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25 pages, 19784 KB  
Article
Spatiotemporal Dynamics of Anthropogenic Night Light in China
by Christopher Small
Lights 2025, 1(1), 4; https://doi.org/10.3390/lights1010004 - 21 Nov 2025
Viewed by 393
Abstract
Anthropogenic night light (ANL) provides a unique observable for the spatially explicit mapping of human-modified landscapes in the form of lighted infrastructure. Since 2013, the Visible Infrared Imaging Radiometer Suite (VIIRS) Day Night Band (DNB) on the Suomi NPP satellite has provided more [...] Read more.
Anthropogenic night light (ANL) provides a unique observable for the spatially explicit mapping of human-modified landscapes in the form of lighted infrastructure. Since 2013, the Visible Infrared Imaging Radiometer Suite (VIIRS) Day Night Band (DNB) on the Suomi NPP satellite has provided more than a decade of near-daily observations of anthropogenic night light. The objective of this study is to quantify changes in ANL in developed eastern China post-2013 using VIIRS DNB monthly mean brightness composites. Specifically, to constrain sub-annual and interannual changes in night light brightness to distinguish between apparent and actual change of ANL sources, and then conduct a spatiotemporal analysis of observed changes to identify areas of human activity, urban development and rural electrification. This analysis is based on a combination of time-sequential bitemporal brightness distributions and quantification of the spatiotemporal evolution of night light using Empirical Orthogonal Function (EOF) analysis. Bitemporal brightness distributions show that bright (>~1 nW/cm2/sr) ANL is heteroskedastic, with temporal variability diminishing with increasing brightness. Hence, brighter lights are more temporally stable. In contrast, dimmer (<~1 nW/cm2/sr) ANL is much more variable on monthly time scales. The same patterns of heteroskedasticity and variability of the lower tail of the brightness distribution are observed in year-to-year distributions. However, year-to-year brightness increases vary somewhat among different years. While bivariate distributions quantify aggregate changes on both subannual and interannual time scales, spatiotemporal analysis quantifies spatial variations in the year-to-year temporal evolution of ANL. The spatial distribution of brightening (and, much less commonly, dimming) revealed by the EOF analysis indicates that most of the brightening since 2013 has occurred at the peripheries of large cities and throughout the networks of smaller settlements on the North China Plain, the Yangtze River Valley, and the Sichuan Basin. A particularly unusual pattern of sequential brightening and dimming is observed on the Loess Plateau north of Xi’an, where extensive terrace construction has occurred. All aspects of this analysis highlight the difference between apparent and actual changes in night light sources. This is important because many users of VIIRS night light attribute all observed changes in imaged night light to actual changes in anthropogenic light sources—without consideration of low luminance variability related to the imaging process itself. Full article
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21 pages, 4852 KB  
Article
Series Arc Fault Detection Method Based on Time Domain Imaging and Long Short-Term Memory Network for Residential Applications
by Ruobo Chu, Schweitzer Patrick and Kai Yang
Algorithms 2025, 18(8), 497; https://doi.org/10.3390/a18080497 - 11 Aug 2025
Viewed by 1421
Abstract
This article presents a novel method for detecting series arc faults (SAFs) in residential applications using time-domain imaging (TDI) and Long Short-Term Memory (LSTM) networks. The proposed method transforms current signals into grayscale images by filtering out the fundamental frequency, allowing key arc [...] Read more.
This article presents a novel method for detecting series arc faults (SAFs) in residential applications using time-domain imaging (TDI) and Long Short-Term Memory (LSTM) networks. The proposed method transforms current signals into grayscale images by filtering out the fundamental frequency, allowing key arc fault characteristics—such as high-frequency noise and waveform distortions—to become visually apparent. The use of Ensemble Empirical Mode Decomposition (EEMD) helped isolate meaningful signal components, although it was computationally intensive. To address real-time requirements, a simpler yet effective TDI method was developed for generating 2D images from current data. These images were then used as inputs to an LSTM network, which captures temporal dependencies and classifies both arc faults and appliance types. The proposed TDI-LSTM model was trained and tested on 7000 labeled datasets across five common household appliances. The experimental results show an average detection accuracy of 98.1%, with reduced accuracy for loads using thyristors (e.g., dimmers). The method is robust across different appliance types and conditions; comparisons with prior methods indicate that the proposed TDI-LSTM approach offers superior accuracy and broader applicability. Trade-offs in sampling rates and hardware implementation were discussed to balance accuracy and system cost. Overall, the TDI-LSTM approach offers a highly accurate, efficient, and scalable solution for series arc fault detection in smart home systems. Full article
(This article belongs to the Special Issue AI and Computational Methods in Engineering and Science)
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18 pages, 10902 KB  
Article
Analyzing the Sources and Variations of Nighttime Lights in Hong Kong from VIIRS Monthly Data
by Shengjie Liu, Chu Wing So and Chun Shing Jason Pun
Remote Sens. 2025, 17(8), 1447; https://doi.org/10.3390/rs17081447 - 18 Apr 2025
Cited by 4 | Viewed by 3432
Abstract
The long-term monitoring of nighttime lights is essential for understanding sources of light pollution. Nighttime lights observed in space are affected by atmospheric conditions as they transmit from the Earth surface through clouds and aerosols to the top of the atmosphere. In this [...] Read more.
The long-term monitoring of nighttime lights is essential for understanding sources of light pollution. Nighttime lights observed in space are affected by atmospheric conditions as they transmit from the Earth surface through clouds and aerosols to the top of the atmosphere. In this study, based on the monthly cloud-free VIIRS/DNB products, we analyzed the long-term nighttime lights in Hong Kong (2012–2020). We found that the monthly variations in nighttime lights were large, especially in bright regions. The 12-month average of nighttime lights ranged from 13.0 to 18.9 nWcm−2sr−1. Public transportation facilities, such as port facilities and the airport, were the brightest, twice as bright as other urban areas. Public residential areas were slightly brighter than private ones. These urban areas were at least four times brighter than undeveloped regions, showing a significant alteration in light at night due to artificial facilities. Further, we used an unsupervised clustering method to identify specific patterns. While nighttime lights were stable in most regions, increasing trends were found at construction sites of a new artificial island and the airport expansion. Abnormal patterns, such as wildfires, were also recognized. We found that the background nighttime lights were brighter in wet months (e.g., April) and dimmer in dry months (e.g., January). The amount of water in the atmosphere affects nighttime light scattering, with a linear correlation (R = 0.68) between humidity and the occurrence of bright nighttime lights each month. The diverse sources and variations in nighttime lights call for continuous monitoring and advanced analytical methods to better understand their environmental and societal impacts. Full article
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17 pages, 1427 KB  
Article
Tropical Glaciation and Glacio-Epochs: Their Tectonic Origin in Paleogeography
by Hsien-Wang Ou
Climate 2025, 13(1), 9; https://doi.org/10.3390/cli13010009 - 2 Jan 2025
Cited by 1 | Viewed by 1374
Abstract
Precambrian tropical glaciation is an enigma of Earth’s climate. Overlooking fundamental difference of land/sea icelines, it was equated with a global frozen ocean, which is at odds with the sedimentary evidence of an active hydrological cycle, and its genesis via the runaway ice–albedo [...] Read more.
Precambrian tropical glaciation is an enigma of Earth’s climate. Overlooking fundamental difference of land/sea icelines, it was equated with a global frozen ocean, which is at odds with the sedimentary evidence of an active hydrological cycle, and its genesis via the runaway ice–albedo feedback conflicts with the mostly ice-free Proterozoic when its trigger threshold was well exceeded by the dimmer sun. In view of these shortfalls, I put forth two key hypotheses of the tropical glaciation: first, if seeded by mountain glaciers, the land ice would advance on sea level to be halted by above-freezing summer temperature, which thus abuts an open cozonal ocean; second, a tropical supercontinent would block the brighter tropical sun to cause the required cooling. To test these hypotheses, I formulate a minimal tropical/polar box model to examine the temperature response to a varying tropical land area and show that tropical glaciation is indeed plausible when the landmass is concentrated in the tropics despite uncertain model parameters. In addition, given the chronology of paleogeography, the model may explain the observed deep time climate to provide a unified account of the faint young Sun paradox, Precambrian tropical glaciations, and Phanerozoic glacio-epochs, reinforcing, therefore, the uniformitarian principle. Full article
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19 pages, 8774 KB  
Article
Simulation Environment for the Testing of Electrical Arc Fault Detection Algorithms
by Jinmi Lezama, Patrick Schweitzer, Etienne Tisserand and Serge Weber
Electronics 2024, 13(20), 4099; https://doi.org/10.3390/electronics13204099 - 17 Oct 2024
Cited by 3 | Viewed by 2596
Abstract
Electrical arc fault detector development requires many tests to develop and validate detection algorithms. The use of artificial intelligence or mathematical transformation requires the use of consequential datasets of current signatures corresponding to as many different situations as possible. In addition, one of [...] Read more.
Electrical arc fault detector development requires many tests to develop and validate detection algorithms. The use of artificial intelligence or mathematical transformation requires the use of consequential datasets of current signatures corresponding to as many different situations as possible. In addition, one of the main drawbacks is that these experiments take a great deal of time and are often laborious in the laboratory. To overcome these limitations, a virtual test bench based on the modeling of a modular 230 VAC electrical circuit has been developed. The simulated network is composed of different home appliances (resistor, vacuum cleaner, dimmer, etc.) and its configurations are those of single and combined loads. The fault modeled is an electric arc, modeled by active diode switching, which can be inserted at any point of the circuit. This arc model takes into account the random variations in the restrike and arc voltage. All the appliance models are validated by comparing the frequential (harmonic distortion) and temporal (agreement index) signatures of the measured currents in real situations to those obtained by modeling. The results obtained using the model and experiment network show that the current signatures are comparable in both cases. Further, two detection algorithms are tested on those current signatures obtained by the modeling and experimentation. The results are comparable and provide identical detection thresholds. Full article
(This article belongs to the Special Issue Compatibility, Power Electronics and Power Engineering)
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12 pages, 1572 KB  
Article
Sperm Chromatin Dispersion Test Detects Sperm DNA Fragmentation Mainly Associated with Unviable Spermatozoa and Underestimates the Values with Respect to TUNEL Assay
by Maria Emanuela Ragosta, Giulia Traini, Lara Tamburrino, Selene Degl’Innocenti, Maria Grazia Fino, Sara Dabizzi, Linda Vignozzi, Elisabetta Baldi and Sara Marchiani
Int. J. Mol. Sci. 2024, 25(8), 4481; https://doi.org/10.3390/ijms25084481 - 19 Apr 2024
Cited by 8 | Viewed by 4197
Abstract
Several clinical laboratories assess sperm DNA fragmentation (sDF) in addition to semen analysis in male infertility diagnosis. Among tests evaluating sDF, TUNEL (Terminal deoxynucleotidyl transferase dUTP nick end labeling) and SCD (Sperm Chromatin Dispersion) are widely used. Our lab developed a modified version [...] Read more.
Several clinical laboratories assess sperm DNA fragmentation (sDF) in addition to semen analysis in male infertility diagnosis. Among tests evaluating sDF, TUNEL (Terminal deoxynucleotidyl transferase dUTP nick end labeling) and SCD (Sperm Chromatin Dispersion) are widely used. Our lab developed a modified version of TUNEL (TUNEL/PI) able to distinguish two sperm populations (PI Brighter and PI Dimmer) differently associated with sperm viability and reproductive outcomes. The aim of this study was to compare sDF levels detected by SCD and TUNEL/PI in the semen samples from 71 male subjects attending our Andrology Laboratory. Our results demonstrate that SCD is less sensitive in determining sDF compared to TUNEL/PI. The statistically significant positive correlation found between sDF evaluated by SCD and PI Dimmer (consisting of all dead spermatozoa) suggests that SCD mainly detects sDF in unviable spermatozoa. We confirmed that most spermatozoa detected by SCD are unviable by performing SCD after incubation in hypo-osmotic medium to discriminate viable and unviable cells in 52 samples. Such results might explain the lower ability of this test in discriminating couples having successful ART outcomes demonstrated in published metanalyses. Overall, our results indicate that SCD is less sensitive in evaluating sDF for diagnostic purposes. Full article
(This article belongs to the Collection Feature Papers in “Molecular Biology”)
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10 pages, 4047 KB  
Article
Photonic Weyl Waveguide and Saddle-Chips-like Modes
by Hanyu Wang, Wei Xu, Zhihong Zhu and Biao Yang
Nanomaterials 2024, 14(7), 620; https://doi.org/10.3390/nano14070620 - 1 Apr 2024
Cited by 1 | Viewed by 2143
Abstract
Topological Weyl semimetals are characterized by open Fermi arcs on their terminal surfaces, these materials not only changed accepted concepts of the Fermi loop but also enabled many exotic phenomena, such as one-way propagation. The key prerequisite is that the two terminal surfaces [...] Read more.
Topological Weyl semimetals are characterized by open Fermi arcs on their terminal surfaces, these materials not only changed accepted concepts of the Fermi loop but also enabled many exotic phenomena, such as one-way propagation. The key prerequisite is that the two terminal surfaces have to be well separated, i.e., the Fermi arcs are not allowed to couple with each other. Thus, their interaction was overlooked before. Here, we consider coupled Fermi arcs and propose a Weyl planar waveguide, wherein we found a saddle-chips-like hybridized guiding mode. The hybridized modes consist of three components: surface waves from the top and bottom surfaces and bulk modes inside the Weyl semimetal. The contribution of these three components to the hybridized mode appears to be z-position-dependent rather than uniform. Beyond the conventional waveguide framework, those non-trivial surface states, with their arc-type band structures, exhibit strong selectivity in propagation direction, providing an excellent platform for waveguides. Compared with the conventional waveguide, the propagation direction of hybridized modes exhibits high z-position-dependency. For example, when the probe plane shifts from the top interface to the bottom interface, the component propagating horizontally becomes dimmer, while the component propagating vertically becomes brighter. Experimentally, we drilled periodic holes in metal plates to sandwich an ideal Weyl meta-crystal and characterize the topological guiding mode. Our study shows the intriguing behaviors of topological photonic waveguides, which could lead to beam manipulation, position sensing, and even 3D information processing on photonic chip. The Weyl waveguide also provides a platform for studying the coupling and the interaction between surface and bulk states. Full article
(This article belongs to the Special Issue 2D Materials and Metamaterials in Photonics and Optoelectronics)
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8 pages, 2763 KB  
Article
High Electric Field Enhancement Induced by Modal Coupling for a Plasmonic Dimer Array on a Metallic Film
by Jiawei Liu, Ziming Meng and Jinyun Zhou
Photonics 2024, 11(2), 183; https://doi.org/10.3390/photonics11020183 - 17 Feb 2024
Cited by 4 | Viewed by 2093
Abstract
A giant electric field on a subwavelength scale is highly beneficial for boosting the light–matter interaction. In this paper, we investigated a hybrid structure consisting of a hemispheric dimer array and a gold film and realized resonant mode coupling of the surface lattice [...] Read more.
A giant electric field on a subwavelength scale is highly beneficial for boosting the light–matter interaction. In this paper, we investigated a hybrid structure consisting of a hemispheric dimer array and a gold film and realized resonant mode coupling of the surface lattice resonance (SLR) and surface plasmon polariton (SPP). Mode coupling is demonstrated by observing anti-crossing in reflection spectra, which corresponds to Rabi splitting. Although the resonance coupling does not enter the strong coupling regime, an improved quality factor (Q~350) and stronger electric field enhancement in the gap region of the dimer (i.e., hot spot) in our hybrid structure are obtained compared to those of the single dimer or dimer array only. Remarkably, the magnitude of electric field enhancement over 500 can be accessible. Such high field enhancement makes our hybridized structure a versatile platform for the realization of ultra-sensitive biosensing, low-threshold nanolasing, low-power nonlinear optical devices, etc. Full article
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7 pages, 2082 KB  
Proceeding Paper
Conception of a Lighting Control and Management System with Graphical User Interface
by Mohamed Issam Ziane, Ghanem Kamel Ghalem, Bouchra Djelloul and Hadjer Khelil
Eng. Proc. 2023, 37(1), 32; https://doi.org/10.3390/ECP2023-14658 - 17 May 2023
Cited by 1 | Viewed by 1683
Abstract
Lighting is the largest source of electricity consumption. The implementation of new technologies makes it possible to reduce the energy bill as well as the operating costs. In this work, we created a control and management system for exterior lighting using creative, intelligent, [...] Read more.
Lighting is the largest source of electricity consumption. The implementation of new technologies makes it possible to reduce the energy bill as well as the operating costs. In this work, we created a control and management system for exterior lighting using creative, intelligent, and autonomous methods. The project allows control room operators to monitor the system and interact when needed. Our project is subdivided into three major parts, ordering, data processing, and action. The first part is carried out in two modes: manually using an Optocoupler and controlled with a graphical interface by RS232 serial-type communication. The second part is processed by a microcontroller; as for the third part, it controls three poles through an MOC3023 Optotriac IC and BTA16-600B Triac for full and half lighting. For the controlled mode, we used the dimmer principle which works by essentially chopping parts out of the AC voltage. The brightness of the lamp is determined by the power transferred to it, so the more the waveform is chopped, the more it dims. A zero crossing control is needed for phase cutting. The graphical application of our project has a rather rough design. It is divided into two windows: the first consists of a connection window, and the second one is for the main control interface. On this control interface, there are basically three tabs: connection and serial connection status, control, and operating mode. Full article
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10 pages, 4256 KB  
Communication
A Novel Single X-Wire AM Mini-LED Backlight Unit with Motion Blur Reduction for High-Image-Quality LCD TVs
by Hansai Ji, Youngjin Lim, Chenghui Yan, Jinle Li, Zhiguo Li and Di Geng
Electronics 2023, 12(8), 1936; https://doi.org/10.3390/electronics12081936 - 20 Apr 2023
Cited by 3 | Viewed by 3146
Abstract
We have demonstrated a high-image-quality 85-inch 4 K high-dynamic-range (HDR) LCD display with 2304 dimming zones using a single X-wire AM mini-LED backlight unit (BLU) with motion blur and residual image reduction technology. Our latest work proposed the new single X-wire AM driving [...] Read more.
We have demonstrated a high-image-quality 85-inch 4 K high-dynamic-range (HDR) LCD display with 2304 dimming zones using a single X-wire AM mini-LED backlight unit (BLU) with motion blur and residual image reduction technology. Our latest work proposed the new single X-wire AM driving method, consisting of one matrix control IC/dimming controller (DCON) and X-wires of mini-LED driver ICs (dimmers), which eliminates extra scanning, sensing lines and pixel/source driver IC using an adaptive addressing dimming method. Additionally, a single X-wire controlled system can realize a flexible and expandable layout, which can achieve ultra thin and low cost in ultra-high dimming zones and large size display. Furthermore, the horizontal-scan (H-scan) driving method, which reduces motion blur and residual images using a scanning black frame insertion (BFI) technology, is utilized. The proposed mini-LED BLU can save about 9% power consumption compared to the conventional one in normal displays. Full article
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18 pages, 1607 KB  
Article
Construction and Evaluation of a Novel MAP Immunoassay for 9 Nutrition-and-Health-Related Protein Markers Based on Multiplex Liquid Protein Chip Technique
by Jiyong Yin, Jiangping Niu, Junsheng Huo, Jing Sun, Jian Huang and Chaoqun Sun
Nutrients 2023, 15(6), 1522; https://doi.org/10.3390/nu15061522 - 21 Mar 2023
Cited by 2 | Viewed by 2449
Abstract
We attempted to construct and evaluate a novel detection method to realize simultaneous detection based on a multiplex liquid protein chip technique for nine nutrition-and-health-related protein markers to meet the requirement of an accurate, simultaneous and comprehensive analysis of the proteomics of nutrition [...] Read more.
We attempted to construct and evaluate a novel detection method to realize simultaneous detection based on a multiplex liquid protein chip technique for nine nutrition-and-health-related protein markers to meet the requirement of an accurate, simultaneous and comprehensive analysis of the proteomics of nutrition and health. The lower limits of detection, biological limits of detection and regression equations of serum ferritin (SF), soluble transferrin receptor (sTfR), c-reactive protein (CRP), retinol-binding protein4 (RBP4), apolipoprotein B (ApoB), alpha-fetoprotein (AFP), prealbumin (PA), carcino-embryonic antigen (CEA) and D-Dimmer (D-D) were determined after a series of optimal experiments. Then, the results of the methodological evaluation for this novel method indicated that the accuracies were between 70.12% and 127.07%, the within-run precisions were between 0.85% and 7.31%, the between-run precisions were between 3.53% and 19.07%, the correlation coefficients between this method and other methods were above 0.504 (p < 0.05), and the direct bilirubin (DBIL) of low concentration and the indirect bilirubin (IBIL) of high concentration could not interfere with the detected results of nine indicators. The novel multiplex detection method, which can increase accuracy and improve the ability of comprehensive analysis, can basically meet the requirement of detection and the diagnosis of the proteomics of nutrition and health. Full article
(This article belongs to the Section Nutrition Methodology & Assessment)
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17 pages, 8996 KB  
Article
Efficiency Analysis of Roadway Lighting Replacement in a Selected Polish Municipality
by Krzysztof Zima and Wojciech Ciepłucha
Appl. Sci. 2023, 13(5), 3257; https://doi.org/10.3390/app13053257 - 3 Mar 2023
Cited by 8 | Viewed by 3079
Abstract
The paper addresses the problem of the efficiency of road lighting replacement in a selected municipality. The following question arose: can the replacement of lighting bring measurable financial benefits in the short or long term, and does increasing the comfort of road use [...] Read more.
The paper addresses the problem of the efficiency of road lighting replacement in a selected municipality. The following question arose: can the replacement of lighting bring measurable financial benefits in the short or long term, and does increasing the comfort of road use in terms of lighting involve higher costs? During the global energy crisis, reducing the operating costs of road lighting has become the goal of many analyses and studies. Professionally selected lighting of streets and sidewalks is a factor that significantly affects the safety of road users. The problem of many studies is the omission of safety considerations, lighting comfort and budgetary possibilities of municipalities. The authors conducted comparative analyses of solution variants, examining both road lighting comfort and costs as an innovative element of research. The DIALux application was used to analyse the changes in road lighting depending on the luminaires used and the changes in pole spacing influenced by the height of the light point. Variant and scenario analyses were incorporated into the efficiency analyses, while the calculations themselves were based on detailed cost analyses with reference to Polish catalogues of material inputs and market prices. The authors conducted cost analyses of lighting dismantling and installation, including the subsequent operating costs over 20 years for seven variants of poles with their systems and four variants of luminaires. The results were compared with the existing lighting system in use. An original element of the study is the use of BIM analyses with design variants, combined with analyses of the technical condition of the existing lighting network and an illuminance analysis with estimates of the height and spacing of poles. Numerous studies indicate that it is very cost-effective to replace old lighting systems, especially those based on high-intensity discharge (HID) sodium lamps, with more modern LED lamps additionally equipped with twilight dimmers. The analyses also demonstrated that cost-efficient lighting replacement could go hand in hand with improved road lighting comfort without the need to incur additional costs, which is often overlooked in various studies. The analysis performed for a model lighting network indicates that savings of nearly 60% are possible over 20 years. Full article
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23 pages, 4233 KB  
Review
An Overview of the Penguin Visual System
by Peter W. Hadden and Jie Zhang
Vision 2023, 7(1), 6; https://doi.org/10.3390/vision7010006 - 17 Jan 2023
Cited by 7 | Viewed by 10481
Abstract
Penguins require vision that is adequate for both subaerial and submarine environments under a wide range of illumination. Here we provide a structured overview of what is known about their visual system with an emphasis on how and how well they achieve these [...] Read more.
Penguins require vision that is adequate for both subaerial and submarine environments under a wide range of illumination. Here we provide a structured overview of what is known about their visual system with an emphasis on how and how well they achieve these goals. Amphibious vision is facilitated by a relatively flat cornea, the power in air varying from 10.2 dioptres (D) to 41.3 D depending on the species, and there is good evidence for emmetropia both above and below water. All penguins are trichromats with loss of rhodopsin 2, a nocturnal feature, but only deeper diving penguins have been noted to have pale oil droplets and a preponderance of rods. Conversely, the diurnal, shallow-diving little penguin has a higher ganglion cell density (28,867 cells/mm2) and f-number (3.5) than those that operate in dimmer light. In most species studied, there is some binocular overlap, but this reduces upon submergence. However, gaps in our knowledge remain, particularly with regard to the mechanism of accommodation, spectral transmission, behavioural measurements of visual function in low light, and neural adaptations to low light. The rarer species also deserve more attention. Full article
(This article belongs to the Special Issue Vision in Aquatic Environment)
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6 pages, 999 KB  
Proceeding Paper
Use of Oxidative Coupling Strategy as a Means to Increase In Vitro Antioxidant Activity of Vanillin Derivatives
by Leandro G. Gutierrez, Ana P. Reinick, Carla M. Ormachea, Vanina A. Guntero and Cristián A. Ferretti
Chem. Proc. 2022, 12(1), 31; https://doi.org/10.3390/ecsoc-26-13553 - 14 Nov 2022
Cited by 1 | Viewed by 1733
Abstract
The aim of this study was to investigate the antioxidant properties in vitro of three different vanillic dimmers (Compounds 1a–c). They were synthesized through an oxidative coupling strategy in good yields. The targeted compounds were found to be highly active for the [...] Read more.
The aim of this study was to investigate the antioxidant properties in vitro of three different vanillic dimmers (Compounds 1a–c). They were synthesized through an oxidative coupling strategy in good yields. The targeted compounds were found to be highly active for the total antioxidant assay, as well as for the lipid peroxidation test. All investigated compounds exhibited superior or comparable antioxidant capacity in comparison to precursor vanillin, proving that oxidative coupling is a great strategy to increase the antioxidant behavior of vanillin derivatives. Full article
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11 pages, 2042 KB  
Article
How Extraction and Purification Affect MALDI-TOF MS Characterization of Mangrove Condensed Tannins, An Ecologically Important Secondary Metabolites in Coastal Wetland Ecosystem
by Tao Lang, Ping Xiang, Mingdang Li, Zhiteng Chen, Fenglan Li, Mingguo Jiang and Haichao Zhou
Sustainability 2022, 14(22), 14960; https://doi.org/10.3390/su142214960 - 11 Nov 2022
Cited by 5 | Viewed by 2360
Abstract
Mangrove plants are rich in tannins, especially condensed tannins (CTs), which play an important role in biogeochemistry in coastal wetland ecosystem due to their functions of binding nutrients and heavy metal chelation. This study aims to obtain authentic chemical structures of mangrove CTs [...] Read more.
Mangrove plants are rich in tannins, especially condensed tannins (CTs), which play an important role in biogeochemistry in coastal wetland ecosystem due to their functions of binding nutrients and heavy metal chelation. This study aims to obtain authentic chemical structures of mangrove CTs by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS). Four organic solvents (n-hexane, ether, chloroform, and EtOAc (ethyl acetate)) were used for extraction tests and three purification methods (Method 1, Sephadex LH-20 absorbed tannins, and nontannins fraction were washed by 50% methanol (mp) solution; Method 2, Sephadex LH-20 absorbed tannins and nontannins fraction were washed by 100% ethanol (ep), and released in 70% acetone solution; and Method 3, Yb3+ selectivity precipitated tannins) were conducted to investigate their influences on the characterization of CTs from two mangrove species, Bruguiera gymnorhiza and Kandelia obovata. The results showed that (1) EtOAc was used as an extraction solvent, leading to unauthentic structural properties of CTs; (2) the distribution patterns of the polymers in mangrove CTs purified with 50% methanol elicited the least different trends with those of CTs in the two mangrove crude extracts, and the lower oligomers (dimmer-hexamer) and higher polymers were lost during purification of CTs by 100% ep. Therefore, based on the toxicity and price of solvents, the crude CTs from mangrove plants can be extracted with n-hexane or ether to remove lipid and pigment impurities and then purified with 50% methanol, which is a complete set of methods to obtain completely authentic structural information of mangrove CTs. This study can offer more accurate structural information of mangrove CTs and new insights for the conservation of mangrove living environments for follow-up research. Full article
(This article belongs to the Special Issue Research on Water and Soil Conservation)
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