Search Results (1,119)

A comprehensive techno-economic assessment was undertaken to determine the viability of bioethanol production from sugarcane bagasse in Thailand through organosolv fractionation, incorporating three distinct catalytic systems: sulfuric acid, formic acid, and sodium methoxide. Rigorous process simulations were executed using Aspen Plus, facilitating the derivation of detailed mass and energy balances, which served as the foundational input for downstream cost modeling. Economic performance metrics, including the total annualized cost and minimum ethanol selling price, were systematically quantified for each scenario. Among the evaluated configurations, the formic acid-catalyzed organosolv system exhibited superior techno-economic attributes, achieving the lowest unit production costs of 1.14 USD/L for ethanol and 1.84 USD/kg for lignin, corresponding to an estimated ethanol selling price of approximately 1.14 USD/L. This favorable outcome was attained with only moderate capital intensity, indicating a well-balanced trade-off between operational efficiency and investment burden. Conversely, the sodium methoxide-based process configuration imposed the highest economic burden, with a TAC of 15.27 million USD/year, culminating in a markedly elevated MESP of 5.49 USD/kg (approximately 4.33 USD/L). The sulfuric acid-driven system demonstrated effective delignification performance. Sensitivity analysis revealed that reagent procurement costs exert the greatest impact on TAC variation, highlighting chemical expenditure as the key economic driver. These findings emphasize the critical role of solvent choice, catalytic performance, and process integration in improving the cost-efficiency of lignocellulosic ethanol production. Among the examined options, the formic acid-based organosolv process stands out as the most economically viable for large-scale implementation within Thailand’s bioeconomy. Full article

A just and sustainable energy transition in historically coal-dependent regions like Kentucky requires more than the adoption of new technologies and market-based solutions. This study uses a stated preferences approach to evaluate public support for various attributes of energy transition programs, revealing broad backing for moving away from coal, as indicated by a negative willingness to pay (WTP) for the status quo (–USD 4.63). Key findings show strong bipartisan support for solar energy, with Democrats showing the highest WTP at USD 8.29, followed closely by Independents/Others at USD 8.22, and Republicans at USD 8.08. Wind energy also garnered support, particularly among Republicans (USD 4.04), who may view it as more industry-compatible and less ideologically polarizing. Job creation was a dominant priority across political affiliations, especially for Independents (USD 9.07), indicating a preference for tangible, near-term economic benefits. Similarly, preserving cultural values tied to coal received support among Independents/Others (USD 4.98), emphasizing the importance of place-based identity in shaping preferences. In contrast, social support programs (e.g., job retraining) and certain post-mining land uses (e.g., recreation and conservation) were less favored, possibly due to their abstract nature, delayed benefits, and political framing. Findings from Kentucky offer insights for other coal-reliant states like Wyoming, West Virginia, Pennsylvania, Indiana, and Illinois. Ultimately, equitable transitions must integrate local voices, address cultural and economic realities, and ensure community-driven planning and investment. Full article

Ecosystem restoration represents a promising solution for enhancing ecosystem services and environmental sustainability. However, border regions—characterized by ecological fragility and geopolitical complexity—remain underrepresented in ecosystem service and restoration research. To fill this gap, we coupled spatially explicit models (e.g., InVEST and RUSLE) with scenario analysis to quantify the ecosystem service potential that could be achieved in China’s Tibetan borderlands under two interacting agendas: ecological restoration and border-strengthening policies. Restoration feasibility was evaluated through combining local biophysical constraints, economic viability (via restoration-induced carbon gains vs. opportunity costs), operational practicality, and simulated infrastructure expansion. The results showed that per-unit-area ecosystem services in border counties (particularly Medog, Cona, and Zayu) exceed that of interior Tibet by a factor of two to four. Combining these various constraints, approximately 4–17% of the border zone remains cost-effective for grassland or forest restoration. Under low carbon pricing (US$10 t⁻¹ CO₂), the carbon revenue generated through restoration is insufficient to offset the opportunity cost of agricultural production, constituting a major constraint. Habitat quality, soil conservation, and carbon sequestration increase modestly when induced by restoration, but a pronounced carbon–water trade-off emerges. Planned infrastructure reduces restoration benefits only slightly, whereas raising the carbon price to about US$50 t⁻¹ CO₂ substantially expands such benefits. These findings highlight both the opportunities and limits of ecosystem restoration in border regions and point to carbon pricing as the key policy lever for unlocking cost-effective restoration. Full article

This review outlines a comprehensive methodology for the research and development of heterogeneous catalytic technologies (R&D_HeCaTe). Emphasis is placed on the fundamental interactions between reactants, solvents, and heterogeneous catalysts—specifically the roles of catalytic centers and support materials (e.g., functional groups) in modulating activation energies and stabilizing catalytic functionality. Particular attention is given to catalyst deactivation mechanisms and potential regeneration strategies. The application of molecular modeling and chemical engineering analyses, including reaction kinetics, thermal effects, and mass and heat transport phenomena, is identified as essential for R&D_HeCaTe. Reactor configuration is discussed in relation to key physicochemical parameters such as molecular diffusivity, reaction exothermicity, operating temperature and pressure, and the phase and “aggressiveness” of the reaction system. Suitable reactor types—such as suspension reactors, fixed-bed reactors, and flow microreactors—are evaluated accordingly. Economic and environmental considerations are also addressed, with a focus on the complexity of reactions, selectivity versus conversion trade-offs, catalyst disposal, and separation challenges. To illustrate the breadth and applicability of the proposed framework, representative industrial processes are discussed, including ammonia synthesis, fluid catalytic cracking, methanol production, alkyl tert-butyl ethers, and aniline. Full article

Silvopastoral systems, though ecologically beneficial, remain underrepresented in the European Union’s Common Agricultural Policy and are seldom studied in Mediterranean contexts. The current study assesses both the environmental and economic aspects of five typical silvopastoral systems in central Greece, encompassing cattle, sheep, and goat farming. A Life Cycle Assessment approach was implemented to quantify greenhouse gas emissions using economic allocation, distributing impacts between milk and meat outputs. Enteric fermentation was the major emission source, accounting for up to 65.14% of total emissions in beef-based systems, while feeding and soil emissions were more prominent in mixed and small ruminant systems. Total farm-level emissions ranged from 60,609 to 273,579 kg CO₂eq per year. Economically, only beef-integrated systems achieved an average annual profitability above EUR 20,000 per farm, based on financial data averaged over the last five years (2020–2024) from selected case studies in central Greece, while the remaining systems fell below the national poverty threshold for an average household, underscoring concerns about their economic viability. The findings underline the dual challenges of economic viability and policy neglect, stressing the need for targeted support if these multifunctional systems are to add value to EU climate goals and rural sustainability. Full article

Direct electrification and hydrogen utilization represent two key pathways for decarbonizing the glass industry, with their effectiveness subject to adequate furnace design and renewable energy availability. This study presents a techno-economic assessment for optimal solar energy integration in a representative 300 t/d oxyfuel container glass furnace with a specific energy consumption of 4.35 GJ/t. A mixed-integer linear programming formulation is developed to evaluate specific melting costs, carbon emissions, and renewable energy self-consumption and self-production rates across three scenarios: direct solar coupling, battery storage, and a hydrogen-based infrastructure. Battery storage achieves the greatest reductions in specific melting costs and emissions, whereas hydrogen integration minimizes electricity export to the grid. By incorporating capital investment considerations, the study quantifies the cost premiums and capacity requirements under varying decarbonization targets. A combination of 30 MW of solar plant and 9 MW of electric boosting enables the realization of around 30% carbon reduction while increasing total costs by 25%. Deeper decarbonization targets require more advanced systems, with batteries emerging as a cost-effective solution. These findings offer critical insights into the economic and environmental trade-offs, as well as the technical constraints associated with renewable energy adoption in the glass industry, providing a foundation for strategic energy and decarbonization planning. Full article

This study proposes an integrated, machine learning-based multi-objective optimization framework to evaluate and optimize the utilization of steel slag in road base layers, simultaneously addressing economic costs and environmental impacts. A comprehensive dataset of 482 scenarios was engineered based on literature-informed parameters, encompassing transport distance, processing energy intensity, initial moisture content, gradation adjustments, and regional electricity emission factors. Four advanced tree-based ensemble regression algorithms—Random Forest Regressor (RFR), Extremely Randomized Trees (ERTs), Gradient Boosted Regressor (GBR), and Extreme Gradient Boosting Regressor (XGBR)—were rigorously evaluated. Among these, GBR demonstrated superior predictive performance (R² > 0.95, RMSE < 7.5), effectively capturing complex nonlinear interactions inherent in slag processing and logistics operations. Feature importance analysis via SHapley Additive exPlanations (SHAP) provided interpretative insights, highlighting transport distance and energy intensity as dominant factors affecting unit cost, while moisture content and grid emission factor predominantly influenced CO₂ emissions. Subsequently, the Gradient Boosted Regressor model was integrated into a Non-Dominated Sorting Genetic Algorithm II (NSGA-II) framework to explore optimal trade-offs between cost and emissions. The resulting Pareto front revealed a diverse solution space, with significant nonlinear trade-offs between economic efficiency and environmental performance, clearly identifying strategic inflection points. To facilitate actionable decision-making, the Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) method was applied, identifying an optimal balanced solution characterized by a transport distance of 47 km, energy intensity of 1.21 kWh/ton, moisture content of 6.2%, moderate gradation adjustment, and a grid CO₂ factor of 0.47 kg CO₂/kWh. This scenario offered a substantial reduction (45%) in CO₂ emissions relative to cost-minimized solutions, with a moderate increase (33%) in total cost, presenting a realistic and balanced pathway for sustainable infrastructure practices. Overall, this study introduces a robust, scalable, and interpretable optimization framework, providing valuable methodological advancements for sustainable decision making in infrastructure planning and circular economy initiatives. Full article

Against the backdrop of rapid urbanization in western China, which has triggered remarkable land-use changes and habitat degradation, Chengdu, as a developed city in China, plays a demonstrative and leading role in the economic and social development of China during the transition period. Therefore, integrated modeling approaches are required to balance development and conservation. This study responds to this need by conducting a scenario-based assessment of urbanization-induced land-use changes and regional habitat quality dynamics in Chengdu (1990–2030), using the FLUS-InVEST model. By integrating remote sensing-derived land-use data from 1990, 1995, 2000, 2005, 2010, 2015, and 2020, we simulate future regional habitat quality under three policy scenarios: natural development, ecological priority, and cropland protection. Key findings include the following: (1) From 1990 to 2020, cropland decreased by 1917.78 km², while forestland and built-up areas increased by 509.91 km² and 1436.52 km², respectively. Under the 2030 natural development scenario, built-up expansion and cropland reduction are projected. Ecological priority policies would enhance forestland (+4.2%) but slightly reduce cropland. (2) Regional habitat quality declined overall (1990–2020), with the sharpest drop (ΔHQ = −0.063) occurring between 2000 and 2010 due to accelerated urbanization. (3) Scenario analysis reveals that the ecological priority strategy yields the highest regional habitat quality (HQ_mean = 0.499), while natural development results in the lowest (HQ_mean = 0.444). This study demonstrates how the FLUS-InVEST model can quantify the trade-offs between urbanization and regional habitat quality, offering a scientific framework for balancing development and ecological conservation in rapidly urbanizing regions. The findings highlight the effectiveness of ecological priority policies in mitigating habitat degradation, with implications for similar cities seeking sustainable land-use strategies that integrate farmland protection and forest restoration. Full article

Achieving carbon emission reductions in the residential building sector while maintaining economic growth represents a global challenge, particularly in rapidly developing regions with internal disparities. This study examines Jiangsu Province in eastern China—a economic hub with north-south development gradients—to develop an integrated framework for differentiated carbon reduction pathways. The methodology combines spatial autocorrelation analysis, logarithmic mean Divisia index (LMDI) decomposition, system dynamics modeling, and Tapio decoupling analysis to examine urban residential building emissions across three regions from 2016–2022. Results reveal significant spatial clustering of emissions (Moran’s I peaking at 0.735), with energy consumption per unit area as the dominant driver across all regions (contributing 147.61%, 131.82%, and 147.57% respectively). Scenario analysis demonstrates that energy efficiency policies can reduce emissions by 10.1% while maintaining 99.2% of economic performance, enabling carbon peak achievement by 2030. However, less developed northern regions emerge as binding constraints, requiring technology investments. Decoupling analysis identifies region-specific optimal pathways: conventional development for advanced regions, balanced approaches for transitional areas, and subsidies for lagging regions. These findings challenge assumptions about environment-economy trade-offs and provide a replicable framework for designing differentiated climate policies in heterogeneous territories, offering insights for similar regions worldwide navigating the transition to sustainable development. Full article

Traffic crashes and congestion generate high social and economic costs, yet traditional traffic monitoring methods, such as police patrols, fixed cameras, and helicopters, are costly, labor-intensive, and limited in spatial coverage. This paper presents a novel Drone Routing and Scheduling with Flexible Multiple Visits (DRSFMV) framework, an optimization model for planning drone-based highway monitoring under realistic operational constraints, including battery limits, variable monitoring durations, recharging at a depot, and target-specific inter-visit time limits. A mixed-integer nonlinear programming (MINLP) model and a linearized version (MILP) are presented to solve the problem. Due to the NP-hard nature of the underlying problem structure, a heuristic solver, Hexaly, is also used. A case study using real traffic census data from three Southern California counties tests the models across various network sizes and configurations. The MILP solves small and medium instances efficiently, and Hexaly produces high-quality solutions for large-scale networks. Results show clear trade-offs between drone availability and time-slot flexibility, and demonstrate that stricter revisit constraints raise operational cost. Full article

The global transition to clean energy necessitates integrated solutions that ensure both environmental sustainability and energy security. This paper proposes a scenario-based modeling framework for urban hybrid energy systems combining small modular reactors (SMRs), photovoltaic (PV) generation, and battery storage within a smart grid architecture. SMRs offer compact, low-carbon, and reliable baseload power suitable for urban environments, while PV and storage enhance system flexibility and renewable integration. Six energy mix scenarios are evaluated using a lifecycle-based cost model that incorporates both capital expenditures (CAPEX) and cumulative carbon costs over a 25-year horizon. The modeling results demonstrate that hybrid SMR–renewable systems—particularly those with high nuclear shares—can reduce lifecycle CO₂ emissions by over 90%, while maintaining long-term economic viability under carbon pricing assumptions. Scenario C, which combines 50% SMR, 40% PV, and 10% battery, emerges as a balanced configuration offering deep decarbonization with moderate investment levels. The proposed framework highlights key trade-offs between emissions and capital cost and seeking resilient and scalable pathways to support the global clean energy transition and net-zero commitments. Full article

Gobi solar greenhouses (GSGs) enhance energy, food, and financial security in Gobi Desert regions through passive solar utilization. Thermal mass walls are critical for plant thermal comfort in GSGs but can lead to resource waste if poorly designed. This study pioneers the integration of payback period constrains into thermal mass wall optimization, establishing a new performance–cost trade-off approach for GSG wall design, balancing thermal performance and economic feasibility. We quantified energy-conserving benefits against wall-construction costs to derive the optimal inner-layer thicknesses under <25% GSG lifespan payback criteria. Three GSG thermal mass walls in China’s Hexi Corridor were optimized. For the concrete-layered, stone-layered, and pebble-soil walls, the optimum inner-layer thicknesses were 0.47, 0.65, and 1.24 m, respectively, with extra costs of 620.75, 767.60, and 194.56 RMB yuan; annual energy-conserving benefits of 82.77, 102.35, and 51.88 RMB yuan·yr⁻¹; and payback periods of 7.5, 7.5, and 3.75 years. A dynamic thermal load analysis confirmed that GSGs with optimized walls required no heating during a sunny winter solstice night. Cooling loads of 33.15–35.27 kW further indicated the potential to maintain thermal comfort under colder weather conditions. This approach improves plant thermal comfort cost-effectively, advancing sustainable Gobi agriculture. Full article

This study explores the complex interaction between the Internet of Things (IoT) and the new energy sector and analyzes how their integration can catalyze a transition toward a sustainable low-carbon economy. Through the full-sample and rolling sub-sample methods, we empirically examine the dynamic interrelationship between China’s IoT index (IoT) and the New Energy Index (NEI). Quantitative analysis reveals significant time-varying characteristics and bidirectional causal complexity in the interaction between the IoT and new energy. The IoT has a dual-edged impact on the development of new sources of energy. In the long run, the IoT plays a dominant role in incentivizing new energy, helping to enhance its stability and economic value. However, during stages characterized by technological bottlenecks or resource competition, the high energy consumption of IoT infrastructure may suppress the investment returns of new energy. Simultaneously, new energy has both positive and negative impacts on the IoT. On the one hand, new energy provides low-cost, sustainable power to support the IoT, driving the construction of the IoT ecosystem. On the other hand, it may threaten the continuity of IoT power supply, and the complexity of standardization and regulation in the sector may constrain the development of the IoT. This study provides a fresh perspective on promoting the integration of digital technology and green energy, uncovering nonlinear trade-offs between innovation-driven growth and carbon reduction goals, and offering policy insights for cross-sectoral collaboration to achieve sustainability. Full article

This study investigates the application of the Analytic Hierarchy Process (AHP) as a decision-support mechanism for managing complex sustainability issues in industrial settings, specifically within the framework of circular economy principles. Focusing on a case from the brewery sector, developed under the EU ECOFACT initiative, this research evaluates ten distinct configurations for the must cooling process. These alternatives are assessed using environmental, economic, and technical criteria, drawing on data from life cycle assessment (LCA) and life cycle costing (LCC) methodologies. The findings indicate that selecting an optimal scenario involves balancing trade-offs among electricity and water consumption, operational efficiency, and overall environmental impacts. Notably, Scenario 3 emerges as the most balanced option, consistently demonstrating superior performance across the primary evaluation criteria. The use of AHP in this context proves valuable by introducing structure and transparency to a multifaceted decision-making process where quantitative metrics and sustainability objectives intersect. By integrating empirical industrial data with an established multi-criteria decision approach, this study highlights both the practical utility and existing limitations of conventional AHP, particularly its diminished ability to discriminate between alternatives when their scores are closely aligned. These insights suggest that hybrid or advanced AHP methodologies may be necessary to facilitate more nuanced decision-making for circular economy transitions in industrial environments. Full article

Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO₂) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO₂ severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO₂ thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO₂, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO₂ thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO₂ technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO₂-philic groups. Rheological tests conducted under scCO₂ conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO₂ (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO₂ and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO₂ thickeners. This research lays the foundation for green CO₂-based energy extraction technologies. Full article