Search Results (57)

Alluvial fan scree deposits (AFSDs) in arid/semi-arid regions are highly susceptible to rainfall-induced erosion, posing significant risks to infrastructure like oil pipelines. This study evaluates the efficacy of SH polymer materials in enhancing AFSD erosion resistance through three experimental approaches: film characterization, rainfall erosion simulation, and environmental compatibility assessment. Tensile tests demonstrated that SH polymer films (0.16–0.56 mm thick) retained >80% mass after prolonged immersion, exhibiting prolonged ductility (250 mm elongation) and stable post-immersion softening, ideal for enduring cyclic erosion. Rainfall simulations (200 mm/h intensity) revealed that SH application rates ≥ 1.5 kg/m² reduced soil loss by >90%, with 2.0 kg/m² ensuring near-complete slope integrity across planar/curved morphologies. Ecological tests confirmed SH’s environmental friendliness, as treated soils supported robust tall fescue growth without permeability inhibition. The findings advocate SH polymers as a sustainable solution for AFSD stabilization, combining mechanical resilience, terrain adaptability, and eco-compatibility. Full article

This study explores a series of eco-compatible, safe, inexpensive, and recyclable catalysts for the aza-Michael reaction, an essential transformation for constructing C-N bonds. In particular, we focus on hydrothermal carbons (HCB and HCC) prepared from chestnut cupule waste under mild, aqueous conditions, offering a sustainable alternative to traditional pyrolytic methods. These carbonaceous solids, thoroughly characterized by physicochemical techniques, exhibit notable catalytic activity, completing aza-Michael reactions in as little as 5–30 min for various model substrates. Their performance was benchmarked against Montmorillonite K10, [Cho][Pro] ionic liquid, and K10+[Cho][Pro], with the latter combination and [Cho][Pro] alone giving the fastest conversions. For example, the reaction of benzylamine with acrylonitrile reached complete conversion (typically 95% yield) in five minutes using [Cho][Pro], K10+[Cho][Pro], or likewise with HCB and HCC. Although the reactions catalyzed by hydrothermal carbons did not outperform in general those using K10-[Cho][Pro] or [Cho][Pro], they proceeded rapidly and afforded good to excellent yields. Furthermore, the HCC catalyst demonstrated excellent recyclability, maintaining its activity and yield over at least five cycles. These findings underscore the potential of hydrothermal carbons as efficient green heterogeneous catalysts, combining high surface area, porosity, and reusability with strong catalytic performance and scalability, in alignment with the principles of the circular economy. Full article

Organic soil pollution poses a persistent threat to environmental sustainability by disrupting nutrient cycling and ecosystem functioning. The biochar-activated persulfate (PS)-based advanced oxidation process (AOP) has emerged as a promising strategy for the sustainable remediation of organic-contaminated soils. This review provides a comprehensive overview of the recent progress in the PS-based degradation of organic pollutants, with a particular focus on the role of biochar as an efficient and environmental activator. This review further summarizes advancements in the design of modified biochars, including metal (Fe, Cu, Co, Mn, Zn, and La), non-metal (N, S, B, P), and functional group modifications, aimed at enhancing the PS activation efficiency while minimizing secondary environmental risks. Importantly, the overlooked contributions of soil microorganisms in PS/biochar systems are discussed, highlighting their potential to complement chemical oxidation and contribute to eco-compatible remediation pathways. This review emphasizes the sustainability-oriented evolution of PS/biochar technology, highlighting the importance of a cost-efficient implementation, ecological compatibility, and the rational engineering of smart, regenerable catalysts. These insights support the advancement of PS/biochar-based AOPs toward scalable, intelligent, and environmentally sustainable soil remediation. Full article

Marine microplastic pollution has emerged as a pressing environmental issue, with significant implications for aquatic ecosystems, human health and global biodiversity. Ports, acting as semi-enclosed environments, are critical zones where plastic waste, including microplastics, plastic fragments smaller than 5 mm, tend to accumulate. These settings provide controlled conditions that are ideal for deploying innovative solutions to monitor and mitigate the impact of microplastic pollution. This paper presents the design, development and initial testing of an autonomous surface drone engineered specifically to monitor and collect microplastics in port environments. Unlike traditional marine drones, this device operates exclusively at the water surface, leveraging mechanical filtration systems to capture and quantify microplastic fragments. Designed for cost-efficiency, ease of manufacturing and operational simplicity, this drone aligns with principles of environmental sustainability and scalability. By integrating readily available materials and modular components, it offers a replicable model for addressing microplastic pollution in localized aquatic systems. Full article

In many developing countries, human health problems are solved using local plants. Knowledge of their chemical composition and biological activities can contribute to the creation of natural-based products usefully employed in human health. In this work, we analysed Paederia grandidieri leaves extracted with diverse eco-compatible procedures and subjected to chemical, microbiological, and cellular compatibility assays. Fresh leaves of P. grandidieri were harvested in southern Madagascar, where most of the population relies on P. grandidieri for daily dental care. Leaves were dried and powdered. Distilled water and ethanol at 25 °C and 60 °C from 6 to 24 h were used for extraction. Polyphenol composition, antioxidant activity, and antibacterial, prebiotic, and cytotoxic properties of the extracts were analysed. The aqueous extracts contained higher levels of flavan-3-ols and flavanones, while the hydro-alcoholic extracts were richer in flavonols and flavones. The aqueous extracts showed the highest total phenolic and total flavonoid contents, and antioxidant activity. The hydro-alcoholic extracts showed antibacterial effects against Listeria monocytogenes and Pseudomonas aeruginosa, two key foodborne and environmental pathogens, while the aqueous extracts showed prebiotic effects against Streptococcus salivarius. The cytotoxic effects of P. grandidieri leaf extracts were evaluated using the MTT assay on mouse fibroblasts (L929 cell line). The most cytotoxic extract was the aqueous extract at 25 °C. Given that P. grandidieri is routinely employed by the southern Madagascar population with healthy and strong teeth with fewer cases of tooth decay with respect to other regions, and in light of the significant chemical and microbiological properties, we maintain that P. grandidieri can be a suitable candidate for the production of pro-health products for the oral cavity. More in-depth studies will ensure a broader picture of the impact of extracts, especially for possible oral use. Full article

A century after the first scientific research on the chemical structures of pyrethrins was published (in 1923), this paper aims to provide an exhaustive review of the historical research pathways and relative turning points that led to the discovery and mass production of pyrethroids, which have become among the most commercially successful insecticides. These compounds, which are not specific to any particular pest, are used globally and offer cost-effective advantages against a broad spectrum of pests in both agricultural and non-agricultural situations. They are utilized in the context of both harvest and post-harvest applications, as well as in the implementation of public health programs and veterinary applications. Currently, the research for new pyrethroids has essentially reached a standstill due to the increasingly widespread occurrence of insecticide resistance in pests. Nevertheless, several research paths remain open regarding these pesticides. This paper represents the current state of knowledge regarding pyrethroids, exposing both their advantages and disadvantages. Moreover, further investigation, at the molecular level, on their mode of action (MoA) could be very useful to improve their specificity. The results of this review may stimulate additional research for the development of novel pyrethroids having enhanced efficacy, low cost and reduced environmental impact. Full article

Here, we describe some well-known multicomponent reactions and the progress made over the past decade to make these processes even more environmentally friendly. We focus on the Mannich, Hantzsch, Biginelli, Ugi, Passerini, Petasis, and Groebke–Blackburn–Bienaymé reactions. After describing the origin of the reactions and their mechanisms, we summarize some advances in terms of the eco-compatibility of these different MCRs. These are followed by examples of some reactions, considered as variants, which are less well documented but which are promising in terms of structures generated or synthetic routes. Full article

The aquatic ecotoxicity of three α-amino acid-derived polyamidoamines (PAAs) was studied using zebrafish embryos as a viable vertebrate model organism. The PAAs examined were water-soluble amphoteric polyelectrolytes with a primarily negative charge, which were efficient flame retardants for cotton. The fish embryo acute toxicity test performed with PAA water solutions using 1.5–500 mg L⁻¹ concentrations showed that toxicity did not statistically differ from the control. The survival rates were indeed >90%, even at the highest concentration; the hatching rates were >80%; and the numbers of morphological defects were comparable to those of the control. Tests using transgenic zebrafish lines indicated that the numbers of microscopic vascular and musculoskeletal defects were comparable to the control, with one random concentration showing doubled alterations. Sensory–motor tests in response to visual and tactile stimuli were also performed. In the presence of PAAs, embryos exposed to alternating light/dark cycles showed an insignificant mobility reduction during the dark phase. Touch-evoked response tests revealed a mild effect of PAAs on the neuromotor system at concentrations > 10 mg L⁻¹. The cystine/glycine copolymer at 100 mg L⁻¹ exhibited the greatest effect. Overall, the studied PAAs showed a minimal impact on aquatic systems and should be further considered as promising ecofriendly materials. Full article

There is currently growing interest in the creation of artificial microbial consortia, especially in the field of developing and applying various bioremediation processes. Heavy metals, dyes, synthetic polymers (microplastics), pesticides, polycyclic aromatic hydrocarbons and pharmaceutical agents are among the pollutants that have been mainly targeted by bioremediation based on various consortia containing fungi (mycelial types and yeasts). Such consortia can be designed both for the treatment of soil and water. This review is aimed at analyzing the recent achievements in the research of the artificial microbial consortia that are useful for environmental and bioremediation technologies, where various fungal cells are applied. The main tendencies in the formation of certain microbial combinations, and preferences in their forms for usage (suspended or immobilized), are evaluated using current publications, and the place of genetically modified cells in artificial consortia with fungi is assessed. The effect of multicomponence of the artificial consortia containing various fungal cells is estimated, as well as the influence of this factor on the functioning efficiency of the consortia and the pollutant removal efficacy. The conclusions of the review can be useful for the development of new mixed microbial biocatalysts and eco-compatible remediation processes that implement fungal cells. Full article

Among semiconductor metal oxides, that are an important class of sensing materials, titanium dioxide (TiO₂) thin films are widely employed as sensors because of their high chemical and mechanical stability in harsh environments, non-toxicity, eco-compatibility, and photocatalytic properties. TiO₂-based chemical oxygen demand (COD) sensors exploit the photocatalytic properties of TiO₂ in inducing the oxidation of organic compounds to CO₂. In this work, we discuss nanostructured TiO₂ thin films grown via low-pressure metal organic chemical vapor deposition (MOCVD) on metallic AISI 316 mesh. To increase the surface sensing area, different inorganic acid-based chemical etching protocols have been developed, determining the optimal experimental conditions for adequate substrate roughness. Both chemically etched pristine meshes and the MOCVD-coated ones have been studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray (EDX) microanalysis, and X-ray photoelectron spectroscopy (XPS). We demonstrate that etching by HCl/H₂SO₄ at 55 °C provides the most suitable surface morphology. To investigate the behavior of the developed high surface area TiO₂ thin films as COD sensors, photocatalytic degradation of functional model pollutants based on ISO 10678:2010 has been tested, showing for the best performing acid-etched mesh coated with polycrystalline TiO₂ an increase of 60% in activity, and degrading 66 µmol of MB per square meter per hour. Full article

Intensive agriculture maintains high crop yields through chemical inputs, which are well known for their adverse effects on environmental quality and human health. Innovative technologies are required to reduce the risk generated by the extensive and harmful use of pesticides. The plant biostimulants made from humic substances isolated from recyclable biomass offer an alternative approach to address the need for replacing conventional agrochemicals without compromising the crop yield. The stimulatory effects of humic substances are commonly associated with plant hormones, particularly auxins. However, jasmonic acid (JA) is crucial metabolite in mediating the defence responses and governing plant growth and development. This work aimed to evaluate the changes in the biosynthesis and signalling pathway of JA in tomato seedlings treated with humic acids (HA) isolated from vermicompost. We use the tomato model system cultivar Micro-Tom (MT) harbouring a reporter gene fused to a synthetic promoter that responds to jasmonic acid (JERE::GUS). The transcript levels of genes involved in JA generation and activity were also determined using qRT-PCR. The application of HA promoted plant growth and altered the JA status, as revealed by both GUS and qRT-PCR assays. Both JA enzymatic synthesis (LOX, OPR3) and JA signalling genes (JAZ and JAR) were found in higher transcription levels in plants treated with HA. In addition, ethylene (ETR4) and auxin (ARF6) signalling components were positively modulated by HA, revealing a hormonal cross-talk. Our results prove that the plant defence system linked to JA can be emulated by HA application without growth inhibition. Full article

Symmetrical and dissymmetrical bolaforms were prepared with good to high yields from unsaturated L-rhamnosides and phenolic esters (ferulic, phloretic, coumaric, sinapic and caffeic) using two eco-compatible synthetic strategies involving glycosylation, enzymatic synthesis and cross-metathesis under microwave activation. The plant-eliciting activity of these new compounds was investigated in Arabidopsis model plants. We found that the monocatenar rhamnosides and bolaforms activate the plant immune system with a response depending on the carbon chain length and the nature of the hydrophilic heads. Their respective antioxidant activities were also evaluated, as well as their cytotoxic properties on dermal cells for cosmetic uses. We showed that phenolic ester-based compounds present good antioxidant activities and that their cytotoxicity is low. These properties are also dependent on the carbon chains used. Full article

Geopolymer, a sustainable alternative to ordinary Portland cement (OPC), offers reduced embodied energy, lower carbon emissions, enhanced durability, eco-compatibility, and waste valorization potential. In confining structural members, geopolymer still has limitations with respect to its brittleness and other properties. Enhancing the properties of geopolymer by adding banana fibers (BF) and fly ash (FA) to form banana geotextile-reinforced geopolymer mortar (BGT-RGM) as confining material, is investigated in this experimental study. BGT-RGM is a textile-reinforced mortar with varying thickness of BF-reinforced geopolymer mortar (BFRGM) through NaOH-treated 10 mm BFs and 2 mm banana geotextile (BGT) having varied grid spacings. To develop BGT-RGM, the physical, mechanical, and chemical properties of the BFs were determined, while BFRGMs were evaluated for compressive and dog-bone tensile strengths, workability, scanning electron microscopy (SEM) imaging, and thermogravimetric analysis (TGA). The BGT-RGM-confined and unconfined concrete were evaluated, and the strength variations were imparted by the confinement as reflected on the stress-strain curves. The local crack formation mode of failure was also determined through crack patterns during an axial load test. The BGT-RGM with 20 mm thickness of BFRGM with 15 mm and 20 mm geotextile grid spacings, exhibited 33.3% and 33.1% increases in strength, respectively. Future investigations towards the development and application of BGT-RGM are also discussed. Full article

The work carried out as part of construction on a ring road around Nardò (Lecce, South Italy) involved a votive aedicule attached to the perimeter wall of a rural building that had been scheduled for demolition. Provision was made for the movement and relocation of the building, dedicated to St. Mary Magdalene, to an adjacent area, in addition to the restoration of the pictorial decoration itself. The intervention was designed to conserve the building as testimony of its use for future generations, given its value and sense of identity for the local community. The project was largely conservatory, thus guaranteeing the continuity of its still active devotional function. In this sense, the restoration of the building was also associated with an educational aim of raising awareness of the importance of eco-compatible care of the landscape. So, this project highlights the importance of social, as much as environmental, sustainability. Full article

Photoaging is the premature aging of the skin caused by repeated exposure to ultraviolet (UV) rays. The harmful effects of UV rays—from the sun or from artificial sources—alter normal skin structures and cause visible damage, especially in the most exposed areas. Fighting premature aging is one of the most important challenges of the medical landscape. Additionally, consumers are looking for care products that offer multiple benefits with reduced environmental and economic impact. The growing requests for bioactive compounds from aromatic plants for pharmaceutical and cosmetic applications have to find new sustainable methods to increase the effectiveness of new active formulations derived from eco-compatible technologies. The principle of sustainable practices and the circular economy favor the use of bioactive components derived from recycled biomass. The guidelines of the European Commission support the reuse of various types of organic biomass and organic waste, thus transforming waste management problems into economic opportunities. This review aims to elucidate the main mechanisms of photoaging and how these can be managed using natural renewable sources and specific bioactive derivatives, such as humic extracts from recycled organic biomass, as potential new actors in modern medicine. Full article