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Article

52 Citations

4,296 Views

14 Pages

A Molecular Electron Density Theory Study of the Chemoselectivity, Regioselectivity, and Diastereofacial Selectivity in the Synthesis of an Anticancer Spiroisoxazoline derived from α-Santonin

Luis R. Domingo,
Mar Ríos-Gutiérrez and
Nivedita Acharjee

Molecules2019, 24(5), 832;https://doi.org/10.3390/molecules24050832

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26 February 2019

The [3 + 2] cycloaddition (32CA) reaction of an α-santonin derivative, which has an exocyclic C–C double bond, with p-bromophenyl nitrile oxide yielding only one spiroisoxazoline, has been studied within the molecular electron density the...

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Article

17 Citations

8,568 Views

13 Pages

Study of Stereoselectivity in Organometallic Additions to 1,2-O-Isopropylidene-O-R-α-D-xylopentodialdo-1,4-furanose

Tibor Gracza and
Peter Szolcsányi

Molecules2000, 5(12), 1386-1398;https://doi.org/10.3390/51201386

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21 December 2000

Diastereofacial selectivity of the addition of organometallic reagents to 1,2-Oisopropylidene-O-R-α-D-xylopentodialdo-1,4-furanoses (6) was studied.

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