blowing positions to avoid the local kinetic energy loss caused by airflow offset. At the same time, the deflection angle of the side-blowing lances should be consistent with the direction of the circulation formed by the non-uniform bottom blowing. (4) Under the rational combined stirring method, the scrap steel moved faster, and the bonding phenomenon was significantly reduced. And the temperature difference decreased the fastest. In summary, the rational combined stirring method is the most preferred method for mixing. Full article
(This article belongs to the Special Issue Advanced Ladle Metallurgy and Secondary Refining)
16 pages, 6941 KB  
Article
Microstructural, Corrosion and Mechanical Properties of Ni–Al–Cr/SiC Coatings on Inconel 600 Deposited by Arc Welding
by Tayfun Çetin
Crystals 2026, 16(1), 49; https://doi.org/10.3390/cryst16010049 - 11 Jan 2026
Viewed by 249
Abstract
In this study, the microstructural, mechanical, wear, and corrosion behavior of Ni-Al-Cr and Ni–Al–Cr/SiC composite coatings with different composition ratios, produced by electric arc melting on Inconel 600 substrates, was systematically investigated. Microhardness measurements revealed a significant and consistent increase in the hardness [...] Read more.
In this study, the microstructural, mechanical, wear, and corrosion behavior of Ni-Al-Cr and Ni–Al–Cr/SiC composite coatings with different composition ratios, produced by electric arc melting on Inconel 600 substrates, was systematically investigated. Microhardness measurements revealed a significant and consistent increase in the hardness values of the coatings depending on the increase in SiC reinforcement ratio (1%, 3%, and 5%). Wear tests showed that the coated samples exhibited significantly higher wear resistance compared to the pure Inconel 600 substrate. A significant improvement in wear resistance was achieved with the addition of SiC at 1% and 3% weight percentages; the width and depth of wear tracks were significantly reduced with SiC reinforcement. In contrast, increasing the SiC ratio to 5% weight percentage led to a decrease in wear resistance. This was attributed to particle aggregation at high SiC content, weakening of bonds at the matrix-reinforcement interface, and the behavior of SiC particles separated from the matrix as third-body abrasives. Electrochemical corrosion tests have shown that SiC-reinforced coatings form a more stable and permanent passive film, and corrosion resistance increases as the SiC content increases (1%, 3%, and 5%). The results indicate that the SiC reinforcement ratio affects the mechanical and electrochemical properties of Ni-Al-Cr/SiC composite coatings produced by electric arc melting. Full article
(This article belongs to the Special Issue Microstructure Analysis, Phase Composition and Properties of Metal)
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22 pages, 9932 KB  
Article
Grinding-Electrode-Assisted Short Electric Arc Machining of GH4099: A Composite Approach to Surface Integrity
by Bingbing Wang, Shengwei Ding, Jianping Zhou, Jiangtao Hu, Tianyu Sun and Lei Sha
Materials 2026, 19(1), 61; https://doi.org/10.3390/ma19010061 - 23 Dec 2025
Viewed by 332
Abstract
This study introduces a composite method that integrates a diamond-coated tubular grinding electrode with short electric arc machining (SEAM) for GH4099. Mechanical micro-grinding and arc erosion act concurrently within the inter-electrode gap, enabling an in situ “erode–dress” coupling in which the grinding action [...] Read more.
This study introduces a composite method that integrates a diamond-coated tubular grinding electrode with short electric arc machining (SEAM) for GH4099. Mechanical micro-grinding and arc erosion act concurrently within the inter-electrode gap, enabling an in situ “erode–dress” coupling in which the grinding action levels nascent craters and promotes debris evacuation while SEAM supplies localized thermal–electrical energy for removal. A design-of-experiment scheme probes discharge and grinding factors, and performance is evaluated by material removal behavior, electrode wear, and surface integrity. Within a robust window (12–24 V; 500–2000 r/min), the composite process sustains stable discharges without catastrophic melting at 24 V and yields dense, uniform textures. Representative surfaces show controllable areal roughness (Sa ≈ 14–27 µm across 80#–600#), reflecting a practical finishing–efficiency trade-off. Multi-scale characterization (3D topography, cross-sectional metallography, SEM) evidences suppression of recast steps, macro-protrusions, and irregular pits, with more evenly distributed, shallower grinding traces compared to those with single-mode SEAM. The comparative analyses clarify discharge stabilization and recast-layer mitigation mechanisms, establishing a feasible pathway to high-quality, high-efficiency composite SEAM of GH4099 without resorting to overly aggressive electrical conditions. Full article
(This article belongs to the Section Electronic Materials)
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49 pages, 13896 KB  
Review
A Review on In-Situ Monitoring in Wire Arc Additive Manufacturing: Technologies, Applications, Challenges, and Needs
by Mohammad Arjomandi, Jackson Motley, Quang Ngo, Yoosuf Anees, Muhammad Ayaan Afzal and Tuhin Mukherjee
Machines 2026, 14(1), 19; https://doi.org/10.3390/machines14010019 - 22 Dec 2025
Viewed by 1009
Abstract
Wire Arc Additive Manufacturing (WAAM), also known as Wire Arc Directed Energy Deposition, is used for fabricating large metallic components with high deposition rates. However, the process often leads to residual stress, distortion, defects, undesirable microstructure, and inconsistent bead geometry. These challenges necessitate [...] Read more.
Wire Arc Additive Manufacturing (WAAM), also known as Wire Arc Directed Energy Deposition, is used for fabricating large metallic components with high deposition rates. However, the process often leads to residual stress, distortion, defects, undesirable microstructure, and inconsistent bead geometry. These challenges necessitate reliable in-situ monitoring for process understanding, quality assurance, and control. While several reviews exist on in-situ monitoring in other additive manufacturing processes, systematic coverage of sensing methods specifically tailored for WAAM remains limited. This review fills that gap by providing a comprehensive analysis of existing in-situ monitoring approaches in WAAM, including thermal, optical, acoustic, electrical, force, and geometric sensing. It compares the relative maturity and applicability of each technique, highlights the challenges posed by arc light, spatter, and large melt pool dynamics, and discusses recent advances in real-time defect detection and control, process monitoring, microstructure and property prediction, and minimization of residual stress and distortion. Apart from providing a synthesis of the existing literature, the review also provides research needs, including the standardization of monitoring methodologies, the development of scalable sensing systems, integration of advanced AI-driven data analytics, coupling of real-time monitoring with multi-physics modeling, exploration of quantum sensing, and the transition of current research from laboratory demonstrations to industrial-scale WAAM implementation. Full article
(This article belongs to the Special Issue In Situ Monitoring of Manufacturing Processes)
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12 pages, 4199 KB  
Article
Comparative Study on Reduction in Oolitic High-Phosphorus Iron-Ore Lumps and Pellets Under H2 Atmosphere
by Haoting Ma, Yan Liu and Huiqing Tang
Metals 2025, 15(12), 1319; https://doi.org/10.3390/met15121319 - 28 Nov 2025
Viewed by 357
Abstract
High-phosphorus iron ore can be utilized using a technical route of hydrogen-based shaft furnace reduction, followed by electric arc furnace (EAF) melting separation. In shaft furnace reduction, both pellet and lump ore could serve as feedstock. To optimize the charge pattern in the [...] Read more.
High-phosphorus iron ore can be utilized using a technical route of hydrogen-based shaft furnace reduction, followed by electric arc furnace (EAF) melting separation. In shaft furnace reduction, both pellet and lump ore could serve as feedstock. To optimize the charge pattern in the H2-based shaft furnace, an investigation of the reduction behavior of high-phosphorus iron ore lumps and pellets under H2 atmosphere was conducted. Results revealed distinct differences between the lumps and the pellets in terms of physicochemical characteristics, maximum reduction fractions, microstructure evolution, and reduction kinetics characteristics. The lumps exhibited a notable presence of oolitic structures with 60.08 wt.% total iron, 11.69 wt.%. Fe2+ ion, and 0.80 wt.% phosphorus. Under H2 atmosphere, the lumps achieved a maximum reduction fraction of 0.80. During the reduction, fayalite formed in the early stage, and glassy phases appeared in the later stage. The rate-controlling steps included internal gas diffusion, interfacial chemical reaction, and solid-state diffusion of ions. In contrast, the oolitic structures were completely disrupted in the pellets. The pellets contained 56.01 wt.% total iron, 0.86 wt.% Fe2+ ions, and 0.73 wt.% phosphorus. The pellets reached a full reduction under H2 atmosphere with negligible formation of fayalite and glassy phases. The rate-controlling steps included internal gas diffusion and interfacial chemical reaction. Full article
(This article belongs to the Special Issue Recent Developments in Ironmaking)
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23 pages, 6053 KB  
Article
Investigation of the Possibility of Obtaining Metallized Titanomagnetite Briquettes Suitable for Utilization in the Steelmaking Process
by Andrey N. Dmitriev, Galina Yu. Vitkina, Elena A. Vyaznikova, Roman V. Alektorov, Vladimir V. Kataev, Larisa A. Marshuk and Yulia E. Burova
Metals 2025, 15(11), 1250; https://doi.org/10.3390/met15111250 - 16 Nov 2025
Cited by 1 | Viewed by 403
Abstract
The present study explores the production of metallized titanomagnetite briquettes, with a view to addressing two key issues. Firstly, it seeks to address the growing shortage of high-quality iron-bearing raw materials. Secondly, it looks at how to meet the increasingly stringent environmental constraints. [...] Read more.
The present study explores the production of metallized titanomagnetite briquettes, with a view to addressing two key issues. Firstly, it seeks to address the growing shortage of high-quality iron-bearing raw materials. Secondly, it looks at how to meet the increasingly stringent environmental constraints. The conventional blast-furnace treatment of titanomagnetite is hindered by the formation of refractory Ti-rich slags. It is hereby proposed that a single-cycle briquetting process in conjunction with a thermal reduction route should be utilized. This approach enables precise regulation of the Fe/flux ratio. Experiments were conducted on a low-grade titanomagnetite concentrate (68.5% Fe) from the Pervouralsk deposit (Russia). Cylindrical briquettes (D 15–20 mm, h 8–10 mm) were subjected to a pressure of 300 MPa during the pressing process, with the utilization of diverse binders comprising rubber cement, CaO, graphite + water, and basic oxygen-furnace (BOF) slag + sodium silicate. Following an oxidative pre-heating process at 1300 °C for two hours, followed by a gas-based reduction process at 1050 °C for three hours, with a CO/N2 ratio of 90/10, the products demonstrated an oxidation rate of 85–95% and a cold compression strength of 16–80 MPa. The highest observed strength (80 MPa) was obtained with a binder comprising CaO·MgO·2SiO2 (diopside/merwinite), which forms a low-viscosity melt, fills 90% of pores and crystallizes as acicular Mg-SFCA-I during cooling. Conversely, the CaO·TiO2 and FeO·TiO2 + Fe3C associations yield brittle structures and a maximum strength of 16 MPa. The optimum briquette (0.55% CaO, D/H = 20/10 mm) exhibited a 95.7% metallization degree, a compressive strength of 48.9 MPa, and dimensional changes within acceptable limits, thus fulfilling the requirements for electric arc furnace feedstock. Further research is required in the form of a full Life Cycle Assessment and pilot-scale testing. However, the results obtained thus far confirm that titanomagnetite briquettes with a binder consisting of CaO, MgO and SiO2 are a promising alternative to pellets for low-carbon steelmaking. Full article
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17 pages, 2347 KB  
Essay
Study on Combustion Characteristics and Damage of Single-Phase Ground Fault Arc in 10 kV Distribution Network Cable
by Ziheng Pu, Yiyu Du, Shuai Wang, Zhigang Ren, Kuan Ye and Wei Guo
Fire 2025, 8(11), 414; https://doi.org/10.3390/fire8110414 - 26 Oct 2025
Viewed by 935
Abstract
The neutral point of a 10 kV distribution network often adopts an arc suppression coil or high resistance grounding mode to ensure the reliability of the power supply. The single-phase grounding fault current is below 10 A, and the distribution network can continue [...] Read more.
The neutral point of a 10 kV distribution network often adopts an arc suppression coil or high resistance grounding mode to ensure the reliability of the power supply. The single-phase grounding fault current is below 10 A, and the distribution network can continue to operate with the fault for up to 2 h. However, long-time arc faults may ignite cables and cause electrical fires, causing further damage to adjacent cables and seriously affecting the safety of the power grid. To study the combustion characteristics of a single-phase grounding fault of a distribution network cable under the action of a long-term small current arc, the cable fault ignition test was carried out by using the arc ignition method of welding tin wire fuses. Then, the temperature distribution of the cable channel in an electrical fire was simulated, based on an FDS simulation, and the damage of adjacent cables under typical layout was further analyzed. The results show that the 10 kV cable was quickly ignited by the high temperature arc within 0.04 s after the breakdown and damage of the cable. Flammable XLPE insulation melted or even dripped off at a high temperature in fire. Thus, the fire spread to both ends when burning. Under the condition of 4–10 A, the maximum flame temperatures above the arc fault point reached 725 °C, 792 °C, 812 °C and 907 °C, respectively. According to the network structure, some protection, such as fireproof tape, needs to be applied directly above the faulty cable when the fault current exceeds 6 A. Full article
(This article belongs to the Special Issue Cable and Wire Fires)
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28 pages, 33891 KB  
Article
Influence of Substrate Preheating on Processing Dynamics and Microstructure of Alloy 718 Produced by Directed Energy Deposition Using a Laser Beam and Wire
by Atieh Sahraeidolatkhaneh, Achmad Ariaseta, Gökçe Aydin, Morgan Nilsen and Fredrik Sikström
Metals 2025, 15(11), 1184; https://doi.org/10.3390/met15111184 - 25 Oct 2025
Viewed by 900
Abstract
Effective thermal management is essential in metal additive manufacturing to ensure process stability and desirable material properties. Directed energy deposition using a laser beam and wire (DED-LB/w) enables the production of large, high-performance components but remains sensitive to adverse thermal effects during multi-layer [...] Read more.
Effective thermal management is essential in metal additive manufacturing to ensure process stability and desirable material properties. Directed energy deposition using a laser beam and wire (DED-LB/w) enables the production of large, high-performance components but remains sensitive to adverse thermal effects during multi-layer deposition due to heat accumulation. While prior studies have investigated interlayer temperature control and substrate preheating in DED modalities, including laser-powder and arc-based systems, the influence of substrate preheating in DED-LB/w has not been thoroughly examined. This study employs substrate preheating to simulate heat accumulation and assess its effects on melt pool geometry, wire–melt pool interaction, and the microstructural evolution of Alloy 718. Experimental results demonstrate that increased substrate temperatures lead to a gradual expansion of the melt pool, with a notable transition occurring beyond 400 °C. Microstructural analysis reveals that elevated preheat temperatures promote coarser secondary dendrite arm spacing and the development of wider columnar grains. Moreover, Nb-rich secondary phases, including the Laves phase, exhibit increased size but relatively unchanged area fractions. Observations from electrical conductance measurements and coaxial visual imaging show that preheat temperature significantly affects the process dynamics and microstructural evolution, providing a basis for advanced process control strategies. Full article
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16 pages, 4244 KB  
Article
Case Study on Investigation of Electrical Cabinet Fire Caused by Poor Electrical Contact
by Jing Zhang, Changzheng Li, Guofeng Su and Wenzhong Mi
Fire 2025, 8(11), 412; https://doi.org/10.3390/fire8110412 - 24 Oct 2025
Viewed by 2099
Abstract
Electrical cabinet fire is a prevalent type of electrical fire. It can result in significant casualties and major damage to residential dwellings, chemical plants, or other facilities. This study proposes an investigation methodology for electrical cabinet fires. It includes evidence collection and reasoning [...] Read more.
Electrical cabinet fire is a prevalent type of electrical fire. It can result in significant casualties and major damage to residential dwellings, chemical plants, or other facilities. This study proposes an investigation methodology for electrical cabinet fires. It includes evidence collection and reasoning inference, reverse deduction, and comprehensive analysis. Using a cabinet fire as a case study, macro and micro trace analyses are performed utilizing a stereomicroscope, a scanning electron microscope, and an energy-dispersive spectrometer. The typical characteristics of traces, encompassing melting marks, arc beads, and displacement, are summarized. The evidence suggests that poor electrical contact is the primary cause. A thermal–electrical–mechanical coupling model is developed to simulate poor contact on copper busbars. The results reveal that thermal stress caused by local overheating can lead to the deformation and displacement of the busbar. The calculation indicates that the temperature rise triggered by poor contact can reach 1040 °C. The maximum displacement of the busbar caused by thermal stress is 6.2 mm. Force analysis indicates that one busbar will descend under gravity and come into contact with another busbar of a different phase. The short circuit triggered by direct contact caused fire. To prevent such accidents, it is essential to verify that the specifications of bolts correspond to those of screw holes to avoid poor contact. Furthermore, insulating plates should be installed between distinct-phase busbars to prevent short circuits. Full article
(This article belongs to the Special Issue Advances in Industrial Fire and Urban Fire Research: 2nd Edition)
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18 pages, 3237 KB  
Review
Thermodynamic Guidelines for Minimizing Chromium Losses in Electric Arc Furnace Steelmaking
by Anže Bajželj and Jaka Burja
Metals 2025, 15(10), 1129; https://doi.org/10.3390/met15101129 - 11 Oct 2025
Viewed by 716
Abstract
In the production of stainless steel, chromium losses, particularly in the electric arc furnace (EAF) phase, pose a challenge. This study addresses these issues by reviewing and analyzing the thermodynamics of the Fe-Cr-C-O-(Si) system, highlighting discrepancies in existing literature regarding Gibbs free energies, [...] Read more.
In the production of stainless steel, chromium losses, particularly in the electric arc furnace (EAF) phase, pose a challenge. This study addresses these issues by reviewing and analyzing the thermodynamics of the Fe-Cr-C-O-(Si) system, highlighting discrepancies in existing literature regarding Gibbs free energies, interaction parameters, and other thermodynamic data. We developed a simple to use thermodynamic model to simulate the oxidation process using established data from scientific literature. The model calculates the equilibrium solubilities of chromium and carbon, showing how process variables like temperature, partial pressure of carbon monoxide, and silicon concentration influence chromium oxidation. The findings confirm that higher temperatures and the presence of silicon significantly reduce chromium loss by favoring carbon oxidation over chromium. The research concludes by providing practical guidelines for minimizing chromium losses in EAFs, such as protecting scrap with carbon, silicon, and aluminum; controlling oxygen intake; and ensuring a high melt temperature during decarburization. These guidelines aim to improve the economic efficiency and sustainability of stainless steel production. The paper is an expanded version of a prior conference paper. Full article
(This article belongs to the Special Issue Recent Developments and Research on Ironmaking and Steelmaking)
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16 pages, 12504 KB  
Article
Effect of Si Content on the Mechanical Behavior, Corrosion Resistance, and Passive Film Characteristics of Fe–Co–Ni–Cr–Si Medium-Entropy Alloys
by Sen Yang, Ran Wei, Xin Wei, Jiayi Cao and Jiepeng Ren
Coatings 2025, 15(10), 1137; https://doi.org/10.3390/coatings15101137 - 1 Oct 2025
Viewed by 907
Abstract
The nominal compositions of Fe65Co10−xNi10−xCr15Si2x (x = 1, 2, and 3 at.%) medium-entropy alloys (MEAs) were designed and fabricated by vacuum arc melting. Their microstructure, hardness, and mechanical properties were [...] Read more.
The nominal compositions of Fe65Co10−xNi10−xCr15Si2x (x = 1, 2, and 3 at.%) medium-entropy alloys (MEAs) were designed and fabricated by vacuum arc melting. Their microstructure, hardness, and mechanical properties were systematically characterized. Corrosion behavior was evaluated in 3.5 wt.% NaCl solution by potentiodynamic polarization and electrochemical impedance spectroscopy. The investigated MEAs exhibit a dual-phase microstructure composed of face-centered cubic (FCC) and body-centered-cubic (BCC) phases. With increasing Si content, yield strength and ultimate tensile strength increase, while uniform elongation decreases. Hardness also increases with increasing Si content. For the x = 3 MEA, the yield strength, ultimate tensile strength, and hardness of are ~518 MPa, ~1053 MPa, and 262 ± 4.8 HV, respectively. The observed strengthening can be primarily attributed to solid solution strengthening effect by Si. Polarization curves indicate that the x = 3 MEA exhibits the best corrosion resistance with the lowest corrosion current density ((0.401 ± 0.19) × 10−6 A × cm−2) and corrosion rate ((4.65 ± 0.19) × 10–2 μm × year−1)). Equivalent electric circuit analysis suggests the formation of a stable passive oxide film on the MEAs. This conclusion is supported by the capacitive behavior, high impedance values (> 104 Ω cm2) at low frequencies, and phase angles within a narrow window of 80.05°~80.64° in the medium-frequency region. The passive-film thickness was calculated and the corrosion morphology was analyzed by SEM. These results provide a reference for developing high-strength, corrosion-resistant, medium-entropy alloys. Full article
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23 pages, 18943 KB  
Article
Influence of Tramp Elements on Phase Transformations, Microstructure and Hardness of a 0.3 wt.%C Low-Alloyed Steel
by Marek Gocnik, Lukas Hatzenbichler, Michael Meindlhumer, Phillip Haslberger, Matthew Galler, Andreas Stark, Claes-Olof A. Olsson, Jozef Keckes and Ronald Schnitzer
Metals 2025, 15(9), 1053; https://doi.org/10.3390/met15091053 - 20 Sep 2025
Viewed by 1157
Abstract
Decarbonizing the steel industry relies on a transition from carbon-intensive blast furnace technology to scrap-based secondary steelmaking using electric arc furnaces. This transition introduces tramp elements and leads to their gradual accumulation, which can significantly influence the functional properties of chemically sensitive steel [...] Read more.
Decarbonizing the steel industry relies on a transition from carbon-intensive blast furnace technology to scrap-based secondary steelmaking using electric arc furnaces. This transition introduces tramp elements and leads to their gradual accumulation, which can significantly influence the functional properties of chemically sensitive steel grades. In this study, the combined impact of several tramp element contents on the phase transformations, microstructure and mechanical properties of a 0.3 wt.% C low-alloyed steel was investigated. To achieve this, a reference alloy was produced using the conventional blast furnace production route. It was then compared with two trial alloys, which contained intentionally elevated levels of tramp elements and were produced through an experimental melting route designed to simulate scrap-based electric arc furnace production. The experimental characterization included light optical and electron microscopy, electron back-scatter diffraction, in situ synchrotron high-energy X-ray diffraction coupled with dilatometry, and Vickers hardness testing. The results revealed the formation of displacive transformation products such as martensite and showed that austenite was retained in the tramp element-enriched trial alloys. The combination of solid solution strengthening and martensitic transformation led to a gradual increase in hardness. These findings underscore the critical role of tramp elements in determining the microstructural and mechanical response of steels produced from scrap-based feedstock. Full article
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16 pages, 1268 KB  
Article
Reduction of Liquid Steelmaking Slag Using Hydrogen Gas as a Reductant
by Mykyta Levchenko, Hans Peter Markus, Marcus Schreiner, Martin Gräbner and Olena Volkova
Metals 2025, 15(9), 984; https://doi.org/10.3390/met15090984 - 3 Sep 2025
Viewed by 1256
Abstract
Electric arc furnace slag is a major by-product of steelmaking, yet its industrial utilization remains limited due to its complex chemical and mineralogical composition. This study presents a hydrogen-based approach to recover metallic components from EAF slag for potential reuse in steelmaking. Laboratory [...] Read more.
Electric arc furnace slag is a major by-product of steelmaking, yet its industrial utilization remains limited due to its complex chemical and mineralogical composition. This study presents a hydrogen-based approach to recover metallic components from EAF slag for potential reuse in steelmaking. Laboratory experiments were conducted by melting 50 g of industrial slag samples at 1600 °C and injecting hydrogen gas through a ceramic tube into the liquid slag. After cooling, both the slag and the metallic phases were analyzed for their chemical and phase compositions. Additionally, the reduction process was modeled using a combination of approaches, including the thermochemical software FactSage 8.1, models for density, surface tension, and viscosity, as well as a diffusion model. The injection of hydrogen resulted in the reduction of up to 40% of the iron oxide content in the liquid slag. In addition, the fraction of reacted hydrogen gas was calculated. Full article
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17 pages, 6873 KB  
Article
Analysis of the Corrosive Process Originating from Electrical Arcs on Ag–Ni Contacts Based on Residual Layer Distribution
by Claudia-Olimpia Stasac, Andrei-Dan Tomșe, Traian Octavian Costea, Vlad-Andrei Moldovan, Livia Bandici, Mircea-Nicolae Arion and Francisc-Ioan Hathazi
Processes 2025, 13(9), 2808; https://doi.org/10.3390/pr13092808 - 2 Sep 2025
Cited by 1 | Viewed by 1060
Abstract
This study investigates the arc-induced degradation mechanisms of Ag–Ni (90/10) electrical contacts under controlled laboratory cycling conditions using a custom PLC-controlled switching system. The degradation process is characterized by three distinct wear stages: initial arc erosion with localized material removal, a restructuring phase [...] Read more.
This study investigates the arc-induced degradation mechanisms of Ag–Ni (90/10) electrical contacts under controlled laboratory cycling conditions using a custom PLC-controlled switching system. The degradation process is characterized by three distinct wear stages: initial arc erosion with localized material removal, a restructuring phase marked by melting and material redistribution, and a final film deposition stage leading to topographical homogenization but functional degradation. Raman spectroscopy confirms progressive nickel oxide and carbonaceous contamination, correlating with contact resistance trends that exhibit multi-phase behavior. Subsurface analysis reveals critical structural damage at mid-life cycles, emphasizing the importance of preventive maintenance. The findings advance understanding of wear mechanisms in Ag–Ni contacts and provide insights into optimizing their service life in industrial switching applications. Full article
(This article belongs to the Section Materials Processes)
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25 pages, 7708 KB  
Review
A Review of Heat Transfer and Numerical Modeling for Scrap Melting in Steelmaking Converters
by Mohammed B. A. Hassan, Florian Charruault, Bapin Rout, Frank N. H. Schrama, Johannes A. M. Kuipers and Yongxiang Yang
Metals 2025, 15(8), 866; https://doi.org/10.3390/met15080866 - 1 Aug 2025
Viewed by 1931
Abstract
Steel is an important product in many engineering sectors; however, steelmaking remains one of the largest CO2 emitters. Therefore, new governmental policies drive the steelmaking industry toward a cleaner and more sustainable operation such as the gas-based direct reduction–electric arc furnace process. [...] Read more.
Steel is an important product in many engineering sectors; however, steelmaking remains one of the largest CO2 emitters. Therefore, new governmental policies drive the steelmaking industry toward a cleaner and more sustainable operation such as the gas-based direct reduction–electric arc furnace process. To become carbon neutral, utilizing more scrap is one of the feasible solutions to achieve this goal. Addressing knowledge gaps regarding scrap heterogeneity (size, shape, and composition) is essential to evaluate the effects of increased scrap ratios in basic oxygen furnace (BOF) operations. This review systematically examines heat and mass transfer correlations relevant to scrap melting in BOF steelmaking, with a focus on low Prandtl number fluids (thick thermal boundary layer) and dense particulate systems. Notably, a majority of these correlations are designed for fluids with high Prandtl numbers. Even for the ones tailored for low Prandtl, they lack the introduction of the porosity effect which alters the melting behavior in such high temperature systems. The review is divided into two parts. First, it surveys heat transfer correlations for single elements (rods, spheres, and prisms) under natural and forced convection, emphasizing their role in predicting melting rates and estimating maximum shell size. Second, it introduces three numerical modeling approaches, highlighting that the computational fluid dynamics–discrete element method (CFD–DEM) offers flexibility in modeling diverse scrap geometries and contact interactions while being computationally less demanding than particle-resolved direct numerical simulation (PR-DNS). Nevertheless, the review identifies a critical gap: no current CFD–DEM framework simultaneously captures shell formation (particle growth) and non-isotropic scrap melting (particle shrinkage), underscoring the need for improved multiphase models to enhance BOF operation. Full article
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